CN1523138A - Process for making plastic surface by electroplating - Google Patents
Process for making plastic surface by electroplating Download PDFInfo
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- CN1523138A CN1523138A CNA031046479A CN03104647A CN1523138A CN 1523138 A CN1523138 A CN 1523138A CN A031046479 A CNA031046479 A CN A031046479A CN 03104647 A CN03104647 A CN 03104647A CN 1523138 A CN1523138 A CN 1523138A
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Abstract
The present invention relates to an electroplating process on plastic surface. It is applicable for forming a multiple metal layer on surface of plastic element. Said process includes the following steps: firstly, forming an electroconductive medium on surface of plastic element, then adopting electrolysis-free electroplating mode to form at least one chemical metal layer (for example chemical copper layer and chemical nickel layer) on surface of plastic element, then regulating material characteristics of surface of plastic element and adopting electrolytic electroplating mode to form at least one electroplated metal layer (for example electroplated copper layer, electroplated nickel layer and electroplated chrome layer). Said electroplated metal layer has high structure strength and high conductivity.
Description
Technical field
The invention relates to a kind of plastic surface galvanizing manufacture craft, and particularly relevant for a kind of plastic surface galvanizing manufacture craft of integrating single face plating and two-sided plating manufacture craft.
Background technology
With regard to the process for treating surface of present plastic components, for the surface at plastic components forms a metal level, beautifying the appearance of plastic components, or allow the surface of plastic components have the effect of metallic shield, known technology roughly is to adopt atomized spray painting or galvanized mode to reach.Plating is broadly divided into " metallide " and reaches " electroless plating (claiming chemical plating again) " two kinds.At first, the principle of metallide is with the metal ion in the metal salt solution, and reception adds electronics and becomes metallics, and is attached to the surface of desire plating thing.In addition, electroless plating then is to utilize the reductive agent that is added, and makes metal ion be reduced into metallics, and is attached to the surface of desire plating thing.It should be noted that, with regard to known plastic surface galvanizing manufacture craft, the common single face that has is electroplated manufacture craft and two-sided plating manufacture craft, and single face plating manufacture craft is to utilize the principle of electroless plating, in order to metal level is formed at the local surfaces of plastic components, two-sided plating manufacture craft then is to utilize the principle of metallide, in order to the multiple layer metal layer is formed at all surfaces of plastic components.
Fig. 1 is that known a kind of single face is electroplated the schema of manufacture craft.Please refer to shown in Figure 1, for the surface at a plastic components forms a multi-metal layer, with regard to single face is electroplated manufacture craft, shown in step 10, at first in the mode of sprayed coating, form the local surfaces of a conducting medium, make follow-up metal level easily in this local surfaces that is attached to plastic components in plastic components.Then, shown in step 12,, form a chemical copper layer in the surface of plastic components in the mode of electroless plating.At last, shown in step 14,, form the surface of a chemical nickel in the chemical copper layer again in the mode of electroless plating.
It should be noted that, because it is to utilize the distributed areas of conducting medium that single face is electroplated manufacture craft, define the desire plating surface of plastic components, but, single face has the advantage of parcel plating so electroplating manufacture craft, but it is thinner to be subject to its metal level that can form, and the structural strength of thin metal level is relatively poor, and its resistance value also higher relatively (about 1～5 Europe mother (ohm)), this will be unfavorable for plastic components its for electromagnetic metallic shield ability.
Fig. 2 is the schema of known a kind of two-sided plating manufacture craft.Please refer to shown in Figure 2, for the surface at a plastic components forms a multi-metal layer, with regard to two-sided plating manufacture craft, shown in step 20, at first pre-electroplating treatment manufacture craft (for example degreasing, alligatoring, neutralization, activation and speedization etc.) is carried out on the surface of plastic components, make the surface of plastic components for metallics, have good adhesive ability, be beneficial to adhering to of follow-up metal level.Then, shown in step 22,, form the surface of an electroless nickel layer, in order to as Seed Layer (seed layer) in plastic components in the mode of electroless plating.Afterwards, shown in step 24, be Seed Layer with above-mentioned electroless nickel layer, again in the mode of metallide, form the surface of a copper electroplating layer in electroless nickel layer.Then, shown in step 26,, form the surface of an electroless nickel layer in copper electroplating layer equally again in the mode of metallide.At last, shown in step 28, also can be again form the surface of an electrodeposited chromium layers in electroless nickel layer in the mode of metallide.
It should be noted that, because two-sided plating manufacture craft mainly is to utilize the mode of metallide, can form compact structure and thicker electroplated metal layer, make these electroplated metal layers have preferable structural strength and conduction value, and make the surface of plastic components can present preferable outward appearance.Yet because two-sided plating manufacture craft must be through an alligatoring manufacture craft, it mainly is with in the whole immersion acid solution of plastic components, with the surface of alligatoring plastic components, so will destroy the primary characteristic (for example toughness) of the material of plastic components.In addition, same owing to above-mentioned alligatoring manufacture craft, two-sided plating also has more a shortcoming, promptly is to reach the optionally effect of the local surfaces of electroplating plastic element.
Summary of the invention
Therefore, purpose of the present invention is providing a kind of plastic surface galvanizing manufacture craft exactly, in order to the local surfaces of electroplating plastic element optionally, and the electroplated metal layer that can make the surface of plastic components has high structural strength and high conductance, can keep the primary characteristic of the material of plastic components simultaneously.
For reaching above-mentioned purpose of the present invention, the present invention proposes a kind of plastic surface galvanizing manufacture craft, be applicable to and form a multi-metal layer on the surface of a plastic components, at first form the surface of a conducting medium in plastic components, follow mode with electroless plating, form a chemical copper layer in the surface of plastic components, and, form the surface of an electroless nickel layer in the chemical copper layer equally in the mode of electroless plating.Then, adjust the material behavior on the surface of plastic components, again in the mode of metallide, form the surface of a copper electroplating layer in electroless nickel layer, and same mode with metallide, form the surface of an electroless nickel layer, can form the surface of an electrodeposited chromium layers equally in the mode of metallide at last in electroless nickel layer in copper electroplating layer.
Described according to preferred embodiment of the present invention, above-mentioned plastic surface galvanizing manufacture craft, it is when forming conducting medium in plastic components surperficial, and conducting medium is formed at the surface of plastic components in the mode of sprayed coating.In addition, conducting medium is the interface promoting agent for example, and the composition of interface promoting agent mainly comprises dodecyl sodium sulfate.
Described according to preferred embodiment of the present invention, above-mentioned plastic surface galvanizing manufacture craft, when being to adjust the material behavior on surface of plastic components, and make the surface of plastic components have negative charge relatively, and for example be to make the surface of plastic components accumulate relatively through perfluoro-compound negative charge is arranged.
Based on above-mentioned, the present invention is the mode by an adjustment material behavior, known single face be can integrate effectively and manufacture craft and two-sided plating manufacture craft electroplated, die the present invention except that the advantage of the parcel plating that can reach single face plating manufacture craft, and can have the high structural strength and the high conductance of the formed electroplated metal layer of two-sided plating manufacture craft concurrently.In addition, plastic components still can keep the primary characteristic (for example toughness) of its material.
For above-mentioned purpose of the present invention, feature and advantage can be become apparent, a preferred embodiment cited below particularly, and cooperate appended graphicly, elaborate.
Description of drawings
Fig. 1 is that known a kind of single face is electroplated the schema of manufacture craft;
Fig. 2 is the schema of known a kind of two-sided plating manufacture craft; And
Fig. 3 is according to the schema of the plastic surface galvanizing manufacture craft of a preferred embodiment of the present invention.
Embodiment
Fig. 3 illustrates the schema according to the plastic surface galvanizing manufacture craft of a preferred embodiment of the present invention.Please refer to shown in Figure 3ly, plastic surface galvanizing manufacture craft of the present invention is applicable to and forms a multi-metal layer on the surface of a plastic components.Shown in step 100, at first form the surface of a conducting medium in plastic components, it for example is mode with sprayed coating, conducting medium is formed at the desire plating surface of plastic components, and this conducting medium for example is the interface promoting agent, this interface promoting agent for example be dodecyl sodium sulfate (Sodium Dodecyl Sulfate, SDS), with so that the desire plating surface of plastic material is hydrophilic state, be beneficial to the desire plating surface that follow-up metallics is easily attached to plastic components.Then, shown in step 102,, form a chemical copper layer in the surface of plastic components in the mode of electroless plating.Afterwards, shown in step 104, the mode with electroless plating forms the surface of a chemical nickel in the chemical copper layer again.Then, shown in step 106, adjust the material behavior on the desire plating surface of plastic components, for example make the desire plating surface of plastic components have negative charge relatively, and its inflation method is for example utilized fluorochemical (Fluoride) to make the desire plating surface of plastic components accumulate relatively negative charge is arranged.Then, shown in step 108,, form the surface of a copper electroplating layer in electroless nickel layer in the mode of metallide.Then, shown in step 110,, form the surface of an electroless nickel layer in copper electroplating layer in the mode of metallide.At last, shown in step 112, can be again form the surface of an electrodeposited chromium layers in electroless nickel layer in the mode of metallide.
The leading portion manufacture craft (step 100, step 102 and step 104) of plastic surface galvanizing manufacture craft of the present invention can be at the local electroless plating of electing property of the surface of plastic components, afterwards shown in step 106, more adjust the material behavior on the surface of plastic components, make the desire plating surface of plastic components have negative charge relatively, make back segment manufacture craft (step 108, step 110 and step 112) carry out metallide on the desire plating surface of plastic components easily.Therefore, plastic surface galvanizing manufacture craft of the present invention is to integrate known single face to electroplate manufacture craft and two-sided plating manufacture craft.Thus, plastic surface galvanizing manufacture craft of the present invention more can have the high structural strength and the high conductance (resistance value is lower than 0.1 Europe mother (ohm)) of the formed electroplated metal layer of two-sided plating manufacture craft concurrently except that the advantage of the parcel plating that can reach single face plating manufacture craft.It should be noted that because plastic surface galvanizing manufacture craft of the present invention need not carried out the alligatoring manufacture craft of known two-sided plating manufacture craft, so can keep the primary characteristic (for example toughness) of the material of plastic components.
In preferred embodiment of the present invention, at first forming a conducting medium after the surface of plastic components, then form a chemical copper layer and an electroless nickel layer in regular turn, and after the material behavior on the surface of adjusting plastic components, form a copper electroplating layer, an electroless nickel layer and an electrodeposited chromium layers more in regular turn.Yet, being familiar with this operator should know by inference, the present invention is forming a conducting medium behind the desire plating surface of plastic components, mode that can also electroless plating, optionally form the desire plating surface of one or more layers chemical metal layer in plastic components, and after the material behavior on the desire plating surface of adjusting plastic components, mode that more can electroless plating optionally forms one or more layers electroplated metal layer.
In sum, plastic surface galvanizing manufacture craft of the present invention is the step by an adjustment material behavior, electroplates manufacture craft and two-sided plating manufacture craft so can integrate known single face effectively.Therefore, the present invention more can have the high structural strength and the high conductance of the electroplated metal layer of two-sided plating manufacture craft concurrently except that the advantage of the parcel plating that can reach single face plating manufacture craft, keep the primary characteristic of the material of plastic components simultaneously.
Though the present invention with a preferred embodiment openly as above; right its is not in order to limiting the present invention, anyly is familiar with this operator, without departing from the spirit and scope of the present invention; when can doing a little change and retouching, so protection scope of the present invention is as the criterion when looking claims person of defining.
Claims (12)
1, a kind of plastic surface galvanizing manufacture craft is applicable on the surface of a plastic components to form a multi-metal layer that it is characterized in that: this plastic surface galvanizing manufacture craft comprises the following steps: at least
(a) form a conducting medium in the surface of this plastic components;
(b), form a chemical copper layer in the surface of this plastic components in the mode of electroless plating;
(c), form the surface of an electroless nickel layer in this chemical copper layer in the mode of electroless plating;
(d) adjust the material behavior on the surface of this plastic components;
(e), form the surface of a copper electroplating layer in this electroless nickel layer in the mode of metallide;
(f), form the surface of an electroless nickel layer in this copper electroplating layer in the mode of metallide; And
(g), form the surface of an electrodeposited chromium layers in this electroless nickel layer in the mode of metallide.
2, plastic surface galvanizing manufacture craft as claimed in claim 1 is characterized in that: in step (a), this conducting medium is formed at the surface of this plastic components in the mode of sprayed coating.
3, plastic surface galvanizing manufacture craft as claimed in claim 1 is characterized in that: this conducting medium is the interface promoting agent.
4, plastic surface galvanizing manufacture craft as claimed in claim 3, it is characterized in that: the composition of this interface promoting agent mainly comprises dodecyl sodium sulfate.
5, plastic surface galvanizing manufacture craft as claimed in claim 1 is characterized in that: in step (d), comprise making the surface of this plastic components have negative charge relatively.
6, plastic surface galvanizing manufacture craft as claimed in claim 5 is characterized in that: in step (d), comprise that making the surface of this plastic components accumulate relatively through perfluoro-compound has negative charge.
7, a kind of plastic surface galvanizing manufacture craft is characterized in that: be applicable on the surface of a plastic components to form a multi-metal layer, this plastic surface galvanizing manufacture craft comprises the following steps: at least
(a) form a conducting medium in the surface of this plastic components;
(b), form the surface of at least one chemical metal layer in this plastic components in the mode of electroless plating;
(c) adjust the material behavior on the surface of this plastic components; And
(d), form the surface of at least one electroplated metal layer in this chemical metal layer in the mode of metallide.
8, plastic surface galvanizing manufacture craft as claimed in claim 7 is characterized in that: in step (a), this conducting medium is formed at the surface of this plastic components in the mode of sprayed coating.
9, plastic surface galvanizing manufacture craft as claimed in claim 7 is characterized in that: this conducting medium is the interface promoting agent.
10, plastic surface galvanizing manufacture craft as claimed in claim 9, it is characterized in that: the composition of this interface promoting agent mainly comprises dodecyl sodium sulfate.
11, plastic surface galvanizing manufacture craft as claimed in claim 7 is characterized in that: in step (c), comprise making the surface of this plastic components have negative charge relatively.
12, plastic surface galvanizing manufacture craft as claimed in claim 11 is characterized in that: in step (c), comprise that making the surface of this plastic components accumulate relatively through perfluoro-compound has negative charge.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 03104647 CN1238572C (en) | 2003-02-19 | 2003-02-19 | Process for making plastic surface by electroplating |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 03104647 CN1238572C (en) | 2003-02-19 | 2003-02-19 | Process for making plastic surface by electroplating |
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| CN1523138A true CN1523138A (en) | 2004-08-25 |
| CN1238572C CN1238572C (en) | 2006-01-25 |
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| CN 03104647 Expired - Fee Related CN1238572C (en) | 2003-02-19 | 2003-02-19 | Process for making plastic surface by electroplating |
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Cited By (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100460569C (en) * | 2005-12-20 | 2009-02-11 | 天津三五二二工厂 | Solution for plating conductive coating |
| CN101113527B (en) * | 2006-07-28 | 2011-01-12 | 比亚迪股份有限公司 | Electroplating product and method for preparing same |
| CN101613862B (en) * | 2008-06-27 | 2011-07-27 | 深圳富泰宏精密工业有限公司 | Plastic surface processing method |
| CN102277569A (en) * | 2010-01-15 | 2011-12-14 | 比亚迪股份有限公司 | Plastic product preparation method and plastic product |
| CN102296331A (en) * | 2010-06-24 | 2011-12-28 | 詹涂城 | Making method for hierarchic visual effect of plastic electroplating |
| CN102418091A (en) * | 2010-04-14 | 2012-04-18 | 比亚迪股份有限公司 | Plastic product and preparation method for same |
| CN103802576A (en) * | 2012-11-05 | 2014-05-21 | 上海英雄礼赞文具礼品有限公司 | Laser engraving gold-plating varnishing process |
| US8841000B2 (en) | 2010-08-19 | 2014-09-23 | Byd Company Limited | Metalized plastic articles and methods thereof |
| US8920936B2 (en) | 2010-01-15 | 2014-12-30 | Byd Company Limited | Metalized plastic articles and methods thereof |
| US9103020B2 (en) | 2010-02-26 | 2015-08-11 | Byd Company Limited | Metalized plastic articles and methods thereof |
| CN105937044A (en) * | 2015-03-06 | 2016-09-14 | 丰田合成株式会社 | Plating method |
| CN107620095A (en) * | 2017-09-29 | 2018-01-23 | 佛山市春暖花开科技有限公司 | A kind of composite-layer metal electroplating process |
| CN110996639A (en) * | 2019-11-15 | 2020-04-10 | 上海阿莱德实业股份有限公司 | Low-cost non-metal shielding cover and preparation method thereof |
| CN111996567A (en) * | 2020-09-03 | 2020-11-27 | 深圳市生利科技有限公司 | Chromium plating process for PA plastic material and product thereof |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101555614B (en) * | 2008-04-11 | 2011-03-30 | 深圳富泰宏精密工业有限公司 | Plastic surface galvanizing method |
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2003
- 2003-02-19 CN CN 03104647 patent/CN1238572C/en not_active Expired - Fee Related
Cited By (23)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100460569C (en) * | 2005-12-20 | 2009-02-11 | 天津三五二二工厂 | Solution for plating conductive coating |
| CN101113527B (en) * | 2006-07-28 | 2011-01-12 | 比亚迪股份有限公司 | Electroplating product and method for preparing same |
| CN101613862B (en) * | 2008-06-27 | 2011-07-27 | 深圳富泰宏精密工业有限公司 | Plastic surface processing method |
| CN102277569A (en) * | 2010-01-15 | 2011-12-14 | 比亚迪股份有限公司 | Plastic product preparation method and plastic product |
| CN102277569B (en) * | 2010-01-15 | 2013-04-10 | 比亚迪股份有限公司 | Plastic product preparation method and plastic product |
| US10392708B2 (en) | 2010-01-15 | 2019-08-27 | Byd Company Limited | Metalized plastic articles and methods thereof |
| US9435035B2 (en) | 2010-01-15 | 2016-09-06 | Byd Company Limited | Metalized plastic articles and methods thereof |
| US8920936B2 (en) | 2010-01-15 | 2014-12-30 | Byd Company Limited | Metalized plastic articles and methods thereof |
| US9103020B2 (en) | 2010-02-26 | 2015-08-11 | Byd Company Limited | Metalized plastic articles and methods thereof |
| CN102418091A (en) * | 2010-04-14 | 2012-04-18 | 比亚迪股份有限公司 | Plastic product and preparation method for same |
| CN102418091B (en) * | 2010-04-14 | 2014-02-12 | 比亚迪股份有限公司 | Plastic product and preparation method for same |
| CN102296331A (en) * | 2010-06-24 | 2011-12-28 | 詹涂城 | Making method for hierarchic visual effect of plastic electroplating |
| US8846151B2 (en) | 2010-08-19 | 2014-09-30 | Byd Company Limited | Metalized plastic articles and methods thereof |
| US8841000B2 (en) | 2010-08-19 | 2014-09-23 | Byd Company Limited | Metalized plastic articles and methods thereof |
| US9770887B2 (en) | 2010-08-19 | 2017-09-26 | Byd Company Limited | Metalized plastic articles and methods thereof |
| CN103802576B (en) * | 2012-11-05 | 2018-05-08 | 上海英雄礼赞文具礼品有限公司 | A kind of gold-plated Lacquer finish technique of laser carving |
| CN103802576A (en) * | 2012-11-05 | 2014-05-21 | 上海英雄礼赞文具礼品有限公司 | Laser engraving gold-plating varnishing process |
| CN105937044A (en) * | 2015-03-06 | 2016-09-14 | 丰田合成株式会社 | Plating method |
| CN105937044B (en) * | 2015-03-06 | 2018-09-14 | 丰田合成株式会社 | Coating method |
| CN107620095A (en) * | 2017-09-29 | 2018-01-23 | 佛山市春暖花开科技有限公司 | A kind of composite-layer metal electroplating process |
| CN110996639A (en) * | 2019-11-15 | 2020-04-10 | 上海阿莱德实业股份有限公司 | Low-cost non-metal shielding cover and preparation method thereof |
| CN110996639B (en) * | 2019-11-15 | 2021-06-11 | 上海阿莱德实业股份有限公司 | Low-cost non-metal shielding cover and preparation method thereof |
| CN111996567A (en) * | 2020-09-03 | 2020-11-27 | 深圳市生利科技有限公司 | Chromium plating process for PA plastic material and product thereof |
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| Publication number | Publication date |
|---|---|
| CN1238572C (en) | 2006-01-25 |
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