Summary of the invention
The present invention is in order to overcome weak point of the prior art, provide a kind of China ink layer blanching seal performance good, the transferring rate height, thermal adaptation is extensive, stock carrier PP, PE, PVC, aluminium foil, paper chemical fibre etc. all there is good adhesive, wear-resisting wiping, anti-boiling have the coating of the sign carbon ribbon of good bonding force with assistant coating.
The present invention is achieved through the following technical solutions: a kind of printing ink paint, comprise following component by weight percentage, polyamide resin 10-15%, modified rosin resin 6-9%, polyethylene wax 3-7%, filler 7-23%, pigment 9-11%, dispersion agent 0.1-0.5%, flow agent 0.1-0.3%, solvent 35-60%.Polyamide resin is a thermoplasticity, and in 50% ethanolic soln, softening temperature is at 80-180 ℃, 25 ℃ of viscosity, and the amine value is not more than 10.The softening temperature of modified rosin resin is at 100-150 ℃, and acid number is less than 20.Polyethylene wax is a powdery, and softening temperature is 90-140 ℃, and fineness is not more than 10 μ m.
Printing ink paint of the present invention can be transferred on the carrier of undertaking the printing of after being subjected to scald fully, and the China ink layer has adaptability widely to the carrier of undertaking the printing of, and sticking power is good, scrape resistant, anti-boiling, adhesion, the transferring rate height.
Embodiment
Example 1: the present embodiment polyamide resin is selected the P-1155 of Lauth OY for use, modified rosin fat can adopt 210 of Suichuan resin, polyethylene wax can be selected the LumaxAL3 of BASF AG for use, filler can be selected calcium carbonate superfine powder and zinc sulfide white for use, and pigment is that carbon black is selected the Cabet800 of Cabot Co.,Ltd for use, and dispersion agent is selected Bi Ke K-163 for use, flow agent is selected the product of Dow Corning Corporation for use, code 5T, solvent be for being dimethylbenzene 70% by weight percentage, Virahol 30%.Get the raw materials ready by following prescription, elder generation in solvent, is sequentially added into other components to the resin heating for dissolving again, by shredder system is uniformly dispersed, and particle diameter gets final product below depositing 10 μ m.
Polyamide resin | 15g |
Modified rosin resin | 7g |
Polyethylene wax Luwax AL3 | 5g |
Lime carbonate | 20g |
Zinc sulfide white | 3g |
Carbon black | 11g |
Dispersion agent | 0.5g |
Flow agent | 0.3g |
Solvent | 38.2g |
Example 2: the present embodiment polyamide resin is selected the P-1155 of Lauth OY for use, modified rosin fat can adopt 210 of Suichuan resin, polyethylene wax can be selected the LumaxAL3 of BASF AG for use, filler can be selected calcium carbonate superfine powder and zinc sulfide white for use, and pigment is that carbon black is selected the Cabet800 of Cabot Co.,Ltd for use, and dispersion agent is selected Bi Ke K-163 for use, flow agent is selected the product of Dow Corning Corporation for use, code 5T, solvent are dimethylbenzene 60% by weight percentage, Virahol 40%.Get the raw materials ready by following prescription, elder generation in solvent, is sequentially added into other components to the resin heating for dissolving again, by shredder system is uniformly dispersed, and particle diameter gets final product below 10 μ m.
Polyamide resin | 10g |
Modified rosin resin | 9g |
Polyethylene wax Luwax AL3 | 5g |
Lime carbonate | 12g |
Zinc sulfide white | 3g |
Carbon black | 11g |
Dispersion agent | 0.5g |
Flow agent | 0.3g |
Solvent | 49.2g |
Embodiment 3: the present embodiment polyamide resin is selected the P-1155 of Lauth OY for use, modified rosin fat can adopt 210 of Suichuan resin, polyethylene wax can be selected the LumaxAL3 of BASF AG for use, filler can be selected calcium carbonate superfine powder and zinc sulfide white for use, and pigment is that carbon black is selected the Cabet800 of Cabot Co.,Ltd for use, and dispersion agent is selected Bi Ke K-163 for use, flow agent is selected the product of Dow Corning Corporation for use, code 5T, solvent be for being dimethylbenzene 70% by weight percentage, Virahol 30%.By following prescription, elder generation in solvent, is sequentially added into other components to the resin heating for dissolving again, by shredder system is uniformly dispersed, and grain is through getting final product below 10 μ m.
Polyamide resin | 12g |
Modified rosin resin | 6g |
Polyethylene wax Luwax AL3 | 6g |
Lime carbonate | 12g |
Zinc sulfide white | 3g |
Carbon black | 11g |
Dispersion agent | 0.5g |
Flow agent | 0.3g |
Solvent | 49.2g |
Embodiment 4: the present embodiment polyamide resin is selected the P-1155 of Lauth OY for use, modified rosin fat can adopt 210 of Suichuan resin, polyethylene wax can be selected the LumaxAL3 of BASF AG for use, filler can be selected calcium carbonate superfine powder and zinc sulfide white for use, and pigment is that carbon black is selected the Cabet800 of Cabot Co.,Ltd for use, and dispersion agent is selected Bi Ke K-163 for use, flow agent is selected the product of Dow Corning Corporation for use, code 5T, solvent be for being dimethylbenzene 70% by weight percentage, Virahol 30%.By following prescription, elder generation in solvent, is sequentially added into other components to the resin heating for dissolving again, by shredder system is uniformly dispersed, and grain is through getting final product below 10 μ m.
Polyamide resin | 12g |
Modified rosin resin | 7g |
Polyethylene wax Luwax AL3 | 3g |
Lime carbonate | 12g |
Zinc sulfide white | 3g |
Carbon black | 11g |
Dispersion agent | 0.5g |
Flow agent | 0.3g |
Solvent | 51.2g |
Embodiment 5: the present embodiment polyamide resin is selected the P-1155 of Lauth OY for use, modified rosin fat can adopt 210 of Suichuan resin, polyethylene wax can be selected the LumaxAL3 of BASF AG for use, filler can be selected calcium carbonate superfine powder and zinc sulfide white for use, and pigment is that carbon black is selected the Cabet800 of Cabot Co.,Ltd for use, and dispersion agent is selected Bi Ke K-163 for use, flow agent is selected the product of Dow Corning Corporation for use, code 5T, solvent be for being dimethylbenzene 70% by weight percentage, Virahol 30%.By following prescription, elder generation in solvent, is sequentially added into other components to the resin heating for dissolving again, by shredder system is uniformly dispersed, and grain is through getting final product below 10 μ m.
Polyamide resin | 12g |
Modified rosin resin | 7g |
Polyethylene wax Luwax AL3 | 7g |
Lime carbonate | 12g |
Zinc sulfide white | 3g |
Carbon black | 11g |
Dispersion agent | 0.5g |
Flow agent | 0.3g |
Solvent | 47.2g |
Embodiment 6: the present embodiment polyamide resin is selected the P-1155 of Lauth OY for use, modified rosin fat can adopt 210 of Suichuan resin, polyethylene wax can be selected the LumaxAL3 of BASF AG for use, filler can be selected calcium carbonate superfine powder and zinc sulfide white for use, and pigment is that carbon black is selected the Cabet800 of Cabot Co.,Ltd for use, and dispersion agent is selected Bi Ke K-163 for use, flow agent is selected the product of Dow Corning Corporation for use, code 5T, solvent be for being dimethylbenzene 70% by weight percentage, Virahol 30%.By following prescription, elder generation in solvent, is sequentially added into other components to the resin heating for dissolving again, by shredder system is uniformly dispersed, and grain is through getting final product below 10 μ m.
Polyamide resin | 12g |
Modified rosin resin | 7g |
Polyethylene wax Luwax AL3 | 7g |
Lime carbonate | 20g |
Zinc sulfide white | 3g |
Carbon black | 11g |
Dispersion agent | 0.5g |
Flow agent | 0.3g |
Solvent | 39.2g |
Embodiment 7: the present embodiment polyamide resin is selected the P-1155 of Lauth OY for use, modified rosin fat can adopt 210 of Suichuan resin, polyethylene wax can be selected the LumaxAL3 of BASF AG for use, filler can be selected calcium carbonate superfine powder and zinc sulfide white for use, and pigment is that carbon black is selected the Cabet800 of Cabot Co.,Ltd for use, and dispersion agent is selected Bi Ke K-163 for use, flow agent is selected the product of Dow Corning Corporation for use, code 5T, solvent be for being dimethylbenzene 70% by weight percentage, Virahol 30%.By following prescription, elder generation in solvent, is sequentially added into other components to the resin heating for dissolving again, by shredder system is uniformly dispersed, and grain is through getting final product below 10 μ m.
Polyamide resin | 12g |
Modified rosin resin | 7g |
Polyethylene wax Luwax AL3 | 7g |
Lime carbonate | 4g |
Zinc sulfide white | 3g |
Carbon black | 11g |
Dispersion agent | 0.5g |
Flow agent | 0.3g |
Solvent | 55.2g |
Embodiment 8: the present embodiment polyamide resin is selected the P-1155 of Lauth OY for use, modified rosin fat can adopt 210 of Suichuan resin, polyethylene wax can be selected the LumaxAL3 of BASF AG for use, filler can be selected calcium carbonate superfine powder and zinc sulfide white for use, and pigment is selected red for use, and dispersion agent is selected Bi Ke K-163 for use, flow agent is selected the product of Dow Corning Corporation for use, code 5T, solvent are dimethylbenzene 60% by weight percentage, Virahol 40%.Get the raw materials ready by following prescription, elder generation in solvent, is sequentially added into other components to the resin heating for dissolving again, by shredder system is uniformly dispersed, and particle diameter gets final product below 10 μ m.By following prescription, elder generation in solvent, is sequentially added into other components to the resin heating for dissolving again, by shredder system is uniformly dispersed, and grain is through getting final product below 10 μ m.
Polyamide resin | 12g |
Modified rosin resin | 7g |
Polyethylene wax Luwax AL3 | 7g |
Lime carbonate | 12g |
Zinc sulfide white | 3g |
Red | 9g |
Dispersion agent | 0.5g |
Flow agent | 0.3g |
Solvent | 49.2g |
Embodiment 9: the present embodiment polyamide resin is selected the P-1155 of Lauth OY for use, modified rosin fat can adopt 210 of Suichuan resin, polyethylene wax can be selected the LumaxAL3 of BASF AG for use, filler can be selected calcium carbonate superfine powder and zinc sulfide white for use, and pigment is that carbon black is selected the Cabet800 of Cabot Co.,Ltd for use, and dispersion agent is selected Bi Ke K-163 for use, flow agent is selected the product of Dow Corning Corporation for use, code 5T, solvent are dimethylbenzene 60% by weight percentage, Virahol 40%.Get the raw materials ready by following prescription, elder generation in solvent, is sequentially added into other components to the resin heating for dissolving again, by shredder system is uniformly dispersed, and particle diameter gets final product below 10 μ m.By following prescription, elder generation in solvent, is sequentially added into other components to the resin heating for dissolving again, by shredder system is uniformly dispersed, and grain is through getting final product below 10 μ m.
Polyamide resin | 12g |
Modified rosin resin | 7g |
Polyethylene wax Luwax AL3 | 7g |
Lime carbonate | 20g |
Zinc sulfide white | 3g |
Carbon black | 10g |
Dispersion agent | 0.5g |
Flow agent | 0.3g |
Solvent | 40.2g |
Embodiment 10: the polyamide resin present embodiment is selected the P-1155 of Lauth OY for use, modified rosin fat can adopt 210 of Suichuan resin, polyethylene wax can be selected the LumaxAL3 of BASF AG for use, filler can be selected calcium carbonate superfine powder and zinc sulfide white for use, pigment is selected red for use, and dispersion agent is selected the K-100 of Germany for use, and flow agent is selected U.S. Yi Si Man flow agent product for use, solvent is dimethylbenzene 60% by weight percentage, Virahol 40%.By following prescription, elder generation in solvent, is sequentially added into other components to the resin heating for dissolving again, by shredder system is uniformly dispersed, and grain is through getting final product below 10 μ m.
Polyamide resin | 12g |
Modified rosin resin | 7g |
Polyethylene wax Luwax AL3 | 7g |
Lime carbonate | 20g |
Zinc sulfide white | 3g |
Red | 10g |
Dispersion agent | 0.1g |
Flow agent | 0.3g |
Solvent | 40.6g |
Embodiment 11: the polyamide resin present embodiment is selected the P-1155 of Lauth OY for use, modified rosin fat can adopt 210 of Suichuan resin, polyethylene wax can be selected the LumaxAL3 of BASF AG for use, filler can be selected calcium carbonate superfine powder and zinc sulfide white for use, pigment is selected red for use, and dispersion agent is selected the K-100 of Germany for use, and flow agent is selected U.S. Yi Si Man flow agent product for use, solvent is dimethylbenzene 60% by weight percentage, Virahol 40%.By following prescription, elder generation in solvent, is sequentially added into other components to the resin heating for dissolving again, by shredder system is uniformly dispersed, and grain is through getting final product below 10 μ m.
Polyamide resin | 12g |
Modified rosin resin | 7g |
Polyethylene wax Luwax AL3 | 7g |
Lime carbonate | 20g |
Zinc sulfide white | 3g |
Red | 10g |
Dispersion agent | 0.3g |
Flow agent | 0.3g |
Solvent | 40.4g |
Embodiment 12: the polyamide resin present embodiment is selected the P-1155 of Lauth OY for use, modified rosin fat can adopt 210 of Suichuan resin, polyethylene wax can be selected the LumaxAL3 of BASF AG for use, filler can be selected calcium carbonate superfine powder and zinc sulfide white for use, pigment is selected red for use, and dispersion agent is selected the K-100 of Germany for use, and flow agent is selected U.S. Yi Si Man flow agent product for use, solvent is dimethylbenzene 60% by weight percentage, Virahol 40%.By following prescription, elder generation in solvent, is sequentially added into other components to the resin heating for dissolving again, by shredder system is uniformly dispersed, and grain is through getting final product below 10 μ m.
Polyamide resin | 12g |
Modified rosin resin | 7g |
Polyethylene wax Luwax AL3 | 7g |
Lime carbonate | 20g |
Zinc sulfide white | 3g |
Red | 10g |
Dispersion agent | 0.3g |
Flow agent | 0.1g |
Solvent | 40.7g |
Embodiment 13: the polyamide resin present embodiment is selected the P-1155 of Lauth OY for use, modified rosin fat can adopt 210 of Suichuan resin, polyethylene wax can be selected the LumaxAL3 of BASF AG for use, filler can be selected calcium carbonate superfine powder and zinc sulfide white for use, pigment is selected red for use, and dispersion agent is selected the K-100 of Germany for use, and flow agent is selected U.S. Yi Si Man flow agent product for use, solvent is dimethylbenzene 70% by weight percentage, Virahol 30%.By following prescription, elder generation in solvent, is sequentially added into other components to the resin heating for dissolving again, by shredder system is uniformly dispersed, and grain is through getting final product below 10 μ m.
Polyamide resin | 12g |
Modified rosin resin | 7g |
Polyethylene wax Luwax AL3 | 7g |
Lime carbonate | 20g |
Zinc sulfide white | 3g |
Red | 11g |
Dispersion agent | 0.3g |
Flow agent | 0.2g |
Solvent | 39.5g |
Embodiment 14 polyamide resin present embodiments are selected the P-1155 of Lauth OY for use, modified rosin fat can adopt 210 of Suichuan resin, polyethylene wax can be selected the LumaxAL3 of BASF AG for use, filler can be selected calcium carbonate superfine powder and zinc sulfide white for use, pigment is selected red for use, and dispersion agent is selected the K-100 of Germany for use, and flow agent is selected U.S. Yi Si Man flow agent product for use, solvent is dimethylbenzene 70% by weight percentage, Virahol 30%.By following prescription, elder generation in solvent, is sequentially added into other components to the resin heating for dissolving again, by shredder system is uniformly dispersed, and grain is through getting final product below 10 μ m.:
Polyamide resin | 10g |
Modified rosin resin | 6g |
Polyethylene wax Luwax AL3 | 3g |
Lime carbonate | 8g |
Zinc sulfide white | 3g |
Red | 9.5g |
Dispersion agent | 0.3g |
Flow agent | 0.2g |
Solvent | 60g |
Embodiment 15: the polyamide resin present embodiment is selected the P-1155 of Lauth OY for use, modified rosin fat can adopt 210 of Suichuan resin, polyethylene wax can be selected the LumaxAL3 of BASF AG for use, filler can be selected calcium carbonate superfine powder and zinc sulfide white for use, pigment is selected red for use, and dispersion agent is selected the K-100 of Germany for use, and flow agent is selected U.S. Yi Si Man flow agent product for use, solvent is dimethylbenzene 60% by weight percentage, Virahol 40%.By following prescription, elder generation in solvent, is sequentially added into other components to the resin heating for dissolving again, by shredder system is uniformly dispersed, and grain is through getting final product below 10 μ m.
Polyamide resin | 15g |
Modified rosin resin | 9g |
Polyethylene wax Luwax AL3 | 7g |
Lime carbonate | 20g |
Zinc sulfide white | 3g |
Red | 10.5g |
Dispersion agent | 0.3g |
Flow agent | 0.2g |
Solvent | 35g |
The coating that makes with printing ink paint of the present invention can be transferred on the carrier of undertaking the printing of after being subjected to scald fully, the China ink layer will have adaptability widely to the carrier of undertaking the printing of, sticking power is good, scrape resistant, anti-boiling, adhesion, can be fit to the undertake the printing of blanching formula of carrier of various speed, differing temps, difference and indicate band.
Fundamental property sees the following form:
Performance | Index | Remarks |
Color | Black | The condition of boiling be 100 ℃ following 30 minutes |
Thickness | ????12-14μm |
Light Yin Wendu | ????100-150℃ |
Adapt to base material | PP, PE, PET aluminium foil etc. |
Sticking power | Anti-set-off, scrape resistant, anti-boiling |