CN1587144A - Glaze pulp for processing glazed tile and its producing glaze pulp and method for processing glazed tile using glaze pulp - Google Patents
Glaze pulp for processing glazed tile and its producing glaze pulp and method for processing glazed tile using glaze pulp Download PDFInfo
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- CN1587144A CN1587144A CN 200410051476 CN200410051476A CN1587144A CN 1587144 A CN1587144 A CN 1587144A CN 200410051476 CN200410051476 CN 200410051476 CN 200410051476 A CN200410051476 A CN 200410051476A CN 1587144 A CN1587144 A CN 1587144A
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- Prior art keywords
- glaze slip
- ceramic tile
- powdered frit
- glaze
- stpp
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/14—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Glass Compositions (AREA)
Abstract
The glaze slurry is compounded with glaze powder and proper amount of water, and features that the glaze powder consists of mica 0.001-90 wt%, and transparent or opal glass 10-99.99 wt%. The present invention utilizes the characteristics of mica, which has small specific weight, high smelting point and gold luster after being calcined at certain temperature, to make the glazed tile exhibit gold luster or luster in other color. The glazed tile has beautiful color, unique pattern and excellent decorative effect as well as simple production process and high durability.
Description
Technical field
The present invention relates to a kind ofly process glaze slip that ceramic tile uses and enamel frit makeing slurry thereof and with the method for glaze slip processing ceramic tile.
Background technology
At present, the ceramic tile of building faced usefulness generally be earlier by glazing equipment after glaze slip is executed on the adobe surface of moulding, by silk screen printing pattern directly is printed on the brick face then, form through high-temperature calcination again.Yet, the ceramic tile of the decorative pattern that this employing silk-screen printing technique forms on the brick surface, its pattern tradition, color and luster dimness are difficult to form the stronger metalluster of one deck decorative effect on the brick face.Thereby cause its poor, no modern sense of decorative effect, of low grade in actual applications, can not adapt to modern architecture and decorate the problems such as development need of making rapid progress.
Summary of the invention
The objective of the invention is to solve above-mentioned existing problems, provide can in the glaze layer on brick surface, produce after a kind of calcining and can send metalluster or other color glossy suspension point-like particle, and the glaze slip used of the processing ceramic tile that color and luster is beautiful, style is unique, decorative effect is strong and enamel frit makeing slurry thereof and with the method for glaze slip processing ceramic tile.
Technical scheme of the present invention is achieved in that
A kind ofly process the glaze slip that ceramic tile is used, add an amount of water by powdered frit and be made into, its characteristics are that described powdered frit comprises following main ingredient by weight percentage:
Sheet mica: 0.001%～90%;
Transparent or emulsion opal glass: 10%～99.99%.
In order to prevent that effectively being made into the back glaze slip precipitates, influence the performance of glaze slip, above-mentioned powdered frit also comprises the additive of following weight percent:
High territory: 0%～20%;
Methylcellulose gum (CMC): 0%～3%;
Tripoly phosphate sodium STPP (STPP): 0%～3%;
For making the present invention can make the ceramic tile of various different colours, to adapt to the demand that different occasions are decorated, above-mentioned powdered frit comprises that also weight percent is: 0%～10% mineral dye.
In order to make the present invention can be by the weight percent of each component of above-mentioned powdered frit, make and be fit to the glaze slip that the processing ceramic tile is used, the present invention also comprises the method that is used to prepare glaze slip, its step is as follows:
(1) earlier will each starting material except that sheet mica adds ball mill respectively by weight percentage or other disintegrating apparatus is pulverized, and make the powder of 325 mesh screen residues 2%～4% after pulverizing;
(2) be that 20～60 purpose sheet micas add in the agitator by weight percentage and stir with powder and fineness, obtain powdered frit;
(3) powdered frit that stirring obtained adds an amount of water, and to be made into proportion be 1.60～1.98 glaze slip.
For the glaze slip that makes the present invention can utilize aforesaid method to make processes the ceramic tile that gold is beautiful, texture good, decorative effect is strong, the present invention also comprises the method for utilizing the above-mentioned glaze slip processing ceramic tile for preparing, and its step is as follows:
(1) by glazing equipment with the glaze slip for preparing with 800～2000g/m
2Weight is drenched on the adobe surface;
(2) adobe that will drench glaze slip is delivered in the kiln and is calcined with 800～1300 ℃ high temperature.
The present invention since adopt main ingredients such as sheet mica, transparent or emulsion opal glass be made into by weight percentage powdered frit with and preparation glaze slip and with the method for glaze slip processing ceramic tile, make the present invention effectively utilize the proportion of sheet mica little, melt temperature is high and can produce the characteristic of golden metalluster after the calcining in certain temperature range, can send metalluster or other color glossy suspension point-like particle thereby make the present invention send can produce in the glaze layer on brick surface after the kiln calcining by the adobe of pouring being executed glaze slip.Not only have the characteristics that color and luster is beautiful, style is unique, decorative effect is strong, but also have simple, the long-lived characteristics of manufacturing process.
Embodiment
Embodiment one
The glaze slip that processing ceramic tile of the present invention is used, add an amount of water by powdered frit and be made into slurries, for glaze slip of the present invention is applied on the brick, can realize calcining back generation in the glaze layer on brick surface and have metalluster or other color glossy suspension point-like particle, but also having characteristics such as color and luster is beautiful, style is unique, good decorating effect, wherein said glaze slip comprises following main ingredient by weight percentage: sheet mica: 0.001%～90%; Transparent or emulsion opal glass: 10%～99.99%.Simultaneously, in order to prevent that effectively being made into the back glaze slip precipitates, influence the performance of glaze slip, above-mentioned powdered frit also comprises the additive of following weight percent: high territory: 0%～20%; Methylcellulose gum (CMC): 0%～3%; Tripoly phosphate sodium STPP (STPP): 0%～3%.Meanwhile, in order to make the described glaze slip that makes can produce the ceramic tile of various different colours, to adapt to the demand that different occasions are decorated, above-mentioned powdered frit comprises that also weight percent is: 0%～10% mineral dye again.
Embodiment two
For can being manufactured out, glaze slip of the present invention has better golden metalluster, color and luster is more beautiful, smooth, and the ceramic tile of better quality, each component of the described powdered frit of present embodiment and the preferable weight percent of each additive are: sheet mica: 0.01%～50%; Transparent or emulsion opal glass: 30.5%～98.78%; High territory: 1%～15%; Methylcellulose gum (CMC): 0.1%～1.5%; Tripoly phosphate sodium STPP (STPP): 0.1%～1.5%; Mineral dye: 0.01%～1.5%.Then, the powdered frit for preparing is added an amount of water and be made into slurries.
Embodiment three
For suspension point-like particle in the glaze layer that makes the ceramic tile that glaze slip of the present invention manufactures out can produce golden beautiful metalluster, have the effect that stereoscopic sensation is strong, texture good, decorative effect is strong, each component of the described powdered frit of present embodiment and the optimum weight percentage of each additive are: sheet mica: 0.1%～3%; Transparent or emulsion opal glass: 85%～96.39%; High territory: 2.9%～10%; Methylcellulose gum (CMC): 0.3%～0.5%; Tripoly phosphate sodium STPP (STPP): 0.3%～0.5%; Mineral dye: 0.01%～1%.Then, the powdered frit for preparing is added an amount of water and be made into slurries.
Embodiment four
In order to make the present invention can be by the weight percent of each component of the powdered frit of the foregoing description, make and be fit to the glaze slip that the processing ceramic tile is used, the present invention also comprises the method that is used to prepare glaze slip, its step is as follows:
(1) earlier will each starting material except that sheet mica adds ball mill respectively by weight percentage or other disintegrating apparatus is pulverized, and make the powder of 325 mesh screen residues 2%～4% after pulverizing;
(2) be that 20～60 purpose sheet micas add in the agitator by weight percentage and stir with powder and fineness, obtain powdered frit;
(3) powdered frit that stirring obtained adds an amount of water, and to be made into proportion be 1.60～1.98 glaze slip.
Simultaneously, be suspension point-like uniform particles, exquisiteness in the glaze layer that makes the ceramic tile of producing, the optimum fineness of the sheet mica in the above-mentioned steps (2) is 30～40 orders.Meanwhile, can not produce aberration in order to ensure ceramic tile, the best proportion that is made into glaze slip in the above-mentioned steps (3) is 1.85～1.92.
Embodiment five
For the glaze slip that makes the present invention can utilize embodiment four to prepare processes the ceramic tile that gold is beautiful, texture good, decorative effect is strong, present embodiment also comprises the method for utilizing glaze slip processing ceramic tile, and its step is as follows:
(1) by glazing equipment with the glaze slip for preparing with 800～2000g/m
2Weight is drenched on the adobe surface;
(2) adobe that will drench glaze slip is delivered in the kiln and is calcined with 800～1300 ℃ high temperature.
Crack performance can not take place in good ceramic tile in order to make calcining, and color and luster is even, and calcining temperature preferably is controlled at 1000～1185 ℃ in the above-mentioned steps (2).
Claims (10)
1, a kind ofly process the glaze slip that ceramic tile is used, add an amount of water by powdered frit and be made into, it is characterized in that described powdered frit comprises following main ingredient by weight percentage:
Sheet mica: 0.001%～90%;
Transparent or emulsion opal glass: 10%～99.99%.
2, the glaze slip of using according to the described processing ceramic tile of claim 1 is characterized in that above-mentioned powdered frit also comprises the additive of following weight percent:
High territory: 0%～20%;
Methylcellulose gum (CMC): 0%～3%;
Tripoly phosphate sodium STPP (STPP): 0%～3%.
3, the glaze slip of using according to the described processing ceramic tile of claim 1 is characterized in that above-mentioned powdered frit comprises that also weight percent is: 0%～10% mineral dye.
4, the glaze slip of using according to claim 1 or 2 or 3 described processing ceramic tiles is characterized in that each component of above-mentioned powdered frit and the preferable weight percent of each additive are:
Sheet mica: 0.01%～50%;
Transparent or emulsion opal glass: 30.5%～98.78%;
High territory: 1%～15%;
Methylcellulose gum (CMC): 0.1%～1.5%;
Tripoly phosphate sodium STPP (STPP): 0.1%～1.5%;
Mineral dye: 0.01%～1.5%.
5, the glaze slip of using according to the described processing ceramic tile of claim 4 is characterized in that each component of above-mentioned powdered frit and the optimum weight percentage of each additive are:
Sheet mica: 0.1%～3%;
Transparent or emulsion opal glass: 85%～96.39%;
High territory: 2.9%～10%;
Methylcellulose gum (CMC): 0.3%～0.5%;
Tripoly phosphate sodium STPP (STPP): 0.3%～0.5%;
Mineral dye: 0.01%～1%.
6, a kind ofly prepare the method for glaze slip, it is characterized in that comprising the steps: according to claim 1
(1) earlier will each starting material except that sheet mica adds ball mill respectively by weight percentage or other disintegrating apparatus is pulverized, and make the powder of 325 mesh screen residues 2%～4% after pulverizing;
(2) be that 20～60 purpose sheet micas add in the agitator by weight percentage and stir with powder and fineness, obtain powdered frit;
(3) powdered frit that stirring obtained adds an amount of water, and to be made into proportion be 1.60～1.98 glaze slip.
7, according to the method for the described preparation glaze slip of claim 6, the optimum fineness that it is characterized in that the sheet mica in the above-mentioned steps (2) is 30～40 orders.
8, according to the method for the described preparation glaze slip of claim 6, the best proportion that it is characterized in that being made in the above-mentioned steps (3) glaze slip is 1.85～1.92.
9, a kind of method of processing ceramic tile according to the glaze slip of claim 6 preparation is characterized in that comprising the steps:
(1) by glazing equipment with the glaze slip for preparing with 800～2000g/m
2Weight is drenched on the adobe surface;
(2) adobe that will drench glaze slip is delivered in the kiln and is calcined with 800～1300 ℃ high temperature.
10,, it is characterized in that calcining temperature preferably is controlled at 1000～1185 ℃ in the above-mentioned steps (2) according to the method for the described worker's ceramic tile of claim 9.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200410051476 CN1587144A (en) | 2004-09-15 | 2004-09-15 | Glaze pulp for processing glazed tile and its producing glaze pulp and method for processing glazed tile using glaze pulp |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200410051476 CN1587144A (en) | 2004-09-15 | 2004-09-15 | Glaze pulp for processing glazed tile and its producing glaze pulp and method for processing glazed tile using glaze pulp |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1587144A true CN1587144A (en) | 2005-03-02 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 200410051476 Pending CN1587144A (en) | 2004-09-15 | 2004-09-15 | Glaze pulp for processing glazed tile and its producing glaze pulp and method for processing glazed tile using glaze pulp |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102515853A (en) * | 2011-12-30 | 2012-06-27 | 江苏拜富科技有限公司 | Preparation method of zirconium silicate wrapped high-temperature sulfur cadmium selenide bright red pigment |
| CN103497007A (en) * | 2013-09-17 | 2014-01-08 | 佛山市五月玫瑰陶瓷有限公司 | Ceramic tile with dispersed shimmering powder and manufacturing method thereof |
| CN108129166A (en) * | 2017-12-07 | 2018-06-08 | 苏州物非物文化创意有限公司 | A kind of production method of ceramic glaze |
| CN110683766A (en) * | 2019-11-22 | 2020-01-14 | 重庆唯美陶瓷有限公司 | Full-polished glaze and preparation method thereof, black ink-jet ceramic tile and manufacturing method thereof |
-
2004
- 2004-09-15 CN CN 200410051476 patent/CN1587144A/en active Pending
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102515853A (en) * | 2011-12-30 | 2012-06-27 | 江苏拜富科技有限公司 | Preparation method of zirconium silicate wrapped high-temperature sulfur cadmium selenide bright red pigment |
| CN103497007A (en) * | 2013-09-17 | 2014-01-08 | 佛山市五月玫瑰陶瓷有限公司 | Ceramic tile with dispersed shimmering powder and manufacturing method thereof |
| CN103497007B (en) * | 2013-09-17 | 2016-01-27 | 佛山市五月玫瑰陶瓷有限公司 | A kind of ceramic tile with dispersal type shimmering powder and manufacture method thereof |
| CN108129166A (en) * | 2017-12-07 | 2018-06-08 | 苏州物非物文化创意有限公司 | A kind of production method of ceramic glaze |
| CN110683766A (en) * | 2019-11-22 | 2020-01-14 | 重庆唯美陶瓷有限公司 | Full-polished glaze and preparation method thereof, black ink-jet ceramic tile and manufacturing method thereof |
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