CN1490354A - Plastic alloy containing polycarbonate thermoplastic elastomer - Google Patents
Plastic alloy containing polycarbonate thermoplastic elastomer Download PDFInfo
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- CN1490354A CN1490354A CNA021374511A CN02137451A CN1490354A CN 1490354 A CN1490354 A CN 1490354A CN A021374511 A CNA021374511 A CN A021374511A CN 02137451 A CN02137451 A CN 02137451A CN 1490354 A CN1490354 A CN 1490354A
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Abstract
A plastic alloy is prepared from biphenol-type polycarbonate, the atactic styrene-maleic acid anhydride copolymer, thermoplastic elastomer, antioxidizing agent and glass fibre. Its advantages are high antiageing performance, high high-temp resistance and high impact strength.
Description
Technical field
The present invention relates to contain the polycarbonate thermoplastic elastomer polyblend.
Background technology
Polycarbonate is widely used in preparing various high performance plastics alloys with mechanical property, thermotolerance and the shock resistance of excellence, as polyblends such as PC/PBT, PC/PET, PC/PE, PC/ABS, PC/PA or PC/TPU commercialization production is arranged all.Wherein the PC/ABS polyblend becomes a kind of output maximum in the polycarbonate plastic alloy again with good anti-stress cracking, processing fluidity and lower cost.But the PC/ABS polyblend also exists weathering resistance difference and the lower shortcoming of thermotolerance.
U.S. Pat P5137970 has introduced by addition portion and has divided special polycarbonate (thermotolerance is higher than general bisphenol-a polycarbonate) to improve the stable on heating method of PC/ABS polyblend, as consist of the polyblend of PC/SAN/ABS 60/16/24, in PC (common bisphenol-a polycarbonate), add 20 parts of dihydroxyphenyl propanes and 1, two (the 4-hydroxy phenyls)-3 of 1-, 3, the dimension card heat resisting temperature of alloy can be brought up to 131 ℃ from 122 ℃ during the polycarbonate of 5-trimethyl-cyclohexane (mol ratio 45: 55) copolymerization.U.S. Pat P4367310 has introduced and added the stable on heating method of SMA resin improved in the PC/ABS alloy, as consists of polyblend heat-drawn wire (4.6 kg/cm of PC/SMA/ABS 40/35/25
2Load) 124 ℃ have been reached.But therefore above-mentioned alloy all exists the relatively poor shortcoming of ageing resistance owing to all contain the divinyl rubber phase composition.
Atactic styrene-maleic anhydride copolymer (SMA resin) has good processing fluidity and thermotolerance, therefore and thermotolerance improves along with the raising of maleic anhydride content, is to replace ABS to prepare all desirable feedstock of good polycarbonate alloy of thermotolerance and processing fluidity.But shock resistance is poor because the fragility of SMA resin is big for the PC/SMA polyblend of the direct blend preparation of polycarbonate (PC) and SMA resin, has limited its range of application.
Summary of the invention
Technical problem to be solved by this invention is that the polyblend that makes in the above-mentioned document exists loss of properties on aging, and shock strength is poor, and the not good problem of resistance toheat, and a kind of polycarbonate thermoplastic elastomer polyblend that newly contains is provided.It is good that this polyblend has ageing-resistant performance, the high and good characteristics of resistance toheat of shock strength.
For solving the problems of the technologies described above, the technical solution used in the present invention is as follows: a kind of polycarbonate thermoplastic elastomer polyblend that contains comprises following component in parts by weight:
A) the bisphenol type polycarbonate is 20～90 parts;
B) atactic styrene-maleic anhydride copolymer is 1～60 part, and wherein maleic anhydride content is 5～35% by weight percentage;
C) be selected from ethylene-propylene copolymer, ethylene-propylene-diene copolymer, hydrogenated styrene-butadiene-styrene block copolymers, ethylene-vinyl acetate copolymer or the acrylate nucleocapsid structure multipolymer at least a 1～40 part;
D) be selected from ultra-violet stabilizer, oxidation inhibitor, fire retardant, mineral filler, glass fibre, pigment or the lubricant at least a 0.02～76 part.
In the technique scheme, bisphenol type polycarbonate preferred version is a bisphenol A polycarbonate, by 2, two (4-hydroxy phenyl) propane of 2-and phosgene or diphenyl carbonate reaction make, weight-average molecular weight is 8000～200000, and the intrinsic viscosity that records in 25 ℃ of methylene dichloride is 0.40～1.0 liter/gram; Another preferred version of bisphenol type polycarbonate is by two (4-hydroxy phenyl) methane, 2,2-two (3,5-dimethyl-4-hydroxy phenyl) propane, 2,2-two (3,5-two chloro-4-hydroxy phenyls) propane, 2,2-two (3,5-two bromo-4-hydroxy phenyls) propane, 1,1-bis(4-hydroxyphenyl) cyclohexane, 4, two (4-hydroxy phenyl) heptane or two (3 of 4-, 5-dimethyl-4-hydroxy phenyl) sulfone and phosgene or diphenyl carbonate reaction make, and the bisphenol type polycarbonate is 50～90 parts in the parts by weight preferable range.In parts by weight, atactic styrene-maleic anhydride copolymer consumption preferable range is 5～40 parts, wherein maleic anhydride content by weight percentage preferable range be 8～25%, weight-average molecular weight can be 10～300,000, preferable range is 15～250,000.Be selected from least a consumption in ethylene-propylene copolymer, ethylene-propylene-diene copolymer, hydrogenated styrene-butadiene-styrene block copolymers, ethylene-vinyl acetate copolymer or the acrylate nucleocapsid structure multipolymer, in the parts by weight preferable range is 5～25 parts, and preferred version is for being selected from acrylate nucleocapsid structure multipolymer.These thermoplastic elastic bodies should have lower second-order transition temperature (T
g) as 0 ℃, better scope is to be lower than-20 ℃.The inventor thinks that being particularly suitable for weathering resistance impact modifying agent of the present invention is acrylate nucleocapsid structure multipolymer (ACR), this multipolymer is generally by at least 50%, the soft nuclear polymer of the acrylate of best 70～85% weight contents and no more than 50%, the crust polymer of the methyl methacrylate of best 30～15% weight contents or methyl methacrylate and styrene copolymerized formation, using maximum soft nuclear structures of acrylate is the butyl acrylate polymkeric substance, and its weight-average molecular weight is at least 500000.Acrylate nucleocapsid structure multipolymer (ACR) generally adopts the manufacturing of multistage emulsion polymerisation process, and detailed methods of fabrication can be with reference to European patent EP 0536935.The oxidation inhibitor preferred version that uses among the present invention is antioxidant 1010, and the mineral filler preferred version is a titanium dioxide.Using glass fibre can increase substantially the mechanical property and the resistance toheat of polyblend of the present invention among the present invention, because a) component and b among the present invention) component all has engaging force preferably with glass fibre.
The preparation of polyblend of the present invention can be adopted the mixing machine of Banbury (Banbury) Banbury mixer, single screw extrusion machine, twin screw extruder or other form to mix mentioned component under molten state and obtain.In order to obtain well behaved polyblend, each component should be strict dry before mixing, can be as polycarbonate (PC) 120 ℃ of vacuum-dryings 6～8 hours, the SMA resin is 90～100 ℃ of dryings 2～4 hours, the using method that concrete drying conditions can provide with reference to each raw materials producers.The melt processing temperature scope generally can be in each component on the high melting temperature 30 ℃ to the temperature range between the lowest decomposition temperature, select, the preparation polyblend of the present invention the melt processing temperature scope with 240 ℃ to 300 ℃ for well, be preferably between 250～280 ℃.
The raw material that the present invention uses is as follows:
The PC resin is an a) component, and U.S. GE Plastics Company is produced, Lexan141R-111, melt flow rate (MFR) (300 ℃, 11.8N load) 10.5 grams/10 minutes.
The SMA resin is b) component, Shanghai Petroleum Chemical Engineering Institute produces, maleic anhydride quality percentage composition 18%, melt flow rate (MFR) (220 ℃, 49.05N load) 1.45 grams/10 minutes.
Acrylate impact modifying agent (ACR), Wu Yu chemistry Singapore company limited, KM355P, T
g=-21 ℃ (DMTA method).
ABS resin, Taiwan Qi Mei industrial, PA747, melt flow rate (MFR) (200 ℃, 49.05N load) 0.8 gram/10 minutes.
Antioxidant 1010, Shanghai Gaoqiao vapour clings to chemical company limited, Irganox1010.
Alkali free glass fibre, huge strong glass fibre company limited of Tongxiang, Zhejiang megalith group, RP930,13 microns of diameters.
Titanium dioxide, German Sachtleben-chemie GMBH company, LW-S-01.
Testing method:
Tensile property is pressed ASTM D638, I type sample, and non-enhancing sample draw speed 50 mm/min, glass fibre strengthens sample draw speed 5.1 mm/min.
Bending property is pressed ASTM D790,3.2 mm thick samples, 51 millimeters of spans, trial speed 1.3 mm/min.
The IZOD notched Izod impact strength is pressed ASTM D256A.
Heat-drawn wire (HDT) is pressed ASTM D648,1.82MPa load, 6.4 mm thick samples.
Calcination resistates content is pressed ASTM D2584.
Air oven aging test is pressed GB/T 7141, and 120 ℃ were worn out 200 hours in the climatic chamber, observes colour-change after 320 hours and measures shock strength.
Dynamic mechanical property is measured, and presses ASTM D5279, measures the loss tangent (tan﹠amp of polyblend; ) temperature variant curve, condition determination is a temperature from room temperature to 200 ℃, frequency 1Hz, the thick sample of 1mm
Owing to added the Weather resistant thermoplastic elastomerics, thereby polyblend has good aging properties and high heat-drawn wire and high shock strength, obtained better technical effect in the polyblend of the present invention.
Description of drawings
Fig. 1 is the temperature variant curve of mechanical loss angle tangent (DMTA curve) of PC/SMA/ACR polyblend
C is the curve of embodiment 1 among Fig. 1, and F is the curve of embodiment 2, and I is the curve of embodiment 3, and L is the curve of embodiment 4.
The invention will be further elaborated below by embodiment.
Embodiment
[comparative example 1～2 and embodiment 1]
Add co-rotating twin screw extruder (Leistritz Micro 27 types mixing the back by weight ratio shown in the table one in a container for stirring through auxiliary agents such as exsiccant material resin and oxidation inhibitor, L/D=36) in the hopper, the twin screw extruder barrel zone temperature rises to 260 ℃ gradually from charging opening to head by 210 ℃, under the condition of 50 rev/mins of 100 rev/mins of extruder screw rotating speeds and feeder screw speeds above-mentioned material is extruded into bar-shaped sample through the twin screw extruder blend and promptly obtains required polyblend through the water-bath cooling and dicing again.The polyblend particle that obtains is put into convection oven and is used injection moulding machine (Chinese Liuzhou plastics machinery head factory after 2 hours in 85 ℃ of dryings, the SZ-68/400 type) is injection molded into test bars, injecting condition is 260 ℃ of barrel temperatures, 60 ℃ of die temperatures, injection pressure (gauge pressure) 10MPa.Sample is test performance after room temperature is placed 24 hours.
The test result of comparative example 1～2 and embodiment 1 as shown in Table 1.
The composition and the performance of table one comparative example 1～2 and embodiment 1 polyblend
| Test number | Comparative example 1 | Comparative example 2 | Embodiment 1 |
| Form (weight percent) PC SMA ABS ACR antioxidant 1010 | ? ????85 ????15 ? ? ????0.5 | ? ???65 ? ???35 ? ???0.5 | ? ????70 ????20 ? ????10 ????0.5 |
| The performance yield tensile strength, the MPa fracture tensile strength, the MPa elongation at break, the % flexural strength, the MPa bending elastic modulus, the MPa heat-drawn wire, ℃ vicat softening point temperature, ℃ breach IZOD shock strength, 23 ℃ of joules per meter, 3.2 6.4 | ? ????68.6 ????58.9 ????180 ????99.5 ????2528 ????128 ????144 ? ????124 ????95 ????- ????- | 53.7 43.8 79 81.0 2,256 110 124 677 472 257 (flavescence) 164 (serious flavescence) | 57.2 47.4 95 94.9 2,303 122 137 671 508 534 (nondiscolourings) 459 (nondiscolouring) |
Maleic anhydride counts 15% with weight percentage among the notes SMA, and weight-average molecular weight is 160,000.
Can find out that from above-mentioned example two kinds of direct blend of resin of PC and SMA (comparative example 1) are though the PC/SMA polyblend of preparation has higher heat-drawn wire and vicat softening point temperature, shock strength is lower; The blend of PC and ABS (comparative example 2) is though there is high shock strength, but heat-drawn wire is lower and heat aging performance is very poor, show as the low as sample of shock strength conservation rate under the thermal ageing state and dropped to 257 joules per meter through 120 ℃ of 200 hours shock strengths that wear out from 677 joules per meter, fall reaches 62%; Aging impact strength decreased amplitude was more up to 76% through 320 hours, and the outward appearance variable color of seriously turning to be yellow.And that PC/SMA/ thermoplastic elastomer (ACR) resin combination (embodiment 1) of the present invention preparation has high heat-drawn wire and shock strength and ageing-resistant performance is good, show as shock strength conservation rate height under the thermal ageing state and dropped to 534 joules per meter through 120 ℃ of aging 200 hours shock strengths from 671 joules per meter as sample, fall only has 20%; Aging impact strength decreased amplitude only had 31% through 320 hours, and nondiscoloration.
[embodiment 2～5]
With the same processing condition of embodiment 1, just maleic anhydride is 25% by weight percentage among the SMA, and weight-average molecular weight is 250,000.The weight percentage of SMA resin in resin combination becomes 10%, 30%, 40% or 35% respectively, and the weight percentage of ACR is respectively 10%, 10%, 10% or 15%, the PC/SMA/ thermoplastic elastomer resin composition performance such as the table two of preparation.
The composition and the performance of table two PC/SMA/ thermoplastic elastomer polyblend
| Test number | Embodiment 2 | Embodiment 3 | Embodiment 4 | Embodiment 5 |
| Form (weight percent) PC SMA ACR antioxidant 1010 | ???80 ???10 ???10 ???0.5 | ??60 ??30 ??10 ??0.5 | ??50 ??40 ??10 ??0.5 | ??50 ??35 ??15 ??0.5 |
| The performance yield tensile strength, the MPa fracture tensile strength, the MPa elongation at break, the % flexural strength, the MPa bending elastic modulus, the MPa heat-drawn wire, ℃ vicat softening point temperature, ℃ breach IZOD shock strength, 23 ℃ of joules per meter, 3.2 millimeters 6.4 millimeters | ? ???52.1 ???48.3 ???149 ???88.9 ???2228 ???124 ???138 ? ???684 ???704 | ? ??58.2 ??48.1 ??71 ??97.2 ??2468 ??120 ??134 ? ??558 ??296 | ? ??61.6 ??49.4 ??50 ??103 ??2683 ??119 ??134 ? ??339 ??110 | ? ??48.4 ??43.4 ??81 ??86.0 ??2247 ??116 ??130 ? ??401 ??136 |
Can find out from embodiment 2～5, along with the mechanical property (tensile strength, flexural strength, bending elastic modulus) of increase PC/SMA/ thermoplastic elastomer (ACR) polyblend of SMA resin content improves gradually, thermotolerance (heat-drawn wire, vicat softening point temperature) and shock strength decrease but still keep higher numerical value.The content that increases thermoplastic elastomer (ACR) can improve the shock strength of PC/SMA/ thermoplastic elastomer resin composition.The temperature variant curve of mechanical loss angle tangent (DMTA curve) of embodiment 1～4 resin combination finds that all alloys of the present invention all have only a second-order transition temperature (T
gAbout=151 ℃), illustrating between each composition of polyblend of the present invention has good consistency, therefore shows excellent comprehensive performances.
[embodiment 6]
Composition and processing condition are just introduced continuous alkali free glass fibre from twin screw extruder machine barrel middle part charging opening all with embodiment 1, promptly obtain glass fibre enhanced PC/SMA/ thermoplastic elastomer resin composition, its performance such as table three.
The performance of table three glass fibre enhanced PC/SMA/ thermoplastic elastomer polyblend
| Test number | Embodiment 6 |
| Form (weight percent) PC SMA ACR antioxidant 1010 titanium dioxide | ? ????70 ????20 ????10 ????0.5 ????0.5 |
| Performance calcination resistates content, the % fracture tensile strength, the MPa elongation at break, the % flexural strength, the MPa bending elastic modulus, the MPa heat-drawn wire, ℃ vicat softening point temperature, ℃ breach IZOD shock strength, 23 ℃ of joules per meter, 3.2 millimeters 6.4 millimeters | ? ????22.9 ????98.2 ????9.2 ????130 ????5641 ????135 ????142 ? ????98 ????76 |
Find out that from embodiment 6 PC/SMA/ thermoplastic elastomer polyblend of the present invention strengthens the back mechanical property through glass fibre and resistance toheat all has significantly raising, this is because PC and SMA resin that the present invention uses all have engaging force preferably with glass fibre.
Claims (8)
1, a kind of polycarbonate thermoplastic elastomer polyblend that contains comprises following component in parts by weight:
A) the bisphenol type polycarbonate is 20～90 parts;
B) atactic styrene-maleic anhydride copolymer is 1～60 part, and wherein maleic anhydride content is 5～35% by weight percentage;
C) be selected from ethylene-propylene copolymer, ethylene-propylene-diene copolymer, hydrogenated styrene-butadiene-styrene block copolymers, ethylene-vinyl acetate copolymer or the acrylate nucleocapsid structure multipolymer at least a 1～40 part;
D) be selected from ultra-violet stabilizer, oxidation inhibitor, fire retardant, mineral filler, glass fibre, pigment or the lubricant at least a 0.02～76 part.
2, according to the described polycarbonate thermoplastic elastomer polyblend that contains of claim 1, it is characterized in that the bisphenol type polycarbonate is a bisphenol A polycarbonate, by 2, two (4-hydroxy phenyl) propane of 2-and phosgene or diphenyl carbonate reaction make, weight-average molecular weight is 8000～200000, and the intrinsic viscosity that records in 25 ℃ of methylene dichloride is 0.40～1.0 liter/gram.
3, according to the described polycarbonate thermoplastic elastomer polyblend that contains of claim 1, it is characterized in that the bisphenol type polycarbonate is by two (4-hydroxy phenyl) methane, 2,2-two (3,5-dimethyl-4-hydroxy phenyl) propane, 2,2-two (3,5-two chloro-4-hydroxy phenyls) propane, 2,2-two (3,5-two bromo-4-hydroxy phenyls) propane, 1,1-bis(4-hydroxyphenyl) cyclohexane, 4, two (4-hydroxy phenyl) heptane of 4-or two (3,5-dimethyl-4-hydroxy phenyl) sulfone and phosgene or diphenyl carbonate reaction make.
4,, it is characterized in that the bisphenol type polycarbonate counts 50～90 parts with parts by weight according to the described polycarbonate thermoplastic elastomer polyblend that contains of claim 1.
5, according to the described polycarbonate thermoplastic elastomer polyblend that contains of claim 1, it is characterized in that in the parts by weight atactic styrene-maleic anhydride copolymer be 5～40 parts, wherein maleic anhydride content is 8～25% by weight percentage.
6, according to the described polycarbonate thermoplastic elastomer polyblend that contains of claim 1, it is characterized in that being selected from ethylene-propylene copolymer, ethylene-propylene-diene copolymer, hydrogenated styrene-butadiene-styrene block copolymers, ethylene-vinyl acetate copolymer or the acrylate nucleocapsid structure multipolymer at least a, is 5～25 parts in the parts by weight consumption.
7, according to the described polycarbonate thermoplastic elastomer polyblend that contains of claim 1, it is characterized in that c) component is selected from acrylate nucleocapsid structure multipolymer.
8, according to the described polycarbonate thermoplastic elastomer polyblend that contains of claim 1, it is characterized in that oxidation inhibitor is selected from antioxidant 1010, mineral filler is selected from titanium dioxide.
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| CN101205358B (en) * | 2007-09-30 | 2011-04-27 | 佛山市顺德区瑞能科技有限公司 | Polycarbonate composition having high light reflectivity and uses thereof |
| CN101851410B (en) * | 2010-06-04 | 2012-05-23 | 北京化工大学 | High-transparency high-toughness polycarbonate regenerated material compound and preparation method thereof |
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| CN103443167A (en) * | 2010-12-23 | 2013-12-11 | 拜耳知识产权有限责任公司 | Method for improving soot dispersion |
| CN103396661A (en) * | 2013-07-10 | 2013-11-20 | 深圳市科聚新材料有限公司 | Halogen-free high-heat-resistance glass fiber reinforced PC/SMA (Polycarbonate/Styrene Maleic Anhydride) alloy and preparation method thereof |
| CN103396661B (en) * | 2013-07-10 | 2016-01-27 | 深圳市科聚新材料有限公司 | A kind of Halogen-free high heat-resistant glass fiber reinforced PC/SMA alloy and preparation method thereof |
| CN103525053A (en) * | 2013-09-28 | 2014-01-22 | 昆山市周市溴化锂溶液厂 | Modified polycarbonate composition and preparation method thereof |
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