CN1424349A - 耐候抗冲苯乙烯工程塑料合金及其制备方法 - Google Patents
耐候抗冲苯乙烯工程塑料合金及其制备方法 Download PDFInfo
- Publication number
- CN1424349A CN1424349A CN 01142633 CN01142633A CN1424349A CN 1424349 A CN1424349 A CN 1424349A CN 01142633 CN01142633 CN 01142633 CN 01142633 A CN01142633 A CN 01142633A CN 1424349 A CN1424349 A CN 1424349A
- Authority
- CN
- China
- Prior art keywords
- engineering plastic
- plastic alloy
- marquis
- styrene
- impact styrene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000956 alloy Substances 0.000 title claims abstract description 16
- 229910045601 alloy Inorganic materials 0.000 title claims abstract description 16
- 229920006351 engineering plastic Polymers 0.000 title claims abstract description 16
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 title claims description 29
- 238000002360 preparation method Methods 0.000 title claims description 12
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 7
- 229920001577 copolymer Polymers 0.000 claims abstract description 7
- 229920000515 polycarbonate Polymers 0.000 claims abstract description 7
- 239000004417 polycarbonate Substances 0.000 claims abstract description 7
- 238000001035 drying Methods 0.000 claims abstract description 4
- 238000002156 mixing Methods 0.000 claims abstract description 4
- 239000000463 material Substances 0.000 claims description 15
- 229940074869 marquis Drugs 0.000 claims description 12
- 239000003112 inhibitor Substances 0.000 claims description 8
- 230000003647 oxidation Effects 0.000 claims description 8
- 238000007254 oxidation reaction Methods 0.000 claims description 8
- 239000000203 mixture Substances 0.000 claims description 5
- 239000006096 absorbing agent Substances 0.000 claims description 4
- 239000003963 antioxidant agent Substances 0.000 claims description 4
- 230000003078 antioxidant effect Effects 0.000 claims description 4
- -1 octyl phenyl Chemical group 0.000 claims description 4
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 claims description 3
- 239000012964 benzotriazole Substances 0.000 claims description 3
- 238000005453 pelletization Methods 0.000 claims description 3
- OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical class OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 claims description 3
- 239000002994 raw material Substances 0.000 claims description 3
- 229920000800 acrylic rubber Polymers 0.000 claims description 2
- 150000002989 phenols Chemical class 0.000 claims description 2
- 229920000058 polyacrylate Polymers 0.000 claims description 2
- 229920001971 elastomer Polymers 0.000 abstract description 2
- 239000000806 elastomer Substances 0.000 abstract description 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 abstract 1
- 239000005977 Ethylene Substances 0.000 abstract 1
- 230000003064 anti-oxidating effect Effects 0.000 abstract 1
- 238000001816 cooling Methods 0.000 abstract 1
- 230000003287 optical effect Effects 0.000 abstract 1
- 239000002245 particle Substances 0.000 abstract 1
- 239000003381 stabilizer Substances 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
- 238000000034 method Methods 0.000 description 6
- 150000002148 esters Chemical class 0.000 description 5
- 238000005516 engineering process Methods 0.000 description 3
- 230000002194 synthesizing effect Effects 0.000 description 3
- 239000002253 acid Substances 0.000 description 2
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 description 2
- 239000003610 charcoal Substances 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 238000004891 communication Methods 0.000 description 2
- 230000002950 deficient Effects 0.000 description 2
- 230000006866 deterioration Effects 0.000 description 2
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 description 2
- 238000007373 indentation Methods 0.000 description 2
- 239000004611 light stabiliser Substances 0.000 description 2
- 238000000465 moulding Methods 0.000 description 2
- 229910052754 neon Inorganic materials 0.000 description 2
- GKAOGPIIYCISHV-UHFFFAOYSA-N neon atom Chemical compound [Ne] GKAOGPIIYCISHV-UHFFFAOYSA-N 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 238000003466 welding Methods 0.000 description 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- KLSLBUSXWBJMEC-UHFFFAOYSA-N 4-Propylphenol Chemical compound CCCC1=CC=C(O)C=C1 KLSLBUSXWBJMEC-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
- 230000006750 UV protection Effects 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 239000004816 latex Substances 0.000 description 1
- 229920000126 latex Polymers 0.000 description 1
- 230000000877 morphologic effect Effects 0.000 description 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical class OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 235000019260 propionic acid Nutrition 0.000 description 1
- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 description 1
- 238000005070 sampling Methods 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 229920001909 styrene-acrylic polymer Polymers 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
Abstract
Description
实施例1 | 实施例2 | 实施例3 | |
苯乙烯-丙烯腈-丙烯酸酯共聚物 | 300 | 500 | 650 |
聚碳酸酯 | 650 | 400 | 350 |
ACR弹性体 | 50 | 100 | 0 |
抗氧剂 | 2 | 2 | 2 |
紫外光稳定剂 | 2 | 0 | 2 |
性能指标 | 实施例1 | 实施例2 | 实施例3 |
拉伸强度(Mpa) | 56 | 52 | 58 |
简支梁缺口冲击强度(Mpa) | 560 | 230 | 110 |
球压痕硬度(N/mm2) | 110 | 126 | 128 |
弯曲强度(Mpa) | 88 | 84.2 | 86.5 |
弯曲模量(Mpa) | 2600 | 2460 | 2780 |
耐候性 | 氖灯加速老化1600小时色牢度为5级 | ||
模塑收缩率(%) | 0.5-0.7 | 0.5-0.7 | 0.5-0.7 |
性能指标 | 上海制笔化工厂MAS-711 | GELOYXP4025 | 实施例1 | 实施例2 | 实施例3 |
拉伸强度(Mpa) | 65 | 59 | 56 | 52 | 58 |
简支梁缺口 | 25 | 171 | 560 | 230 | 110 |
球压痕硬度 | 130 | - | 110 | 126 | 128 |
弯曲强度(Mpa) | 90 | 88 | 88 | 84.2 | 86.5 |
弯曲模量(Mpa) | 3600 | 2586 | 2600 | 2460 | 2780 |
耐候性 | 氖灯加速老化1600小时色牢度为5级 | ||||
模塑收缩率(%) | 0.5 | 0.5-0.7 | 0.5-0.7 | 0.5-0.7 | 0.5-0.7 |
Claims (6)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN 01142633 CN1227291C (zh) | 2001-12-12 | 2001-12-12 | 耐候抗冲苯乙烯工程塑料合金及其制备方法 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN 01142633 CN1227291C (zh) | 2001-12-12 | 2001-12-12 | 耐候抗冲苯乙烯工程塑料合金及其制备方法 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN1424349A true CN1424349A (zh) | 2003-06-18 |
CN1227291C CN1227291C (zh) | 2005-11-16 |
Family
ID=4676865
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN 01142633 Expired - Lifetime CN1227291C (zh) | 2001-12-12 | 2001-12-12 | 耐候抗冲苯乙烯工程塑料合金及其制备方法 |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN1227291C (zh) |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101805502A (zh) * | 2010-04-08 | 2010-08-18 | 上海金昌工程塑料有限公司 | 永久抗静电的pc/asa材料 |
CN101942188A (zh) * | 2010-09-28 | 2011-01-12 | 苏州旭光聚合物有限公司 | 一种永久抗静电pc/asa复合材料及其制备方法 |
CN101205274B (zh) * | 2006-12-18 | 2011-06-01 | 奇美实业股份有限公司 | 橡胶改质苯乙烯系树脂组成物 |
CN103788611A (zh) * | 2012-10-30 | 2014-05-14 | 合肥杰事杰新材料股份有限公司 | 高强度导电聚碳酸酯合金环保复合材料及其制备方法 |
WO2019122103A1 (en) * | 2017-12-21 | 2019-06-27 | Ineos Styrolution Group Gmbh | Repair and assembly part of a wind turbine blade |
CN114891308A (zh) * | 2016-08-10 | 2022-08-12 | 深圳毅彩鸿翔新材料科技有限公司 | 抗紫外耐候性asa树脂、共挤塑料制品、薄膜和制品 |
-
2001
- 2001-12-12 CN CN 01142633 patent/CN1227291C/zh not_active Expired - Lifetime
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101205274B (zh) * | 2006-12-18 | 2011-06-01 | 奇美实业股份有限公司 | 橡胶改质苯乙烯系树脂组成物 |
CN101805502A (zh) * | 2010-04-08 | 2010-08-18 | 上海金昌工程塑料有限公司 | 永久抗静电的pc/asa材料 |
CN101942188A (zh) * | 2010-09-28 | 2011-01-12 | 苏州旭光聚合物有限公司 | 一种永久抗静电pc/asa复合材料及其制备方法 |
CN103788611A (zh) * | 2012-10-30 | 2014-05-14 | 合肥杰事杰新材料股份有限公司 | 高强度导电聚碳酸酯合金环保复合材料及其制备方法 |
CN114891308A (zh) * | 2016-08-10 | 2022-08-12 | 深圳毅彩鸿翔新材料科技有限公司 | 抗紫外耐候性asa树脂、共挤塑料制品、薄膜和制品 |
WO2019122103A1 (en) * | 2017-12-21 | 2019-06-27 | Ineos Styrolution Group Gmbh | Repair and assembly part of a wind turbine blade |
EP4219624A1 (en) * | 2017-12-21 | 2023-08-02 | INEOS Styrolution Group GmbH | Use of repair and assembly part of a wind turbine blade |
Also Published As
Publication number | Publication date |
---|---|
CN1227291C (zh) | 2005-11-16 |
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C14 | Grant of patent or utility model | ||
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Owner name: HEFEI JIESHIJIE NEW MATERIAL CO., LTD. Free format text: FORMER OWNER: JIESHIJIE NOVEL MATERIALS CO., LTD, SHANGHAI Effective date: 20060915 |
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Effective date of registration: 20060915 Address after: 201109 No. 800 North Song Road, Shanghai, Minhang District Patentee after: Hefei Genius New Materials Co., Ltd. Address before: 201109, No. 800, North Song Road, North Qiao Town, Shanghai, Minhang District Patentee before: Jieshijie New Materials Co., Ltd., Shanghai |
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Effective date of registration: 20070514 Pledge (preservation): Pledge |
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Assignee: Qingdao Gon Technology Development Co., Ltd. Assignor: Hefei Genius New Materials Co., Ltd. Contract fulfillment period: 2008.9.18 to 2018.9.17 Contract record no.: 2008370000090 Denomination of invention: Weatherproof styrene engineering plastic alloy and preparation thereof Granted publication date: 20051116 License type: Exclusive license Record date: 20081105 |
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LIC | Patent licence contract for exploitation submitted for record |
Free format text: EXCLUSIVE LICENSE; TIME LIMIT OF IMPLEMENTING CONTACT: 2008.9.18 TO 2018.9.17; CHANGE OF CONTRACT Name of requester: QINGDAO GUOEN SCIENCE DEVELOPMENT CO., LTD. Effective date: 20081105 |
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Date of cancellation: 20100406 Granted publication date: 20051116 Pledgee: Hefei Heng Hai investment holding group company Pledgor: Hefei Genius New Materials Co., Ltd. Registration number: 200734352 |
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Address after: 230601 Hefei economic and Technological Development Zone, Anhui Lianhua Road, No. 2388 Patentee after: Hefei Genius New Materials Co., Ltd. Address before: 201109 Minhang District North Road, Shanghai, No. 800 Patentee before: Hefei Genius New Materials Co., Ltd. |
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PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: Weatherproof styrene engineering plastic alloy and preparation thereof Effective date of registration: 20150205 Granted publication date: 20051116 Pledgee: Hefei Heng Hai investment holding group company Pledgor: Hefei Genius New Materials Co., Ltd. Registration number: 2015340000004 |
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PC01 | Cancellation of the registration of the contract for pledge of patent right |
Date of cancellation: 20151201 Granted publication date: 20051116 Pledgee: Hefei Heng Hai investment holding group company Pledgor: Hefei Genius New Materials Co., Ltd. Registration number: 2015340000004 |
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PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: Weatherproof styrene engineering plastic alloy and preparation thereof Effective date of registration: 20160415 Granted publication date: 20051116 Pledgee: Hefei Heng Hai investment holding group company Pledgor: Hefei Genius New Materials Co., Ltd. Registration number: 2016340000015 |
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Granted publication date: 20051116 |