CN1433834A - Method for urea catalyst simultaneously processing flue gas and desulfurizing denitrification - Google Patents
Method for urea catalyst simultaneously processing flue gas and desulfurizing denitrification Download PDFInfo
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- CN1433834A CN1433834A CN03113768A CN03113768A CN1433834A CN 1433834 A CN1433834 A CN 1433834A CN 03113768 A CN03113768 A CN 03113768A CN 03113768 A CN03113768 A CN 03113768A CN 1433834 A CN1433834 A CN 1433834A
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- urea
- flue gas
- absorption liquid
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- titanium dioxide
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
- Y02A50/20—Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters
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Abstract
The present invention relates to a method for desulfurization and denitrogenation at the same time of treating flue gas by using urea catalyst. Said method uses the urea as absorbing agent, and uses titanium dioxide or diatomite as catalyst to prepare absorption liquor, makes the flue gas mixw ith the absorption liquor to recover ammonium sulfate and ammonium nitrate, and can make comprehensive utilization to prepare fertilizer. Said invention is high-effective, can stably remove SO2 and NOx, the SO2 removing rate is up to above 95% and the NOx removing rate is up to 80%. It has no secondary pollution and is low in cost, so that it is suitable for industrial production.
Description
(1) technical field
The present invention relates to boiler flue gas purification and administer technical field, specifically refer to the simultaneously method of desulfurization removing nitric of a kind of urea seeding agent smoke treatment.
(2) background technology
Atmosphere pollution is one of serious problems of facing of 21st century human society survival and development. And the most serious atmosphere pollution is the acidifying pollution, and amount of pollutant is large, and pollution range is wide, causes regional environment acidifying. The environment acidifying mainly comes from the sulfur dioxide-SO with toxic emission2(sulfur dioxide) and nitrogen oxide-NOX(nitrogen oxides), the processes such as industrial production, communications and transportation, castoff burning and civilian burning all can give off SO2、NO
X, particularly the boiler combustion pollution is the most serious, 90% SO in the air2With 60% NOxFlue gas from the boiler combustion discharging. At present, the method for home and abroad simultanously desulfurizing and denitrification mainly contains following several: (1) plasma method, and it comprises two kinds of electron beam and impulse electric coronas, and this technique is very complicated, and it is volatile to adopt ammonia to make absorbent, causes ammonia loss and exhaust pollution. Korea S has the people to utilize low-temperature plasma reactor to carry out flue gas desulfuration and denitrification, but the secondary wastewater that produces pollution also is difficult to process; (2) catalysis method is in lab scale or pilot scale stage at present, and the preparation of catalyst system therefor and the complexity of regenerating, and it is volatile to adopt ammonia to make absorbent simultaneously, causes ammonia loss and exhaust pollution; (3) wet chemical, chemical method mostly is used for desulfuration in furnace and takes off, the wet flue gas of having studied simultaneously desulfurization removing nitric technology is iron complex method, iron complex liquid-film method mostly, polyethylene glycol and ethylene glycol amine liquid-film method also someone are studied, these methods are the same with low-temperature plasma technique, and the secondary wastewater of generation pollutes and is difficult to process. Chinese patent application 01130154.6 discloses a kind of " wet urea additive process for simultanously desulfurizing and denitrification ", the method is utilized a set of equipment that is comprised of dispensing canister, absorption tower, dense circulating absorption solution storage pond, evaporimeter, drying machine, make absorbent, organic amine or phosphoric acid salt with urea and make additive, remove the SO in the flue gas2And NOx, and the reclaim sulfuric acid ammonium is made fertilizer. But the additive relative cost of the most critical that the method is utilized is higher, has limited industrial applications.
(3) summary of the invention
Purpose of the present invention is exactly in order to solve the deficiencies in the prior art part, and the simultaneously method of desulfurization removing nitric of a kind of urea seeding agent smoke treatment is provided. The method technique is simple, stability and high efficiency, and with low cost.
A kind of urea seeding agent smoke treatment of the present invention is the method for desulfurization removing nitric simultaneously, makes absorbent with urea, and flue gas enters continuously from the absorption tower import, with the abundant hybrid reaction of absorption liquid, removes SO in the absorption tower2And NOx, it is characterized in that, adopt titanium dioxide or diatomite to make the catalyst preparation absorption liquid, and reclaim sulfuric acid ammonium and ammonium nitrate are made fertilizer.
In order to realize better the present invention, being formulated as of described absorption liquid: in dispensing canister, add entry, urea and titanium dioxide or diatomite catalyst, the weight percent content that makes urea is 5～30%, and titanium dioxide or diatomaceous weight percent content are (50～500) * 10-4%, the weight percent content of water are 69.95～94.995%, get final product after stirring with mixer; The removal process of described ammonium sulfate and ammonium nitrate is: absorption liquid enters dense circulating absorption solution pond and stores, by the evaporation feed pump absorption liquid is pumped into evaporimeter again, after evaporation and concentration to total solid percentage by weight is 70～85%, pump in the drying machine dry by the dry feed pump again, make chemical fertilizer ammonium sulfate and ammonium nitrate, emit comprehensive utilization of resources from outlet.
The present invention compared with prior art has following advantage and beneficial effect:
But the inventive method Simultaneous Stabilization ground, remove SO efficiently2、NO
x, miniature boiler is smoke abatement simultaneously.
2. the byproduct of the inventive method is ammonium sulfate (NH4)
2SO
4And ammonium nitrate, comprehensive utilization is as fertilizer; And the urea absorption agent is not volatile overflows non-secondary pollution with flue gas.
3. absorbent urea of the present invention and byproduct of ammonium sulfate and ammonium nitrate easily transport, store.
4. the catalyst of the present invention's employing is with low cost, and can recycle and reuse.
Simple, the small investment of the inventive method technological process (for wet desulphurization equipment commonly used 1/3～1/2), operating cost has competitiveness.
(4) specific embodiment
Below in conjunction with embodiment, the present invention is done in further detail explanation.
The inventor has a lot of successful examples of implementation through research, the test of long period. The below tabulates four embodiment in table 1. Table 1
| The absorption liquid preparation | In the tank, add entry, urea and titanium dioxide, the content that makes urea is 5%, and content of titanium dioxide is 500 * 10-4%, the content of water is 94.95%, stirs. | In the tank, add entry, urea and titanium dioxide, the content that makes urea is 30%, and content of titanium dioxide is 50 * 10-4%, the content of water is 69.995%, stirs. | In, adding entry, urea, diatomite, the content that makes urea is 5%, diatomite content is 500 * 10-4%, the content of water is 94.95%, stirs. | In the tank, add entry, urea, diatomite, the content that makes urea is 30%, and diatomite content is 50 * 10-4%, the content of water is 69.995%, stirs. |
| Process conditions | Absorb 1～3 meter of tower height without nozzle atomization, _=0.6 meter, flue-gas temperature is 250 ℃, SO2Concentration is 500 * 10-4％，NO xConcentration is 3000 * 10-4%, liquid-gas ratio are 10 liters/cubic metre, and gas speed is 5 meter per seconds | Absorb 1～3 meter of tower height without nozzle atomization, _=0.6 meter, flue-gas temperature is 40 ℃, SO2Concentration is 4000 * 10-4％，NO xConcentration is 300 * 10-4%, liquid-gas ratio are 0.5 liter/cubic metre, and gas speed is 1 meter per second | Absorb 1～3 meter of tower height without nozzle atomization, _=0.6 meter, flue-gas temperature is 250 ℃, SO2Concentration is 500 * 10-4 ％，NO xConcentration is 3000 * 10-4%, liquid-gas ratio are 10 liters/cubic metre, and gas speed is 5 meter per seconds | Absorb 1～3 meter of tower height without nozzle atomization, _=0.6 meter, flue-gas temperature is 40 ℃, SO2Concentration is 4000 * 10-4％，NO xConcentration is 300 * 10-4%, liquid-gas ratio are 0.5 liter/cubic metre, and gas speed is 1 meter per second |
| Process and result | Absorption liquid is placed the absorption tower forced circulation, allow flue gas continuously by the absorption tower, flue gas generates ammonium sulfate, ammonium nitrate and nitrogen on absorption tower and urea reaction as a result, and ammonium sulfate, ammonium nitrate are concentrated into 70%, and drying is made fertilizer again; SO as a result2Clearance 95% with | Absorption liquid is placed the absorption tower forced circulation, allow flue gas continuously by the absorption tower, flue gas generates ammonium sulfate, ammonium nitrate and nitrogen on absorption tower and urea reaction as a result, and ammonium sulfate, ammonium nitrate are concentrated into 85%, and drying is made fertilizer again; SO as a result2Clearance 95% with | Absorption liquid is placed the absorption tower forced circulation, allow flue gas continuously by the absorption tower, flue gas generates ammonium sulfate, ammonium nitrate and nitrogen on absorption tower and urea reaction as a result, and ammonium sulfate, ammonium nitrate are concentrated into 75%, and drying is made fertilizer again; SO as a result2Clearance 95% with | Absorption liquid is placed the absorption tower forced circulation, allow flue gas continuously by the absorption tower, flue gas generates ammonium sulfate, ammonium nitrate and nitrogen on absorption tower and urea reaction as a result, and ammonium sulfate, ammonium nitrate are concentrated into 85%, and drying is made fertilizer again; SO as a result2Clearance 95% with |
| On, NOxClearance is more than 80%. | On, NOxClearance is more than 80%. | On, NOxClearance is more than 80%. | On, NOxClearance is more than 80%. |
Claims (3)
1. the method for a urea seeding agent smoke treatment while desulfurization removing nitric is made absorbent with urea, and flue gas enters continuously from the absorption tower import, with the abundant hybrid reaction of absorption liquid, removes SO in the absorption tower2And NOx, it is characterized in that, adopt titanium dioxide or diatomite to make the catalyst preparation absorption liquid, and reclaim sulfuric acid ammonium and ammonium nitrate are made fertilizer.
2. the described a kind of urea seeding agent smoke treatment method of desulfurization removing nitric simultaneously according to claim 1, it is characterized in that, being formulated as of described absorption liquid: in dispensing canister, add entry, urea and titanium dioxide or diatomite catalyst, the weight percent content that makes urea is 5～30%, and titanium dioxide or diatomaceous weight percent content are (50～500) * 10-4%, the weight percent content of water are 69.95～94.995%, get final product after stirring with mixer.
3. the described a kind of urea seeding agent smoke treatment method of desulfurization removing nitric simultaneously according to claim 1, it is characterized in that, the removal process of described ammonium sulfate and ammonium nitrate is: absorption liquid enters dense circulating absorption solution pond and stores, by the evaporation feed pump absorption liquid is pumped into evaporimeter again, after evaporation and concentration to total solid percentage by weight is 70～85%, pump into drying in the drying machine by the dry feed pump again, make chemical fertilizer ammonium sulfate and ammonium nitrate, emit comprehensive utilization of resources from outlet.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB031137687A CN1192814C (en) | 2003-02-20 | 2003-02-20 | Method for urea catalyst simultaneously processing flue gas and desulfurizing denitrification |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB031137687A CN1192814C (en) | 2003-02-20 | 2003-02-20 | Method for urea catalyst simultaneously processing flue gas and desulfurizing denitrification |
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| CN1433834A true CN1433834A (en) | 2003-08-06 |
| CN1192814C CN1192814C (en) | 2005-03-16 |
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Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100340325C (en) * | 2005-09-29 | 2007-10-03 | 华南理工大学 | Flue gas simultaneous desulfurization and denitrogenation by utilizing triethylenediamine cobalt (III) and carbamide |
| CN100425327C (en) * | 2005-12-23 | 2008-10-15 | 浙江大学 | Chloric strong oxidant enhanced wet combined urea desulfurizing and denitrifying process |
| CN100425326C (en) * | 2005-12-23 | 2008-10-15 | 浙江大学 | Alkali earth metal compound enhanced wet combined urea desulfurizing and denitrifying process |
| CN100460045C (en) * | 2006-05-31 | 2009-02-11 | 中国石油化工股份有限公司 | Process for disposing SOx in discharge gas |
| CN101797505A (en) * | 2010-04-22 | 2010-08-11 | 华中科技大学 | Desulfuration and denitration catalyst and preparation method thereof |
| CN101653695B (en) * | 2009-09-18 | 2011-06-08 | 王子国 | Method of byproduct compound fertilizer by desulfurizing and denitrifying smoke gas by urea catalytic partial reaction |
| CN1843575B (en) * | 2006-03-29 | 2012-07-04 | 华北电力大学 | Method and apparatus for optic catalytic oxidizing, desulfurizing and denitrifying flue gas simultaneously |
| CN102698599A (en) * | 2012-05-25 | 2012-10-03 | 湖南湘达环保工程有限公司 | Synchronous desulfurization and denitration method for smoke by using urine as absorbent |
| CN104722199A (en) * | 2015-03-02 | 2015-06-24 | 内蒙古阜丰生物科技有限公司 | Smoke-removing and dust-removing method of amino-acid production process |
| CN104722165A (en) * | 2015-03-03 | 2015-06-24 | 内蒙古阜丰生物科技有限公司 | Environmental-protection process for purifying tail gas in production of amino acid |
| CN104722183B (en) * | 2015-03-02 | 2016-07-27 | 内蒙古阜丰生物科技有限公司 | The process technique of the flue gas that one seed amino acid preparation process produces |
| CN106178904A (en) * | 2016-09-09 | 2016-12-07 | 成都九十度工业产品设计有限公司 | A kind of emission-control equipment and waste gas processing method |
| CN106823721A (en) * | 2017-02-23 | 2017-06-13 | 中国石油大学(北京) | A kind of flue gas desulfurization and denitrification agent and its preparation method and application |
-
2003
- 2003-02-20 CN CNB031137687A patent/CN1192814C/en not_active Expired - Fee Related
Cited By (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100340325C (en) * | 2005-09-29 | 2007-10-03 | 华南理工大学 | Flue gas simultaneous desulfurization and denitrogenation by utilizing triethylenediamine cobalt (III) and carbamide |
| CN100425327C (en) * | 2005-12-23 | 2008-10-15 | 浙江大学 | Chloric strong oxidant enhanced wet combined urea desulfurizing and denitrifying process |
| CN100425326C (en) * | 2005-12-23 | 2008-10-15 | 浙江大学 | Alkali earth metal compound enhanced wet combined urea desulfurizing and denitrifying process |
| CN1843575B (en) * | 2006-03-29 | 2012-07-04 | 华北电力大学 | Method and apparatus for optic catalytic oxidizing, desulfurizing and denitrifying flue gas simultaneously |
| CN100460045C (en) * | 2006-05-31 | 2009-02-11 | 中国石油化工股份有限公司 | Process for disposing SOx in discharge gas |
| CN101653695B (en) * | 2009-09-18 | 2011-06-08 | 王子国 | Method of byproduct compound fertilizer by desulfurizing and denitrifying smoke gas by urea catalytic partial reaction |
| CN101797505A (en) * | 2010-04-22 | 2010-08-11 | 华中科技大学 | Desulfuration and denitration catalyst and preparation method thereof |
| CN102698599A (en) * | 2012-05-25 | 2012-10-03 | 湖南湘达环保工程有限公司 | Synchronous desulfurization and denitration method for smoke by using urine as absorbent |
| CN104722199A (en) * | 2015-03-02 | 2015-06-24 | 内蒙古阜丰生物科技有限公司 | Smoke-removing and dust-removing method of amino-acid production process |
| CN104722183B (en) * | 2015-03-02 | 2016-07-27 | 内蒙古阜丰生物科技有限公司 | The process technique of the flue gas that one seed amino acid preparation process produces |
| CN104722199B (en) * | 2015-03-02 | 2016-07-27 | 内蒙古阜丰生物科技有限公司 | The smoke abatement of amino acids production technique takes off dust collecting method |
| CN104722165A (en) * | 2015-03-03 | 2015-06-24 | 内蒙古阜丰生物科技有限公司 | Environmental-protection process for purifying tail gas in production of amino acid |
| CN104722165B (en) * | 2015-03-03 | 2016-02-24 | 内蒙古阜丰生物科技有限公司 | A kind of environment-protective process purifying amino acids production tail gas |
| CN106178904A (en) * | 2016-09-09 | 2016-12-07 | 成都九十度工业产品设计有限公司 | A kind of emission-control equipment and waste gas processing method |
| CN106823721A (en) * | 2017-02-23 | 2017-06-13 | 中国石油大学(北京) | A kind of flue gas desulfurization and denitrification agent and its preparation method and application |
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| Publication number | Publication date |
|---|---|
| CN1192814C (en) | 2005-03-16 |
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Granted publication date: 20050316 Termination date: 20100220 |