CN1597840A - Light storage luminous energy saving material made by mini-glass bead and its use - Google Patents
Light storage luminous energy saving material made by mini-glass bead and its use Download PDFInfo
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- CN1597840A CN1597840A CN 200410043783 CN200410043783A CN1597840A CN 1597840 A CN1597840 A CN 1597840A CN 200410043783 CN200410043783 CN 200410043783 CN 200410043783 A CN200410043783 A CN 200410043783A CN 1597840 A CN1597840 A CN 1597840A
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Abstract
The invention discloses a light-storing, light-emitting, energy-saving material made of glass microball, using glass microball as a substrate, and using a long-afterglow light-storing and -emitting material to activate glass microball to make it. Its raw materials in weight percent: glass microball (20-450 Mesh) 70-80% and long-afterglow light -storing and -emitting material 20-30%. As compared with alkaline-earth aluminate, alkaline-earth silicate or aluminosilicate, sulfide and thio-oxide long-afterglow light -storing and -emitting luminous materials activated by rare-earth ionic europium, etc, it has the same property and effect, and can completely replace the long-afterglow light -storing and -emitting luminous materials, and it has wide use, simple process, easily obtained raw materials, and the price reduced by above 50%.
Description
Technical field: the invention belongs to light-accumulating luminous material, specifically is a kind of light-accumulated luminous energy-saving material made from glass microballon, is used to make light-accumulated luminous energy-saving coatings or roadmarking, line, holds light, luminous, reflective nameplate sign.
Background technology: light-accumulating luminous material claims " steady persistence " again, is commonly called as " glowing powder ", belongs to a kind of of embedded photoluminescent material, is meant the short irradiation through light sources such as daylight and long ultraviolet rays, close light source after, still can continue luminous material in a very long time.In the nineties in 20th century, all the time be that zinc sulphide series glowing powder product dominates, updating and exploring through over one hundred year Technology, the substrate material of glowing powder no longer is confined to early stage single zinc sulphide system, has developed into present multiple substrate material systems such as other sulfide.Especially enter the nineties in 20th century, Xi with good luminous performance and long afterglow property is native Li child Eu, the appearance of the strontium aluminate prase glowing powder of activated by dysprosium, cove lighting and Emergency Light facility have been widely used in, aviation, field such as instrument display panel such as gentle car of navigation and industrial art coating.At present domestic existing many families produce bright material enterprise at night, the serial light-accumulated luminous pigment that more representational manufacturer such as Luming Light Source Co. Ltd., Dalian produce.Chinese patent ZL92110744.7, Chinese patent ZL96102906.4 provide a kind of " synthesis technique of noctilucent material " and a kind of " long afterglow luminous material " respectively, the raw material of its use is aluminate and rare earth ion europium, activates the alkaline earth aluminate noctilucent material with the rare earth ion europium.The common issue with of these light-accumulating luminous materials is to cost an arm and a leg, and the product of research and development circulates slowly socially, can not be as soon as possible by people's widespread use.
Number of patent application 02116213.1 provides " a kind of light accumulating, emitting and reflecting glass microballon ", is employing glass powder and afterglow material, other material, forms by 1000-1300 ℃ of fusion and refining allotment by a certain percentage.
Summary of the invention: the purpose of this invention is to provide a kind of light-accumulated luminous energy-saving material made from glass microballon and uses thereof, make substrate material with glass microballon, use a kind of steady persistence light-accumulating luminous material to activate glass microballon, the material of production has light-accumulated luminous function and the effect same with the steady persistence light-accumulating luminous material; Surface decoration spraying with the light-accumulated luminous energy-saving coatings of this material produce, handicraft model or buildings, security warning label; Reduce the price of material and product.
Should with technical scheme be achieved in that a kind of preparation method of the light-accumulated luminous energy-saving material made from glass microballon be with glass microballon as substrate material, use the steady persistence light-accumulating luminous material to activate glass microballon and make;
Its raw material is formed and content is by weight percentage:
Glass microballon (20-450Mesh) 70-80%
Steady persistence light-accumulating luminous material 20-30%
Steady persistence light-accumulating luminous material in the prescription (abbreviation long-afterglow material) specifically is meant with series such as the europkium-activated alkaline earth aluminate of rare earth ion, alkaline-earth silicate, alkaline-earth aluminosilicate, sulfide, oxysulfides and holds light, luminescent material, is commercially available finished product (series product of MingFa optical Science Co., Ltd., DaLian Road).
Select for use the glass microballon of 20-200Mesh to make light-accumulated luminous energy-saving material with long-afterglow material in the above-mentioned prescription, product is the sandblast pulvis, is used for making decorating the spraying materials, decorates sandblast as appearance; Specifically be used for the surface spraying of various paint, coating, advertising board, safety sign, handicraft model, light-accumulated luminous decoration function is played in sandblast on buildings external and internal wall surface paint, the coating.
Select for use the glass microballon of 200-450Mesh to make light-accumulated luminous energy-saving material with long-afterglow material in the above-mentioned prescription, product is a pulvis subtilis, is used to prepare light-accumulated luminous energy-saving coatings.The light-accumulated luminous energy-saving material made from glass microballon accounts for the 20-30 of weight % in producing light-accumulated luminous energy-saving coatings prescription, with other component sum be 100%.
Glass microballon in the prescription, it is a kind of glass sand that discarded glass (simple glass, silicate glass, special glass) is processed into, different with glass powder is that discarded glass is processed into the 10-450Mesh glass sand earlier, and then with glass sand in the glass microballon stove, temperature adopts fire to go up floating and air inducing technology, with glass sand moment Cheng Yuan under 1000-1300 ℃ high temperature, freely falling body sifts out the glass microballon of different model to discharge port through vibrator; Also can be according to different demands, be that the major ingredient plated film of heating is made the coated glass microballon in order to silicone oil once more with the glass microballon of above-mentioned production.The coated glass microballon is Paint Gloss, transparent, reflective, and has floating preferably and self-cleaning.Glass microballon is to be made by simple glass, silicate glass, special glass discarded glass or three kinds of blended discarded glass, has good chemical stability, and physical strength and hardness are not polluted article surface.And the glass microballon of making itself has floatability and self-cleaning preferably, can well fuse and surface bonding with other material (comprising the starting material that held light, luminescent material or preparation coating, paint, printing ink by series such as the europkium-activated alkaline earth aluminate of rare earth ion, alkaline-earth silicate, alkaline-earth aluminosilicate, sulfide, oxysulfides).Glass microballon itself has certain reflective function, and the past is made coating with it, as the reflective sign of road, graticule, reflectively makes caution, points out by light-illuminating.Because glass microballon itself can not hold light, necessary dependence activation of source just have luminescent properties, otherwise self can not be luminous after glass microballon is activated.And the rare earth ion europium or by series such as the europkium-activated alkaline earth aluminate of rare earth ion, alkaline-earth silicate, alkaline-earth aluminosilicate, sulfide, oxysulfide hold light, luminescent material can be as activation of source, the efficient glass microballon that activates makes the material of making have the light of holding, reflective, luminescent properties.Therefore, to make activation of source and glass microballon mixing preparation by serial steady persistence light-accumulating luminous materials such as the europkium-activated alkaline earth aluminate of rare earth ion, alkaline-earth silicate, alkaline-earth aluminosilicate, sulfide, oxysulfides, efficiently excite glass microballon, make the glass microballon that excites to produce luminous, the last energy level that is delivered to laser of high-quantum efficiency, reach resonance radiation, glass microballon optical pumping efficient and output luminous power are equated with the europkium-activated long-afterglow material function of rare earth ion.
Product of the present invention is a powdery, and outward appearance and glow color see the following form:
Table 1: the outward appearance of product of the present invention and glow color
| Color type | Appearance color | Glow color | Color type | Appearance color | Glow color |
| Bright place | The dark place | Bright place | The dark place | ||
| ??1 | Light gray | Royal purple | ??4 | Shallow white | Blue |
| ??2 | Light green | Bluish-green | ??5 | Red | Scarlet |
| ??3 | Pale yellow | Yellowish green | ??6 | Orange | Orange red |
The present invention sees the following form with commercial like product (long-afterglow material) price contrast at present:
Table 2: the present invention and present commercial like product price contrast table
| Product of the present invention | The commercially available prod | ||||||
| Appearance color | Glow color | Median size um | Unit price unit/kg | Appearance color | Glow color | Median size um | Unit price unit/kg |
| Light gray | Royal purple | 30-50 | ?260 | Light gray | Royal purple | 30-50 | 565 |
| Pale yellow | Yellowish green | 20-40 | ?95 | Pale yellow | Yellowish green | 20-40 | 200 |
| Light green | Bluish-green | 45-65 | ?480 | Light green | Bluish-green | 45-65 | 960 |
| Shallow white | Blue | 45-60 | ?300 | Shallow white | Blue | 45-60 | 600 |
| Red | Scarlet | 20-30 | ?370 | Red | Scarlet | 20-30 | 740 |
The present invention sees the following form with present commercial like product (long-afterglow material) performance comparison:
Table 3: the present invention and present commercial like product performance comparison table
| Appearance color | Glow color | Median size um | Fluorescent lifetime hour | Hold between the light time minute | Luminosity (mcd/m 2) | |||
| ??1min | ??5min | ??10mi ?n | ||||||
| Product of the present invention | Light gray | Royal purple | ??30-50 | ??12 | ??20 | ??17±17％ | ||
| Pale yellow | Yellowish green | ??20-40 | ??12 | ??20 | ??1000±10％ | ??280±10％ | ??160±10％ | |
| Light green | Bluish-green | ??45-60 | ??12 | ??20 | ??2780±5％ | ??870±5％ | ??470±5％ | |
| Shallow white | Blue | ??45-60 | ??12 | ??20 | ??630±5％ | ??190±5％ | ??165±5％ | |
| Red | Scarlet | ??20-30 | ??12 | ??20 | ??480±10％ | |||
| The commercially available prod | Light gray | Royal purple | ??30-50 | ??12 | ??20 | ??17±17％ | ||
| Pale yellow | Yellowish green | ??20-40 | ??12 | ??20 | ??1000±10％ | ??280±10％ | ??60±10％ | |
| Light green | Bluish-green | ??45-65 | ??12 | ??20 | ??2780±5％ | ??870±5％ | ??470±5％ | |
| Shallow white | Blue | ??45-60 | ??12 | ??20 | ??630±5％ | ??190±5％ | ??165±5％ | |
| Red | Scarlet | ??20-30 | ??12 | ??20 | ??480±10％ |
Annotate: 1, the commercially available prod is a long after glow luminous material in the table, and price, performance data are reported from the quotation and the quality supervision and test of production unit (MingFa optical Science Co., Ltd., DaLian Road).
2, the price correlation data is the commercially available price of two kinds of products.
Characteristics that the present invention has and positively effect:
1, the light-accumulated luminous energy-saving material that makes as base starting material of glass microballon, compare with the steady persistence light-accumulating luminous material, it holds light, the luminous impact of performance is identical, can replace fully all activating the serial steady persistence light-accumulating luminous material that alkaline earth aluminate, alkaline-earth silicate, alkaline-earth aluminosilicate, sulfide, oxysulfide etc. make by the rare earth ion europium.
2, the light-accumulated luminous energy-saving material that makes as base starting material of glass microballon, compare with the steady persistence light-accumulating luminous material that all makes with the europkium-activated alkaline earth aluminate of rare earth ion, alkaline-earth silicate, alkaline-earth aluminosilicate, sulfide, oxysulfide etc., it is of many uses, technology is simple, raw material is easy to get, and price reduces more than 50%.
3, the coating and the sandblast pulvis that make of the light-accumulated luminous energy-saving material that makes with glass microballon, be used for the surface spraying of various paint, coating, advertising board, safety sign, handicraft model, sandblast on buildings external and internal wall surface paint, the coating, light-accumulated luminous decoration function effect is splendid.
4, reasonable use renewable resource, for a new way is opened up in the application of glass microballon.
Embodiment:
Embodiment 1: the light-accumulated luminous energy-saving material made from glass microballon (pulvis subtilis)
Form and performance index
| Proportion of composing | Luminous | Wavelength | Particle diameter | Afterglow intensity | Afterglow intensity | Twilight sunset |
| Long-afterglow material | Glass microballon | Color | nm | ?Mesh | ??mcd/m 2??10min | ??mcd/m 2??60min | Time h |
| 30 | 70 | Yellowish green | 520 | ?325-450 | ??400 | ??60 | ＞200 |
By last table proportion of composing, take by weighing 300kg long-afterglow material (by the europkium-activated alkaline-earth aluminosilicate of ion), 700kg glass microballon, mixed at room temperature, stir, the light-accumulated luminous energy-saving material of making is a pulvis subtilis, glass microballon is 2000 yuan/ton * 0.7 ton=1400 yuan/ton, and the cost of its product is because of adopting glass microballon than all saving more than 60% with long-afterglow material.Use above-mentioned light-accumulated luminous energy-saving material (pulvis subtilis) to produce light-accumulated luminous energy-saving coatings, its prescription composition is counted with weight %:
Light-accumulated luminous energy-saving material (200-325Mesh pulvis subtilis) 25%
Compound resin 35%
Softening agent 15%
Solvent oil 25%
Softening agent in the prescription is to be used to increase viscosity, the 200# gasoline that solvent oil is to use.
Take by weighing in the light-accumulated luminous energy-saving material 250kg of 200-450Mesh, compound resin 350kg, softening agent 150kg, the solvent 250kg input stirred pot, stir at normal temperatures, the energy-saving coatings that makes, its quality index standard up to specification, cost value are 3.2 ten thousand yuan/ton.
Embodiment 2: the light-accumulated luminous energy-saving material made from glass microballon (pulvis subtilis)
Form and performance index
| Proportion of composing | Glow color | Wavelength nm | Particle diameter Mesh | Afterglow intensity mcd/m 2??10min | Afterglow intensity mcd/m 2??60min | Time of persistence h | |
| Long-afterglow material | Glass microballon | ||||||
| 20 | 80 | Yellowish green | ?520 | ???325-450 | ??400 | ??60 | ?＞200 |
By above-mentioned formula rate, take by weighing 300kg long-afterglow material (by the europkium-activated alkaline-earth aluminosilicate of ion), 700kg glass microballon.With the light-accumulated luminous energy-saving coatings of above-mentioned light-accumulated luminous energy-saving material preparation, its configuration proportion and preparation method are the same.
Embodiment 3: the light-accumulated luminous energy-saving material made from glass microballon (sandblast pulvis)
Form and performance index
| Proportion of composing | Glow color | Wavelength nm | Particle diameter Mesh | Afterglow intensity mcd/m 2??10min | Afterglow intensity mcd/m 2??60min | Time of persistence h | |
| Long-afterglow material | Glass microballon | ||||||
| ??20 | ?80 | Dark green | ?490 | ??20-200 | ??350 | ??50 | ?＞200 |
Take by weighing long-afterglow material 200kg, glass microballon (20-200Mesh) 800kg by last table proportion of composing, fully stir under the room temperature, making light-accumulated luminous energy-saving material is the sandblast pulvis.With the sandblast on various paint, coating, advertising board, safety sign, buildings external and internal wall surface paint or coating of above-mentioned light-accumulated luminous energy-saving material, decoration, light-accumulated luminous decorative effect is splendid.
Embodiment 4: the light-accumulated luminous energy-saving material made from glass microballon (sandblast pulvis)
Form and performance index
| Proportion of composing | Glow color | Wavelength nm | Particle diameter Mesh | Afterglow intensity mcd/m 2??10min | Afterglow intensity mcd/m 2??60min | Time of persistence h | |
| Long-afterglow material | Glass microballon | ||||||
| ??30 | ?70 | Dark green | ??490 | ???20-200 | ??350 | ??50 | ＞200 |
Take by weighing long-afterglow material 300kg, glass microballon (20-200Mesh) 700kg by last table proportion of composing, under the room temperature, fully stir, make light-accumulated luminous energy-saving material.Above-mentioned light-accumulated luminous energy-saving material is used on the lacquer, coating of handicraft model, handicraft model extexine sandblast to be decorated, and its light-accumulated luminous decorative effect is splendid.
Claims (8)
1, a kind of light-accumulated luminous energy-saving material made from glass microballon.
2, the light-accumulated luminous energy-saving material made from glass microballon according to claim 1 is characterized in that: raw material is formed and content is by weight percentage: glass microballon (20-450Mesh) 70-80%, long-afterglow material 20-30%.
3, a kind of light-accumulated luminous energy-saving coatings of light-accumulated luminous energy-saving material preparation made from glass microballon.
4, the energy-saving coatings for preparing according to the described light-accumulated luminous energy-saving material made from glass microballon of claim 3, it is characterized in that: in the formula rate of light-accumulated luminous energy-saving coatings, count 20-30 with the light-accumulated luminous energy-saving material that glass microballon is made, with other component be 100% with weight %.
5, a kind of sandblast pulvis of light-accumulated luminous energy-saving material preparation made from glass microballon.
6, the sandblast pulvis of light-accumulated luminous energy-saving material preparation made from glass microballon according to claim 5, it is characterized in that: its raw material is formed and content is by weight percentage: glass microballon (20-200Mesh) 70-80%, long-afterglow material 20-30%.
7, according to the sandblast pulvis of claim 5 or 6 described light-accumulated luminous energy-saving materials preparations made from glass microballon, be used for decorating sandblast on buildings external and internal wall paint, the coating surface.
8, according to the sandblast pulvis of claim 5 or 6 described light-accumulated luminous energy-saving materials preparations made from glass microballon, as decorating sandblast on handicraft model and outside surface paint, the coating.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200410043783 CN1597840A (en) | 2004-08-06 | 2004-08-06 | Light storage luminous energy saving material made by mini-glass bead and its use |
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| CN 200410043783 CN1597840A (en) | 2004-08-06 | 2004-08-06 | Light storage luminous energy saving material made by mini-glass bead and its use |
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| CN1597840A true CN1597840A (en) | 2005-03-23 |
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Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101864127A (en) * | 2010-06-29 | 2010-10-20 | 彩虹集团公司 | Long-afterglow fluorescent powder sizing agent |
| CN101948658A (en) * | 2010-09-26 | 2011-01-19 | 上海朗琦土木工程技术有限公司 | Road guardrail coating with width marking and warning function and preparation method thereof |
| CN102107178A (en) * | 2009-12-28 | 2011-06-29 | 李威汉 | Fluorescent material coating method and substrate prepared by same |
| CN105331171A (en) * | 2015-12-08 | 2016-02-17 | 安徽中益新材料科技有限公司 | Retro-reflection energy-storing luminous paint and preparing method thereof |
| CN109642150A (en) * | 2016-08-09 | 2019-04-16 | 专利应用技术公司 | Luminescent marking comprising ground glass |
| CN110577798A (en) * | 2018-06-07 | 2019-12-17 | 中环海化(厦门)船舶智能涂料有限公司 | Energy-storage luminous self-cleaning water-based paint special for highway tunnel |
| CN112160158A (en) * | 2020-09-15 | 2021-01-01 | 浙江夜光明光电科技股份有限公司 | Preparation process of printed light-reflecting and light-storing fabric prepared by same |
| CN114686030A (en) * | 2020-12-28 | 2022-07-01 | 广东三和化工科技有限公司 | Noctilucent aerosol paint and preparation method thereof |
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2004
- 2004-08-06 CN CN 200410043783 patent/CN1597840A/en active Pending
Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102107178A (en) * | 2009-12-28 | 2011-06-29 | 李威汉 | Fluorescent material coating method and substrate prepared by same |
| CN102107178B (en) * | 2009-12-28 | 2013-06-05 | 李威汉 | Fluorescent material coating method and substrate prepared by same |
| CN101864127A (en) * | 2010-06-29 | 2010-10-20 | 彩虹集团公司 | Long-afterglow fluorescent powder sizing agent |
| CN101864127B (en) * | 2010-06-29 | 2011-11-16 | 彩虹集团公司 | Long-afterglow fluorescent powder sizing agent |
| CN101948658A (en) * | 2010-09-26 | 2011-01-19 | 上海朗琦土木工程技术有限公司 | Road guardrail coating with width marking and warning function and preparation method thereof |
| CN105331171A (en) * | 2015-12-08 | 2016-02-17 | 安徽中益新材料科技有限公司 | Retro-reflection energy-storing luminous paint and preparing method thereof |
| CN109642150A (en) * | 2016-08-09 | 2019-04-16 | 专利应用技术公司 | Luminescent marking comprising ground glass |
| CN109642150B (en) * | 2016-08-09 | 2022-07-01 | 专利应用技术公司 | Luminescent sign comprising frosted glass |
| CN110577798A (en) * | 2018-06-07 | 2019-12-17 | 中环海化(厦门)船舶智能涂料有限公司 | Energy-storage luminous self-cleaning water-based paint special for highway tunnel |
| CN112160158A (en) * | 2020-09-15 | 2021-01-01 | 浙江夜光明光电科技股份有限公司 | Preparation process of printed light-reflecting and light-storing fabric prepared by same |
| CN112160158B (en) * | 2020-09-15 | 2022-10-04 | 浙江夜光明光电科技股份有限公司 | Preparation process of printed light-reflecting and light-storing fabric prepared by same |
| CN114686030A (en) * | 2020-12-28 | 2022-07-01 | 广东三和化工科技有限公司 | Noctilucent aerosol paint and preparation method thereof |
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