CN1702130A - Aqueous rust proof coating and preparation method thereof - Google Patents
Aqueous rust proof coating and preparation method thereof Download PDFInfo
- Publication number
- CN1702130A CN1702130A CN 200410018597 CN200410018597A CN1702130A CN 1702130 A CN1702130 A CN 1702130A CN 200410018597 CN200410018597 CN 200410018597 CN 200410018597 A CN200410018597 A CN 200410018597A CN 1702130 A CN1702130 A CN 1702130A
- Authority
- CN
- China
- Prior art keywords
- water
- rust
- iron oxide
- phosphoric acid
- talcum powder
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 title claims abstract description 20
- 238000002360 preparation method Methods 0.000 title claims abstract description 7
- 239000011248 coating agent Substances 0.000 title description 11
- 238000000576 coating method Methods 0.000 title description 11
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 21
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims abstract description 18
- NIXOWILDQLNWCW-UHFFFAOYSA-N Acrylic acid Chemical compound OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims abstract description 11
- 238000004132 cross linking Methods 0.000 claims abstract description 11
- 239000000839 emulsion Substances 0.000 claims abstract description 11
- 239000003973 paint Substances 0.000 claims abstract description 11
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims abstract description 9
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 claims abstract description 9
- 239000004576 sand Substances 0.000 claims abstract description 5
- 238000001914 filtration Methods 0.000 claims abstract description 3
- 239000000203 mixture Substances 0.000 claims abstract description 3
- LPXPTNMVRIOKMN-UHFFFAOYSA-M sodium nitrite Chemical compound [Na+].[O-]N=O LPXPTNMVRIOKMN-UHFFFAOYSA-M 0.000 claims description 14
- 239000000080 wetting agent Substances 0.000 claims description 9
- ZTFZSHLWORMEHO-UHFFFAOYSA-A pentaaluminum;[oxido(phosphonatooxy)phosphoryl] phosphate Chemical compound [Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O.[O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O.[O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O ZTFZSHLWORMEHO-UHFFFAOYSA-A 0.000 claims description 7
- 229920001495 poly(sodium acrylate) polymer Polymers 0.000 claims description 7
- 235000010288 sodium nitrite Nutrition 0.000 claims description 7
- NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical compound [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 claims description 7
- 239000002002 slurry Substances 0.000 claims description 4
- 238000005516 engineering process Methods 0.000 claims description 2
- 238000009775 high-speed stirring Methods 0.000 claims description 2
- 238000003801 milling Methods 0.000 claims description 2
- 238000003756 stirring Methods 0.000 claims description 2
- 239000008400 supply water Substances 0.000 claims description 2
- 239000000945 filler Substances 0.000 claims 1
- 238000001035 drying Methods 0.000 abstract description 8
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 abstract description 6
- 229910001385 heavy metal Inorganic materials 0.000 abstract description 4
- 238000000034 method Methods 0.000 abstract description 4
- 239000004411 aluminium Substances 0.000 abstract 2
- 229910052782 aluminium Inorganic materials 0.000 abstract 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 abstract 2
- 239000003906 humectant Substances 0.000 abstract 2
- 238000002156 mixing Methods 0.000 abstract 2
- 210000002966 serum Anatomy 0.000 abstract 2
- 159000000000 sodium salts Chemical class 0.000 abstract 2
- 231100000331 toxic Toxicity 0.000 abstract 1
- 230000002588 toxic effect Effects 0.000 abstract 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 4
- 229910052804 chromium Inorganic materials 0.000 description 4
- 239000011651 chromium Substances 0.000 description 4
- 230000007613 environmental effect Effects 0.000 description 4
- FJWGYAHXMCUOOM-QHOUIDNNSA-N [(2s,3r,4s,5r,6r)-2-[(2r,3r,4s,5r,6s)-4,5-dinitrooxy-2-(nitrooxymethyl)-6-[(2r,3r,4s,5r,6s)-4,5,6-trinitrooxy-2-(nitrooxymethyl)oxan-3-yl]oxyoxan-3-yl]oxy-3,5-dinitrooxy-6-(nitrooxymethyl)oxan-4-yl] nitrate Chemical compound O([C@@H]1O[C@@H]([C@H]([C@H](O[N+]([O-])=O)[C@H]1O[N+]([O-])=O)O[C@H]1[C@@H]([C@@H](O[N+]([O-])=O)[C@H](O[N+]([O-])=O)[C@@H](CO[N+]([O-])=O)O1)O[N+]([O-])=O)CO[N+](=O)[O-])[C@@H]1[C@@H](CO[N+]([O-])=O)O[C@@H](O[N+]([O-])=O)[C@H](O[N+]([O-])=O)[C@H]1O[N+]([O-])=O FJWGYAHXMCUOOM-QHOUIDNNSA-N 0.000 description 3
- 239000008139 complexing agent Substances 0.000 description 3
- 229920001220 nitrocellulos Polymers 0.000 description 3
- 229940079938 nitrocellulose Drugs 0.000 description 3
- 239000000049 pigment Substances 0.000 description 3
- 239000004593 Epoxy Substances 0.000 description 2
- 239000000020 Nitrocellulose Substances 0.000 description 2
- 230000002378 acidificating effect Effects 0.000 description 2
- 238000005187 foaming Methods 0.000 description 2
- 238000007689 inspection Methods 0.000 description 2
- 239000004922 lacquer Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 230000035939 shock Effects 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 239000002253 acid Substances 0.000 description 1
- 238000003556 assay Methods 0.000 description 1
- 230000001680 brushing effect Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- UCNNJGDEJXIUCC-UHFFFAOYSA-L hydroxy(oxo)iron;iron Chemical compound [Fe].O[Fe]=O.O[Fe]=O UCNNJGDEJXIUCC-UHFFFAOYSA-L 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 230000009972 noncorrosive effect Effects 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 230000037452 priming Effects 0.000 description 1
- 230000002787 reinforcement Effects 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- NDKWCCLKSWNDBG-UHFFFAOYSA-N zinc;dioxido(dioxo)chromium Chemical compound [Zn+2].[O-][Cr]([O-])(=O)=O NDKWCCLKSWNDBG-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Paints Or Removers (AREA)
Abstract
The invention relates to water-based antirusting paint operable with rust and the method for preparation. The water-based paint contains talcum powder, iron oxide red, phosphoric acid, CF-01 non-ionic humectant, P-19 polyacrylic sodium salt disperser, aluminium tropolyphosphate, self crosslinking acroleic acid emulsion, erinitrit and water added up to 100% (weight). The method for preparation is as following: mixing by homogenizer match said P-19 polyacrylic sodium salt disperser, CF-01 non-ionic humectant, talcum powder, iron oxide red, aluminium tropolyphosphate, and erinitrit, then sending the mixture to sand mill and sanding to prepare the serum of a fineness less than 60 micrometre, adding self crosslinking acroleic acid emulsion and phosphoric acid to the serum and mixing thoroughly, and filtering to prepare the product. It has a characteristic of no-containing of toxic and heavy metal, drying quickly, operable with rust, and corrosion-preventive property nice.
Description
Technical field
The present invention relates to a kind of water-based antirusting paint operable with rust, the invention still further relates to this preparation method for coating.
Background technology
Traditional low-solid content solvent-borne type epoxy rust-proofing primer contains 50% organic solvent approximately.These organic solvent prices are expensive day by day with the shortage of oil equal energy source, and enter atmosphere, contaminate environment, harm humans health in the manufacturing and the construction stage of coating.Along with expanding economy and human life quality's raising, the cry of the claimed self-living space of people is also more and more higher, and environmental regulation is also more and more stricter.The reinforcement of environmental regulation has limited the application of heavy metallic pigment in coating such as lead, chromium.Traditional aqueous rusty rust-proofing primer, heavy metal rust-stabilising pigments such as, the chromium leaded for antirust interpolation zinc-chrome yellow etc. that has come antirust, as CN1361210A; What have has added water soluble resin in order to improve the coating surface performance, slow-drying, and as CN1456603A, CN1456600A.
Summary of the invention
The object of the invention is exactly the shortcoming that overcomes solvent-borne type and above several aqueous rusty rust-inhibiting paints, utilizes the good and drying of surface property self-crosslinking acrylic emulsion and the antirust complexing agent of acidic derusting rapidly, and a kind of Rust-resisting coating is provided.This coating material production, use simply can be with the rust operation, and be dry rapid; With water is solvent, and does not contain heavy metals such as chromium, lead, is the Rust-resisting coating of a kind of superior performance, safety, environmental protection.
The weight percent of water-based antirusting paint operable with rust of the present invention is composed as follows:
Talcum powder 1～6%,
Red iron oxide 8～20%,
Phosphoric acid 0.2～1.2%,
Soxylat A 25-7 non-ionic wetting agent 0.1～0.6%,
(CF-01 wetting agent)
P-19 sodium polyacrylate dipersant 0.3～1.2%,
Aluminium triphosphate 3～12%,
Self-crosslinking acrylic emulsion 30～60%,
Sodium Nitrite 0.1～0.2%,
Water adds to 100%.
The weight percent composition of rust proof paint of the present invention is preferably:
Talcum powder 3～5%,
Red iron oxide 10～15%,
Phosphoric acid 0.4～1.0%,
Soxylat A 25-7 non-ionic wetting agent 0.2～0.5%,
(CF-01 wetting agent)
P-19 sodium polyacrylate dipersant 0.5～1%,
Aluminium triphosphate 5～10%,
Self-crosslinking acrylic emulsion 40～50%,
Sodium Nitrite 0.1～0.2%,
Water adds to 100%.
CF-01 non-ionic wetting agent, P-19 sodium polyacrylate dipersant are the commodity that Shanghai Changfeng Chemical Factory of Shanghai Coatings Co., Ltd. produces.
Preparation method's of the present invention processing step is as follows:
(1) in the container of band high speed agitator, adds certain water gaging by proportioning, after P-19 sodium polyacrylate dipersant, Soxylat A 25-7 non-ionic wetting agent, talcum powder, red iron oxide, aluminium triphosphate, the Sodium Nitrite high-speed stirring, put into sand mill and carry out sand milling, making fineness, to be lower than 60 microns slurries stand-by;
(2) by proportioning self-crosslinking acrylic emulsion and complexing agent phosphoric acid are added in the prepared slurries of step (1), supply water to 100% weight percent, fully stir evenly, get product after the filtration.
Compared with prior art the present invention has following advantage: one, being solvent with water, not containing heavy metals such as chromium, lead, is a kind of coating of safe, nontoxic, environmental protection.Two, adopt surface property good, drying self-crosslinking acrylic emulsion rapidly is main base-material, coating fast drying of the present invention, acid and alkali-resistance, the corrosion of anti-atmospheric environment.Three, adopt the antirust complexing agent of acidic derusting, coating of the present invention can be with the rust operation, and rustless property is good.
Embodiment
In order to further specify the present invention, now for following embodiment, but the present invention is not limited to embodiment.
Following examples detect with reference to H06-2 iron oxide red, iron black epoxy ester undercoat HG2239-91 standard-required.
The test rating and the method for inspection are as follows:
| Project | Index | The method of inspection |
| Time of drying (h) | Do solid work≤24,120 ℃ of oven dry≤1 surface drying≤2 | ??GB1278-79 |
| Density (g/ml) | ??1.20 | ??GB/T6750-1986 |
| Viscosity (T-4) | ??≥45s | ??GB/T6753.4-1998 |
| Hardness | ??≥0.4 | ??GB/T1730-1993 |
| Snappiness (mm) | ??≤1 | ??GB/T1731-1993 |
| Shock strength | ??50cm | ??GB/T1732-93 |
| Sticking power | ≤ 2 grades | ??GB1720-79 |
| Resistance to salt water | 48 hours non-foaming, non-corrosive | ??GB/T1771-91 |
| Nitrocellulose lacquer resistance | Film color does not expand, and is non-foaming | When priming paint is not dried, the brushing pyroxylin(e)finish |
The prescription of embodiment 1～embodiment 5 (weight %)
| Prescription is formed | Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | Embodiment 5 |
| Talcum powder | ??1 | ??3 | ??3 | ??4 | ??6 |
| Red iron oxide | ??8 | ??15 | ??10 | ??10 | ??20 |
| Phosphoric acid | ??0.2 | ??0.5 | ??0.4 | ??1 | ??1.2 |
| ??CF-01 | ??0.1 | ??0.3 | ??0.3 | ??0.4 | ??0.6 |
| The P-19 dispersion agent | ??0.3 | ??0.5 | ??0.5 | ??1 | ??1.2 |
| Aluminium triphosphate | ??3 | ??6 | ??3 | ??12 | ??12 |
| The self-crosslinking acrylic emulsion | ??60 | ??40 | ??40 | ??50 | ??30 |
| Sodium Nitrite | ??0.1 | ??0.1 | ??0.1 | ??0.2 | ??0.2 |
| Water | ??27.3 | ??34.6 | ??42.7 | ??21.4 | ??28.8 |
| The prescription total amount | ??100 | ??100 | ??100 | ??100 | ??100 |
Detected result
| Project | Assay | ||||
| Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | Embodiment 5 | |
| Time of drying (h) | By | By | By | By | By |
| Density (g/ml) | ??1.22 | ??1.22 | ??1.24 | ??1.26 | ??1.30 |
| Viscosity (T-4) (S) | ??50 | ??55 | ??60 | ??62 | ??60 |
| Hardness | ??0.5 | ??0.6 | ??0.6 | ??0.6 | ??0.7 |
| Snappiness (mm) | ??0.5 | ??1 | ??1 | ??0.5 | ??1 |
| Shock strength | By | By | By | By | By |
| Sticking power | ??1 | ??2 | ??2 | ??1 | ??2 |
| Resistance to salt water | By | By | By | By | By |
| Nitrocellulose lacquer resistance | By | By | By | By | By |
According to above result, can select the prescription of different resin-pigment ratios according to the different metal surface requirements, obtain the product of different performance.
Claims (3)
1, a kind of water-based antirusting paint operable with rust is characterized in that its weight percent is composed as follows:
Talcum powder 1～6%,
Red iron oxide 8～20%,
Phosphoric acid 0.2～1.2%,
Soxylat A 25-7 non-ionic wetting agent 0.1～0.6%,
P-19 sodium polyacrylate dipersant 0.3～1.2%,
Aluminium triphosphate 3～12%,
Self-crosslinking acrylic emulsion 30～60%,
Sodium Nitrite 0.1～0.2%,
Water adds to 100%.
2, water-based antirusting paint operable with rust according to claim 1 is characterized in that its weight percent composition is preferably:
Talcum powder 3～5%,
Red iron oxide 10～15%,
Phosphoric acid 0.4～1.0%,
Soxylat A 25-7 non-ionic wetting agent 0.2～0.5%,
P-19 sodium polyacrylate dipersant 0.5～1%,
Aluminium triphosphate 5～10%,
Self-crosslinking acrylic emulsion 40～50%,
Sodium Nitrite 0.1～0.2%,
Water adds to 100%.
3, a kind of preparation method of water-based antirusting paint operable with rust is characterized in that its technology is as follows:
(1) in the container of band high speed agitator, adds a certain amount of water by proportioning, after P-19 sodium polyacrylate dipersant, Soxylat A 25-7 non-ionic wetting agent, talcum powder, red iron oxide, aluminium triphosphate, the Sodium Nitrite high-speed stirring, put into sand mill and carry out sand milling, when face wherein, when the filler grain granularity is lower than 60 microns, stop to grind, it is stand-by to make slurries;
(2) by proportioning self-crosslinking acrylic emulsion and phosphoric acid are added in the prepared slurries of step (1), supply water to 100% weight percent, fully stir evenly, get product after the filtration.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2004100185979A CN1333023C (en) | 2004-05-24 | 2004-05-24 | Aqueous rust proof coating and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2004100185979A CN1333023C (en) | 2004-05-24 | 2004-05-24 | Aqueous rust proof coating and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1702130A true CN1702130A (en) | 2005-11-30 |
| CN1333023C CN1333023C (en) | 2007-08-22 |
Family
ID=35632099
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB2004100185979A Expired - Fee Related CN1333023C (en) | 2004-05-24 | 2004-05-24 | Aqueous rust proof coating and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1333023C (en) |
Cited By (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1995249B (en) * | 2006-11-22 | 2011-01-19 | 刘天仕 | Aqueous modified polyester anti-corrosive paint for rust article |
| CN1986649B (en) * | 2005-12-19 | 2011-12-14 | 深圳市海川实业股份有限公司 | Hydrophobic water-base iron red color paste |
| CN102993792A (en) * | 2012-10-15 | 2013-03-27 | 怀远县巨龙机械制造有限公司 | High-gloss metal anti-rust paint and preparation method thereof |
| CN102986867A (en) * | 2012-10-15 | 2013-03-27 | 怀远县巨龙机械制造有限公司 | Grain drying machine with circulating hot air |
| CN102993841A (en) * | 2012-10-15 | 2013-03-27 | 怀远县巨龙机械制造有限公司 | Water-based flame-retardant antirust paint |
| CN103289488A (en) * | 2012-12-06 | 2013-09-11 | 侯保荣 | Oxidative polymerization type adhesive |
| CN103509394A (en) * | 2013-09-10 | 2014-01-15 | 马鞍山市金韩涂料制造有限公司 | Red iron oxide antirust paint and preparation method thereof |
| CN103567887A (en) * | 2013-11-20 | 2014-02-12 | 江苏江旭铸造集团有限公司 | Casting sand |
| CN103602183A (en) * | 2013-10-22 | 2014-02-26 | 广州擎天材料科技有限公司 | Fast-curing indentation-proof water-based paint for galvanized sheet and preparation method thereof |
| CN103642338A (en) * | 2013-07-15 | 2014-03-19 | 抚顺市海丰化工有限公司 | Water-based self-crosslinking acrylic acid iron oxide red antiseptic paint and preparation method therefor |
| CN103665981A (en) * | 2013-11-29 | 2014-03-26 | 江苏太平洋液压机械制造有限公司 | Anticorrosive paint containing acrylic emulsion |
| CN103756452A (en) * | 2013-12-25 | 2014-04-30 | 苏州市邦成电子科技有限公司 | Metal antirust paint and preparation method thereof |
| CN104312368A (en) * | 2014-11-05 | 2015-01-28 | 徐强 | Water-soluble phenolic anti-rust paint and preparation method thereof |
| CN104341924A (en) * | 2014-11-14 | 2015-02-11 | 无锡伊佩克科技有限公司 | Water-based antirust and rust removing asphalt ship bottom coating and preparation method for same |
| CN106675144A (en) * | 2016-12-01 | 2017-05-17 | 河池市技术开发中心 | Antirust paint for blade of farm cultivator |
| CN106854403A (en) * | 2016-12-27 | 2017-06-16 | 成都渝三峡油漆有限公司 | A kind of water-based primer-topcoat in one type paint and preparation method thereof |
| CN110885578A (en) * | 2019-12-06 | 2020-03-17 | 山东方大杭萧钢构科技有限公司 | Water-based antirust coating applied to steel structure and preparation method thereof |
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| CN1046344A (en) * | 1989-04-15 | 1990-10-24 | 林贻训 | Rust-resisting coating |
| CN1048872A (en) * | 1989-07-17 | 1991-01-30 | 薛志纯 | On rust paint |
| CN1057473A (en) * | 1991-06-22 | 1992-01-01 | 太原市电器工程公司 | Rust-removing and heat-resisting priming paint |
| CN1087924A (en) * | 1992-12-09 | 1994-06-15 | 李士福 | Rust-resisting coating and manufacture method thereof |
| CN1162487C (en) * | 2001-08-17 | 2004-08-18 | 成贵闪 | Antirust priming paint |
| CN1141344C (en) * | 2001-10-17 | 2004-03-10 | 中国人民解放军海军舰船维修研究所 | Priming paint for wet and rusted surface |
| CN1458197A (en) * | 2002-12-31 | 2003-11-26 | 叶春山 | Anti-rust paint capable of being apinted to rusty surface and its preparing method |
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- 2004-05-24 CN CNB2004100185979A patent/CN1333023C/en not_active Expired - Fee Related
Cited By (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1986649B (en) * | 2005-12-19 | 2011-12-14 | 深圳市海川实业股份有限公司 | Hydrophobic water-base iron red color paste |
| CN1995249B (en) * | 2006-11-22 | 2011-01-19 | 刘天仕 | Aqueous modified polyester anti-corrosive paint for rust article |
| CN102993792A (en) * | 2012-10-15 | 2013-03-27 | 怀远县巨龙机械制造有限公司 | High-gloss metal anti-rust paint and preparation method thereof |
| CN102986867A (en) * | 2012-10-15 | 2013-03-27 | 怀远县巨龙机械制造有限公司 | Grain drying machine with circulating hot air |
| CN102993841A (en) * | 2012-10-15 | 2013-03-27 | 怀远县巨龙机械制造有限公司 | Water-based flame-retardant antirust paint |
| CN102993841B (en) * | 2012-10-15 | 2015-12-02 | 怀远县巨龙机械制造有限公司 | A kind of waterborne flame retardant anticorrosive paint |
| CN103289488B (en) * | 2012-12-06 | 2015-11-18 | 侯保荣 | A kind of Oxidative polymerization type adhesive |
| CN103289488A (en) * | 2012-12-06 | 2013-09-11 | 侯保荣 | Oxidative polymerization type adhesive |
| CN103642338A (en) * | 2013-07-15 | 2014-03-19 | 抚顺市海丰化工有限公司 | Water-based self-crosslinking acrylic acid iron oxide red antiseptic paint and preparation method therefor |
| CN103509394A (en) * | 2013-09-10 | 2014-01-15 | 马鞍山市金韩涂料制造有限公司 | Red iron oxide antirust paint and preparation method thereof |
| CN103602183A (en) * | 2013-10-22 | 2014-02-26 | 广州擎天材料科技有限公司 | Fast-curing indentation-proof water-based paint for galvanized sheet and preparation method thereof |
| CN103567887A (en) * | 2013-11-20 | 2014-02-12 | 江苏江旭铸造集团有限公司 | Casting sand |
| CN103665981A (en) * | 2013-11-29 | 2014-03-26 | 江苏太平洋液压机械制造有限公司 | Anticorrosive paint containing acrylic emulsion |
| CN103756452A (en) * | 2013-12-25 | 2014-04-30 | 苏州市邦成电子科技有限公司 | Metal antirust paint and preparation method thereof |
| CN104312368A (en) * | 2014-11-05 | 2015-01-28 | 徐强 | Water-soluble phenolic anti-rust paint and preparation method thereof |
| CN104341924A (en) * | 2014-11-14 | 2015-02-11 | 无锡伊佩克科技有限公司 | Water-based antirust and rust removing asphalt ship bottom coating and preparation method for same |
| CN106675144A (en) * | 2016-12-01 | 2017-05-17 | 河池市技术开发中心 | Antirust paint for blade of farm cultivator |
| CN106854403A (en) * | 2016-12-27 | 2017-06-16 | 成都渝三峡油漆有限公司 | A kind of water-based primer-topcoat in one type paint and preparation method thereof |
| CN110885578A (en) * | 2019-12-06 | 2020-03-17 | 山东方大杭萧钢构科技有限公司 | Water-based antirust coating applied to steel structure and preparation method thereof |
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