CN1528719A - Safety firecracker compound containing perchlorate - Google Patents
Safety firecracker compound containing perchlorate Download PDFInfo
- Publication number
- CN1528719A CN1528719A CNA2003101104067A CN200310110406A CN1528719A CN 1528719 A CN1528719 A CN 1528719A CN A2003101104067 A CNA2003101104067 A CN A2003101104067A CN 200310110406 A CN200310110406 A CN 200310110406A CN 1528719 A CN1528719 A CN 1528719A
- Authority
- CN
- China
- Prior art keywords
- perchlorate
- powder
- firecracker
- potassium
- safety
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- VLTRZXGMWDSKGL-UHFFFAOYSA-M perchlorate Inorganic materials [O-]Cl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-M 0.000 title claims abstract description 23
- VLTRZXGMWDSKGL-UHFFFAOYSA-N perchloric acid Chemical compound OCl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-N 0.000 title claims abstract description 23
- 150000001875 compounds Chemical class 0.000 title 1
- 239000000843 powder Substances 0.000 claims abstract description 19
- AXZAYXJCENRGIM-UHFFFAOYSA-J dipotassium;tetrabromoplatinum(2-) Chemical group [K+].[K+].[Br-].[Br-].[Br-].[Br-].[Pt+2] AXZAYXJCENRGIM-UHFFFAOYSA-J 0.000 claims abstract description 12
- 229910001487 potassium perchlorate Inorganic materials 0.000 claims abstract description 12
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims abstract description 8
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims abstract description 8
- 235000019362 perlite Nutrition 0.000 claims abstract description 8
- 239000010451 perlite Substances 0.000 claims abstract description 8
- GDDNTTHUKVNJRA-UHFFFAOYSA-N 3-bromo-3,3-difluoroprop-1-ene Chemical compound FC(F)(Br)C=C GDDNTTHUKVNJRA-UHFFFAOYSA-N 0.000 claims abstract description 4
- OOULUYZFLXDWDQ-UHFFFAOYSA-L barium perchlorate Chemical compound [Ba+2].[O-]Cl(=O)(=O)=O.[O-]Cl(=O)(=O)=O OOULUYZFLXDWDQ-UHFFFAOYSA-L 0.000 claims abstract description 4
- 239000003814 drug Substances 0.000 claims description 17
- 239000000203 mixture Substances 0.000 claims description 8
- 239000005864 Sulphur Substances 0.000 claims description 7
- 239000004411 aluminium Substances 0.000 claims description 7
- 229910052782 aluminium Inorganic materials 0.000 claims description 7
- VKJKEPKFPUWCAS-UHFFFAOYSA-M potassium chlorate Chemical compound [K+].[O-]Cl(=O)=O VKJKEPKFPUWCAS-UHFFFAOYSA-M 0.000 abstract description 11
- 239000000126 substance Substances 0.000 abstract description 3
- SHFGJEQAOUMGJM-UHFFFAOYSA-N dialuminum dipotassium disodium dioxosilane iron(3+) oxocalcium oxomagnesium oxygen(2-) Chemical compound [O--].[O--].[O--].[O--].[O--].[O--].[O--].[O--].[Na+].[Na+].[Al+3].[Al+3].[K+].[K+].[Fe+3].[Fe+3].O=[Mg].O=[Ca].O=[Si]=O SHFGJEQAOUMGJM-UHFFFAOYSA-N 0.000 abstract 1
- 239000011593 sulfur Substances 0.000 abstract 1
- 229910052717 sulfur Inorganic materials 0.000 abstract 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 238000000354 decomposition reaction Methods 0.000 description 3
- 229910052760 oxygen Inorganic materials 0.000 description 3
- 239000001301 oxygen Substances 0.000 description 3
- 238000004880 explosion Methods 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000003750 conditioning effect Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000003721 gunpowder Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 230000002829 reductive effect Effects 0.000 description 1
Landscapes
- Finger-Pressure Massage (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
Abstract
The invention relates to a perchlorate-containing safe firecracker powder, combined of perchlorate, aluminum powder, sulfur and perlite powder, where the perchlorate is potassium perchlorate, barium perchlorate, ammonium perchlorate, or their optional combination. If adopting a perchlorate, first choose potassium perchlorate. Its formula is simple, its components are little, its chemical stability and safety are good, without potassium chlorate. It has advantages of low mechanical sensibility and high safety, good bang rate and sound-level value, etc. It is an ideal safe firecracker powder.
Description
Technical field
The present invention relates to a kind of safe firecracker medicine, particularly relate to a kind of safe firecracker medicine that contains perchlorate.
Background technology
In the prior art, Potcrate is because of its oxygen level height, decomposition temperature is low, relative price is low, and after combustiblematerials mixed, blast performance was good, and be widely used in the firework industry, afterwards susceptibility is high because Potcrate mixes with combustiblematerials, and often careless manipulation and cause explosion hazard aborning causes tremendous loss to people's lives and properties.In order to ensure the safety of people's lives and properties, State Council has issued " No. 52 " file in 2002, prohibite in the fireworks and firecrackers industry and use oxymuriate.Though it is definite fully that the time that carry out and implement various places does not also have, the dynamics of forbidding is not completely unified yet, and it is the fact that needn't doubt that oxymuriate withdraws from firework system industry.
Summary of the invention
The objective of the invention is to overcome above-mentioned deficiency, a kind of good firecracker medicine that contains perchlorate of safety performance simple, that composition is few of filling a prescription is provided.
For achieving the above object, the present invention carries out the formula of medicine adjustment and improved on prior art; A kind of safe firecracker medicine that contains perchlorate is characterized in that described safe firecracker medicine is to be combined by perchlorate, aluminium powder, sulphur and four kinds of compositions of perlite powder, and the weight proportion of its component is as follows:
Perchlorate 300-600 gram sulphur 10-100 gram
Aluminium powder 100-350 gram perlite powder 150-350 gram
Described perchlorate is potassium perchlorate or barium perchlorate or ammoniumper chlorate or their arbitrary combination.
From above-mentioned prescription as can be seen, safe firecracker medicine is simply to replace oxymuriate with perchlorate to make oxygenant, in actual production process, in the component as adopt a kind of perchlorate, first-selected potassium perchlorate.Potassium perchlorate except have with the many similar oxidation susceptibilities of Potcrate, the temperature required Potcrate that the is higher than when difference of it and Potcrate maximum just is that potassium perchlorate decomposes, decomposition is heat absorption, oxygen discharging speed is also slow; But its oxygen level also is higher than Potcrate, and this is also just meeting the principle of firework industry " safety first, quality are last ".
Adopt potassium perchlorate to replace Potcrate as oxygenant, the decomposition temperature height of potassium perchlorate, chemical stability is better than Potcrate, to the susceptibility of machinery less than the Potcrate height; Aluminium powder is a light metal, can improve quick-fried temperature to improve the brisance and the sound.Sulphur is to make reductive agent and combustiblematerials; Perlite powder is a weighting agent, is the conditioning agent of medicine density, makes the powder charge thing loose, in order to igniting.
The present invention compared with prior art, safety firecracker medicine only has only four kinds of compositions to form, so prescription simply, component is few.Adopt perchlorate to replace Potcrate as oxygenant, chemical stability is good, improved the safety performance of firecracker gunpowder greatly, safety firecracker medicine is spent quick-fried measuring station complete detection through province, set off the requirement that every indexs such as explosion sound rate, sound level all meet national standard and State Council " 52 " number literary composition from safety performance, the product of medicine, thus practical.
Embodiment
A kind of safe firecracker medicine that contains perchlorate is to be combined by perchlorate, aluminium powder, sulphur and four kinds of compositions of perlite powder, and perchlorate is potassium perchlorate or barium perchlorate or ammoniumper chlorate or their arbitrary combination.Making the special dress of firecracker product the earth with potassium perchlorate as oxygenant below, red (specification: 37 * 6.5mm) is that present invention is described for example.
Press the firecracker mixture with 2 jin of 5 Qian Weiyi base, meter 1025 grams can be adorned 38 medicine cakes (each cake has 391 bobbins approximately).Get potassium perchlorate 450 gram, sulphur 100 grams, aluminium powder 275 grams and perlite powder 200 grams mix, adopts traditional with medicine, powder charge, insert and draw, seal, tie the whip method, the special red firecracker of the earth of adorning.
Claims (1)
1, a kind of safe firecracker medicine that contains perchlorate is characterized in that:
A, the described safe firecracker medicine that contains perchlorate are to be combined by perchlorate, aluminium powder, sulphur and four kinds of compositions of perlite powder, and the weight proportion of its component is as follows:
Perchlorate 300-600 gram sulphur 10-100 gram
Aluminium powder 100-350 gram perlite powder 150-350 gram;
B, described perchlorate are potassium perchlorate or barium perchlorate or ammoniumper chlorate or their arbitrary combination.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200310110406 CN1228281C (en) | 2003-10-09 | 2003-10-09 | Safety firecracker compound containing perchlorate |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200310110406 CN1228281C (en) | 2003-10-09 | 2003-10-09 | Safety firecracker compound containing perchlorate |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1528719A true CN1528719A (en) | 2004-09-15 |
| CN1228281C CN1228281C (en) | 2005-11-23 |
Family
ID=34304670
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 200310110406 Expired - Fee Related CN1228281C (en) | 2003-10-09 | 2003-10-09 | Safety firecracker compound containing perchlorate |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1228281C (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102838434A (en) * | 2012-08-06 | 2012-12-26 | 黄锐 | Reducing agent of firecrackers and fireworks |
| CN106927984A (en) * | 2017-03-15 | 2017-07-07 | 江西佳联科技有限公司 | A kind of powder of firecracker containing active constituent |
| CN110498723A (en) * | 2019-06-22 | 2019-11-26 | 中国人民解放军69080部队 | Ammonium dihydrogen phosphate new application, the smoke agent and preparation method for adding it |
| CN110498724A (en) * | 2019-06-22 | 2019-11-26 | 中国人民解放军69080部队 | Reduce smoke composition, the preparation method and application of initial reaction temperature |
-
2003
- 2003-10-09 CN CN 200310110406 patent/CN1228281C/en not_active Expired - Fee Related
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102838434A (en) * | 2012-08-06 | 2012-12-26 | 黄锐 | Reducing agent of firecrackers and fireworks |
| CN102838434B (en) * | 2012-08-06 | 2015-03-25 | 黄锐 | Reducing agent of firecrackers and fireworks |
| CN106927984A (en) * | 2017-03-15 | 2017-07-07 | 江西佳联科技有限公司 | A kind of powder of firecracker containing active constituent |
| CN110498723A (en) * | 2019-06-22 | 2019-11-26 | 中国人民解放军69080部队 | Ammonium dihydrogen phosphate new application, the smoke agent and preparation method for adding it |
| CN110498724A (en) * | 2019-06-22 | 2019-11-26 | 中国人民解放军69080部队 | Reduce smoke composition, the preparation method and application of initial reaction temperature |
| CN110498723B (en) * | 2019-06-22 | 2021-01-29 | 中国人民解放军69080部队 | New application of ammonium dihydrogen phosphate, smoke agent added with ammonium dihydrogen phosphate and preparation method of smoke agent |
| CN110498724B (en) * | 2019-06-22 | 2021-01-29 | 中国人民解放军69080部队 | Fuming composition capable of reducing initial reaction temperature, preparation method and application |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1228281C (en) | 2005-11-23 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| ASS | Succession or assignment of patent right |
Owner name: HUNAN XIELI REAL ESTATE DEVELOPMENT ( GROUP ) CO. Free format text: FORMER OWNER: YI XIANYUN Effective date: 20070720 |
|
| C41 | Transfer of patent application or patent right or utility model | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20070720 Address after: Tiantai road CUSTOMS BUILDING 412207 Zhuzhou City in Hunan province Tianyuan District 6 Building Patentee after: Hunan synergy real estate development (Group) Co., Ltd. Address before: 412207 easy village group, Qingshui village, South Bridge Town, Hunan, Liling Patentee before: Yi Xianyun |
|
| C17 | Cessation of patent right | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20051123 Termination date: 20091109 |