CN1597638A - Fertilizer synergist and its preparation method - Google Patents
Fertilizer synergist and its preparation method Download PDFInfo
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- CN1597638A CN1597638A CN 200410028199 CN200410028199A CN1597638A CN 1597638 A CN1597638 A CN 1597638A CN 200410028199 CN200410028199 CN 200410028199 CN 200410028199 A CN200410028199 A CN 200410028199A CN 1597638 A CN1597638 A CN 1597638A
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- fertilizer synergist
- zeolite
- polygorskite
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Abstract
A synergist of fertilizer is prepared from hydroscopic resin, trace elements, bentone, sodium humate, zeolite, palygorskite and glaucontie through proportional mixing. Its preparing process is also disclosed.
Description
Technical field
The present invention relates to a kind of fertilizer, relate in particular to a kind of fertilizer synergist and preparation method thereof.
Background technology
The world enters 21st century, and development of Chinese economy continues representing powerful growth momentum.National standard of living has also had significant progress, and the mode of life of well-to-do level becomes a reality in developed regions, and people pay attention to the quality and the quality of living more.In Economic development, safeguard the sustainable development idea of the eubiosis, become the target that national governments pay close attention to.Environmental protection becomes the trend of 21st century.As everyone knows, in the present circumstance, in order to improve the output of farm crop, the producers of agricultural-food use chemical fertilizer in a large number, when improving output, the destruction of ecotope are displayed more and more significantly.Because crop is not high to the utilization ratio of chemical fertilizer, cause a large amount of nitrogen losses in physical environment again, cause the unbalance of ecology.
Be increasing crop yield, more existing volume increase elements are developed out, No. 00130604.9 suggested a kind of rice growth regulator and production method thereof of patent of Chinese patent for example, it is characterized in that with the humic acids being main raw material, produce nitro-humic acid ammonium, Sodium salts humic acids, potassium humate through technologies such as nitration reaction, ammonium reaction, extraction, separation, dryings, be equipped with constant, trace element and rare earth element again, synthesize formulated these materials.This rice growth regulator has certain effect to growth, growth and the volume increase that promotes rice crop, but can't get effect to the aspects such as quality of the improvement of soil, joint fertilizer, ecological environmental protection, raising farm crop.
Summary of the invention
Low for the utilization rate of fertilizer that overcomes prior art, influence the eubiosis, can't improve soil and improve the shortcoming of crops quality and a kind of fertilizer synergist and preparation method thereof is provided.
For realizing purpose of the present invention, fertilizer synergist of the present invention, mainly formulated by a certain percentage by water-absorbing resin, trace element, wilkinite, Sodium salts humic acids, zeolite, polygorskite, glaukonine.
The quality percentage composition of described water-absorbing resin is 10-20%, trace element quality percentage composition is 0.5-2%, wilkinite quality percentage composition is 20-50%, Sodium salts humic acids quality percentage composition is 10-30%, zeolite quality percentage composition is 5-15%, polygorskite quality percentage composition is 10-30%, and glaukonine quality percentage composition is 10-30%.
Described water-absorbing resin, trace element, wilkinite are mixing in 10: 1: 25 by mass ratio, and the mass ratio of described zeolite and polygorskite is 1: 1.5.
The present invention also provides the preparation method of described fertilizer synergist, mainly may further comprise the steps:
(1) water-absorbing resin and wilkinite carry out pre-mixing by predetermined proportion;
(2) zeolite powder, polygorskite are mixed by predetermined proportion;
(3) add Sodium salts humic acids in the mixture to step (2) gained, carry out radiation treatment again; And
(4) mixture behind the mixture of step (1) and step (3) irradiation being carried out secondary mixes.
The radiation treatment of described step (3) is to use the Co60 ray as source of radiation, and the dose rate of its source of radiation is 1 * 10
-2～50 * 10
-2GY/S, the total dose of source of radiation is 0.1 * 10
2～4.0 * 10
2GY, the radiated time of source of radiation is 1 * 10
2～20 * 10
2Second.
Described step also is added with trace element in (1), the fashionable glaukonine that also adds of secondary mixing in the described step (4).
The quality percentage composition of each raw material of preparation process is: water-absorbing resin 10-20%, micro-0.5-2%, wilkinite 20-50%, Sodium salts humic acids 10-30%, zeolite 5-15%, polygorskite 10-30%, glaukonine 10-30%.
Water-absorbing resin, trace element, wilkinite are mixing in 10: 1: 25 by mass ratio in the described step (1), and the mass ratio of described step (2) zeolite and polygorskite is 1: 1.5.
Described step (3) is that the mixture with zeolite and polygorskite adds Sodium salts humic acids when being warming up to 80-200 ℃ again, and the adjusting pH value is 3-6, carries out radiation treatment.
Add pore-creating agent when adding Sodium salts humic acids in the described step (3).
The invention has the beneficial effects as follows: because fertilizer synergist of the present invention is mainly formulated by water-absorbing resin, trace element, wilkinite, Sodium salts humic acids, zeolite, polygorskite, glaukonine, add high-tech plant growth factor and promoted crop to absorb the plant growth promoter of new generation of nutritional factor, it does not contain any harmful chemical component, good improving the soil arranged, improve soil moisture content, the water conservation water saving, the effect of raising crop quality and output; The physics and the biological characteristics that utilize fertilizer synergist to have, absorbed air that can be a large amount of and the nomadic nitrogen in the soil make it slowly to discharge and reduce evaporation and loss, have improved the usefulness of using of fertilizer.Experiment shows: under common comparable conditions; under the situation of a large amount of minimizing chemical nitrogen fertilizer amounts of application; the effect that improves crops quality and maintenance or raising crop yield is still arranged; therefore the minimizing of applying quantity of chemical fertilizer; alleviated of the influence of a large amount of loss nitrogens to physical environment; in addition; because it is to the slowly-releasing usefulness of fertilizer; reduced the link that farm crop are topdressed in process of growth; alleviated peasant's labour intensity and reduced production cost, improved economic benefit, preserved the ecological environment simultaneously; improve crop anti-adversity, strengthen the disease and insect resistance of crop; lodging tolerance.
Description of drawings
Fig. 1 is the production scheme of fertilizer synergist of the present invention.
Embodiment
The present invention also provides the preparation method of described fertilizer synergist, mainly may further comprise the steps:
(1) water-absorbing resin, trace element, wilkinite carry out pre-mixing by predetermined proportion;
(2) will be crushed to 100 purpose zeolites, thread powder in slope mixes by predetermined proportion;
Add Sodium salts humic acids and the mixed liquid of pore-creating agent water when (3) mixture of step (2) gained being warming up to 80-200 ℃, the adjusting pH value is 3-6, carries out radiation treatment again;
(4) carry out secondary and mix adding the activation glaukonine in the mixture behind the mixture of step (1) and step (3) irradiation; And
(5) drying, check, metering, packing.
The quality percentage composition of each raw material is in the preparation process: water-absorbing resin 10-20%, micro-0.5-2%, wilkinite 20-50%, Sodium salts humic acids 10-30%, zeolite 5-15%, polygorskite 10-30%, glaukonine 10-30%.
Wherein water-absorbing resin, trace element, wilkinite are preferably mixing in 10: 1: 25 by mass ratio, and the mass ratio of zeolite and polygorskite is preferably 1: 1.5.
Example one
Raw materials used and the matter percentage composition of preparation fertilizer synergist is:
Water-absorbing resin 10% trace element 1%
Wilkinite 25% Sodium salts humic acids 10%
Zeolite 10% polygorskite 15%
Glaukonine 25% pore-creating agent water mixes liquid 4%
Its concrete steps are: water-absorbing resin, trace element, the wilkinite of at first getting above-mentioned mass percent carry out pre-mixing by predetermined proportion; Then, zeolite, polygorskite are crushed to 100 orders premix according to the above ratio respectively, add the mixed liquid of Sodium salts humic acids and pore-creating agent water when being warming up to 80-200 ℃, regulating P H value is 3-6, carries out the radiation treatment of doses and time again; Afterwards, with water-absorbing resin, trace element, bentonitic pre-composition, the mixture of the zeolite after the radiation treatment, polygorskite, Sodium salts humic acids etc. carries out remix with sea green stone flour; At last, drying, check, metering, packing just can obtain fertilizer synergist of the present invention.
Wherein, aforementioned trace element is: boron, potassium, sodium, molybdenum, selenium, strontium, silicon, calcium, or other rare earth element.Aforementioned pore-creating agent is selected the pore-creating agent of prior art for use.
Aforementioned radiation treatment is to use nuclear radiation tech, to improve the activity of fertilizer synergist of the present invention, it is characterized in that using the Co60 ray as source of radiation, the aforementioned mixture of irradiation.The dose rate of its source of radiation is 1 * 10
-2～50 * 10
-2GY/S, the total dose of source of radiation is 0.1 * 10
2～4.0 * 102
GY, the radiated time of source of radiation is 1 * 10
2～20 * 10
2Second.The irradiation distance of source of radiation is a 1-5 rice.
Example two
Raw materials used and the matter percentage composition of preparation fertilizer synergist is:
Water-absorbing resin 15% trace element 0.5%
Wilkinite 20% Sodium salts humic acids 15%
Zeolite 15% polygorskite 20%
Glaukonine 14.5%
Its concrete steps are identical with example one.
Example three
Raw materials used and the matter percentage composition of preparation fertilizer synergist is:
Water-absorbing resin 20% wilkinite 50%
Sodium salts humic acids 10% zeolite 5%
Polygorskite 15%
Its concrete preparation process is identical with example one.
Fertilizer synergist of the present invention presents the Powdered or particulate state of chocolate, tawny, green, chocolate, and contains elements such as boron, potassium, sodium, molybdenum, selenium, strontium, silicon, calcium, magnesium and phosphorus.Experimental results show that it has following function:
(1) soil provisions: by using, replenished required middle amount and the trace element of crop growth, improved the required bioelement content of soil fertility and crop growth significantly, thereby the yield and quality that improves farm crop is played an important role to soil.
(2) joint fertile, preserve the ecological environment: the physics and the biological characteristics that utilize fertilizer synergist to have, absorbed air that can be a large amount of and the nomadic nitrogen in the soil make it slowly to discharge and reduce evaporation and run off, and have improved the usefulness of using of fertilizer.Experiment shows: under common comparable conditions, under the situation of a large amount of minimizing chemical nitrogen fertilizer amounts of application, the effect that improves crops quality and maintenance or raising crop yield is arranged still.Just because of this, the minimizing of applying quantity of chemical fertilizer has alleviated because of nitrogen is a large amount of and has run off to the influence of physical environment.In addition,, alleviated peasant's labour intensity and reduced production cost, improved economic benefit because it to the slowly-releasing usefulness that fertilizer has, has reduced the link that farm crop are topdressed in process of growth.
(3) increase production, increase income, improve the quality of farm crop:
Reducing the chemical nitrogen fertilizer amount of application and be affixed by under the situation of fertilizer synergist, farm crop still can keep output or volume increase.Meanwhile the quality of farm crop also has significant raising.Because the price of fertilizer synergist is also well below the price of chemical fertilizer, so for the peasant, the effect that reduces cost, reduces expenditure and increases income is arranged.In addition, owing to can add the beneficial element that human bodies such as a certain proportion of molybdenum, selenium, chromium need as required in the fertilizer synergist, with the rich molybdenum of these agricultural-food of producing, rich selenium, Fu Ge.
(4) soil moisture conservation water saving, improve soil moisture content:
Fertilizer synergist of the present invention can absorb moisture content in soil after using, that reduces moisture content blends evaporation down, improves the utilization ratio of agricultural irrigation water, also can reduce irrigation frequency, thereby save water resources.Cause the soil of soil compaction phenomenon to for a long time using chemical fertilizer in a large number, after having used fertilizer synergist, can alleviate effectively and the solution phenomenon that hardens, recover soil fertility, make soil become soft, improve soil water storage self-restraint ability.
(5) improve crop anti-adversity, strengthen disease and insect resistance, the lodging tolerance of crop:
Behind the applying fertilizer synergistic agent, crop growth amount strengthens, and the thick leaf of plant bar is big, well developed root system, and the ripening stage is in advance.Experiment shows: the corn ripening stage shifts to an earlier date 5-7 days, watermelon shifts to an earlier date 10 days, tomato shifts to an earlier date 2-5 days.In actual production, huge economic is arranged.Experiment shows: under equal comparable conditions, and the crop disease-resistant insect pest, cold hardiness, alkaline-resisting power all is greatly improved, and resistance strengthens.
All harmful heavy metal projects of fertilizer synergist of the present invention detect and all are not higher than national green fertilizer specified standards.Toxicological experiment shows that fertilizer synergist meets the innoxious standard of national fertilizer industry fully.
Fertilizer synergist of the present invention has carried out field experiment tens of times, and experimental subjects relates to multiclass plant varieties such as food crop, cash crop, fruit tree, forestry tea, and experimental result all demonstrates the effect of highly significant.The synergistic agent of entrusting vegetables institute of the Chinese Academy of Agricultural Sciences and crop to bear is tested in the fertilizer efficiency effectiveness of maize planting and tomato, conclusion confirms to replace chemical fertilizer 75% when above in equivalent, and fertilizer synergist still has the effect of significant promotion crop yield and raising quality of agricultural product.
Use fertilizer synergist of the present invention, synergistic agent and other fertilizer mixings are used, effect is best.
Claims (10)
1, a kind of fertilizer synergist, mainly formulated by water-absorbing resin, trace element, wilkinite, Sodium salts humic acids, zeolite, polygorskite, glaukonine.
2, fertilizer synergist as claimed in claim 1, it is characterized in that: the quality percentage composition of described water-absorbing resin is 10-20%, trace element quality percentage composition is 0.5-2%, wilkinite quality percentage composition is 20-50%, Sodium salts humic acids quality percentage composition is 10-30%, zeolite quality percentage composition is 5-15%, and polygorskite quality percentage composition is 10-30%, and glaukonine quality percentage composition is 10-30%.
3, fertilizer synergist as claimed in claim 2 is characterized in that: described water-absorbing resin, trace element, wilkinite are mixing in 10: 1: 25 by mass ratio, and the mass ratio of described zeolite and polygorskite is 1: 1.5.
4, it is mainly formulated by water-absorbing resin, wilkinite, Sodium salts humic acids, zeolite and polygorskite for a kind of fertilizer synergist, and its preparation method mainly may further comprise the steps:
(1) water-absorbing resin and wilkinite are carried out pre-mixing by predetermined proportion;
(2) zeolite, polygorskite are mixed by predetermined proportion;
(3) in the mixture of step (2) gained, add Sodium salts humic acids, carry out radiation treatment again; And
(4) mixture behind the mixture of step (1) and step (3) irradiation being carried out secondary mixes.
5, the preparation method of fertilizer synergist as claimed in claim 4 is characterized in that: the radiation treatment of described step (3) is to use the Co60 ray as source of radiation, and the dose rate of its source of radiation is 1 * 10
-2～50 * 10
-2GY/S, the total dose of source of radiation is 0.1 * 10
2～4.0 * 10
2GY, the radiated time of source of radiation is 1 * 10
2～20 * 10
2Second.
6, the preparation method of fertilizer synergist as claimed in claim 4 is characterized in that: described step also is added with trace element in (1), the fashionable glaukonine that also adds of secondary mixing in the described step (4).
7, the preparation method of fertilizer synergist as claimed in claim 6, it is characterized in that: the quality percentage composition of each raw material of preparation process is: water-absorbing resin 10-20%, trace element 0.5-2%, wilkinite 20-50%, Sodium salts humic acids 10-30%, zeolite 5-15%, polygorskite 10-30%, glaukonine 10-30%.
8, the preparation method of fertilizer synergist as claimed in claim 7 is characterized in that: water-absorbing resin, trace element, wilkinite are mixing in 10: 1: 25 by mass ratio in the described step (1), and the mass ratio of described step (2) zeolite and polygorskite is 1: 1.5.
9, the preparation method of fertilizer synergist as claimed in claim 1 is characterized in that: described step (3) is that the mixture with zeolite and polygorskite adds Sodium salts humic acids when being warming up to 80-200 ℃, and the adjusting pH value is 3-6, carries out radiation treatment again.
10, the preparation method of fertilizer synergist as claimed in claim 9 is characterized in that: add Sodium salts humic acids in the described step (3) and add pore-creating agent simultaneously.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2004100281995A CN100334042C (en) | 2004-07-23 | 2004-07-23 | Fertilizer synergist and its preparation method |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2004100281995A CN100334042C (en) | 2004-07-23 | 2004-07-23 | Fertilizer synergist and its preparation method |
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|---|---|
| CN1597638A true CN1597638A (en) | 2005-03-23 |
| CN100334042C CN100334042C (en) | 2007-08-29 |
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| CN101353285B (en) * | 2008-08-29 | 2010-11-17 | 薛立成 | Natural multifunctional mineral compound fertilizer |
| CN102060606A (en) * | 2010-11-21 | 2011-05-18 | 甘肃昊洲肥业有限公司 | Intelligent environment-friendly fertilizer synergist |
| CN102010063B (en) * | 2009-09-05 | 2012-08-01 | 钟诗群 | Water quality improver or feed and fertilizer synergist and production method thereof |
| CN102850131A (en) * | 2012-09-24 | 2013-01-02 | 株洲市农业科学研究所、株洲市三生肥业有限公司 | Multifunctional slow-release/controlled-release fertilizer synergist and production technique of synergist |
| CN103030458A (en) * | 2012-09-18 | 2013-04-10 | 吴江 | Fertilizer synergist and preparation method thereof |
| CN103204726A (en) * | 2012-01-11 | 2013-07-17 | 党剑 | Nitrogen fixation urea |
| CN103204727A (en) * | 2012-01-11 | 2013-07-17 | 党剑 | Nitrogen fixation and water retention agent |
| CN103351216A (en) * | 2013-06-08 | 2013-10-16 | 中国矿业大学(北京) | Nitrogen fertilizer high-molecular composite synergist, and preparation method thereof |
| CN105075637A (en) * | 2015-09-07 | 2015-11-25 | 中国科学院微生物研究所 | Potato cultivation method |
| CN110016350A (en) * | 2019-04-29 | 2019-07-16 | 深圳润康生态环境股份有限公司 | Arable land heavy-metal contaminated soil preparation for repairing and preparation method thereof |
| CN110877995A (en) * | 2018-08-23 | 2020-03-13 | 广西和齐成农业股份有限公司 | Organic-inorganic fruit-strengthening fertilizer prepared from molasses humic acid and preparation method thereof |
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| CN1049203C (en) * | 1994-05-24 | 2000-02-09 | 四川联合大学 | Solid composite containing sulfuric acid and its application |
| CN1311287A (en) * | 2001-02-28 | 2001-09-05 | 陈胜利 | Long acting multifunction soil additive |
| CN1386725A (en) * | 2001-05-17 | 2002-12-25 | 么向和 | Multifunctional additive of fertilizer |
-
2004
- 2004-07-23 CN CNB2004100281995A patent/CN100334042C/en not_active Expired - Fee Related
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101353285B (en) * | 2008-08-29 | 2010-11-17 | 薛立成 | Natural multifunctional mineral compound fertilizer |
| CN102010063B (en) * | 2009-09-05 | 2012-08-01 | 钟诗群 | Water quality improver or feed and fertilizer synergist and production method thereof |
| CN102060606A (en) * | 2010-11-21 | 2011-05-18 | 甘肃昊洲肥业有限公司 | Intelligent environment-friendly fertilizer synergist |
| CN103204726A (en) * | 2012-01-11 | 2013-07-17 | 党剑 | Nitrogen fixation urea |
| CN103204727A (en) * | 2012-01-11 | 2013-07-17 | 党剑 | Nitrogen fixation and water retention agent |
| CN103030458A (en) * | 2012-09-18 | 2013-04-10 | 吴江 | Fertilizer synergist and preparation method thereof |
| CN102850131A (en) * | 2012-09-24 | 2013-01-02 | 株洲市农业科学研究所、株洲市三生肥业有限公司 | Multifunctional slow-release/controlled-release fertilizer synergist and production technique of synergist |
| CN103351216A (en) * | 2013-06-08 | 2013-10-16 | 中国矿业大学(北京) | Nitrogen fertilizer high-molecular composite synergist, and preparation method thereof |
| CN105075637A (en) * | 2015-09-07 | 2015-11-25 | 中国科学院微生物研究所 | Potato cultivation method |
| CN110877995A (en) * | 2018-08-23 | 2020-03-13 | 广西和齐成农业股份有限公司 | Organic-inorganic fruit-strengthening fertilizer prepared from molasses humic acid and preparation method thereof |
| CN110016350A (en) * | 2019-04-29 | 2019-07-16 | 深圳润康生态环境股份有限公司 | Arable land heavy-metal contaminated soil preparation for repairing and preparation method thereof |
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| CN100334042C (en) | 2007-08-29 |
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Address after: Guangdong city of Shenzhen province Futian District Xinghe Century Towers A901 room zip code: 518026 Co-patentee after: Wu Lanna Patentee after: Wujiang Address before: 53 Lotus Village North Village, Shenzhen, Guangdong province 508,: 518036 Co-patentee before: Wu Lanna Patentee before: Wujiang |
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