CN1788959A - Method for preparing veneer brick using fly ash - Google Patents
Method for preparing veneer brick using fly ash Download PDFInfo
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- CN1788959A CN1788959A CNA2005101115592A CN200510111559A CN1788959A CN 1788959 A CN1788959 A CN 1788959A CN A2005101115592 A CNA2005101115592 A CN A2005101115592A CN 200510111559 A CN200510111559 A CN 200510111559A CN 1788959 A CN1788959 A CN 1788959A
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/91—Use of waste materials as fillers for mortars or concrete
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Abstract
The process of producing facing brick with flyash includes the following steps: A. drying flyash, yellow mud, fire resistant sand and feldspar in ventilating and drying chamber at 15-25 deg.c for 36-48 hr, mixing and grinding; B. mixing the mixture with water in the ratio of 100 to 5-8 in a stirrer for 3-5 min, ageing at room temperature for 12-24 hr, 50-100 mesh sieving and pressing to form in a brick making machine; and C. drying the adobe at 50-100 deg.c for 10-14 hr and calcining in a push bat kiln at 950-1051 deg.c for 17-19 hr to produce the facing brick. The present invention has low power consumption, no secondary pollution and effective utilization of flyash resource, and the facing brick product has excellent macro performance and may be used in paving road.
Description
Technical field
The present invention relates to a kind of sintering feed or waste material or refuse of using and prepare the method for construction material, relate to the method that a kind of flying dust that utilizes consumer waste incineration to produce prepares the architectural coating brick in particular as mortar, concrete or artificial stone filler.
Background technology
Domestic garbage incineration flyash is a kind of generally acknowledged hazardous waste, has wherein concentrated a large amount of heavy metals and has included a spot of hypertoxic dioxin organic matter, and China GWKB3-2000 expressly provides that flying dust is that a kind of hazardous waste must carry out harmless treatment.But flying dust is again a kind of resource, contains more silicate, aluminate in the flying dust, can be used as the admixture of construction material; Vitreum and many active network activated metal ions more in the flying dust make that again flying dust has certain activity; In addition, the particle diameter about flying dust 200 orders is formed the activity that has also increased flying dust, can save the energy consumption in the resource process.At present, the research that flying dust is handled disposal both at home and abroad mainly concentrates harmless treatment formerly to advance on the landfill yard landfill again, and the research of utilization of relevant flying dust seldom.
The development of garbage incineration technology makes the discharge capacity of domestic garbage incineration flyash increase year by year, in Shanghai, after the existing all the people present's incineration plant in Shanghai all put into effect, a day disposal of refuse amount reached several kilotons, and the ash discharge amount is if calculate then four factories day ash discharge amount up to the hundreds of ton according to 2～4%.The main processing method of flying dust is to solidify to insert the hazardous waste landfill yard then at present.Solidification process has not only been wasted many cement-based materials, and solidifies the back volumetric expansion, has increased space shared in the hazardous waste landfill yard; The high cost that hazardous waste landfill yard administrative expenses quite high (being 2,700 yuan/ton at present), flying dust enter the processing of hazardous waste landfill yard has caused very big burden to finance; The flyash curing body of inserting the hazardous waste landfill yard can not recycling, has caused the waste of ample resources; From long-range angle, flying dust advances landfill yard also can cause secondary pollution.This shows that it is a kind of temporary transient safe but costly method that flying dust is disposed in the hazardous waste landfill yard.In addition, China gives birth to the construction speed of the construction speed of suitable garbage burning factory considerably beyond the hazardous waste landfill yard at present, and every day, a large amount of flying dusts was all waited safe handling.Domestic only in Shanghai, several urban construction such as Shenzhen, Shenyang satisfy the hazardous waste landfill yard of technical specification, and the landfill ability of the landfill yard of building and service life also are limited.It is extremely urgent to seek more economical rational flyash treatment method thus.
The method of disposal of flying dust recycling has: curing/stabilizing comprises cement solidification, bitumen solidification, chemical agent stabilisation etc.; High-temperature process comprises sintering and fusion/vitrifying etc., inserts special landfill yard or recycling then; Extract the heavy metal in the flying dust, comprise that acidleach is got, biology and biologic product extractions, high temperature extraction etc., then with the heavy metal resources utilization of extraction.Wherein the high-temperature process technology be at present unique can destroy dioxin and other toxic organics the flying dust treatment technology, can be divided into: glass solidification (vitrification), fusion separate (fusion) and sintering (sintering).It is that flying dust is heated to melt temperature (1,200～1,400 ℃) that fusion separates, lower boiling heavy metal and salt will be evaporated to gas phase after the fusion, collected by the exhaust dust-precipitating system, difficult volatilization heavy metal separates recyclable utilization because of the bottom that the big part of density sinks to smelting furnace; Another part then residues in the slag.Form glass state material after slag quenches, can be used as building materials and use.The fusing fly ash treatment technology is most widely used in Japan, and at present nearly 4% lime-ash adopts fusion method to handle, and in the incineration residue fusion factory that builds He moved 21 families is arranged approximately by 1999.Though simple fusing fly ash technology can obtain certain appearance solidification effect that subtracts, but because the hardness of gained vitreous material, hot property etc. are relatively poor, thereby limited its application in fields such as construction materials, usually can only be used for the composite material of roadbed material, cement concrete or send into the landfill yard landfill once more, added value is lower; Can produce the melting furnace flying dust (its Cd and Pb concentration are 5-10 times before the fusion) of a small amount of high concentration in the melting process again; The expense of fusing fly ash is also very high, is difficult in the whole world promote.Glass solidification is that the mixture with flying dust or flying dust and frit is heated to 1, melt temperature more than 000～1,200 ℃, and the atmosphere of control smelting furnace prevents the volatilization of heavy metal, melt substance quenches and forms glassy state, thereby harmful substance is cured in the pollution of having avoided in the glassy state environment.People such as Young Jun Park add in flying dust behind the 5%SiO2 1, fusion 30min under 500 ℃ of high temperature, after treating the physics and chemical state change of flying dust, cooling makes it solidify to form the glass solidification body, by Vitrea compact crystal structure flying dust is enclosed in the vitreum securely.The Vitrea dimension formula intensity of gained is 4,000～5, and 000MPa, rupture strength are 60～90MPa, and fracture toughness reaches 0.9MPa m1/2, fully can recycling.This kind processing method has good loss of weight, subtracts the appearance effect flying dust, because chloride is gone up all substantially and evaporated 1,500 ℃ the time, flying dust generally can loss of weight about 2/3.Heavy metal is strapped in the network structure of SiO2 silicon-oxy tetrahedron composition securely after the fusion simultaneously, and leaching rate is very low, can satisfy present leaching standard.But power consumption is up to 600～1,250kWh/t, and produced the flue dust that contains plurality of heavy metal and sour gas in the melting process, and increased the system handles expense, make disposal cost up to 166～500 dollars/t, have only economically developed country scale to use.In people's such as T.Mangialardi the research flying dust being pressed into the bottom surface diameter is 15mm, height is the small cylindrical base substrate of 20mm, then 1,140 ℃ high temperature is calcining 60min down, the compression strength of sintering curing body reaches 28N/mm2, satisfy the requirement of Italy to coarse aggregate intensity in the concrete, therefore this flying dust sintering curing body can be used as the admixture in the concrete.But this method requires flying dust to carry out preliminary treatment through washing, otherwise the sulfate in the flying dust, villaumite and vitreum are totally unfavorable to the sintering curing process.1,140 ℃ calcining high temperature makes the energy consumption of this processing method and expense very high, and the firming body of calcining gained just uses as coarse aggregate, is worth low cost in can not the compensation deals process, is the method for the low output of a kind of high energy consumption; In addition, produced secondary pollution in the water-washing process again, increased the burden of environment, therefore the angle from sustainable development is a kind of worthless method.People such as A.polettini have done further research on the basis of T.Mangialardi sintering processing method, added additives such as cullet and some ores and excite the activity of flying dust in flying dust, the result has calcined out performance better flying dust sintering curing body and need not wash preliminary treatment.But its calcining heat is still up to 1,100～1, and 150 ℃, energy consumption is very high, is difficult to promote.And gained sintering curing body can not directly be used as building materials, can only be used as concrete admixture, and economic benefit is lower.The method of above-mentioned flying dust resource all is to consider to sinter flying dust into concrete aggregate, and not only the energy consumption high production is low, and the volatilization of heavy metal is very serious under high-temperature calcination, causes secondary pollution thereby the concentration of heavy metal is very high in the discharged flue gas; Gained sintering curing body is in case damaged in addition, and the heavy metal that is included in the inside will leach in suitable environment, causes environmental pollution.
Summary of the invention
Technical problem to be solved by this invention provides and a kind ofly prepares the method for architectural coating brick with flying dust, and this method non-secondary pollution, energy consumption be low, can easyly realize the flying dust resource reliably.
The technical solution used in the present invention: a kind ofly prepare the method for tapestry brick, comprise the following steps: with flying dust
(a) with flying dust 5～30 parts (weight portion), cream-coloured mud 40～65 parts (weight portion), fire sand 5～30 parts (weight portion) and feldspar 5～20 parts (weight portion) aeration-drying 36～48 hours in 20 ± 5 ℃ hothouse, carry out combined grinding then, the material fineness accounts for 55%～70% between 200～250 orders;
(b) material through grinding adds the water stirring in mixer, and every 100kg material adds water 5～8L, stirs 3～5 minutes, leave standstill ageing in 12～24 hours under the room temperature, material after the ageing is after 50～100 mesh sieves, and in the moulding of brickmaking make-up machine upward pressure, briquetting pressure is controlled to be 400～700kg/cm
2
(c) obtained by molding base substrate dry 12 ± 2h in 50～100 ℃ of dry kilns goes into pushed bat kiln calcining 18 ± 1h then, and the pushed bat kiln firing temperature is controlled to be 950～1050 ℃ and makes tapestry brick.
The described combined grinding of step a is to carry out in by jaw crusher and Raymond mill combination milling equipment dimerous, material at first carries out the one-level fragmentation in jaw crusher, material through fragmentation is transported to the bistrique storehouse by bucket elevator, enter Raymond mill subsequently and carry out two-stage crushing, particle diameter is collected in material bin through the whirlwind tube less than 100 purpose particles.
The described pressure forming of step b is finished by twice pressurization, and 240～420kg/cm pressurizes for the first time
2, be pressurization at full capacity for the second time.
Beneficial effect of the present invention: the present invention is used to develop tapestry brick with domestic garbage incineration flyash, can thoroughly destroy wherein dioxin by calcining, and solidifies the heavy metal in the flying dust, reaches the purpose of domestic garbage incineration flyash harmless treatment.Non-secondary pollution of the present invention, low, the easy purpose that realizes the flying dust resource reliably of energy consumption.The dimensional discrepancy of the flying dust tapestry brick of the present invention's preparation reaches the requirement of excellent tapestry brick among the GB5101-2003; Apparent mass has reached among the GB5101-2003 requirement to imperial and Grade A; Strength grade reaches the MU15 strength grade; Water absorption rate maximum＜14%, and average saturation coefficient＜0.88, maximum saturation coefficient＜0.9, goods reach the requirement of antagonism weathering capacity among the GB5101-2003 fully; Goods satisfy the requirement of anti-freezing property fully; Lime blowing reaches the requirement of first-class or high-class product; Scum reaches the requirement of high-class product or Grade A; Resistance to chemical attack is the A level.Gained flying dust tapestry brick goods have macro property preferably, can be used for paving purposes such as road.
Description of drawings
Fig. 1 is the XRD figure spectrum of experiment with domestic garbage incineration flyash;
Fig. 2 is the XRD figure spectrum of experiment with cream-coloured mud;
Fig. 3 is the XRD figure spectrum of experiment with fire sand;
Fig. 4 is the XRD figure spectrum of experiment with feldspar;
Fig. 5 prepares the tapestry brick process chart with flying dust.
The specific embodiment
Below by accompanying drawing the present invention is described in further detail: experiment is taken from PVG domestic garbage burning electricity generation factory with domestic garbage incineration flyash, and main chemical compositions is CaO, SiO
2, Al
2O
3, as shown in table 1.Show that as the XRD figure of Fig. 1 domestic garbage incineration flyash spectrum its essential mineral composition is the silicate of silica and calcium, potassium, aluminium, glassy phase content is very high, as shown in Figure 1.The SiO that contains in the domestic garbage incineration flyash
2With Al
2O
3Be the raw-material main chemical composition of flying dust tapestry brick, CaO wherein, other active basic anhydride and glassy phase can reduce the sintering temperature of flying dust tapestry brick.Therefore, domestic garbage incineration flyash can be used for developing the flying dust tapestry brick.The addition content of domestic garbage incineration flyash is 5～30% in the experiment.
The table 1 experiment main chemical compositions (%) of domestic garbage incineration flyash
| Chemical composition | CaO | SiO 2 | Al 2O 3 | Fe 2O 3 | MgO |
| Content | 30.8～39.1％ | 19.3～25.2 | 4.6～9.5 | 2.8～5.6 | 2.0～4.1 |
Experiment is a kind of ecru potter's clay that occurring in nature exists with cream-coloured mud, mainly originates on the mountain of Yixing, Jiangsu Province periphery.The main chemical compositions of cream colour mud is SiO
2With Al
2O
3, as shown in table 2; The essential mineral composition is quartzy (SiO
2), illite (K (Al, Fe, Mg) (Si, Al)
4O
10(OH)
2) and kaolinite (Al
2Si
2O
5(OH)
4), its XRD figure spectrum is as shown in Figure 2.The addition content of cream-coloured mud is 40～65% in the experiment.
Table 2 is tested the main chemical compositions (%) with cream-coloured mud
| Chemical composition | SiO2 | Al2O3 | Fe2O3 | K2O | Na2O | CaO | MgO | TiO2 |
| Percentage composition | 65.2～ 73.0 | 12.5～ 20.2 | 0.9～ 2.0 | 1.8～ 4.9 | 0.6～ 1.9 | 0.2～ 1.7 | 0.6～ 1.9 | 0.5～ 2.8 |
Experiment is pulverized the grog that forms with fire-resistant base and is claimed fire sand, and its adding can improve yield rate.The fire sand main chemical compositions is SiO
2With Al
2O
3, as shown in table 3; It is quartzy (SiO that essential mineral is formed
2), cordierite ((Mg, Fe)
2Al
4Si
5O
18), halloysite (CaAl
2Si
2O
84H
2O), illite (K (Al, Fe, Mg) (Si, Al)
4O
10(OH)
2) and muscovite (KAl
2(AlSi
3O
10) (OH)
2), its XRD figure spectrum is as shown in Figure 3.The addition content of fire sand is 5～30% in the experiment.
The table 3 experiment chemical composition (%) of fire sand
| Chemical composition | SiO 2 | Al 2O 3 | Fe 2O 3 | K 2O | CaO | MgO | TiO 2 |
| Percentage composition | 56.～64.1 | 25.～31.2 | 1.2～3.5 | 1.1～2.5 | 0.4～1.0 | 1.9～3.5 | 0.5～1.4 |
Experiment is taken from Yixing, Jiangsu building ceramics factory with feldspar, and main chemical compositions is SiO
2, Al
2O
3, K
2O, Na
2O etc., as shown in table 4; The essential mineral composition is potassic feldspar (KAlSi
3O
8), albite (NaAlSi
3O
8), quartz and muscovite, its XRD figure spectrum is as shown in Figure 4.The addition content of experiment andesine is 5～20%.
The table 4 experiment chemical composition (%) of feldspar
| Chemical composition | SiO 2 | Al 2O 3 | K 2O | CaO | Na 2O |
| Percentage composition | 43.1～56.1 | 11.2～19.4 | 16.8～25.9 | 5.7～11.6 | 9.6～20.2 |
The method for preparing tapestry brick with flying dust is as shown in Figure 5: a kind of method for preparing tapestry brick with flying dust, comprise the following steps: that (a) is with flying dust 5～30 parts (weight portion), cream-coloured mud 40～65 parts (weight portion), fire sand 5～30 parts (weight portion) and feldspar 5～20 parts (weight portion) aeration-drying 36～48 hours in 20 ± 5 ℃ hothouse, carry out combined grinding then, the material fineness accounts for 55%～70% between 200～250 orders; (b) material through grinding adds the water stirring in mixer, and every 100kg material adds water 5～8L, stirs 3～5 minutes, leave standstill ageing in 12～24 hours under the room temperature, material after the ageing is after 50～100 mesh sieves, and in the moulding of brickmaking make-up machine upward pressure, briquetting pressure is controlled to be 400～700kg/cm
2(c) obtained by molding base substrate dry 12 ± 2h in 50～100 ℃ of dry kilns goes into pushed bat kiln calcining 18 ± 1h then, and the pushed bat kiln firing temperature is controlled to be 950～1050 ℃ and makes tapestry brick.The described combined grinding of step a is to carry out in by jaw crusher and Raymond mill combination milling equipment dimerous, material at first carries out the one-level fragmentation in jaw crusher, material through fragmentation is transported to the bistrique storehouse by bucket elevator, enter Raymond mill subsequently and carry out two-stage crushing, particle diameter is collected in material bin through the whirlwind tube less than 100 purpose particles.The described pressure forming of step b is finished by twice pressurization, and 240～420kg/cm pressurizes for the first time
2, be pressurization at full capacity for the second time.
Embodiment:
The main chemical compositions of domestic garbage incineration flyash, cream-coloured mud, fire sand and feldspar is shown in table 4～7 among the embodiment.
The table 4 experiment main chemical compositions (%) of domestic garbage incineration flyash
| Chemical composition | CaO | SiO 2 | Al 2O 3 | K 2O | Na 2O | Fe 2O 3 | MgO |
| Content | 35.8 | 20.5 | 5.8 | 4.0 | 3.7 | 3.2 | 2.1 |
The main chemical compositions of the cream-coloured mud of table 5 (%)
| Chemical composition | SiO 2 | Al 2O 3 | Fe 2O 3 | K 2O | Na 2O | CaO | MgO | TiO 2 |
| Percentage composition | 72.3 | 16.4 | 1.6 | 3.7 | 0.8 | 0.3 | 0.6 | 0.8 |
The main chemical compositions of table 6 fire sand (%)
| Chemical composition | SiO 2 | Al 2O 3 | Fe 2O 3 | K 2O | Na 2O | CaO | MgO | TiO 2 |
| Percentage composition | 61.3 | 29.4 | 2.2 | 1.9 | 0.2 | 0.7 | 2.9 | 1.0 |
The table 7 experiment chemical composition (%) of feldspar
| Chemical composition | SiO 2 | Al 2O 3 | K 2O | CaO | Na 2O |
| Percentage composition | 43.1～56.1 | 11.2～19.4 | 16.8～25.9 | 5.7～11.6 | 9.6～20.2 |
Material is at first hothouse (19 ℃) aeration-drying 40 hours, grinding in the special-purpose milling equipment of building ceramics factory then, and the discharging grain composition is as shown in table 8.
Table 8 discharging grain composition (%)
| Granulometric range | ＞100 | 100～200 orders | 200～250 orders | 250～300 orders | ＜300 orders |
| Percentage composition | 5 | 15 | 61 | 12 | 7 |
Material stirs through add water behind the grinding in mixer, and the amount of water of every 100kg material is 7.5L, stirs 4 minutes, at room temperature leaves standstill afterwards and makes its ageing in 18 hours.Material after the ageing is after sieve (80 order), and purpose is to promote the homogenizing of material and the formation of micelle.Material after ageing is sieved carries out pressure forming on the brickmaking make-up machine, the model of make-up machine is TC2680, and power of motor is 7.5KW, and briquetting pressure is 700kg/cm
2, briquetting pressure is 420kg/cm for the first time
2, briquetting pressure is 700kg/cm for the second time
2The obtained by molding base substrate is (60 ℃) dry 13h in dry kiln.Dried base substrate is gone into pushed bat kiln and is calcined, and whole calcination process 18.5h, the firing temperature of pushed bat kiln are controlled at 980 ℃, make the flying dust tapestry brick at last.The dimensional discrepancy of flying dust tapestry brick reaches the requirement of excellent tapestry brick among the GB5101-2003 after testing; Apparent mass has reached among the GB5101-2003 requirement to imperial and Grade A; Strength grade reaches the MU15 strength grade; Water absorption rate maximum＜14%, and average saturation coefficient＜0.88, maximum saturation coefficient＜0.9, goods reach the requirement of antagonism weathering capacity among the GB5101-2003 fully; Goods satisfy the requirement of anti-freezing property fully; Lime blowing reaches the requirement of first-class or high-class product; Scum reaches the requirement of high-class product or Grade A; Resistance to chemical attack is the A level.
Above said content only is the basic explanation of the present invention under conceiving, and according to any equivalent transformation that technical scheme of the present invention is done, all should belong to protection scope of the present invention.
Claims (3)
1. one kind prepares the method for tapestry brick with flying dust, comprises the following steps:
(a) with flying dust 5～30 parts (weight portion), cream-coloured mud 40～65 parts (weight portion), fire sand 5～30 parts (weight portion) and feldspar 5～20 parts (weight portion) aeration-drying 36～48 hours in 20 ± 5 ℃ hothouse, carry out combined grinding then, the material fineness accounts for 55%～70% between 200～250 orders;
(b) material through grinding adds the water stirring in mixer, and every 100kg material adds water 5～8L, stirs 3～5 minutes, leave standstill ageing in 12～24 hours under the room temperature, material after the ageing is after 50～100 mesh sieves, and in the moulding of brickmaking make-up machine upward pressure, briquetting pressure is controlled to be 400～700kg/cm
2
(c) obtained by molding base substrate dry 12 ± 2h in 50～100 ℃ of dry kilns goes into pushed bat kiln calcining 18 ± 1h then, and the pushed bat kiln firing temperature is controlled to be 950～1050 ℃ and makes tapestry brick.
2. according to the described a kind of method for preparing tapestry brick with flying dust of claim 1, it is characterized in that: the described combined grinding of step a is to carry out in by jaw crusher and Raymond mill combination milling equipment dimerous, material at first carries out the one-level fragmentation in jaw crusher, material through fragmentation is transported to the bistrique storehouse by bucket elevator, enter Raymond mill subsequently and carry out two-stage crushing, particle diameter is collected in material bin through the whirlwind tube less than 100 purpose particles.
3. a kind ofly prepare the method for tapestry brick with flying dust according to claim 1 is described, it is characterized in that: the described pressure forming of step b is finished by twice pressurization, and 240～420kg/cm pressurizes for the first time
2, be pressurization at full capacity for the second time.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2005101115592A CN100491096C (en) | 2005-12-15 | 2005-12-15 | Method for preparing veneer brick using fly ash |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2005101115592A CN100491096C (en) | 2005-12-15 | 2005-12-15 | Method for preparing veneer brick using fly ash |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1788959A true CN1788959A (en) | 2006-06-21 |
| CN100491096C CN100491096C (en) | 2009-05-27 |
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ID=36787164
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB2005101115592A Expired - Fee Related CN100491096C (en) | 2005-12-15 | 2005-12-15 | Method for preparing veneer brick using fly ash |
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| CN (1) | CN100491096C (en) |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102775130A (en) * | 2012-07-19 | 2012-11-14 | 上海应用技术学院 | Sintered brick prepared from domestic waste incineration fly ash and phosphorite tailings and preparation method thereof |
| CN104891961A (en) * | 2015-05-27 | 2015-09-09 | 内江博达科技有限公司 | Method for producing thinned ceramic tile by recycling of waste incineration fly ash |
| CN105036703A (en) * | 2015-07-30 | 2015-11-11 | 江苏省宜兴彩陶工艺厂 | High-dense low-water-absorption ceramic product and preparation method thereof |
| CN106396619A (en) * | 2016-09-07 | 2017-02-15 | 安徽金生金世电子科技有限公司 | High-temperature-resistant wall brick and preparation method thereof |
| CN106431195A (en) * | 2016-09-07 | 2017-02-22 | 安徽金生金世电子科技有限公司 | Firewall brick and preparation method thereof |
| CN106431196A (en) * | 2016-09-07 | 2017-02-22 | 安徽金生金世电子科技有限公司 | Thermal insulation firewall brick and preparation method thereof |
| CN106431197A (en) * | 2016-09-07 | 2017-02-22 | 安徽金生金世电子科技有限公司 | Thermal insulation wall brick and preparation method thereof |
| CN106631051A (en) * | 2016-09-07 | 2017-05-10 | 安徽金生金世电子科技有限公司 | Refractory wall brick and preparation method thereof |
-
2005
- 2005-12-15 CN CNB2005101115592A patent/CN100491096C/en not_active Expired - Fee Related
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102775130A (en) * | 2012-07-19 | 2012-11-14 | 上海应用技术学院 | Sintered brick prepared from domestic waste incineration fly ash and phosphorite tailings and preparation method thereof |
| CN102775130B (en) * | 2012-07-19 | 2014-04-16 | 上海应用技术学院 | Sintered brick prepared from domestic waste incineration fly ash and phosphorite tailings and preparation method thereof |
| CN104891961A (en) * | 2015-05-27 | 2015-09-09 | 内江博达科技有限公司 | Method for producing thinned ceramic tile by recycling of waste incineration fly ash |
| CN105036703A (en) * | 2015-07-30 | 2015-11-11 | 江苏省宜兴彩陶工艺厂 | High-dense low-water-absorption ceramic product and preparation method thereof |
| CN105036703B (en) * | 2015-07-30 | 2017-06-13 | 江苏省宜兴彩陶工艺厂 | Ceramic of fine and close low water suction high and preparation method thereof |
| CN106396619A (en) * | 2016-09-07 | 2017-02-15 | 安徽金生金世电子科技有限公司 | High-temperature-resistant wall brick and preparation method thereof |
| CN106431195A (en) * | 2016-09-07 | 2017-02-22 | 安徽金生金世电子科技有限公司 | Firewall brick and preparation method thereof |
| CN106431196A (en) * | 2016-09-07 | 2017-02-22 | 安徽金生金世电子科技有限公司 | Thermal insulation firewall brick and preparation method thereof |
| CN106431197A (en) * | 2016-09-07 | 2017-02-22 | 安徽金生金世电子科技有限公司 | Thermal insulation wall brick and preparation method thereof |
| CN106631051A (en) * | 2016-09-07 | 2017-05-10 | 安徽金生金世电子科技有限公司 | Refractory wall brick and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN100491096C (en) | 2009-05-27 |
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