CN1514509A - Manufacturing method of high power type lithium ion battery - Google Patents

Manufacturing method of high power type lithium ion battery Download PDF

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Publication number
CN1514509A
CN1514509A CNA031263003A CN03126300A CN1514509A CN 1514509 A CN1514509 A CN 1514509A CN A031263003 A CNA031263003 A CN A031263003A CN 03126300 A CN03126300 A CN 03126300A CN 1514509 A CN1514509 A CN 1514509A
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Prior art keywords
lithium ion
negative
coated
positive
make
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CN1228881C (en
Inventor
任英姿
宋伟恒
李福林
章杰
杨书廷
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Henan Lithium Power Source Co Ltd
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ZHONGKE SCIENCE-TECHNOLOGY Co Ltd XINXIANG
OXYGEN-FREE COPPER MATERIAL GENERAL FACTORY XINXIANG
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50Manufacturing or production processes characterised by the final manufactured product

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  • Secondary Cells (AREA)
  • Battery Electrode And Active Subsutance (AREA)

Abstract

Anode material of dynamical type of lithium ion battery with capacity in 3Ah-200Ah is prepared according to following steps. Even slurry of combining spherical shaped lithium manganate with added rare earth oxide 1%-1.5% is coated on continuous metal mesh. In charging procedure, electrons are released; and in discharging procedure electrons are obtained. Even slurry of cladding carbon as well as added 0.01%-0.5% organic acid and 0.5%-10% adhesive are as material of cathode. In charging procedure, electrons are obtained; and in dischaging procedure electrons are released. Positive and negative pole plates are prepared by using current corrector. Battery is combined through cascading method in sequence of cathode, diaphragm, anode, diaphragm so as to form laminated bodies of electrodes. Diaphragm separates anode and cathode. The invention possesses advantages of lightweight, high energy, high operating voltages and good safety feature.

Description

A kind of high-power power-type lithium ion battery manufacturing process
Technical field:
The present invention relates to a kind of high-power power-type lithium ion battery manufacturing process, the capacity that is specially adapted to is at the high-power square box hat of 3Ah-200Ah power lithium-ion battery.
Background technology:
The lithium ion battery in market is based on little square now, capacity is at 450mAh-2000mAh, mainly be applicable to fields such as household electrical appliance, ventilating system, electrical source of power, big capacity square lithium ion battery only uses as power supply at mine lamp and video camera etc., and positive electrode material cobalt acid lithium, the negative material carbosphere, its shortcoming is: poor safety performance, capacity are little.
Summary of the invention:
Task of the present invention is to propose a kind of high-power 3Ah-200Ah, high power capacity, the manufacturing process of the power-type lithium ion battery that security performance is high task of the present invention is finished like this, positive electrode is to use spherical lithium manganate, it is characterized in that: capacity is the positive electrode spherical lithium manganate of 3Ah-200Ah power-type lithium ion battery, after adding rare earth oxide 1%-1.5% even slurry, be coated on the wire netting continuously, in charging process, discharge electronics, lithium ion is deviate from, migration also embeds negative electrode, discharge obtains electronics, lithium ion embeds the cyclical stability and the high temperature cyclic performance that will effectively improve battery in the positive pole, the negative material carbon coated, add organic acid 0.01%-0.5%, after adhesive is the 0.5%-10% even slurry, be coated in continuously to make on the wire netting and form, when charging, obtain electronics, make lithium ion be embedded into negative pole, discharge electronics at discharge process, make lithium ion deviate from migration and imbed in the positive pole, utilize collector self afflux, just make, negative plate, just, the negative electrode lug just is, the active material that negative collector is not coated with partly constitutes, press negative pole with laminating method, barrier film, anodal, the sequential combination battery of barrier film, form the electrode duplexer, separate with barrier film between battery plus-negative plate.Described rare earth oxide is a ytterbium oxide, and neodymia, organic acid are glacial acetic acid, and adhesive is a fluororesin.After the positive electrode substance is closed slurry, be coated in continuously on the wire netting, described wire netting is meant aluminium foil or aluminium net, after the negative material substance is closed slurry, is coated in continuously on the wire netting, and described wire netting is meant Copper Foil or copper mesh.The present invention has following effect: advantages such as the lithium ion battery made from this technology is good with its intrinsic high working voltage discharge platform, lightness, high-energy, operating voltage height, security performance, environmentally safe.
Embodiment:
The high-power 3Ah-200Ah power-type lithium ion battery manufacturing process that the present invention proposes is as follows:
Embodiment 1:
With safe spherical lithium manganate is positive electrode, the interpolation weight ratio is 1% rare earth oxide such as ytterbium oxide and neodymia, behind the even slurry, being coated in online manufacturing of aluminium foil or aluminium continuously forms, discharge electronics in charging process, lithium ion is deviate from, and migration also embeds negative electrode, discharge obtains electronics, and lithium ion embeds the cyclical stability and the high temperature cyclic performance that will effectively improve battery in the positive pole.Negative pole adopts inexpensive carbon coated, adding weight ratio is 0.01% organic acid such as glacial acetic acid, adhesive fluororesin weight ratio is 0.5%, behind the even slurry, be coated in continuously to make on Copper Foil or the copper mesh and form, when charging, obtain electronics, make lithium ion be embedded into negative pole, in discharge process, discharge electronics, make lithium ion deviate from migration and imbed in the positive pole, utilize collector self afflux to make positive/negative plate, the positive and negative electrode lug is partly to be made of the active material that positive and negative collector is not coated with, press negative pole with laminating method, barrier film, anodal, the sequential combination battery of barrier film forms the electrode duplexer, separates with barrier film between battery plus-negative plate.
Embodiment 2:
With safe spherical lithium manganate is positive electrode, the interpolation weight ratio is 1.5% rare earth oxide such as ytterbium oxide and neodymia, behind the even slurry, being coated in online manufacturing of aluminium foil or aluminium continuously forms, discharge electronics in charging process, lithium ion is deviate from, and migration also embeds negative electrode, discharge obtains electronics, and lithium ion embeds the cyclical stability and the high temperature cyclic performance that will effectively improve battery in the positive pole.Negative pole adopts inexpensive carbon coated, adding weight ratio is 0.5% organic acid such as glacial acetic acid, adhesive fluororesin weight ratio is 5%, behind the even slurry, be coated in continuously to make on Copper Foil or the copper mesh and form, when charging, obtain electronics, make lithium ion be embedded into negative pole, in discharge process, discharge electronics, make lithium ion deviate from migration and imbed in the positive pole, utilize collector self afflux to make positive/negative plate, the positive and negative electrode lug is partly to be made of the active material that positive and negative collector is not coated with, press negative pole with laminating method, barrier film, anodal, the sequential combination battery of barrier film forms the electrode duplexer, separates with barrier film between battery plus-negative plate.
Embodiment 3:
With safe spherical lithium manganate is positive electrode, the interpolation weight ratio is 1% rare earth oxide such as ytterbium oxide and neodymia, behind the even slurry, being coated in online manufacturing of aluminium foil or aluminium continuously forms, discharge electronics in charging process, lithium ion is deviate from, and migration also embeds negative electrode, discharge obtains electronics, and lithium ion embeds the cyclical stability and the high temperature cyclic performance that will effectively improve battery in the positive pole.Negative pole adopts inexpensive carbon coated, adding weight ratio is 0.5% organic acid such as glacial acetic acid, adhesive fluororesin weight ratio is 0.5%, behind the even slurry, be coated in continuously to make on Copper Foil or the copper mesh and form, when charging, obtain electronics, make lithium ion be embedded into negative pole, in discharge process, discharge electronics, make lithium ion deviate from migration and imbed in the positive pole, utilize collector self afflux to make positive/negative plate, the positive and negative electrode lug is partly to be made of the active material that positive and negative collector is not coated with, press negative pole with laminating method, barrier film, anodal, the sequential combination battery of barrier film forms the electrode duplexer, separates with barrier film between battery plus-negative plate.
Embodiment 4:
With safe spherical lithium manganate is positive electrode, the interpolation weight ratio is 1.2% rare earth oxide such as ytterbium oxide and neodymia, behind the even slurry, being coated in online manufacturing of aluminium foil or aluminium continuously forms, discharge electronics in charging process, lithium ion is deviate from, and migration also embeds negative electrode, discharge obtains electronics, and lithium ion embeds the cyclical stability and the high temperature cyclic performance that will effectively improve battery in the positive pole.Negative pole adopts inexpensive carbon coated, adding weight ratio is 0.2% organic acid such as glacial acetic acid, adhesive fluororesin weight ratio is 10%, behind the even slurry, be coated in continuously to make on Copper Foil or the copper mesh and form, when charging, obtain electronics, make lithium ion be embedded into negative pole, in discharge process, discharge electronics, make lithium ion deviate from migration and imbed in the positive pole, utilize collector self afflux to make positive/negative plate, the positive and negative electrode lug is partly to be made of the active material that positive and negative collector is not coated with, press negative pole with laminating method, barrier film, anodal, the sequential combination battery of barrier film forms the electrode duplexer, separates with barrier film between battery plus-negative plate.
Embodiment 5:
With safe spherical lithium manganate is positive electrode, the interpolation weight ratio is 1.5% rare earth oxide such as ytterbium oxide and neodymia, behind the even slurry, being coated in online manufacturing of aluminium foil or aluminium continuously forms, discharge electronics in charging process, lithium ion is deviate from, and migration also embeds negative electrode, discharge obtains electronics, and lithium ion embeds the cyclical stability and the high temperature cyclic performance that will effectively improve battery in the positive pole.Negative pole adopts inexpensive carbon coated, adding weight ratio is 0.1% organic acid such as glacial acetic acid, adhesive fluororesin weight ratio is 5%, behind the even slurry, be coated in continuously to make on Copper Foil or the copper mesh and form, when charging, obtain electronics, make lithium ion be embedded into negative pole, in discharge process, discharge electronics, make lithium ion deviate from migration and imbed in the positive pole, utilize collector self afflux to make positive/negative plate, the positive and negative electrode lug is partly to be made of the active material that positive and negative collector is not coated with, press negative pole with laminating method, barrier film, anodal, the sequential combination battery of barrier film forms the electrode duplexer, separates with barrier film between battery plus-negative plate.
Embodiment 6:
With safe spherical lithium manganate is positive electrode, the interpolation weight ratio is 1.2% rare earth oxide such as ytterbium oxide and neodymia, behind the even slurry, being coated in online manufacturing of aluminium foil or aluminium continuously forms, discharge electronics in charging process, lithium ion is deviate from, and migration also embeds negative electrode, discharge obtains electronics, and lithium ion embeds the cyclical stability and the high temperature cyclic performance that will effectively improve battery in the positive pole.Negative pole adopts inexpensive carbon coated, adding weight ratio is 0.1% organic acid such as glacial acetic acid, adhesive fluororesin weight ratio is 7%, behind the even slurry, be coated in continuously to make on Copper Foil or the copper mesh and form, when charging, obtain electronics, make lithium ion be embedded into negative pole, in discharge process, discharge electronics, make lithium ion deviate from migration and imbed in the positive pole, utilize collector self afflux to make positive/negative plate, the positive and negative electrode lug is partly to be made of the active material that positive and negative collector is not coated with, press negative pole with laminating method, barrier film, anodal, the sequential combination battery of barrier film forms the electrode duplexer, separates with barrier film between battery plus-negative plate.
Embodiment 7:
With safe spherical lithium manganate is positive electrode, the interpolation weight ratio is 1.2% rare earth oxide such as ytterbium oxide and neodymia, behind the even slurry, being coated in online manufacturing of aluminium foil or aluminium continuously forms, discharge electronics in charging process, lithium ion is deviate from, and migration also embeds negative electrode, discharge obtains electronics, and lithium ion embeds the cyclical stability and the high temperature cyclic performance that will effectively improve battery in the positive pole.Negative pole adopts inexpensive carbon coated, adding weight ratio is 0.01% organic acid such as glacial acetic acid, adhesive fluororesin weight ratio is 7%, behind the even slurry, be coated in continuously to make on Copper Foil or the copper mesh and form, when charging, obtain electronics, make lithium ion be embedded into negative pole, in discharge process, discharge electronics, make lithium ion deviate from migration and imbed in the positive pole, utilize collector self afflux to make positive/negative plate, the positive and negative electrode lug is partly to be made of the active material that positive and negative collector is not coated with, press negative pole with laminating method, barrier film, anodal, the sequential combination battery of barrier film forms the electrode duplexer, separates with barrier film between battery plus-negative plate.
Embodiment 8:
With safe spherical lithium manganate is positive electrode, the interpolation weight ratio is 1% rare earth oxide such as ytterbium oxide and neodymia, behind the even slurry, being coated in online manufacturing of aluminium foil or aluminium continuously forms, discharge electronics in charging process, lithium ion is deviate from, and migration also embeds negative electrode, discharge obtains electronics, and lithium ion embeds the cyclical stability and the high temperature cyclic performance that will effectively improve battery in the positive pole.Negative pole adopts inexpensive carbon coated, adding weight ratio is 0.5% organic acid such as glacial acetic acid, adhesive fluororesin weight ratio is 7%, behind the even slurry, be coated in continuously to make on Copper Foil or the copper mesh and form, when charging, obtain electronics, make lithium ion be embedded into negative pole, in discharge process, discharge electronics, make lithium ion deviate from migration and imbed in the positive pole, utilize collector self afflux to make positive/negative plate, the positive and negative electrode lug is partly to be made of the active material that positive and negative collector is not coated with, press negative pole with laminating method, barrier film, anodal, the sequential combination battery of barrier film forms the electrode duplexer, separates with barrier film between battery plus-negative plate.
Embodiment 9:
With safe spherical lithium manganate is positive electrode, the interpolation weight ratio is 1.5% rare earth oxide such as ytterbium oxide and neodymia, behind the even slurry, being coated in online manufacturing of aluminium foil or aluminium continuously forms, discharge electronics in charging process, lithium ion is deviate from, and migration also embeds negative electrode, discharge obtains electronics, and lithium ion embeds the cyclical stability and the high temperature cyclic performance that will effectively improve battery in the positive pole.Negative pole adopts inexpensive carbon coated, adding weight ratio is 0.5% organic acid such as glacial acetic acid, adhesive fluororesin weight ratio is 10%, behind the even slurry, be coated in continuously to make on Copper Foil or the copper mesh and form, when charging, obtain electronics, make lithium ion be embedded into negative pole, in discharge process, discharge electronics, make lithium ion deviate from migration and imbed in the positive pole, utilize collector self afflux to make positive/negative plate, the positive and negative electrode lug is partly to be made of the active material that positive and negative collector is not coated with, press negative pole with laminating method, barrier film, anodal, the sequential combination battery of barrier film forms the electrode duplexer, separates with barrier film between battery plus-negative plate.
Embodiment 10:
With safe spherical lithium manganate is positive electrode, the interpolation weight ratio is 1% rare earth oxide such as ytterbium oxide and neodymia, behind the even slurry, being coated in online manufacturing of aluminium foil or aluminium continuously forms, discharge electronics in charging process, lithium ion is deviate from, and migration also embeds negative electrode, discharge obtains electronics, and lithium ion embeds the cyclical stability and the high temperature cyclic performance that will effectively improve battery in the positive pole.Negative pole adopts inexpensive carbon coated, adding weight ratio is 0.1% organic acid such as glacial acetic acid, adhesive fluororesin weight ratio is 0.5%, behind the even slurry, be coated in continuously to make on Copper Foil or the copper mesh and form, when charging, obtain electronics, make lithium ion be embedded into negative pole, in discharge process, discharge electronics, make lithium ion deviate from migration and imbed in the positive pole, utilize collector self afflux to make positive/negative plate, the positive and negative electrode lug is partly to be made of the active material that positive and negative collector is not coated with, press negative pole with laminating method, barrier film, anodal, the sequential combination battery of barrier film forms the electrode duplexer, separates with barrier film between battery plus-negative plate.
0.2C capacity The 2C percentage that discharges 5V overcharges 100 times circulation volume descends
Embodiment 1 ????110 ????90 Do not explode ????6%
Embodiment 2 ????113 ????94 Do not explode ????3.5%
Embodiment 3 ????108 ????90 Do not explode ????4%
Embodiment 4 ????105 ????86 Do not explode ????5%
Embodiment 5 ????106 ????87 Do not explode ????6%
Embodiment 6 ????109 ????94 Do not explode ????5.5%
Embodiment 7 ????112 ????96 Do not explode ????4%
Embodiment 8 ????111 ????89 Do not explode ????4.5%
Embodiment 9 ????104 ????84 Do not explode ????5%
Embodiment 10 ????109 ????91 Do not explode ????4%

Claims (3)

1. high-power power-type lithium ion battery manufacturing process, positive electrode is to use spherical lithium manganate, it is characterized in that: capacity is the positive electrode spherical lithium manganate of 3Ah-200Ah power-type lithium ion battery, after adding rare earth oxide 1%1.5% even slurry, be coated on the wire netting continuously, in charging process, discharge electronics, lithium ion is deviate from, migration also embeds negative electrode, discharge obtains electronics, lithium ion embeds the cyclical stability and the high temperature cyclic performance that will effectively improve battery in the positive pole, the negative material carbon coated, add organic acid 0.01%-0.5%, after adhesive is the 0.5%-10% even slurry, be coated in continuously to make on the wire netting and form, when charging, obtain electronics, make lithium ion be embedded into negative pole, discharge electronics at discharge process, make lithium ion deviate from migration and imbed in the positive pole, utilize collector self afflux, just make, negative plate, just, the negative electrode lug just is, the active material that negative collector is not coated with partly constitutes, press negative pole with laminating method, barrier film, anodal, the sequential combination battery of barrier film forms the electrode duplexer, separates with barrier film between battery plus-negative plate.
2. a kind of high-power power-type lithium ion battery manufacturing process according to claim 1, it is characterized in that: described rare earth oxide is a ytterbium oxide, and neodymia, organic acid are glacial acetic acid, and adhesive is a fluororesin.
3. a kind of high-power power-type lithium ion battery manufacturing process according to claim 1, it is characterized in that: after the positive electrode substance is closed slurry, be coated on the wire netting continuously, described wire netting is meant aluminium foil or aluminium net, after the negative material substance is closed slurry, be coated in continuously on the wire netting, described wire netting is meant Copper Foil or copper mesh.
CNB031263003A 2003-08-08 2003-08-08 Manufacturing method of high power type lithium ion battery Expired - Fee Related CN1228881C (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN100367563C (en) * 2006-04-18 2008-02-06 南京视威电子有限公司 Large equivalent combined Li ion cells unit
CN103035925A (en) * 2011-09-30 2013-04-10 天津市捷威动力工业有限公司 Lithium-ion power battery, lithium-ion power battery current collecting body, negative electrode pole piece
CN101626094B (en) * 2008-07-11 2015-09-30 东莞新能源科技有限公司 Lithium ion battery and battery thereof
US9741996B2 (en) 2007-12-25 2017-08-22 Byd Co. Ltd. Construction of electrochemical storage cell

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN100367563C (en) * 2006-04-18 2008-02-06 南京视威电子有限公司 Large equivalent combined Li ion cells unit
US9741996B2 (en) 2007-12-25 2017-08-22 Byd Co. Ltd. Construction of electrochemical storage cell
US10147930B2 (en) 2007-12-25 2018-12-04 Shenzhen Byd Auto R&D Company Limited Construction of electrochemical storage cell with conductive block
US10381632B2 (en) 2007-12-25 2019-08-13 Shenzhen Byd Auto R&D Company Limited Construction of electrochemical storage cell with conductive bridge
CN101626094B (en) * 2008-07-11 2015-09-30 东莞新能源科技有限公司 Lithium ion battery and battery thereof
CN103035925A (en) * 2011-09-30 2013-04-10 天津市捷威动力工业有限公司 Lithium-ion power battery, lithium-ion power battery current collecting body, negative electrode pole piece

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