CN1516614A - Method and device for cleaning gas - Google Patents

Method and device for cleaning gas Download PDF

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Publication number
CN1516614A
CN1516614A CNA03800450XA CN03800450A CN1516614A CN 1516614 A CN1516614 A CN 1516614A CN A03800450X A CNA03800450X A CN A03800450XA CN 03800450 A CN03800450 A CN 03800450A CN 1516614 A CN1516614 A CN 1516614A
Authority
CN
China
Prior art keywords
flow
guider
gas
flies
core
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CNA03800450XA
Other languages
Chinese (zh)
Inventor
�����ء��ڶ�άϣ
阿恩特·黑尔维希
��ɳ�����ɿ�
克劳斯·沙伊班纳克
阿克塞尔·利贝尔
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
GEA Bischoff GmbH
Original Assignee
Lurgi Bischoff GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Lurgi Bischoff GmbH filed Critical Lurgi Bischoff GmbH
Publication of CN1516614A publication Critical patent/CN1516614A/en
Pending legal-status Critical Current

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • B01D53/06Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with moving adsorbents, e.g. rotating beds
    • B01D53/10Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with moving adsorbents, e.g. rotating beds with dispersed adsorbents
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01FMIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F23/00Mixing according to the phases to be mixed, e.g. dispersing or emulsifying
    • B01F23/30Mixing gases with solids
    • B01F23/39Mixing systems, i.e. flow charts or diagrams
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01FMIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F25/00Flow mixers; Mixers for falling materials, e.g. solid particles
    • B01F25/30Injector mixers
    • B01F25/31Injector mixers in conduits or tubes through which the main component flows
    • B01F25/313Injector mixers in conduits or tubes through which the main component flows wherein additional components are introduced in the centre of the conduit
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2253/00Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/10Inorganic adsorbents
    • B01D2253/104Alumina
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/20Halogens or halogen compounds
    • B01D2257/202Single element halogens
    • B01D2257/2027Fluorine

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Dispersion Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Devices And Processes Conducted In The Presence Of Fluids And Solid Particles (AREA)
  • Treating Waste Gases (AREA)

Abstract

The invention relates to a method for cleaning gas by means of fine-particle adsorbing agents in a flow reactor through which the gas that is to be cleaned flows in a turbulent manner. According to the inventive method, a velocity profile that comprises a core flow and an area which is located between the wall of the flow reactor and the core flow and in which the flow velocity is higher than that of the core flow, is created in the gas flow. The fine-particle adsorbing agents are fed into the area of the core flow. The invention also relates to a flow reactor for carrying out the inventive method.

Description

The method and apparatus that is used for gas purification
Technical field
The present invention relates to a kind of method of carrying out gas purification in flying flow reactor with meticulous adsorbent, flowing through to turbulence to be clean, this flies flow reactor.
Background technology
For example in aluminium industry, use such method that Fluoride Separation is come out.Meticulous alundum (Al (AL 2O 3) carry out suction-operated, after charging, fluoride can be imported reduction process and produce aluminium.
According to by method known among the US 4 501 599, the fine solid material that is used as adsorbent is fluidized in flying the feed tube of flow reactor, and is placed in the injector that flies flow reactor inside by one and is input into air-flow to be clean.These solid matters come out from the opening radial spray on the injector circumference, and are brought into air-flow.Air-flow is turbulent, and this is just flying to occur a substantially the same flow velocity on the entire cross section of flow reactor, and the solid matter of high concentration more or less is equally distributed.Loaded by very big wearing and tearing at this wall that flies flow reactor.
Summary of the invention
The objective of the invention is to, reduce the wearing and tearing that fly on the flow reactor wall by introducing a kind of method.
This purpose realizes by a kind of method with the described feature of beginning by the present invention, promptly, in air-flow, produce a velocity profile, this velocity profile has a core to flow, and between the wall that flies flow reactor and core flow, a zone being arranged, flow also to compare with core and have higher flow velocity in this zone; And and with in the meticulous adsorbent introduction core flow region.Adjustment mobile section according to the present invention impels the dilution in the wall near zone.For this reason, along with the flow equilibrium that the length of flow appearance of progression is flowed to core from the wall near zone, solid matter concentrates in the core flow region thus.Described these effects are supported by the following method, are about to meticulous adsorbent and introduce in the core flow region.Reach high solid substance concentration away from the wall that flies flow reactor by introducing method of the present invention.The wearing and tearing of wall load has just reduced thus.
Object of the present invention also relates to a flow reactor that flies that is suitable for implementing this method, comprising:
A container of flowing through by gas to be clean;
One in air-flow with the guider of chamber wall arrangement separated by a distance;
The feeding device that is used for meticulous adsorbent (Adsorbentien) that at least one is connected with guider;
Wherein, the gas guider of flowing through, this gas are compared lower flow velocity with one with the main flow that flows through on next door, the guider outside and are flowed out from guider on the gas flow direction of the container of flowing through, and the adsorbent that will send into the guider inner chamber is taken away together.These meticulous solid matters, are admitted in the air-flow with high solid substance concentration on the flow direction of gas flow to be purified according to the present invention, and the air-flow that does not contain solid matter that is had high flow velocities at this this feed air-flow coats.In this manner, can be by above-mentioned effect with high solid substance concentration away from wall.
Guider preferably constitutes passage in container both ends open and that flowed through by the shunting of gas to be clean.A large amount of solid matters slow down the air-flow in this zone, occur near the desired mobile section that has high flow rate wall thus.
Be also that in invention scope connection one is used for the gas pipeline of carrier gas on guider, the flow of this carrier gas can irrespectively be regulated with the air-flow of gas to be clean.Carrier gas also can be a gas to be clean.The gas flow that these are introduced by guider and flow through on next door, the guider outside can be regulated separately in this embodiment.Mobile section in flying flow reactor is changed.
According to a kind of preferred structure of the present invention, a plurality of feeding devices that are used for adsorbent are set, they are star-shaped to be connected with each perforate of guider shell side.Chute, vibratory sluice, conveyer belt or auger conveyor all can be used as feeding device.
Description of drawings
Explain the present invention below by the accompanying drawing that an embodiment only is shown.In the accompanying drawing:
Fig. 1 is the longitudinal section that flies flow reactor that is used for gas purification;
Fig. 2 be along Fig. 1 center line I-I intercepting sectional view;
Fig. 3 is another structure that flies flow reactor.
The specific embodiment
Flying flow reactor (Flugstromreaktor) shown in these figure, comprising container 1, a feeding device 4 that is used for meticulous (feinteilig) adsorbent that in air-flow, is connected with guider 3 of flowing through by gas to be clean 2 aspect its basic structure with the guider 3 and of chamber wall arrangement separated by a distance.Described feeding device 4 star-shaped each perforate with guider 3 shell side that are used for the fine solid material are connected, and are designed to chute, vibratory sluice, conveyer belt, auger conveyor or the like.
Guider 3 is by the gas percolation.Described gas longshore current flows out from guider through the gas flow direction of container 1, and the adsorbent of inserting guider 3 inner chambers is taken away.The flow velocity of effluent air/solid matter from guider-air-flow is less than the flow velocity of the air-flow that does not conform to solid matter that flows through from next door, guider 3 outsides.This has caused a velocity profile that schematically illustrates 5 in Fig. 1.As can be seen, produced a velocity profile 5 in air-flow from this diagram, this velocity profile has a core to flow 6, and flows with core at the wall that flies flow reactor and between 6 a zone 7 to be arranged, and it has higher flow velocity with comparing than core mobile 6.Meticulous adsorbent is introduced into the core flow region.Along with the length of flow (FliessLaenge) of progression, flow velocity 6 during core flows and the flow velocity 7 that centers in the mobile annular flow of core balance each other.One lateral flow that is orientated from outside to inside 8 is got in touch with the equilibrium phase of described velocity profile, and this lateral flow 8 is marked by flow arrow in Fig. 1.Concentrating of solid matter in the mobile nucleus of described lateral flow 8 supports.Simultaneously, the described lateral flow 8 of orientation from outside to inside also impels the gas from the wall near zone to contact with solid matter.
In the embodiment shown in Fig. 1 and 2, guider 3 constitutes passage in container 1 both ends open and that flowed through by the shunting of gas gas to be clean.Inserted a large amount of solid matters in the guider 3 and slowed down air-flow, occurred thus at the mobile section shown in Fig. 1 by guider 3.This configuration is particularly suitable for big solid matter mass flow.
In the embodiment shown in Fig. 3, connection one is used for the gas pipeline 9 of carrier gas on guider 3, and its flow can irrespectively be regulated with gas flow 2 to be clean.By regulating the delivery air-flow mobile section in flying flow reactor is changed, and it is conditioned with suitable manner.

Claims (6)

1. be used in flying flow reactor with the method for meticulous adsorbent Purge gas, flow through turbulence to be clean that this flies flow reactor, it is characterized in that,
In air-flow, produce a velocity profile, this velocity profile has a core to flow, and between the wall that flies flow reactor and core flow, a zone being arranged, flow to compare with core and have higher flow velocity in this zone, and described meticulous adsorbent is introduced in the core flow region.
2. be used for the flow reactor that flies of Purge gas, comprise:
One container (1) of flowing through by gas to be clean;
One in air-flow and with the guider (3) of chamber wall arrangement separated by a distance; And
The feeding device that is used for Powdered adsorbent (4) that at least one is connected with guider (3);
It is characterized in that, the gas guider (3) of flowing through, this gas is on the flow direction of the gas (2) of the container of flowing through (1), from guider (3), flow out with respect to the lower flow velocity of main flow that flows through on guider (3) outside next door with one, and the adsorbent that will enter guider (3) inner chamber is taken away together.
3. according to the described flow reactor that flies of claim 2, it is characterized in that described guider (3) constitutes passage in container (1) both ends open and that flowed through by the shunting of gas to be clean.
4. according to the described flow reactor that flies of claim 2, it is characterized in that go up the gas pipeline (9) that connection one is used for carrier gas at guider (3), the flow of this carrier gas can irrespectively be regulated with air-flow to be clean.
5. according to the described flow reactor that flies of one of claim 2 to 4, it is characterized in that, a plurality of feeding devices (4) that are used for adsorbent are set, their star-shaped each perforates with guider (3) shell side are connected.
6. according to the described flow reactor that flies of one of claim 2 to 5, it is characterized in that described feeding device (4) constitutes chute, vibratory sluice, conveyer belt or auger conveyor.
CNA03800450XA 2002-03-30 2003-03-28 Method and device for cleaning gas Pending CN1516614A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE10214400.1 2002-03-30
DE10214400A DE10214400B4 (en) 2002-03-30 2002-03-30 Traction current reactor for gas cleaning

Publications (1)

Publication Number Publication Date
CN1516614A true CN1516614A (en) 2004-07-28

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
CNA03800450XA Pending CN1516614A (en) 2002-03-30 2003-03-28 Method and device for cleaning gas

Country Status (5)

Country Link
CN (1) CN1516614A (en)
AU (1) AU2003233949A1 (en)
DE (1) DE10214400B4 (en)
RU (1) RU2004115637A (en)
WO (1) WO2003082440A1 (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101687135B (en) * 2007-07-05 2013-08-14 开利公司 Fluid purifier with non-laminar flow structure
CN104694971A (en) * 2013-12-10 2015-06-10 沈阳铝镁设计研究院有限公司 Unpowered revolving airflow device

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1584367A1 (en) * 2004-04-08 2005-10-12 Austrian Energy & Environment AG Process and device for feeding of solids
IL176899A0 (en) * 2006-07-17 2006-12-10 E E R Env Energy Resrc Israel Apparatus and method for the removal of gaseous pollutants from an upwardly flowing gas stream

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2695265A (en) * 1949-04-27 1954-11-23 Kellogg M W Co Injection mixer for use in catalytic hydrocarbon conversion processes
DE2617053A1 (en) * 1976-04-17 1977-11-10 Heinz Hoelter Desulphurisation and denitration of crude gas - using dry absorbent injected into contact tube
US4073832A (en) * 1976-06-28 1978-02-14 Texaco Inc. Gas scrubber
CA1197074A (en) * 1981-12-04 1985-11-26 Isaias Loukos Method and apparatus for cleaning waste gases from aluminum production facilities
FR2534831A1 (en) * 1982-10-25 1984-04-27 Air Ind INSTALLATION FOR INJECTING A POWDERY MATERIAL, IN PARTICULAR AN ADSORBENT MATERIAL, INTO A CONTACT COLUMN
DE3526756A1 (en) * 1985-07-26 1987-01-29 Babcock Anlagen Ag Process for separating off ammonia residues from fly ash and steam generation plant having a treatment vessel for carrying out the process
DE29807889U1 (en) * 1998-05-02 1998-07-30 Rob Ing Rudolf Ohlmann Techn B Device for introducing an adsorbent into an exhaust gas
SE516013C2 (en) * 1998-12-23 2001-11-05 Flaekt Ab Method and apparatus for mixing a flowing gas and a powdered material
DE50000461D1 (en) * 2000-02-21 2002-10-17 Rwe Rheinbraun Ag Process and sorbent for dry cleaning of exhaust gases

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101687135B (en) * 2007-07-05 2013-08-14 开利公司 Fluid purifier with non-laminar flow structure
CN104694971A (en) * 2013-12-10 2015-06-10 沈阳铝镁设计研究院有限公司 Unpowered revolving airflow device
CN104694971B (en) * 2013-12-10 2017-01-18 沈阳铝镁设计研究院有限公司 Unpowered revolving airflow device

Also Published As

Publication number Publication date
AU2003233949A1 (en) 2003-10-13
RU2004115637A (en) 2005-05-20
DE10214400A1 (en) 2003-10-23
DE10214400B4 (en) 2004-03-25
WO2003082440A1 (en) 2003-10-09

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PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C02 Deemed withdrawal of patent application after publication (patent law 2001)
WD01 Invention patent application deemed withdrawn after publication