CN1597634A - Preparation method of chitin oligosaccharide zinc borone magnesium fertilizer - Google Patents
Preparation method of chitin oligosaccharide zinc borone magnesium fertilizer Download PDFInfo
- Publication number
- CN1597634A CN1597634A CN200410035619.2A CN200410035619A CN1597634A CN 1597634 A CN1597634 A CN 1597634A CN 200410035619 A CN200410035619 A CN 200410035619A CN 1597634 A CN1597634 A CN 1597634A
- Authority
- CN
- China
- Prior art keywords
- acid
- chitin
- zinc
- preparation
- chitosan
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229920002101 Chitin Polymers 0.000 title claims abstract description 34
- 239000003337 fertilizer Substances 0.000 title claims abstract description 14
- 229920001542 oligosaccharide Polymers 0.000 title claims description 16
- 150000002482 oligosaccharides Chemical class 0.000 title claims description 16
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 title claims description 11
- 239000011701 zinc Substances 0.000 title claims description 11
- 229910052725 zinc Inorganic materials 0.000 title claims description 11
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 title claims description 9
- 229910052749 magnesium Inorganic materials 0.000 title claims description 9
- 239000011777 magnesium Substances 0.000 title claims description 9
- 238000002360 preparation method Methods 0.000 title claims description 8
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims abstract description 13
- 108090000790 Enzymes Proteins 0.000 claims abstract description 7
- 102000004190 Enzymes Human genes 0.000 claims abstract description 7
- 239000002253 acid Substances 0.000 claims abstract description 7
- 150000001413 amino acids Chemical class 0.000 claims abstract description 7
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 claims abstract description 6
- 239000004327 boric acid Substances 0.000 claims abstract description 6
- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 claims abstract description 5
- 229960001763 zinc sulfate Drugs 0.000 claims abstract description 5
- 229910000368 zinc sulfate Inorganic materials 0.000 claims abstract description 5
- 229920001661 Chitosan Polymers 0.000 claims description 9
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 6
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 4
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 4
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 4
- YIXJRHPUWRPCBB-UHFFFAOYSA-N magnesium nitrate Chemical compound [Mg+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O YIXJRHPUWRPCBB-UHFFFAOYSA-N 0.000 claims description 4
- 229960000583 acetic acid Drugs 0.000 claims description 3
- 239000012362 glacial acetic acid Substances 0.000 claims description 3
- RPAJSBKBKSSMLJ-DFWYDOINSA-N (2s)-2-aminopentanedioic acid;hydrochloride Chemical class Cl.OC(=O)[C@@H](N)CCC(O)=O RPAJSBKBKSSMLJ-DFWYDOINSA-N 0.000 claims description 2
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 2
- 239000003905 agrochemical Substances 0.000 abstract description 2
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 abstract 2
- 238000001914 filtration Methods 0.000 abstract 1
- 238000010438 heat treatment Methods 0.000 abstract 1
- 229910052943 magnesium sulfate Inorganic materials 0.000 abstract 1
- 235000019341 magnesium sulphate Nutrition 0.000 abstract 1
- 235000015097 nutrients Nutrition 0.000 abstract 1
- 201000010099 disease Diseases 0.000 description 7
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 7
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 5
- 229910052796 boron Inorganic materials 0.000 description 5
- 230000008635 plant growth Effects 0.000 description 5
- 230000000694 effects Effects 0.000 description 3
- 230000012010 growth Effects 0.000 description 3
- 244000052616 bacterial pathogen Species 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- 241000894006 Bacteria Species 0.000 description 1
- 102000012286 Chitinases Human genes 0.000 description 1
- 108010022172 Chitinases Proteins 0.000 description 1
- OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 description 1
- 102000012214 Immunoproteins Human genes 0.000 description 1
- 108010036650 Immunoproteins Proteins 0.000 description 1
- 208000008167 Magnesium Deficiency Diseases 0.000 description 1
- JLVVSXFLKOJNIY-UHFFFAOYSA-N Magnesium ion Chemical compound [Mg+2] JLVVSXFLKOJNIY-UHFFFAOYSA-N 0.000 description 1
- 108700001094 Plant Genes Proteins 0.000 description 1
- ZGBSOTLWHZQNLH-UHFFFAOYSA-N [Mg].S(O)(O)(=O)=O Chemical compound [Mg].S(O)(O)(=O)=O ZGBSOTLWHZQNLH-UHFFFAOYSA-N 0.000 description 1
- PGTXKIZLOWULDJ-UHFFFAOYSA-N [Mg].[Zn] Chemical compound [Mg].[Zn] PGTXKIZLOWULDJ-UHFFFAOYSA-N 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 229920000615 alginic acid Polymers 0.000 description 1
- 235000010443 alginic acid Nutrition 0.000 description 1
- 230000000845 anti-microbial effect Effects 0.000 description 1
- 230000000259 anti-tumor effect Effects 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 230000008952 bacterial invasion Effects 0.000 description 1
- ZAIPMKNFIOOWCQ-UEKVPHQBSA-N cephalexin Chemical compound C1([C@@H](N)C(=O)N[C@H]2[C@@H]3N(C2=O)C(=C(CS3)C)C(O)=O)=CC=CC=C1 ZAIPMKNFIOOWCQ-UEKVPHQBSA-N 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000007850 degeneration Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 230000005089 fruit drop Effects 0.000 description 1
- 230000002068 genetic effect Effects 0.000 description 1
- 150000002337 glycosamines Chemical class 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 208000006278 hypochromic anemia Diseases 0.000 description 1
- 230000006698 induction Effects 0.000 description 1
- 230000001939 inductive effect Effects 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 230000009545 invasion Effects 0.000 description 1
- 235000004764 magnesium deficiency Nutrition 0.000 description 1
- 229910001425 magnesium ion Inorganic materials 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 230000000050 nutritive effect Effects 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000000575 pesticide Substances 0.000 description 1
- 230000037039 plant physiology Effects 0.000 description 1
- 150000003384 small molecules Chemical class 0.000 description 1
- 230000004936 stimulating effect Effects 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- WQSRXNAKUYIVET-UHFFFAOYSA-N sulfuric acid;zinc Chemical compound [Zn].OS(O)(=O)=O WQSRXNAKUYIVET-UHFFFAOYSA-N 0.000 description 1
- 239000011573 trace mineral Substances 0.000 description 1
- 235000013619 trace mineral Nutrition 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- 210000003462 vein Anatomy 0.000 description 1
Landscapes
- Fertilizers (AREA)
Abstract
A fertilizer rich in nutrients with the functions of both fertilizer and agricultural chemical is prepared through dissolving chitin in acid, heating, adding H2O2 or enzyme, degradating, filtering, and adding amino acid, zinc sulfate, magnesium sulfate and boric acid.
Description
Technical field
The present invention relates to a kind of preparation method of chitin oligosaccharide zinc boric magnesium fertilizer.
Background technology
Chitin oligosaccharide is the aminosugar of the class low polymerization degree that produced after hydrolysis by chitin and chitosan, and the scope of the polymerization degree is generally at 2-17.Because the solvability of chitin is poor, has so also just limited its application.Yet chitin oligosaccharide is a kind of small molecules, water-soluble, can be absorbed by human body, animal, plant body, it not only has some similar quality of chitin and chitosan, and some physiologically actives and functional property are more remarkable, as the defence capability of the anti-microbial effect of chitin oligosaccharide, antitumor, opposing bacterial invasion, regulate plant physiology, promote plant-growth, disease-resistant change isoreactivity.Inhibiting rates such as the common bacteriosis of plant, mildew are reached more than 90%, chitin oligosaccharide can be used as the inductor that activates the chitin enzyme in plant, make the induced reaction of chitinase rapid, make acting on of oligose reach maximum in 12-24 hour, the inducing plant alexin, thereby make plant play the egodefense effect, suppress growth of pathogenic bacteria; Can also regulate closing of plant gene in addition, promote the activation of vegetable cell, the stimulating plant growth with open.Chitin oligosaccharide also is the non-specific signal of plant identification pathogenic bacteria invasion, many plants are shown intensive immune induction activity, can excite the genetic expression of plant, produce disease-resistant chitin enzyme, chitoanase, plant protecting chemical and immunoprotein, these materials can suppress and the growth of kill bacteria, reach disease-resistant purpose.But not seeing so far has with the report of chitin oligosaccharide as the fertilizer of substrate.
Summary of the invention
The purpose of this invention is to provide a kind of preparation method of chitin oligosaccharide zinc boric magnesium fertilizer, it can satisfy the demand of prior art.
A kind of preparation method of chitin oligosaccharide zinc boric magnesium fertilizer is characterized in that chitin or chitosan are dissolved temperature control with acid, the molecular chain that adds hydrogen peroxide or enzyme brisement chitin or chitin, degraded 0.5-12 hour, and filtered, add amino acid, zinc sulfate, sal epsom, boric acid.
Fertilizer of the present invention had both contained activated chitin oligosaccharide, zinc, magnesium, boron trace element that some amount is arranged again, zinc, boron, magnesium ion are again the indispensable nutritive elements of plant-growth, zinc can have production-increasing function to plant, magnesium deficiency, zinc just suppress plant-growth, chlorosis between vein, and cause the various plants disease, and magnesium is chlorophyllous important component, can improve the resistance against diseases of plant; Boron deficiency can make the plant fruit drop serious.The complex compound that chitin oligosaccharide and zinc-magnesium, boron plasma generate, make the effect such as disease-resistant, degeneration-resistant, promotes growth of chitin oligosaccharide more remarkable, not only had the characteristics of fertilizer but also the performance of agricultural chemicals had been arranged, reach combination of pesticide and fertilizer, can improve the resistance against diseases of plant, also having improved the quality of crop, promoted plant-growth, is a kind of rare environmental type fertilizer.
Embodiment
With 10 kilograms of chitins, with 200 kilogram of 2% (concentration expressed in percentage by weight, glacial acetic acid aqueous solution dissolving down together), stir, temperature is controlled at 85 ℃, adds 4 kilogram 30% hydrogen peroxide oxidation, degraded 5 hours, filter, add 6 kilograms of amino acid, 5 kilo sulfuric acid zinc, 4 kilo sulfuric acid magnesium, 8 kilograms of boric acid, get finished product.
Chitin in the present embodiment can be used chitosan instead; Glacial acetic acid can be used hydrochloric acid, sulfuric acid or phosphoric acid instead; Hydrogen peroxide can be used algin catenase instead; The part by weight of described chitin or chitosan and acid and hydrogen peroxide or enzyme is respectively 10: 1-8: 0.1-8.The weight ratio scope of chitin or chitosan and amino acid, zinc sulfate, magnesium nitrate and boric acid respectively is 10: 1-10: 1-10: 1-10: 1-15.
Chitin oligosaccharide content: 0.001-30% in the fertilizer of the present invention (concentration expressed in percentage by weight, down together); The content of amino nitrogen is: 0.01-20%; The total amount of zinc, boron, magnesium is: 0.001-20%; Amino acid: 0.1-60%.
Claims (3)
- The preparation method of 1 one kinds of chitin oligosaccharide zinc boric magnesium fertilizers is characterized in that chitin or chitosan are dissolved temperature control with acid, the molecular chain that adds hydrogen peroxide or enzyme brisement chitin or chitin, degraded 0.5-12 hour, and filtered, add amino acid, zinc sulfate, sal epsom, boric acid.
- 2 preparation methods as claimed in claim 1 is characterized in that described acid is glacial acetic acid, hydrochloric acid, sulfuric acid, phosphoric acid or mixing acid, and the part by weight of described chitin or chitosan and acid and hydrogen peroxide or enzyme is respectively 10: 1-8: 1-8.
- 3 preparation methods as claimed in claim 1 is characterized in that the weight ratio scope of described chitin or chitosan and amino acid, zinc sulfate, magnesium nitrate and boric acid respectively is 10: 1-10: 1-10: 1-10: 1-15.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN200410035619.2A CN1234271C (en) | 2004-08-27 | 2004-08-27 | Preparation method of chitin oligosaccharide zinc borone magnesium fertilizer |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN200410035619.2A CN1234271C (en) | 2004-08-27 | 2004-08-27 | Preparation method of chitin oligosaccharide zinc borone magnesium fertilizer |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1597634A true CN1597634A (en) | 2005-03-23 |
| CN1234271C CN1234271C (en) | 2006-01-04 |
Family
ID=34664279
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN200410035619.2A Withdrawn - After Issue CN1234271C (en) | 2004-08-27 | 2004-08-27 | Preparation method of chitin oligosaccharide zinc borone magnesium fertilizer |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1234271C (en) |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101381258A (en) * | 2008-10-24 | 2009-03-11 | 北京易众恒科技有限公司 | Environment-friendly type foliage fertilizer |
| CN101455208A (en) * | 2008-10-24 | 2009-06-17 | 北京易众恒科技有限公司 | Seed treatment agent and preparation technique thereof |
| CN101250075B (en) * | 2008-03-18 | 2010-06-09 | 吉林农业大学 | Ginseng foliar fertilizer |
| CN101974038A (en) * | 2010-09-28 | 2011-02-16 | 农业部规划设计研究院 | Oligomeric amino sugar acid and preparation method thereof |
| CN102144637A (en) * | 2010-12-23 | 2011-08-10 | 海南正业中农高科股份有限公司 | Chitosan oligosaccharide composite with cold-resistant function and application of composite |
| CN101993257B (en) * | 2009-08-27 | 2013-05-15 | 林大昌 | Method for preparation of high-activity compound organic fertilizer by waste acid liquid of D-glucosamine hydrochloride |
| CN104230579A (en) * | 2014-10-15 | 2014-12-24 | 青岛力力惠生物科技有限公司 | Preparation method for chitin-rich compound fertilizer |
| CN104692932A (en) * | 2015-02-12 | 2015-06-10 | 海南正业中农高科股份有限公司 | Synergistic composition containing chitosan oligosaccharide and amino acid |
| CN106135263A (en) * | 2016-05-14 | 2016-11-23 | 海南正业中农高科股份有限公司 | Compositions containing organic zinc and application thereof |
-
2004
- 2004-08-27 CN CN200410035619.2A patent/CN1234271C/en not_active Withdrawn - After Issue
Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101250075B (en) * | 2008-03-18 | 2010-06-09 | 吉林农业大学 | Ginseng foliar fertilizer |
| CN101455208A (en) * | 2008-10-24 | 2009-06-17 | 北京易众恒科技有限公司 | Seed treatment agent and preparation technique thereof |
| CN101381258A (en) * | 2008-10-24 | 2009-03-11 | 北京易众恒科技有限公司 | Environment-friendly type foliage fertilizer |
| CN101993257B (en) * | 2009-08-27 | 2013-05-15 | 林大昌 | Method for preparation of high-activity compound organic fertilizer by waste acid liquid of D-glucosamine hydrochloride |
| CN101974038A (en) * | 2010-09-28 | 2011-02-16 | 农业部规划设计研究院 | Oligomeric amino sugar acid and preparation method thereof |
| CN101974038B (en) * | 2010-09-28 | 2013-09-11 | 农业部规划设计研究院 | Oligomeric amino sugar acid and preparation method thereof |
| CN102144637B (en) * | 2010-12-23 | 2012-07-04 | 海南正业中农高科股份有限公司 | Chitosan oligosaccharide composite with cold-resistant function and application of composite |
| CN102144637A (en) * | 2010-12-23 | 2011-08-10 | 海南正业中农高科股份有限公司 | Chitosan oligosaccharide composite with cold-resistant function and application of composite |
| CN104230579A (en) * | 2014-10-15 | 2014-12-24 | 青岛力力惠生物科技有限公司 | Preparation method for chitin-rich compound fertilizer |
| CN104230579B (en) * | 2014-10-15 | 2016-08-24 | 青岛力力惠生物科技股份有限公司 | Preparation method of chitin-rich compound fertilizer |
| CN104692932A (en) * | 2015-02-12 | 2015-06-10 | 海南正业中农高科股份有限公司 | Synergistic composition containing chitosan oligosaccharide and amino acid |
| CN106135263A (en) * | 2016-05-14 | 2016-11-23 | 海南正业中农高科股份有限公司 | Compositions containing organic zinc and application thereof |
| CN106135263B (en) * | 2016-05-14 | 2019-07-30 | 海南正业中农高科股份有限公司 | Composition and application thereof containing organic zinc |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1234271C (en) | 2006-01-04 |
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Address after: 266003 Shandong province Qingdao City fish Road No. 5 Patentee after: QINGDAO SEAWIN BIOTECH GROUP Co.,Ltd. Address before: 266071, room 508, Science Park, Qingdao National University, 23 East Hongkong Road, Laoshan District, Shandong, Qingdao Patentee before: QINGDAO SEAWIN BIOTECH GROUP Co.,Ltd. |
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Denomination of invention: Preparation of chitooligosaccharide zinc boron magnesium fertilizer Effective date of registration: 20210622 Granted publication date: 20060104 Pledgee: Qingdao high tech Industrial Development Zone sub branch of China Construction Bank Co.,Ltd. Pledgor: QINGDAO SEAWIN BIOTECH GROUP Co.,Ltd. Registration number: Y2021370010037 |
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