CN1532235A - Friction color changing infrared hidden anti-fake ink - Google Patents
Friction color changing infrared hidden anti-fake ink Download PDFInfo
- Publication number
- CN1532235A CN1532235A CNA031145760A CN03114576A CN1532235A CN 1532235 A CN1532235 A CN 1532235A CN A031145760 A CNA031145760 A CN A031145760A CN 03114576 A CN03114576 A CN 03114576A CN 1532235 A CN1532235 A CN 1532235A
- Authority
- CN
- China
- Prior art keywords
- low
- ink vehicle
- melting ink
- pigment
- melting
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The infrared hidden anti-fake print ink capable of changing color in rubbing consists of pigment, binding material, stuffing and assistants. The pigment has the property of change color in rubbing and absorbing infrared completely; the binding material includes phenolic resin as the component 1, vegetable oil modified alkyd resin as the component 2 and gel type binding material as the component 3; and the assistants include anti-stick agent, drying agent and rheological assistant. The present invention solves the technological problem of making print ink possess several anti-fake effects, and the print ink has obvious anti-fake effect.
Description
Technical field
The present invention relates to a kind of anti-forgery ink that is used for printing, be specifically related to a kind of friction variable color infrared hidden anti-fake print ink.
Background technology
At present, the printing ink of single anti-counterfeiting performance can not satisfy modern false proof requirement, if need multiple anti-fake, then needs repeatedly printing, the production cost height; Anti-counterfeiting characteristic is not obvious, or is easy to copy, or is not easy to popular the discriminating.
Summary of the invention
The invention solves the single technical problem of printing ink antifalse effect in the background technology.
Technical solution of the present invention is:
A kind of friction variable color infrared hidden anti-fake print ink comprises pigment, low-melting ink vehicle, stopping composition and auxiliary agent, and its special character is: described pigment is the pigment that has friction reaction variable color and have infrared hypersorption character; Described low-melting ink vehicle comprises low-melting ink vehicle 1, low-melting ink vehicle 2 and low-melting ink vehicle 3, and described low-melting ink vehicle 1 is a resol, and described connection material 2 is plant oil modified Synolac, and described connection material 3 connects material for gel-type; Described auxiliary agent comprises removes stick, siccative and auxiliary rheological agents.
The resol of above-mentioned low-melting ink vehicle 1 can be the Abietyl modified phenol and the rosin modified phenolic resin of formaldehyde condensation, or Abietyl modified diphenylol propane, or nonyl phenol, or the rosin modified phenolic resin of the mixed phenol of above-mentioned several aldehydes matters and formaldehyde condensation, or the resol resin that in the presence of catalyzer, generates of diphenylol propane and formaldehyde, form through glycerine esterification with the rosin reaction again, or Abietyl modified xylenol glycerine resol, or Abietyl modified diphenylol propane tetramethylolmethane resol etc.; The plant oil modified Synolac of above-mentioned connection material 2 can be modification of flax oil glycerine one a phthalate anhydride Synolac, or modification of flax oil glycerine-isophthalic alkyd resin, or modification of flax oil glycerine-tetramethylolmethane-isophthalic alkyd resin, or modification of flax oil glycerine-TriMethylolPropane(TMP)-phthalate anhydride Synolac, or modification of flax oil glycerine-TriMethylolPropane(TMP)-isophthalic alkyd resin, or modification of flax oil TriMethylolPropane(TMP)-isophthalic anhydride Synolac, or modification of flax oil TriMethylolPropane(TMP)-tetramethylolmethane-phthalate anhydride Synolac, or modification of flax oil TriMethylolPropane(TMP)-tetramethylolmethane-isophthalic alkyd resin, or tung oil-modified above-mentioned Synolac etc.; It can be the Abietyl modified phenol and the rosin modified phenolic resin of formaldehyde condensation that the gel-type of above-mentioned connection material 3 connects material, or the resol that the rosin modified phenolic resin of the mixed phenol of Abietyl modified diphenylol propane or nonyl phenol or aforementioned aldehydes matter and formaldehyde condensation uses can be identical with the resol that low-melting ink vehicle uses, or Abietyl modified diphenylol propane tetramethylolmethane resol etc.; Above-mentioned stopping composition is advisable to adopt colloid calcium or barium sulfate etc.; The above-mentioned stick of removing is advisable to adopt wax etc.; Above-mentioned siccative is advisable to adopt cobalt, manganese, zirconium, plumbous organic acid salt etc.; Above-mentioned auxiliary rheological agents is advisable to adopt anti-sedimentation agent, flocculation agent, dispersion agent or wetting agent and solvent etc.
Also can add fluorescent material in the above-mentioned printing ink.
The weight percent composition of above-mentioned anti-forgery ink prescription can be
Pigment 10%～25%, low-melting ink vehicle 45%～70%, stopping composition 10%～25%, auxiliary agent 5%～10%.
The preferable weight percent composition of above-mentioned anti-forgery ink prescription can be
Pigment 15%～20%, low-melting ink vehicle 45%～55%, stopping composition 15%～20%, auxiliary agent 5%～10%.
The preferable concrete weight percent composition of above-mentioned anti-forgery ink prescription can be
Pigment 15%～20%, low-melting ink vehicle 1 20%～30%, low-melting ink vehicle 2 15%～25%,
Low-melting ink vehicle 3 5%～15%, stopping composition 15%～20%, auxiliary agent 5%～10%.
The preferable weight percent composition of above-mentioned anti-forgery ink prescription can be
Pigment 20%, low-melting ink vehicle 1 23%, low-melting ink vehicle 2 20%,
Low-melting ink vehicle 3 10%, stopping composition 20%, auxiliary agent 7%.
The preferable weight percent composition of above-mentioned anti-forgery ink prescription can be
Pigment 25%, low-melting ink vehicle 1 28%, low-melting ink vehicle 2 15%,
Low-melting ink vehicle 3 10%, stopping composition 20%, auxiliary agent 7%.
The preferable weight percent composition of above-mentioned anti-forgery ink prescription can be
Pigment 15%, low-melting ink vehicle 1 23%, low-melting ink vehicle 2 25%,
Low-melting ink vehicle 3 12%, stopping composition 18%, auxiliary agent 7%.
The present invention has the following advantages:
1. the present invention is mainly used in the false proof of printings such as all kinds of Valued Securities, bill, product external packaging, trade mark, embellish and pressing, and is extremely difficult imitated, and is easy to popular discriminating, and anti-counterfeiting characteristic is obvious, has improved multi-faceted false proof means;
2. the drawback of the printability difference that has fundamentally solved the extruding of microcapsule fearness and caused have good printability and very strong re-workability, and printing effect is good;
3. production cost is significantly less than the market value of domestic and international like product;
4. under visible light, infrared light condition, all anti-counterfeiting characteristic can be arranged, belong to friction variable color infrared hidden anti-fake print ink, have the multiple anti-fake feature;
5. employing the present invention, 10000/hour printings of high-speed offset press, lines are smooth, and the site is full, and scumming is not piled China ink, not dry plate; Dry product becomes redness under the external force friction, printing figure message disappears under 800～1400nm infrared detection condition, realizes stealthy;
6. three kinds of anti-counterfeiting characteristics have compatibility, do not disturb mutually:
1]. need only irreversible variable color just not occur with certain external force friction printed matter by instrument, be complementary color with former printing mass colour, i.e. tool friction variable color feature is convenient to identification, belongs to a line anti-counterfeiting technology;
2]. the printing mass colour is invisible under infrared light, promptly has an infrared stealth feature, needs specific apparatus to detect, and belongs to three-way anti-counterfeiting technology;
3]. add fluorescent material in printing ink, printing fluorescent characteristics can occur under the UV-light of Renminbi detecting instrument, has the instrument recognition feature, belongs to the two wires anti-counterfeiting technology;
Embodiment
The present invention adopts the reactive pigment principle, and this pigment particle size is generally less than 5 μ m, and when being subjected to the external force extruding, the pigment reaction generates and the moving phase material that was complementary color originally, and color changeable effect is very obvious.Thereby this pigment is not disturbed by mechanical force under wet environment, can be used for all kinds of printing press operations, and printability is good.
The present invention mainly is made up of pigment, low-melting ink vehicle, stopping composition and auxiliary agent.
Pigment is the pigment that has friction reaction variable color and have infrared hypersorption character.Have large, medium and small three kinds of spherical particles in 675 times of structure for amplifying of this pigment, big particulate is a sandwich structure, in, small particle is transparent or opaque shape.After certain external force friction, large, medium and small three kinds of spherical particles disappear in the pigment, are amorphous state, are redness.Low-melting ink vehicle is made up of low-melting ink vehicle 1, low-melting ink vehicle 2 and low-melting ink vehicle 3.Low-melting ink vehicle 1 is a resol, requires its ir-absorbance low, and pigment wetting is good, the oxidation filming type drying.Low-melting ink vehicle 2 is plant oil modified Synolac, requires its ir-absorbance to be lower than pigment.Pigment wettability is good.Low-melting ink vehicle 3 is the gel-type low-melting ink vehicle, requires ir-absorbance to be lower than pigment.Wherein, the resol that is used for low-melting ink vehicle 1 can be the Abietyl modified phenol and the rosin modified phenolic resin of formaldehyde condensation, or the mixed phenol of Abietyl modified diphenylol propane or nonyl phenol or above-mentioned several aldehydes matters and the rosin modified phenolic resin of formaldehyde condensation, or the resol resin that in the presence of catalyzer, generates of diphenylol propane and formaldehyde, making through glycerine esterification with the rosin reaction, or Abietyl modified xylenol glycerine resol, or Abietyl modified diphenylol propane tetramethylolmethane resol.
Be used to connect and expect that 2 plant oil modified Synolac can be modification of flax oil glycerine one a phthalate anhydride Synolac, or modification of flax oil glycerine-isophthalic alkyd resin, or modification of flax oil glycerine-tetramethylolmethane-isophthalic alkyd resin, or modification of flax oil glycerine-TriMethylolPropane(TMP)-phthalate anhydride Synolac, or modification of flax oil glycerine-TriMethylolPropane(TMP)-isophthalic alkyd resin, or modification of flax oil TriMethylolPropane(TMP)-isophthalic anhydride Synolac, or modification of flax oil TriMethylolPropane(TMP)-tetramethylolmethane-phthalate anhydride Synolac, or modification of flax oil TriMethylolPropane(TMP)-tetramethylolmethane-isophthalic alkyd resin, or tung oil-modified above-mentioned Synolac.
Be used to connect material 3 gel-types and connect to expect it to be the Abietyl modified phenol and the rosin modified phenolic resin of formaldehyde condensation, or the resol that the rosin modified phenolic resin of the mixed phenol of Abietyl modified diphenylol propane or nonyl phenol or above-mentioned several aldehydes matters and formaldehyde condensation uses can be identical with the resol that low-melting ink vehicle uses, or Abietyl modified diphenylol propane tetramethylolmethane resol.Production technique can be a fatty acid process, also can be ester-interchange method, can be scorification, can be solvent method.
Stopping composition can be colloid calcium, barium sulfate; Removing stick can be wax; Siccative can be siccative such as cobalt, manganese, zirconium, plumbous organic acid salt; Auxiliary rheological agents can be anti-sedimentation agent, flocculation agent, dispersion agent, wetting agent, solvent or the like
The weight percent of the present invention's prescription is formed:
Pigment 8%～30%, low-melting ink vehicle 35%～75%, stopping composition 5%～30%, auxiliary agent 1%～15%.
The preferable weight percent of the present invention's prescription is formed:
Pigment 15%～20%, low-melting ink vehicle 45%～55%, stopping composition 15%～20%, auxiliary agent 5%～10%.
The preferable concrete weight percent of the present invention's prescription is formed:
Pigment 15%～20%, low-melting ink vehicle 1 20%～30%, low-melting ink vehicle 2 15%～25%,
Low-melting ink vehicle 3 5%～15%, stopping composition 15%～20%, auxiliary agent 5%～10%.
Specific embodiment:
Prescription 1: low-melting ink vehicle 1 23%, low-melting ink vehicle 2 20%, low-melting ink vehicle 3 10%,
Pigment 20%, stopping composition 20%, auxiliary agent 7%.
Prescription 2: low-melting ink vehicle 1 28%, low-melting ink vehicle 2 15%, low-melting ink vehicle 3 10%,
Pigment 25%, stopping composition 20%, auxiliary agent 7%.
Prescription 3: low-melting ink vehicle 1 23%, low-melting ink vehicle 2 25%, low-melting ink vehicle 3 12%,
Pigment 15%, stopping composition 18%, auxiliary agent 7%.
Adopt printing, the security feature of the present invention's prescription: the printing of 10000/speed at one hour rating of high-speed offset press, lines are smooth, and the site is full, and scumming is not piled China ink, not dry plate.Dry product becomes redness under the external force friction, printing figure message disappears under 800～1400nm infrared detection condition, realizes stealthy.Printing ink of the present invention can be friction variable color infrared hidden anti-fake print ink, promptly possesses simultaneously under visible light, infrared light condition anti-counterfeiting characteristic is arranged.Add ultraviolet fluorescence powder or materials such as magnetic or infrared up-conversion phosphor in printing ink after, can not destroy original anti-counterfeiting characteristic, this printing ink apparent fluorescence also can occur under the ultraviolet lamp or have magnetic or infrared laser pen irradiation false proof characteristics such as apparent fluorescence spot down; The friction discoloration effect is arranged under visible light, and irreversible; Color cryptomorphic effect is arranged under the infrared light condition.
Claims (9)
1. a friction variable color infrared hidden anti-fake print ink comprises pigment, low-melting ink vehicle, stopping composition and auxiliary agent, it is characterized in that: described pigment is the pigment that has friction reaction variable color and have infrared hypersorption character; Described low-melting ink vehicle comprises low-melting ink vehicle 1, low-melting ink vehicle 2 and low-melting ink vehicle 3, and described low-melting ink vehicle 1 is a resol, and described connection material 2 is plant oil modified Synolac, and described connection material 3 connects material for gel-type; Described auxiliary agent comprises removes stick, siccative and auxiliary rheological agents.
2. friction variable color infrared hidden anti-fake print ink as claimed in claim 1, it is characterized in that: the resol of described low-melting ink vehicle 1 is the Abietyl modified phenol and the rosin modified phenolic resin of formaldehyde condensation, or Abietyl modified diphenylol propane, or nonyl phenol, or the rosin modified phenolic resin of the mixed phenol of above-mentioned several aldehydes matters and formaldehyde condensation, or the resol resin that in the presence of catalyzer, generates of diphenylol propane and formaldehyde, form through glycerine esterification with the rosin reaction again, or Abietyl modified xylenol glycerine resol, or Abietyl modified diphenylol propane tetramethylolmethane resol; The plant oil modified Synolac of described connection material 2 is modification of flax oil glycerine one phthalate anhydride Synolac, or modification of flax oil glycerine-isophthalic alkyd resin, or modification of flax oil glycerine-tetramethylolmethane-isophthalic alkyd resin, or modification of flax oil glycerine-TriMethylolPropane(TMP)-phthalate anhydride Synolac, or modification of flax oil glycerine-TriMethylolPropane(TMP)-isophthalic alkyd resin, or modification of flax oil TriMethylolPropane(TMP)-isophthalic anhydride Synolac, or modification of flax oil TriMethylolPropane(TMP)-tetramethylolmethane-phthalate anhydride Synolac, or modification of flax oil TriMethylolPropane(TMP)-tetramethylolmethane-isophthalic alkyd resin, or tung oil-modified above-mentioned Synolac; It is the Abietyl modified phenol and the rosin modified phenolic resin of formaldehyde condensation that the gel-type of described connection material 3 connects material, or the resol that the rosin modified phenolic resin of the mixed phenol of Abietyl modified diphenylol propane or nonyl phenol or aforementioned aldehydes matter and formaldehyde condensation uses can be identical with the resol that low-melting ink vehicle uses, or Abietyl modified diphenylol propane tetramethylolmethane resol; Described stopping composition is colloid calcium or barium sulfate; The described stick of removing is a wax; Described siccative is cobalt, manganese, zirconium, plumbous organic acid salt; Described auxiliary rheological agents is anti-sedimentation agent, flocculation agent, dispersion agent or wetting agent and solvent.
3. friction variable color infrared hidden anti-fake print ink as claimed in claim 1 or 2 is characterized in that: also comprise fluorescent material in the described printing ink.
4. friction variable color infrared hidden anti-fake print ink as claimed in claim 1 or 2, it is characterized in that: the weight percent of this anti-forgery ink prescription consists of pigment 10%～25%, low-melting ink vehicle 45%～70%, stopping composition 10%～25%, auxiliary agent 5%～10%.
5. friction variable color infrared hidden anti-fake print ink as claimed in claim 4, it is characterized in that: the weight percent of described anti-forgery ink prescription consists of
Pigment 15%～20%, low-melting ink vehicle 45%～55%, stopping composition 15%～20%, auxiliary agent 5%～10%.
6. friction variable color infrared hidden anti-fake print ink as claimed in claim 5, it is characterized in that: the weight percent of described anti-forgery ink prescription consists of
Pigment 15%～20%, low-melting ink vehicle 1 20%～30%, low-melting ink vehicle 2 15%～25%,
Low-melting ink vehicle 3 5%～15%, stopping composition 15%～20%, auxiliary agent 5%～10%.
7. friction variable color infrared hidden anti-fake print ink as claimed in claim 6, it is characterized in that: the weight percent of described anti-forgery ink prescription consists of
Pigment 20%, low-melting ink vehicle 1 23%, low-melting ink vehicle 2 20%,
Low-melting ink vehicle 3 10%, stopping composition 20%, auxiliary agent 7%.
8. friction variable color infrared hidden anti-fake print ink as claimed in claim 6, it is characterized in that: the weight percent of described anti-forgery ink prescription consists of
Pigment 25%, low-melting ink vehicle 1 28%, low-melting ink vehicle 2 15%,
Low-melting ink vehicle 3 10%, stopping composition 20%, auxiliary agent 7%.
9. friction variable color infrared hidden anti-fake print ink as claimed in claim 6, it is characterized in that: the weight percent of described anti-forgery ink prescription consists of
Pigment 15%, low-melting ink vehicle 1 23%, low-melting ink vehicle 2 25%,
Low-melting ink vehicle 3 12%, stopping composition 18%, auxiliary agent 7%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNA031145760A CN1532235A (en) | 2003-03-25 | 2003-03-25 | Friction color changing infrared hidden anti-fake ink |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNA031145760A CN1532235A (en) | 2003-03-25 | 2003-03-25 | Friction color changing infrared hidden anti-fake ink |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1532235A true CN1532235A (en) | 2004-09-29 |
Family
ID=34283999
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNA031145760A Pending CN1532235A (en) | 2003-03-25 | 2003-03-25 | Friction color changing infrared hidden anti-fake ink |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1532235A (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104231747A (en) * | 2013-06-07 | 2014-12-24 | 上海造币有限公司 | Pad printing ink and safety products |
| CN106032079A (en) * | 2015-03-20 | 2016-10-19 | 浙江汇锋新材料有限公司 | Camouflage cloth for preventing recognition by infrared ray |
| CN108364055A (en) * | 2018-02-09 | 2018-08-03 | 上海川光信息科技有限公司 | A kind of multidimensional spectrum bar code ink |
| CN106367983B (en) * | 2015-07-23 | 2019-01-08 | 浙江汇锋新材料股份有限公司 | A kind of aqueous, environmental protective printing colour camoufague cloth and its manufacturing method |
| CN110223596A (en) * | 2019-07-09 | 2019-09-10 | 深圳大学 | Antifalsification label based on stress irradiance |
| CN114634735A (en) * | 2022-04-27 | 2022-06-17 | 广州市麦修拓包装设备有限公司 | Ink slurry for small character code spraying, preparation method thereof and ink |
-
2003
- 2003-03-25 CN CNA031145760A patent/CN1532235A/en active Pending
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104231747A (en) * | 2013-06-07 | 2014-12-24 | 上海造币有限公司 | Pad printing ink and safety products |
| CN104231747B (en) * | 2013-06-07 | 2017-02-08 | 上海造币有限公司 | Pad printing ink and safety products |
| CN106032079A (en) * | 2015-03-20 | 2016-10-19 | 浙江汇锋新材料有限公司 | Camouflage cloth for preventing recognition by infrared ray |
| CN106032079B (en) * | 2015-03-20 | 2018-07-20 | 浙江汇锋新材料股份有限公司 | A kind of anti-infrared identification colour camoufague cloth |
| CN106367983B (en) * | 2015-07-23 | 2019-01-08 | 浙江汇锋新材料股份有限公司 | A kind of aqueous, environmental protective printing colour camoufague cloth and its manufacturing method |
| CN108364055A (en) * | 2018-02-09 | 2018-08-03 | 上海川光信息科技有限公司 | A kind of multidimensional spectrum bar code ink |
| CN108364055B (en) * | 2018-02-09 | 2021-06-04 | 苗鹏 | Printing ink for multi-dimensional spectrum bar code |
| CN110223596A (en) * | 2019-07-09 | 2019-09-10 | 深圳大学 | Antifalsification label based on stress irradiance |
| CN110223596B (en) * | 2019-07-09 | 2022-02-22 | 深圳大学 | Anti-counterfeit label based on stress luminescence |
| CN114634735A (en) * | 2022-04-27 | 2022-06-17 | 广州市麦修拓包装设备有限公司 | Ink slurry for small character code spraying, preparation method thereof and ink |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101284965B (en) | Water-based intaglio ink equal to plate engraving ink and uses thereof | |
| EP3380331B1 (en) | Printed watermark | |
| CN1138893C (en) | Valuable document | |
| CN107532030B (en) | Fine particle dispersion, process for producing the same, forgery-preventing ink composition, and forgery-preventing printed matter | |
| KR20150118093A (en) | Method for printing multi-characteristic intaglio features | |
| CN1532235A (en) | Friction color changing infrared hidden anti-fake ink | |
| CN102643577A (en) | Environment-friendly printing ink suitable for high speed rotary printing | |
| CN107429097B (en) | Near-infrared absorbing fine particle dispersion, method for producing same, forgery-preventing ink composition, and forgery-preventing printed matter | |
| CN110452580A (en) | A kind of anti-forgery ink and preparation method thereof with particular spectral lines feature | |
| CN115244145B (en) | UV-VIS radiation curable security ink | |
| CN107429098B (en) | Near-infrared absorbing fine particle dispersion, method for producing same, forgery-preventing ink composition, and forgery-preventing printed matter | |
| CN1712466A (en) | Magnetic block printing ink | |
| CN102648252A (en) | Intaglio printing ink | |
| CN1923921A (en) | Noctilucence printing ink | |
| CN101033351A (en) | High speed coating carbon belt printing ink material and producing method thereof | |
| CN1083502A (en) | Anti-forgery colour printing ink | |
| CN1569981A (en) | Multiple fake-proof print oil with memory code and its checking method | |
| CN1616566A (en) | Coating oil fo alcohol soluble intaglio paper box pre-printing | |
| CN1483893A (en) | Anti-counterfeit fabre. anti-counterfeit anti-altering paper made from same and mfg method thereof | |
| EP1565323B1 (en) | Safety element exhibiting properties activable by energy supply | |
| US10576773B2 (en) | Security element, method for producing the same and value document | |
| Princi | Handbook of polymers in paper conservation | |
| CN2835324Y (en) | Dedicated paper for anti-fake postage ticket with phosphor dot | |
| CN103694785A (en) | Offset print colorless irradiating luminescent anti-forgery ink and preparation method thereof | |
| CN1424369A (en) | Erase color variable ink |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C12 | Rejection of a patent application after its publication | ||
| RJ01 | Rejection of invention patent application after publication |