CN1709563A - Plasma fluidized bed for treating material under normal temperature atmosphere and method thereof - Google Patents
Plasma fluidized bed for treating material under normal temperature atmosphere and method thereof Download PDFInfo
- Publication number
- CN1709563A CN1709563A CN 200410048304 CN200410048304A CN1709563A CN 1709563 A CN1709563 A CN 1709563A CN 200410048304 CN200410048304 CN 200410048304 CN 200410048304 A CN200410048304 A CN 200410048304A CN 1709563 A CN1709563 A CN 1709563A
- Authority
- CN
- China
- Prior art keywords
- gas
- bed
- bed body
- voltage
- atmospheric pressure
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Images
Abstract
The invention relates to a kind of plasma sulfurization bed processing materials at room temperature atmospheric pressure. It includes: the bed body produced by insulating material, the downer port of which equips a gas divider, and under the gas divider equips an infundibular gas inlet, which is connected to the gas source to the conduit with gas flowmeter; the side surface of the upper bed body has gas exit, leave a hole above the position of the gas exit of the bed body; the hole equips a conduit with valve, which is linked through a feed-in tundish; set a outer electrode below the gas exit of the bed body to a segment of the outer surface of the gas divider, and the outer electrode is connected to one end of the high voltage alternating current supply; the inner electrode is inserted into the bed body, sealed and fixed at the upper port of the bed body through a insulating board; the inner electrode reaching outside the upper port of the bed body is connected to the other end of the high voltage alternating current supply. The processing method of the invention can operate at room temperature atmospheric pressure without needing vacuum equipment, so its operating cost is low. It won't damage the powdered material, and is suitable to wide area of modified materials.
Description
Technical field
The present invention relates to a kind of plasma processing apparatus that is used for material is carried out the modification processing, particularly relate to a kind of plasma fluidisation bed and processing method of under the normal temperature atmospheric pressure, material being handled.
Technical background
Current fluid unit and technology are ripe relatively, are used widely at chemical enterprise.The technology of material being handled with plasma is comparative maturity also, the applicant with regard to this subject application some patents.And the plasma fluidisation bed that physical method is combined with chemical method and makes, still just begun development in the world, seen a kind of radio frequency plasma fluid bed from external report, as document 1:Plasma fluidized bedimaging and possible strong coupling effects, APPLIED PHYSICSLETTERS, Vol76No.18,2000.5. introduced: this plasma fluidisation bed mainly contains four parts and forms: fluidizing gas control, gas distributor, produce the radio frequency induction coil of plasma, quartz ampoule.The fluidizing gas control system is an importance of fluid bed regulation and control, and it can have influence on the fluidisation degree of particle, and gas distributor can make air-flow be evenly distributed, and coil links to each other with radio-frequency power supply and will produce plasma in the quartz ampoule that the certain vacuum degree is arranged.Quartzy light transmission is good, utilizes the quartz ampoule can be to the relevant parameter of batch (-type) plasma fluidisation bed, measures as the electron temperature of plasma and density etc.This radio frequency plasma fluid bed as shown in Figure 1, its operation principle is to use the 13.56MHz radio-frequency power supply to produce plasma at the glass tube internal induction of certain vacuum degree, the bottom of fluid bed leads to argon gas, and when argon gas reached certain air-flow, the particle in the pipe will suspend and produce the fluidisation phenomenon.This device only could produce plasma under the certain vacuum condition, vacuum equipment can increase operating cost, and the existence of vacuum condition has simultaneously influenced its scope of application.
Also has a kind of direct-current plasma fluid bed, as document 2:A direct current, plasmafluidized bed reactor:its characteristics and application in diamondsynthesis, POWDER TECHNOLOGY, the batch (-type) fluid bed that 88 (1996) 65-70 are introduced, this batch (-type) fluid bed as shown in Figure 2, the logical argon gas in bottom makes the powder particle fluidisation, reacting gas enters from wall one side, the generation of plasma relies on draws electric arc to realize between negative and positive the two poles of the earth, the argon gas that the plasma that generates is fed by the bottom is blown in the fluid bed, reacting gas feeds from the side of gas distributor position, need use water quench because electrode temperature is higher, also limit material modified kind simultaneously.Owing to the existence of these shortcomings, influenced the effective utilization of this two classes plasma fluidisation bed.
Summary of the invention
The objective of the invention is to overcome the defective of above-mentioned prior art; A kind of surface modification treatment that both had been suitable for various dusty materials is provided, can carries out thin-film material again and the degradation treatment of sewage waste gas; The applicability of particularly non-conductive dusty material better processing effect is wide, plasma fluidisation bed and the processing method that can handle material under the normal temperature atmospheric pressure.
The object of the present invention is achieved like this:
The plasma fluidisation bed of under the normal temperature atmospheric pressure material being handled provided by the invention is made up of plasma generation system and powder fluidization system, specifically installs as Fig. 3. shown in.This fluid bed comprises: a body 13, its body 13 lower port are provided with a gas distributor 6 and an infundibulate air inlet 14 are installed below gas distributor 6, and air inlet 14 links to each other with source of the gas 1 by the pipeline 15 of band gas flowmeter 16; Have gas vent 12 on the sidewall on bed body 13 tops, perforate on the position of the gas vent 12 of bed body, the feed pipe 23 of a band valve is installed in this hole, and its pipeline is communicated with a feed hopper 3; On 6 one sections outer walls of gas distributor an external electrode 2 to be set, external electrode 2 is connected with lead with a utmost point of high-voltage ac power 9 at the gas vent 12 of bed body; Interior electrode 8 inserts in the bed body, and passes through an insulation board 5 sealing and fixing in bed body upper port, and the interior electrode 8 that exposes a body upper port is connected with lead with another utmost point of high-voltage ac power 9; Described bed body 13 usefulness insulating materials are made.
Described gas distributor 6 is a nonmetallic slices, has circular hole on it, and the size in aperture is decided according to material modified particle diameter, is generally less than pending material modified particle diameter.This nonmetallic slices comprises organic or inorganic material, for example engineering plastics, ceramic material, quartz glass or mica etc.
The dispatch from foreign news agency that is provided with on described bed body 13 outer walls is a hollow shell very, and the top of this shell has conducting liquid outlet 4, and its underpart has conducting liquid inlet 7, is filled with conducting liquid 24 in it; Perhaps dispatch from foreign news agency very coats a body 13 outer wall last layer conducting films; Perhaps uniform winding conductive filament, and isolate with insulating materials between the internal and external electrode.
Electrode can be that conducting metal rod, conductive metal pipe or conducting metal are made annular electrode etc. in described, and interior number of electrodes is at least one, is arranged in the pipe.
Described high-voltage ac power 9 adopts voltage at 0-30KV, and frequency is at the adjustable ac high voltage source of 20-40KHz.
Described modified gas can feed from air inlet, also can feed with fluidizing gas from the bottom, and fluidizing gas is air, argon gas, nitrogen etc.
Described conducting liquid comprise by the liquid of conductive materials preparation all can, for example: running water, water-soluble inorganic salt solution etc.
Described bed body 13 usefulness insulating materials are made, and insulating materials comprises lucite, engineering plastics, ceramic material, quartz glass etc.
The method of under the normal temperature atmospheric pressure dusty material being handled provided by the invention is included on the plasma fluidisation bed and carries out according to the following steps:
1. when using conduction liquid to do external electrode, at first in the hollow shell of plasma fluidisation bed external electrode, feed conducting liquid, and insert in the conducting liquid utmost point of high-voltage ac power fixedly connected; Perhaps the metal external electrode directly is connected with a utmost point of high-voltage ac power;
2. in funnel, add the dusty material for the treatment of modification, open the dusty material of valve then this dusty material transfer predetermined amounts in fluid bed;
Interior electrode be connected with another utmost point of high-voltage ac power;
4. open gas cylinder or compressed gas source, by the gas flowmeter on gas circuit control gas flow rate, when gas flow rate reached predetermined fluidizing velocity, dusty material will be in fluidisation attitude (different particles, different air velocities);
5. open high-voltage ac power, voltage is adjusted to when producing plasma, feeds and treats modified gas;
6. after material modification is finished, strengthen fluidisation gas flow modified powder is taken out of fluid bed, separate then.
Also be included in and add the catalyst granules that is suitable for waste gas to be measured on the gas distributor, waste gas to be measured feeds from bed body air inlet, and the adjustments of gas flow velocity is less than the carrying velocity of catalyst.Its concrete processing method is as follows:
The method of under the normal temperature atmospheric pressure waste water being handled provided by the invention is included on the plasma fluidisation bed and carries out according to the following steps:
1. when carrying out wastewater treatment, must do external electrode with waste water, at first in the hollow shell (external electrode) of plasma fluidisation bed external electrode, feed waste water, and require to get final product unidirectional feeding feeding also capable of circulation according to different disposal, and insert in the waste water (external electrode) utmost point of high-voltage ac power fixedly connected;
Interior electrode be connected with another utmost point of high-voltage ac power;
3. open compressed gas source, by the control of the gas flowmeter on gas circuit gas flow rate;
4. open high-voltage ac power, voltage is adjusted to the generation plasma, and according to discharge scenario adjustments of gas flow again, prevents the uniformity of the excessive influence discharge of air-flow;
5. will be passed into the waste water that flows through outer shell through the gas of fluid bed, waste water will effectively be degraded under the effect of ultraviolet ray and oxide group.
Also be included in and feed the waste water that adds alkali in the outer shell, add the catalyst that is suitable for pending waste gas on the gas distributor, waste gas to be measured feeds from bed body air inlet, and the adjustments of gas flow velocity is less than the carrying velocity of catalyst.Its concrete processing method is as follows:
The method of under the normal temperature atmospheric pressure waste gas being handled provided by the invention is included on the plasma fluidisation bed and carries out according to the following steps:
1. when using conduction liquid to do external electrode, at first in the hollow shell of plasma fluidisation bed external electrode, feed conducting liquid, and insert in the conducting liquid utmost point of high-voltage ac power fixedly connected; Perhaps the metal external electrode directly is connected with a utmost point of high-voltage ac power;
Interior electrode be connected with another utmost point of high-voltage ac power;
3. in funnel, add the catalyst that is suitable for pending waste gas, open valve then this catalyst is carried appropriate amount of catalysts in fluid bed;
4. feed waste gas from air inlet, regulate exhaust gas flow by gas flowmeter and make catalyst be in fluidisation or the non-state of taking out of gets final product;
5. open high-voltage ac power, voltage is adjusted to the generation plasma, and according to discharge scenario adjustments of gas flow again, to guarantee the exhaust-gas treatment quality;
6. the waste gas after will handling will filter sour gas oxidized and soluble in water in the waste gas by alkaline solution.
The method of under the normal temperature atmospheric pressure waste water and gas being handled simultaneously provided by the invention is included on the plasma fluidisation bed and carries out according to the following steps:
1. in outer shell, feed the waste water add behind the alkali, and extremely link to each other with high-voltage ac power one with lead;
Interior electrode be connected with another utmost point of high-voltage ac power;
3. in funnel, add the catalyst that is suitable for pending waste gas, open valve then this catalyst is carried appropriate amount of catalysts in fluid bed;
4. feed waste gas from bed body air inlet, regulate exhaust gas flow by gas flowmeter and make catalyst be in fluidisation or the non-state of taking out of gets final product;
5. open high-voltage ac power, voltage is adjusted to the generation plasma, and according to discharge scenario adjustments of gas flow again, to guarantee the exhaust-gas treatment quality;
6. the waste gas after will handling will filter sour gas oxidized and soluble in water in the waste gas by waste water, and acid and alkali generation neutralization reaction that sour gas generates become innocuous substance.
The invention has the advantages that: the plasma fluidisation bed that material is handled provided by the invention is owing to adopt continuous feeding and external electrode conductive structure, and can move under the normal temperature atmospheric pressure does not need vacuum equipment, and operating cost is low.Moreover since fluid bed in temperature near normal temperature, can not damage dusty material, material modified scope applicatory is wide, and modification is even.External electrode is a conductive and heat-conductive liquid, so can well lead away the heat on the discharge medium pipe, this device can be worked for a long time; This device is the continuity operation, can obviously enhance productivity; And simple in structure, cost is low.
Modification is by installing top funnel continuous charging for dusty material to utilize device of the present invention, when the bottom feeds air-flow in a certain speed, gravity and buoyancy that dusty material is suffered reach balance, at this moment particle will be suspended in the fluid bed and do not taken out of (at this moment the speed of gas is fluidizing velocity), can add modified gas in company with air-flow.When interior electrode and outside when adding the high frequency high tension voltage between the conducting liquid (external electrode), will between quartzy tube wall and interior electrode, produce plasma, owing to contain a large amount of charged particles in the plasma, particle can with the modified gas molecular collision, so just, produce many active groups, active group will become functional film layer at the dusty material surface aggregate, thereby reach the purpose of dusty material modification, add air flow after modification is finished again the powder of modification is taken out of separation (speed at this moment is carrying velocity).This processing method is simple, and does not need vacuum equipment, reduces operating cost widely.
Description of drawings
Fig. 1 is existing radio frequency plasma fluidized-bed structure schematic diagram
Fig. 2 is existing direct-current plasma fluidized-bed structure schematic diagram
Fig. 3 is a plasma fluidisation bed structure schematic diagram of the present invention
The drawing explanation
1. source of the gas 2. external electrodes 3. feed hoppers
4. conducting liquid exports 6. gas distributor of 5. fixed heads (various insulating materials)
7. electrode 9. high-voltage ac powers in the liquid-inlet 8.
10. lead 11. valves 12. gas vents
13 body 14 air inlets 15 pipelines
16 gas flowmeters, 17 radio frequency induction coils, 18 quartz ampoules
19 negative electrodes, 20 anodes, 21 cooling waters
22 plasmas, 23 feed pipes, 24 conducting liquids
The specific embodiment
With reference to Fig. 3, to make one and can handle dusty material, water is the plasma fluidisation bed that external electrode is worked under the normal temperature atmospheric pressure.
Adopt insulating materials, for example a diameter is that the lucite cylinder of ф 20mm * long 150mm is done a body 13, bed body 13 lower port are installed a gas distributor 6, this gas distributor 6 is for evenly having the circular hole that diameter is alternately arranged for ф 0.2mm on the machine glass flake, number is decided (also can use the general gas distributor of fluid bed) according to the granular size of concrete material, with the infundibulate air inlet 14 that a lucite system is installed below gas distributor 6, air inlet 14 links to each other with source of the gas 1 by the pipeline 15 of band valve; Have gas vent 12 on the sidewall on bed body 13 tops, perforate on the position of the gas vent 12 of bed body, the feed pipe 23 of a band valve is installed in this hole, and its feed pipe 23 is communicated with a funnel shaped feed hopper 3; At the gas vent 12 of bed body so that one section hollow shell to be set on the outer wall of gas distributor 6, the top of this shell has conducting liquid outlet 4, its underpart has conducting liquid inlet 7, be filled with conducting liquid 24 in it as external electrode 2, external electrode 2 is connected with lead 10 with a utmost point of high-voltage ac power 9; The interior electrode 8 that stainless steel tube (electrode material that uses in the plasma processing apparatus all can) is usually made inserts in the bed bodies, and pass through an insulation poly (methyl methacrylate) plate 5 sealing and fixing on bed body 3 upper port, the interior electrode 8 that exposes a body upper port is connected with another polar conductor of high-voltage ac power 8, high-voltage ac power 9 adopts voltage at 0-30KV, and frequency is at the adjustable power supply of 20-40KHz.
The atmospheric pressure plasma fluid bed shown in Figure 3 that utilizes the foregoing description to make, carry out the specific embodiment that modification is handled to material:
One, for example utilize Fig. 3 to realize modification to Paris white powder material hydrophilicity: calcium carbonate powder is a very excellent material of a kind of hydrophilicity, and make it become non-hydrophilicity material only needs get final product at powder surface coating one deck low-surface-energy material.
1. at first in the hollow shell of plasma fluidisation bed external electrode, feed ordinary tap water, and insert in the conducting liquid utmost point of high-voltage ac power fixedly connected; Perhaps the metal external electrode directly is connected with a utmost point of high-voltage ac power;
2. the gas distributor that will have 5 microns in an aperture is put into the fluid bed bottom and is installed;
3. in funnel 3, add diameter again and be about 5 microns calcium carbonate powder, open the calcium carbonate powder of valve then this dusty material transfer predetermined amounts in fluid bed;
4. interior electrode is linked to each other with lead with another electrode of high-voltage ac power;
5. open the argon gas valve and adjust gas flow rate to 3L/s, the calcium carbonate powder in the fluid bed will fluidisation, controls gas flow rate by the gas flowmeter on the gas circuit, and when gas flow rate reached predetermined fluidizing velocity, dusty material will be in the fluidisation attitude; (different granular sizes, different air velocities);
6. regulate high-voltage ac power and will in fluid bed, produce plasma to 10KV, at this moment in argon gas, add HMDO steam, this organosilicon steam will be ionized into active group under action of plasma, form organosilyl low surface aggregate thing on the calcium carbonate powder surface, calcium carbonate powder just becomes hydrophobic material like this.
Two, waste water and gas is handled
Processing has three kinds of pattern: a. separately to the wastewater treatment pattern to waste water and gas at this contrive equipment; B. separately to the exhaust-gas treatment pattern; C. waste water and gas tupe simultaneously.For example utilizing Fig. 3. device is handled chemical plant wastewater and vehicle exhaust.
A. independent wastewater treatment pattern
The waste water that the chemical plant is discharged feeds external electrode (also can make waste water cycle through external electrode), bubbling air in the discharge tube, repeat step to the embodiment one of dusty material processing method, regulate high-voltage ac power to 10KV, make and produce plasma in the fluid bed and make the air of ionization pass through waste water, under the oxidisability active group in ionized air and the effect of plasma middle-ultraviolet lamp, waste water can effectively be degraded.
B. carry out the processing of waste gas (vehicle exhaust) separately:
External electrode can add any conducting liquid, and present embodiment is with KCl or the formulated conducting solution of NaCl inorganic salts, also available other any type of electrode, and on gas distributor, add catalyst granules corresponding to pending waste gas as V
2O
5, TiO
2Deng, repeating step to the embodiment one of dusty material processing method, vehicle exhaust feeds from bed body air inlet, by gas flowmeter control gas flow rate, makes its flow velocity be less than the carrying velocity of catalyst, after it flows through region of discharge, the NO in the waste gas, SO
2Will be oxidized to gas soluble in water Deng pernicious gas, reach the purpose of processing.
When C. waste water and gas is handled simultaneously: logical waste water in the external electrode shell, the tail gas that is open to the traffic in the discharge tube, and on gas distributor, add catalyst V
2O
5, TiO
2Deng, through waste water by adding alkali after after handling of the waste gas of region of discharge (in waste water, add an amount of alkali can with the sour gas reaction in the waste gas, thereby sour gas is filtered), will sour gas oxidized and soluble in water in the waste gas be filtered, acid and alkali generation neutralization reaction that sour gas generates become innocuous substance.
The discharge type of these three kinds of patterns is identical with calcium carbonate powder modification operation form, will not tire out and state.
Claims (10)
1. plasma fluidisation bed of under the normal temperature atmospheric pressure, material being handled, comprise: a body (13), its body (13) lower port is provided with a gas distributor (6), with installation one infundibulate air inlet (14) below gas distributor (6), air inlet (14) links to each other with source of the gas (1) by the pipeline (15) of band gas flowmeter (16); Have gas vent (12) on the sidewall on bed body (13) top, it is characterized in that: also be included in perforate on the position of gas vent (12) of a body, the pipeline of a band valve is installed in this hole, and its pipeline is communicated with a feed hopper (3); On (6) one sections outer walls of gas distributor an external electrode (2) to be set, external electrode (2) is electrically connected with a utmost point of high-voltage ac power (9) at the gas vent (12) of bed body; Interior electrode (8) inserts in the bed body, and passes through an insulation board (5) sealing and fixing in bed body upper port, and the interior electrode (8) that exposes a body upper port is electrically connected with another utmost point of high-voltage ac power (9); Described bed body (13) is made of insulating materials.
2. by the described plasma fluidisation bed of under the normal temperature atmospheric pressure, material being handled of claim 1, it is characterized in that: described external electrode (2) is for being provided with a hollow shell on bed body (13) outer wall, the top of this shell has conducting liquid import (4), its underpart has conducting liquid outlet (7), is filled with conducting liquid (24) in it and forms.
3. by the described plasma fluidisation bed of under the normal temperature atmospheric pressure material being handled of claim 1, it is characterized in that: described external electrode (8) is for coating bed body (13) outer wall last layer conducting film; Perhaps uniform winding conductive filament, and isolate with insulating materials between the internal and external electrode.
4. by the described plasma fluidisation bed of under the normal temperature atmospheric pressure, material being handled of claim 1, it is characterized in that: electrode (8) is that conducting metal rod, conductive metal pipe or conducting metal are made annular electrode in described, and interior number of electrodes is at least one, is arranged in the pipe.
5. by the described plasma fluidisation bed of under the normal temperature atmospheric pressure material being handled of claim 1, it is characterized in that: described high-voltage ac power (9) adopts voltage at 0-30KV, and frequency is at the adjustable ac high voltage source of 20-40KHz.
6. by the described plasma fluidisation bed of under the normal temperature atmospheric pressure, material being handled of claim 1, it is characterized in that: described modified gas feeds from air inlet, or feed with fluidizing gas from the bottom, fluidizing gas is air, argon gas, nitrogen.
7. by the described plasma fluidisation bed of under the normal temperature atmospheric pressure material being handled of claim 1, it is characterized in that: described conducting liquid comprises by the liquid of conductive materials preparation, water-soluble inorganic salt solution or running water.
8. an application rights requires the 1 described method of on the plasma fluidisation bed of under the normal temperature atmospheric pressure material being handled material being handled, and comprises according to the following steps and carrying out:
A. when using conduction liquid to do external electrode, at first in the hollow shell of plasma fluidisation bed external electrode, feed conducting liquid, and insert in the conducting liquid utmost point of high-voltage ac power fixedly connected; Perhaps the metal external electrode directly is connected with a utmost point of high-voltage ac power;
B. in funnel, add the dusty material for the treatment of modification, open the dusty material of valve then this dusty material transfer predetermined amounts in fluid bed;
C. interior electrode be connected with another utmost point of high-voltage ac power;
D. open gas cylinder or compressed gas source,, gas flow rate is reached predetermined fluidizing velocity by the control of the gas flowmeter on gas circuit gas flow rate;
E. open high-voltage ac power, voltage is adjusted to when producing plasma, feeds and treats modified gas;
F. after material modification is finished, strengthen fluidisation gas flow modified powder is taken out of fluid bed, separate then.
9. by on the described plasma fluidisation of claim 8 bed, the method of under the normal temperature atmospheric pressure, material being handled, it is characterized in that: also be included in and add the catalyst granules that is suitable for waste gas to be measured on the gas distributor, waste gas to be measured feeds from bed body air inlet, and the adjustments of gas flow velocity is less than the carrying velocity of catalyst.
10. by on the described plasma fluidisation of claim 8 bed, the method of under the normal temperature atmospheric pressure, material being handled, it is characterized in that: also be included in and feed the waste water that adds alkali in the outer shell, add the catalyst that is suitable for pending waste gas on the gas distributor, waste gas to be measured feeds from bed body air inlet, and the adjustments of gas flow velocity is less than the carrying velocity of catalyst.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2004100483041A CN100376319C (en) | 2004-06-17 | 2004-06-17 | Plasma fluidized bed for treating material under normal temperature atmosphere and method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2004100483041A CN100376319C (en) | 2004-06-17 | 2004-06-17 | Plasma fluidized bed for treating material under normal temperature atmosphere and method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1709563A true CN1709563A (en) | 2005-12-21 |
| CN100376319C CN100376319C (en) | 2008-03-26 |
Family
ID=35705894
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB2004100483041A Expired - Fee Related CN100376319C (en) | 2004-06-17 | 2004-06-17 | Plasma fluidized bed for treating material under normal temperature atmosphere and method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN100376319C (en) |
Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102120166A (en) * | 2010-12-17 | 2011-07-13 | 中国科学技术大学 | Low-temperature cold plasma magnetic fluidized bed reactor |
| CN102744020A (en) * | 2011-04-22 | 2012-10-24 | 苏州市奥普斯等离子体科技有限公司 | Powder material low temperature plasma surface treatment method and its apparatus |
| CN103194001A (en) * | 2013-04-27 | 2013-07-10 | 重庆邮电大学 | Plasma treatment device and plasma treatment method for polymer material surface modification |
| CN103242679A (en) * | 2013-05-20 | 2013-08-14 | 南通市争妍颜料化工有限公司 | Device for loading groups on surfaces of pigment particles and application of device |
| CN103594317A (en) * | 2013-11-27 | 2014-02-19 | 苏州市奥普斯等离子体科技有限公司 | Improved type powder material surface plasma processing device |
| CN104114649A (en) * | 2011-12-05 | 2014-10-22 | 索尔维公司 | Use of atmospheric plasma for the surface of inorganic particles and inorganic particles comprising an organic fluorine-containing surface modification |
| CN104284505A (en) * | 2014-10-27 | 2015-01-14 | 核工业西南物理研究院 | Normal-pressure low-temperature plasma running water form powder material modifying system |
| CN104607457A (en) * | 2014-12-23 | 2015-05-13 | 中山大学 | Device for treating organic contaminated soil on plasma fluidized bed |
| CN107028765A (en) * | 2017-05-05 | 2017-08-11 | 盐城卫生职业技术学院 | Pharmaceutical process plant and drug handling device |
| CN110292854A (en) * | 2019-07-03 | 2019-10-01 | 浙江工商大学 | A kind of pulse plasma couples the apparatus and method of double-fluidized-bed catalytic degradation VOCs |
| CN110724434A (en) * | 2019-10-15 | 2020-01-24 | 华北电力大学 | Nano SiC/epoxy coating material, preparation method and application thereof |
| CN113413835A (en) * | 2021-06-17 | 2021-09-21 | 杭州永青环保技术有限公司 | Normal-pressure plasma fluidized bed device without inner electrode and application thereof |
| CN115055140A (en) * | 2022-07-12 | 2022-09-16 | 南京工业大学 | Coaxial DBD powder cladding device of circulation integral type |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2582542B1 (en) * | 1985-05-31 | 1987-08-28 | Cle Groupe Technip | PROCESS FOR TREATING A FLUIDIZED BED IN A REACTOR AND PLANT FOR CARRYING OUT SAID METHOD |
| FR2582541B1 (en) * | 1985-05-31 | 1987-08-28 | Cle Groupe Technip | PROCESS FOR TREATING A FLUIDIZED BED AND INSTALLATION COMPRISING THE APPLICATION OF THIS PROCESS |
| US20030157000A1 (en) * | 2002-02-15 | 2003-08-21 | Kimberly-Clark Worldwide, Inc. | Fluidized bed activated by excimer plasma and materials produced therefrom |
-
2004
- 2004-06-17 CN CNB2004100483041A patent/CN100376319C/en not_active Expired - Fee Related
Cited By (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102120166A (en) * | 2010-12-17 | 2011-07-13 | 中国科学技术大学 | Low-temperature cold plasma magnetic fluidized bed reactor |
| CN102744020B (en) * | 2011-04-22 | 2016-02-17 | 苏州市奥普斯等离子体科技有限公司 | A kind of powder material low temperature plasma surface treatment and device thereof |
| CN102744020A (en) * | 2011-04-22 | 2012-10-24 | 苏州市奥普斯等离子体科技有限公司 | Powder material low temperature plasma surface treatment method and its apparatus |
| CN104114649A (en) * | 2011-12-05 | 2014-10-22 | 索尔维公司 | Use of atmospheric plasma for the surface of inorganic particles and inorganic particles comprising an organic fluorine-containing surface modification |
| CN103194001A (en) * | 2013-04-27 | 2013-07-10 | 重庆邮电大学 | Plasma treatment device and plasma treatment method for polymer material surface modification |
| CN103242679A (en) * | 2013-05-20 | 2013-08-14 | 南通市争妍颜料化工有限公司 | Device for loading groups on surfaces of pigment particles and application of device |
| CN103594317A (en) * | 2013-11-27 | 2014-02-19 | 苏州市奥普斯等离子体科技有限公司 | Improved type powder material surface plasma processing device |
| CN104284505A (en) * | 2014-10-27 | 2015-01-14 | 核工业西南物理研究院 | Normal-pressure low-temperature plasma running water form powder material modifying system |
| CN104607457A (en) * | 2014-12-23 | 2015-05-13 | 中山大学 | Device for treating organic contaminated soil on plasma fluidized bed |
| CN107028765A (en) * | 2017-05-05 | 2017-08-11 | 盐城卫生职业技术学院 | Pharmaceutical process plant and drug handling device |
| CN110292854A (en) * | 2019-07-03 | 2019-10-01 | 浙江工商大学 | A kind of pulse plasma couples the apparatus and method of double-fluidized-bed catalytic degradation VOCs |
| CN110292854B (en) * | 2019-07-03 | 2021-10-29 | 浙江工商大学 | Device and method for catalytic degradation of VOCs (volatile organic compounds) by pulse plasma coupling double fluidized beds |
| CN110724434A (en) * | 2019-10-15 | 2020-01-24 | 华北电力大学 | Nano SiC/epoxy coating material, preparation method and application thereof |
| CN113413835A (en) * | 2021-06-17 | 2021-09-21 | 杭州永青环保技术有限公司 | Normal-pressure plasma fluidized bed device without inner electrode and application thereof |
| CN113413835B (en) * | 2021-06-17 | 2022-10-21 | 杭州永青环保技术有限公司 | Normal-pressure plasma fluidized bed device without inner electrode and application thereof |
| CN115055140A (en) * | 2022-07-12 | 2022-09-16 | 南京工业大学 | Coaxial DBD powder cladding device of circulation integral type |
Also Published As
| Publication number | Publication date |
|---|---|
| CN100376319C (en) | 2008-03-26 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN1709563A (en) | Plasma fluidized bed for treating material under normal temperature atmosphere and method thereof | |
| CN107162158B (en) | Fenton fluidized bed reactor and method | |
| CN2813596Y (en) | Dielectric blocking discharge plasma waste gas and waste liquid purifying device | |
| CN103451623B (en) | A kind of Atomic layer deposition method of Coated powder and device | |
| CN1467152A (en) | Manufacturing method for a carbon nanomaterial, a manufacturing apparatus for a carbon nanomaterial, and manufacturing facility for a carbon nanomaterial | |
| CN102671582A (en) | Reactor and method for producing particle materials | |
| CN105645559A (en) | Device for treating industrial wastewater according to ozone catalytic oxidation method and treatment process | |
| CN110642320B (en) | A rotatory packed bed for handling ammonia nitrogen waste water | |
| CN102249452B (en) | Drinking water advanced treatment system and method based on hydraulic circulating reactor | |
| CN2718948Y (en) | Plasma material processing equipment | |
| CN111807600A (en) | Method and device for treating trimethoprim wastewater | |
| CN1229815C (en) | Atomic energy power plant system and its running method | |
| CN104556348A (en) | Magnetic catalytic ozonation device and method | |
| CN1041703A (en) | Device from the fluid medium separation of ferromagnetic materials | |
| CN205590393U (en) | Industrial waste water's device is handled to ozone catalytic oxidation method | |
| CN114192091B (en) | Plasma device system and method for surface modification of powder material | |
| CN218321079U (en) | Built-in denitrification fluidizing device | |
| CN207259201U (en) | The equipment handled using photochemical catalytic oxidation cooling circulating water and landscape water | |
| CN105417641A (en) | Efficient bin type micro-electrolysis generator and waste water treatment process thereof | |
| CN112802731B (en) | Material circulation modification device based on dielectric barrier discharge plasma | |
| CN105948346B (en) | A kind of toxic organic sewage treatment device of inclined-plate clarifying basin compound needle barrel plasma | |
| CN207047035U (en) | A kind of novel fluidization bed photocatalysis sewage purifier | |
| CN115477379B (en) | Method for degrading organic wastewater by utilizing integral catalyst and liquid film to regulate and strengthen plasma | |
| CN115055140B (en) | Coaxial DBD powder cladding device of circulation integral type | |
| RU67987U1 (en) | DEVICE FOR GRANULATING A TECHNOGLEROD WET METHOD |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C17 | Cessation of patent right | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20080326 Termination date: 20100617 |