CN1768129A - Method for surface-metallizing wax objects, especially for silver-plating candles to give them a bright shine - Google Patents
Method for surface-metallizing wax objects, especially for silver-plating candles to give them a bright shine Download PDFInfo
- Publication number
- CN1768129A CN1768129A CN200480009117.0A CN200480009117A CN1768129A CN 1768129 A CN1768129 A CN 1768129A CN 200480009117 A CN200480009117 A CN 200480009117A CN 1768129 A CN1768129 A CN 1768129A
- Authority
- CN
- China
- Prior art keywords
- solution
- drying
- sensitizing
- article
- priming paint
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11C—FATTY ACIDS FROM FATS, OILS OR WAXES; CANDLES; FATS, OILS OR FATTY ACIDS BY CHEMICAL MODIFICATION OF FATS, OILS, OR FATTY ACIDS OBTAINED THEREFROM
- C11C5/00—Candles
- C11C5/008—Candles characterised by their form; Composite candles, e.g. candles containing zones of different composition, inclusions, or the like
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Composite Materials (AREA)
- Wood Science & Technology (AREA)
- General Chemical & Material Sciences (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
- Paints Or Removers (AREA)
- Chemically Coating (AREA)
- Lubricants (AREA)
- Fats And Perfumes (AREA)
- Laminated Bodies (AREA)
Abstract
The invention relates to a method for surface-metallizing wax objects, especially for silver-plating candles to give them a bright de luxe shine. The inventive method comprises the steps of applying a base coat to the surface of the object to be finished, drying the base coat, treating the surface of the base coat layer with a presensitizing solution, applying a solution containing a metallization agent to the presensitized surface of the base coat layer while depositing a metallization layer, drying the metallization layer so produced, applying a transparent coating varnish and drying the coating varnish layer so produced.
Description
Technical field
The present invention relates to a kind of being used for carries out surface metalation/metallizing, particularly candle is carried out the silver plated method of specular gloss wax system article.
Background technology
By the known a kind of method that the decoration with metallic surface decoration is used candle that is used to make of EP0308921B1, wherein at first apply candle with alcohol, then metallize in a vacuum.In order to form as far as possible all even persistent metal layer, between coating and metallization, should carry out at least 60 hours ageing treatment.This means, the step of depositing consuming time must be set in the production process of candle, also must provide corresponding space for the described step of depositing in addition.In addition, also have such shortcoming in this known method, promptly can only intricately carry out, and will adopt the vacuum-evaporator unit that is restricted on the output.This makes that the manufacturing cost of this decorative candle is extremely expensive.
Summary of the invention
Described problem by prior art is set out, the objective of the invention is, provide a kind of being used for that wax system article are carried out surface metalation, particularly candle carried out the silver plated method of specular light moorland, under identical decorative quality, described method can more reasonably and with the cost on the lower device be implemented.
Described purpose can realize by the method steps that provides in the characteristic of claim 1:
-on article surface to be put in order, apply priming paint,
-make the priming paint drying,
-utilize pre-sensitizing solution that the surface of prime coat is handled,
-on the surface of prime coat pre-sensitizing, apply the solvent that comprises metalating agent, deposit a metal layer simultaneously,
-make formed metal layer drying,
-apply transparent coating varnish, and
-make formed covering enamelled coating drying.
By applying priming paint on the surface for the treatment of arrangement (veredeln) at wax system article, can carry out surface dressing to all types of for example unvarnished candles.Described priming paint is that metalized provides the foundation/substrate, and particularly makes it possible to achieve wetting.Described in addition priming paint is also guaranteed good adhering on article surface.
Adopt pre-sensitizing solution, to guarantee wetting to matrix surface, to carry out further wet-chemical preparation step and ensuing metalized.Improve metal layer adhering on matrix thus.This can further improve by the multiple pre-sensitizing solution of preferred employing.
Next carry out real article surface metallization by applying metallization solution, described metallization solution deposition becomes metal layer.This preferably by spray a kind of two-pack, by reducing solution and the metallization solution composition spray solution carry out.Component described here is preferably soon being mixed before the spraying in the injector head of spray equipment, and metallization particulate precipitation wherein takes place during spraying process.Form the layer of thin highly reflective.Described reducing solution is based on the carbohydrate of modification, and for silver plated situation, metallization solution is a kind of solution that mainly comprises silver diamminonitrate and ammonium hydroxide and sodium hydroxide.Also add the stable additive of using of small quantities of usual.
By being applied to the covering enamelled coating on the metal layer, can protect metallization (layer) not corrode, particularly flavescence or blackening.Also can form the glossy or lacklustre design of the painted of minute surface ornamental portion or formation surface tissue by transparent covering enamelled coating.For the wax system article of surface metalation, can realize multiple designability in appearance thus.
Described coating varnish preferably is made up of one or more binding agent dispersion liquids based on urethane, polyester and/or polyacrylic ester.Can in coating varnish and priming paint, add the foam-expelling agent in addition, to guarantee all since wax system article are immersed corresponding lacquer bathe in the time bubble that forms during the pouring off of the lacquer of article, break fully.
Draw further feature, details and the advantage of the method according to this invention by the content that the following describes.
Embodiment
The following describes the trailing that is used for all types of unvarnished candles, described candle is provided with the silvered film of specular gloss.
In first method steps, apply priming paint with following component by immersing candle:
| Component | Type | Amount g -1 |
| Polyester polyol CEL L2 resin Eastman CAB 553-0.4 1-methoxypropanol-2 ethanol 99% acetone Efka-2038 Addid 131 | Softening agent binding agent binding agent solvent solvent solvent antifoamer levelling agent and wetting agent | 1.93 15.83 5.37 7.37 67.78 0.48 0.50 0.74 |
| ∑ | Priming paint | 100.00 |
The solvent composition of this priming paint accounts for 76.48%, and its solid particulate composition accounts for 23.52%.With described priming paint adjust under 20 ℃ in the DIN of 4mm dish the viscosity of 15s.Filler of this priming paint (F ü lle) and gloss work for quality and its gloss of later silvered film.
In manual or the immersion enamelling process that carries out with machine, after the pouring off of lacquer, dry the remnants lacquer droplet that remains in place, candle bottom.After this to the paint film of paint film-also comprise candle bottom-carry out complete drying completely.Described complete drying can for example at room temperature carry out at least 12 hours time period with suspension status, promptly for example can carry out at night.
Carry out the coating of silvered film then, describedly carry out coated with a plurality of steps.Therefore, with two kinds of pre-sensitizing solution the prime coat of complete drying is handled.First kind of pre-sensitizing solvent mainly comprises carbohydrate and a spot of adjustment additive of modification, and described additive is present in the spissated mixture of tart.This pre-sensitizing solution is by the U.S., NY, and Vernon, and the Spraylat Corp.NT. company of Aachen, Germany sells with Item Number 12751 with title TL-30 and by the applicant.This aqueous, transparent, filemot liquid can be water-soluble fully, and can carry out acid-reaction.
Under the condition of diluting by 1: 9, use described first kind of pre-sensitizing solution with deionized water.
The candle that is provided with priming paint is immersed described pre-sensitizing solution, next use deionized water rinsing.
Next apply second kind of pre-sensitizing solution, described pre-sensitizing solution mainly comprises tin-halogen compounds and hydrochloric acid.This is a kind of moisture, transparent, colourless to slightly yellowy liquid, and this liquid has irritating smell and can be water-soluble fully.This pre-sensitizing solution is used to make silvered film to adhere to the best on prime coat.
Use described second kind of pre-sensitizing solution with dilution at high proportion, for example one milliliter described solution is added in one liter the deionized water.
Described second kind of pre-sensitizing solution is sold with Item Number 12752 with title " SCS " or by the applicant by Spraylat company.
For ensuing silver-plated, adopt the silver plating process of wet-chemical.Initial soln is mainly to comprise the acidic reduction solution of the carbohydrate of modification and minor amounts of additives and by two kinds of isolating basic solution composition silver solution.
Described reducing solution is sold with Item Number 12753 with title " BKR-5 " or by the applicant by Spraylat company.This solution has about 0.5 to 1.0 pH value (at 22 ℃) and is a kind of aqueous, transparent, slightly pinkish liquid.Really has the additive that the first silver-colored basic solution comprises silver diamminonitrate, ammonium hydroxide and plays stabilization on a small quantity.This is a kind of aqueous, transparent, blue liquid, and this liquid has the smell of intensive ammonia.This solution can be water-soluble fully.Its pH value is about 11 to 12 at 22 ℃.
This basic solution mixes with the second basic solution by identical volume share, and the second basic solution comprises sodium hydroxide, ammonium hydroxide and plays the additive of stabilization on a small quantity.This is a kind of aqueous, transparent, virellous liquid, and this liquid has the smell of ammonia equally.Its pH value is about 13 at 22 ℃.The described second basic solution is that solution is quickened in a kind of reaction basically, wherein can improve speed of response by increasing addition.
These two kinds of silver-colored solution are sold with Item Number 12754 and 12755 with title " BKA-5 " and " BKS-5 " or by the applicant by Spraylat company.Described reducing solution and be filled into respectively in the pressurized vessel that separates of spray equipment by the silver-colored solution of two kinds of aforementioned basic solution compositions mixes two kinds of solution in the injector head at described spray equipment before being about to spraying.Silver-colored particulate precipitation takes place from injector head to the spraying path for the treatment of the surface that mirror-polishing is handled here.Injection duration is about 10 to 15 seconds, up to realizing complete silver plated surface by forming the successive silvered film.Spray pressure is about 2bar, and wherein the mixing nozzle head has the nozzle of 1mm.
After the candle with primer coating immerses pre-sensitizing solution and after the solution of metallize, carry out follow-up flushing by spraying with deionized water respectively.Utilize the spraying gun of dish type spraying gun or band pressurized vessel to carry out described water hydro-peening, wherein adopt the jet size of 1.8mm.
After applying metal layer, make described candle drying at least four hours, but the process of painting should finish here after 24 hours.
Apply a kind of transparent coating varnish, it is flavescence or blackening that described coating varnish is used to protect silvered film that burn into does not take place for this reason.This japanning process is also finished by immersed method, and final drying can be carried out under envrionment conditions, or by the auxiliary shortening in period of heat.
By covering the enamelled coating final effect/precision work (Finish) of change candle like this, promptly specular layer is dyeed.The processing of can frosting in addition.
Provide the example of the component of various coating varnishes below:
-glossiness coating varnish
| Component | FK％ -1Type | Amount g -1 |
| Halwedrol OX 87/40W Joncryl 95 Tafigel PUR 40-solution S urfynol DF-66 deionized water butanediol Surfynol 2502 Byk 347 | 40.0 binding agent dispersion liquid (PUR) 30.0 binding agent dispersion liquids (PA) 20.0 thickeners 49.0 antifoamers 0.0 water 0.0 solvent 0.0 wetting agent 82.0 wetting agents | 773.00 200.00 5.00 5.40 5.40 3.30 1.10 1.50 |
| Butyleneglycol | 0.0 solvent | 4.50 |
| Fisantrol 3010 | 50.0 be used to improve the additive of surface flatness | 2.00 |
| □ | 39.80 glossiness varnish | 1001.20 |
-lacklustre coating varnish (first flexible program)
| Component | FK％ -1 | Type | Amount g -1 |
| Halwedrol TN 6880-2/40W Tafigel PUR 40-solution D euteron MK Syloid ED-30 water Byk 027 | 40.0 20.0 100.0 100.0 0.0 100.0 | Binding agent dispersion liquid (PUR) the thickening material plastics agent water defoaming that frosts that frosts | 783.40 22.00 35.00 60.00 92.80 6.80 |
| ∑ | 44.31 | Matt varnish 1 | 1000.00 |
-lacklustre coating varnish (second flexible program)
| Component | FK％ -1 | Type | Amount g -1 |
| Halwedrol OX 87/40W Joncryl 95 Deuteron MK Syloid ED-30 water Latekoll D 32% Byk 027 | 40.0 30.0 100.0 100.0 0.0 32.0 100.0 | The binding agent dispersion liquid, (PUR) binding agent dispersion liquid, (PA) the plastics agent water hickener defoaming that frosts that frosts | 673.00 173.00 50.00 38.00 51.00 10.00 5.00 |
| ∑ | 43.52 | Matt varnish 2 | 1000.00 |
Adjusting to the viscosity of aforementioned coating varnish at 20 ℃ is 27 seconds in the DIN of 4mm dish.Undertaken painted by 10% the solution that adds corresponding pigment in the 1-methoxypropanol-2 (1-Metoxiprohanol-2) respectively.Next it is 13 seconds by adding in the DIN dish that deionized water adjusts to viscosity at 4mm.
Shown in the component, described coating varnish is by forming based on one or more binding agent dispersion liquids in the mixture of urethane, polyester and/or polyacrylic ester as described above.Binding agent described here is deposited Shi Buhui and flavescence occurred or more weak flavescence only occurs under standard conditions.
The coating varnish that frosts additionally comprises one or more agent of frosting, and the described agent of frosting can be made up of different classes of compounds.
Can reduce solids component in the coating varnish by thickening material.Suitable wetting agent is guaranteed silvered film to be taken place enough wetting by coating varnish.
Set foam-expelling agent make all since wax system article are immersed corresponding lacquer bathe in the time bubble that forms during the pouring off of the lacquer of article, break fully.
Basically can prevent fully that by coating varnish oxygen from arriving silvered film, this has just formed the corrosion protection of wishing.The loss of gloss of the silvered film of also avoiding thus (promptly so-called " oxidation tint (Anlaufen) ").
The exsiccant paint film is also guaranteed the abundant burning of candle in addition, and promptly described paint film can not break when candle combustion, and described paint film can not pollute and itself can be not on fire candlestick.The feature of exsiccant paint film also is in addition, have enough water tolerance at (35 ℃ and below 80% the relative humidity) under the common storage condition, be that described paint film can not dissolve automatically, and do not apply the bigger shearing force that is parallel to the lacquer surface and just described paint film can't be removed.
Claims (14)
1. one kind is used for wax system article are carried out surface metalation, particularly candle carried out the silver plated method of specular gloss, it is characterized in that, comprises following method steps:
-on article surface to be put in order, apply priming paint,
-make the priming paint drying,
-utilize pre-sensitizing solution that the surface of prime coat is handled,
-on the surface of prime coat pre-sensitizing, apply the solvent that comprises metalating agent, depositing a metal layer,
-make formed metal layer drying,
-apply transparent coating varnish, and
-make formed covering enamelled coating drying.
2. the method for claim 1 is characterized in that, applies described priming paint by immersed method.
3. method as claimed in claim 2 is characterized in that, based on solvent, binding agent and additive, particularly makes described priming paint based on tenderizer, flow agent and wetting agent and defoaming.
4. as claim 2 or 3 described methods, it is characterized in that, the drying of priming paint was preferably at room temperature carried out 12 hours at least, so that the prime coat complete drying.
5. each described method in the claim as described above is characterized in that, article are immersed at least a pre-sensitizing solution, carries out pre-sensitizing with the surface to prime coat.
6. method as claimed in claim 5 is characterized in that, adopts a kind of first pre-sensitizing solution and a kind of second pre-sensitizing solution based on hydrochloric acid and tin-halogen compounds that mainly comprises the carbohydrate of modification.
7. each described method in the claim as described above is characterized in that, by spray a kind of two-pack, apply metal layer by the spray solution of reducing solution and metallization solution composition.
8. method as claimed in claim 7 is characterized in that, before being about to spraying, reducing solution and metallization solution is mixed.
9. as claim 7 or 8 described being used for wax system article are carried out silver plated method, it is characterized in that described reducing solution mainly comprises the carbohydrate of modification.
10. as each described being used in the claim 7 to 9 wax system article are carried out silver plated method, it is characterized in that described metallization solution mainly comprises silver diamminonitrate and ammonium hydroxide.
11. method as claimed in claim 10 is characterized in that, adds a kind of reaction that mainly comprises ammonium hydroxide and sodium hydroxide and quicken solution in metallization solution.
12. each described method in the claim is characterized in that as described above, applies the covering enamelled coating by article being immersed in single component or the multi-component binding agent dispersion liquid based on urethane, polyester and/or polyacrylic ester.
13. method as claimed in claim 12 is characterized in that, described binding agent dispersion liquid comprises a kind of defoaming.
14. as claim 12 or 13 described methods, it is characterized in that, in described binding agent dispersion liquid, add frost agent and/or pigment.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE10315322A DE10315322A1 (en) | 2003-04-04 | 2003-04-04 | Process for the surface metallization of wax articles, in particular for mirror-silvering of candles |
| DE10315322.5 | 2003-04-04 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1768129A true CN1768129A (en) | 2006-05-03 |
| CN100354402C CN100354402C (en) | 2007-12-12 |
Family
ID=32981025
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB2004800091170A Expired - Fee Related CN100354402C (en) | 2003-04-04 | 2004-03-05 | Method for surface-metallizing wax objects, especially for silver-plating candles to give them a bright shine |
Country Status (5)
| Country | Link |
|---|---|
| EP (1) | EP1611228B1 (en) |
| CN (1) | CN100354402C (en) |
| AT (1) | ATE341601T1 (en) |
| DE (2) | DE10315322A1 (en) |
| WO (1) | WO2004087853A1 (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL1034166C2 (en) * | 2007-07-19 | 2009-01-20 | Hendrikus Antinius Van Dijk | Candle provided with a foil and method for manufacturing a candle. |
| DE202014006874U1 (en) * | 2014-08-22 | 2014-09-26 | Hendrikus Antonius van Dijk | Candle provided with a cover |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DD228707A3 (en) * | 1983-09-19 | 1985-10-16 | Wittol Wittenberg Veb | METHOD FOR THE PRODUCTION OF COLORED CANDLES AND WAX FORMING BODIES WITH METALLIC SURFACE EFFECT |
| DE3731896A1 (en) * | 1987-09-23 | 1989-04-13 | Eika Wachswerke Fulda Gmbh | METHOD FOR PRODUCING SPARK PLUGS AND SPARK PLUG PRODUCED BY THIS METHOD |
| US6562085B1 (en) * | 2001-06-06 | 2003-05-13 | Ciba Specialty Chemicals Corporation | Candle wax compositions stabilized with UV absorber-metal combinations |
-
2003
- 2003-04-04 DE DE10315322A patent/DE10315322A1/en not_active Withdrawn
-
2004
- 2004-03-05 DE DE502004001681T patent/DE502004001681D1/en not_active Expired - Lifetime
- 2004-03-05 WO PCT/EP2004/002252 patent/WO2004087853A1/en active IP Right Grant
- 2004-03-05 CN CNB2004800091170A patent/CN100354402C/en not_active Expired - Fee Related
- 2004-03-05 AT AT04717599T patent/ATE341601T1/en not_active IP Right Cessation
- 2004-03-05 EP EP04717599A patent/EP1611228B1/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| WO2004087853A1 (en) | 2004-10-14 |
| EP1611228B1 (en) | 2006-10-04 |
| DE502004001681D1 (en) | 2006-11-16 |
| ATE341601T1 (en) | 2006-10-15 |
| DE10315322A1 (en) | 2004-10-14 |
| EP1611228A1 (en) | 2006-01-04 |
| CN100354402C (en) | 2007-12-12 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| EP1557483A1 (en) | Method for forming thin silver mirror film, and method for forming coating film comprising thin silver mirror film | |
| DE102005000836B4 (en) | Process for coating polymer composite parts | |
| AU2017273936A1 (en) | 3C1B coating, method of applying the same and substrate coated therewith | |
| JP2003526012A (en) | Method for applying a phosphate coating and use of a metal part phosphatized by the method | |
| CN1936075A (en) | Electroplating-substituted cladding coating and process | |
| CN107953693B (en) | Environment-friendly water transfer printing process and corresponding component surface structure | |
| EP0729390A1 (en) | Repair enamelling process with several layers of enamel | |
| CN100354402C (en) | Method for surface-metallizing wax objects, especially for silver-plating candles to give them a bright shine | |
| EP1088598B1 (en) | Process for making a polymer film on a metallic substrate, concentrate and treatment solution for this purpose | |
| EP1819781B1 (en) | Flake pigment mixture and multilayer coating method | |
| CA1339915C (en) | Method for the electrophoretic dip coating of chromatizable metal surfaces | |
| CN112371466A (en) | Three-dimensional crack coating, preparation method thereof, lamp fitting and lamp | |
| KR101085551B1 (en) | Process for ultraviolet mirror coating | |
| KR101701634B1 (en) | Color steel sheet and method of manufacturing the same | |
| CN109207987B (en) | Mechanical galvanized carbon steel clamping and pressing type pipe fitting and preparation process thereof | |
| CN111974657A (en) | Preparation method of colorful coating, colorful coating and lamp fitting | |
| CN1569986A (en) | High adhesion metal conditioner for coating metal | |
| DE102006016862A1 (en) | Pressure vessel assembly, ready to use set and method for chemical spray metallization of surfaces | |
| DE10315229A1 (en) | Water vapor plasma process to increase the surface energy of a surface | |
| KR100380754B1 (en) | A method for manufacturing steel roof with good corrosion resistance | |
| WO2004069948A2 (en) | Method for adhesively coating a substrate with a metal layer | |
| CN100371400C (en) | Additive for raising spraying quality of fluorocarbon paint | |
| EP4355927A2 (en) | Decorative plastic component and method for producing such a component | |
| CN113103486A (en) | Hot galvanizing plastic dipping coating method | |
| JPH10244213A (en) | Method for formation of bright paint film and article coated therewith |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20071212 Termination date: 20150305 |
|
| EXPY | Termination of patent right or utility model |