CN1604959A - Delivery of benefit agents - Google Patents

Abstract

The present invention relates to a cleaning composition comprising an immiscible liquid system having at least one liquid-liquid interface with an interfacial tension greater than 5 mN/m. The less polar solvent in the system has a carbon chain length of at least 4, or is a silicone with more than 3 SiO units. The composition furthermore comprises from 0.001-20% by weight of a benefit agent such as a fluorescer, a dye transfer inhibitor, a fabric softening agent or an anti-redeposition agent. The compositions provide for an improved delivery and efficacy of the benefit agents in e.g. a fabric cleaning process.

Description

The cleaning combination that comprises the immiscible fluid system

Technical field

The present invention relates to a kind of cleaning/cleaning composition, and relate to of the improvement of this cleaning/cleaning composition of application the method or the technology of cleaning/washing.Specifically, this cleaning/cleaning composition is a transport property of being devoted to provide by the immiscible fluid with high interfacial tension the enhancement of accelerant.

Background of invention and prior art

Usually, fabric is that water and a kind of detergent surfactant system are cleaned, and this is called as and washes.Tensio-active agent is attracted to fabric and dirt on the two and therefore reduced interfacial energy separately, so just feasiblely removes dirt from fabric and becomes easy.Alternatively, also can be with the method for so-called dry-cleaning, wherein used organic solvent such as tetrachloroethylene (PCE), based on the solvent of oil or be called Stoddard's solvent, chlorofluorocarbon CFC-113 and 1,1,1-trichloroethane etc., all these solvents generally all are aided with tensio-active agent.These organic solvents can help to remove oily dirt under the condition that washing composition exists.Removing of dirt can be reached by reducing interfacial tension in a small amount, the big portion of particulate state dirt can be removed by stirring is provided.

The efficient of having known fabric cleaning composition can be enhanced by add some accelerants in prescription, and these accelerants have such as fabric softener, white dyes, dye transfer inhibitor, white dyes etc.Yet, when these accelerants and surfactant system are formulated together, can throw into question, for example, fabric softener generally is a cationic, when with prescription in the anionic detergent actives can cause unstable in the storage process when combining.Also have, when the nonionic surfactant of they and ethoxyquin in conjunction with the time also can cause the viscosity aspect problem of prescription, and this problem is more obvious when temperature is higher than 37 ℃.

US-A-3,640,881 (Hoechst Celanese Corp.) disclose and have contained a kind of wetting ability white dyes and the compsition for dry washing of coordinate detergent materials mutually with it, can be used to clean simultaneously and the brightened goods structure, particularly contain the white clothes of suitable content regenerated fiber.This technology partly is based on such discovery, the white dyes that promptly can be scattered in common organic dry-cleaning system in the water can play the effect of brightness regenerated when having a small amount of moisture content to exist, prevent that woven fabric structure from shading, fade, turn to be yellow or obtaining other undesirable character when dry-cleaning.Use detergent materials, particularly amphoteric detergent materials, promoting upward, light effect is very important.

We are early reporting and in the common pending application WO-A-01/90474 of issue on November 29 calendar year 2001, a kind of method of cleaning fabrics is disclosed, wherein used the liquid-liquid interface of at least two kinds of unmixing liquid phases under agitation, its interfacial tension is greater than 5mN/m.Wherein verified, under the condition that does not have other detergent active and accelerant to exist, this immiscible system can be reached effective cleanup action.

The organic solvent that is used to clean generally is deleterious, and can cause other problem, so for example they are the flammable potential fires that cause.Be solvent vapour loss and escape into tendency in the atmosphere in the cleaning system to the main concern of solvent cleaning in addition, particularly when they use at elevated temperatures.Solvent cleaning technology is generally used the chlorating solvent, and the minimizing of this and ozonosphere is relevant.Having carried out some attempts avoiding these problems and seeks suitable surrogate.

No matter used type of solvent, promptly no matter they are water or organic solvent, for quickening to remove soluble soil or insoluble particulate state dirt, it is very important in cleaning medium clothes being stirred.In the dry-cleaning process, when using tensio-active agent, also can use about 10% water at most together simultaneously, so that removing of water-soluble spot becomes easy with solvent systems.

The common pending application application 999/MUM/2001 that we submitted in October 12 calendar year 2001, lecture the immiscible liquid phase of a kind of usefulness and come method of cleaning fabrics, the carbon chain lengths of wherein less polar solvent is greater than 6, and/or be the siloxanes that contains more than 3 SiO units, be used for preventing the problem of toxicity, combustibility and environmental protection aspect, kept good cleanup action simultaneously fabric.

General introduction of the present invention

Have now found that, be used for cleaning/efficient of the accelerant of washing system, can be improved greater than the immiscible fluid system of 5mN/m by using its interfacial tension, and can not meet those problems when using the conventional surfactants system, the carbon chain lengths of less polar solvent is at least 4 in this immiscible fluid system, perhaps also can be with the siloxanes that contains more than 3 SiO units.

The invention summary

Like this, according to one aspect of the present invention, provided a kind of cleaning/cleaning composition, it contains:

I. an interfacial tension is greater than the immiscible liquid system of 5mN/m, and the carbon chain lengths that wherein less polar solvent has is at least 4, and/or is a kind of siloxanes that contains more than 3 SiO units; With

One or more accelerants of ii.0.001-20% (after this will being described more maturely), it can be dissolved at least a liquid phase.

The carbon chain lengths that preferably less polar solvent has is greater than 6.The concentration of the liquid of preferred especially polarity maximum is that the carbon chain lengths of the less solvent of the 10.1-90% (v/v) of unmixing system and polarity is greater than 12, more preferably greater than 16.

According to another aspect of the present invention, provided a kind of method of improved cleaning/laundering of textile fabrics, it is included under the agitation condition and implements said cleaning/washing step with the cleaning/cleaning composition that contains following component:

I. an interfacial tension is greater than the immiscible liquid system of 5mN/m, and the carbon chain lengths that wherein less polar solvent has is at least 4, and/or is a kind of siloxanes that contains more than 3 SiO units; With

One or more accelerants of ii.0.001-20%, the latter is dissolvable in water at least a liquid phase.

Detailed Description Of The Invention

Like this, provided a kind of fabric cleaning composition according to basic characteristic of the present invention, the latter is contained immiscible fluid system and one or more the said accelerant of its interfacial tension greater than 5mN/m.The transmission of accelerant is enhanced by using immiscible liquid system.Interfacial tension can be measured by the whole bag of tricks, such as stopping dripping method, sessile drop method, revolving and drip method, drop-volume method or Wilhelmy slide method etc.Be purpose of the present invention, interfacial tension can be measured with the Wilhelmy method, promptly with having the k12 type tensiometer of Kruss treater 25 ℃ of measurements.For some system, its interfacial tension may change when being subjected to shearing force, and this generally can run in washing process.Traditionally under these conditions interfacial tension is called " dynamic interface tension force " (DIFT), it can be measured by maximum bubble pressure method.

Accelerant

The optional autofluorescence whitening agent of these accelerants, tensio-active agent, hydrotropic agent, enzyme, SYNTHETIC OPTICAL WHITNER, dye transfer inhibitor, white dyes, fabric softener, anti-redeposited dose, ionogen, polymkeric substance, builder, spices, anti-creasing agent, ironing assistant etc.The concentration range that these reagent exist is composition 0.001-20% by weight.Preferably in pressing the 0.001-0.5% scope of composition weight meter, dye transfer inhibitor is in the 0.001-1% scope for the concentration of white dyes, and fabric softener resists redeposited dose in the 0.001-1% scope in the 0.001-20% scope.

Solvent

The solvent that is used for immiscible fluid system of the present invention should be done like this, promptly will make the interfacial tension of liquid unmixing system greater than 5mN/m.The solvent that polarity is bigger can be selected from water, aromatic solvent, halogenated solvent such as methyl halide, 1,1-ethylene dichloride, perchloro ethene, tetracol phenixin, 1,1,2-three chloro-1,2,2-Halothane, chlorobenzene, bromobenzene, heterogeneous ring compound etc., and the alcohols that is less than 4 carbon atoms, ester class, ketone etc.The preferred bigger solvent of polarity is a water.Also can use the mixture of solvent.

Carbon chain lengths is at least 4, is preferably greater than 6 less optional alkane (the chemical formula C that carries side chain or line style of solvent of polarity _nH _2n+2, wherein the n value is at least 4), include but not limited to hexane, heptane, octane, nonane, decane, 12 carbon alkane, n-tridecane, n-tetradecane, pentadecane etc., and their mixture.Commercially available such mixture comprises Isopar L (C ₁₁-C ₁₅Alkane-by the production of Exxon company) and DF 2000 (C ₁₁-C ₁₅Isoalkane; CAS#90622-58-5 is produced by Exxon company).They also can be selected from the alkene of band side chain and line style, include but not limited to, and octene, nonene, decene, undecylene, dodecylene etc., they can have one or more pairs of keys, also available their mixture.

Also can use ethers, comprise that the fluoro ethers (is C such as MSX 4518 HFE 7100 ₄F ₉-OCH ₃) and oxyethyl group nine fluorine butane HFE-7200 (be C ₄F ₉-OC ₂H ₅); Ester class such as dibutyl phthalate, dioctyl phthalate (DOP), C ₈-C ₂₄Saturated and/or undersaturated fatty acid methyl ester, and terpene, Zhu such as limonene, the perhaps mixture of above these compounds.Particularly preferred ester class is C ₁₀-C ₁₈Fatty acid methyl ester such as Laurate methyl, Myristicin acid methylester, methyl stearate, methyl linoleate, Linolenic acid methylester and their mixture.

Have more than the solvent of 3 SiO units optional from polydimethyl siloxane oil.Be called as line style and the cyclic siloxanes of Lx and Dx, wherein x is wherein suitable examples greater than 3.Concrete example comprises octamethylcyclotetrasiloxane (D4) (from Dow-Corning company), decamethylcyclopentaandoxane (D5), ten diformazan basic rings, six siloxanes (D6), decamethyl tetrasiloxane (L4) and ten dimethyl, five siloxanes (L5).

Stir

No matter using the solvent of which kind of type, is water or organic solvent, and for quickening to remove solvability dirt or insoluble particulate state dirt, it all is very important stirring clothes in cleaning medium.Stirring can provide by turbine, and the latter has been contained vertical distributions type and through distributions type or the combination of the two, thereby makes that immiscible fluid takes place to mix completely.Stir also can by be called as that bright shaped form turbine provides or by turbine type water screw, axial flow turbo-machine, Ping Yeshi turbine, be inverted blade turbomachine, ship propeller waits provides.This stirring action also can be used for finishing by rolling.Alternatively, stirring action also can provide by the combination of rotation and the effect of rolling.Also can use stirring action such as the using gas of other form to spray or ultrasonic wave etc.The stirring of general known other form also can be used in this area, as long as it can guarantee that immiscible liquid phase can obtain good mixing.

Character of the present invention, its purpose and benefit will become more obvious by following explanation, and this description comprises the embodiment of the relevant non-resistance system property of specified characteristic above the present invention.

Embodiment 1-10

Embodiment 1

Preparing the people with the method that describes below is the test fabric of making dirty, and the immiscible fluid as the washing system is compared the dispensing and the influence and the ortho-water solution washing agent system of accelerant.

The test preparation of fabric

Carbon black N220, Carbot (15 milligrams) are added in the solution that 5 milligram of 12 carbon sodium alkyl sulfate form in 100 ml deionized water, and in ultrasonic bath, mixture are disperseed equably by supersound process.Fritter plain weave calico (10 centimetres of 10 cm x) (by the Hindustan Spinning of Mumbai and the poplin cloth fabric of Weaving Mills manufacturing) immerses in this mixture up to estimating cotton by complete wetting (10-20 second) with hand.Then swatch is taken out from suspension, allowed its natural drip-dry and spend the night at air drying.

The mensuration of detersive power

The specific fabric swatch of making dirty of measuring as stated above preparation with Macbeth Colour-Eye 7000A type reflexometer is at the initial reflection degree of 460 nanometers, wherein is excluded by ultraviolet contribution (after this to be called as R460 ^*).Be to detect the contribution of white dyes, also measured its reflectance numerical value (after this being called as R460) 460 nanometers (ultraviolet contribution is excluded).Three cloth specimens are put in 500 milliliters of Erlenmeyer flasks, wherein be added with in 300 ml waters and the 0.75 gram table 1 testing liquid that the washing composition formulation described is formed.In room temperature with the vibrations agitator with the 120rpm rotating speed with Erlenmeyer flask contents stirred 30 minutes, so that effective mixing of liquid becomes easy.After the washing cloth specimen dry air out of the ordinary and measure the final reflectance numerical value of these cloth specimens in 460 nanometers.Final reflectance numerical value is deducted initial reflection degree value promptly obtain reflectance changing value Δ R; The mean value that the reflectance that three other cloth specimens of branch record changes is provided in the table of listing below.

Table 1

Composition by weight	％
		Linear C12 alkylbenzene sulfonate	25.9
Aliphatic alcohol ethyl oxide	2.0
		SODA ASH LIGHT 99.2	25.1
Tripoly phosphate sodium STPP (STPP) (ultrawhite)	33.1
		Silica	4.8
Xylo-Mucine (white level)	2.1
		Clorox	0.1
S-WAT	0.5
		SoKanlan CP-5 (acrylate/maleate copolymer)	1.0
Sayinase/Lipolase (proteolytic enzyme+lipase)	0.6
		Spices	0.5
Moisture content is added to 100
		Amount to	100

I. white dyes is to the influence of fabric brightness

With above-mentioned schedule of operation, evaluate the influence of adding white dyes 0.0024 grams per liter Tinopal CBS-X to detersive power to various washing systems.The data of brightness value are listed in table 1a.

Repeat the aforesaid operations program, but water+the contain detergent washing medium (embodiment 2) of 0.0024 grams per liter white dyes; Water+detergent washing medium is replaced 300 ml deionized water (embodiment 3) and water+detergent washing medium is replaced 300 ml deionized water and 0.0024 grams per liter white dyes (embodiment 4); Water+detergent washing medium is replaced 300 milliliters of mixtures of methyl esters [from P﹠amp; CE 2170, the CAS#67762-40-7 of G company (Malaysia); Be the mixture of Laurate methyl and Myristicin acid methylester] and the mixture (embodiment 5) of water to make at 20: 80; Water+detergent washing medium is replaced the 300 milliliters of methyl esters CD 2170 that make by 20: 80 ratio and the mixture+0.0024 grams per liter white dyes (embodiment 6) of water; It (from the product of Chicago,U.S Columbus Foods, mainly is C that water+detergent washing medium is replaced 300 milliliters of methyl soyate ₁₈Fatty acid methyl ester) and the mixture (embodiment 7) made by 20: 80 ratios of water; Water and detergent washing medium are replaced mixture+0.0024 grams per liter white dyes (embodiment 8) that 300 milliliters of methyl soyate and water are made by 20: 80 ratios; Water and detergent washing system are replaced 300 milliliters of siloxanes L5 (ten dimethyl, five siloxanes, from Dow corning company) and the mixture (embodiment 9) made by 20: 80 ratios of water, water and detergent system are replaced mixture+0.0024 grams per liter white dyes (implementation column 10) that 300 milliliters of siloxanes L5 (from Dow Corning company) and water are made by 20: 80 ratios.The average change value of these system reflectance numerical value is reported among the table 1a.

Table 1a

Embodiment	The washing system	Detersive power Δ R460
			?1	Detergent composition (table 1)	3.9±1.5
?2	Detergent composition+white dyes	6.2±1.4
			?3	Water	5.5±1.3
?4	Water+white dyes	7.5±1.2
			?5	Methyl esters: water is 20: 80	16.1±1.6
?6	Methyl esters: water is 20: the 80+ white dyes	21.2±0.6
			?7	Soybean oil methyl ester: water is 20: 80	18.9±1.5
?8	Soybean oil methyl ester: water is 20: the 80+ white dyes	25.6±0.4
			?9	Siloxanes L5: water is 20: 80	16.5±0.7
?10	Siloxanes L5: water is 20: the 80+ white dyes	22.2±0.6

The data that are provided in to show among the 1a show, when white dyes is dispensed into unmixing system such as methyl soyate: water is in 20: 80 the system time, and fabric brightness has tangible improvement when being dispensed in detergent formulation or the pure aquatic system than white dyes.

Embodiment 11-18

Ii. the influence that dye transfer is suppressed

The cotton fabric that three 8 * 8 centimetres of commodity black (from the vegetable dye of Kanmani textiles Selam-Tamilnadu) dyed is put in 500 milliliters of Erlenmeyer flasks, wherein added the detergent composition of describing in 300 ml waters+0.75 gram table 2 (embodiment 11).Measure initial brightness value (Lba value) with Macbeth Colour-Eye reflexometer.Stirred 30 minutes with the rotating speed of a vibrations agitator with 120rpm in room temperature then, this makes effective mixing of liquid become easy.Washing is carried out dry air to swatch out of the ordinary later on and is measured the final brightness E value (Lba) of all swatch of washing.Calculate the change value of brightness and the mean value that three cloth specimens record is provided in to show the 2a by deduct the original intensity value from final brightness value.

Table 2

Composition by weight	％
		LAS?AD	25.0
Aliphatic alcohol ethyl oxide	2.0
		SODA ASH LIGHT 99.2	24.3
STPP (ultrawhite)	32.0
		Silica	4.6
SCMC (white level)	2.0
		Clorox (AD bleaching)	0.1
S-WAT	0.5
		CP-5	1.0
White dyes	0.37
		Laundrosil PRT2-blue (photobleaching)	2.00
Orange yellow soda ash spot	1.0
		Proteolytic enzyme/lipase	0.60
Spices	0.50
		Moisture content	4.03
Amount to	100.00

Similarly, other washing system is repeated this schedule of operation, such as water+0.75 detergent washing medium and 0.03 gram dye transfer polymkeric substance Chromabond 100 (both sexes polyvinyl-pyridine betaine of producing by the ISP of Mumbai) (embodiment 12); Water+detergent washing medium is replaced 300 ml deionized water (embodiment 13); Water+detergent washing medium is replaced 300 ml deionized water and 0.03 gram dye transfer polymkeric substance Chromabond (embodiment 14); Water+detergent washing medium is replaced 300 milliliters of mixtures (embodiment 15) of being made by 20: 80 ratio by HFE 7100 (MSX 4518 of being bought by 3M) and water; Water+detergent washing medium is replaced 300 milliliters of mixture and dye transfer polymkeric substance Chromobond (0.1 grams per liter) (embodiment 16) that made by 20: 80 ratio by HFE 7100 and water; Water+detergent washing medium replaced 300 milliliters by methyl esters CE 1218 (by Malaysian P ﹠amp; The mixture C AS#68397-84-8 that forms by Laurate methyl, Myristicin acid methylester and methyl stearate that G company buys) and the mixture (embodiment 17) made by 20: 80 ratio of water; Water+detergent washing medium is replaced 300 milliliters of mixture and dye transfer polymkeric substance Chromobond (0.1 grams per liter) (embodiment 18) that made by 20: 80 ratio by methyl esters CE 1218 and water; The average inhibition of the dye transfer value of these systems is reported among the table 2a.

Table 2a

Sample	Washing system	Dye transfer suppresses (unit)
			?11	The detergent composition that table 2 is listed	?16.0±0.75
?12	Detergent composition+Chromabond	?11.8±0.25
			?13	Water	?17.7±0.1
?14	Water+Chromabond	?7.8±0.02
			?15	HFE7100: water is 20: 80	?16.4±1.3
?16	20: 80 HFE7100: water mixture+Chromabond	?7.8±0.5
			?17	20: 80 methyl esters CE 1218: the mixture of water	?21.0±1.7
?18	20: 80 methyl esters CE 1218: the mixture+Chromabond of water	?9.2±0.2

The data of listing among the table 2a show that when washing process was finished with the unmixing system, its dye transfer came to be suppressed significantly compared with the system that only contains washing composition/Chromabond.Like this, in oil/water cleaning system this polymkeric substance authorize dyestuff, such as vegetable dye with stability.

Embodiment 19-29

Iii. anti-redeposited dose influence

Repetition is generalized schedule of operation in embodiment 1, but the polymkeric substance SCMC[of water+detergent washing medium (composition of this washing composition is listed in the table 3) and the redeposited usefulness of 0.048 gram anti-soil dirt is available from the Xylo-Mucine of kalpana chemical company, gather for degree between 0.9-1.05 viscosity (2% solution is the 30-100 centipoise)] (embodiment 19); Replace water+detergent washing medium (embodiment 20) with 300 ml deionized water; Replace water+detergent washing medium (embodiment 21) with 300 ml deionized water and 0.016 grams per liter SCMC; Replace water+detergent washing medium (embodiment 22) with 300 milliliters by the HFE 7100 of 20: 80 ratio preparation and the mixture of water; Replace water+detergent washing medium (embodiment 23) with 300 milliliters by the HFE 7100 of 20: 80 ratio preparation and the mixture and the 0.048 grams per liter SCMC of water; Replace water+detergent washing medium (embodiment 24) with 300 milliliters by the methyl esters CE 1218 of 20: 80 ratio preparation and the mixture of water; Replace water+detergent washing medium (embodiment 25) with 300 milliliters by the methyl esters CE 1218 of 20: 80 ratio preparation and the mixture of water and the SCMC of 0.048 grams per liter; With 300 milliliters of methyl soyate by 20: 80 ratio preparation (mainly is C ₁₈Fatty acid methyl ester) and the mixture of water replace water+detergent washing medium (embodiment 26); Replace water+detergent washing medium (embodiment 27) with 300 milliliters by the methyl soyate of 20: 80 ratio preparation and the mixture of water and the SCMC of 0.048 grams per liter; Replace water+detergent washing medium (embodiment 28) with 300 milliliters by the siloxanes LS (ten dimethyl, five siloxanes are available from Dow Corning company) of 20: 80 ratio preparation and the mixture of water; Replace water+detergent washing medium (embodiment 29) with 300 milliliters by the siloxanes LS of 20: 80 ratio preparation and the mixture of water and the SCMC of 0.048 grams per liter.The mean change amount of the reflectance numerical value of these systems is reported among the table 3a.

Table 3

Composition by weight	％
		LAS?AD	25.5
Aliphatic alcohol ethyl oxide	2.0
		SODA ASH LIGHT 99.2	24.8
STPP (ultrawhite)	32.7
		Silica	4.7
Clorox (AD bleaching)	0.1
		S-WAT	0.5
CP-5	1.0
		White dyes	0.4
LaundrosilPRT2-indigo plant	2.0
		Orange spot	1.0
Proteolytic enzyme/lipase	0.6
		Spices	0.5
Moisture content	4.2
		Amount to	100.0

Table 3a

Embodiment	The washing system	Detersive power Δ R 460 *
			?1	Detergent composition (table 3)	?6.0±1.0
?19	Detergent composition+ARD	?6.2±1.2
			?20	Water	?～4.5±1.1
?21	Water+SCMC	?～4.5±1.0
			?22	HFE7100: water 20: 80	?20.4±0.16
?23	HFE7100: water 20: 80+SCMC	?23±0.2
			?24	Methyl esters+water	?16.1±1.6
?25	Methyl esters+water mixture of 20: 80+SCMC	?19.2±2.6
			?26	20: 80 methyl soyate+water mixture	?18.9±1.5
?27	20: 80 methyl soyate+water mixture+SCMC	?21.5±0.7
			?28	Siloxanes L5+ water	?16.5±0.7
?29	Mixture+the SCMC of siloxanes+water of 20: 80	?18.5±0.7

The data that table 3a provides show, when washing process is with oil: water be 20: 80 immiscible system and and SCMC when together implementing, the precipitating action again of dirt than the system that contains washing composition/SCMC or or even the system of independent water/SCMC be suppressed more significantly.This confirms to use in the unmixing system SCMC than more effective in detergent system.

Claims (22)

1. cleaning combination that comprises the immiscible fluid system, this system contains at least one liquid-liquid interface, its interfacial tension is greater than 5mN/m, the carbon chain lengths that the less solvent of system Semi-polarity has is at least 4, or have a siloxanes more than 3 SiO units, it is characterized by one or more accelerants that this composition contains 0.001-20%, the latter dissolves at least a liquid phase of liquid system.

2. the composition of claim 1 is characterized by the less carbon chain lengths that solvent had of polarity greater than 6.

3. the composition of claim 1 is characterized by the less carbon chain lengths that solvent had of polarity greater than 12.

4. the composition of claim 1 is characterized by the less carbon chain lengths that solvent had of polarity greater than 16.

5. the composition of claim 1-4, it is characterized by the less solvent of polarity is hydro carbons.

6. the composition of claim 5, it is characterized by the less solvent of polarity is C ₁₁-C ₁₅Hydrocarbon mixture.

7. the composition of claim 1-4, it is characterized by the less solvent of polarity is fluoroether.

8. the composition of claim 7, it is characterized by the less solvent of polarity is MSX 4518 or oxyethyl group nine fluorine butane.

9. the composition of claim 1-4, it is characterized by the less solvent of polarity is saturated or undersaturated C ₈-C ₂₄Fatty acid methyl ester.

10. the composition of claim 9, it is characterized by the less solvent of polarity is saturated or undersaturated C ₁₀-C ₁₈Fatty acid methyl ester.

11. the composition of claim 1, it is characterized by the less solvent of polarity is polydimethylsiloxane.

12. the composition of claim 11, it is characterized by this polydimethylsiloxane is ten dimethyl, five siloxanes.

13. the composition of claim 1-12 is characterized by interfacial tension greater than 10mN/m.

14. the composition of claim 13 is characterized by interfacial tension greater than 20mN/m.

15. the composition of claim 1-14, the concentration range that it is characterized by the bigger liquid of polarity are 10.1-90% (V/V).

16. the composition of claim 15, the concentration range that it is characterized by the bigger liquid of polarity has 5 fens clock times at least between 40-90 (V/V) when being used for cleaning process.

17. the composition of claim 1-16, it is characterized by the bigger liquid of polarity is water.

18. the composition of claim 1-17, it is characterized by accelerant is to be selected from white dyes, dye transfer inhibitor, fabric softener, anti-redeposited dose and their mixture.

19. the composition of claim 18, the concentration that it is characterized by white dyes is 0.001-0.5% by weight; The concentration of dye transfer inhibitor is 0.001-1% by weight; The concentration of fabric softener is 0.001-20% by weight; Anti-redeposited dose concentration is 0.001-1% by weight.

20. in the fabric cleaning process, use the composition of claim 1-19.

21. the fabric that a cleaning is made dirty or the method for soft furnishings, it is included under the agitation condition and handles these fabrics made dirty or soft furnishings with the composition of claim 1-19.

22. the method that crust is made in a cleaning dirty, it is included under the agitation condition and handles this surface with the composition of claim 1-19.