CN1597634A - Preparation method of chitin oligosaccharide zinc borone magnesium fertilizer - Google Patents
Preparation method of chitin oligosaccharide zinc borone magnesium fertilizer Download PDFInfo
- Publication number
- CN1597634A CN1597634A CN200410035619.2A CN200410035619A CN1597634A CN 1597634 A CN1597634 A CN 1597634A CN 200410035619 A CN200410035619 A CN 200410035619A CN 1597634 A CN1597634 A CN 1597634A
- Authority
- CN
- China
- Prior art keywords
- acid
- chitin
- zinc
- preparation
- chitosan
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229920002101 Chitin Polymers 0.000 title claims abstract description 34
- 239000003337 fertilizer Substances 0.000 title claims abstract description 14
- 229920001542 oligosaccharide Polymers 0.000 title claims description 16
- 150000002482 oligosaccharides Chemical class 0.000 title claims description 16
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 title claims description 11
- 239000011701 zinc Substances 0.000 title claims description 11
- 229910052725 zinc Inorganic materials 0.000 title claims description 11
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 title claims description 9
- 229910052749 magnesium Inorganic materials 0.000 title claims description 9
- 239000011777 magnesium Substances 0.000 title claims description 9
- 238000002360 preparation method Methods 0.000 title claims description 8
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims abstract description 13
- 108090000790 Enzymes Proteins 0.000 claims abstract description 7
- 102000004190 Enzymes Human genes 0.000 claims abstract description 7
- 239000002253 acid Substances 0.000 claims abstract description 7
- 150000001413 amino acids Chemical class 0.000 claims abstract description 7
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 claims abstract description 6
- 239000004327 boric acid Substances 0.000 claims abstract description 6
- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 claims abstract description 5
- 229960001763 zinc sulfate Drugs 0.000 claims abstract description 5
- 229910000368 zinc sulfate Inorganic materials 0.000 claims abstract description 5
- 229920001661 Chitosan Polymers 0.000 claims description 9
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 6
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 4
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 4
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 4
- YIXJRHPUWRPCBB-UHFFFAOYSA-N magnesium nitrate Chemical compound [Mg+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O YIXJRHPUWRPCBB-UHFFFAOYSA-N 0.000 claims description 4
- 229960000583 acetic acid Drugs 0.000 claims description 3
- 239000012362 glacial acetic acid Substances 0.000 claims description 3
- RPAJSBKBKSSMLJ-DFWYDOINSA-N (2s)-2-aminopentanedioic acid;hydrochloride Chemical class Cl.OC(=O)[C@@H](N)CCC(O)=O RPAJSBKBKSSMLJ-DFWYDOINSA-N 0.000 claims description 2
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 2
- 239000003905 agrochemical Substances 0.000 abstract description 2
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 abstract 2
- 238000001914 filtration Methods 0.000 abstract 1
- 238000010438 heat treatment Methods 0.000 abstract 1
- 229910052943 magnesium sulfate Inorganic materials 0.000 abstract 1
- 235000019341 magnesium sulphate Nutrition 0.000 abstract 1
- 235000015097 nutrients Nutrition 0.000 abstract 1
- 201000010099 disease Diseases 0.000 description 7
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 7
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 5
- 229910052796 boron Inorganic materials 0.000 description 5
- 230000008635 plant growth Effects 0.000 description 5
- 230000000694 effects Effects 0.000 description 3
- 230000012010 growth Effects 0.000 description 3
- 244000052616 bacterial pathogen Species 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- 241000894006 Bacteria Species 0.000 description 1
- 102000012286 Chitinases Human genes 0.000 description 1
- 108010022172 Chitinases Proteins 0.000 description 1
- OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 description 1
- 102000012214 Immunoproteins Human genes 0.000 description 1
- 108010036650 Immunoproteins Proteins 0.000 description 1
- 208000008167 Magnesium Deficiency Diseases 0.000 description 1
- JLVVSXFLKOJNIY-UHFFFAOYSA-N Magnesium ion Chemical compound [Mg+2] JLVVSXFLKOJNIY-UHFFFAOYSA-N 0.000 description 1
- 108700001094 Plant Genes Proteins 0.000 description 1
- ZGBSOTLWHZQNLH-UHFFFAOYSA-N [Mg].S(O)(O)(=O)=O Chemical compound [Mg].S(O)(O)(=O)=O ZGBSOTLWHZQNLH-UHFFFAOYSA-N 0.000 description 1
- PGTXKIZLOWULDJ-UHFFFAOYSA-N [Mg].[Zn] Chemical compound [Mg].[Zn] PGTXKIZLOWULDJ-UHFFFAOYSA-N 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 229920000615 alginic acid Polymers 0.000 description 1
- 235000010443 alginic acid Nutrition 0.000 description 1
- 230000000845 anti-microbial effect Effects 0.000 description 1
- 230000000259 anti-tumor effect Effects 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 230000008952 bacterial invasion Effects 0.000 description 1
- ZAIPMKNFIOOWCQ-UEKVPHQBSA-N cephalexin Chemical compound C1([C@@H](N)C(=O)N[C@H]2[C@@H]3N(C2=O)C(=C(CS3)C)C(O)=O)=CC=CC=C1 ZAIPMKNFIOOWCQ-UEKVPHQBSA-N 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000007850 degeneration Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 230000005089 fruit drop Effects 0.000 description 1
- 230000002068 genetic effect Effects 0.000 description 1
- 150000002337 glycosamines Chemical class 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 208000006278 hypochromic anemia Diseases 0.000 description 1
- 230000006698 induction Effects 0.000 description 1
- 230000001939 inductive effect Effects 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 230000009545 invasion Effects 0.000 description 1
- 235000004764 magnesium deficiency Nutrition 0.000 description 1
- 229910001425 magnesium ion Inorganic materials 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 230000000050 nutritive effect Effects 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000000575 pesticide Substances 0.000 description 1
- 230000037039 plant physiology Effects 0.000 description 1
- 150000003384 small molecules Chemical class 0.000 description 1
- 230000004936 stimulating effect Effects 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- WQSRXNAKUYIVET-UHFFFAOYSA-N sulfuric acid;zinc Chemical compound [Zn].OS(O)(=O)=O WQSRXNAKUYIVET-UHFFFAOYSA-N 0.000 description 1
- 239000011573 trace mineral Substances 0.000 description 1
- 235000013619 trace mineral Nutrition 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- 210000003462 vein Anatomy 0.000 description 1
Landscapes
- Fertilizers (AREA)
Abstract
Description
Claims (3)
- The preparation method of 1 one kinds of chitin oligosaccharide zinc boric magnesium fertilizers is characterized in that chitin or chitosan are dissolved temperature control with acid, the molecular chain that adds hydrogen peroxide or enzyme brisement chitin or chitin, degraded 0.5-12 hour, and filtered, add amino acid, zinc sulfate, sal epsom, boric acid.
- 2 preparation methods as claimed in claim 1 is characterized in that described acid is glacial acetic acid, hydrochloric acid, sulfuric acid, phosphoric acid or mixing acid, and the part by weight of described chitin or chitosan and acid and hydrogen peroxide or enzyme is respectively 10: 1-8: 1-8.
- 3 preparation methods as claimed in claim 1 is characterized in that the weight ratio scope of described chitin or chitosan and amino acid, zinc sulfate, magnesium nitrate and boric acid respectively is 10: 1-10: 1-10: 1-10: 1-15.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN200410035619.2A CN1234271C (en) | 2004-08-27 | 2004-08-27 | Preparation method of chitin oligosaccharide zinc borone magnesium fertilizer |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN200410035619.2A CN1234271C (en) | 2004-08-27 | 2004-08-27 | Preparation method of chitin oligosaccharide zinc borone magnesium fertilizer |
Publications (2)
Publication Number | Publication Date |
---|---|
CN1597634A true CN1597634A (en) | 2005-03-23 |
CN1234271C CN1234271C (en) | 2006-01-04 |
Family
ID=34664279
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN200410035619.2A Withdrawn - After Issue CN1234271C (en) | 2004-08-27 | 2004-08-27 | Preparation method of chitin oligosaccharide zinc borone magnesium fertilizer |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN1234271C (en) |
Cited By (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101381258A (en) * | 2008-10-24 | 2009-03-11 | 北京易众恒科技有限公司 | Environment-friendly type foliage fertilizer |
CN101455208A (en) * | 2008-10-24 | 2009-06-17 | 北京易众恒科技有限公司 | Seed treatment agent and preparation technique thereof |
CN101250075B (en) * | 2008-03-18 | 2010-06-09 | 吉林农业大学 | Ginseng foliar fertilizer |
CN101974038A (en) * | 2010-09-28 | 2011-02-16 | 农业部规划设计研究院 | Oligomeric amino sugar acid and preparation method thereof |
CN102144637A (en) * | 2010-12-23 | 2011-08-10 | 海南正业中农高科股份有限公司 | Chitosan oligosaccharide composite with cold-resistant function and application of composite |
CN101993257B (en) * | 2009-08-27 | 2013-05-15 | 林大昌 | Method for preparation of high-activity compound organic fertilizer by waste acid liquid of D-glucosamine hydrochloride |
CN104230579A (en) * | 2014-10-15 | 2014-12-24 | 青岛力力惠生物科技有限公司 | Preparation method for chitin-rich compound fertilizer |
CN104692932A (en) * | 2015-02-12 | 2015-06-10 | 海南正业中农高科股份有限公司 | Synergistic composition containing chitosan oligosaccharide and amino acid |
CN106135263A (en) * | 2016-05-14 | 2016-11-23 | 海南正业中农高科股份有限公司 | Compositions containing organic zinc and application thereof |
-
2004
- 2004-08-27 CN CN200410035619.2A patent/CN1234271C/en not_active Withdrawn - After Issue
Cited By (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101250075B (en) * | 2008-03-18 | 2010-06-09 | 吉林农业大学 | Ginseng foliar fertilizer |
CN101455208A (en) * | 2008-10-24 | 2009-06-17 | 北京易众恒科技有限公司 | Seed treatment agent and preparation technique thereof |
CN101381258A (en) * | 2008-10-24 | 2009-03-11 | 北京易众恒科技有限公司 | Environment-friendly type foliage fertilizer |
CN101993257B (en) * | 2009-08-27 | 2013-05-15 | 林大昌 | Method for preparation of high-activity compound organic fertilizer by waste acid liquid of D-glucosamine hydrochloride |
CN101974038A (en) * | 2010-09-28 | 2011-02-16 | 农业部规划设计研究院 | Oligomeric amino sugar acid and preparation method thereof |
CN101974038B (en) * | 2010-09-28 | 2013-09-11 | 农业部规划设计研究院 | Oligomeric amino sugar acid and preparation method thereof |
CN102144637B (en) * | 2010-12-23 | 2012-07-04 | 海南正业中农高科股份有限公司 | Chitosan oligosaccharide composite with cold-resistant function and application of composite |
CN102144637A (en) * | 2010-12-23 | 2011-08-10 | 海南正业中农高科股份有限公司 | Chitosan oligosaccharide composite with cold-resistant function and application of composite |
CN104230579A (en) * | 2014-10-15 | 2014-12-24 | 青岛力力惠生物科技有限公司 | Preparation method for chitin-rich compound fertilizer |
CN104230579B (en) * | 2014-10-15 | 2016-08-24 | 青岛力力惠生物科技股份有限公司 | Preparation method of chitin-rich compound fertilizer |
CN104692932A (en) * | 2015-02-12 | 2015-06-10 | 海南正业中农高科股份有限公司 | Synergistic composition containing chitosan oligosaccharide and amino acid |
CN106135263A (en) * | 2016-05-14 | 2016-11-23 | 海南正业中农高科股份有限公司 | Compositions containing organic zinc and application thereof |
CN106135263B (en) * | 2016-05-14 | 2019-07-30 | 海南正业中农高科股份有限公司 | Composition and application thereof containing organic zinc |
Also Published As
Publication number | Publication date |
---|---|
CN1234271C (en) | 2006-01-04 |
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Owner name: CHINA OCEAN UNIVERSITY ORGANISM PROJECT DEVELOPMEN Free format text: FORMER OWNER: CHINA OCEAN UNIV. Effective date: 20090821 |
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Effective date of registration: 20090821 Address after: No. 23, Hongkong East Road, Shandong, Qingdao Patentee after: China Ocean University Organism Project Development Co.,Ltd. Address before: Shandong province Qingdao City fish Road No. 5 Patentee before: Ocean University of China |
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C56 | Change in the name or address of the patentee |
Owner name: QINGDAO SEAWIN BIOTECH GROUP CO., LTD. Free format text: FORMER NAME: CHINA OCEAN UNIVERSITY ORGANISM PROJECT DEVELOPMENT CO., LTD. |
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CP03 | Change of name, title or address |
Address after: 266071, room 508, Science Park, Qingdao National University, 23 East Hongkong Road, Laoshan District, Shandong, Qingdao Patentee after: QINGDAO SEAWIN BIOTECH GROUP Co.,Ltd. Address before: 266017 No. 23 East Hongkong Road, Shandong, Qingdao Patentee before: China Ocean University Organism Project Development Co.,Ltd. |
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C56 | Change in the name or address of the patentee | ||
CP02 | Change in the address of a patent holder |
Address after: 266003 Shandong province Qingdao City fish Road No. 5 Patentee after: QINGDAO SEAWIN BIOTECH GROUP Co.,Ltd. Address before: 266071, room 508, Science Park, Qingdao National University, 23 East Hongkong Road, Laoshan District, Shandong, Qingdao Patentee before: QINGDAO SEAWIN BIOTECH GROUP Co.,Ltd. |
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PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: Preparation of chitooligosaccharide zinc boron magnesium fertilizer Effective date of registration: 20210622 Granted publication date: 20060104 Pledgee: Qingdao high tech Industrial Development Zone sub branch of China Construction Bank Co.,Ltd. Pledgor: QINGDAO SEAWIN BIOTECH GROUP Co.,Ltd. Registration number: Y2021370010037 |
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Address after: 266000 No. 127 Huizhiqiao Road, Qingdao High-tech Zone, Shandong Province Patentee after: Qingdao Haida biological Group Co.,Ltd. Address before: 266003 Shandong province Qingdao City fish Road No. 5 Patentee before: QINGDAO SEAWIN BIOTECH GROUP Co.,Ltd. |
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Date of cancellation: 20220506 Granted publication date: 20060104 Pledgee: Qingdao high tech Industrial Development Zone sub branch of China Construction Bank Co.,Ltd. Pledgor: QINGDAO SEAWIN BIOTECH GROUP Co.,Ltd. Registration number: Y2021370010037 |
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AV01 | Patent right actively abandoned |
Granted publication date: 20060104 Effective date of abandoning: 20221009 |
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Granted publication date: 20060104 Effective date of abandoning: 20221009 |
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