CN1613923A - Alcohol soluble notch board paper box preprinting ink - Google Patents
Alcohol soluble notch board paper box preprinting ink Download PDFInfo
- Publication number
- CN1613923A CN1613923A CN 200410012541 CN200410012541A CN1613923A CN 1613923 A CN1613923 A CN 1613923A CN 200410012541 CN200410012541 CN 200410012541 CN 200410012541 A CN200410012541 A CN 200410012541A CN 1613923 A CN1613923 A CN 1613923A
- Authority
- CN
- China
- Prior art keywords
- resin
- ethanol
- intaglio plate
- pigment
- ink
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 title claims abstract description 12
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 claims abstract description 24
- MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Natural products CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 claims abstract description 17
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 claims abstract description 17
- 239000000975 dye Substances 0.000 claims abstract description 10
- LLHKCFNBLRBOGN-UHFFFAOYSA-N propylene glycol methyl ether acetate Chemical compound COCC(C)OC(C)=O LLHKCFNBLRBOGN-UHFFFAOYSA-N 0.000 claims abstract description 6
- 239000000049 pigment Substances 0.000 claims description 18
- 229920005989 resin Polymers 0.000 claims description 18
- 239000011347 resin Substances 0.000 claims description 18
- 229920000742 Cotton Polymers 0.000 claims description 13
- 239000000843 powder Substances 0.000 claims description 13
- 229920001169 thermoplastic Polymers 0.000 claims description 12
- 239000004416 thermosoftening plastic Substances 0.000 claims description 12
- 238000000034 method Methods 0.000 claims description 10
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical class COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims description 8
- 229960000935 dehydrated alcohol Drugs 0.000 claims description 8
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 claims description 8
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 6
- 229920006026 co-polymeric resin Polymers 0.000 claims description 6
- 239000012046 mixed solvent Substances 0.000 claims description 5
- 238000002360 preparation method Methods 0.000 claims description 5
- 238000003756 stirring Methods 0.000 claims description 5
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 claims description 4
- 229920000178 Acrylic resin Polymers 0.000 claims description 4
- 239000004925 Acrylic resin Substances 0.000 claims description 4
- DKPFZGUDAPQIHT-UHFFFAOYSA-N Butyl acetate Natural products CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 claims description 4
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 claims description 4
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 claims description 4
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 claims description 4
- 229940043232 butyl acetate Drugs 0.000 claims description 4
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 claims description 4
- YKYONYBAUNKHLG-UHFFFAOYSA-N propyl acetate Chemical compound CCCOC(C)=O YKYONYBAUNKHLG-UHFFFAOYSA-N 0.000 claims description 4
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 claims description 4
- 229910052500 inorganic mineral Inorganic materials 0.000 claims description 3
- 239000011707 mineral Substances 0.000 claims description 3
- 239000012860 organic pigment Substances 0.000 claims description 3
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 2
- 239000005977 Ethylene Substances 0.000 claims description 2
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 2
- QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical compound C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 claims description 2
- 229920002678 cellulose Polymers 0.000 claims description 2
- 239000001913 cellulose Substances 0.000 claims description 2
- JMMWKPVZQRWMSS-UHFFFAOYSA-N isopropanol acetate Natural products CC(C)OC(C)=O JMMWKPVZQRWMSS-UHFFFAOYSA-N 0.000 claims description 2
- 229940011051 isopropyl acetate Drugs 0.000 claims description 2
- GWYFCOCPABKNJV-UHFFFAOYSA-N isovaleric acid Chemical compound CC(C)CC(O)=O GWYFCOCPABKNJV-UHFFFAOYSA-N 0.000 claims description 2
- 239000004033 plastic Substances 0.000 claims description 2
- 229920003023 plastic Polymers 0.000 claims description 2
- 229920006122 polyamide resin Polymers 0.000 claims description 2
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 2
- 229920002803 thermoplastic polyurethane Polymers 0.000 claims description 2
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 abstract 1
- 239000000020 Nitrocellulose Substances 0.000 abstract 1
- 235000019439 ethyl acetate Nutrition 0.000 abstract 1
- 229920001220 nitrocellulos Polymers 0.000 abstract 1
- 238000005516 engineering process Methods 0.000 description 8
- 238000004519 manufacturing process Methods 0.000 description 8
- 238000007639 printing Methods 0.000 description 8
- 239000002904 solvent Substances 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 3
- 230000001815 facial effect Effects 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- -1 Isopropyl ester Chemical class 0.000 description 2
- 238000005520 cutting process Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- CDXSJGDDABYYJV-UHFFFAOYSA-N acetic acid;ethanol Chemical compound CCO.CC(O)=O CDXSJGDDABYYJV-UHFFFAOYSA-N 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 238000007646 gravure printing Methods 0.000 description 1
- 239000001023 inorganic pigment Substances 0.000 description 1
- 238000007645 offset printing Methods 0.000 description 1
- 238000006748 scratching Methods 0.000 description 1
- 230000002393 scratching effect Effects 0.000 description 1
Landscapes
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
An alcohol-soluble preprinting ink on gravure carton is composed of 6-10% nitrocellulose, methacrylate ester7-13%, propylene glycol methylether acetate 4-12%, dioctyl phthalate 2-6%, the dyestuff 15-25%, acetic ester 12-23%,absolute ethyl alcohol 32-43%. The ink has good glossiness, colour saturation degree and recurrence of halftone dot. It can defend the fake and resist to 180deg.C.
Description
One, technical field:
The invention belongs to a kind of printing ink, be specifically related to a kind of intaglio plate carton Preprinted ink of pure dissolubility.
Two, background technology
The method of the colored Corrugated Box of traditional mode of production is directly to utilize the flexo technology to print on the good carton of cross cutting, and this method production efficiency is low, and the carton pattern that makes is simple, and the color dimness can only be applied in some low-grade occasions.Occur the employing lithographic plate afterwards and preprinted technology production carton, and promptly on monolithic carton facial tissue, adopted the method for offset printing to print earlier, and utilized facing machine that the facial tissue and the corrugation that print is compound then, be die-cut to various box-shapeds again.The pattern that the carton that this kind method makes is relative is abundanter, and color is also vivid, but production efficiency is still extremely low, and maximum defective is its stable between can't guaranteeing batch, even also can't guarantee together with the stability of a collection of product.
It is to adopt large-scale set type gravure printing machine reel to web feed printing that the intaglio plate carton is preprinted technology, and the rolled paper that prints directly is combined into carton board with corrugation as the carton facial tissue on corrugated paper production line, again shape by die-cutting.The special process that the technology of preprinting the intaglio plate carton adopts requires used printing ink also must satisfy the requirement of printing post-treatment except that satisfying print request, the high temperature and the scratching of the compound tense of anti-the corrugation.
Preprint the branch that water-based and solvent borne are arranged again owing to the printing ink difference that adopts in the technology at the intaglio plate carton, wherein performances such as solvent borne ink printing effect, colorimetric purity, print speed, carton water resisting property are far superior to water color ink.
Three, summary of the invention
The present invention is exactly that will to solve the carton pattern that traditional printing ink prints out abundant inadequately, and color is vivid inadequately, and production efficiency is low, the problem of the stability between can't guaranteeing batch.
Technical scheme of the present invention: a kind of ethanol-soluble type intaglio plate carton Preprinted ink, it is to be made by the component of following content proportioning: (by weight)
Soluble cotton 6～10%
Thermoplastic methacrylic methyl esters resin 7～13%
Propylene glycol methyl ether acetate 4～12%
Dioctyl phthalate (DOP) 2～6%
Pigment precast body 15～25%
Acetate ethanol 12～23%
Dehydrated alcohol 32～43%
Wherein the pigment precast body is by 35% soluble cotton, 5% dioctyl phthalate (DOP) and 60% pigment dyestuff powder are formed: the product that the following company of the optional usefulness of pigment dyestuff powder produces: the model of Switzerland vapour Bagong department production is the product of 2BXL, the model that Japan DIC company produces is the product of 5412SD, and the model that German BASF AG produces is 8730 product.A kind of preparation method of ethanol-soluble type intaglio plate carton Preprinted ink, with soluble cotton, thermoplastic methacrylic methyl esters resin and pigment precast body ethyl acetate, the predissolve of dehydrated alcohol mixed solvent, add each component of residue again and stir, the temperature in the operating process can not be above 60 ℃.Wherein thermoplastic methacrylic methyl esters resin can select for use following resin to replace: thermoplastic acrylic resin, ethylene/vinyl acetate copolymer resins, vinylchlorid/vinyl acetate between to for plastic copolymer resins, vinylchlorid/vinyl ether copolymer resins, Mierocrystalline cellulose and derivatives class resin thereof, polyamide resin, urethane resin, polyvinyl alcohol resin, modified rosin resin.Ethyl acetate can select for use n-propyl acetate or isopropyl acetate or butylacetate to replace.Dehydrated alcohol can select for use Virahol or n-propyl alcohol to replace.The pigment precast body can select for use organic pigment powder body or mineral dye powder to replace.
Ethanol-soluble type intaglio plate carton preprinted printing ink is to cooperate the intaglio plate carton to preprint technology with the best kind of performance, adopts the solvent based on alcohol will drop to minimum to environment and personnel's harm simultaneously.The present invention adopts special pigment refinement coating technology, and alcohol is primary solvent, has excellent gloss, higher colorimetric purity and good dot reproduction, and each batch preprinted the pattern color unanimity, production efficiency height, carton intensity height.Have antifalsification, the special connection expected design, and ability is high temperature more than 180 ℃, guarantees the compound and use properties of corrugation.
The effect of invention also can be illustrated by following contrast experiment, and experimental result is as follows:
Four, embodiment
Embodiment 1
Soluble cotton 7%
Thermoplastic methacrylic methyl esters resin 12%
Propylene glycol methyl ether acetate 8%
Dioctyl phthalate (DOP) 2%
Pigment precast body 15%
Ethyl acetate 15%
Dehydrated alcohol 41%
The pigment precast body is by 35% soluble cotton, and 5% dioctyl phthalate (DOP) and 60% pigment dyestuff powder are formed.The model that the pigment dyestuff powder selects for use Switzerland vapour Bagong department to produce is the product of IBXL.A kind of preparation method of ethanol-soluble type intaglio plate carton Preprinted ink, with soluble cotton, thermoplastic methacrylic methyl esters resin and pigment precast body ethyl acetate, the predissolve of dehydrated alcohol mixed solvent, add each component of residue again and stir, the temperature in the operating process is no more than 60 ℃.
Embodiment 2
Soluble cotton 10%
Thermoplastic acrylic resin 13%
Propylene glycol methyl ether acetate 4%
Dioctyl phthalate (DOP) 4%
Pigment dyestuff powder 20%
Butylacetate 14%
Virahol 35%
A kind of preparation method of ethanol-soluble type intaglio plate carton Preprinted ink, with soluble cotton, thermoplastic acrylic resin and organic pigment powder butylacetate, isopropyl alcohol mixed solvent predissolve, add each component of residue again and stir, the temperature in the operating process is no more than 60 ℃.
Embodiment 3
Soluble cotton 6%
Modified rosin resin 8%
Propylene glycol methyl ether acetate 6%
Dioctyl phthalate (DOP) 5%
Mineral dye powder 18%
Isopropyl ester 20%
N-propyl alcohol 37%
A kind of preparation method of ethanol-soluble type intaglio plate carton Preprinted ink, with soluble cotton, modified rosin resin and inorganic pigment powder isopropyl ester, the predissolve of n-propyl alcohol mixed solvent, add each component of residue again and stir, the temperature in the operating process is no more than 60 ℃.
Claims (5)
1, a kind of ethanol-soluble type intaglio plate carton Preprinted ink, it is characterized in that: it is to be made by the component of following content proportioning: (by weight)
Soluble cotton 6～10%
Thermoplastic methacrylic methyl esters resin 7～13%
Propylene glycol methyl ether acetate 4～12%
Dioctyl phthalate (DOP) 2～6%
Pigment precast body 15～25%
Ethyl acetate 12～23%
Dehydrated alcohol 32～43%
Wherein the pigment precast body is by 35% soluble cotton, and 5% dioctyl phthalate (DOP) and 60% pigment dyestuff powder are formed.
A kind of preparation method of ethanol-soluble type intaglio plate carton Preprinted ink, with soluble cotton, thermoplastic methacrylic methyl esters resin and pigment precast body ethyl acetate, the predissolve of dehydrated alcohol mixed solvent, add each component of residue again and stir, the temperature in the operating process can not be above 60 ℃.
2, a kind of ethanol-soluble type intaglio plate carton Preprinted ink as claimed in claim 1, it is characterized in that: thermoplastic methacrylic methyl esters resin can select for use following resin to replace: thermoplastic acrylic resin, ethylene/vinyl acetate copolymer resins, vinylchlorid/vinyl acetate between to for plastic copolymer resins, vinylchlorid/vinyl ether copolymer resins, Mierocrystalline cellulose and derivatives class resin thereof, polyamide resin, urethane resin, polyvinyl alcohol resin, modified rosin resin.
3, a kind of ethanol-soluble type intaglio plate carton Preprinted ink as claimed in claim 1, it is characterized in that: a kind of ethanol-soluble type intaglio plate carton Preprinted ink as claimed in claim 1 is characterized in that: ethyl acetate can select for use n-propyl acetate or isopropyl acetate or butylacetate to replace.
4, a kind of ethanol-soluble type intaglio plate carton Preprinted ink as claimed in claim 1 is characterized in that: dehydrated alcohol can select for use Virahol or n-propyl alcohol to replace.
5, a kind of ethanol-soluble type intaglio plate carton Preprinted ink as claimed in claim 1 is characterized in that: the pigment precast body can select for use organic pigment powder body or mineral dye powder to replace.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200410012541 CN1288217C (en) | 2004-09-18 | 2004-09-18 | Alcohol soluble notch board paper box preprinting ink |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200410012541 CN1288217C (en) | 2004-09-18 | 2004-09-18 | Alcohol soluble notch board paper box preprinting ink |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1613923A true CN1613923A (en) | 2005-05-11 |
| CN1288217C CN1288217C (en) | 2006-12-06 |
Family
ID=34763265
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 200410012541 Expired - Fee Related CN1288217C (en) | 2004-09-18 | 2004-09-18 | Alcohol soluble notch board paper box preprinting ink |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1288217C (en) |
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2009127127A1 (en) * | 2008-04-18 | 2009-10-22 | 中国科学院化学研究所 | Ink resin used for intaglio printing and its preparing method |
| CN103265842A (en) * | 2013-05-31 | 2013-08-28 | 苏州凹凸彩印厂 | Gravure printing ink for damp-proof glass paper and preparation method of gravure printing ink |
| CN103333547A (en) * | 2013-06-05 | 2013-10-02 | 苏州凹凸彩印厂 | Gravure ink for glass protection and preparation method thereof |
| CN103852815A (en) * | 2014-03-11 | 2014-06-11 | 深圳市科彩印务有限公司 | Variable saturation optical interference radiochromic anti-counterfeit film and preparation method thereof |
| CN103965682A (en) * | 2014-04-16 | 2014-08-06 | 大亚科技股份有限公司 | Environment-friendly water-based ink |
| CN104212234A (en) * | 2014-09-10 | 2014-12-17 | 黄山新力油墨科技有限公司 | Alcohol-soluble type flexograhic printing ink |
| CN104774493A (en) * | 2015-03-26 | 2015-07-15 | 安徽雅美油墨有限公司 | Low-cost environmental-protection ink mixed with bagasse |
| CN105131705A (en) * | 2015-08-31 | 2015-12-09 | 厦门欧化实业有限公司 | Alcohol-soluble ink and preparing method thereof |
| CN106366763A (en) * | 2016-06-17 | 2017-02-01 | 临泉县亚泰包装有限公司 | Production method of anti-counterfeiting ink used for carton printing |
| CN107793835A (en) * | 2017-11-24 | 2018-03-13 | 天长市天翔包装有限公司 | A kind of aqueous, environmental protective gravure ink and preparation method thereof |
| CN112694786A (en) * | 2020-12-28 | 2021-04-23 | 黄山新力油墨科技有限公司 | Alcohol-soluble flexographic inner printing ink suitable for extrusion compounding process and preparation method thereof |
-
2004
- 2004-09-18 CN CN 200410012541 patent/CN1288217C/en not_active Expired - Fee Related
Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2009127127A1 (en) * | 2008-04-18 | 2009-10-22 | 中国科学院化学研究所 | Ink resin used for intaglio printing and its preparing method |
| CN103265842A (en) * | 2013-05-31 | 2013-08-28 | 苏州凹凸彩印厂 | Gravure printing ink for damp-proof glass paper and preparation method of gravure printing ink |
| CN103333547A (en) * | 2013-06-05 | 2013-10-02 | 苏州凹凸彩印厂 | Gravure ink for glass protection and preparation method thereof |
| CN103852815A (en) * | 2014-03-11 | 2014-06-11 | 深圳市科彩印务有限公司 | Variable saturation optical interference radiochromic anti-counterfeit film and preparation method thereof |
| CN103965682A (en) * | 2014-04-16 | 2014-08-06 | 大亚科技股份有限公司 | Environment-friendly water-based ink |
| CN104212234A (en) * | 2014-09-10 | 2014-12-17 | 黄山新力油墨科技有限公司 | Alcohol-soluble type flexograhic printing ink |
| CN104774493A (en) * | 2015-03-26 | 2015-07-15 | 安徽雅美油墨有限公司 | Low-cost environmental-protection ink mixed with bagasse |
| CN105131705A (en) * | 2015-08-31 | 2015-12-09 | 厦门欧化实业有限公司 | Alcohol-soluble ink and preparing method thereof |
| CN106366763A (en) * | 2016-06-17 | 2017-02-01 | 临泉县亚泰包装有限公司 | Production method of anti-counterfeiting ink used for carton printing |
| CN107793835A (en) * | 2017-11-24 | 2018-03-13 | 天长市天翔包装有限公司 | A kind of aqueous, environmental protective gravure ink and preparation method thereof |
| CN112694786A (en) * | 2020-12-28 | 2021-04-23 | 黄山新力油墨科技有限公司 | Alcohol-soluble flexographic inner printing ink suitable for extrusion compounding process and preparation method thereof |
| CN112694786B (en) * | 2020-12-28 | 2022-11-01 | 黄山新力油墨科技有限公司 | Alcohol-soluble flexographic inner printing ink suitable for extrusion compounding process and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1288217C (en) | 2006-12-06 |
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Owner name: SHANXI JINGHUAKE INDUSTRY & TRADE CO., LTD. Free format text: FORMER OWNER: WANG ERJIAN Effective date: 20070119 |
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Effective date of registration: 20070119 Address after: 030006 Shanxi Jinghua industry and Trade Co., Ltd., 15, Gaoxin street, Shanxi, Taiyuan Patentee after: Jinghua Science and Industry and Trade Co., Ltd., Shanxi Address before: 030006 Shanxi Jinghua industry and Trade Co., Ltd., 15, Gaoxin street, Shanxi, Taiyuan Patentee before: Wang Erjian |
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Granted publication date: 20061206 Termination date: 20140918 |
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