CN1437647A - Supertwisted nematic liquid crystal displays, liquid crystal compositions and compounds - Google Patents
Supertwisted nematic liquid crystal displays, liquid crystal compositions and compounds Download PDFInfo
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Abstract
The invention relates to supertwist liquid-crystal displays (STN-LCDs) having short switching times and good steepnesses and angle dependencies, and to the novel nematic liquid-crystal mixtures used therein, which comprise compounds of formula (A) together with compounds of formula (IB), wherein R<3>, R<4>, L<1>, L<2>, m, Y<1>, Y<2> and W have the meanings given in the text and to compounds of formula (IA).
Description
The present invention relates to have short switching time and good steepness and the STN LCD (STN-LCD) and the use therein novel nematic liquid crystal mixture of dependence of angle.
STN-LCD in the title is for example from EP O, 131,216B1; DE 3,423,993 A1; EP0,098,070 A2; M.Schadt and F.Leenhouts, 17th Freiburg conferenceon liquid crystals (8-10.04.87); People such as K.Kawasaki, SID 87 Digest391 (20.6); M.Schadt and F.Leenhouts, SID 87 Digest 372 (20.1); People such as K.katoh, Japanese Journal of Appl ied Physics, Vol.26, No.11, L 1784-L 1786 (1987); People such as F.Leenhouts, Appl.Phys.Lett.
50(21), 1468 (1987); H.A.van Sprang and H.G.Koopman, J.Appl.Phys.
62(5), 1734 (1987); T.J.Scheffer and J.Nehring, Appl.Phys.Lett.
45(10), 1021 (1984), M.Schadt and Leenhouts, Appl.Phys.Lett.
50(5), 236 (1987) and E.P.Raynes, Mol.Cryst.Liq.Cryst.Letters, Vol.4 (1) is known among the pp.1-8 (1986).Term STN-LCD comprises having 160 ° of display elements that reverse to any suitable height of 720 ° of torsion(al)angles here, display element (people such as C.M.Waters as people such as Waters, Proc.Soc.Inf.Disp. (New York) (1985) (3rd Inter.Display conference, Kobe, Japan), (DEOS 3 for STN-LCD, 503,259), SBE-LCD (T.J.Scheffer and J.Nehring, Appl.Phys.Lett.45 (1984) 1021), OM1-LCD (M.Schadt and F.Leenhouts, Appl.Phys.Lett.50 (1987), 236, DST-LCD (EP OS 0,246,842) or BW-STN-LCD (people such as K.Kawasaki, SID87 Digest 391 (20.6)).
Compare with standard TN indicating meter, the difference of this type of STN-LCD is: the obviously better steepness (being designated hereinafter simply as " steepness ") of electric light characteristic curve and the relevant therewith better correlative value and the dependence of angle of significantly lower contrast gradient.Wherein interested especially be have especially short switching time STN-LCD (especially under quite low temperature).For realizing short switching time, be with rotary viscosity up to now, particularly the rotary viscosity of liquid crystal compound is optimized, and uses the best of breed of the monotropic transformation additive of liquid crystal components and non-essential quite high vapour pressure to be optimized usually.
Yet, be not sufficient to be fit to all application the switching time that reaches.
Also can have the more liquid crystal compound realization of high birefringence Δ n by LC layer thickness and the use that reduces STN-LCD shorter switching time.
Yet the final mixture that obtains of all these methods that reaches shorter switching time still is not enough to be fit to each application.
Further requirement to STN-LCD is higher multiplex transmission performance (drive IC that causes smaller amounts), lower threshold voltage and high steepness.
For obtaining the STN-LCD of high steepness, liquid crystal compound should show quite high elastic constant K
33/ K
11Ratio and quite low Δ ε/ε
⊥Value, wherein Δ ε is a dielectric anisotropy, ε
For with the specific inductivity of long molecular axis vertical direction.
Except the optimization contrast gradient with switching time, these important requirements below these liquid crystal compounds for example also should satisfy:
1. the wide d/p window of cell gap d and pitch (pitch) p, it is defined as the lower limit of d/p value and the scope between the upper limit.
2. high chemical stability.
3. high resistance.
4. threshold voltage is to the low dependency of temperature and frequency.
Yet, can not obtain optimum parameter simultaneously for above-mentioned all these performances, because have differing materials parameter such as dielectric properties and elastic otherwise impact.Therefore, the parameters combination of Huo Deing is still not ideal enough so far, particularly for high multiplex transmission STN-LCD (having multiplex transmission rate 1/400), and the low multiplex transmission STN-LCD (the multiplex transmission rate is respectively 1/64 and 1/16) of neutralization.
Therefore, still need have short switching time and have wide use temperature scope, high steepness (promptly low steepness value), the good dependence of angle of contrast gradient and the improvement STN-LCD that satisfies above-mentioned requirements of low threshold voltage simultaneously especially.
The object of the invention is to provide STN-LCD, they only have the above-mentioned shortcoming of not half, or do not have above-mentioned shortcoming fully, and has the temperature dependency of short switching time, high steepness and improved operating voltage under the very suitable overall performance, particularly low temperature simultaneously.
Have now found that this purpose can realize that this mixture comprises the compound of formula IA by using the nematic liquid crystal mixture
With the compound of formula IB,
R wherein
3For having the alkenyl of 2 to 7 carbon atoms, R
4For having fluoridizing or alkyl, alkoxyl group, alkenyl or the alkenyloxy of nonfluorinated of 1 to 12 carbon atom, one of them or two non-conterminous CH
2Group can by-O-,-CH=CH-,-CO-,-OCO-or-COO-by the O atom directly mode adjacent one another are replace, or when m=1, R
4Also can be Q-Y, Q is CF
2, OCF
2, CFH, OCFH or singly-bound, Y is F or Cl, L
1And L
2Be H or F independently of one another, m is 0 or 1, Y
1And Y
2Be H or F independently of one another, W is
R
5For having the alkenyl or the alkynyl of 2 to 10 carbon atoms, R
6For having the alkyl or the alkoxyl group of 1 to 10 carbon atom, have 2 to 10 carbon atom chain thiazolinyls, alkenyloxy, alkynyl or alkynyloxy groups, and R
7For having the alkynyl or the alkynyloxy group of 2 to 10 carbon atoms.When W is
Or
The time, Y
1And Y
2In at least one be preferably F, most preferably be F simultaneously.
In addition usually, Y
1And Y
2In at least one be preferably F, most preferably be F simultaneously.
Use the compound of formula IA and the compound of formula IB to cause especially at the liquid crystal compound that is used for STN-LCD of the present invention:
High steepness
Have low temperature dependent low threshold voltage and
Special short switching time at low temperatures.
In addition, liquid crystal compound of the present invention shows below advantageous property:
-low viscosity,
The low temperature dependency of-threshold voltage and operating voltage and
-mixture improvement stability at low temperatures in indicating meter.
Therefore, the present invention relates to a kind of STN-LCD, it has
-two parallel outside plates of face, they form an element with framework,
-be present in the nematic liquid crystal mixture of the positive dielectric anisotropy in this element,
-electrode layer has the overlapping alignment layer on the outside plate inboard,
The longitudinal axis of-Yue 1 ° to 30 ° molecule on the lamina rara externa surface and the pre-tilt angle between the lamina rara externa and
The torsion(al)angle of liquid crystal compound in-22.5 to 600 ° the element from alignment to alignment,
Wherein the nematic liquid crystal mixture is gone up substantially by following component and is formed:
A) liquid crystal of 30-90% weight
Component A, comprise that dielectric anisotropy is greater than one or more compounds of+1.5;
B) liquid crystal of 10-55% weight
B component, comprise that dielectric anisotropy is one or more compounds of-1.5 to+1.5;
C) liquid crystal of 0-10% weight
Component D, comprise dielectric anisotropy be lower than one or more compounds of-1.5 and
D) randomly, a kind of optical activity component C, it is about 0.2 to 1.3 that its amount should make ratio between the natural pitch of layer thickness (spacing of the lamina rara externa that face is parallel) and chiral nematic liquid crystal compound,
It is characterized in that this liquid crystal compound comprises the compound of at least a formula IA
Wherein
R
3For having the alkenyl of 2 to 7 carbon atoms,
R
4For having fluoridizing or alkyl, alkoxyl group, alkenyl or the alkenyloxy of nonfluorinated of 1 to 12 carbon atom, one of them or two non-conterminous CH
2Group can by-O-,-CH=CH-,-CO-,-OCO-or-COO-by the O atom directly mode adjacent one another are replace, or when m=1, R
4Also can be Q-Y,
Q is CF
2, OCF
2, CFH, OCFH or singly-bound,
Y is F or Cl,
L
1And L
2Be H or F independently of one another,
M is 0 or 1,
Has a following general formula with at least a
Component ACompound,
Y wherein
1And Y
2Being H or F independently of one another, is F one of at least preferably, and most preferably the both is F, and W is
R
5For having the alkenyl or the alkynyl of 2 to 10 carbon atoms, R
6For having the alkyl or the alkoxyl group of 1 to 10 carbon atom, have 2 to 10 carbon atom chain thiazolinyls, alkenyloxy, alkynyl or alkynyloxy groups, and R
7For having the alkynyl or the alkynyloxy group of 2 to 10 carbon atoms.
Another object of the present invention is the liquid crystal compound of the present invention of the described STN-LCD of being used for of context.
Formula IA comprises following sub-general formula:
R wherein
3, L
1, L
2, Q and Y have formula IA implication and
R
4For having fluoridizing or alkyl, alkoxyl group, alkenyl or the alkenyloxy of nonfluorinated of 1 to 12 carbon atom, one of them or two non-conterminous CH
2Group can by-O-,-CH=CH-,-CO-,-OCO-or-COO-by the O atom directly mode adjacent one another are replace.
In formula IA-1, IA-2 and IA-3, R
3Be preferably 1E-alkenyl or 3E-alkenyl especially with 2 to 7 carbon atoms.
The particularly preferred compound of formula IA-1 is R wherein
4Be those of alkenyl with 2 to 7 carbon atoms, particularly those compounds of following formula:
R wherein
3aAnd R
4aBe H, CH independently of one another
3, C
2H
5Or just-C
3H
7And alkyl is the alkyl with 1 to 7 carbon atom.
Particularly preferably be STN-LCD of the present invention, wherein liquid crystal compound comprises at least a compound that is selected from formula IA-1a and IA-1c, wherein R
3aAnd R
4aHas identical implication respectively.
In the compound of formula IA-2, particularly preferably be wherein L
1And L
2Those of expression H.
The preferred compound of other of formula IA-2 is R wherein
4For having 1 to 8 carbon atom, the particularly alkyl of 1,2 or 3 carbon atom and R
3Be those of 1E-alkenyl with 2 to 7 carbon atoms, particularly 2,3 or 4 carbon atoms or 3E-alkenyl.
In the compound of formula IA-3, particularly preferably be wherein L
1And L
2In one or two expression F and Q-Y be F or OCF
3Those.
The preferred compound of other of formula IA-3 is R wherein
3Be those of 1E-alkenyl with 2 to 7 carbon atoms, particularly 2,3 or 4 carbon atoms or 3E-alkenyl.
Dielectric anisotropy belongs to defined above for-1.5 to+1.5 formula IA-1 and the compound of IA-2
B component, and dielectric anisotropy belongs to component A defined above greater than+1.5 formula IA-2 and the particularly polar compound of formula IA-3.
The compound combination of formula IA and IB causes having the mixture of the present invention of low especially rotary viscosity value and has high electric light curve steepness and the STN-LCD of fast switching time especially at low temperatures.
Formula IB comprises following preferred sub-general formula:
R wherein
aFor having the alkenyl of 2 to 5 carbon atoms, preferred vinyl or 3-butenyl, R
bBe alkyl with 1 to 7 carbon atom or alkenyl, preferably have the positive alkyl of 1 to 5 carbon atom, R with 2 to 7 carbon atoms
cFor having the alkynyl of 2 to 7 carbon atoms, preferred 1-pentynyl, ethyl acetylene base or 1-proyl.
Particularly preferably be the compound of formula IB1, IB3, IB6 and IB7.
Other compounds of component A are preferably selected from formula II compound,
Wherein
R has fluoridizing or alkyl, alkoxyl group, alkenyl or the alkenyloxy of nonfluorinated of 1 to 12 carbon atom, one of them or two non-conterminous CH
2Group can by-O-,-CH=CH-,-CO-,-OCO-or-COO-by the O atom directly mode adjacent one another are replace,
With
Be independently of one another
Or
L
5And L
6Be H or F independently of one another, Z
1And Z
2Be independently of one another-COO-,-CH
2CH
2-,-CH=CH-,-C ≡ C-or singly-bound and n are 0,1 or 2.The particularly preferred compound of formula II is those compounds of following formula:
Wherein R is suc as formula the definition among the II, and the R in these formulas is preferably alkyl or the alkoxyl group with 1 to 8 carbon atom especially.
Particularly preferably be the compound of formula IIa, IIb, IIc, IId and IIe, especially the compound of formula IIa and IIb.
Preferred ingredient A also comprises one or more compounds of formula III
R wherein
8For having the alkyl or the alkoxyl group of 1 to 7 carbon atom, Z
2Have a kind of implication that formula II provides independently of one another with n,
For
Or
And L
1, L
2, L
5And L
6Be H or F independently of one another.The compound of formula III is preferably selected from following formula:
Wherein R, L
1And L
2A kind of implication that has formula III independently of one another.Particularly preferably be the compound of formula III b, IIIc and IIIf, the compound of especially following sub-general formula:
R wherein
8Definition as above.The further preferably compound of formula III h, wherein L
2Be H, L
1Be H or F, particularly F.Preferred liquid crystal compound of the present invention comprises one or more compounds of formula V:
Wherein R has a kind of implication among the formula II, Y
2Be F or Cl, particularly wherein R is alkyl or alkoxyl group and/or the Y with 1 to 8 carbon atom
2Be F.
Except the compound of formula II, component A also can comprise and is selected from following general formula I I
*One or more compounds with terminal fluorine or fluorinated groups:
Wherein R, A, B, Z
1, Z
2Have a kind of implication among the formula II independently of one another with n,
L
3And L
4Be H or F independently of one another,
Y
1For F or Cl and
Q
1Be CF
2, OCF
2, CFH, OCFH or singly-bound,
Condition is L
3, L
4And Q
1-Y
1Be not simultaneously F and when n be 1, A and B are 1,4-cyclohexylidene and Z
1And Z
2During for singly-bound, R is not for having the alkenyl of 2 to 7 carbon atoms.
Formula II
*Particularly preferred compound those compounds that are following general formula:
Wherein R is suc as formula the definition among the II, L
3And L
4Be H or F independently of one another.R in these general formulas is preferably alkyl or the alkoxyl group with 1 to 8 carbon atom especially.
Formula IA, IB, II, II
*, each compound of III, V and other compound that can be used among the STN-LCD of the present invention be known, maybe can be produced, be similar to known compound and the technology for example in WO9623851, WO9105780, DE4327749, EP390329, JP2807357 or EP679707, described.The preferred compound of formula IB can be according to following path of preparing:
DCC: dicyclohexylcarbodiimide
DMAP:4-N, the N-Dimethylamino pyridine
BuLi: n-Butyl Lithium
Especially, the compound of formula IA has low viscosity, particularly low rotary viscosity, low elasticity constant ratio (K
3/ K
1) value, therefore and cause short switching time, and the compound (particularly when for example being present in the indicating meter of the present invention with a large amount) with formula II of high dielectric anisotropy causes the threshold voltage that reduces.
Can be used for the compound that preferred liquid crystal compound of the present invention contains one or more components A, preferably its ratio is 30% to 90%, preferred 45% to 75%.These compounds or this compound have greater than+3 the dielectric anisotropy of (be preferably greater than+8, particularly greater than+12).
Further preferred mixture comprises:
One or more, two kinds of compounds particularly to five kinds of formula IA,
One or more, two kinds of compounds particularly to five kinds of formula IB,
One or more, two kinds of compounds particularly to six kinds of formula II,
One or more, particularly two kinds to the compound of six kinds of formula IIIs and
One or more, the compound of particularly a kind of, two or three general formula V.
Preferred liquid crystal compound contains one or more B group compounds, and preferably its ratio is 10-45%.These compounds or this compound of B group have low rotary viscosity γ especially
1Value.
Preferred ingredient B comprises one or more compounds that are selected from the IV1 to IV9 with two rings:
And/or be selected from one or more compounds of the IV10 to IV24 with three rings:
And/or be selected from one or more compounds of the IV10 to IV24 with three rings:
R wherein
1And R
2Have a kind of implication that in formula II, R is provided independently of one another, and 1 among IV10 to IV19 and the IV23 to IV31, the 4-phenyl also can be single or polysubstituted by F independently of each other.
R wherein
2For the compound of the formula IV24 of alkenyl with 2 to 5 carbon atoms is preferred.
In the compound of formula IV25 to IV31, particularly preferably be wherein R
1Be alkyl, R
2Be those of alkyl or alkoxyl group (having 1 to 7 carbon atom separately).Further preferably L is the compound of F among formula IV25 and the IV31.
In the compound of formula IV1 to IV30, R
1And R
2Be preferably straight chained alkyl or alkoxyl group especially with 1 to 12 carbon atom.
The also optional photolytic activity that contains of LC mixture
Component C, its amount should make ratio between the natural pitch of layer thickness (spacing of the carrier board that face is parallel) and chiral nematic liquid crystal compound greater than 0.2, to be fit to required torsion(al)angle.Suitable doping agent can be selected from various known chiral materials and commercially available doping agent such as n-nonanoic acid cholesterol ester, S811 (Merck KGaA, Darmstadt, FRG) and CB 15 (MerckLtd., the former, BDH, Poole, UK).Selection itself to it is unimportant.
The amount of the compound of component C is preferably 0 to 10%, and particularly 0 to 5%, more preferably 0 to 3%.
In another embodiment preferred, the LC mixture comprises 2 to 65%, the liquid crystal tolane compound of preferred 5 to 35% (weight).So can reduce STN-LCD component thickness and switching time.Tolane compound is preferably selected from the T group compound that comprises T1a, T1b and T2a to T2h:
R wherein
1A kind of implication with R among the formula II, L
1To L
6Be H or F independently of one another, Q and Y have a kind of implication that provides among the formula I.
The particularly preferred compound of formula T2e is a group L wherein
1To L
6One, two or three are that F and all the other are H (L wherein
1With L
2, L
3With L
4And L
5With L
6Be not F simultaneously) those.
Ratio from the component of T group is preferably 2% to 65%, and particularly 5% to 35%.
The dielectric anisotropy that liquid crystal compound also can comprise 0-10% is-2 or lower one or more compounds (component D).
Component D preferably includes one or more and contains structural unit 2,3-two fluoro-1, and the compound of 4-phenylene is as the compound of describing at DE-OS 38 07 801,38 07 861,38 07 863,38 07 864 and 38 07 908 for example.Particularly preferably be the tolane compound that has according to this structural unit of PCT/DE88/00133, particularly those compounds of formula T2f and T2g.
Other known compounds of component D are for example disclosed structural unit that contains in DE-OS 32 31 707 or DE-OS 3,407 013
Or
2,3-dicyano quinhydrones or cyclohexane derivant.
The compound ratio of component D that comprises one or more compounds of dielectric anisotropy＜-1.5 is preferably about 0% to 10%, particularly about 0% to 5%.Those skilled in the art can easily regulate this ratio to produce required threshold voltage, can use all habitual liquid crystalline cpds of Δ ε＜-1.5 in principle.
Indicating meter of the present invention does not especially preferably contain the compound of component D.
At R and R
1To R
4Implication in the term alkenyl comprise straight chain and branched chain thiazolinyl, have 2 to 7 carbon atoms for R, for R, R
2, R
3And R
4Have 2 to 12 carbon atoms.Straight alkenyl is preferred.Further preferred alkenyl is C
2-C
4-1E-alkenyl, C
4-C
7-3E-alkenyl, C
5-C
7-4-alkenyl, C
6-C
7-5-alkenyl and C
7-6-alkenyl, particularly C
2-C
7-1E-alkenyl, C
4-C
7-3E-alkenyl and C
5-C
7-4-alkenyl.
The example of preferred alkenyl is vinyl, 1E-propenyl, 1E-butenyl, 1E-pentenyl, 1E-hexenyl, 1E-heptenyl, 3-butenyl, 3E-pentenyl, 3E-hexenyl, 3E-heptenyl, 4-pentenyl, 4Z-hexenyl, 4E-hexenyl, 4Z-heptenyl, 5-hexenyl and 6-heptenyl.Having at the most, the alkenyl of 5 carbon atoms is particularly preferred.More particularly preferably be vinyl, 1E-propenyl, 1E-butenyl, 3E-butenyl and 3E-pentenyl, particularly vinyl and 3E-butenyl.
In further particularly preferred embodiment, liquid crystal compound of the present invention contains:
The compound of-at least a following various IA-1a, IA-2a and IA-3a:
Wherein alkenyl and alkenyl
*Independently of one another for having the alkenyl of 2 to 7 carbon atoms, alkyl
*For having the alkyl of 1,2 or 3 carbon atom.
-one or more, the compound of preferred two to six kinds of following formula I B1, IB3, IB4 and IB5:
R wherein
aAnd R
bHas the implication that provides above.
One or more of-11 to 55% weight, preferred 15 to 42% weight, particularly two kinds of alkenyl compounds to four kinds of formula IA,
The polar chain alkenyl compound of one or more of-12 to 24% weight, particularly a kind of or two kinds of formula IA-3,
One or more of-5 to 25% weight, preferred 7 to 20% weight, particularly two kinds to the four kinds compounds that are selected from formula IB,
One or more of-12 to 48% weight, preferred 18 to 36% weight, particularly two kinds to six kinds compounds with formula III of terminal cyano group, these compounds are preferably selected from formula III b and IIIc especially,
-2 to 16% weight, one or more of preferred 3 to 9% weight, the particularly pyrimidine compound of one or both formulas V,
One or more of-2 to 35% weight, preferred 5 to 20% weight, the particularly tolane compound of two kinds to four kinds T groups, these compounds are preferably selected from formula T2a and T2b especially.
Further preferred embodiment relates to liquid crystal compound, this mixture
-containing 3 to 8 kinds of compounds of total of formula IA to IB, the amount of these compounds is 15 to 45% weight of total mixture, preferred 20 to 40% weight,
-contain greater than having of 58% weight positive dielectric anisotropy, particularly dielectric anisotropy greater than+12 compound,
-do not contain formula IV-1 to IV-31 B component compound and/or do not contain the compound of component D,
-form by the compound of formula IA, IB, II, III, V and the compound of T group basically.
Special when being used to have the STN-LCD of big element spacing, mixture of the present invention is characterised in that: the master switch time (t that it is low
Always=t
Open+ t
Close).For example the low switch time is requirement to the particularly important of STN-LCD when being used for portable computer so that its better display highlighting move.Particularly preferably being switching time is 300msec or lower, particularly 250msec or lower indicating meter.
STN-LCD of the present invention is characterised in that the threshold voltage that it is low.This threshold voltage is preferably 1.3V or lower, particularly 1.25V or lower.
Liquid crystal compound in STN-LCD of the present invention is positive dielectricity, Δ ε 〉=1.5.Particularly preferably be the mixture of Δ ε 〉=3, the mixture of more preferred Δ ε 〉=5.
Liquid crystal compound of the present invention shows favourable threshold voltage V
10/0/20With rotary viscosity γ
1If fixed light path difference d Δ n, then the value of element gap d is measured by optical anisotropy Δ n.Especially under high d Δ n value, using the liquid crystal compound of the present invention with higher delta n value is preferably, because in the case, can choose quite little d value, so causes improved switching time of value.Yet, comprise that the feature of the liquid-crystal display of the present invention of the liquid crystal compound of the present invention with less Δ n value is favourable value switching time equally.
The feature of liquid crystal compound of the present invention also is the steepness value that it is favourable, and particularly is being higher than under 20 ℃ the temperature, can drive with high multiplex transmission rate.In addition, these mixtures show the low frequency dependence of high stability, high resistance and threshold voltage.Liquid-crystal display of the present invention shows the wide operating temperature range and the good angle of visibility dependency of contrast gradient.
By the LCD element structure of the present invention that polarizer, electrode base board and surface-treated electrode (so that the preferred orientation of the liquid crystal molecule that is adjacent (passive directed dipole) is reversed 160 ° to 720 ° mutually from an electrode to another electrode usually) constitute, be equivalent to the habitual structure of this type of display device under each situation.Here the habitual structure of term is used as a broad terms, also comprises all derivatives and the improvement of super torsion element, particularly matrix display element.Surface tilt angle at two back up pad places can be identical or different, and the preferred angled angle is identical.
In TN-indicating meter of the present invention, be preferably 0 ° to 7 ° at the major axis and the pitch angle between the substrate of the molecule at substrate surface place, particularly 0.01 ° to 5 °, very preferably 0.1 to 2 °.In STN-indicating meter of the present invention, described pitch angle is preferably 1 ° to 30 °, and particularly 1 ° to 12 °, very preferably 3 ° to 10 °.
The torsion(al)angle of the liquid crystal compound between the alignment on two substrates of element is 22.5 ° to 170 ° for TN-indicating meter of the present invention, particularly 45 ° to 130 °, and very preferably 80 ° to 115 °.For the STN-indicating meter, this torsion(al)angle is 100 ° to 600 °, particularly 170 ° to 300 °, and very preferably 180 ° to 270 °.
Yet display device of the present invention and the basic difference based between the display device of twisted nematic element of habitually practising so far are the selections of liquid crystal components in liquid crystal layer.
The liquid crystal compound that the present invention uses can prepare by the mode of itself being accustomed to.Usually, the component of using with relatively small amount with aequum at high temperature is dissolved in the component that constitutes main composition easily.The solution of described component in organic solvent such as acetone, chloroform or methyl alcohol can also be mixed, and after mixing, for example remove and desolvate by distillation.
It is known and be described in other additives in the document that dielectric medium also can comprise those skilled in the art.The polygenetic dye that for example, can add 0-15%.
The following examples are used to illustrate the present invention, and do not represent a kind of restriction.
Write a Chinese character in simplified form and have following implication:
The double refraction of Δ n under 589nm and 20 ℃
T
AveAverage switching time=0.5 (t
Open+ t
Close)
t
OpenFrom being opened into the time that reaches 90% maximum countrast,
t
CloseFrom closing to the time that reaches 10% maximum countrast,
V
10Threshold voltage (volt)
V
90Saturation voltage
V
90/ V
10Steepness
γ
RotRotary viscosity (mPas)
In context, except as otherwise noted, all temperature are degree centigrade that all per-cents are weight percentage.Value when the value of switching time and viscosity is meant 20 ℃.Be average t defined above switching time
Ave
STN-LCD addresses (multiplex transmission ratio 1: 240, bias current (bias) 1: 15) in the multiplex operation mode.
In the present patent application and the following examples, all chemical structures of LC compound provide by acronym, and its conversion to chemical formula is undertaken by mode as follows.All residue C
nH
2n+1And C
mH
2m+1For having the straight chained alkyl of a n and m carbon atom respectively.Code among the table B is self-explanatory.In Table A, only provide the acronym of nuclear structure.In concrete compound, dash and substituent R are followed in this type of acronym back
1, R
2, L
1And L
2Code as follows:
The compound that provides among Table A and the B is the particularly preferred component of the present invention.R
1，R
2，L
1，
R
1R
2L
1L
2L
3L
2Code nm C
nH
2n+1C
mH
2m+1H H HnOm C
nH
2n+1OC
mH
2m+1H H HnO.m OC
nH
2n+1C
mH
2m+1H H HnmFF C
nH
2n+1OC
mH
2m+1F F HnOmFF C
nH
2n+1OC
mH
2m+1F F Hn C
nH
2n+1CN H H HnN.F C
nH
2n+1CN H F HnN.F.F C
nH
2n+1CN H F FnF C
nH
2n+1F H H HnF.F C
nH
2n+1F H F HnF.F.F C
nH
2n+1F H F FnOF OC
nH
2n+1F H H HnCl C
nH
2n+1Cl H H HnCL.F C
nH
2n+1F H F HnCL.F.F C
nH
2n+1F H F FnCF
3C
nH
2n+1CF
3H H HnOCF
3C
nH
2n+1OCF
3H H HnOCF
3.F C
nH
2n+1OCF
3H F HnOCF
3.F.F C
nH
2n+1OCF
3H F FnOCF
2C
nH
2n+1OCHF
3H H HnOCF
2.F C
nH
2n+1OCHF
3H F HnOCF
2.F.F C
nH
2n+1OCHF
3H F FnF.Cl C
nH
2n+1F H Cl Hn-V C
nH
2n+1-CH=CH
2H H HVn-m-CH=CH-C
nH
2n+1C
mH
2m+1H H H
Table A:(L
1, L
2, L
3H or F)
Table B: 
Embodiment 1STN indicating meter comprises the liquid crystal media with following performance: clearing point+91 ℃
Δn 0.1398
V
10 1.09V
V
90/ V
101.073 form by following component:
ME2N.F 8.00％
ME3N.F 9.00％
ME4N.F 11.00％
PCH-3N.F.F 10.00％
CC-3-V1 6.00％
CCG-V-F 16.00％
CCPC-33 5.00％
CCPC-34 5.00％
CCPC-35 5.00％
CBC-33F 5.00％
CBC-53F 5.00％
CBC-55F 2.00％
PPTUI-3-2 5.00％
YZU-4-N 8.00% embodiment 2STN indicating meter comprises the liquid crystal media with following performance: clearing point+90 ℃
Δn 0.1391
V
10 1.10V
V
90/ V
101.055 form by following component:
ME2N.F 8.00％
ME3N.F 9.00％
ME4N.F 12.00％
PCH-3N.F.F 10.00％
CC-3-V1 3.00％
CCG-V-F 15.00％
CCP-V-1 6.00％
CCPC-33 5.00％
CCPC-34 5.00％
CCPC-35 5.00％
CBC-33F 4.00％
CBC-53F 4.00％
PPTUI-3-2 6.00％
DU-5-N 8.00% embodiment 3STN indicating meter comprises the liquid crystal media with following performance: clearing point+91 ℃
Δn 0.1478
V
10 1.09V
V
90/ V
101.064 form by following component:
ME2N.F 8.00％
ME3N.F 9.00％
ME4N.F 12.00％
PCH-3N.F.F 10.00％
CC-3-V1 3.00％
CCG-V-F 14.00％
CCP-V-1 6.00％
CCPC-33 5.00％
CCPC-34 5.00％
CCPC-35 5.00％
CBC-33F 4.50％
CBC-53F 4.50％
PPTUI-3-2 6.00％
DU-3-N 8.00% embodiment 4STN indicating meter comprises the liquid crystal media with following performance: clearing point+89 ℃
Δn 0.1418
V
10 1.05V
V
90/ V
101.067 form by following component:
ME2N.F 8.00％
ME3N.F 8.00％
ME4N.F 9.00％
PCH-3N.F.F 10.00％
CC-3-V1 10.00％
CCG-V-F 14.00％
CCP-V-1 7.00％
CCPC-33 4.00％
CCPC-34 4.00％
CCPC-35 4.00％
CBC-33F 4.00％
CBC-53F 4.00％
PPTUI-3-2 6.00％
The fusing point of UZU-3A-N 8.00% compound UZU-3A-N is that 69 ℃ of embodiment 5STN indicating meters comprise the liquid crystal media with following performance: clearing point+90 ℃
Δn 0.1400
V
10 1.04V
V
90/ V
101.087 form by following component:
ME2N.F 8.00％
ME3N.F 9.00％
ME4N.F 10.00％
PCH-3N.F.F 10.00％
CC-3-V1 6.00％
CCG-V-F 17.00％
CCP-V-1 8.00％
CCPC-33 5.00％
CCPC-34 5.00％
CCPC-35 5.00％
CBC-33F 3.00％
PPTUI-3-2 6.00％
The fusing point of PZU-V2-N 8.00% Compound P ZU-V2-N is 37 ℃, and monotropic clearing point is that 8.2 ℃ of embodiment 6STN indicating meters comprise the liquid crystal media with following performance: clearing point+91 ℃
Δn 0.1381
V
10 1.06V
V
90/ V
101.094 form by following component:
ME2N.F 8.00％
ME3N.F 9.00％
ME4N.F 10.00％
PCH-3N.F.F 10.00％
CC-3-V1 3.00％
CCG-V-F 16.00％
CCP-V-1 8.00％
CCPC-33 5.00％
CCPC-34 5.00％
CCPC-35 5.00％
CBC-33F 3.00％
CBC-53F 3.00％
CBC-55F 3.00％
PPTUI-3-2 4.00％
Thio-A 8.00% embodiment 7STN indicating meter comprises the liquid crystal media with following performance: clearing point+90 ℃
Δn 0.1315
V
10 1.07V
V
90/ V
101.084 form by following component:
ME2N.F 8.00％
ME3N.F 9.00％
ME4N.F 12.00％
PCH-3N.F.F 10.00％
CC-3-V1 5.00％
CCG-V-F 17.00％
CCP-V-1 6.00％
CCPC-33 5.00％
CCPC-34 5.00％
CCPC-35 5.00％
CBC-33F 3.00％
CBC-53F 4.00％
PPTUI-3-2 3.00％
The fusing point of PYP-3N.F.F 8.00% Compound P YP-3N.F.F is 69 ℃.Embodiment 8STN indicating meter comprises the liquid crystal media with following performance: clearing point+91 ℃
Δn 0.1341
V
10 1.07V
V
90/ V
101.028 form by following component:
ME2N.F 8.00％
ME3N.F 9.00％
ME4N.F 10.00％
PCH-3N.F.F 10.00％
CC-3-V1 5.00％
CCG-V-F 18.00％
CCP-V-1 8.00％
CCPC-33 5.00％
CCPC-34 5.00％
CCPC-35 5.00％
CBC-33F 3.00％
CBC-53F 3.00％
PPTUI-3-2 3.00％
The fusing point of PYP-4N.F.F 8.00% Compound P YP-4N.F.F is 78 ℃.Embodiment 9STN indicating meter comprises the liquid crystal media with following performance: clearing point+90 ℃
Δn 0.1385
V
10 1.12V
V
90/ V
101.098 form by following component:
ME2N.F 8.00％
ME3N.F 8.00％
ME4N.F 11.00％
PCH-3N.F.F 10.00％
CC-3-V1 10.00％
CCG-V-F 17.00％
CCP-V-1 8.00％
CCPC-33 4.00％
CCPC-34 4.00％
CCPC-35 5.00％
PPTUI-3-2 7.00％
Thio-B 8.00% embodiment 10STN indicating meter comprises the liquid crystal media with following performance: clearing point+97 ℃
Δn 0.1613
V
10 1.23V
V
90/V
10 1.069
T
Ave163msec is made up of following component:
ME2N.F 4.00％
ME3N.F 4.00％
PCH-3N.F.F 15.00％
PZU-V2-N 14.00％
CC-3-V1 8.00％
CCP-V-1 13.00％
CVCP-V-O1 4.50％
CVCP-1V-O1 4.50％
PPTUI-3-2 16.00％
CBC-33F 4.00％
CBC-53F 4.00％
CCZU-3-F 9.00％
Claims (13)
1. STN LCD comprises
-two outside plates that face is parallel, they form an element with framework,
-be present in the nematic liquid crystal mixture of the positive dielectric anisotropy in the element,
-electrode layer has the overlapping alignment layer on the outside plate inboard, and this electrode layer is with orthogonal row waveshape each pixel of encoding,
-Yue 1 ° to 30 ° in the outside plate surface the molecule longitudinal axis and the pre-tilt angle between the outside plate and
The torsion(al)angle of liquid crystal compound in-22.5 ° to 600 ° the element from alignment to alignment,
Wherein the nematic liquid crystal mixture is gone up substantially by following component and is formed:
A) liquid crystal of 30-90% weight
Component A, comprise that dielectric anisotropy is greater than one or more compounds of+1.5;
B) liquid crystal of 10-55% weight
B component, comprise that dielectric anisotropy is one or more compounds of-1.5 to+1.5;
C) liquid crystal of 0-10% weight
Component D, comprise dielectric anisotropy be lower than one or more compounds of-1.5 and
D) optical activity component C, it is about 0.2 to 1.3 that its amount should make ratio between the natural pitch of layer thickness (spacing of the outside plate that face is parallel) and chiral nematic liquid crystal compound,
It is characterized in that this liquid crystal compound comprises the compound of at least a formula IA
Wherein
R
3For having the alkenyl of 2 to 7 carbon atoms,
R
4For having fluoridizing or alkyl, alkoxyl group, alkenyl or the alkenyloxy of nonfluorinated of 1 to 12 carbon atom, one of them or two non-conterminous CH
2Group can by-O-,-CH=CH-,-CO-,-OCO-or-COO-by the O atom directly mode adjacent one another are replace, or when m=1, R
4Also can be Q-Y,
Q is CF
2, OCF
2, CFH, OCFH or singly-bound,
Y is F or Cl,
L
1And L
2Be H or F independently of one another,
M is 0 or 1,
With at least a formula IB's
Component ACompound,
Y wherein
1And Y
2Be H or F independently of one another, W is
R
5For having the alkenyl or the alkynyl of 2 to 10 carbon atoms, R
6For having the alkyl or the alkoxyl group of 1 to 10 carbon atom, have 2 to 10 carbon atom chain thiazolinyls, alkenyloxy, alkynyl or alkynyloxy groups, and R
7For having the alkynyl or the alkynyloxy group of 2 to 10 carbon atoms.
2. according to the indicating meter of claim 1, it is characterized in that the compound of formula IA is selected from following general formula I A-1, IA-2 and IA-3:
R wherein
3, L
1, L
2, Q and Y have the implication that in the formula IA of claim 1, provides and
R
4For having fluoridizing or alkyl, alkoxyl group, alkenyl or the alkenyloxy of nonfluorinated of 1 to 12 carbon atom, one of them or two non-conterminous CH
2Group can by-O-,-CH=CH-,-CO-,-OCO-or-COO-by the O atom directly mode adjacent one another are replace.
3. according to the indicating meter of claim 1 or 2, it is characterized in that the compound of general formula I B is selected from following general formula I B1 to IB7:
R wherein
aFor having the alkenyl of 2 to 5 carbon atoms, R
bBe alkyl with 1 to 7 carbon atom or alkenyl, R with 2 to 7 carbon atoms
cFor having the alkynyl of 2 to 7 carbon atoms.
4. according to the indicating meter of an aforementioned claim, it is characterized in that,
Component AOne or more compounds that also comprise formula II:
Wherein
R has fluoridizing or alkyl, alkoxyl group, alkenyl or the alkenyloxy of nonfluorinated of 1 to 12 carbon atom, one of them or two non-conterminous CH
2Group can by-O-,-CH=CH-,-CO-,-OCO-or-COO-by the O atom directly mode adjacent one another are replace,
With
Be independently of one another
Or
L
5And L
6Be H or F independently of one another,
Z
1And Z
2Be independently of one another-COO-,-CH
2CH
2-,-CH=CH-,-C ≡ C-or singly-bound and
N is 0,1 or 2.
5. according to the indicating meter of claim 4, it is characterized in that the compound of formula II is selected from following general formula:
Wherein in R such as the claim 4 to the definition of formula II.
6. according to the indicating meter of aforementioned at least one claim, it is characterized in that,
Component AOne or more compounds that further comprise general formula III:
R wherein
8For having the alkyl or the alkoxyl group of 1 to 7 carbon atom, Z
2Have a kind of implication that in the claim 4 formula II is provided independently of one another with n,
For
Or
With
L
1, L
2, L
5And L
6Be H or F independently of one another.
7. according to the indicating meter of claim 6, it is characterized in that the compound of formula III is selected from following general formula:
R wherein
8As in the claim 6 to the definition of formula III.
8. according to the indicating meter of at least one of claim 1 to 7, it is characterized in that liquid crystal compound further comprises the compound of one or more formulas V:
Wherein R has a kind of implication that in the claim 4 formula II is provided, Y
2Be F or Cl.
9. according to the indicating meter of at least one of claim 1 to 8, it is characterized in that liquid crystal compound contains the compound of 3 to 8 kinds of formula IA and IB altogether, wherein the amount of these compounds is 15 to 45% weight of total mixture.
10. according to the indicating meter of at least one of claim 1 to 9, it is characterized in that liquid crystal compound comprises greater than the positive dielectric anisotropy of 58% weight greater than one or more compounds of+12.
11. the indicating meter according at least one of claim 1 to 10 is characterized in that, its threshold voltage is 1.3V or lower.
12. as defined liquid crystal compound or composition at least one item of claim 1 to 11.
13. the compound of formula I,
Y wherein
1And Y
2Be H or F independently of one another, W is
R
5For having the alkenyl or the alkynyl of 2 to 10 carbon atoms,
R
6For having the alkyl or the alkoxyl group of 1 to 10 carbon atom, have 2 to 10 carbon atoms alkenyl, alkenyloxy, alkynyl or alkynyloxy group and
R
7For having the alkynyl or the alkynyloxy group of 2 to 10 carbon atoms.
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP00104080.7 | 2000-02-28 | ||
| DE10009234.9 | 2000-02-28 | ||
| DE10009234 | 2000-02-28 | ||
| EP00104080 | 2000-02-28 |
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| Publication Number | Publication Date |
|---|---|
| CN1437647A true CN1437647A (en) | 2003-08-20 |
| CN1248033C CN1248033C (en) | 2006-03-29 |
Family
ID=26004546
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB008192170A Expired - Fee Related CN1248033C (en) | 2000-02-28 | 2000-12-14 | Supertwisted nematic liquid crystal displays, liquid crystal compositions and compounds |
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| Country | Link |
|---|---|
| EP (1) | EP1261679A1 (en) |
| JP (1) | JP5236140B2 (en) |
| CN (1) | CN1248033C (en) |
| AU (1) | AU2001223656A1 (en) |
| WO (1) | WO2001064814A1 (en) |
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| CN102660298A (en) * | 2012-05-16 | 2012-09-12 | 河北迈尔斯通电子材料有限公司 | Mixed liquid crystal material for electric meter of smart grid |
| CN115029142A (en) * | 2021-03-04 | 2022-09-09 | 北京八亿时空液晶科技股份有限公司 | Liquid crystal composition and application thereof |
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| US7045176B2 (en) * | 2002-11-28 | 2006-05-16 | Samsung Electronics Co., Ltd. | Liquid crystal composition having high-speed response property and liquid crystal display using the same |
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| DE19707956A1 (en) * | 1997-02-27 | 1998-09-03 | Merck Patent Gmbh | TN and STN liquid crystal display |
| DE19732502A1 (en) * | 1997-07-29 | 1999-02-04 | Merck Patent Gmbh | STN liquid crystal display |
| TW579388B (en) * | 1997-11-28 | 2004-03-11 | Dainippon Ink & Chemicals | Fluorine-substituted-4-alkenylbenzoic acid and derivatives thereof, and nematic liquid crystal composition containing cyanophenyl benzoate derivatives and liquid crystal display system using the same |
| DE69938744D1 (en) * | 1998-11-19 | 2008-06-26 | Merck Patent Gmbh | Supertwist nematic liquid crystal displays |
| EP1310541B1 (en) * | 1998-11-19 | 2008-05-14 | MERCK PATENT GmbH | Supertwisted nematic liquid crystal displays |
| DE10018598A1 (en) * | 1999-04-30 | 2000-11-02 | Merck Patent Gmbh | Electro-optical liquid crystal display and medium for active matrix display with in-plane switching contains 4-cyanophenyl benzoate and also benzonitrile and/or phenyl ester compounds |
| AU2001223692A1 (en) * | 2000-02-07 | 2001-08-20 | Merck Patent G.M.B.H | Benzoic acid esters, and liquid-crystalline medium |
| DE60101239T2 (en) * | 2000-03-07 | 2004-08-26 | Merck Patent Gmbh | Supertwist nematic liquid crystal displays |
-
2000
- 2000-12-14 CN CNB008192170A patent/CN1248033C/en not_active Expired - Fee Related
- 2000-12-14 JP JP2001564304A patent/JP5236140B2/en not_active Expired - Fee Related
- 2000-12-14 EP EP00987402A patent/EP1261679A1/en not_active Withdrawn
- 2000-12-14 WO PCT/EP2000/012732 patent/WO2001064814A1/en active Application Filing
- 2000-12-14 AU AU2001223656A patent/AU2001223656A1/en not_active Abandoned
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102660298A (en) * | 2012-05-16 | 2012-09-12 | 河北迈尔斯通电子材料有限公司 | Mixed liquid crystal material for electric meter of smart grid |
| CN102660298B (en) * | 2012-05-16 | 2014-04-23 | 河北迈尔斯通电子材料有限公司 | Mixed liquid crystal material for electric meter of smart grid |
| CN115029142A (en) * | 2021-03-04 | 2022-09-09 | 北京八亿时空液晶科技股份有限公司 | Liquid crystal composition and application thereof |
| WO2022184098A1 (en) * | 2021-03-04 | 2022-09-09 | 北京八亿时空液晶科技股份有限公司 | Liquid crystal composition and application thereof |
| CN115029142B (en) * | 2021-03-04 | 2023-10-24 | 北京八亿时空液晶科技股份有限公司 | Liquid crystal composition and application thereof |
| TWI820620B (en) * | 2021-03-04 | 2023-11-01 | 大陸商北京八億時空液晶科技股份有限公司 | A kind of liquid crystal composition and its application |
Also Published As
| Publication number | Publication date |
|---|---|
| JP2003525474A (en) | 2003-08-26 |
| EP1261679A1 (en) | 2002-12-04 |
| JP5236140B2 (en) | 2013-07-17 |
| CN1248033C (en) | 2006-03-29 |
| AU2001223656A1 (en) | 2001-09-12 |
| WO2001064814A1 (en) | 2001-09-07 |
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