CN1796623B - Composite fiber with excellent conductivity and method for manufacturing same - Google Patents
Composite fiber with excellent conductivity and method for manufacturing same Download PDFInfo
- Publication number
- CN1796623B CN1796623B CN2005101025740A CN200510102574A CN1796623B CN 1796623 B CN1796623 B CN 1796623B CN 2005101025740 A CN2005101025740 A CN 2005101025740A CN 200510102574 A CN200510102574 A CN 200510102574A CN 1796623 B CN1796623 B CN 1796623B
- Authority
- CN
- China
- Prior art keywords
- conductive
- cnt
- core
- weight
- manufacture method
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000000835 fiber Substances 0.000 title claims abstract description 33
- 239000002131 composite material Substances 0.000 title claims abstract description 20
- 238000000034 method Methods 0.000 title claims abstract description 20
- 238000004519 manufacturing process Methods 0.000 title claims description 10
- 239000000463 material Substances 0.000 claims abstract description 38
- 238000009987 spinning Methods 0.000 claims abstract description 10
- 229920001169 thermoplastic Polymers 0.000 claims abstract description 8
- 239000004416 thermosoftening plastic Substances 0.000 claims abstract description 8
- 239000002657 fibrous material Substances 0.000 claims abstract description 5
- 239000004020 conductor Substances 0.000 claims description 6
- 239000004033 plastic Substances 0.000 claims description 6
- 229920003023 plastic Polymers 0.000 claims description 6
- 229920000642 polymer Polymers 0.000 claims description 6
- 239000005020 polyethylene terephthalate Substances 0.000 claims description 3
- 229920000139 polyethylene terephthalate Polymers 0.000 claims description 3
- 239000004952 Polyamide Substances 0.000 claims description 2
- 229920002647 polyamide Polymers 0.000 claims description 2
- -1 polyethylene terephthalate Polymers 0.000 claims description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract description 7
- 239000002041 carbon nanotube Substances 0.000 abstract description 7
- 229910021393 carbon nanotube Inorganic materials 0.000 abstract description 6
- 239000006258 conductive agent Substances 0.000 abstract description 4
- 239000011162 core material Substances 0.000 abstract 1
- 239000006185 dispersion Substances 0.000 description 7
- 229920001940 conductive polymer Polymers 0.000 description 4
- 229920002994 synthetic fiber Polymers 0.000 description 4
- 206010061592 cardiac fibrillation Diseases 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 230000002600 fibrillogenic effect Effects 0.000 description 3
- 229920002521 macromolecule Polymers 0.000 description 3
- 239000004677 Nylon Substances 0.000 description 2
- 229920002292 Nylon 6 Polymers 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 230000002950 deficient Effects 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 229920001778 nylon Polymers 0.000 description 2
- 230000003068 static effect Effects 0.000 description 2
- 239000012209 synthetic fiber Substances 0.000 description 2
- 241000208125 Nicotiana Species 0.000 description 1
- 235000002637 Nicotiana tabacum Nutrition 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
Images
Classifications
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/09—Addition of substances to the spinning solution or to the melt for making electroconductive or anti-static filaments
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D5/00—Formation of filaments, threads, or the like
- D01D5/28—Formation of filaments, threads, or the like while mixing different spinning solutions or melts during the spinning operation; Spinnerette packs therefor
- D01D5/30—Conjugate filaments; Spinnerette packs therefor
- D01D5/34—Core-skin structure; Spinnerette packs therefor
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
- D01F8/04—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
- D01F8/12—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one polyamide as constituent
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2331/00—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
- D10B2331/02—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyamides
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2331/00—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
- D10B2331/04—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyesters, e.g. polyethylene terephthalate [PET]
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2401/00—Physical properties
- D10B2401/16—Physical properties antistatic; conductive
Abstract
The present invention relates to a making method for the composite conductive fiber with high electro-conductivity. Dispersing the carbon nanotubes as conductive agent to the thermoplastic high molecule to form the core material; making the non-conductive fiber material as surface material and compositely spinning with the two materials to get the center-eccentric type cross section, and then make the electro-conductive fiber with high electro-conductivity in the thermal stretch working procedure.
Description
Technical field
The present invention relates to a kind of manufacture method of conductivity type composite fibre.
Background technology
In general, one of shortcoming of chemical fibre such as polyamide fiber and polyethylene terephthalate (PET) fiber is charged because of static easily.In order to overcome this shortcoming, can allow synthetic fiber possess electric conductivity.Wherein relatively typical method exactly with CNT as conductive agent be distributed to form core on the thermal plastic high polymer and non-conductive fibrous material as the skin material, both are carried out composite spinning and make the electric conductivity conductive fiber.The CNT diameter is 10～100nm, and length is about 1～40 μ m, and dispersion amount reaches 5～25 weight % usually.After being distributed to CNT in the condensate, owing to CNT is in contact with one another or very makes this condensate have electric conductivity near tunnel (Tunnel) effect that causes.For CNT being in contact with one another or very approaching, need make the dispersion concentration of CNT reach quite high degree.
On the other hand, conductive composite fibre can make product have antistatic performance after being applied to fiber products such as carpet and dust-free clothes, and is therefore, very extensive as the antistatic material range of application.In order to prevent that computer from breaking down because of static, the electric conductivity that the carpet requirement in the computer room has higher level.At present, mainly adopt conductive layer to be exposed to fiber (the clear 57-25647 of Japanese publication communique) or the back processing conductive fiber that behind fiber surface covering conductive materials, processes or the metal fibre etc. of fiber surface in high conductive fiber field.
But conductive layer is exposed to the synthetic fiber of whole fiber surface, and carbon dust will come off and reduce the operation percent of pass by the precursor from move in throwing and following process stage.In addition, the surface conductance material of back processing type conductive fiber also is easier to come off, and fibrillation (Fibrillation) problem then in use appears in metal fibre.In a word, the practicality of prior art is in-problem.
Summary of the invention
The object of the present invention is to provide a kind of shortcoming that had not both had above-mentioned high conductive fiber, throwing is good again, prevents the manufacture method that comes off and reduce electric conductivity and do not have the high electroconductive synthetic fibre of silk quality defectives such as fibrillation because of conductive materials.That is to say, CNT is distributed to as conductive agent forms core on the thermal plastic high polymer; Non-conductive fibrous material carried out composite spinning as the skin material to both and obtain the high conduction conductive fiber in eccentric type cross section.
The manufacture method of the high electroconductive synthetic fibre of the present invention comprises following operation: (1) is distributed to material preparatory process on the thermal plastic high polymer to CNT with 5～25 weight %; (2) be core with the material that obtains in the above-mentioned material preparatory process, non-conducting material carried out the spinning process of composite spinning operation as the skin material.
That is to say, the present invention relates to a kind of manufacture method of high conductivity composite conducting fiber.CNT is distributed to as conductive agent forms core on the thermal plastic high polymer; Non-conductive fibrous material is carried out composite spinning and obtains the eccentric type cross section both as the skin material, make the high conductivity conductive fiber by the hot-stretch operation then.
The CNT diameter is 10～100nm, and length is about 1～40 μ m, and dispersion amount reaches 5～25 weight % usually.Performance and cost performance during with 7～15 weight % are best.After being distributed to CNT in the condensate, owing to CNT is in contact with one another or very makes this condensate have electric conductivity near tunnel (Tunnel) effect that causes.For CNT being in contact with one another or very approaching, need make the dispersion concentration of CNT reach quite high degree.
When the dispersion amount of CNT is lower than 7 weight %, can not obtain satisfied electric conductivity; When dispersion amount was higher than 25 weight %, though electric conductivity is fine, expense was very high, and the even dispersion of CNT simultaneously also can become a difficult problem.In addition, when length of carbon nanotube less than 1 μ m of the present invention, can't reach satisfied tunnel effect and reduce electric conductivity; When surpassing 40 μ m, then can influence the machinability (Processibility) of technology for making tobacco threds.In addition, containing the compositely proportional of the core of CNT and general macromolecule skin material by weight should be at (core: the skin material) in 5: 95 to 20: 80 the scope.Compositely proportional is lower than at 5: 95 o'clock, will can not satisfy the conduction requirement because of electric conductivity reduces, and has surpassed at 20: 80 o'clock, then can defective products occur in spinning process, has increased the difficulty when making fiber.As shown in Figure 1, composite conducting fiber of the present invention is made up of skin material and core, and the skin material is a non-conducting material, and core is then for to comprise CNT at interior conductive material.
Description of drawings
Fig. 1 is the composite fibre sectional view of the embodiment of the invention.
The specific embodiment
Further specify at the present invention below in conjunction with embodiment and reference example.
Under remember that embodiment is intended to illustrate the present invention, it can not limit to protection scope of the present invention.
In order to obtain to have the filament in cross section as shown in Figure 1, as the 2nd material, the 1st material is for the sulfuric acid relative viscosity is 3.0 common nylon 6 to present embodiment with the thermoplastic conductive polymer that contains CNT, carries out composite spinning at both then and makes.The 1st material: the compositely proportional of the 2nd material is 90: 10 by weight, and in eccentric nozzle, the skin material is common nylon 6, and core is then for containing the conduction nylon of 7 weight % CNTs.The condensate that spues by spinning-nozzle is with 1, and the speed of 000m/min coils into the undrawn yarn of 180 DENIER (denier), 6 filaments (filament), makes 60 DENIER, 6 filamentary drawn yarns through the hot-stretch operation then.The characteristic such as the table 1 of the electric conductivity nylon composite fibre of making according to preceding method.
The content of carbon nanotubes of the thermoplastic conductive polymer in the 2nd material is brought up to the 15 weight %, and remainder and embodiment 1 are identical.
Reference example 1
The content of carbon nanotubes of the thermoplastic conductive polymer in the 2nd material is that remainder and embodiment 1 are identical the 4 weight %.
Reference example 2
The content of carbon nanotubes of the thermoplastic conductive polymer in the 2nd material is that remainder and embodiment 1 are identical the 30 weight %.
Reference example 3
Except with the 1st material (skin material): the compositely proportional of the 2nd material (core) is adjusted into 96: 4, and remainder and embodiment 1 are identical.
Reference example 4
Except with the 1st material (skin material): the compositely proportional of the 2nd material (core) is adjusted into 75: 25, and remainder and embodiment 1 are identical.
[table 1]
In sum, when off-centre constructed in accordance is wrapped the core composite fibre, it is the thermoplastic conductive macromolecule of 5～25 weight % that core uses conductive carbon nanotube content, the skin material uses non-conductive thermoplastic macromolecule, compositely proportional (core: the skin material) be 5: 95～20: 80 by weight, and then a kind of high conductivity conductive filament is provided.
Though the present invention only has been described in detail at specific embodiment, but in technological thought category of the present invention, various distortion and modification can appear, therefore this is very tangible same industry personage, and to belong to claim scope of the present invention be natural for this distortion and modification.
Claims (4)
1. the manufacture method of a high conductivity composite fibre is characterized in that:
Comprise following two operations:
(1) with 5～25 weight % CNT is distributed to material preparatory process on the thermal plastic high polymer; And
(2) be core with the material that obtains in the above-mentioned material preparatory process, non-conducting material carried out the spinning process of composite spinning operation as the skin material.
2. the manufacture method of high conductivity composite fibre according to claim 1 is characterized in that:
Above-mentioned non-conductive thermoplastic macromolecular material is made up of polyamide or polyethylene terephthalate.
3. the manufacture method of high conductivity composite fibre according to claim 1 is characterized in that:
Core is 5: 95～20: 80 scope by weight to the compositely proportional of skin material.
4. the high conductivity composite fibre that makes according to each described manufacture method in the claim 1～3 is characterized in that:
With 5～25 weight % CNT to be distributed to material on the thermal plastic high polymer be core, be the skin material with the non-conductive fiber material.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR10-2004-0118130 | 2004-12-31 | ||
| KR1020040118130 | 2004-12-31 | ||
| KR1020040118130A KR100583366B1 (en) | 2004-12-31 | 2004-12-31 | Manufacturing method of conjugate fiber having high conductivity |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1796623A CN1796623A (en) | 2006-07-05 |
| CN1796623B true CN1796623B (en) | 2011-06-01 |
Family
ID=36817935
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2005101025740A Expired - Fee Related CN1796623B (en) | 2004-12-31 | 2005-09-12 | Composite fiber with excellent conductivity and method for manufacturing same |
Country Status (2)
| Country | Link |
|---|---|
| KR (1) | KR100583366B1 (en) |
| CN (1) | CN1796623B (en) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP5557992B2 (en) * | 2008-09-02 | 2014-07-23 | 国立大学法人北海道大学 | Conductive fiber, conductive yarn, fiber structure having carbon nanotubes attached thereto, and manufacturing method thereof |
| KR101493730B1 (en) * | 2008-09-22 | 2015-02-17 | (주)효성 | Conductive composite fiber |
| DE102008064579B4 (en) * | 2008-12-22 | 2012-03-15 | Siemens Aktiengesellschaft | Method and carrier cylinder for producing an electrical winding |
| FR2946176A1 (en) * | 2009-05-27 | 2010-12-03 | Arkema France | MULTILAYER CONDUCTIVE FIBER AND PROCESS FOR OBTAINING IT BY CO-EXTRUSION |
| KR101551429B1 (en) * | 2009-12-31 | 2015-09-21 | 주식회사 효성 | Process for preparing conductive polyamide conjugated yarn having fluidized carbon nanotube |
| CN113565714B (en) * | 2020-04-28 | 2023-03-28 | 清华大学 | Nanofiber actuator and method of making the same |
| CN115522270B (en) * | 2022-10-26 | 2023-04-28 | 山东金冠网具有限公司 | Conductive polymer fiber with sheath-core structure and preparation method thereof |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1089314A (en) * | 1992-12-29 | 1994-07-13 | 天津纺织工学院 | Multi-function electromagnetic radiation shielding fibre and manufacture method thereof |
| WO2002055769A1 (en) * | 2000-11-03 | 2002-07-18 | Honeywell International Inc. | Spinning, processing, and applications of carbon nanotube filaments, ribbons, and yarns |
| CN1410475A (en) * | 2002-03-14 | 2003-04-16 | 四川大学 | Polymer/carbon nano pipe composite powder and its solid phase shear break up preparation method |
| CN1410455A (en) * | 2002-03-14 | 2003-04-16 | 四川大学 | Preparation method of polymer/carbon nano pipe composite emulsion and its in situ emulsion polymerization |
| US20030165648A1 (en) * | 2002-03-04 | 2003-09-04 | Alex Lobovsky | Composite material comprising oriented carbon nanotubes in a carbon matrix and process for preparing same |
| CN1472239A (en) * | 2003-07-04 | 2004-02-04 | 清华大学 | Method for preparing polymer and active carbon nanometer tube powder composition |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP3859647B2 (en) * | 2004-01-16 | 2006-12-20 | 松下電器産業株式会社 | Semiconductor integrated circuit test method and semiconductor integrated circuit |
-
2004
- 2004-12-31 KR KR1020040118130A patent/KR100583366B1/en not_active IP Right Cessation
-
2005
- 2005-09-12 CN CN2005101025740A patent/CN1796623B/en not_active Expired - Fee Related
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1089314A (en) * | 1992-12-29 | 1994-07-13 | 天津纺织工学院 | Multi-function electromagnetic radiation shielding fibre and manufacture method thereof |
| WO2002055769A1 (en) * | 2000-11-03 | 2002-07-18 | Honeywell International Inc. | Spinning, processing, and applications of carbon nanotube filaments, ribbons, and yarns |
| US20030165648A1 (en) * | 2002-03-04 | 2003-09-04 | Alex Lobovsky | Composite material comprising oriented carbon nanotubes in a carbon matrix and process for preparing same |
| CN1410475A (en) * | 2002-03-14 | 2003-04-16 | 四川大学 | Polymer/carbon nano pipe composite powder and its solid phase shear break up preparation method |
| CN1410455A (en) * | 2002-03-14 | 2003-04-16 | 四川大学 | Preparation method of polymer/carbon nano pipe composite emulsion and its in situ emulsion polymerization |
| CN1472239A (en) * | 2003-07-04 | 2004-02-04 | 清华大学 | Method for preparing polymer and active carbon nanometer tube powder composition |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1796623A (en) | 2006-07-05 |
| KR100583366B1 (en) | 2006-05-26 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN1796623B (en) | Composite fiber with excellent conductivity and method for manufacturing same | |
| Dias | Electronic textiles: Smart fabrics and wearable technology | |
| EP1559815B1 (en) | Conductive yarn, method of manufacture and use thereof | |
| Xue et al. | Electrically conductive yarns based on PVA/carbon nanotubes | |
| US10138580B2 (en) | Nanofiber yarns, thread, rope, cables, fabric, articles and methods of making the same | |
| US4207376A (en) | Antistatic filaments having an internal layer comprising carbon particles and process for preparation thereof | |
| JP4786711B2 (en) | Method for producing conductive long fiber composite material | |
| EP1961846B1 (en) | Electrically conductive filaments, fabrics made of these filaments and their use | |
| Raji et al. | Electrical conductivity in textile fibers and yarns | |
| US20060019093A1 (en) | Antistatic polymer monofilament, method for making an antistatic polymer monofilament for the production of spiral fabrics and spiral fabrics formed with such monofilaments | |
| AU2003265320B2 (en) | Pitch based graphite fabrics and needled punched felts for fuel cell gas diffusion layer substrates and high thermal conductivity reinforced composites | |
| CN109183226A (en) | A kind of high-performance conductive yarn | |
| KR20200126406A (en) | Nanomaterial-Coated Fiber | |
| CN212934184U (en) | Intelligent flexible elastic conductive wire for wearing | |
| CN100376733C (en) | Strong conveyor belt and polyester fibre silk fabric core used thereof | |
| KR101788634B1 (en) | Method for Producing Carbon NanoTube Fiber | |
| CN102031588A (en) | Durable carbon black conductive fiber and preparation method thereof | |
| EP1961845A2 (en) | Electrically conductive filaments, fabrics made of these filaments and their use | |
| JPS61127198A (en) | Conductive composite body and manufacture thereof | |
| JP2005002535A (en) | Conductive conjugate fiber | |
| CN106310560A (en) | Anti-static safety belt | |
| RU2790823C1 (en) | Electrically conductive composite fiber and method for its production and application | |
| CN210030974U (en) | Conductive fiber and composite spinning assembly for preparing conductive fiber | |
| CN111809284A (en) | Conductive core-spun yarn and preparation method thereof | |
| KR20110004636A (en) | Static dissipative and anti-bacterial fiber comprising needle shaped zinc oxide whisker |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20110601 Termination date: 20150912 |
|
| EXPY | Termination of patent right or utility model |