CN1535575A - Phenoxy microbial ester water dispersible granules and water suspension agent - Google Patents
Phenoxy microbial ester water dispersible granules and water suspension agent Download PDFInfo
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- CN1535575A CN1535575A CNA031131115A CN03113111A CN1535575A CN 1535575 A CN1535575 A CN 1535575A CN A031131115 A CNA031131115 A CN A031131115A CN 03113111 A CN03113111 A CN 03113111A CN 1535575 A CN1535575 A CN 1535575A
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- kresoxim
- methyl
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- dispersible granules
- water dispersible
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Abstract
The present invention relates to a phenoxy bacterioester water dispersing granules preparation and a phenoxy bacterioester water suspension agent, the former is a granules preparation obtained by mixing phenoxy bacterioester with adjuvant and pilling material together, and can be quickly disintegrated in water, dispersed and formed into high suspended and stable dispersion system, and the latter is a high-dispersity and stable liquid preparation using water as medium and obtained by mixing phenoxy bacterioester together with adjuvant and water. As compared with wettable powder preparation said two preparations are large in density, small in volume, have good dispersity and high suspension rate, and can raise control effect.
Description
One, technical field
The present invention relates to a kind of novel formulation of disinfectant use in agriculture, specifically two of the bactericide kresoxim-methyl kinds of preparations, i.e. kresoxim-methyl water dispersible granules (WDG) and kresoxim-methyl aqueous suspension agent (SC).
Two, background technology
Kresoxim-methyl (Kresoxim-methyl) has another name called kresoxim-methyl, belongs to methoxy acrylic bactericide.
Structural formula:
Chemical name is:
(E)-α-methoxy imino-2-[(2-methylphenoxy)-methyl] methyl phenylacetate.Be mainly used in wheat, corn, jowar, paddy rice, fruit tree, vegetables, potatoes and other crops, most of diseases that pathomycetes such as Ascomycetes, Basidiomycetes, Fungi Imperfecti and oomycetes subclass are caused have treatment, protection and eradicant action.It is quite valued both at home and abroad in recent years new outstanding kind.CN1237088A discloses the method for this compound control fungi, but does not point out formulation.The disclosed microbicide compositions of CN1359620A is the complex preparation of this compound and other bactericide.The preparation of current kresoxim-methyl is based on wetting powder, and kind is single, and is producing, packing dust drift in the use, and contaminated environment directly endangers the operator, and bactericidal effect is poor simultaneously.
Three, summary of the invention
Water dispersible granules (Water dispersible granule, WDG or WG) disintegration soon, dispersion in water, the dispersion of form higher suspension.It comprises components such as active component, wetability, dispersant, disintegrant, stabilizing agent, burl agent and filler.
Aqueous suspension agent (Suspension concentrate or SC) is to be dispersion medium with water, the formulations of pesticide that former medicine, auxiliary agent (wetting agent, dispersant, thickener, stabilizing agent, antifreezing agent and defoamer) are made through waterproof pulverization.It has polymolecularity and stability.
Task of the present invention is processed into kresoxim-methyl water dispersible granules (calling kresoxim-methyl WDG in the following text) and aqueous suspension agent (calling kresoxim-methyl SC in the following text) exactly.
Each weight percentages of components of kresoxim-methyl WDG is:
Kresoxim-methyl 5-90%
Auxiliary agent 0.5-50%
Filler 5-45%.
Preferred percentage by weight is:
Kresoxim-methyl 45-80%
Auxiliary agent 10-30%
Filler 10-25%.
Described auxiliary agent is meant dispersant and/or wetting agent, disintegrant, stability, binding agent.
Each weight percentages of components of kresoxim-methyl SC:
Kresoxim-methyl 5-50%
Auxiliary agent 0.5-30%
Water surplus.
Preferred percentage by weight is:
Kresoxim-methyl 20-40%
Auxiliary agent 10-25%
Water surplus.
Described auxiliary agent refers to dispersant and/or wetting agent, stabilizing agent, thickener, antifreezing agent, defoamer.
Described dispersant has: sodium phosphate trimer, sodium lignin sulfonate, NNO, calcium lignosulfonate, polyoxyethylene polyoxypropylene block copolymer, rope uncle SOPA, diffusion agent N O, dispersing agent MF.Can use separately, also can two or more composite uses.
Described wetting agent has that tea is withered, Chinese honey locust, sldium lauryl sulfate, ethoxylated dodecyl alcohol sodium sulphate, octylphenol polyethylene oxyethylene group ether sulfate, rope uncle SOPA, neopelex, draw back powder, penetrant t, penetrating agent JFC, Tween 80.Can use separately, also can two or more composite uses.
Dispersant and wetting agent mostly are surfactant greatly, as a rule, add dispersant and just can save wetting agent, and vice versa.
Described stabilizing agent has: tributyl phosphate, triphenyl phosphite, BHT.Can use or mix use separately.
Described disintegrant has: ammonium sulfate, calcium chloride, magnesium chloride, aluminium chloride, bentonite, urea.Can use separately, also can two or more mixing use.
Described binding agent is starch, dextrin, gum Arabic, soybean protein, gelatine, sodium sulphate, gypsum, polyvinyl alcohol, rosin, paraffin, carboxymethyl cellulose, sodium silicate.Can use separately, also can two or more mixing use.
Described filler has: white carbon, potter's clay, bentonite, precipitated calcium carbonate, attapulgite, talcum powder, kaolin, mica.Can use separately, also can two or more mixing use.
Described thickener has gum Arabic, xanthans, methylcellulose, carboxymethyl cellulose, hydroxyethylcellulose, PAA, polyvinyl alcohol, silicic acid, bentonite, aluminium-magnesium silicate.Can use separately, also can two or more mixing use.
Described antifreezing agent has ethylene glycol, urea, propane diols, glycerine, glycerine-ether diglycol.Can use separately, also can two or more mixing use.
Described defoamer has, organosilicon ketone, C
8-C
10Fatty alcohol, ester one ether type compound.
More than all auxiliary agents all are known substances, also be material commonly used and that know in the pesticidal preparations processing.
Known equipment and technology are also used in the preparation of the present composition.
The processing of kresoxim-methyl WDG: former medicine, auxiliary agent and filler are mixed the first comminution by gas stream in back in proportion, add the water of 15-20% then, obtain the water dispersible granules product through kneading, granulation, drying, screening.Perhaps former medicine, auxiliary agent and filler are mixed in proportion the first wet method sand milling in back and obtain slurry, obtain product through kneading, granulation, drying and screening again.The technical indicator of product is as follows:
Kresoxim-methyl content, % (m/m) 5-90
Moisture, %≤1.0
PH value scope 5.0-7.5
Wetting time, S≤60
Screen analysis (by 75 μ m testing sieves), % 〉=95.0
Suspensibility, % 〉=70.0
Disintegration time, min≤3.0
Particle size range, (0.1-2.0) mm, % 〉=95.0
Lasting foam number, ml≤25.0
Heat storage stability (54 ± 2 ℃, 14d) resolution ratio, %≤5.0
The processing of kresoxim-methyl SC: with former medicine, auxiliary agent with part water mixes in proportion after high speed shear, wet method sand milling obtain semi-finished product, fill up the product that water is deployed into regulation content again.The technical indicator of product is as follows:
Kresoxim-methyl content, % (m/m) 5-50%
PH value scope 5.0-7.5
Screen analysis (by 75 μ m testing sieves), % 〉=95.0
Suspensibility, % 〉=90.0
Pourability is toppled over back residue, %≤5.0
Washing back residue, %≤0.5
Lasting foam number, ml≤25.0
Heat storage stability (54 ± 2 ℃, 14d) resolution ratio, %≤5.0
Kresoxim-methyl WDG, SC preparation, no dust drift in production, use, packaging process is to operator's safety, environmentally friendly, to compare with wetting powder, the product relative density is big, volume is little, bring great convenience for packing, storage, transportation, packing material is also easily handled; Good dispersion in the water, the suspensibility height, control efficiency is good.
Four, embodiment
Non-limiting examples is described below:
A, kresoxim-methyl water dispersible granules (WDG)
1, gets the former medicine 5.6kg of 90% kresoxim-methyl, wetting agent SOPA5kg, dispersant NNO0.8Kg, disintegrant ammonium sulfate 2kg, binding agent carboxymethyl cellulose 1kg, stabilizing agent BHT2kg, filler potter's clay 76.4kg, through mixing, comminution by gas stream, adding 20kg water, mixing, kneading, granulation, drying, sieve the kresoxim-methyl water dispersible granules.Or through wet method sand milling, drying, granulation, drying, sieve kresoxim-methyl WDG.
2, get the former medicine 11.2kg of 90% kresoxim-methyl, the withered 3kg of wetting agent tea, draw back powder 2kg, dispersant sodium lignin sulfonate 10kg, disintegrant calcium chloride 4kg, adhesive starch 1.5kg, stabilizing agent tributyl phosphate 1kg, filler white carbon 15kg, kaolin 48.7kg, 1 preparation method gets kresoxim-methyl WDG by example.
3, get the former medicine 21.1kg of 95% kresoxim-methyl, wetting agent Chinese honey locust 2kg, sldium lauryl sulfate 4kg, dispersant sulfomethylated lignin calcium 6kg, dispersing agent MF 3kg, disintegrant magnesium chloride 2kg, bentonite 7kg, binding agent dextrin 1kg, stabilizing agent triphenyl phosphite 2kg, filler talcum powder 10kg, mica 41.9kg, 1 preparation method gets kresoxim-methyl WDG by example.
4, get the former medicine 31.6kG of 95% kresoxim-methyl, wetting agent ethoxylated dodecyl alcohol sodium sulphate 3kg, octylphenol polyethylene oxyethylene group ether sulfate 4kg, dispersant polyoxyethylene poly-oxygen propylene aether block copolymer 5kg, rope uncle SOPA3kg, disintegrant urea 5kg, binding agent plaster of paris 3kg, stabilizing agent triphenyl phosphite 2kg, filler attapulgite 10kG, precipitated calcium carbonate 23.4kg, 1 preparation method gets kresoxim-methyl WDG by example.
5, get the former medicine 44.5kg of 90% kresoxim-methyl, wetting agent lauryl sodium sulfate 2kg, dispersant NO10kg, disintegrant bentonite 4kg, binding agent polyvinyl alcohol 2kg, stabilizing agent BHT1.5kg, filler white carbon 36kg, 1 preparation method gets kresoxim-methyl WDG by example.
6, get the former medicine 52.7kg of 95% kresoxim-methyl, lubricated penetrant t 3kg, dispersant calcium lignosulfonate 7kg, disintegrant aluminium chloride 3kg, binding agent carboxymethyl cellulose 1.5kg, stabilizing agent BHT1.5kg, filler bentonite 31.3kg, 1 preparation method gets kresoxim-methyl WDG by example.
7, get the former medicine 63.2kg of 95% kresoxim-methyl, wetting agent Tween 80 4kg, dispersant calcium lignosulfonate 6kg, disintegrant ammonium sulfate 3kg, binding agent gelatine 2kg, stabilizing agent BHT1.5kg, filler white carbon 20.3kg, 1 preparation method gets kresoxim-methyl WDG by example.
8, get the former medicine 73.7kg of 95% kresoxim-methyl, wetting agent penetrating agent JFC 4kg, dispersant NNO6kg, disintegrant ammonium sulfate 3kg, binding agent sodium silicate 1kg, stabilizing agent BHT1kg, filler potter's clay 11.3kg, 1 preparation method gets kresoxim-methyl WDG by example.
9, get the former medicine 84.3kg of 95% kresoxim-methyl, dispersant NO6kg, disintegrant ammonium sulfate 1kg, binding agent gum Arabic 1.5kg, stabilizing agent BHT1kg, filler potter's clay 6.2kg, 1 preparation method gets kresoxim-methyl WDG by example.
10, get the former medicine 94.8kg of 95% kresoxim-methyl, wetting agent neopelex 2kg, disintegrant ammonium sulfate 1kg, adhesive starch 0.5kg, stabilizing agent BHT0.5kg, filler white carbon 1.2kg, 1 preparation method gets kresoxim-methyl WDG by example.
B, kresoxim-methyl aqueous suspension (SC)
11, get the former medicine 5.3kg of 95% benzene oxygen bacterium acid, wetting agent SOPA4kg, dispersant NO10kg, stabilizing agent BHT2kg, antifreezing agent propane diols 6kg, thickener gum Arabic 3.5kg, defoamer organic silicone 0.5kg, water 68.7kg, by high speed shear, sand milling, modulation after intact kresoxim-methyl SC.
12, get the former medicine 10.6kg of 95% kresoxim-methyl, the withered 7kg of wetting agent tea, dispersant NNO8kg, stabilizing agent BHT2kg, antifreeze glycol 8kg, thickener xanthans 0.5kg, defoamer C
8～C
10Fatty alcohol 0.5kg, water 63.4kg, by high speed shear, sand milling, modulation after intact kresoxim-methyl SC.
13, get the former medicine 22.3kg of 95% kresoxim-methyl, wetting agent draws back powder 5kg, dispersant calcium lignosulfonate 7kg, stabilizing agent BHT2kg, antifreezing agent urea 5kg, thickener carboxymethyl cellulose 2.5kg, defoamer ester-ether type compound 1kg, water 55.2kg, by high speed shear, sand milling, modulation after intact kresoxim-methyl SC.
14, get the former medicine 26.4kg of 95% kresoxim-methyl, wetting agent seepage T4kg, Dispersant MF 8kg, stabilizing agent tributyl phosphate 1kg, antifreezing agent glycerine 5kg, thickener PAA 0.5kg, defoamer C
8～C
10Fatty alcohol 0.5kg, water 54.6kg, by high speed shear, sand milling, modulation after intact kresoxim-methyl SC.
15, get the former medicine 31.6kg of 95% kresoxim-methyl, wetting agent neopelex 1kg, dispersant polyoxyethylene poly-oxygen propylene aether block copolymer 10kg, stabilizing agent triphenyl phosphite 2kg, antifreezing agent glycerine-ether diglycol 5kg, thickener xanthans 0.5kg, defoamer C
8～C
10Fatty alcohol 0.5kg, water 49.4kg, by high speed shear, sand milling, modulation after intact kresoxim-methyl SC.
16, get the former medicine 36.9kg of 95% kresoxim-methyl, wetting agent octylphenol polyethylene oxyethylene group ether sulfate 6kg, pentasodium triphosphate of dispersing agent 5kg, stabilizing agent triphenyl phosphite 2kg, antifreeze glycol 5kg, thickener xanthans 0.5kg, defoamer organic silicone 0.5kg, water 44.1kg, by high speed shear, sand milling, modulation after intact kresoxim-methyl SC.
17, get the former medicine 42.2kg of 95% kresoxim-methyl, wetting agent penetrating agent JFC 3kg, dispersant sodium lignin sulfonate 6kg, stabilizing agent triphenyl phosphite 2kg, antifreeze glycol 6kg, thickener xanthans 0.2kg, defoamer organic silicone 0.5kg, water 40.1kg, by high speed shear, sand milling, modulation after intact kresoxim-methyl SC.
18, get the former medicine 47.4kg of 95% kresoxim-methyl, the withered 8kg of wetting agent tea, stabilizing agent BHT1kg, antifreeze glycol 5kg, thickener xanthans 0.15kg, defoamer organic silicone 0.5kg, water 37.95kg, by high speed shear, sand milling, modulation after intact kresoxim-methyl SC.
19, get the former medicine 52.7kg of 95% kresoxim-methyl, dispersant calcium lignosulfonate 7kg, stabilizing agent BHT1kg, antifreeze glycol 5kg, thickener xanthans 0.1kg, defoamer organic silicone 0.5kg, water 33.7kg, by high speed shear, sand milling, modulation after intact kresoxim-methyl SC.
Claims (15)
1, a kind of kresoxim-methyl water dispersible granules, its component and content (percentage by weight) are:
Kresoxim-methyl 5-90%
Auxiliary agent 0.5-50%
Filler 5-45%.
2, kresoxim-methyl water dispersible granules according to claim 1, the preferred content of each component is:
Kresoxim-methyl 45-80%
Auxiliary agent 10-30%
Filler 10-25%.
3, kresoxim-methyl water dispersible granules according to claim 1 and 2 is characterized in that: described auxiliary agent is meant dispersant and/or wetting agent, disintegrant, stabilizing agent, binding agent.
4, kresoxim-methyl water dispersible granules according to claim 1 and 2 is characterized in that: described filler is one or more the mixed fillers in white carbon, potter's clay, bentonite, precipitated calcium carbonate, attapulgite, talcum powder, kaolin, the mica.
5, a kind of kresoxim-methyl aqueous suspension agent, its component and content (percentage by weight) are:
Kresoxim-methyl 5-50%
Auxiliary agent 0.5-30%
Water surplus.
6, kresoxim-methyl aqueous suspension agent according to claim 5, the preferred content of each component is:
Kresoxim-methyl 20-45%
Auxiliary agent 10-25%
Water surplus.
7, it is characterized in that according to claim 5 or 6 described kresoxim-methyl aqueous suspension agents: described auxiliary agent is meant dispersant and/or wetting agent, stabilizing agent, thickener, antifreezing agent, defoamer.
8, according to claim 3 or 7 described kresoxim-methyl water dispersible granules and aqueous suspension agents, it is characterized in that: described dispersant is one or more mixed dispersants in sodium phosphate trimer, sodium lignin sulfonate, NNO, calcium lignosulfonate, polyoxyethylene poly-oxygen propylene aether block copolymer, rope uncle SOPA, diffusion agent N O, the dispersing agent MF.
9, according to claim 3 or 7 described kresoxim-methyl water dispersible granules and aqueous suspension agents, it is characterized in that: described wetting agent is that tea is withered, Chinese honey locust, sldium lauryl sulfate, ethoxylated dodecyl alcohol sodium sulphate, octylphenol polyethylene oxyethylene group ether sulfate, rope uncle SOPA, neopelex, draw back in powder, penetrant t, penetrating agent JFC, the Tween 80 one or more and mix wetting agents.
10, according to claim 3 or 7 described kresoxim-methyl water dispersible granules and aqueous suspension agents, it is characterized in that: described stabilizing agent is one or more mixed stabilizers among tributyl phosphate, triphenyl phosphite, the BHT.
11, kresoxim-methyl water dispersible granules according to claim 3 is characterized in that: described disintegrant is one or more mixing disintegrants in ammonium sulfate, calcium chloride, magnesium chloride, aluminium chloride, bentonite, the urea.
12, kresoxim-methyl water dispersible granules according to claim 3 is characterized in that: described binding agent is one or more hybrid adhesives in starch, dextrin, gum Arabic, soybean protein, gelatine, sodium sulphate, gypsum, polyvinyl alcohol, rosin, paraffin, carboxymethyl cellulose, the sodium silicate.
13, kresoxim-methyl aqueous suspension agent according to claim 7 is characterized in that: described thickener has one or more mixing thickeners in gum Arabic, xanthans, methylcellulose, carboxymethyl cellulose, hydroxyethylcellulose, PAA, polyvinyl alcohol, silicic acid, bentonite, the aluminium-magnesium silicate.
14, kresoxim-methyl aqueous suspension agent according to claim 7 is characterized in that: described antifreezing agent has one or more mixing antifreezing agents in ethylene glycol, urea, propane diols, glycerine, the glycerine-ether diglycol.
15, kresoxim-methyl aqueous suspension agent according to claim 7, it is characterized in that: described defoamer has, organosilicon ketone, C
8-C
10In fatty alcohol, the ester one ether type compound one or more mix defoamer.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 03113111 CN1285264C (en) | 2003-04-04 | 2003-04-04 | Phenoxy microbial ester water dispersible granules and water suspension agent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 03113111 CN1285264C (en) | 2003-04-04 | 2003-04-04 | Phenoxy microbial ester water dispersible granules and water suspension agent |
Related Child Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 200610100831 Division CN1899039A (en) | 2003-04-04 | 2003-04-04 | Water dispersion particles and water suspension agent of kresoxim-methyl |
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| Publication Number | Publication Date |
|---|---|
| CN1535575A true CN1535575A (en) | 2004-10-13 |
| CN1285264C CN1285264C (en) | 2006-11-22 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 03113111 Expired - Fee Related CN1285264C (en) | 2003-04-04 | 2003-04-04 | Phenoxy microbial ester water dispersible granules and water suspension agent |
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Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100408587C (en) * | 2006-11-10 | 2008-08-06 | 中国科学院上海有机化学研究所 | Chiral phosphine thiourea compound, synthesis method and its application |
| CN100423639C (en) * | 2006-11-14 | 2008-10-08 | 华南理工大学 | Kresoxim-methyl microemulsion and preparation method thereof |
| WO2009082939A1 (en) * | 2007-12-19 | 2009-07-09 | Rotam Agrochem International Co., Ltd | Agrochemical composition and method for preparing the same |
| CN101185436B (en) * | 2007-11-21 | 2010-12-01 | 张少武 | Chlorbenzuron water-dispersing granules preparation |
| CN102316725A (en) * | 2008-12-18 | 2012-01-11 | 巴斯夫欧洲公司 | Aqueous dispersion comprising pesticide particles and dissolved saccharide |
| CN101773115B (en) * | 2010-01-28 | 2012-02-01 | 惠州市银农科技有限公司 | Preparation method of pesticide water dispersible granules having fast disintegration property |
| CN104222077A (en) * | 2014-09-03 | 2014-12-24 | 陕西省蒲城美尔果农化有限责任公司 | Kresoxim-methyl water dispersible granule composition and preparation method thereof |
| CN104398586A (en) * | 2014-12-18 | 2015-03-11 | 郑州福源动物药业有限公司 | Shuanghuanglian oral liquid for livestock and poultry as well as preparation method of Shuanghuanglian oral liquid |
| CN105340972A (en) * | 2015-12-17 | 2016-02-24 | 唐睿 | Bactericidal composition containing bacillus subtilis and kresoxim-methyl |
-
2003
- 2003-04-04 CN CN 03113111 patent/CN1285264C/en not_active Expired - Fee Related
Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100408587C (en) * | 2006-11-10 | 2008-08-06 | 中国科学院上海有机化学研究所 | Chiral phosphine thiourea compound, synthesis method and its application |
| CN100423639C (en) * | 2006-11-14 | 2008-10-08 | 华南理工大学 | Kresoxim-methyl microemulsion and preparation method thereof |
| CN101185436B (en) * | 2007-11-21 | 2010-12-01 | 张少武 | Chlorbenzuron water-dispersing granules preparation |
| WO2009082939A1 (en) * | 2007-12-19 | 2009-07-09 | Rotam Agrochem International Co., Ltd | Agrochemical composition and method for preparing the same |
| US9426983B2 (en) | 2007-12-19 | 2016-08-30 | Rotam Agrochem International Company Limited | Agrochemical composition and method for preparing the same |
| CN102316725A (en) * | 2008-12-18 | 2012-01-11 | 巴斯夫欧洲公司 | Aqueous dispersion comprising pesticide particles and dissolved saccharide |
| US8541012B2 (en) | 2008-12-18 | 2013-09-24 | Basf Se | Aqueous dispersion comprising pesticide particles and dissolved saccharide |
| CN102316725B (en) * | 2008-12-18 | 2014-08-13 | 巴斯夫欧洲公司 | Aqueous dispersion comprising pesticide particles and dissolved saccharide |
| CN101773115B (en) * | 2010-01-28 | 2012-02-01 | 惠州市银农科技有限公司 | Preparation method of pesticide water dispersible granules having fast disintegration property |
| CN104222077A (en) * | 2014-09-03 | 2014-12-24 | 陕西省蒲城美尔果农化有限责任公司 | Kresoxim-methyl water dispersible granule composition and preparation method thereof |
| CN104398586A (en) * | 2014-12-18 | 2015-03-11 | 郑州福源动物药业有限公司 | Shuanghuanglian oral liquid for livestock and poultry as well as preparation method of Shuanghuanglian oral liquid |
| CN105340972A (en) * | 2015-12-17 | 2016-02-24 | 唐睿 | Bactericidal composition containing bacillus subtilis and kresoxim-methyl |
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| Publication number | Publication date |
|---|---|
| CN1285264C (en) | 2006-11-22 |
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