CN1429866A - Adherable and peelable plastic printing ink and comprehensive antiforge mark made of said printing ink - Google Patents
Adherable and peelable plastic printing ink and comprehensive antiforge mark made of said printing ink Download PDFInfo
- Publication number
- CN1429866A CN1429866A CN 01138136 CN01138136A CN1429866A CN 1429866 A CN1429866 A CN 1429866A CN 01138136 CN01138136 CN 01138136 CN 01138136 A CN01138136 A CN 01138136A CN 1429866 A CN1429866 A CN 1429866A
- Authority
- CN
- China
- Prior art keywords
- plastic film
- ink
- fake mark
- microporous membrane
- comprehensive
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000007639 printing Methods 0.000 title claims description 38
- 229920003023 plastic Polymers 0.000 title claims description 25
- 239000004033 plastic Substances 0.000 title claims description 25
- 239000002985 plastic film Substances 0.000 claims abstract description 63
- 229920006255 plastic film Polymers 0.000 claims abstract description 63
- 238000007646 gravure printing Methods 0.000 claims abstract description 12
- 239000012982 microporous membrane Substances 0.000 claims description 35
- 238000000034 method Methods 0.000 claims description 33
- 239000004820 Pressure-sensitive adhesive Substances 0.000 claims description 24
- 239000000049 pigment Substances 0.000 claims description 24
- 239000002344 surface layer Substances 0.000 claims description 22
- 239000011248 coating agent Substances 0.000 claims description 16
- 238000000576 coating method Methods 0.000 claims description 16
- 239000010410 layer Substances 0.000 claims description 15
- 239000000123 paper Substances 0.000 claims description 15
- 229920002545 silicone oil Polymers 0.000 claims description 14
- 239000002904 solvent Substances 0.000 claims description 14
- 239000000203 mixture Substances 0.000 claims description 13
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 claims description 12
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims description 12
- 239000004793 Polystyrene Substances 0.000 claims description 12
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 12
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims description 12
- 239000011347 resin Substances 0.000 claims description 12
- 229920005989 resin Polymers 0.000 claims description 12
- MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Natural products CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 claims description 10
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 claims description 10
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 claims description 8
- 238000002360 preparation method Methods 0.000 claims description 8
- 229920001577 copolymer Polymers 0.000 claims description 6
- 239000004408 titanium dioxide Substances 0.000 claims description 6
- 239000012790 adhesive layer Substances 0.000 claims description 5
- 235000012204 lemonade/lime carbonate Nutrition 0.000 claims description 5
- 229920002223 polystyrene Polymers 0.000 claims description 5
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 claims description 4
- 239000000758 substrate Substances 0.000 claims description 4
- 239000011230 binding agent Substances 0.000 claims description 3
- 239000003795 chemical substances by application Substances 0.000 claims description 3
- 229910052500 inorganic mineral Inorganic materials 0.000 claims description 3
- 239000011707 mineral Substances 0.000 claims description 3
- 238000003825 pressing Methods 0.000 claims description 3
- 239000003550 marker Substances 0.000 abstract 1
- 239000000976 ink Substances 0.000 description 79
- 239000004698 Polyethylene Substances 0.000 description 14
- 239000004743 Polypropylene Substances 0.000 description 14
- 229920000728 polyester Polymers 0.000 description 14
- -1 polyethylene Polymers 0.000 description 14
- 229920000573 polyethylene Polymers 0.000 description 14
- 229920001155 polypropylene Polymers 0.000 description 14
- 239000003086 colorant Substances 0.000 description 9
- WYUHTVDGHDRPDW-UHFFFAOYSA-N 3-hydroxy-N-phenyl-4-phenyldiazenylnaphthalene-2-carboxamide Chemical compound C1(=CC=CC=C1)N=NC1=C(C(=CC2=CC=CC=C12)C(=O)NC1=CC=CC=C1)O WYUHTVDGHDRPDW-UHFFFAOYSA-N 0.000 description 8
- 239000000463 material Substances 0.000 description 8
- 239000004677 Nylon Substances 0.000 description 7
- 229920001778 nylon Polymers 0.000 description 7
- 239000004417 polycarbonate Substances 0.000 description 7
- 229920000515 polycarbonate Polymers 0.000 description 7
- 239000004800 polyvinyl chloride Substances 0.000 description 7
- XCJYREBRNVKWGJ-UHFFFAOYSA-N copper(II) phthalocyanine Chemical compound [Cu+2].C12=CC=CC=C2C(N=C2[N-]C(C3=CC=CC=C32)=N2)=NC1=NC([C]1C=CC=CC1=1)=NC=1N=C1[C]3C=CC=CC3=C2[N-]1 XCJYREBRNVKWGJ-UHFFFAOYSA-N 0.000 description 6
- 238000004519 manufacturing process Methods 0.000 description 6
- MPVDXIMFBOLMNW-ISLYRVAYSA-N 7-hydroxy-8-[(E)-phenyldiazenyl]naphthalene-1,3-disulfonic acid Chemical compound OC1=CC=C2C=C(S(O)(=O)=O)C=C(S(O)(=O)=O)C2=C1\N=N\C1=CC=CC=C1 MPVDXIMFBOLMNW-ISLYRVAYSA-N 0.000 description 5
- 238000005516 engineering process Methods 0.000 description 4
- OSNILPMOSNGHLC-UHFFFAOYSA-N 1-[4-methoxy-3-(piperidin-1-ylmethyl)phenyl]ethanone Chemical compound COC1=CC=C(C(C)=O)C=C1CN1CCCCC1 OSNILPMOSNGHLC-UHFFFAOYSA-N 0.000 description 3
- 241000675108 Citrus tangerina Species 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 230000001066 destructive effect Effects 0.000 description 3
- 230000008034 disappearance Effects 0.000 description 3
- 235000019239 indanthrene blue RS Nutrition 0.000 description 3
- UHOKSCJSTAHBSO-UHFFFAOYSA-N indanthrone blue Chemical compound C1=CC=C2C(=O)C3=CC=C4NC5=C6C(=O)C7=CC=CC=C7C(=O)C6=CC=C5NC4=C3C(=O)C2=C1 UHOKSCJSTAHBSO-UHFFFAOYSA-N 0.000 description 3
- AXDJCCTWPBKUKL-UHFFFAOYSA-N 4-[(4-aminophenyl)-(4-imino-3-methylcyclohexa-2,5-dien-1-ylidene)methyl]aniline;hydron;chloride Chemical compound Cl.C1=CC(=N)C(C)=CC1=C(C=1C=CC(N)=CC=1)C1=CC=C(N)C=C1 AXDJCCTWPBKUKL-UHFFFAOYSA-N 0.000 description 2
- 241000692870 Inachis io Species 0.000 description 2
- HRMOLDWRTCFZRP-UHFFFAOYSA-L disodium 5-acetamido-3-[(4-acetamidophenyl)diazenyl]-4-hydroxynaphthalene-2,7-disulfonate Chemical compound [Na+].OC1=C(C(=CC2=CC(=CC(=C12)NC(C)=O)S(=O)(=O)[O-])S(=O)(=O)[O-])N=NC1=CC=C(C=C1)NC(C)=O.[Na+] HRMOLDWRTCFZRP-UHFFFAOYSA-L 0.000 description 2
- JYNBEDVXQNFTOX-FMQUCBEESA-N lithol rubine Chemical compound OS(=O)(=O)C1=CC(C)=CC=C1\N=N\C1=C(O)C(C(O)=O)=CC2=CC=CC=C12 JYNBEDVXQNFTOX-FMQUCBEESA-N 0.000 description 2
- 235000010187 litholrubine BK Nutrition 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 238000012546 transfer Methods 0.000 description 2
- WLDHEUZGFKACJH-UHFFFAOYSA-K amaranth Chemical compound [Na+].[Na+].[Na+].C12=CC=C(S([O-])(=O)=O)C=C2C=C(S([O-])(=O)=O)C(O)=C1N=NC1=CC=C(S([O-])(=O)=O)C2=CC=CC=C12 WLDHEUZGFKACJH-UHFFFAOYSA-K 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 229910052793 cadmium Inorganic materials 0.000 description 1
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 description 1
- 239000000549 coloured material Substances 0.000 description 1
- 238000012850 discrimination method Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000010408 film Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000012756 surface treatment agent Substances 0.000 description 1
Landscapes
- Inks, Pencil-Leads, Or Crayons (AREA)
- Printing Methods (AREA)
Abstract
An ink able to be adhered to and torn from plastic film is disclosed, which can be used to prepare antiforge marker by gravure printing on plastic film. It features that its antiforge pattern can be torn from plastic film, but not produce, so having high antiforge effect.
Description
Technical field
The present invention relates to a kind of printing ink goods and with the comprehensive anti-fake mark of this printing ink to manufacture, particularly a kind ofly cohere the plastics gravure printing ink peeled off and in the anti-counterfeiting mark Applications in Fabrication.
Background technology
Comprehensive anti-fake mark relates to nuclear technique, material technology and chemical technology etc., and the comprehensive utilization multiple technologies are finished the making of comprehensive anti-fake mark jointly.Chinese invention patent CN1195833 (application number: 97125868.6) disclose a kind of nuclear track microporous membrane anti-counterfeiting mark goods and recognition methods thereof.This sign is made up of nuclear track microporous membrane, tackiness agent, surface layer, pressure sensitive adhesive and bottom, and to indicate surface layer can be any coloured materials such as paper, plastics, metal.In fact, make surface layer with plastic film, no matter be to include the plastic film that adds tinting material, still the comprehensive anti-fake mark of the plastic film (plastic film that comprises any red ink paste used for seals in two faces) of surperficial red ink paste used for seals making is in taking off the process of tearing the commentaries on classics subsides, tend to remain intact, can't guarantee " disposable " use properties, thereby its antiforge function variation.This is the printing ink layer owing to plastic film, and to the strong adhesion of film, plastic film and ink lay can't be peeled off.Chinese invention patent CN1290728 (application number 00117567) and the disclosed plastic film printing ink of CN1257097 (application number 98111622) and preparation method thereof; and existing plastic film printing ink on the market; the ink lay attachment fastness is good; anti-ly do, the wet friction performance is good; make comprehensive anti-fake mark if use them to be imprinted on the plastic film as surface layer; can take off to tear to change from protected commodity and be affixed on other counterfeit goods, ink lay and plastic film can not peeled off, and make to identify to remain intact.
Summary of the invention
One of purpose of the present invention provides a kind of ink used for plastic of peeling off that coheres; Another object of the present invention provides a kind of utilization can cohere comprehensive anti-fake mark and the method thereof of peeling off the ink used for plastic preparation; make the anti-counterfeiting mark of its making can only stick on the protected commodity once; if taking off to tear to change, attempt is affixed on other commodity; then in taking off the process of tearing; plastic film will be peeled away with printing ink layer; make the anti-counterfeiting mark completely destroy, guarantee that anti-counterfeiting mark " disposable " uses.
The present invention is achieved through the following technical solutions:
A kind of cohering peeled off ink used for plastic, it is characterized in that this printing ink contains resin, solvent, pigment, auxiliary and five kinds of components of stopping composition, and each components contents (weight percent) is respectively:
Resin 3-8%
Solvent 62-75%
Pigment 12-17.5%
Stopping composition 9-11.5%
Auxiliary 0.5-1.0% is wherein:
Resin adopts butadiene-styrene copolymer;
Solvent can be selected at least a in pimelinketone, toluene, dimethylbenzene, ethyl acetate or more than a kind of;
Auxiliary can be selected a kind of from dibutyl phthalate, dioctyl phthalate (DOP);
Stopping composition can be selected a kind of in polystyrene, lime carbonate, titanium dioxide or more than a kind of;
Pigment can be selected a kind of in all kinds of pigment dyestuffs and mineral dye according to required color or more than a kind of.
Utilize the nuclear track microporous membrane comprehensive anti-fake mark of above-mentioned printing ink preparation, comprise nuclear track microporous membrane, adhesive layer, surface layer, pressure-sensitive adhesive layer and bottom, it is characterized in that described surface layer adopts to be printed on below colourless plastic film and the film can cohere the ink lay of peeling off and constitute jointly.
Above-mentioned printing ink is not only applicable to the nuclear track microporous membrane anti-counterfeiting mark, and to can be used for preparing various be other comprehensive anti-fake mark of substrate with plastic film.This comprehensive anti-fake mark comprises plastic film, pressure-sensitive adhesive layer and the bottom (silicone oil paper) that is loaded with anti-counterfeiting information, it is characterized in that increasing one deck and can cohere the ink lay of peeling off between plastic film that is loaded with anti-counterfeiting information and pressure-sensitive adhesive layer.
The method for preparing the nuclear track microporous membrane comprehensive anti-fake mark provided by the invention comprises the steps:
(1) makes nuclear track microporous membrane;
(2) at the non-pattern part coating binder of nuclear track microporous membrane;
(3) on a face of colourless plastic film, stamp and to cohere the ink lay of peeling off with gravure printing machine;
(4) nuclear track microporous membrane that will scribble tackiness agent is compounded on the plastics face that is printed on ink lay;
(5) pressure-sensitive adhesive coating below the ink lay of plastic film;
(6) comprehensive anti-fake mark is placed bottom surface (silicone oil paper).
It is the preparation method of other comprehensive anti-fake mark of substrate with various plastic films that the present invention also provides a kind of, and this method may further comprise the steps:
(1) laser mold pressing, printing process make on the face of plastic film and are loaded with anti-counterfeiting information,
(2) stamp on another face of plastic film and can cohere the ink lay of peeling off,
(3) pressure-sensitive adhesive coating below the ink lay of plastic film,
(4) anti-counterfeiting mark is placed bottom surface (silicone oil paper), make comprehensive anti-fake mark.
Provided by the present invention cohering peeled off ink used for plastic, belongs to the extraordinary gravure ink of volatile dry type.It removes has the printability of common plastics film with gravure ink, levelling property, and viscosity outside performance such as rate of drying and snappiness, rub resistance, solvent resistance and the anti-processing characteristics, the more important thing is that the sticking power of this printing ink and plastic film is moderate.After comprehensive anti-fake mark is attached on the protected commodity, to attempt again to tear when transferring on other counterfeit goods by taking off, ink lay is peeled away from plastic film, is firmly cohered on former commodity by pressure sensitive adhesive not come off, and makes comprehensive anti-fake mark destroyed.
Utilize the comprehensive anti-fake mark of this printing ink to manufacture, not only guaranteed " disposable " use, and its anti-counterfeiting performance improves greatly.The comprehensive anti-fake mark that utilizes this method to make, the pattern on the nuclear track microporous membrane can " disappearance of dripping ", and the nuclear track microporous membrane of taking off can be with the pen print through of tinting, and these antiforge functions are all identical with Chinese invention patent CN 1195833 with discrimination method.But when taking off together with surface layer when tearing it down, the sign among the CN 1195833 still can " disappearance of dripping "; And the comprehensive anti-fake mark among the present invention is colourless plastic film because of surface layer, have below its film and can cohere the plastic gravure ink lay of peeling off, in taking off the process of tearing, two portions of surface layer can separate fully, ink lay below the plastic film strips down because of cohering from plastic film of pressure sensitive adhesive, take off the sign that only has plastic film in the surface layer that tears it down like this, the pattern on the nuclear track microporous membrane wherein no longer can " disappearance of dripping ", and this moment, sign was destroyed fully.
Description of drawings
Fig. 1 is the structural representation of nuclear track microporous membrane comprehensive anti-fake mark of the present invention.
Fig. 2 is the structural representation of another kind of comprehensive anti-fake mark of the present invention.
Embodiment
This comprehensive anti-fake mark making method that designs among the present invention is to realize by cohering the plastic gravure ink printing of peeling off.
This printing ink is made up of resin, solvent, pigment, auxiliary and five kinds of components of stopping composition.
Resin is a butadiene-styrene copolymer;
Solvent can be selected at least a in pimelinketone, toluene, dimethylbenzene, these lower boilings of ethyl acetate, volatile solvent or more than a kind of.
Pigment can be selected a kind of in all kinds of pigment dyestuffs and mineral dye according to required color or more than a kind of.
That auxiliary rises in printing ink is lubricated, froth breaking, dispersion, plastification, can select a kind of from dibutyl phthalate or dioctyl phthalate (DOP).
Stopping composition is the material that adds for the sticking power between control ink lay and plastic film, can select a kind of in polystyrene, lime carbonate, titanium dioxide or more than a kind of.
The main processes of making printing ink is:
1. with resin dissolves in solvent, standby as the connection material of printing ink;
2. pigment, auxiliary material, stopping composition are made an addition to and connect in the material, and mix;
3. grind with sand mill and make finished product printing ink.
This printing ink can be used the gravure printing machine printing on polyester (PET), polyethylene (PE), polypropylene (PP) nylon (PA), polyvinyl chloride (PVC), polystyrene (PS), polycarbonate plastic films such as (PC), formation can be cohered the ink lay of peeling off.
Nuclear track microporous membrane comprehensive anti-fake mark provided by the invention comprises nuclear track microporous membrane 1, and adhesive layer 2, surface layer 3, pressure-sensitive adhesive layer 4 and bottom (silicone oil paper) 5, the surface layer 3 ink lay 3b that peels off that coheres below colourless plastic film 3a and film constitutes.In comprehensive anti-fake mark making processes, nuclear track microporous membrane, adhesive layer, pressure-sensitive adhesive layer and bottom all do not change, and are printed on the plastic film that can cohere the ink lay of peeling off below wherein surface layer is used instead, adhesive layer is arranged, pressure-sensitive adhesive coating again under the ink lay above the plastic film.The formation of nuclear track microporous membrane comprehensive anti-fake mark is seen shown in Figure 1.
This comprehensive anti-fake mark making method that provides among the present invention, be not only applicable to the nuclear track microporous membrane anti-counterfeiting mark, and applicable to various be the anti-counterfeiting mark of substrate with plastic film, as plastic film system have a laser rainbow embossed holographic image anti-counterfeiting mark, be imprinted on the anti-counterfeiting mark made on the plastic film etc. with various anti-forgery inks.This kind comprehensive anti-fake mark by the plastic film 6 that is loaded with anti-counterfeiting mark, can cohere 5 of ink lay 3b, pressure sensitive adhesive 4 and bottoms (silicone oil paper) peeling off and form.The basal surface of sign stamps one deck ink lay, pressure-sensitive adhesive coating again with cohering the ink used for plastic of peeling off before pressure-sensitive adhesive coating.So both kept original antiforge function, and increased again and can cohere the ink lay of peeling off, also can to set off the pattern that makes in the sign more attractive in appearance because of versicolor background color, and can to tear in the transfer process sign destroyed taking off, guaranteed the use of " disposable ".The formation of this class comprehensive anti-fake mark as shown in Figure 2.
With cohering concrete steps and the method for peeling off ink used for plastic making nuclear track microporous membrane comprehensive anti-fake mark be:
1. make nuclear track microporous membrane,
2. at the non-pattern part coating binder of nuclear track microporous membrane,
3. on a face of plastic film, stamp and to cohere the ink lay of peeling off, as the face of comprehensive anti-fake mark with gravure printing machine
Layer;
4. will finish 1., 2. the nuclear track microporous membrane of operation is compounded on the face of finishing the 3. printing ink layer of the plastic film of operation,
5. pressure-sensitive adhesive coating below the ink lay of plastic film,
6. comprehensive anti-fake mark is placed bottom surface (silicone oil paper).Wherein step 1., 2., 4., 5., detailed making method 6. sees CN 1195833A.
Peel off ink used for plastic and make the concrete steps and the method for other comprehensive anti-fake marks and be with cohering:
1. laser mold pressing, printing process make on the face of plastic film and are loaded with anti-counterfeiting information,
2. on another face of plastic film, stamp and can cohere the ink lay of peeling off,
3. pressure-sensitive adhesive coating below the ink lay of plastic film,
4. comprehensive anti-fake mark places bottom surface (silicone oil paper), makes comprehensive anti-fake mark.
Peel off the comprehensive anti-fake mark that ink used for plastic is made with cohering, (silicone oil paper) transfer sticks on the smooth surface of protected commodity or its packing from the bottom surface it during use.The material of face of being stuck is: paper, plastics, glass, metal, timber, pottery or stone material comprise the face of crossing through printing, coating, glazing treatment, but should there be the surface treatment agent that contains paraffin, silicone oil, oil component in these faces.
Embodiment 1:
1) printing ink basic components:
Title | Content (w%) | Title | Content (w%) |
Resin: divinyl-styrol copolymer | ????8 | Auxiliary: dibutyl phthalate | ????1.0 |
Solvent: pimelinketone | ????22 | Stopping composition: lime carbonate | ????1.0 |
Dimethylbenzene | ????23 | Titanium dioxide | ????7.5 |
Ethyl acetate | ????20 | Pigment: | ????17.5 |
2) used other pigment during different colours:
Color | Pigment name and consumption (w%) | Color | Pigment name and consumption (w%) |
Bright red | 808 reds 17.5 | Purple | Pake purpke 17.5 |
Bronze red | Unified bronze red 17.5 | Purplish red | Pake purpke 10.0 precious red BK 7.5 |
Dark red | Iron oxide red powder 7.5 Lithol Reds 10.0 | Dark rhodo | Precious red BK 17.5 |
Rhodo | Precious red BK 12.0 fuchsin 6B 5.5 | ||
Tangerine | Unified bronze red 12.5 is consolidated orange G 5.0 forever | Medium green | Dark green G 14.0 benzidine yellow Gs 3.5 of phthalein |
Orange | Consolidate orange G 17.5 forever | Dark green | The dark green G 17.5 of phthalein |
Dark blue | Phthalocyanine blue BGS 17.5 | Medium blue | Phthalocyanine blue BGS 12.0 peacock blue 5.5 |
3) printing ink to manufacture is seen the main processes of making printing ink.
4) be imprinted on polyester (PET), polyethylene (PE), polypropylene (PP) nylon (PA), polyvinyl chloride (PVC), polystyrene (PS), the polycarbonate plastic films such as (PC) with gravure printing machine, make the surface layer of nuclear track microporous membrane anti-counterfeiting mark.
5) making of comprehensive anti-fake mark is seen with cohering concrete steps and the method that ink used for plastic is made comprehensive anti-fake mark of peeling off.
Can be made into the nuclear track microporous membrane comprehensive anti-fake mark that has different pattern that various surface layers by different colours are setting off.
If through the same 1), 2), 3) after the step, again through following making processes:
4 ') one side has been loaded with polyester (PET), polyethylene (PE), polypropylene (PP) nylon (PA), polyvinyl chloride (PVC), the polystyrene (PS) of anti-counterfeiting information, the another side of polycarbonate plastic films such as (PC), stamps to cohere with gravure printing machine and peels off the ink used for plastic layer;
5 ') pressure-sensitive adhesive coating below the ink lay of plastic film,
6 ') comprehensive anti-fake mark places bottom surface (silicone oil paper), makes comprehensive anti-fake mark.
Can be made into the comprehensive anti-fake mark that has the different preventing fake information that various different colours are setting off like this.
Comprehensive anti-fake mark is attached to protected commodity or its surface of package; after under physical environment, parking 24 hours; take off again and tear sign; if the ink lay area that bonding is peeled off is not less than 5% of the sign total area; think this sign can take off tear bad; if the ink lay area peeled off of bonding is not less than 80% of the sign total area, think that this sign can peel off fully.
Among this embodiment, it is 99% that the taking off of sign torn destructive rate, and the rate of peeling off fully of sign is 80%
Embodiment 2:
1) printing ink basic components:
Title | Content (w%) | Title | Content (w%) |
Resin: divinyl-styrol copolymer | ????6.0 | Pigment | ??12.0 |
Solvent: dimethylbenzene | ????60.0 | Stopping composition: lime carbonate | ??1.0 |
Toluene | ????10.0 | Titanium dioxide | ??4.5 |
Auxiliary: dioctyl phthalate (DOP) | ????0.5 | Polystyrene | ??6.0 |
2) used other pigment during different colours:
Color | Pigment name and consumption (w%) | Color | Pigment name and consumption (w%) |
Bright red | Firm bright red G 12.0 | Purple | Pake purpke 12.0 |
Bronze red | Bronze red 12.0 | Purplish red | Pake purpke 8.0 bright red 6B 4.0 |
Tangerine | Red BBC 8.0 cadmium yellows 4.0 of sun-proof | Medium green | Dark green G 9.0 benzidine yellow Gs 3.0 of phthalein |
Orange | Consolidate orange G 12.0 forever | Dark green | The dark green G 12.0 of phthalein |
Dark blue | Phthalocyanine blue BGS 12.0 | Dark rhodo | Lithol rubine 12.0 |
Medium blue | Phthalocyanine blue BGS 9.0 reddish blue 3.0 | Rhodo | Lithol rubine 9.0 bright red 6B 3.0 |
3) printing ink to manufacture is seen the main processes of making printing ink.
4) be imprinted on polyester (PET), polyethylene (PE), polypropylene (PP) nylon (PA), polyvinyl chloride (PVC), polystyrene (PS), the polycarbonate plastic films such as (PC) with gravure printing machine, make the surface layer of nuclear track microporous membrane anti-counterfeiting mark.
5) making of comprehensive anti-fake mark is seen with cohering concrete steps and the method that ink used for plastic is made comprehensive anti-fake mark of peeling off.
Can be made into the nuclear track microporous membrane comprehensive anti-fake mark that has different pattern that various surface layers by different colours are setting off.
If through the same 1), 2), 3) after the step, again through following making processes:
4 ') one side has been loaded with polyester (PET), polyethylene (PE), polypropylene (PP) nylon (PA), polyvinyl chloride (PVC), the polystyrene (PS) of anti-counterfeiting information, the another side of polycarbonate plastic films such as (PC), stamps to cohere with gravure printing machine and peels off the ink used for plastic layer;
5 ') pressure-sensitive adhesive coating below the ink lay of plastic film,
6 ') comprehensive anti-fake mark places bottom surface (silicone oil paper), makes comprehensive anti-fake mark.
Can be made into the nuclear track microporous membrane comprehensive anti-fake mark that has different pattern that various surface layers by different colours are setting off.
Among this embodiment, it is 100% that the taking off of sign torn destructive rate, and the rate of peeling off fully of sign is 92%
Embodiment 3:
1) printing ink basic components:
Title | Content (w%) | Title | Content (w%) |
Resin: divinyl-styrol copolymer | ????3.0 | Pigment | ???13.0 |
Solvent: dimethylbenzene | ????72.0 | Stopping composition: titanium dioxide | ???5.2 |
Auxiliary: dioctyl phthalate (DOP) | ????0.8 | Polystyrene | ???6.0 |
2) used other pigment during different colours:
Color | Pigment name and consumption (w%) | Color | Pigment name and consumption (w%) |
Bright red | Everbright fast red 13.0 | Purple | Pake purpke 13.0 |
Bronze red | Unified bronze red 13.0 | Purplish red | Pake purpke 9.0 precious red BK 4.0 |
Tangerine | Unified bronze red 10.0 is consolidated orange G 3.0 forever | Medium green | Dark green G 10.0 benzidine yellow 10Gs 3.0 of phthalein |
Orange | Consolidate orange G 12.0 808 reds 1.0 forever | Dark green | The dark green G 13.0 of phthalein |
Dark blue | Phthalocyanine blue BGS 13.0 | Dark rhodo | Precious red BK 13.0 |
Medium blue | Phthalocyanine blue BGS 9.5 peacock blue 3.5 | Rhodo | Precious red BK 10.0 fuchsin 6B 3.0 |
3) printing ink to manufacture is seen the main processes of making printing ink.
4) be imprinted on polyester (PET), polyethylene (PE), polypropylene (PP) nylon (PA), polyvinyl chloride (PVC), polystyrene (PS), the polycarbonate plastic films such as (PC) with gravure printing machine, make the surface layer of nuclear track microporous membrane anti-counterfeiting mark.
5) making of comprehensive anti-fake mark is seen with cohering concrete steps and the method that ink used for plastic is made comprehensive anti-fake mark of peeling off.
Can be made into the nuclear track microporous membrane comprehensive anti-fake mark that has different pattern that various surface layers by different colours are setting off.
If through the same 1), 2), 3) after the step, again through following making processes:
4 ') one side has been loaded with polyester (PET), polyethylene (PE), polypropylene (PP) nylon (PA), polyvinyl chloride (PVC), the polystyrene (PS) of anti-counterfeiting information, the another side of polycarbonate plastic films such as (PC), stamps to cohere with gravure printing machine and peels off the ink used for plastic layer;
5 ') pressure-sensitive adhesive coating below the ink lay of plastic film,
6 ') comprehensive anti-fake mark places bottom surface (silicone oil paper), makes comprehensive anti-fake mark.
Can be made into the comprehensive anti-fake mark that has the different preventing fake information that various different colours are setting off like this.
Among this embodiment, it is 100% that the taking off of sign torn destructive rate, and the rate of peeling off fully of sign is 95%.
Claims (5)
1, a kind of cohering peeled off ink used for plastic, it is characterized in that this printing ink contains resin, solvent, pigment, auxiliary and five kinds of components of stopping composition, and each components contents (weight percent) is respectively:
Resin 3-8%
Solvent 62-75%
Pigment 12-17.5%
Stopping composition 9-11.5%
Auxiliary 0.5-1.0% is wherein:
Resin adopts butadiene-styrene copolymer;
Solvent can be selected at least a in pimelinketone, toluene, dimethylbenzene, ethyl acetate or more than a kind of;
Auxiliary can be selected a kind of from dibutyl phthalate, dioctyl phthalate (DOP);
Stopping composition can be selected a kind of in polystyrene, lime carbonate, titanium dioxide or more than a kind of;
Pigment can be selected a kind of in all kinds of pigment dyestuffs and mineral dye according to required color or more than a kind of.
2, kind adopts the nuclear track microporous membrane comprehensive anti-fake mark of printing ink preparation according to claim 1, comprise nuclear track microporous membrane, adhesive layer, surface layer, pressure-sensitive adhesive layer and bottom, it is characterized in that described surface layer adopts to be printed on below colourless plastic film and the film can cohere the ink lay of peeling off and constitute jointly.
3, a kind of employing according to claim 1 printing ink preparation be the comprehensive anti-fake mark of substrate with the plastic film, comprise the plastic film, pressure-sensitive adhesive layer and the bottom that are loaded with anti-counterfeiting information, it is characterized in that between the plastic film of anti-counterfeiting information and pressure-sensitive adhesive layer, increasing one deck and can cohere the ink lay of peeling off.
4, a kind of preparation is as the method for nuclear track microporous membrane comprehensive anti-fake mark as described in the claim 2, and this method comprises the steps:
(1) makes nuclear track microporous membrane;
(2) at the non-pattern part coating binder of nuclear track microporous membrane;
(3) on a face of colourless plastic film, stamp and to cohere the ink lay of peeling off with gravure printing machine;
(4) nuclear track microporous membrane that scribbles tackiness agent is compounded on the plastics face that is printed on ink lay;
(5) pressure-sensitive adhesive coating below the ink lay of plastic film;
(6) comprehensive anti-fake mark is placed bottom surface (silicone oil paper).
5, a kind of preparation is as the method for comprehensive anti-fake mark as described in the claim 3, this method step specific as follows:
(1) makes on the face of plastic film with laser mold pressing, printing process and be loaded with anti-counterfeiting information;
(2) stamp on another face of plastic film and can cohere the ink lay of peeling off;
(3) pressure-sensitive adhesive coating below the ink lay of plastic film;
(4) anti-counterfeiting mark is placed bottom surface (silicone oil paper), make comprehensive anti-fake mark.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CN 01138136 CN1188480C (en) | 2001-12-31 | 2001-12-31 | Adherable and peelable plastic printing ink and comprehensive antiforge mark made of said printing ink |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
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CN 01138136 CN1188480C (en) | 2001-12-31 | 2001-12-31 | Adherable and peelable plastic printing ink and comprehensive antiforge mark made of said printing ink |
Publications (2)
Publication Number | Publication Date |
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CN1429866A true CN1429866A (en) | 2003-07-16 |
CN1188480C CN1188480C (en) | 2005-02-09 |
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CN 01138136 Expired - Fee Related CN1188480C (en) | 2001-12-31 | 2001-12-31 | Adherable and peelable plastic printing ink and comprehensive antiforge mark made of said printing ink |
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Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102009537A (en) * | 2010-10-12 | 2011-04-13 | 杨建华 | Optical chromatic security label of rubber product and manufacturing method thereof |
CN101018833B (en) * | 2004-08-02 | 2011-06-15 | 埃克阿泰克有限责任公司 | Decorative ink system for automotive plastic glazing |
CN102303440A (en) * | 2011-08-15 | 2012-01-04 | 高邮市卫星卷烟材料有限公司 | Production method of high-gloss one-sided dual-color heat transfer anodized aluminum |
CN102651183A (en) * | 2012-03-15 | 2012-08-29 | 广东溢达纺织有限公司 | Garment tag processing method |
CN102719140A (en) * | 2012-06-12 | 2012-10-10 | 中山市中益油墨涂料有限公司 | Varnish for water-borne anti-counterfeiting ink and water-borne anti-counterfeiting ink prepared by varnish |
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2001
- 2001-12-31 CN CN 01138136 patent/CN1188480C/en not_active Expired - Fee Related
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101018833B (en) * | 2004-08-02 | 2011-06-15 | 埃克阿泰克有限责任公司 | Decorative ink system for automotive plastic glazing |
CN102009537A (en) * | 2010-10-12 | 2011-04-13 | 杨建华 | Optical chromatic security label of rubber product and manufacturing method thereof |
CN102009537B (en) * | 2010-10-12 | 2015-05-13 | 杨建华 | Optical chromatic security label of rubber product and manufacturing method thereof |
CN102303440A (en) * | 2011-08-15 | 2012-01-04 | 高邮市卫星卷烟材料有限公司 | Production method of high-gloss one-sided dual-color heat transfer anodized aluminum |
CN102651183A (en) * | 2012-03-15 | 2012-08-29 | 广东溢达纺织有限公司 | Garment tag processing method |
CN102651183B (en) * | 2012-03-15 | 2014-02-12 | 广东溢达纺织有限公司 | Garment tag processing method |
CN102719140A (en) * | 2012-06-12 | 2012-10-10 | 中山市中益油墨涂料有限公司 | Varnish for water-borne anti-counterfeiting ink and water-borne anti-counterfeiting ink prepared by varnish |
Also Published As
Publication number | Publication date |
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CN1188480C (en) | 2005-02-09 |
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