CN1485379A - Printing ink paint - Google Patents

Printing ink paint Download PDF

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Publication number
CN1485379A
CN1485379A CNA02129268XA CN02129268A CN1485379A CN 1485379 A CN1485379 A CN 1485379A CN A02129268X A CNA02129268X A CN A02129268XA CN 02129268 A CN02129268 A CN 02129268A CN 1485379 A CN1485379 A CN 1485379A
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CN
China
Prior art keywords
resin
solvent
polyethylene wax
polyamide resin
modified rosin
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CNA02129268XA
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Chinese (zh)
Inventor
张振宇
张铁雷
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
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Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Priority to CNA02129268XA priority Critical patent/CN1485379A/en
Publication of CN1485379A publication Critical patent/CN1485379A/en
Pending legal-status Critical Current

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Abstract

A printing-ink paint. It comprises the following components by weight: 10-15% polyamide resin, 6-9% modified abietic resin, 3-7% polyethylene wax, 7-23% fillings,9-11% dyes, 0.1-0.5% dispersing agen t, 0.1-0.3% flattening agent, 35-60% solvent. Polyamide resin is thermoplastic, in 50% alcohol solution, the softening point is 80-180degree C, viscosity is 25degree C, the amine value is below 10. The softening point of modified abietic resin is 100-150degree C, the acid value thereof is below 20. The softening point of polyethylene wax is 90-140degree C, the fineness is below 10mum. The invention is mainly used to produce indication tapes.

Description

Printing ink paint
Technical field
The present invention relates to a kind of coating, more particularly relate to a kind of coating that indicates carbon ribbon.
Background technology
Its ink coating of the carbon ribbon of Xiao Shouing can not be transferred on the carrier of undertaking the printing of after being subjected under the suitable temperature to scald fully in the market, and the China ink layer is to the carrier poor adhesive force of undertaking the printing of, and scrape resistant, boiling resistance are poor.
Summary of the invention
The present invention is in order to overcome weak point of the prior art, provide a kind of China ink layer blanching seal performance good, the transferring rate height, thermal adaptation is extensive, stock carrier PP, PE, PVC, aluminium foil, paper chemical fibre etc. all there is good adhesive, wear-resisting wiping, anti-boiling have the coating of the sign carbon ribbon of good bonding force with assistant coating.
The present invention is achieved through the following technical solutions: a kind of printing ink paint, comprise following component by weight percentage, polyamide resin 10-15%, modified rosin resin 6-9%, polyethylene wax 3-7%, filler 7-23%, pigment 9-11%, dispersion agent 0.1-0.5%, flow agent 0.1-0.3%, solvent 35-60%.Polyamide resin is a thermoplasticity, and in 50% ethanolic soln, softening temperature is at 80-180 ℃, 25 ℃ of viscosity, and the amine value is not more than 10.The softening temperature of modified rosin resin is at 100-150 ℃, and acid number is less than 20.Polyethylene wax is a powdery, and softening temperature is 90-140 ℃, and fineness is not more than 10 μ m.
Printing ink paint of the present invention can be transferred on the carrier of undertaking the printing of after being subjected to scald fully, and the China ink layer has adaptability widely to the carrier of undertaking the printing of, and sticking power is good, scrape resistant, anti-boiling, adhesion, the transferring rate height.
Embodiment
Example 1: the present embodiment polyamide resin is selected the P-1155 of Lauth OY for use, modified rosin fat can adopt 210 of Suichuan resin, polyethylene wax can be selected the LumaxAL3 of BASF AG for use, filler can be selected calcium carbonate superfine powder and zinc sulfide white for use, and pigment is that carbon black is selected the Cabet800 of Cabot Co.,Ltd for use, and dispersion agent is selected Bi Ke K-163 for use, flow agent is selected the product of Dow Corning Corporation for use, code 5T, solvent be for being dimethylbenzene 70% by weight percentage, Virahol 30%.Get the raw materials ready by following prescription, elder generation in solvent, is sequentially added into other components to the resin heating for dissolving again, by shredder system is uniformly dispersed, and particle diameter gets final product below depositing 10 μ m.
Polyamide resin 15g
Modified rosin resin 7g
Polyethylene wax Luwax AL3 5g
Lime carbonate 20g
Zinc sulfide white 3g
Carbon black 11g
Dispersion agent 0.5g
Flow agent 0.3g
Solvent 38.2g
Example 2: the present embodiment polyamide resin is selected the P-1155 of Lauth OY for use, modified rosin fat can adopt 210 of Suichuan resin, polyethylene wax can be selected the LumaxAL3 of BASF AG for use, filler can be selected calcium carbonate superfine powder and zinc sulfide white for use, and pigment is that carbon black is selected the Cabet800 of Cabot Co.,Ltd for use, and dispersion agent is selected Bi Ke K-163 for use, flow agent is selected the product of Dow Corning Corporation for use, code 5T, solvent are dimethylbenzene 60% by weight percentage, Virahol 40%.Get the raw materials ready by following prescription, elder generation in solvent, is sequentially added into other components to the resin heating for dissolving again, by shredder system is uniformly dispersed, and particle diameter gets final product below 10 μ m.
Polyamide resin 10g
Modified rosin resin 9g
Polyethylene wax Luwax AL3 5g
Lime carbonate 12g
Zinc sulfide white 3g
Carbon black 11g
Dispersion agent 0.5g
Flow agent 0.3g
Solvent 49.2g
Embodiment 3: the present embodiment polyamide resin is selected the P-1155 of Lauth OY for use, modified rosin fat can adopt 210 of Suichuan resin, polyethylene wax can be selected the LumaxAL3 of BASF AG for use, filler can be selected calcium carbonate superfine powder and zinc sulfide white for use, and pigment is that carbon black is selected the Cabet800 of Cabot Co.,Ltd for use, and dispersion agent is selected Bi Ke K-163 for use, flow agent is selected the product of Dow Corning Corporation for use, code 5T, solvent be for being dimethylbenzene 70% by weight percentage, Virahol 30%.By following prescription, elder generation in solvent, is sequentially added into other components to the resin heating for dissolving again, by shredder system is uniformly dispersed, and grain is through getting final product below 10 μ m.
Polyamide resin 12g
Modified rosin resin 6g
Polyethylene wax Luwax AL3 6g
Lime carbonate 12g
Zinc sulfide white 3g
Carbon black 11g
Dispersion agent 0.5g
Flow agent 0.3g
Solvent 49.2g
Embodiment 4: the present embodiment polyamide resin is selected the P-1155 of Lauth OY for use, modified rosin fat can adopt 210 of Suichuan resin, polyethylene wax can be selected the LumaxAL3 of BASF AG for use, filler can be selected calcium carbonate superfine powder and zinc sulfide white for use, and pigment is that carbon black is selected the Cabet800 of Cabot Co.,Ltd for use, and dispersion agent is selected Bi Ke K-163 for use, flow agent is selected the product of Dow Corning Corporation for use, code 5T, solvent be for being dimethylbenzene 70% by weight percentage, Virahol 30%.By following prescription, elder generation in solvent, is sequentially added into other components to the resin heating for dissolving again, by shredder system is uniformly dispersed, and grain is through getting final product below 10 μ m.
Polyamide resin 12g
Modified rosin resin 7g
Polyethylene wax Luwax AL3 3g
Lime carbonate 12g
Zinc sulfide white 3g
Carbon black 11g
Dispersion agent 0.5g
Flow agent 0.3g
Solvent 51.2g
Embodiment 5: the present embodiment polyamide resin is selected the P-1155 of Lauth OY for use, modified rosin fat can adopt 210 of Suichuan resin, polyethylene wax can be selected the LumaxAL3 of BASF AG for use, filler can be selected calcium carbonate superfine powder and zinc sulfide white for use, and pigment is that carbon black is selected the Cabet800 of Cabot Co.,Ltd for use, and dispersion agent is selected Bi Ke K-163 for use, flow agent is selected the product of Dow Corning Corporation for use, code 5T, solvent be for being dimethylbenzene 70% by weight percentage, Virahol 30%.By following prescription, elder generation in solvent, is sequentially added into other components to the resin heating for dissolving again, by shredder system is uniformly dispersed, and grain is through getting final product below 10 μ m.
Polyamide resin 12g
Modified rosin resin 7g
Polyethylene wax Luwax AL3 7g
Lime carbonate 12g
Zinc sulfide white 3g
Carbon black 11g
Dispersion agent 0.5g
Flow agent 0.3g
Solvent 47.2g
Embodiment 6: the present embodiment polyamide resin is selected the P-1155 of Lauth OY for use, modified rosin fat can adopt 210 of Suichuan resin, polyethylene wax can be selected the LumaxAL3 of BASF AG for use, filler can be selected calcium carbonate superfine powder and zinc sulfide white for use, and pigment is that carbon black is selected the Cabet800 of Cabot Co.,Ltd for use, and dispersion agent is selected Bi Ke K-163 for use, flow agent is selected the product of Dow Corning Corporation for use, code 5T, solvent be for being dimethylbenzene 70% by weight percentage, Virahol 30%.By following prescription, elder generation in solvent, is sequentially added into other components to the resin heating for dissolving again, by shredder system is uniformly dispersed, and grain is through getting final product below 10 μ m.
Polyamide resin 12g
Modified rosin resin 7g
Polyethylene wax Luwax AL3 7g
Lime carbonate 20g
Zinc sulfide white 3g
Carbon black 11g
Dispersion agent 0.5g
Flow agent 0.3g
Solvent 39.2g
Embodiment 7: the present embodiment polyamide resin is selected the P-1155 of Lauth OY for use, modified rosin fat can adopt 210 of Suichuan resin, polyethylene wax can be selected the LumaxAL3 of BASF AG for use, filler can be selected calcium carbonate superfine powder and zinc sulfide white for use, and pigment is that carbon black is selected the Cabet800 of Cabot Co.,Ltd for use, and dispersion agent is selected Bi Ke K-163 for use, flow agent is selected the product of Dow Corning Corporation for use, code 5T, solvent be for being dimethylbenzene 70% by weight percentage, Virahol 30%.By following prescription, elder generation in solvent, is sequentially added into other components to the resin heating for dissolving again, by shredder system is uniformly dispersed, and grain is through getting final product below 10 μ m.
Polyamide resin 12g
Modified rosin resin 7g
Polyethylene wax Luwax AL3 7g
Lime carbonate 4g
Zinc sulfide white 3g
Carbon black 11g
Dispersion agent 0.5g
Flow agent 0.3g
Solvent 55.2g
Embodiment 8: the present embodiment polyamide resin is selected the P-1155 of Lauth OY for use, modified rosin fat can adopt 210 of Suichuan resin, polyethylene wax can be selected the LumaxAL3 of BASF AG for use, filler can be selected calcium carbonate superfine powder and zinc sulfide white for use, and pigment is selected red for use, and dispersion agent is selected Bi Ke K-163 for use, flow agent is selected the product of Dow Corning Corporation for use, code 5T, solvent are dimethylbenzene 60% by weight percentage, Virahol 40%.Get the raw materials ready by following prescription, elder generation in solvent, is sequentially added into other components to the resin heating for dissolving again, by shredder system is uniformly dispersed, and particle diameter gets final product below 10 μ m.By following prescription, elder generation in solvent, is sequentially added into other components to the resin heating for dissolving again, by shredder system is uniformly dispersed, and grain is through getting final product below 10 μ m.
Polyamide resin 12g
Modified rosin resin 7g
Polyethylene wax Luwax AL3 7g
Lime carbonate 12g
Zinc sulfide white 3g
Red 9g
Dispersion agent 0.5g
Flow agent 0.3g
Solvent 49.2g
Embodiment 9: the present embodiment polyamide resin is selected the P-1155 of Lauth OY for use, modified rosin fat can adopt 210 of Suichuan resin, polyethylene wax can be selected the LumaxAL3 of BASF AG for use, filler can be selected calcium carbonate superfine powder and zinc sulfide white for use, and pigment is that carbon black is selected the Cabet800 of Cabot Co.,Ltd for use, and dispersion agent is selected Bi Ke K-163 for use, flow agent is selected the product of Dow Corning Corporation for use, code 5T, solvent are dimethylbenzene 60% by weight percentage, Virahol 40%.Get the raw materials ready by following prescription, elder generation in solvent, is sequentially added into other components to the resin heating for dissolving again, by shredder system is uniformly dispersed, and particle diameter gets final product below 10 μ m.By following prescription, elder generation in solvent, is sequentially added into other components to the resin heating for dissolving again, by shredder system is uniformly dispersed, and grain is through getting final product below 10 μ m.
Polyamide resin 12g
Modified rosin resin 7g
Polyethylene wax Luwax AL3 7g
Lime carbonate 20g
Zinc sulfide white 3g
Carbon black 10g
Dispersion agent 0.5g
Flow agent 0.3g
Solvent 40.2g
Embodiment 10: the polyamide resin present embodiment is selected the P-1155 of Lauth OY for use, modified rosin fat can adopt 210 of Suichuan resin, polyethylene wax can be selected the LumaxAL3 of BASF AG for use, filler can be selected calcium carbonate superfine powder and zinc sulfide white for use, pigment is selected red for use, and dispersion agent is selected the K-100 of Germany for use, and flow agent is selected U.S. Yi Si Man flow agent product for use, solvent is dimethylbenzene 60% by weight percentage, Virahol 40%.By following prescription, elder generation in solvent, is sequentially added into other components to the resin heating for dissolving again, by shredder system is uniformly dispersed, and grain is through getting final product below 10 μ m.
Polyamide resin 12g
Modified rosin resin 7g
Polyethylene wax Luwax AL3 7g
Lime carbonate 20g
Zinc sulfide white 3g
Red 10g
Dispersion agent 0.1g
Flow agent 0.3g
Solvent 40.6g
Embodiment 11: the polyamide resin present embodiment is selected the P-1155 of Lauth OY for use, modified rosin fat can adopt 210 of Suichuan resin, polyethylene wax can be selected the LumaxAL3 of BASF AG for use, filler can be selected calcium carbonate superfine powder and zinc sulfide white for use, pigment is selected red for use, and dispersion agent is selected the K-100 of Germany for use, and flow agent is selected U.S. Yi Si Man flow agent product for use, solvent is dimethylbenzene 60% by weight percentage, Virahol 40%.By following prescription, elder generation in solvent, is sequentially added into other components to the resin heating for dissolving again, by shredder system is uniformly dispersed, and grain is through getting final product below 10 μ m.
Polyamide resin 12g
Modified rosin resin 7g
Polyethylene wax Luwax AL3 7g
Lime carbonate 20g
Zinc sulfide white 3g
Red 10g
Dispersion agent 0.3g
Flow agent 0.3g
Solvent 40.4g
Embodiment 12: the polyamide resin present embodiment is selected the P-1155 of Lauth OY for use, modified rosin fat can adopt 210 of Suichuan resin, polyethylene wax can be selected the LumaxAL3 of BASF AG for use, filler can be selected calcium carbonate superfine powder and zinc sulfide white for use, pigment is selected red for use, and dispersion agent is selected the K-100 of Germany for use, and flow agent is selected U.S. Yi Si Man flow agent product for use, solvent is dimethylbenzene 60% by weight percentage, Virahol 40%.By following prescription, elder generation in solvent, is sequentially added into other components to the resin heating for dissolving again, by shredder system is uniformly dispersed, and grain is through getting final product below 10 μ m.
Polyamide resin 12g
Modified rosin resin 7g
Polyethylene wax Luwax AL3 7g
Lime carbonate 20g
Zinc sulfide white 3g
Red 10g
Dispersion agent 0.3g
Flow agent 0.1g
Solvent 40.7g
Embodiment 13: the polyamide resin present embodiment is selected the P-1155 of Lauth OY for use, modified rosin fat can adopt 210 of Suichuan resin, polyethylene wax can be selected the LumaxAL3 of BASF AG for use, filler can be selected calcium carbonate superfine powder and zinc sulfide white for use, pigment is selected red for use, and dispersion agent is selected the K-100 of Germany for use, and flow agent is selected U.S. Yi Si Man flow agent product for use, solvent is dimethylbenzene 70% by weight percentage, Virahol 30%.By following prescription, elder generation in solvent, is sequentially added into other components to the resin heating for dissolving again, by shredder system is uniformly dispersed, and grain is through getting final product below 10 μ m.
Polyamide resin 12g
Modified rosin resin 7g
Polyethylene wax Luwax AL3 7g
Lime carbonate 20g
Zinc sulfide white 3g
Red 11g
Dispersion agent 0.3g
Flow agent 0.2g
Solvent 39.5g
Embodiment 14 polyamide resin present embodiments are selected the P-1155 of Lauth OY for use, modified rosin fat can adopt 210 of Suichuan resin, polyethylene wax can be selected the LumaxAL3 of BASF AG for use, filler can be selected calcium carbonate superfine powder and zinc sulfide white for use, pigment is selected red for use, and dispersion agent is selected the K-100 of Germany for use, and flow agent is selected U.S. Yi Si Man flow agent product for use, solvent is dimethylbenzene 70% by weight percentage, Virahol 30%.By following prescription, elder generation in solvent, is sequentially added into other components to the resin heating for dissolving again, by shredder system is uniformly dispersed, and grain is through getting final product below 10 μ m.:
Polyamide resin 10g
Modified rosin resin 6g
Polyethylene wax Luwax AL3 3g
Lime carbonate 8g
Zinc sulfide white 3g
Red 9.5g
Dispersion agent 0.3g
Flow agent 0.2g
Solvent 60g
Embodiment 15: the polyamide resin present embodiment is selected the P-1155 of Lauth OY for use, modified rosin fat can adopt 210 of Suichuan resin, polyethylene wax can be selected the LumaxAL3 of BASF AG for use, filler can be selected calcium carbonate superfine powder and zinc sulfide white for use, pigment is selected red for use, and dispersion agent is selected the K-100 of Germany for use, and flow agent is selected U.S. Yi Si Man flow agent product for use, solvent is dimethylbenzene 60% by weight percentage, Virahol 40%.By following prescription, elder generation in solvent, is sequentially added into other components to the resin heating for dissolving again, by shredder system is uniformly dispersed, and grain is through getting final product below 10 μ m.
Polyamide resin 15g
Modified rosin resin 9g
Polyethylene wax Luwax AL3 7g
Lime carbonate 20g
Zinc sulfide white 3g
Red 10.5g
Dispersion agent 0.3g
Flow agent 0.2g
Solvent 35g
The coating that makes with printing ink paint of the present invention can be transferred on the carrier of undertaking the printing of after being subjected to scald fully, the China ink layer will have adaptability widely to the carrier of undertaking the printing of, sticking power is good, scrape resistant, anti-boiling, adhesion, can be fit to the undertake the printing of blanching formula of carrier of various speed, differing temps, difference and indicate band.
Fundamental property sees the following form:
Performance Index Remarks
Color Black The condition of boiling be 100 ℃ following 30 minutes
Thickness ????12-14μm
Light Yin Wendu ????100-150℃
Adapt to base material PP, PE, PET aluminium foil etc.
Sticking power Anti-set-off, scrape resistant, anti-boiling

Claims (4)

1, a kind of printing ink paint, it is characterized in that, comprise following component by weight percentage, polyamide resin 10-15%, modified rosin resin 6-9%, polyethylene wax 3-7%, filler 7-23%, pigment 9-11%, dispersion agent 0.1-0.5%, flow agent 0.1-0.3%, solvent 35-60%.
2, printing ink paint according to claim 1 is characterized in that, described polyamide resin is a thermoplasticity, and in 50% ethanolic soln, softening temperature is at 80-180 ℃, 25 ℃ of viscosity, and the amine value is not more than 10.
3, printing ink paint according to claim 1 is characterized in that, the softening temperature of described modified rosin resin is at 100-150 ℃, and acid number is less than 20.
4, printing ink paint according to claim 1 is characterized in that, described polyethylene wax is a powdery, and softening temperature is 90-140 ℃, and fineness is not more than 10 μ m.
CNA02129268XA 2002-09-29 2002-09-29 Printing ink paint Pending CN1485379A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CNA02129268XA CN1485379A (en) 2002-09-29 2002-09-29 Printing ink paint

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Application Number Priority Date Filing Date Title
CNA02129268XA CN1485379A (en) 2002-09-29 2002-09-29 Printing ink paint

Publications (1)

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CN1485379A true CN1485379A (en) 2004-03-31

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1308404C (en) * 2004-12-28 2007-04-04 彭立安 Anti-shortsightedness ink and its preparing method
CN1311984C (en) * 2004-04-16 2007-04-25 焦作市卓立烫印材料有限公司 Character-stamping carbon foil
CN100567013C (en) * 2007-06-08 2009-12-09 焦作市卓立烫印材料有限公司 Plastic pipe marking belt
CN101134873B (en) * 2006-08-30 2010-06-09 东莞市佳景印刷材料有限公司 Abietyl modified aqueous resin amination liquid and preparation method thereof
WO2010121449A1 (en) * 2009-04-21 2010-10-28 焦作市卓立烫印材料有限公司 Digital scroll printing carbon ribbon and method for preparing the same
CN112795236A (en) * 2021-02-05 2021-05-14 广东德康化工实业有限公司 Printing ink for printing PE (polyethylene) shrink film and preparation method thereof

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1311984C (en) * 2004-04-16 2007-04-25 焦作市卓立烫印材料有限公司 Character-stamping carbon foil
CN1308404C (en) * 2004-12-28 2007-04-04 彭立安 Anti-shortsightedness ink and its preparing method
CN101134873B (en) * 2006-08-30 2010-06-09 东莞市佳景印刷材料有限公司 Abietyl modified aqueous resin amination liquid and preparation method thereof
CN100567013C (en) * 2007-06-08 2009-12-09 焦作市卓立烫印材料有限公司 Plastic pipe marking belt
WO2010121449A1 (en) * 2009-04-21 2010-10-28 焦作市卓立烫印材料有限公司 Digital scroll printing carbon ribbon and method for preparing the same
CN112795236A (en) * 2021-02-05 2021-05-14 广东德康化工实业有限公司 Printing ink for printing PE (polyethylene) shrink film and preparation method thereof

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