CN1431107A - Car air conditioner making use of quantity of cold of liquefied natural gas - Google Patents

Car air conditioner making use of quantity of cold of liquefied natural gas Download PDF

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Publication number
CN1431107A
CN1431107A CN 03114438 CN03114438A CN1431107A CN 1431107 A CN1431107 A CN 1431107A CN 03114438 CN03114438 CN 03114438 CN 03114438 A CN03114438 A CN 03114438A CN 1431107 A CN1431107 A CN 1431107A
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heat exchanger
cold
natural gas
liquefied natural
air conditioner
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CN100434292C (en
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厉彦忠
王强
陈曦
王江
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Xian Jiaotong University
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Xian Jiaotong University
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Abstract

An air conditioner using the cold of liquefied natural gas for automobile is composed of liquefied natural gas cylinder, coiled-tube beat exchanger arranged in said cylinder, sleeve-tube heat exchanger, finned heat exchanger, cold-accumulating ethanediol box, air cooling heat exchanger and liquid pump, which are communicated. The said fined heat exchanger is communicated with engine via low-pressure gas accumulator and condenser. The cooling water of engine is cooled by heat exchanger and then used to cool engine. Its advantages are better transient and steady-state performance and better cold balancing and regulating function.

Description

Utilize the motorcar air conditioner of cold energy of liquefied natural gas
One, affiliated technical field
The invention belongs to the technical field that eco-friendly car, New Refrigerating method and energy efficient utilize, relate to a kind of motorcar air conditioner that utilizes cold energy of liquefied natural gas.
Two, background technology
Along with the continuous development of auto-industry, natural fuels is used widely as the oligosaprobic alternative motor fuels of a kind of cleaning.Because the normal boiling point low (about 110K) of natural fuels, the more normal temperature compressed natural fuels of application (CNG) mode is about to the natural fuels compression at present, is stored in the bomb interior (gas that can hold 240 times of standard condition lower volume) of 20MPa.Because high pressure storage tank wall thickness, vehicle-mounted heavy exists poor safety performance, a shortcoming such as travelled distance weak point, has restricted the development of natural gas-powered car to a great extent.Liquefied natural gas (LNG) automobile has remedied many deficiencies of CNG automobile, it replaces compressing storage mode in the mode of the liquid storage of atmospheric low-temperature, storage density is 660 times of gas under the standard condition, thereby storage volume reduces greatly, and energy storage density increases, and it is long once to charge continuous travelled distance, and vehicle-mounted container pressure is low, in light weight, safe ready is a kind of motor vehicle fuel that has more advantages for development.
Liquefied natural gas (LNG) is stored under the low temperature of 110K, must re-heat arrive the normal temperature state when entering the automotive engine burning.LNG will discharge a large amount of cold energy vaporizing to the normality process, its refrigerating capacity is about 0.1kWh/L.If this part cold energy is rationally reclaimed, as the low-temperature receiver of vehicle-mounted refrigerating system, as be used for miniature car air-conditioning, motorcoach refrigerator, refrigerating transport vehicle etc., just can save existing mechanical compression automobile refrigerating system.Both saved energy, and reduced the mechanical noise pollution, the air environment that can stop again to be caused because of the CFCs freezing medium leakage is destroyed.Thereby the LNGV (LNGV) of realizing total energy approach is a kind of environmental protection automobile truly.
Use the development tendency of LNGV fairly obvious in the world, China is still in starting.The cold recovery technology of LNG automobile is also at the early-stage in the world, and present German Messer company has developed the platform LNG refrigerating transport vehicle of informing against, and test effect is good.Do not retrieve at present the technical materials of other relevant these aspects as yet.
Three, summary of the invention
The objective of the invention is to, a kind of motorcar air conditioner that utilizes cold energy of liquefied natural gas is provided, utilize cold energy of liquefied natural gas to prepare the LNG motorcar air conditioner, is the thought that the applicant proposes first, and through the in-depth study in 2 years, has confirmed its feasibility.Design philosophy content of the present invention is:
1) LNGV (LNGV) substitutes automobile with compressed natural gas (CNGV) can to solve the automobile load few, and travelled distance is short continuously, safe reliability is low wait not enough.
The cold that discharges during 2) with the LNG re-heat is used for air conditioning for automobiles, realizes that cold energy reclaims, distributes rationally and energy-conservation innovative idea.
3) the LNG motorcar air conditioner replaces traditional fluorine Lyons steam compression type motorcar air conditioner, has reduced the equipment investment of this part on the one hand, and the noise emission when having eliminated compressor operating has reduced fault rate and operating maintenance expense; Fundamentally stopped CFCs refrigerant leakage problem on the other hand.According to statistics, the CFC that the whole world leaks in the atmosphere every year reaches 5.2 ten thousand tons, and wherein 75% is that air conditioning for automobiles leaks, the leakage havoc of CFC atmospheric ozone layer, worsened the environment of human survival.The birth of LNG motorcar air conditioner will fundamentally change this present situation.
4) LNGV (LNGV) has reached energy-conservation and dual purpose environmental protection with the combination of LNG motorcar air conditioner.This achievement in research will provide new thinking for the development of automobile refrigerating air-conditioning.
5) solve wherein many gordian techniquies, realized the big temperature difference heat exchange under the worst cold case.
To achieve these goals, the present invention proposes the motorcar air conditioner that utilizes cold energy of liquefied natural gas, the technical scheme that is adopted has following characteristics: this motorcar air conditioner comprises liquefied natural gas cylinder, coil heat exchanger, double-tube heat exchanger, plate-fin heat exchanger, ethylene glycol cold-accumulating box, air cooling heat exchanger, liquid pump.The equipment relevant with A/C has condenser, coolant storage tank, automotive engine.Coil heat exchanger is arranged in the liquefied natural gas cylinder, and is communicated with double-tube heat exchanger and plate-fin heat exchanger; Tube exchanger is realized the heat exchange of liquified natural gas and gaseous natural gas, and double pipe heat exchanger is realized the heat exchange between cold and hot gas, and plate type finned heat exchanger is realized the heat exchange of gaseous natural gas and ethylene glycol liquid.Ethylene glycol is communicated with air cooling heat exchanger by cold-accumulating box and returns plate-fin heat exchanger through the liquid pump and realize circulation; Natural fuels after the re-heat enters automotive engine after by plate-fin heat exchanger, water-cooled condenser; The heat that automotive engine produces cools off by cooling water expansion tank, and promptly the cooling water expansion tank in the water storage box enters condenser through pump, carries out heat exchange with natural fuels, get back in the automotive engine behind the drop in temperature, driving engine is cooled off, return water storage box behind the temperature build-up, so repeatedly circulation.
Some other characteristics of the present invention are that described liquefied natural gas cylinder is the multi-layer vacuum shielding.
Described plate-fin heat exchanger is five plumes, nine channel heat exchangers.
Described coil heat exchanger is the coil heat exchanger of 3 copper pipe coilings.
The motorcar air conditioner that utilizes cold energy of liquefied natural gas of the present invention shows through laboratory test results, and cold energy of liquefied natural gas reclaims automotive air-conditioning system and has mapping and steady-state behaviour preferably.Under the transient condition, the air heat exchanger leaving air temp just can reach the wind pushing temperature (below 15 ℃) of air-conditioning in a few minutes.During steady state condition, the percent recovery of total system cold remains on more than 80%, and actual cold recovery can satisfy the cooling load demand of miniature car about 2.5kW.It is stable that the cold-storage effect also keeps, and when the LNG stop supplies, cold accumulation system continued cooling after 10 minutes, and the agent for storage of coldness temperature only raises about 2 ℃.Therefore, the LNG motorcar air conditioner has good cold balancing and regulatory function.
Four, description of drawings
Fig. 1 is a principle schematic of the present invention; Symbolic representation among the figure: 1, LNG Dewar 2, coil heat exchanger 3, double-tube heat exchanger 4, plate-fin heat exchanger 5, ethylene glycol cold-accumulating box 6, air cooling heat exchanger 7, liquid pump 8, filter 9, condenser 10,1 of automobile engine 1, coolant storage tank 12, Subzero valve 13, low pressure gasholder
Fig. 2 is an experimental system scheme drawing of the present invention; Symbolic representation among the figure: 1, LNG Dewar 2 coil heat exchangers 3, double-tube heat exchanger 4, plate type finned heat exchanger 5, ethylene glycol cold-accumulating box 6, air cooling heat exchanger 7, liquid pump 8, filter 9, condenser 10 1 of automobile engine 1, coolant storage tank 12, Subzero valve 13, low pressure gasholder 14, LNG fill jar
Fig. 3 is an experimental system outward appearance photo of the present invention.
Five, the specific embodiment
In order more to be expressly understood the present invention, the present invention is described in further detail below in conjunction with accompanying drawing and principle.
Referring to Fig. 1, Fig. 1 is a principle schematic of the present invention; According to technical scheme of the present invention, utilize the motorcar air conditioner of cold energy of liquefied natural gas to comprise: liquefied natural gas cylinder 1, coil heat exchanger 2, double-tube heat exchanger 3, plate-fin heat exchanger 4, ethylene glycol cold-accumulating box 5, air cooling heat exchanger 6, liquid pump 7, filter 8 and relevant condenser 9,1 of automobile engine 0, coolant storage tank 11, Subzero valve 12, low pressure gasholder 13;
Coil heat exchanger 2 is arranged in the liquefied natural gas cylinder 1, and is communicated with double-tube heat exchanger 3 and plate-fin heat exchanger 4; Plate-fin heat exchanger 4 also is connected with ethylene glycol cold-accumulating box 5, liquid pump 7 respectively; Ethylene glycol cold-accumulating box 5 is communicated with air cooling heat exchanger 6 and is connected plate-fin heat exchanger 4 through liquid pump 7; Plate-fin heat exchanger 4 also is communicated with 1 of automobile engine 0 by condenser 9, low pressure gasholder 13;
The heat that 1 of automobile engine 0 produces cools off by cooling water expansion tank, to be cooling water expansion tank enter condenser 9 through coolant storage tank 11 carries out heat exchange with natural fuels, enters behind the drop in temperature in the 1 of automobile engine 0, and driving engine is cooled off, return coolant storage tank 11, so repeatedly circulation.
Liquefied natural gas cylinder 1 is the low temperature fluid reservoir of multi-layer vacuum shielding.
Plate-fin heat exchanger 4 is five plumes, nine channel heat exchangers.
Coil heat exchanger 2 is three coil heat exchangers that copper pipe turns to.
Principle of work of the present invention is that the coil heat exchanger of three copper pipe coilings of dress is connected for filled jar with LNG by cryogenic valve in the LNG Dewar.Plate-fin heat exchanger is five plumes, nine channel heat exchangers, wherein walks natural fuels (four passages) for four strands, and one walks ethylene glycol solution (five passages), and natural fuels and ethylene glycol passage are alternately.During automobile starting, LNG Dewar valve open, the saturated gaseous natural gas on Dewar top enters in the low temperature double-tube heat exchanger under the system pressure effect, the natural fuels higher with the temperature of adverse current carries out interchange of heat, the release portion cold, temperature build-up enters in the plate-fin heat exchanger then, carry out interchange of heat once more with the ethylene glycol solution of adverse current, temperature further rises to more than 0 ℃.The higher natural fuels of the temperature of coming out from plate-fin heat exchanger returns the LNG Dewar, carries out interchange of heat with the outer LNG of pipe in the low-temperature coil heat exchanger, and LNG is gasified, while self drop in temperature, become cryogenic gas, enter heat exchange in the plate-fin heat exchanger again, so carry out twice circulation.In circulation for the third time, natural fuels enters the low temperature double-tube heat exchanger after plate-fin heat exchanger comes out, be used for heating low temperature saturated natural gas from cooled cryostat, then get back to the LNG Dewar, further cooling in the low-temperature coil heat exchanger, enter once more in the plate-fin heat exchanger, carry out interchange of heat with the ethylene glycol solution of shunting.Like this, the low temperature saturated natural gas of coming out from the LNG Dewar by low pressure gasholder, enters the engine cold condenser again through repeatedly lowering the temperature and heating up, and through the further heating of cooling water expansion tank, then sends into the combustion chamber of driving engine.
Carry cold after ethylene glycol solution is cooled and enter cold-storage groove in plate-fin heat exchanger, the ethylene glycol solution that these temperature are lower enters in the air heat exchanger through the pump pressurization, cooling is from the return air in compartment, ethylene glycol solution behind the temperature build-up enters plate-fin heat exchanger once more through filter, carries out interchange of heat with cryogenic natural gas and obtains cold.In air heat exchanger by the return air after the cooling with send the compartment back to after newly wind mixes in proportion, reach the effect of air-conditioning.
In the car running process, according to the flow of air heat exchanger leaving air temp automatically regulating ethylene glycol, to satisfy the cooling load under the different rows turner condition.After avoiding long-time the parking, the air in a car compartment cooling rate is too slow, and the low temperature ethylene glycol solution that comes out from plate-fin heat exchanger can be without cold-storage groove and directly through being pumped into air heat exchanger.When system's cooling surpasses cooling load and requires, again the low temperature ethylene glycol solution is sent into cold-storage groove surplus will have been crossed storage, the air-conditioning cooling load when stopping to satisfy auto idle speed.
Characteristics of the present invention are:
(1) adopt secondary refrigerant indirect heat exchange mode, solved LNG direct quenching ambient air and frosting appears, heat exchanger stops up and the low excessively situation such as health that is unfavorable for of cold air temperature.
The selection of secondary refrigerant: ethylene glycol is a kind of non-toxic, environmental friendly secondary refrigerant, the solidfying point of ethylene glycol solution low (the glycol water solidfying point of variable concentrations is difference to some extent), and specific heat capacity is big, and human body is not had harm.Therefore, can select suitable solution concentration according to the design-calculated needs.Bigger specific heat capacity is for realizing that high efficient heat exchanging and storing of energy have important effect.
Determining of refrigerant state parameter: air-conditioning is about 5 ℃ to the suitable wind pushing temperature of human body, considers the solidfying point parameter of the heat transfer temperature difference and the ethylene glycol of forced air cooler, and the minimum temperature of getting ethylene glycol is between-10 ℃~-5 ℃.
(2) adopt repeatedly the cold extraction method that the gasification latent heat of LNG is converted into gas sensible heat, avoided the frozen problem of secondary refrigerant
Repeatedly the advantage of cold extraction method is: the gasification of LNG is finished in the LNG Dewar fully, promptly phase-change heat-exchanger is placed in the cooled cryostat, what come out from Dewar then is gaseous natural gas fully.Gaseous natural gas can be controlled at higher temperature, avoids freezing ethylene glycol solution in main heat exchanger, causes constricted flow.
(3) adopting based on low temperature multiple flow plate type finned heat exchanger, coil tube type and double pipe heat exchanger is the composite heat-exchange system of assisting, and has solved the uneven problem of heat transfer temperature difference.
The effect of low temperature multiple flow plate type finned heat exchanger is that the cold of LNG is passed to the secondary refrigerant ethylene glycol by gaseous natural gas, realizes the purpose of air-conditioning by the glycol-cooled air.The plate type finned heat exchanger specific floor area is big, volume is little, high-efficiency compact, and a plurality of fluids heat exchange simultaneously, and the heat transfer temperature difference of each passage fluid reaches and optimizes the effect of conducting heat by reasonably design.Realized the fluid heat exchange of five-way road here, heat exchange between four strands of natural fuelses and one ethylene glycol solution.
Tube exchanger is a phase-change heat-exchanger, reaches the purpose of gasification by the natural gas in gaseous state heating liquid.Tube exchanger is placed in the LNG Dewar, does not increase additional space, does not also observe from the outside.Here three mini disk tubular heat exchangers have been arranged.
Double pipe heat exchanger here mainly effect be by the high-temperature gas heating that refluxes LNG saturated vapor from Dewar, promote the inlet temperature that enters the main heat exchanger cold air, avoid freezing of ethylene glycol.Double pipe heat exchanger is very compact, does not occupy additional space, and also has the effect of cold insulation.
(3) utilize secondary refrigerant as agent for storage of coldness, its reserves of rational Match and flow, the adjusting and the deposit of realization cold are to satisfy the demand of cold under the different rows turner condition.
In general, it is many more that driving engine consumes gas fuel, and the cold that LNG provided is also big more.And under different seasons and the different driving operating mode, the demand to air-conditioning cold flow in the car hold does not change because of consume fuel is different.The raising of cold and demand are not necessarily in full accord, may produce contradiction sometimes.The thought of cold-storage is exactly a kind of means that solve the cold imbalance between supply and demand, and cold accumulation system is temporarily laid in the cold of surplus, discharges when the big cold of needs.The invention provides one is the cold-accumulating box of agent for storage of coldness with the ethylene glycol, realizes cold-storage by specific heat capacity and a certain amount of ethylene glycol solution that ethylene glycol is big.The selection of ethylene glycol solution amount has influence on the cold-storage ability, also has influence on the refrigeration cool-down speed when starting.Solution amount is big more, and the cold-storage ability is strong more, and it is slow more to start cooling rate.The present invention adopts the flow bypass under the automatic guidance to coordinate this contradiction.
Adopting the present invention is the miniature car of 1.8L for free air capacity, presses the consumption of the LNG of 20L/100km (about 30L/h) and calculates, and LNG can provide cold 3kW.Consider that the cold loss caused by heat inleak and the re-heat of system not exclusively lose, the cold of recovery can be used for the air-conditioning of miniature car.
Referring to Fig. 2,3; Fig. 2, the 3rd, experimental system scheme drawing of the present invention and photo; 25-30 ℃ of measuring ambient temperature, open the low temperature aie escape valve of LNG tank top after, the temperature that the each point temperature reaches refrigerant ethylene glycol in the chilling air conditioning system over time in the low-temperature heat exchange system in 30 minutes is tested over time; Simultaneously, air heat exchanger cold wind temperature out, the back refrigerant that stops in 5 minutes are also tested over time with air heat exchanger cold wind temperature out, with simulated automotive start, mapping during parking.In addition, outlet of air heat exchanger cold wind and agent for storage of coldness ethylene glycol turnover plate-fin heat exchanger temperature are tested over time during also to systematic steady state, and also under the varying environment temperature, the cold of system recoveries is tested simultaneously.Laboratory test results shows that cold energy of liquefied natural gas reclaims automotive air-conditioning system and has mapping and steady-state behaviour preferably.Under the transient condition, the air heat exchanger leaving air temp just can reach the wind pushing temperature (below 15 ℃) of air-conditioning in a few minutes.During steady state condition, the percent recovery of total system cold remains on more than 80%, and actual cold recovery can satisfy the cooling load demand of miniature car about 2.5kW.It is stable that the cold-storage effect also keeps, and when the LNG stop supplies, cold accumulation system continued cooling after 10 minutes, and the agent for storage of coldness temperature only raises about 2 ℃.Therefore, the LNG motorcar air conditioner has good cold balancing and regulatory function.

Claims (4)

1. motorcar air conditioner that utilizes cold energy of liquefied natural gas, it is characterized in that, this motorcar air conditioner comprises, liquefied natural gas cylinder [1], coil heat exchanger [2], double-tube heat exchanger [3], plate-fin heat exchanger [4], ethylene glycol cold-accumulating box [5], air cooling heat exchanger [6], liquid pump [7] and filter [8], relevant device have condenser [9], automotive engine [10], coolant storage tank [11], Subzero valve [12], low pressure gasholder [13]; Coil heat exchanger [2] is arranged in the liquefied natural gas cylinder [1], and is communicated with double-tube heat exchanger [3] and plate-fin heat exchanger [4]; Plate-fin heat exchanger [4] also is connected with ethylene glycol cold-accumulating box [5], liquid pump [7] respectively; Ethylene glycol cold-accumulating box [5] is communicated with air cooling heat exchanger [6] and returns plate-fin heat exchanger [4] through liquid pump [7]; Plate-fin heat exchanger [4] also is communicated with automotive engine [10] by condenser [9], low pressure gasholder [13]; The heat that automotive engine [10] produces cools off by cooling water expansion tank, be that cooling water expansion tank enters condenser [9] through coolant storage tank [11], carry out heat exchange with natural fuels, get back to behind the drop in temperature in the automotive engine [10], driving engine is cooled off, get back to water storage box [11] behind the temperature build-up, so repeatedly circulation.
2. the motorcar air conditioner that utilizes cold energy of liquefied natural gas as claimed in claim 1 is characterized in that, described liquefied natural gas cylinder [1] is the low temperature fluid reservoir of multi-layer vacuum shielding.
3. the motorcar air conditioner that utilizes cold energy of liquefied natural gas as claimed in claim 1 is characterized in that, described plate-fin heat exchanger [4] is five plumes, nine channel heat exchangers.
4. the motorcar air conditioner that utilizes cold energy of liquefied natural gas as claimed in claim 1 is characterized in that, described coil heat exchanger [2] is the coil heat exchanger of three copper pipe coilings.
CNB031144381A 2003-01-17 2003-01-17 Car air conditioner making use of quantity of cold of liquefied natural gas Expired - Fee Related CN100434292C (en)

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CN100434665C (en) * 2007-02-12 2008-11-19 西安交通大学 Liquefied natural gas double-driving automobile circulatory system based on opening Rankine cycle
CN101832696A (en) * 2010-04-29 2010-09-15 中国海洋石油总公司 Method for air separation by storing cold energy of liquefied natural gas
CN102135051A (en) * 2011-01-25 2011-07-27 西安交通大学 Unfrozen heat exchanger for liquefied natural gas (LNG) automobile air conditioner
CN102198783A (en) * 2011-04-11 2011-09-28 上海理工大学 Automotive air conditioning system using cold energy of liquefied natural gas
CN102331127A (en) * 2011-08-23 2012-01-25 华南理工大学 Method and device for making ice by using liquefied natural gas cold energy
CN102398496A (en) * 2011-09-16 2012-04-04 上海交通大学 Air-conditioning system of automobile for improving condensing effect by gasifying liquefied natural gas (LNG)
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CN102485515A (en) * 2010-12-02 2012-06-06 中国国际海运集装箱(集团)股份有限公司 Intelligent refrigerating transport vehicle
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CN101832696A (en) * 2010-04-29 2010-09-15 中国海洋石油总公司 Method for air separation by storing cold energy of liquefied natural gas
CN102485515A (en) * 2010-12-02 2012-06-06 中国国际海运集装箱(集团)股份有限公司 Intelligent refrigerating transport vehicle
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CN102135051A (en) * 2011-01-25 2011-07-27 西安交通大学 Unfrozen heat exchanger for liquefied natural gas (LNG) automobile air conditioner
CN102679474B (en) * 2011-03-14 2015-12-16 许伯彦 A kind ofly reclaim the automotive air-conditioning system of cold energy of liquefied natural gas for cold air distribution
CN102679474A (en) * 2011-03-14 2012-09-19 许伯彦 Automobile air-conditioner system capable of recovering cold energy of liquefied natural gas (LNG)
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CN102331127A (en) * 2011-08-23 2012-01-25 华南理工大学 Method and device for making ice by using liquefied natural gas cold energy
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