CN1406996A - Preparation of amphoteric polyurethane resin and products thereby and amphoteric resin composition - Google Patents
Preparation of amphoteric polyurethane resin and products thereby and amphoteric resin composition Download PDFInfo
- Publication number
- CN1406996A CN1406996A CN02128235A CN02128235A CN1406996A CN 1406996 A CN1406996 A CN 1406996A CN 02128235 A CN02128235 A CN 02128235A CN 02128235 A CN02128235 A CN 02128235A CN 1406996 A CN1406996 A CN 1406996A
- Authority
- CN
- China
- Prior art keywords
- compound
- urethane resin
- amphoteric urethane
- preparation
- group
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000002360 preparation method Methods 0.000 title claims description 106
- 229920005749 polyurethane resin Polymers 0.000 title claims description 6
- 239000011342 resin composition Substances 0.000 title claims 2
- 150000001875 compounds Chemical class 0.000 claims abstract description 208
- 229920002803 thermoplastic polyurethane Polymers 0.000 claims abstract description 203
- -1 polysiloxane Polymers 0.000 claims abstract description 138
- 229920001296 polysiloxane Polymers 0.000 claims abstract description 46
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims abstract description 44
- IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 claims abstract description 43
- 125000000467 secondary amino group Chemical group [H]N([*:1])[*:2] 0.000 claims abstract description 32
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims abstract description 31
- 238000000034 method Methods 0.000 claims abstract description 25
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims abstract description 15
- 229920005862 polyol Polymers 0.000 claims abstract description 14
- 239000005056 polyisocyanate Substances 0.000 claims abstract description 8
- 229920001228 polyisocyanate Polymers 0.000 claims abstract description 8
- 239000007864 aqueous solution Substances 0.000 claims description 70
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 39
- 238000006243 chemical reaction Methods 0.000 claims description 34
- 239000000203 mixture Substances 0.000 claims description 30
- 239000004205 dimethyl polysiloxane Substances 0.000 claims description 28
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 claims description 28
- 238000006276 transfer reaction Methods 0.000 claims description 20
- 239000007795 chemical reaction product Substances 0.000 claims description 14
- 239000000126 substance Substances 0.000 claims description 13
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 9
- 229920001577 copolymer Polymers 0.000 claims description 7
- 229920005604 random copolymer Polymers 0.000 claims description 6
- 239000002537 cosmetic Substances 0.000 abstract description 8
- 150000003077 polyols Chemical class 0.000 abstract description 6
- 238000004519 manufacturing process Methods 0.000 abstract 2
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical group [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 abstract 1
- 125000001302 tertiary amino group Chemical group 0.000 abstract 1
- 239000003795 chemical substances by application Substances 0.000 description 78
- 230000000052 comparative effect Effects 0.000 description 66
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 30
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 27
- 229920005989 resin Polymers 0.000 description 21
- 239000011347 resin Substances 0.000 description 21
- 239000006260 foam Substances 0.000 description 19
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 18
- 238000005406 washing Methods 0.000 description 17
- 229920001451 polypropylene glycol Polymers 0.000 description 16
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 14
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 12
- 239000000499 gel Substances 0.000 description 11
- 239000000443 aerosol Substances 0.000 description 10
- 239000000865 liniment Substances 0.000 description 10
- 229940040145 liniment Drugs 0.000 description 10
- 239000000243 solution Substances 0.000 description 10
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 9
- 239000011248 coating agent Substances 0.000 description 9
- 238000000576 coating method Methods 0.000 description 9
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 9
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 9
- 238000011156 evaluation Methods 0.000 description 8
- 239000003054 catalyst Substances 0.000 description 7
- 239000003960 organic solvent Substances 0.000 description 7
- 239000003380 propellant Substances 0.000 description 7
- 239000002904 solvent Substances 0.000 description 7
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 6
- 230000003648 hair appearance Effects 0.000 description 6
- CRVGTESFCCXCTH-UHFFFAOYSA-N methyl diethanolamine Chemical compound OCCN(C)CCO CRVGTESFCCXCTH-UHFFFAOYSA-N 0.000 description 6
- 229920005906 polyester polyol Polymers 0.000 description 6
- 229920000642 polymer Polymers 0.000 description 6
- PTBDIHRZYDMNKB-UHFFFAOYSA-N 2,2-Bis(hydroxymethyl)propionic acid Chemical compound OCC(C)(CO)C(O)=O PTBDIHRZYDMNKB-UHFFFAOYSA-N 0.000 description 5
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 5
- 239000004721 Polyphenylene oxide Substances 0.000 description 5
- YIMQCDZDWXUDCA-UHFFFAOYSA-N [4-(hydroxymethyl)cyclohexyl]methanol Chemical compound OCC1CCC(CO)CC1 YIMQCDZDWXUDCA-UHFFFAOYSA-N 0.000 description 5
- 239000008367 deionised water Substances 0.000 description 5
- 229910021641 deionized water Inorganic materials 0.000 description 5
- NIMLQBUJDJZYEJ-UHFFFAOYSA-N isophorone diisocyanate Chemical compound CC1(C)CC(N=C=O)CC(C)(CN=C=O)C1 NIMLQBUJDJZYEJ-UHFFFAOYSA-N 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- 229910052757 nitrogen Inorganic materials 0.000 description 5
- 229920000570 polyether Polymers 0.000 description 5
- 230000001953 sensory effect Effects 0.000 description 5
- 238000012360 testing method Methods 0.000 description 5
- 229940058015 1,3-butylene glycol Drugs 0.000 description 4
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 4
- 125000000129 anionic group Chemical group 0.000 description 4
- 235000019437 butane-1,3-diol Nutrition 0.000 description 4
- 239000003921 oil Substances 0.000 description 4
- 239000002245 particle Substances 0.000 description 4
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
- ARSRBNBHOADGJU-UHFFFAOYSA-N 7,12-dimethyltetraphene Chemical compound C1=CC2=CC=CC=C2C2=C1C(C)=C(C=CC=C1)C1=C2C ARSRBNBHOADGJU-UHFFFAOYSA-N 0.000 description 3
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- VFZRZRDOXPRTSC-UHFFFAOYSA-N DMBA Natural products COC1=CC(OC)=CC(C=O)=C1 VFZRZRDOXPRTSC-UHFFFAOYSA-N 0.000 description 3
- SJRJJKPEHAURKC-UHFFFAOYSA-N N-Methylmorpholine Chemical compound CN1CCOCC1 SJRJJKPEHAURKC-UHFFFAOYSA-N 0.000 description 3
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 3
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 3
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 3
- 239000000654 additive Substances 0.000 description 3
- 125000003545 alkoxy group Chemical group 0.000 description 3
- 125000004432 carbon atom Chemical group C* 0.000 description 3
- 239000006185 dispersion Substances 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 125000000524 functional group Chemical group 0.000 description 3
- 235000011187 glycerol Nutrition 0.000 description 3
- XXMIOPMDWAUFGU-UHFFFAOYSA-N hexane-1,6-diol Chemical compound OCCCCCCO XXMIOPMDWAUFGU-UHFFFAOYSA-N 0.000 description 3
- 238000009775 high-speed stirring Methods 0.000 description 3
- 125000001183 hydrocarbyl group Chemical group 0.000 description 3
- 239000011541 reaction mixture Substances 0.000 description 3
- 238000010992 reflux Methods 0.000 description 3
- 229910052710 silicon Inorganic materials 0.000 description 3
- 239000010703 silicon Substances 0.000 description 3
- 229960004418 trolamine Drugs 0.000 description 3
- 238000009736 wetting Methods 0.000 description 3
- 229940008841 1,6-hexamethylene diisocyanate Drugs 0.000 description 2
- MNAHQWDCXOHBHK-UHFFFAOYSA-N 1-phenylpropane-1,1-diol Chemical compound CCC(O)(O)C1=CC=CC=C1 MNAHQWDCXOHBHK-UHFFFAOYSA-N 0.000 description 2
- UPMLOUAZCHDJJD-UHFFFAOYSA-N 4,4'-Diphenylmethane Diisocyanate Chemical compound C1=CC(N=C=O)=CC=C1CC1=CC=C(N=C=O)C=C1 UPMLOUAZCHDJJD-UHFFFAOYSA-N 0.000 description 2
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 2
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- DTGKSKDOIYIVQL-MRTMQBJTSA-N Isoborneol Natural products C1C[C@@]2(C)[C@H](O)C[C@@H]1C2(C)C DTGKSKDOIYIVQL-MRTMQBJTSA-N 0.000 description 2
- 239000005058 Isophorone diisocyanate Substances 0.000 description 2
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 2
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 125000002723 alicyclic group Chemical group 0.000 description 2
- 125000001931 aliphatic group Chemical group 0.000 description 2
- 150000001408 amides Chemical class 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- CKDOCTFBFTVPSN-UHFFFAOYSA-N borneol Natural products C1CC2(C)C(C)CC1C2(C)C CKDOCTFBFTVPSN-UHFFFAOYSA-N 0.000 description 2
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 2
- 239000012973 diazabicyclooctane Substances 0.000 description 2
- 125000005442 diisocyanate group Chemical group 0.000 description 2
- 150000002009 diols Chemical class 0.000 description 2
- DTGKSKDOIYIVQL-UHFFFAOYSA-N dl-isoborneol Natural products C1CC2(C)C(O)CC1C2(C)C DTGKSKDOIYIVQL-UHFFFAOYSA-N 0.000 description 2
- 229960005082 etohexadiol Drugs 0.000 description 2
- JFCQEDHGNNZCLN-UHFFFAOYSA-N glutaric acid Chemical compound OC(=O)CCCC(O)=O JFCQEDHGNNZCLN-UHFFFAOYSA-N 0.000 description 2
- RRAMGCGOFNQTLD-UHFFFAOYSA-N hexamethylene diisocyanate Chemical compound O=C=NCCCCCCN=C=O RRAMGCGOFNQTLD-UHFFFAOYSA-N 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 239000003863 metallic catalyst Substances 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 description 2
- BKIMMITUMNQMOS-UHFFFAOYSA-N nonane Chemical compound CCCCCCCCC BKIMMITUMNQMOS-UHFFFAOYSA-N 0.000 description 2
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 2
- 125000002524 organometallic group Chemical group 0.000 description 2
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 2
- KIDHWZJUCRJVML-UHFFFAOYSA-N putrescine Chemical compound NCCCCN KIDHWZJUCRJVML-UHFFFAOYSA-N 0.000 description 2
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 239000002453 shampoo Substances 0.000 description 2
- 239000007858 starting material Substances 0.000 description 2
- 150000005846 sugar alcohols Polymers 0.000 description 2
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 2
- 230000008719 thickening Effects 0.000 description 2
- REZQBEBOWJAQKS-UHFFFAOYSA-N triacontyl alcohol Natural products CCCCCCCCCCCCCCCCCCCCCCCCCCCCCCO REZQBEBOWJAQKS-UHFFFAOYSA-N 0.000 description 2
- 239000004034 viscosity adjusting agent Substances 0.000 description 2
- WOGVOIWHWZWYOZ-UHFFFAOYSA-N 1,1-diisocyanatoethane Chemical compound O=C=NC(C)N=C=O WOGVOIWHWZWYOZ-UHFFFAOYSA-N 0.000 description 1
- ZXHZWRZAWJVPIC-UHFFFAOYSA-N 1,2-diisocyanatonaphthalene Chemical compound C1=CC=CC2=C(N=C=O)C(N=C=O)=CC=C21 ZXHZWRZAWJVPIC-UHFFFAOYSA-N 0.000 description 1
- 239000005059 1,4-Cyclohexyldiisocyanate Substances 0.000 description 1
- ATOUXIOKEJWULN-UHFFFAOYSA-N 1,6-diisocyanato-2,2,4-trimethylhexane Chemical compound O=C=NCCC(C)CC(C)(C)CN=C=O ATOUXIOKEJWULN-UHFFFAOYSA-N 0.000 description 1
- GVNHOISKXMSMPX-UHFFFAOYSA-N 2-[butyl(2-hydroxyethyl)amino]ethanol Chemical compound CCCCN(CCO)CCO GVNHOISKXMSMPX-UHFFFAOYSA-N 0.000 description 1
- NKFNBVMJTSYZDV-UHFFFAOYSA-N 2-[dodecyl(2-hydroxyethyl)amino]ethanol Chemical compound CCCCCCCCCCCCN(CCO)CCO NKFNBVMJTSYZDV-UHFFFAOYSA-N 0.000 description 1
- BFSVOASYOCHEOV-UHFFFAOYSA-N 2-diethylaminoethanol Chemical compound CCN(CC)CCO BFSVOASYOCHEOV-UHFFFAOYSA-N 0.000 description 1
- ZNQVEEAIQZEUHB-UHFFFAOYSA-N 2-ethoxyethanol Chemical compound CCOCCO ZNQVEEAIQZEUHB-UHFFFAOYSA-N 0.000 description 1
- SVONRAPFKPVNKG-UHFFFAOYSA-N 2-ethoxyethyl acetate Chemical compound CCOCCOC(C)=O SVONRAPFKPVNKG-UHFFFAOYSA-N 0.000 description 1
- UZPWKTCMUADILM-UHFFFAOYSA-N 3-methylcyclohexene Chemical compound CC1CCCC=C1 UZPWKTCMUADILM-UHFFFAOYSA-N 0.000 description 1
- 206010013786 Dry skin Diseases 0.000 description 1
- KGWDUNBJIMUFAP-KVVVOXFISA-N Ethanolamine Oleate Chemical compound NCCO.CCCCCCCC\C=C/CCCCCCCC(O)=O KGWDUNBJIMUFAP-KVVVOXFISA-N 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- FXHOOIRPVKKKFG-UHFFFAOYSA-N N,N-Dimethylacetamide Chemical compound CN(C)C(C)=O FXHOOIRPVKKKFG-UHFFFAOYSA-N 0.000 description 1
- UEEJHVSXFDXPFK-UHFFFAOYSA-N N-dimethylaminoethanol Chemical compound CN(C)CCO UEEJHVSXFDXPFK-UHFFFAOYSA-N 0.000 description 1
- AKNUHUCEWALCOI-UHFFFAOYSA-N N-ethyldiethanolamine Chemical compound OCCN(CC)CCO AKNUHUCEWALCOI-UHFFFAOYSA-N 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 239000005062 Polybutadiene Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- 240000006474 Theobroma bicolor Species 0.000 description 1
- XSTXAVWGXDQKEL-UHFFFAOYSA-N Trichloroethylene Chemical compound ClC=C(Cl)Cl XSTXAVWGXDQKEL-UHFFFAOYSA-N 0.000 description 1
- XMUZQOKACOLCSS-UHFFFAOYSA-N [2-(hydroxymethyl)phenyl]methanol Chemical compound OCC1=CC=CC=C1CO XMUZQOKACOLCSS-UHFFFAOYSA-N 0.000 description 1
- UKLDJPRMSDWDSL-UHFFFAOYSA-L [dibutyl(dodecanoyloxy)stannyl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)O[Sn](CCCC)(CCCC)OC(=O)CCCCCCCCCCC UKLDJPRMSDWDSL-UHFFFAOYSA-L 0.000 description 1
- 150000008065 acid anhydrides Chemical class 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 239000003463 adsorbent Substances 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 230000003750 conditioning effect Effects 0.000 description 1
- 239000006071 cream Substances 0.000 description 1
- 150000004292 cyclic ethers Chemical class 0.000 description 1
- FOTKYAAJKYLFFN-UHFFFAOYSA-N decane-1,10-diol Chemical compound OCCCCCCCCCCO FOTKYAAJKYLFFN-UHFFFAOYSA-N 0.000 description 1
- 239000012975 dibutyltin dilaurate Substances 0.000 description 1
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 230000001804 emulsifying effect Effects 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 230000001815 facial effect Effects 0.000 description 1
- 239000001530 fumaric acid Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- HNDLTSNUZCYNRL-UHFFFAOYSA-N hexadecan-5-ol Chemical compound CCCCCCCCCCCC(O)CCCC HNDLTSNUZCYNRL-UHFFFAOYSA-N 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 238000005984 hydrogenation reaction Methods 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 150000002500 ions Chemical group 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 150000002596 lactones Chemical class 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- HZVOZRGWRWCICA-UHFFFAOYSA-N methanediyl Chemical compound [CH2] HZVOZRGWRWCICA-UHFFFAOYSA-N 0.000 description 1
- LAQFLZHBVPULPL-UHFFFAOYSA-N methyl(phenyl)silicon Chemical compound C[Si]C1=CC=CC=C1 LAQFLZHBVPULPL-UHFFFAOYSA-N 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- GOQYKNQRPGWPLP-UHFFFAOYSA-N n-heptadecyl alcohol Natural products CCCCCCCCCCCCCCCCCO GOQYKNQRPGWPLP-UHFFFAOYSA-N 0.000 description 1
- BDERNNFJNOPAEC-UHFFFAOYSA-N n-propyl alcohol Natural products CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 1
- AHHWIHXENZJRFG-UHFFFAOYSA-N oxetane Chemical compound C1COC1 AHHWIHXENZJRFG-UHFFFAOYSA-N 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 229920002857 polybutadiene Polymers 0.000 description 1
- 229920001610 polycaprolactone Polymers 0.000 description 1
- 239000004632 polycaprolactone Substances 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 238000006068 polycondensation reaction Methods 0.000 description 1
- 229920001195 polyisoprene Polymers 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 229920000259 polyoxyethylene lauryl ether Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 150000003141 primary amines Chemical class 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- CIBMHJPPKCXONB-UHFFFAOYSA-N propane-2,2-diol Chemical compound CC(C)(O)O CIBMHJPPKCXONB-UHFFFAOYSA-N 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000007151 ring opening polymerisation reaction Methods 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 235000013599 spices Nutrition 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 239000003206 sterilizing agent Substances 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 239000012970 tertiary amine catalyst Substances 0.000 description 1
- 150000003512 tertiary amines Chemical class 0.000 description 1
- 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 description 1
- DVKJHBMWWAPEIU-UHFFFAOYSA-N toluene 2,4-diisocyanate Chemical compound CC1=CC=C(N=C=O)C=C1N=C=O DVKJHBMWWAPEIU-UHFFFAOYSA-N 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- IMNIMPAHZVJRPE-UHFFFAOYSA-N triethylenediamine Chemical compound C1CN2CCN1CC2 IMNIMPAHZVJRPE-UHFFFAOYSA-N 0.000 description 1
- 239000002966 varnish Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/65—Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
- C08G18/66—Compounds of groups C08G18/42, C08G18/48, or C08G18/52
- C08G18/6633—Compounds of group C08G18/42
- C08G18/6659—Compounds of group C08G18/42 with compounds of group C08G18/34
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/87—Polyurethanes
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/896—Polysiloxanes containing atoms other than silicon, carbon, oxygen and hydrogen, e.g. dimethicone copolyol phosphate
- A61K8/898—Polysiloxanes containing atoms other than silicon, carbon, oxygen and hydrogen, e.g. dimethicone copolyol phosphate containing nitrogen, e.g. amodimethicone, trimethyl silyl amodimethicone or dimethicone propyl PG-betaine
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/06—Preparations for styling the hair, e.g. by temporary shaping or colouring
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/0804—Manufacture of polymers containing ionic or ionogenic groups
- C08G18/0819—Manufacture of polymers containing ionic or ionogenic groups containing anionic or anionogenic groups
- C08G18/0823—Manufacture of polymers containing ionic or ionogenic groups containing anionic or anionogenic groups containing carboxylate salt groups or groups forming them
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/10—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
- C08G18/12—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step using two or more compounds having active hydrogen in the first polymerisation step
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L75/00—Compositions of polyureas or polyurethanes; Compositions of derivatives of such polymers
- C08L75/04—Polyurethanes
Landscapes
- Health & Medical Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- General Health & Medical Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Polyurethanes Or Polyureas (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Cosmetics (AREA)
Abstract
The invention presents a method for manufacturing an amphoteric urethane resin, improving at least one of the performance of cosmetics including this amphoteric urethane resin and the storage stability of the urethane resin. The method for manufacturing an amphoteric urethane resin uses (A) a polyol; (B) a polyisocyanate; (C) a polysiloxane compound (except any having at least one selected from a hydroxyl group, a primary amino group and a secondary amino group at one or both ends of the siloxane chain); (D) a compound having carboxyl groups and at least one selected from a hydroxyl group, a primary amino group and a secondary amino group; (E) a compound having tertiary amino groups and at least one selected from a hydroxyl group, a primary amino group and a secondary amino group; and the method includes a step of making a prepolymer including isocyanate groups by reacting the compounds (A), (B) and (D) with excessive isocyanate groups; and a step of reacting the prepolymer including the isocyanate groups with the compound (E); wherein the compound (C) is present in at least one of the first step and the second step.
Description
Background of invention
Invention field
Amphoteric resin that the present invention relates to the preparation method of amphoteric urethane resin, obtains with these preparation methods and the resin combination that comprises these amphoteric urethane resins.More specifically, the present invention relates to be used for the resin combination of makeup, relate to the preparation method of the amphoteric urethane resin that is used for this composition, and relate to the amphoteric urethane resin that obtains with this preparation method.
Description of Related Art
Urethane resin has excellent flexibility, hardness and wear resistance, is widely used as for example base material of building, timber and automotive coating.In addition, urethane resin is also attempted the starting material as makeup, has been proposed to be used in the starting material of hair style fixing agent especially.
JP H06-321741A discloses the hair style fixing agent that adopts anionic polyurethane resin can obtain having excellent hair style fixed performance, hair quality and prevent hair scale perk performance.Yet anionic polyurethane resin has bigger surface friction drag, therefore in the hair style fixing agent that adopts anionic polyurethane resin, has the problem of feel, gloss and the cleaning performance difference of hair.
For addressing this problem, JP H11-228363A discloses the used for cosmetic resin combination, and said composition has comprised the amphoteric urethane resin that has carboxyl and uncle's amino in each molecule simultaneously.
Adopted the hair style fixing agent of the used for cosmetic resin combination that comprises this amphoteric urethane resin to obtain than better hair quality of hair style fixing agent that comprises anionic polyurethane resin and hair washing performance, if but estimate them with stricter standard, when on hair, smearing the hair style fixing agent, the gloss of hair and feel, and the spreadability of hair style fixing agent not enough, requires further to improve its performance.As if these problems are because the amphoteric urethane resin surface has bigger frictional coefficient and causes.
In order to solve these problems by the quality that improves the amphoteric urethane resin that comprises in the used for cosmetic resin combination, JP 2000-192476A discloses the polysiloxane compound that has the functional group that comprises reactive hydrogen in the one or both ends of siloxane chain by using, thereby introduces the method for polysiloxane chain in the amphoteric urethane resin skeleton.On the other hand, JP 2001-48735A has proposed to add subsequently the method for polysiloxane compound in the amphoteric urethane resin aqueous solution.
When use has the hair style fixing agent of the used for cosmetic resin compound that comprises amphoteric urethane resin, by using the polysiloxane compound that has the functional group that comprises reactive hydrogen in the one or both ends of siloxane chain to introduce polysiloxane chain (hereinafter referred to as " 1 type amphoteric urethane resin "), the hair style fixed performance is good in the skeleton of described amphoteric urethane resin.Yet when use had the hair style fixing agent of the used for cosmetic resin combination that comprises 1 type amphoteric urethane resin, the spreadability of hair style fixing agent was not enough.
On the other hand, when use has the hair style fixing agent of the used for cosmetic resin compound that comprises improved amphoteric urethane resin, wherein added polysiloxane compound (hereinafter referred to as " 2 type amphoteric urethane resin ") in amphoteric urethane resin solution subsequently, the spreadability of hair style fixing agent is good.Yet in 2 type amphoteric urethane resins, the polysiloxane compound of Jia Ruing can separate from amphoteric urethane resin subsequently, thereby brings the insufficient problem of stability in storage of the makeup that adopt 2 type amphoteric urethane resins.
Therefore an object of the present invention is to address these problems, and the preparation method that amphoteric urethane resin is provided wherein, having at least a kind of and traditional amphoteric urethane resin to compare in the stability in storage of performance of coating, liniment and the makeup of employing amphoteric urethane resin (with regard to the hair style fixing agent, the spreadability when for example referring to the feel of hair style fixed performance, hair quality, hair washing performance, hair and applying the hair style fixing agent) and amphoteric urethane resin improves.The present invention also provides a kind of usefulness amphoteric urethane resin that this preparation method obtains and comprises the resin combination of this amphoteric urethane resin.
The present invention's general introduction
In order to reach these purposes, through further investigation, the inventor finds by polysiloxane compound being limited to some compound, and interpolation time of this polysiloxane compound when limiting the preparation amphoteric urethane resin, the performance of gained amphoteric urethane resin is affected, and obtains the present invention like this.
According to one aspect of the invention, the novel preparation method of amphoteric urethane resin has been proposed, this method adopts:
(A) polyol compound (below be also referred to as " compound (A) ");
(B) polyisocyanate compound (below be also referred to as " compound (B) ");
(C) polysiloxane compound (have at least one group of being selected from hydroxyl, primary amino and secondary amino group except) (below be also referred to as " compound (C) ") in the one or both ends of siloxane chain;
(D) have carboxyl and be selected from the compound (below be also referred to as " compound (D) ") of at least one group of hydroxyl, primary amino and secondary amino group;
(E) it is amino and be selected from the compound (below be also referred to as " compound (E) ") of at least one group of hydroxyl, primary amino and secondary amino group to have a uncle; This method comprises:
The first step prepares the prepolymer that comprises isocyanate groups for making compound (A), (B) and (D) react under the excessive condition of isocyanate groups; With
Second step is for making prepolymer and compound (E) reaction that comprises isocyanate groups;
Wherein the first step and second the step at least one step in have compound (C).
According to a further aspect in the invention, provide the another kind of preparation method of amphoteric urethane resin,
This method is used compound (A) to (E);
This method comprises:
The first step prepares the prepolymer that comprises isocyanate groups for making compound (A), (B) and (E) react under the excessive condition of isocyanate groups; With
Second step is for making prepolymer and compound (D) reaction that comprises isocyanate groups;
Wherein the first step and second the step at least one step in have compound (C).
Like this, in preparation method of the present invention, the reaction sequence of compound (D) and compound (E) can be put upside down.
Preparation method's of the present invention characteristics are the first steps and have compound (C) at least one step in second step.Compound herein (C) can exist in the first step and any moment in second step, and compound (C) needn't just exist from the reaction beginning.When mixing with water, the reaction product in second step should have compound (C) to exist.Therefore, in this specification sheets, " the first step " expression begins to the time the reaction beginning of second step from the first step reaction, the time (more specifically say so when the reaction product in following second step with water mix till) of " second step " expression from the reaction of second step to the step of carrying out subsequently.
Preparation method's of the present invention characteristics be the first step and second the step at least one step in " existence " compound (C).Herein, " existence " is illustrated in and has compound (C) in the reaction system, although do not plan to carry out the active reaction of compound (C), part of compounds (C) reaction must be arranged at last.In other words, preparation method of the present invention plans with amphoteric urethane resin skeleton " constraint " compound (C), or, do not react but do not plan to make compound (C) and amphoteric urethane resin skeleton to carry out chemically reactive with amphoteric urethane resin skeleton " entanglement " compound (C).Yet compound (C) finally also can form the part skeleton of amphoteric urethane resin, as long as the amphoteric urethane resin that can obtain requiring is also included among the preparation method of the present invention.Therefore, " amphoteric urethane resin " of the present invention represents wherein compound (C) by the amphoteric urethane resin of amphoteric urethane resin skeleton " constraint " and/or " entanglement ", but also can be the amphoteric urethane resin that part amphoteric urethane resin skeleton is wherein produced by compound (C).Below set forth the intent of the present invention in more detail.
According to a further aspect of the invention, a kind of amphoteric urethane resin preparation method of novelty has been proposed, this method has used compound (A) to (E) with have a compound (F) of the structural unit of at least one group that is selected from hydroxyl, primary amino and secondary amino group and following formula (11) expression
Chemical formula 3(11)-(C
2H
4O)
p(C
3H
6O)
q-
Wherein " p " is 1 to 500 integer, and " q " is 0 to 400 integer,
Wherein, if the structural unit in the structural formula (11) is C
2H
4O and C
3H
6The multipolymer of O (being q ≠ 0), they can be random copolymers or segmented copolymer (below be also referred to as " compound (F) ");
This method comprises:
The first step prepares the prepolymer that comprises isocyanate groups for making compound (A), (B), (D) and (F) react under the excessive condition of isocyanate groups; With
Second step is for making prepolymer and compound (E) reaction that comprises isocyanate groups;
Wherein the first step and second the step at least one step in have compound (C).
According to a further aspect of the invention, provide the another kind of preparation method of amphoteric urethane resin,
This method is used compound (A) to (F);
This method comprises:
The first step prepares the prepolymer that comprises isocyanate groups for making compound (A), (B), (E) and (F) react under the excessive condition of isocyanate groups; With
Second step is for making prepolymer and compound (D) reaction that comprises isocyanate groups;
Wherein the first step and second the step at least one step in have compound (C).
Like this, in preparation method of the present invention, the reaction sequence of compound (D) and compound (E) can be put upside down.And the meaning in " existence ", " the first step " and " second step " is the same.
In preparation method of the present invention, preferably after second step,, second reaction product that goes on foot carries out transfer reaction by being mixed with water.
In preparation method of the present invention, equally preferably, after second step,, second reaction product that goes on foot carries out transfer reaction by being mixed with buck, or, mix with water then and carry out transfer reaction by in the reaction product in second step, adding basic cpd.
The invention allows for the amphoteric urethane resin that obtains by preparation method of the present invention, and the aqueous solution of this amphoteric urethane resin and comprise the resin combination of this amphoteric urethane resin.
Resin combination of the present invention can be used as for example coating of building, timber and automobile, is used as liniment or is used for makeup, but especially can be used for the used for cosmetic resin combination.
Preferred embodiment is described
In this manual, " (A) polyol compound " refers to prepare urethane resin polyol compound commonly used, has no particular limits.The example of this compound (A) comprises polyester polyol, polyether glycol, polycarbonate polyol, polybutadiene polyol, polyisoprene polyvalent alcohol, polyolefin polyhydric alcohol and polyacrylate polyol.
Especially preferably adopt polyester polyol or polyether glycol as compound (A).
The example of " polyester polyol " comprises by at least a dicarboxylic acid such as succsinic acid, pentanedioic acid, hexanodioic acid, sebacic acid, nonane diacid, toxilic acid, fumaric acid, phthalic acid and terephthalic acid, with at least a such as ethylene glycol, propylene glycol, 1,4-butyleneglycol, 1,3-butyleneglycol, 1,6-hexylene glycol, neopentyl glycol, 1,8-ethohexadiol, 1, the polyester polyol that the polycondensation of the polyvalent alcohol of 10-decanediol, Diethylene Glycol, the spiroglycol and TriMethylolPropane(TMP) obtains, and the polyester polyol that obtains of the ring-opening polymerization by lactone.
As " polyether glycol ", can use by water, the polyvalent alcohol that is used for synthetic above-mentioned polyester polyol, phenol, their acid anhydride such as dihydroxyphenyl propane, or primary amine or secondary amine, the polyether glycol that obtains with open loop polyaddition reaction such as the cyclic ethers of oxyethane, propylene oxide, trimethylene oxide and tetrahydrofuran (THF).The example also comprises polyoxypropylene polyol, polyoxy tetramethylene polyvalent alcohol, and the polyether glycol (under the situation of multipolymer, can adopt segmented copolymer or random copolymers) that obtains of the open loop polyaddition reaction of at least a and dihydroxyphenyl propane by propylene oxide and oxyethane.
Other examples of compound (A) comprise the LMW polyol compound, as 1,4-cyclohexanedimethanol, ethylene glycol, propylene glycol, Isopropanediol, 1,4-butyleneglycol, 1,3-butyleneglycol, butyleneglycol, 1,6-hexylene glycol, neopentyl glycol, 1,8-ethohexadiol, decamethylene-glycol, Diethylene Glycol, dipropylene glycol, the spiroglycol, TriMethylolPropane(TMP), glycerine, two glycerine and triglycerin.
The preferred 1,4 cyclohexane dimethanol that uses is as compound (A).
Compound (A) can be used singly or in combination.
In this manual, if the compound of compound (A) and following compound (F) are overlapping, then this compound is included in the compound (F), and is not included in the compound (A).
Equally, in this manual, if the compound of compound (A) and following compound (D) are overlapping, then this compound is included in the compound (D), and is not included in the compound (A).
In this manual, if the compound of compound (A) and following compound (E) are overlapping, then this compound is included in the compound (E), and is not included in the compound (A).
" (B) polyisocyanate compound " refers to prepare urethane resin polyisocyanate compound commonly used, has no particular limits.The example of this compound (B) comprises organic diisocyanate cpd, as aliphatic vulcabond compound, vulcabond of alicyclic ring compound and aromatic diisocyanate compound.
The example of " aliphatic vulcabond compound " comprises ethylidene diisocyanate, 2,2,4-trimethyl hexamethylene diisocyanate and 1,6-hexamethylene diisocyanate.
The example of " vulcabond of alicyclic ring compound " comprises hydrogenation 4,4 '-diphenylmethanediisocyanate, 1,4-cyclohexyl diisocyanate, tetrahydrotoluene vulcabond, isophorone diisocyanate and iso-borneol alkane vulcabond.The example of " aromatic diisocyanate compound " comprises 4,4 '-diphenylmethanediisocyanate, eylylene diisocyanate, tolylene diisocyanate and naphthalene diisocyanate.
Preferably 1,6-hexamethylene diisocyanate, isophorone diisocyanate and iso-borneol alkane vulcabond are because they have excellent weathering resistance and cheap.
Compound (B) can be used singly or in combination.
" (C) polysiloxane compound (the one or both ends of siloxane chain have at least one group in hydroxyl, primary amino and the secondary amino group except) " refer to have hydroxyl (OH), primary amino (NH except one or both ends at siloxane chain
2) and secondary amino group (polysiloxane compound of the polysiloxane compound of at least one group NH-) has no particular limits, as long as the amphoteric urethane resin that can obtain requiring.
Therefore, compound (C) is included on siloxane chain other parts except that the end polysiloxane compound that (or on siloxane chain middle part) has at least one group in hydroxyl, primary amino and the secondary amino group, and the polysiloxane compound that does not contain any hydroxyl, primary amino or secondary amino group.
The example of compound (C) comprises and is selected from least a of polydimethylsiloxane, polyether-modified siloxanes, cyclosiloxane, phenyl modified siloxanes, alkyl-modified siloxanes and alkoxy-modified siloxanes.
An example of " polydimethylsiloxane " is provided by the compound of following formula (21) expression.
Chemical formula 4
In formula (21), " n " is the integer more than 1 or 1.
Preferably " n " in the formula (21) is 1 to 100 integer, more preferably 1 to 50 integer, most preferably 3 to 30 integer.
The example of " polydimethylsiloxane " comprises Dow Corning Toray Silicone Co., the SH200TM series of Ltd., and Shin-Etsu Chemical Co., the KF96 of Ltd.
TMSeries.
An example of " polyether-modified siloxanes " is provided by the compound of following formula (22) expression.
Chemical formula 5
In formula (22), " m " is the integer more than 0 or 0, and " n " is the integer more than 1 or 1.
R
21Base for following formula (22-2) expression:
Chemical formula 6
-(CH
2)
a-(OC
2H
4)
b-(OC
3H
6)
c-OR
22?????????(22-2)
In formula (22-2), R
22Be hydrogen atom or C
1-C
10Alkyl.
" a " is 1 to 10 integer, and " b " is 1 to 300 integer, and " c " is 0 to 300 integer.
In formula (22), preferably " m " is 1 to 300 integer, more preferably 1 to 100 integer, most preferably 1 to 50 integer." n " be 1 to 300 integer preferably, more preferably 1 to 100 integer, most preferably 1 to 50 integer.
In formula (22-2), " a " be 1 to 5 integer preferably, more preferably 2 to 4 integer." b " be 2 to 50 integer preferably, more preferably 2 to 40 integer, most preferably 2 to 30 integer." c " be 0 to 50 integer preferably, more preferably 0 to 40 integer, most preferably 0 to 30 integer.
For compound (C), preferably in formula 22, " m " is 1 to 300 integer, and " n " is 1 to 300 integer, R
21Be the base of formula (22-2) expression, " a " is 1 to 5 integer, and " b " is 2 to 50 integer, and " c " is 0 to 50 integer.
For compound (C), more preferably in formula 22, " m " is 1 to 100 integer, and " n " is 1 to 100 integer, R
21Be the base of formula (22-2) expression, " a " is 2 to 4 integer, and " b " is 2 to 40 integer, and " c " is 0 to 40 integer.
For compound (C), most preferably in formula 22, " m " is 1 to 50 integer, and " n " is 1 to 50 integer, R
21Be the base of formula (22-2) expression, " a " is 2 to 4 integer, and " b " is 2 to 30 integer, and " c " is 0 to 30 integer.
The examples for compounds of formula (22) expression comprises Dow Corning Toray Silicone Co., the SH3746 of Ltd.
TM, SH3771C
TM, SH3772C
TM, SH3773C
TM, SH3775C
TM, SH3748
TM, SH3749
TM, SH3771M
TM, SH3772M
TM, SH3773M
TMAnd SH3775M
TM, and Shin-EtsuChemical Co., the KF351A of Ltd.
TM, KF353A
TM, KF945A
TM, KF352A
TM, KF61 5A
TM, KF6011
TM, KF6012
TM, KF6013
TM, KF6015
TM, KF6016
TMAnd KF6017
TM
The example of " phenyl modified siloxanes " is provided by the compound of following formula (23) expression.
Chemical formula 7 
In formula (23), R
25And R
26Be C
1-C
12Alkyl is (as the saturated C of straight or branched
1-C
12Alkyl) ,-OSi (CH
3)
3Or phenyl, R
25And R
26Can be identical or different.Yet, R
25And R
26In at least one be phenyl.
" m " is the integer more than 0 or 0, and " n " is the integer more than 1 or 1.
In formula (23), preferably " m " is 0 to 300 integer, more preferably 0 to 100 integer, most preferably 0 to 50 integer." n " be 1 to 500 integer preferably, more preferably 1 to 100 integer, most preferably 1 to 50 integer.
For phenyl modified siloxanes, especially preferred is suc as formula R in (23)
25=CH
3Or-OSi (CH
3)
3, R
26=C
6H
5, m=0, the methyl phenyl silicone of n=1～100.
The example of phenyl modified siloxanes comprises Dow Corning Toray Silicone Co., the SH556 of Ltd.
TM, SF557
TM, SF558
TMAnd SH559
TM, Shin-Etsu Chemical Co., the KF50-100cs of Ltd.
TM, KF50-1000cs
TM, KF53
TM, KF54
TMAnd KF56
TM
The example of " alkyl-modified siloxanes " is provided by the compound of following formula (24) expression.
Chemical formula 8 
In formula (24), R
27To R
29Be C
1-C
50Alkyl, they can be identical or different.Yet, R
27To R
29In at least one be C
5-C
30Alkyl.
" m " is the integer more than 1 or 1, and " n " is the integer more than 1 or 1.
In formula (24), R
27To R
29Be C
1-C
50Alkyl is as the saturated hydrocarbyl of straight or branched.C preferably
5-C
30Alkyl, more preferably C
5-C
20Alkyl most preferably is C
10-C
20Alkyl.
And preferably " m " is 1 to 300 integer, more preferably 1 to 100 integer, most preferably 1 to 50 integer." n " be 1 to 300 integer preferably, more preferably 1 to 100 integer, most preferably 1 to 50 integer.
The example of alkyl-modified siloxanes comprises Dow Corning Toray Silicone Co., the SF8416 of Ltd.
TMAnd Shin-Etsu Chemical Co., the KF-412 of Ltd.
TM, KF-413
TMAnd KF414
TM
The example of " alkoxy-modified siloxanes " is provided by the compound of following formula (25) expression.
Chemical formula 9
In formula (25), R
30To R
32Be C
1-C
12Alkyl, or C
1-C
50Alkoxyl group, and R
30To R
32Can be identical or different.Yet, R
30To R
32In at least one be C
1-C
50Alkoxyl group.
" m " is the integer more than 0 or 0, and " n " is the integer more than 1 or 1.
In formula (25), R
30To R
32Be C
1-C
12Alkyl, or C
1-C
50Alkoxyl group, C
1-C
12The example of alkyl comprises the saturated hydrocarbyl of straight chain and side chain, and C
1-C
50The example of alkoxyl group comprises straight chain and branched alkoxy.The carbonatoms of the alkoxyl group of 1～50 carbonatoms preferably 1～30 is more preferably 1～25, most preferably is 1～20.
Preferably " m " is 1 to 500 integer, more preferably 1 to 100 integer, most preferably 1 to 50 integer." n " be 1 to 100 integer preferably, more preferably 1 to 80 integer, most preferably 1 to 50 integer.
The example of " alkoxy-modified siloxanes " comprises Shin-Etsu Chemical Co., the KF-851 of Ltd.
TMAnd X-22-801B
TM
The example of " cyclosiloxane " is provided by the compound of following formula (26) expression.
Chemical formula 10
In formula (26), R
33Expression C
2-C
12Alkyl, wherein repeating unit can be identical or different.
" m " is the integer more than 1 or 1, and " n " is the integer more than 0 or 0, " m " and " n " and (m+n) be 3～10.
In formula (26), R
33Be C
2-C
12Alkyl is as the saturated hydrocarbyl of straight or branched.R preferably
33Have 2～10, more preferably 2～8,2～5 carbon atoms most preferably.
Preferably " m " is 3～8 integer, more preferably 4～8 integer, most preferably 4～6 integer." n " be 0～7 integer preferably, more preferably 0～5 integer, most preferably 0～3 integer." m " and " n " and (m+n) preferably 3～8, more preferably 4～8, most preferably 4～6.
The example of cyclosiloxane comprises Dow Corning Toray Silicone Co., the SH244 of Ltd.
TM, SH344
TM, SH245
TM, DC345
TMAnd DC246
TM, and Shin-Etsu Chemical Co., the KF-994 of Ltd.
TM, KF995
TMAnd KF9937
TM
Repeating unit shown in the formula (22) to (26) in the compound can be any polymer type, as unregulated polymer or block polymer.
The viscosity (dynamic viscosity) of compound (C) under 25 ℃ is 1～5000mm preferably
2/ s, more preferably 1～2000mm
2/ s, most preferably 1～1000mm
2/ s.
For compound (C), preferably polydimethylsiloxane and polyether-modified siloxanes.
Compound (C) can be used singly or in combination.
" have carboxyl and be selected from the compound (D) of at least one group of hydroxyl, primary amino and secondary amino group " and refer to contain in the molecule at least one group that is selected from hydroxyl, primary amino and secondary amino group and the compound of at least one carboxyl, have no particular limits, need only the amphoteric urethane resin that can obtain requiring with this compound.
The example of compound (D) comprises dimethylol propionic acid, dimethylolpropionic acid and contains the polycaprolactone glycol of carboxyl.
Compound (D) can be used singly or in combination.
" have uncle amino and be selected from the compound (E) of at least one group of hydroxyl, primary amino and secondary amino group " refers to contain in the molecule at least one group that is selected from hydroxyl, primary amino and secondary amino group and the compound of at least one uncle's amino, have no particular limits, need only the amphoteric urethane resin that can obtain requiring with this compound.
The example of compound (E) comprises N-alkyl two chain triacontanol amine compounds, as N methyldiethanol amine, N-ethyldiethanolamine, N butyl diethanol amine, N-lauryl diethanolamine, N-methyl dipropanolamine, and N, N-dialkyl group chain triacontanol amine compound, as N, N-dimethylethanolamine, N, N-diethylethanolamine, N, N-dibutyl thanomin, and trolamine.
Compound (E) can be used singly or in combination.
Compound (C) and compound (A), (B), (D) and weight ratio (E), i.e. (C)/((A)+(B)+(D)+(E)) is preferably 0.1/100～30/100, and more preferably 0.5/100～25/100, most preferably 1/100～20/100.
And, compound (B) and compound (A), (D) and mol ratio (E), i.e. (B)/((A)+(D)+(E)) is preferably 2.0/0.8～2.0/1.8, more preferably 2.0/1.0～2.0/1.8, most preferably 2.0/1.2～2.0/1.8.
The preparation method of amphoteric urethane resin of the present invention comprises:
The first step is for preparation comprises the prepolymer of isocyanate groups, be included in make under the excessive condition of isocyanate groups above-claimed cpd (A), (B) and (D) react and
Second step was the reaction that comprises the prepolymer and the compound (E) of isocyanate groups,
Wherein there is compound (C) in the first step with at least one step in second step.
In the preparation method of the another kind of amphoteric urethane resin of the present invention, the compound (E) and the reaction sequence of compound (D) are put upside down.
The reaction in the first step and second step can be carried out under the reaction conditions that preparation urethane is used always in the presence of suitable polymerisation catalysts.
" polymerisation catalysts " can adopt preparation urethane resin any polymerisation catalysts commonly used.Polymerisation catalysts is had no particular limits, as long as the amphoteric urethane resin that can obtain requiring.Can adopt for example tertiary amine catalyst or organo-metallic catalyst conduct " polymerisation catalysts ".The example of " tertiary amine " comprises [2,2,2]-diazabicyclooctane (DABCO), tetramethylene-diamine, N-methylmorpholine and diazabicylo undecylene (DBU).The example of " organo-metallic catalyst " comprises dibutyltin dilaurate.
In ownership system Preparation Method of the present invention, can be as required in the first step and the reaction of second step with an organic solvent.The organic solvent of the especially preferred urethane resin that is to use energy dissolved compound (A) to (E) and will prepares.The example of this organic solvent comprises acid amides, as N-crassitude, dimethyl fumaramide and N,N-DIMETHYLACETAMIDE; Ketone such as acetone and methylethylketone; Ester such as ethyl acetate and cellosolve acetate or ether cellosolve.
In addition, in preparation method of the present invention, preferably after second step, the reaction product in second step is mixed with water, carry out transfer reaction.
In preparation method of the present invention, preferably pass through the reaction product in second step is mixed with buck, or in the reaction product in second step, add basic cpd in the second step back, mix with water then and carry out transfer reaction.More preferably, the reaction product in second step carries out transfer reaction by being mixed with buck.
Herein, " buck " refers to wherein dissolve alkaline matter, makes it have the water of alkalescence.The example of buck comprises the water that has for example wherein dissolved triethylamine, trolamine, ammonia, sodium hydroxide, potassium hydroxide or 2-amino-2-methyl 1-propyl alcohol.
Preferably in preparation method of the present invention, carry out transfer reaction.In transfer reaction, can use chain propagation agent, can regulate the performance of the final amphoteric urethane resin that obtains by this transfer reaction.
" chain propagation agent " is the compound that is used for transfer reaction.The example of chain propagation agent comprises LMW polyvalent alcohol, amine and water.The LMW examples of polyhydric alcohols comprises dibasic alcohol, as ethylene glycol, propylene glycol, 1, and 4-butyleneglycol, Diethylene Glycol, 1,6-hexylene glycol, the spiroglycol, two (beta-hydroxy oxyethyl group) benzene and xylylene-glycol, and triol such as TriMethylolPropane(TMP) and glycerine.The example of " amine " comprises methylene radical (two Ortho-Chloro aniline).
In the preparation method of amphoteric urethane resin of the present invention, preferably after second step, the reaction product in second step is mixed with buck, in water, to carry out transfer reaction.
In addition, in the preparation method of amphoteric urethane resin of the present invention, preferably in organic solvent, carried out the first step and the second step reaction after, the reaction mixture after second step is mixed with buck, then in water, carry out transfer reaction.
Reaction mixture after second step is mixed with buck, and the setting of then carrying out transfer reaction in water is preferred, because this method can obtain the high-molecular weight amphoteric urethane resin easily.In the preparation method of this set, preferably set preparation condition like this, make that the reaction mixture after second step is the prepolymer that has isocyanate groups at its end of the chain.
In preparation method of the present invention, a kind of preparation method has been proposed, this method has been except that having adopted compound (A) to (E), also adopted " compound (F) that has the structural unit of at least one group that is selected from hydroxyl, primary amino and secondary amino group and following formula (11) expression "
Chemical formula 11
-(C
2H
4O)
p(C
3H
6O)
q-????(11)
Wherein " p " is 1 to 500 integer, and " q " is 0 to 400 integer, if the structural unit of formula (11) is C
2H
4O and C
3H
6The multipolymer of O (being q ≠ 0), then they can be random copolymers or segmented copolymer (hereinafter referred to as " compound (F) ").
Compound (F) is " compound that has the structural unit of at least one group that is selected from hydroxyl, primary amino and secondary amino group and formula (11) expression ", and compound (F) has no particular limits, as long as the amphoteric urethane resin that can obtain requiring.
If the q=0 in the formula (11), the structural unit of formula (11) expression just forms C
2H
4Polymkeric substance (polyoxyethylene) is if q ≠ 0 just forms C
3H
6O and C
2H
4The multipolymer of O.At C
3H
6O and C
2H
4Under the situation of the multipolymer of O, the structural unit of formula (11) expression can be random copolymers or segmented copolymer, and is not subjected to C
2H
4O and C
3H
6The restriction that O arranges.
In formula (11), no matter q ≠ 0 or q=0, " p " preferably 3～250, and more preferably 3～120, most preferably 3～50.
If " p " less than 3, compound (F) does not just contain enough C
2H
4O just is difficult to obtain to have enough hydrophilic amphoteric urethane resin.Therefore, if with amphoteric urethane resin as the hair style fixing agent, the wetting ability of this hair style fixing agent and hair washing performance are just not enough.If " p " greater than 500, compound (F) just contains too many C
2H
4O makes that the wetting ability of amphoteric urethane resin is too strong.Therefore, the wetting ability of hair style fixing agent is just too strong, if with this amphoteric urethane resin as the hair style fixing agent, the moisture resistance of hair is reduction just.
If q ≠ 0 in the formula (11), " q " preferably 3～200 then, more preferably 3～100, most preferably 3～40.
In formula (11), no matter q ≠ 0 or q=0, p+q preferably 3～300, and more preferably 10～120, most preferably 3～50.
In formula (11), though q ≠ 0 or q=0, C
2H
4O and C
3H
6The weight ratio of O (is C
2H
4O/C
3H
6O) preferably 10/0～2/8, more preferably 10/0～3/7, most preferably 10/0～4/6.
For the structural unit of formula (11), preferably q=0.
Preferably compound (F) is introduced type, the two ends introducing NH of OH base for two ends
2The type of base, an end are introduced the type of OH base, or an end is introduced NH
2The type of base.If NH is introduced at the type or the two ends of adopting two ends to introduce the OH base
2The compound (F) of type of base just obtains having the amphoteric urethane resin of the structural unit of formula (11) expression in main chain.If the type or the end that adopt an end to introduce the OH base are introduced NH
2The compound (F) of type of base just obtains having in side chain or on the end of the chain amphoteric urethane resin of the structural unit of formula (11) expression.
The weight-average molecular weight of compound (F) preferably 200～20000, preferred 200～5000, most preferred 500～2000.
The example of compound (F) comprises polyoxyethylene glycol (PEG) and polyethylene-polypropylene glycol (polyethylene-polypropylene segmented copolymer), but polyoxyethylene glycol (or polyoxyethylene polyols) preferably.
Compound (F) can be used singly or in combination.
Therefore, the invention provides the preparation method of amphoteric urethane resin, comprise
By under the excessive condition of isocyanate groups, making compound (A), (B), (D) and (F) reaction, preparation comprise isocyanate groups prepolymer the first step and
Comprise the prepolymer of isocyanate groups and second step of compound (E) reaction,
Wherein there is compound (C) in the first step with at least one step in second step.
The present invention also provides the preparation method of amphoteric urethane resin, comprises
By under the excessive condition of isocyanate groups, making compound (A), (B), (E) and (F) reaction, preparation comprise isocyanate groups prepolymer the first step and
Comprise the prepolymer of isocyanate groups and second step of compound (D) reaction,
Wherein there is compound (C) in the first step with at least one step in second step.
Having added the first step of compound (F) and the second step reaction can be by carrying out with the above-mentioned first and second step similar methods, can carry out in the presence of the suitable polymerisation catalysts and under the reaction conditions used always of preparation urethane.
" polymerisation catalysts ", " organic solvent ", " chain propagation agent " etc. can be same as described above, and when adding compound (F), preferably the first step and second step carry out in organic solvent, and carry out transfer reaction in water.
Compound (C) and compound (A), (B) and (D) arrive the weight ratio of (F), i.e. (C)/((A)+(B)+(D)+(E)+(F)) preferably 0.1/100～30/100, preferred 0.5/100～25/100, most preferred 1/100～20/100.
Compound (B) and compound (A), (D), (E) and mol ratio (F), i.e. (B)/((A)+(D)+(E)+(F)) be 2.0/0.8～2.0/1.8 preferably, preferred 2.0/1.0～2.0/1.8, most preferred 2.0/1.2～2.0/1.8.
The invention provides the amphoteric urethane resin that obtains by above-mentioned preparation method.
All have carboxyl and uncle's amino in each molecule of the amphoteric urethane resin that obtains with preparation method of the present invention.The ratio of carboxyl and uncle's amino (ratio of the quantity of two kinds of functional groups), promptly carboxyl/uncle's amino preferably 1/50～50/1, preferred 1/1～50/1, most preferred 1/1～25/1.If the ratio of carboxyl and uncle's amino is 1/50～50/1 in the amphoteric urethane resin, when use contains the hair style fixing agent of the resin combination that comprises amphoteric urethane resin, can make hair have more comfortable quality, or when making coating or liniment with the resin combination that comprises amphoteric urethane resin, better with the tack of base material.
In preparation method of the present invention, compound (D) and (E) ratio (mol ratio), promptly compound (D)/compound (E) preferably 1/50～50/1, preferred 1/1～50/1, most preferred 1/1～25/1.
Amphoteric urethane resin of the present invention preferably uses with aqueous solution form, and amphoteric urethane resin preferably of the present invention formation aqueous solution when mixing with water.In this manual, " aqueous solution " refers to that not only amphoteric urethane resin is dissolved in the aqueous solution in the water fully, refers to that also amphoteric urethane resin disperses and/or is suspended in aqueous dispersion and/or waterborne suspension in the water.The invention provides the aqueous solution of amphoteric urethane resin of the present invention.
Yet, also can adopt the resinous principle of the amphoteric urethane resin that almost omits solvent and obtain.
In this manual, " water " refers to the water of any kind, comprises distilled water, ion exchanged water and pure water.And in the scope that preparation and quality to required amphoteric urethane resin do not have a negative impact, " water " can also comprise the organic solvent that can dissolve or be dispersed in the water, monomer etc.
The present invention proposes the resin combination that comprises above-mentioned amphoteric urethane resin.Herein, " resin combination " refers to comprise the composition of urethane resin various additives commonly used.The example of this " additive " comprises pigment, dyestuff, tinting material, spices, tensio-active agent, moisture adsorbent, sanitas, sterilizing agent, antiseptic-germicide, antioxidant, thickening material and pH value conditioning agent.Preferably " resin combination " also uses with aqueous solution form.Undoubtedly, also can carry out additional processing, as add other additives, and carry out other suitable modifications according to its purposes to " resin combination ".
" amphoteric urethane resin " of the present invention and " resin combination that comprises amphoteric urethane resin " can be used for urethane resin any field commonly used, as makeup, coating and liniment.Preferably as makeup.The example of " makeup " comprises hair style fixing agent, liniment and viscosity modifier.The example of " hair style fixing agent " comprises the hair style fixing agent of foam, gel, aerosol and pump spray pattern.The example of " liniment " and " viscosity modifier " comprise nurse one's health/shave/emulsifying agent, skin liquid, emulsifying powder at the bottom of, foundation cream, informer, mascara, nail varnish and facial mask.
Adopt amphoteric urethane resin of the present invention, can reach the performance of the coating, liniment and the makeup that improve to adopt amphoteric urethane resin of the present invention with common amphoteric urethane resin comparison and improve at least a effect in the stability in storage of amphoteric urethane resin, especially excellent for makeup.This is seemingly owing to following reason.
As if amphoteric urethane resin of the present invention needn't have the polysiloxane chain of polysiloxane compound (C) by the covalent linkage in its skeleton, and this amphoteric urethane resin has polysiloxane chain by the physical entanglement of the polysiloxane chain of its skeleton and polysiloxane compound (C).As if this mutual entanglement be difficult to polysiloxane compound and gained amphoteric urethane resin are separated because the carrying out of the polyreaction of amphotenic polkyurethanes is further complicated.
In this manual, the entanglement of the skeleton of amphoteric urethane resin and polysiloxane compound is called as the state of amphoteric urethane resin skeleton " constraint " polysiloxane compound.Herein, " constraint " is aqueous solution or aqueous dispersion form and difference according to amphoteric urethane resin.The amphoteric urethane resin skeleton has linear chain structure usually, but also can have the structure of branching or crosslinked structure.If amphoteric urethane resin is " aqueous solution " form, as if be exactly that polysiloxane chain enters in the amphoteric urethane resin skeleton.
On the other hand, if amphoteric urethane resin is " aqueous dispersion " form, as if be exactly that amphoteric urethane resin has the particulate form that is dispersed in the water, this particle can have several forms with respect to " constraint " of polysiloxane chain.In first kind of form, all or part polysiloxane chain constriction is in particle.In second kind of form, polysiloxane link ends constriction is in particle.In the third form, polysiloxane chain is connected to particle surface.First all is equivalent to " constraint " to the third form, and the first any mixture to the third form also is equivalent to constraint.
As if the skeleton of amphoteric urethane resin of the present invention retrained polysiloxane compound (C).Therefore, though polysiloxane chain has flowability relatively, as if polysiloxane compound is difficult separates with amphoteric urethane resin.Therefore, compare with common amphoteric urethane resin, the performance that can reach the coating, liniment and the makeup that improve employing amphoteric urethane resin of the present invention is (for example with regard to the hair style fixing agent, be meant feel such as hair style fixed performance, hair quality, hair washing performance and hair, and the performance of the spreadability when smearing the hair style fixing agent and so on) and at least a effect that improves the stability in storage of amphoteric urethane resin, especially excellent for makeup.
The quality that is pointed out that amphoteric urethane resin excellence of the present invention looks like owing to these reasons, but amphoteric urethane resin of the present invention never is subjected to the restriction of these reasons.
Embodiment
By the following examples with the present invention of comparative example more detailed description.Yet these embodiment only are the parts of the possible embodiment of the present invention, the invention is not restricted to these embodiment.(1) preparation of the amphoteric urethane resin aqueous solution of embodiment and comparative example
The preparation of the amphoteric urethane resin aqueous solution of embodiment 1
With 70g isophorone diisocyanate (IPDI), 63g polypropylene glycol (PPG; Weight-average molecular weight 1000), (viscosity under 25 ℃ is 10mm for 7g 1,4 cyclohexane dimethanol (CHDM), 8g polydimethylsiloxane
2/ s; Dow Corning Toray Silicone Co., the SH200C-10cs of Ltd.
TM) and 20g dimethylolpropionic acid (DMBA) inject the four neck flasks that agitator, thermometer, nitrogen inlet tube and reflux exchanger are housed.Add the 50g ethyl acetate as solvent, and be heated to 80 ℃, with mixture reaction 3 hours with oil bath.Then, add 2g N methyldiethanol amine (NMDEtA) and 60g ethyl acetate, under 80 ℃, reacted again 3 hours, obtain having the prepolymer of remaining isocyanate group.After the prepolymer that will have a remaining isocyanate group is cooled to 50 ℃, it is distributed in the 700g water that contains 10g potassium hydroxide, under 50 ℃, carries out 3 hours transfer reactions, thereby obtain high molecular by high-speed stirring.Ethyl acetate reclaims from obtained aqueous solution, obtains being substantially free of the amphoteric urethane resin aqueous solution of the embodiment 1 of solvent.
The preparation of the amphoteric urethane resin aqueous solution of embodiment 2
Obtain the amphoteric urethane resin aqueous solution of embodiment 2 with the mode identical with embodiment 1 preparation method, different is that (viscosity under 25 ℃ is 1600mm with the polyether-modified siloxanes of 8g
2/ s; Dow CorningToray Silicone Co., the SH3775C of Ltd.
TM) replacement 8g polydimethylsiloxane.
The preparation of the amphoteric urethane resin aqueous solution of embodiment 3
Obtain the amphoteric urethane resin aqueous solution of embodiment 3 with the mode identical with embodiment 1 preparation method, different is that (viscosity under 25 ℃ is 4mm with the 8g cyclosiloxane
2/ s; Dow Corning ToraySilicone Co., the SH245 of Ltd.
TM) replacement 8g polydimethylsiloxane.
The preparation of the amphoteric urethane resin aqueous solution of embodiment 4
Obtain the amphoteric urethane resin aqueous solution of embodiment 4 with the mode identical with embodiment 1 preparation method, different is that (viscosity under 25 ℃ is 22mm with the phenyl modified siloxanes of 8g
2/ s; Dow CorningToray Silicone Co., the SH556 of Ltd.
TM) replacement 8g polydimethylsiloxane.
The preparation of the amphoteric urethane resin aqueous solution of embodiment 5
Obtain the amphoteric urethane resin aqueous solution of embodiment 5 with the mode identical with embodiment 1 preparation method, different is that (viscosity under 25 ℃ is 500mm with the alkyl-modified siloxanes of 8g
2/ s; Shin-EtsuChemical Co., the KF-412 of Ltd.
TM) replacement 8g polydimethylsiloxane.
The preparation of the amphoteric urethane resin aqueous solution of embodiment 6
Obtain the amphoteric urethane resin aqueous solution of embodiment 6 with the mode identical with embodiment 1 preparation method, different is that (viscosity under 25 ℃ is 80mm with the alkoxy-modified siloxanes of 8g
2/ s; Shin-EtsuChemical Co., the KF-851 of Ltd.
TM) replacement 8g polydimethylsiloxane.
The preparation of the amphoteric urethane resin aqueous solution of embodiment 7
Obtain the amphoteric urethane resin aqueous solution of embodiment 7 with the mode identical with embodiment 1 preparation method, different is that (viscosity under 25 ℃ is 10mm with the 20g polydimethylsiloxane
2/ s; Dow CorningToray Silicone Co., the SH200C-10cs of Ltd.
TM) replacement 8g polydimethylsiloxane.
The preparation of the amphoteric urethane resin aqueous solution of embodiment 8
Obtain the amphoteric urethane resin aqueous solution of embodiment 8 with the mode identical with embodiment 1 preparation method, different is that (viscosity under 25 ℃ is 1600mm with the polyether-modified siloxanes of 20g
2/ s; DowCorning Toray Silicone Co., the SH3775C of Ltd.
TM) replacement 8g polydimethylsiloxane.
The preparation of the amphoteric urethane resin aqueous solution of embodiment 9
With 70g isophorone diisocyanate (IPDI), 55g polypropylene glycol (PPG; Weight-average molecular weight 1000), 8g polyoxyethylene glycol (PEG; Weight-average molecular weight 1000), (viscosity under 25 ℃ is 10mm for 7g 1,4 cyclohexane dimethanol (CHDM), 8g polydimethylsiloxane
2/ s; Dow Corning Toray SiliconeCo., the SH200C-10cs of Ltd.
TM) and 20g dimethylolpropionic acid (DMBA) inject the four neck flasks that agitator, thermometer, nitrogen inlet tube and reflux exchanger are housed.Add the 50g ethyl acetate as solvent, and be heated to 80 ℃, with mixture reaction 3 hours with oil bath.Then, add 2g N methyldiethanol amine (NMDEtA) and 60g ethyl acetate, under 80 ℃, reacted again 3 hours, obtain having the prepolymer of remaining isocyanate group.After the prepolymer that will have a remaining isocyanate group is cooled to 50 ℃, it is distributed in the 700g water that contains 10g potassium hydroxide, under 50 ℃, carries out 3 hours transfer reactions, thereby obtain high molecular by high-speed stirring.Ethyl acetate reclaims from obtained aqueous solution, obtains being substantially free of the amphoteric urethane resin aqueous solution of the embodiment 9 of solvent.
The preparation of the amphoteric urethane resin aqueous solution of embodiment 10
Obtain the amphoteric urethane resin aqueous solution of embodiment 10 with the mode identical with embodiment 9 preparation methods, different is that (viscosity under 25 ℃ is 1600mm with the polyether-modified siloxanes of 8g
2/ s; Dow CorningToray Silicone Co., the SH3775C of Ltd.
TM) replacement 8g polydimethylsiloxane.
The preparation of the amphoteric urethane resin aqueous solution of embodiment 11
Obtain the amphoteric urethane resin aqueous solution of embodiment 11 with the mode identical with embodiment 9 preparation methods, different is that (viscosity under 25 ℃ is 10mm with the 20g polydimethylsiloxane
2/ s; Dow CorningToray Silicone Co., the SH200C-10cs of Ltd.
TM) replacement 8g polydimethylsiloxane.
The preparation of the amphoteric urethane resin aqueous solution of embodiment 12
Obtain the amphoteric urethane resin aqueous solution of embodiment 12 with the mode identical with embodiment 9 preparation methods, different is that (viscosity under 25 ℃ is 1600mm with the polyether-modified siloxanes of 20g
2/ s; DowCorning Toray Silicone Co., the SH3775C of Ltd.
TM) replacement 8g polydimethylsiloxane.
The preparation of the amphoteric urethane resin aqueous solution of comparative example 1
Obtain the amphoteric urethane resin aqueous solution of comparative example 1 with the mode identical with embodiment 1 preparation method, different is not use polydimethylsiloxane.
The preparation of the amphoteric urethane resin aqueous solution of comparative example 2
With 70g isophorone diisocyanate (IPDI), 63g polypropylene glycol (PPG; Weight-average molecular weight 1000), 7g 1,4-cyclohexanedimethanol (CHDM) and 20g dimethylolpropionic acid (DMBA) inject the four neck flasks that agitator, thermometer, nitrogen inlet tube and reflux exchanger are housed, add the 50g ethyl acetate as solvent, and be heated to 80 ℃ with oil bath, with mixture reaction 3 hours.Then, add 2gN-methyldiethanolamine (NMDEtA) and 60g ethyl acetate, under 80 ℃, reacted again 3 hours, obtain having the prepolymer of remaining isocyanate group.After the prepolymer that will have a remaining isocyanate group is cooled to 50 ℃, it is distributed in the 700g water that contains 10g potassium hydroxide, under 50 ℃, carries out 3 hours transfer reactions, thereby obtain high molecular by high-speed stirring.Ethyl acetate reclaims from obtained aqueous solution, obtains being substantially free of the amphoteric urethane resin aqueous solution of solvent, and (viscosity under 25 ℃ is 10mm to add the 8g polydimethylsiloxane
2/ s; Dow Corning Toray Silicone Co., the SH200C-10cs of Ltd.
TM), obtain the amphoteric urethane resin aqueous solution of comparative example 2.
The preparation of the amphoteric urethane resin aqueous solution of comparative example 3
Obtain the amphoteric urethane resin aqueous solution of comparative example 3 with the mode identical with comparative example 2 preparation methods, different is that (viscosity under 25 ℃ is 1600mm with the polyether-modified siloxanes of 8g
2/ s; Dow CorningToray Silicone Co., the SH3775C of Ltd.
TM) replacement 8g polydimethylsiloxane.
The preparation of the amphoteric urethane resin aqueous solution of comparative example 4
Obtain the amphoteric urethane resin aqueous solution of comparative example 4 with the mode identical with comparative example 2 preparation methods, different is that (viscosity under 25 ℃ is 4mm with the 8g cyclosiloxane
2/ s; Dow Corning ToraySilicone Co., the SH245 of Ltd.
TM) replacement 8g polydimethylsiloxane.
The preparation of the amphoteric urethane resin aqueous solution of comparative example 5
Obtain the amphoteric urethane resin aqueous solution of comparative example 5 with the mode identical with comparative example 2 preparation methods, different is that (viscosity under 25 ℃ is 22mm with the phenyl modified siloxanes of 8g
2/ s; Dow CorningToray Silicone Co., the SH556 of Ltd.
TM) replacement 8g polydimethylsiloxane.
The preparation of the amphoteric urethane resin aqueous solution of comparative example 6
Obtain the amphoteric urethane resin aqueous solution of comparative example 6 with the mode identical with comparative example 2 preparation methods, different is that (viscosity under 25 ℃ is 500mm with the alkyl-modified siloxanes of 8g
2/ s; Shin-EtsuChemical Co., the KF-412 of Ltd.
TM) replacement 8g polydimethylsiloxane.
The preparation of the amphoteric urethane resin aqueous solution of comparative example 7
Obtain the amphoteric urethane resin aqueous solution of comparative example 7 with the mode identical with comparative example 2 preparation methods, different is that (viscosity under 25 ℃ is 80mm with the alkoxy-modified siloxanes of 8g
2/ s; Shin-EtsuChemical Co., the KF-851 of Ltd.
TM) replacement 8g polydimethylsiloxane.
The preparation of the amphoteric urethane resin aqueous solution of comparative example 8
Obtain the amphoteric urethane resin aqueous solution of comparative example 8 with the mode identical with embodiment 1 preparation method, different is (to introduce the type of OH base at two ends with the 8g polydimethylsiloxanediols diols; Viscosity under 25 ℃ is 62mm
2/ s; Shin-Etsu Chemical Co., the KF-6002 of Ltd.
TM) replace the 8g polydimethylsiloxane, with 55g polypropylene glycol (PPG; Weight-average molecular weight 1000) replaces 63g polypropylene glycol (PPG; Weight-average molecular weight 1000).
The preparation of the amphoteric urethane resin aqueous solution of comparative example 9
Obtain the amphoteric urethane resin aqueous solution of comparative example 9 with the mode identical with embodiment 1 preparation method, different is (at one end to introduce the type of OH base with the 8g polydimethylsiloxanediols diols; Viscosity under 25 ℃ is 88mm
2/ s; Shin-Etsu Chemical Co., the X-22-176B of Ltd.
TM) replace the 8g polydimethylsiloxane, with 55g polypropylene glycol (PPG; Weight-average molecular weight 1000) replaces 63g polypropylene glycol (PPG; Weight-average molecular weight 1000).(2) evaluation of the amphoteric urethane resin aqueous solution of embodiment and comparative example
Estimate as hair style fixing agent foamy
In order to estimate the embodiment that obtains as mentioned above and the amphoteric urethane resin of comparative example, prepare the hair style fixing agent foam of embodiment and comparative example with every kind of amphoteric urethane resin aqueous solution.
In other words, the composition in the table 1 by mixed shown in the table, is stirred to evenly, obtains the X composition of embodiment and comparative example.Then the Y composition in the table 1 is joined in the X composition with ratio shown in the table, prepare the hair style fixing agent foam of each embodiment and comparative example.These foams are called the hair style fixing agent foam of embodiment 1 to 12 and the hair style fixing agent foam of comparative example 1 to 9.
Table 1
A) dry weight.Solution is heated to 105 ℃ of residue weight after reaching 3 hours.
| The hair style fixing agent foam of embodiment and comparative example | Weight % | |
| The X composition | The amphoteric urethane resin aqueous solution of embodiment and comparative example | ????2.5a) |
| Deionized water | ????78.5 | |
| Polyoxyethylene lauryl ether | ????0.5 | |
| The sour diglycollic amide of theobroma oil fat | ????0.5 | |
| Ethanol | ????10.0 | |
| The Y composition | Propellent | ????8.0 |
Use the embodiment of acquisition by this way and the hair style fixing agent foam of comparative example, estimate the feel (below be also referred to as " feel ") of hair style fixed performance (below be also referred to as " fixed performance "), hair quality (below be also referred to as " quality "), hair washing performance (below be also referred to as " hair washing performance "), hair, and the spreadability of hair style fixing agent (below be also referred to as " spreadability ").And, the stability in storage of the amphoteric urethane resin aqueous solution of evaluation embodiment and comparative example.The results are shown in table 2 and the table 3.Fixed performance
Every kind of hair style fixing agent of 0.8g foam is spread upon (length: 25cm on a branch of black natural hair; Weight: 5.0g), at room temperature dry preparation is used to estimate the bundle of hair of solid volatility.With 10 testers that estimate its fixed performance these bundle of hair are carried out sensory test.Interpretational criteria about fixed performance is as follows:
The fixed performance of " A " expression bundle of hair is evaluated as fine by at least 9 testers;
The fixed performance of " B " expression bundle of hair is evaluated as fine by 6 to 8 testers;
The fixed performance of " C " expression bundle of hair is evaluated as fine by 2 to 5 testers;
The fixed performance of " D " expression bundle of hair is by 1 or not have the tester to be evaluated as fine.Quality
Every kind of hair style fixing agent of 0.8g foam is spread upon (length: 25cm on a branch of black natural hair; Weight: 5.0g), at room temperature dry preparation is used to estimate the bundle of hair of quality.With 10 testers that estimate its quality these bundle of hair are carried out sensory test.Interpretational criteria about quality is as follows:
It is very soft that at least 9 testers of " A " expression estimate being felt as of bundle of hair;
It is very soft that 6 to 8 testers of " B " expression estimate being felt as of bundle of hair;
It is very soft that 2 to 5 testers of " C " expression estimate being felt as of bundle of hair;
1 of " D " expression or not have the tester to estimate being felt as of bundle of hair very soft.The hair washing performance
Every kind of hair style fixing agent of 0.8g foam is spread upon (length: 15cm on a branch of black natural hair; Weight: 3.0g), at room temperature dry preparation bundle of hair to be washed.In 40 ℃ of warm water, clean this bundle of hair after 30 seconds, smear the shampoo solution of 0.4g 10%, and cleaned this bundle of hair 30 seconds.After this wash this bundle of hair again with 40 ℃ of warm water, flush away shampoo solution, and, obtain being used to estimate the bundle of hair of hair washing performance like this 50 ℃ of following thorough dryings.With 10 testers that estimate its hair washing performance to the have one's hair wash sensory test of performance of these bundle of hair.Interpretational criteria about the hair washing performance is as follows:
The hair washing performance of " A " expression bundle of hair is evaluated as fine by at least 9 testers;
The hair washing performance of " B " expression bundle of hair is evaluated as fine by 6 to 8 testers;
The hair washing performance of " C " expression bundle of hair is evaluated as fine by 2 to 5 testers;
The hair washing performance of " D " expression bundle of hair is by 1 or not have the tester to be evaluated as fine.Feel
Every kind of hair style fixing agent of 0.8g foam is spread upon (length: 25cm on a branch of black natural hair; Weight: 5.0g), at room temperature dry preparation is used to estimate the bundle of hair of feel.With 10 testers that estimate its feel these bundle of hair are carried out sensory test.Interpretational criteria about feel is as follows:
The feel that at least 9 testers of " A " expression estimate bundle of hair is fine;
The feel that 6 to 8 testers of " B " expression estimate bundle of hair is fine;
The feel that 2 to 5 testers of " C " expression estimate bundle of hair is fine;
1 of " D " expression or not have the tester to estimate the feel of bundle of hair fine.The spreadability of hair style fixing agent
Every kind of hair style fixing agent of 0.8g foam is spread upon (length: 25cm on a branch of black natural hair; Weight: 5.0g), carry out sensory test with 10 testers and judge spreadability, and estimate spreadability as the hair style fixing agent of hair style fixing agent makeup.Interpretational criteria about spreadability is as follows:
The spreadability that at least 9 testers of " A " expression estimate when smearing is fine;
The spreadability that 6 to 8 testers of " B " expression estimate when smearing is fine;
The spreadability that 2 to 5 testers of " C " expression estimate when smearing is fine;
1 of " D " expression or the spreadability that does not have the tester to estimate when smearing are fine.Stability in storage
Various amphoteric urethane resin solution are poured in the clear-glass bottle of 100ml, and placed for 2 week down at 50 ℃.Observe its outward appearance, estimate the stability in storage of amphoteric urethane resin solution.Interpretational criteria about stability in storage is as follows:
" A " expression silicon polymer is without any separation;
" B " expression does not almost have silicon polymer to separate;
The separation of silicon polymer is observed in " D " expression.
Table 2
| Embodiment | ||||||||||||
| 1 | ?2 | ?3 | ?4 | ?5 | ?6 | ?7 | ?8 | ?9 | ?10 | ?11 | ?12 | |
| Fixed performance | A | ?A | ?A | ?A | ?A | ?A | ?A | ?A | ?A | ?A | ?A | ?A |
| Quality | A | ?A | ?A | ?A | ?A | ?A | ?A | ?A | ?A | ?A | ?A | ?A |
| The hair washing performance | B | ?B | ?B | ?B | ?B | ?B | ?B | ?B | ?A | ?A | ?A | ?A |
| Feel | B | ?B | ?B | ?B | ?B | ?B | ?A | ?A | ?B | ?B | ?A | ?A |
| Spreadability | A | ?A | ?A | ?A | ?A | ?A | ?A | ?A | ?A | ?A | ?A | ?A |
| Stability in storage | A | ?A | ?A | ?A | ?A | ?A | ?A | ?A | ?A | ?A | ?A | ?A |
Table 3
| Comparative example | |||||||||
| 1 | ?2 | ??3 | ?4 | ??5 | ?6 | ?7 | ?8 | ?9 | |
| Fixed performance | A | ?C | ??C | ?C | ??C | ?C | ?C | ?A | ?A |
| Quality | A | ?A | ??A | ?A | ??A | ?A | ?A | ?A | ?A |
| The hair washing performance | B | ?B | ??B | ?B | ??B | ?B | ?B | ?B | ?B |
| Feel | C | ?B | ??B | ?B | ??B | ?B | ?B | ?A | ?A |
| Spreadability | C | ?A | ??A | ?A | ??A | ?A | ?A | ?C | ?C |
| Stability in storage | - | ?D | ??D | ?D | ??D | ?D | ?D | ?A | ?A |
As shown in table 2, the amphoteric urethane resin of embodiment all has satisfied performance in from the fixed performance to the stability in storage all are every.On the other hand, as shown in table 3, the amphoteric urethane resin none of comparative example all is satisfied with on all properties.The amphoteric urethane resin of comparative example 1 does not contain polysiloxane compound, so its feel and spreadability are poor.
In the amphoteric urethane resin of comparative example 2 to 7, the reaction product in second step is being mixed back adding polysiloxane compound with water, therefore as if they are 2 type amphoteric urethane resins, and polysiloxane compound not by the constraint of the skeleton of amphoteric urethane resin, causes poor storage stability.And as if because the amphoteric urethane resin of comparative example 2 to 7 contains polysiloxane compound, this compound is not fettered by the skeleton of amphoteric urethane resin, hindered the entanglement of the molecular chain of amphoteric urethane resin, therefore, make film forming ability reduce the fixed performance variation.Comparative example 8 and 9 amphoteric urethane resin are 1 type amphoteric urethane resin, and polysiloxane chain is introduced in the amphoteric urethane resin skeleton, so the spreadability of this hair style fixing agent is poor.Be used for the evaluation of hair style fixing agent gel
In order to estimate the amphoteric urethane resin solution of the foregoing description and comparative example, prepare the hair style fixing agent gel of embodiment and comparative example with every kind of amphoteric urethane resin aqueous solution.
In other words, the composition in the table 4 by mixed shown in the table, is stirred to the formation viscous gel, obtains the X composition of embodiment and comparative example.Join in X composition with ratio shown in the table Y composition in the table 4 then and be mixed to evenly, prepare the hair style fixing agent gel of each embodiment and comparative example.These gels are called the hair style fixing agent gel of embodiment 1 to 12 and the hair style fixing agent gel of comparative example 1 to 9.
Estimate the hair style fixing agent gel of embodiment 1 to 12 and the hair style fixing agent gel of comparative example 1 to 9 with above-mentioned identical evaluation method.Obtain the identical result of hair style fixing agent foam with hair style fixing agent foam and the comparative example 1 to 9 of embodiment 1 to 12.
Table 4
A) dry weight.Solution is heated to 105 ℃ of residue weight after reaching 3 hours.B) Structure 2001 of National Starch and Chemical Company
TMEvaluation as hair style fixing agent aerosol
| The hair style fixing agent gel of embodiment and comparative example | Weight % | |
| The X composition | Thickening material b) | ????1.5 a) |
| Trolamine | ????1.1 | |
| Ethanol | ????10.0 | |
| Propylene glycol | ????0.5 | |
| 1,3 butylene glycol | ????0.5 | |
| Deionized water | ????50.0 | |
| The Y composition | Embodiment or the comparative example amphoteric urethane resin aqueous solution separately | ????2.5 a) |
| Deionized water | ????33.9 | |
In order to estimate the amphoteric urethane resin aqueous solution of the foregoing description and comparative example, prepare the hair style fixing agent aerosol of embodiment and comparative example with every kind of amphoteric urethane resin aqueous solution.
In other words, the composition in the table 5 by mixed shown in the table, is stirred to evenly, obtains the X composition of embodiment and comparative example.Then the Y composition in the table 5 is joined in the X composition in ratio shown in the table, prepare the hair style fixing agent aerosol of each embodiment and comparative example.These aerosols are called the hair style fixing agent aerosol of embodiment 1 to 12 and the hair style fixing agent aerosol of comparative example 1 to 9.
Estimate the hair style fixing agent aerosol of embodiment 1 to 12 and the hair style fixing agent aerosol of comparative example 1 to 9 with above-mentioned identical evaluation method.Obtain the identical result of hair style fixing agent foam with hair style fixing agent foam and the comparative example 1 to 9 of embodiment 1 to 12.
Table 5
A) dry weight.Solution is heated to 105 ℃ of residue weight after reaching 3 hours.Evaluation as hair style fixing agent pump propellant
| The hair style fixing agent aerosol of embodiment and comparative example | Weight % | |
| The X composition | Embodiment or the comparative example amphoteric urethane resin aqueous solution separately | ????2.5 a) |
| Deionized water | ????8.0 | |
| Dioctyl sulfo-sodium succinate | ????0.5 | |
| Propylene glycol | ????0.1 | |
| 1,3 butylene glycol | ????0.3 | |
| Ethanol | ????48.6 | |
| The Y composition | Propellent | ????40.0 |
In order to estimate the amphoteric urethane resin aqueous solution of the foregoing description and comparative example, by with composition shown in the table 6 by mixed shown in this table and be stirred to evenly, prepare the hair style fixing agent pump propellant of embodiment and comparative example with every kind of amphoteric urethane resin aqueous solution.
They are called as the hair style fixing agent pump propellant of embodiment 1 to 12 and the hair style fixing agent pump propellant of comparative example 1 to 9.
Estimate the hair style fixing agent pump propellant of embodiment 1 to 12 and the hair style fixing agent pump propellant of comparative example 1 to 9 with above-mentioned identical evaluation method.Obtain with the hair style fixing agent foam of embodiment 1 to 12 and
The identical result of hair style fixing agent foam of comparative example 1 to 9.
Table 6
A) dry weight.Solution is heated to 105 ℃ of residue weight after reaching 3 hours.
| The hair style fixing agent pump propellant of embodiment and comparative example | Weight % |
| Embodiment or the comparative example amphoteric urethane resin aqueous solution separately | ????2.5 a) |
| Deionized water | ????85.5 |
| Dioctyl sulfo-sodium succinate | ????0.5 |
| Hexadecanol | ????0.5 |
| Stearyl alcohol | ????0.5 |
| Propylene glycol | ????0.5 |
| Ethanol | ????10.0 |
| Antiseptic-germicide | In right amount |
The present invention proposes a kind of preparation method of novelty of amphoteric urethane resin, and with the amphoteric urethane resin of the novelty of this preparation method preparation.This amphoteric urethane resin can be used for coating, liniment and makeup valuably, is used for makeup (as the hair style fixing agent) especially valuably.Be easy to prepare this amphoteric urethane resin with preparation method of the present invention.Compare with common amphoteric urethane resin, use amphoteric urethane resin of the present invention, at least can reach one of following effect: the performance of improving the coating, liniment and the makeup that adopt amphoteric urethane resin of the present invention is (with regard to the hair style fixing agent, spreadability when for example referring to the feel of hair style fixed performance, hair quality, hair washing performance, hair and smearing the hair style fixing agent) and improve the stability in storage of this amphoteric urethane resin.
The present invention can express with other specific forms that do not break away from its spirit or essential characteristic.It is illustrative and nonrestrictive that the application's disclosed embodiment all is considered in all fields, and scope of the present invention is to be illustrated by appended claim, rather than illustrate by the narration of front.Change and all be contemplated as falling with wherein in the institute within the implication of claim and within the claim equivalent scope.
Claims (13)
1, the preparation method of amphoteric urethane resin, this method adopts:
(A) polyol compound;
(B) polyisocyanate compound;
(C) polysiloxane compound (have at least one group of being selected from hydroxyl, primary amino and secondary amino group except) in the one or both ends of siloxane chain;
(D) have carboxyl and the compound that is selected from least one group of hydroxyl, primary amino and secondary amino group;
(E) have uncle's amino and the compound that is selected from least one group of hydroxyl, primary amino and secondary amino group;
This method comprises:
The first step prepares the prepolymer that comprises isocyanate groups for making compound (A), (B) and (D) react under the excessive condition of isocyanate groups; With
Second step is for making prepolymer and compound (E) reaction that comprises isocyanate groups;
Wherein the first step and second the step at least one step in have compound (C).
2, the preparation method of amphoteric urethane resin, this method adopts:
(A) polyol compound;
(B) polyisocyanate compound;
(C) polysiloxane compound (have at least one group of being selected from hydroxyl, primary amino and secondary amino group except) in the one or both ends of siloxane chain;
(D) have carboxyl and the compound that is selected from least one group of hydroxyl, primary amino and secondary amino group;
(E) have uncle's amino and the compound that is selected from least one group of hydroxyl, primary amino and secondary amino group;
This method comprises:
The first step prepares the prepolymer that comprises isocyanate groups for making compound (A), (B) and (E) react under the excessive condition of isocyanate groups; With
Second step is for making prepolymer and compound (D) reaction that comprises isocyanate groups;
Wherein the first step and second the step at least one step in have compound (C).
3, claim 1 or 2 preparation method, wherein compound (C) and compound (A), (B), (D) and weight ratio (E), i.e. (C)/((A)+(B)+(D)+(E)) is 0.1/100～30/100.
4, the preparation method of amphoteric urethane resin, this method adopts:
(A) polyol compound;
(B) polyisocyanate compound;
(C) polysiloxane compound (have at least one group of being selected from hydroxyl, primary amino and secondary amino group except) in the one or both ends of siloxane chain;
(D) have carboxyl and the compound that is selected from least one group of hydroxyl, primary amino and secondary amino group;
(E) have uncle's amino and the compound that is selected from least one group of hydroxyl, primary amino and secondary amino group;
(F) have the compound of the structural unit of at least one group that is selected from hydroxyl, primary amino and secondary amino group and following formula (11) expression
Chemical formula 1
-(C
2H
4O)
p(C
3H
6O)
q-??????????(11)
Wherein " p " is 1 to 500 integer, and " q " is 0 to 400 integer,
Wherein, if the structural unit in the structural formula (11) is C
2H
4O and C
3H
6The multipolymer of O (being q ≠ 0), they can be random copolymers or segmented copolymer;
This method comprises:
Make compound (A), (B), (D) and (F) react under the excessive condition of isocyanate groups, preparation comprises the first step of the prepolymer of isocyanate groups; With
Make second step of the prepolymer that comprises isocyanate groups and compound (E) reaction;
Wherein the first step and second the step at least one step in have compound (C).
5, the preparation method of amphoteric urethane resin, this method adopts:
(A) polyol compound;
(B) polyisocyanate compound;
(C) polysiloxane compound (have at least one group of being selected from hydroxyl, primary amino and secondary amino group except) in the one or both ends of siloxane chain;
(D) have carboxyl and the compound that is selected from least one group of hydroxyl, primary amino and secondary amino group;
(E) have uncle's amino and the compound that is selected from least one group of hydroxyl, primary amino and secondary amino group;
(F) have the compound of the structural unit of at least one group that is selected from hydroxyl, primary amino and secondary amino group and following formula (11) expression
Chemical formula 2
-(C
2H
4O)
p(C
3H
6O)
q-??????????(11)
Wherein " p " is 1 to 500 integer, and " q " is 0 to 400 integer,
Wherein, if the structural unit in the structural formula (11) is C
2H
4O and C
3H
6The multipolymer of O (being q ≠ 0), they can be random copolymers or segmented copolymer;
This method comprises:
Make compound (A), (B), (E) and (F) react under the excessive condition of isocyanate groups, preparation comprises the first step of the prepolymer of isocyanate groups; With
Make second step of the prepolymer that comprises isocyanate groups and compound (D) reaction;
Wherein the first step and second the step at least one step in have compound (C).
6, claim 4 or 5 preparation method, wherein compound (C) and compound (A), (B), (D), (E) and weight ratio (F), i.e. (C)/((A)+(B)+(D)+(E)+(F)) is 0.1/100～30/100.
7, each preparation method in the claim 1 to 6 wherein after second step, carries out transfer reaction by reaction product and the water that mixed for second step.
8, each preparation method in the claim 1 to 6, wherein after second step, carry out transfer reaction by reaction product and the buck that mixed for second step, or by basic cpd being added in the reaction product in second step, mix with water then, carry out transfer reaction.
9, each preparation method in the claim 1 to 8, wherein compound (C) is for being selected from polydimethylsiloxane, polyether-modified siloxanes, cyclosiloxane, phenyl modified siloxanes, alkyl-modified siloxanes, and at least a in the alkoxy-modified siloxanes.
10, the amphoteric urethane resin that obtains by each preparation method in the claim 1 to 9.
11, the amphoteric urethane resin of claim 10 wherein comprises carboxyl and uncle's amino in each molecule.
12, claim 10 or 11 amphoteric urethane resin, it mixes with water and forms the aqueous solution.
13, the polyurethane resin composition that comprises each amphoteric urethane resin in the claim 10 to 12.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP194685/01 | 2001-06-27 | ||
| JP2001194685A JP4688351B2 (en) | 2001-06-27 | 2001-06-27 | Production method of amphoteric urethane resin, amphoteric urethane resin and resin composition obtained by the production method |
| JP194685/2001 | 2001-06-27 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1406996A true CN1406996A (en) | 2003-04-02 |
| CN1260263C CN1260263C (en) | 2006-06-21 |
Family
ID=19032776
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB021282358A Expired - Fee Related CN1260263C (en) | 2001-06-27 | 2002-06-27 | Preparation of amphoteric polyurethane resin and products thereby and amphoteric resin composition |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US6646092B2 (en) |
| EP (1) | EP1275672B1 (en) |
| JP (1) | JP4688351B2 (en) |
| CN (1) | CN1260263C (en) |
| AU (1) | AU783970B2 (en) |
| BR (1) | BR0203347A (en) |
| DE (1) | DE60207154T2 (en) |
| MX (1) | MXPA02006419A (en) |
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| CN1303124C (en) * | 2004-01-30 | 2007-03-07 | 香港理工大学 | Water base block polyurethane, its preparing method and water-proof, heat insulation and wet permeable material made thereof |
| CN101225150B (en) * | 2008-01-28 | 2010-06-09 | 浙江大学 | Method for synthesizing water-dispersion organosilicon-polyurethane block copolymer and its uses |
| CN101225226B (en) * | 2008-01-28 | 2010-11-24 | 浙江大学 | Method for preparing water-dispersion montmorillonite/organic block polyurethane nano composite material and uses thereof |
| CN101917964B (en) * | 2007-11-13 | 2012-09-26 | 株式会社资生堂 | Skin care preparations |
| WO2013007004A1 (en) * | 2011-07-08 | 2013-01-17 | 江苏博特新材料有限公司 | Water-dispersible amphoteric polyurethane, preparation method therefor, and use thereof in reinforcing concrete |
| CN112739774A (en) * | 2018-06-28 | 2021-04-30 | 日东电工株式会社 | Anti-fouling polymer composite |
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| US20070185003A1 (en) * | 2006-01-18 | 2007-08-09 | Invista North America S.A.R.L. | Non-textile polymer compositions and methods |
| JP5463612B2 (en) * | 2006-09-28 | 2014-04-09 | 横浜ゴム株式会社 | Urethane emulsion |
| DE102008006004B3 (en) * | 2008-01-25 | 2009-08-27 | Bayer Materialscience Ag | Thermoplastic polyurethanes and their use |
| EP2113546A1 (en) | 2008-04-28 | 2009-11-04 | Schlumberger Holdings Limited | Swellable compositions for borehole applications |
| KR101789987B1 (en) | 2009-10-30 | 2017-10-25 | 미쯔비시 케미컬 주식회사 | Polyester polyol, polyurethane utilizing the polyester polyol and process for production thereof, and polyurethane molded article |
| JP5269855B2 (en) * | 2010-10-28 | 2013-08-21 | 株式会社 資生堂 | Cosmetics |
| EP2754694A4 (en) * | 2011-12-09 | 2015-05-06 | Dainippon Ink & Chemicals | Film-forming aid, aqueous resin composition and steel sheet surface treatment agent containing same |
| CN105237721A (en) * | 2015-09-17 | 2016-01-13 | 合肥思敬齐化工材料有限责任公司 | Preparation method of aqueous polyurethane resin with high adhesion |
| CN105175671A (en) * | 2015-09-17 | 2015-12-23 | 合肥思敬齐化工材料有限责任公司 | Anionic/cationic polyurethane resin and preparation method thereof |
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-
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- 2001-06-27 JP JP2001194685A patent/JP4688351B2/en not_active Expired - Fee Related
-
2002
- 2002-06-26 US US10/183,744 patent/US6646092B2/en not_active Expired - Lifetime
- 2002-06-26 MX MXPA02006419A patent/MXPA02006419A/en active IP Right Grant
- 2002-06-27 EP EP02014020A patent/EP1275672B1/en not_active Expired - Fee Related
- 2002-06-27 AU AU50677/02A patent/AU783970B2/en not_active Ceased
- 2002-06-27 BR BR0203347-0A patent/BR0203347A/en not_active IP Right Cessation
- 2002-06-27 CN CNB021282358A patent/CN1260263C/en not_active Expired - Fee Related
- 2002-06-27 DE DE60207154T patent/DE60207154T2/en not_active Expired - Lifetime
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN1303124C (en) * | 2004-01-30 | 2007-03-07 | 香港理工大学 | Water base block polyurethane, its preparing method and water-proof, heat insulation and wet permeable material made thereof |
| CN101917964B (en) * | 2007-11-13 | 2012-09-26 | 株式会社资生堂 | Skin care preparations |
| CN101225150B (en) * | 2008-01-28 | 2010-06-09 | 浙江大学 | Method for synthesizing water-dispersion organosilicon-polyurethane block copolymer and its uses |
| CN101225226B (en) * | 2008-01-28 | 2010-11-24 | 浙江大学 | Method for preparing water-dispersion montmorillonite/organic block polyurethane nano composite material and uses thereof |
| WO2013007004A1 (en) * | 2011-07-08 | 2013-01-17 | 江苏博特新材料有限公司 | Water-dispersible amphoteric polyurethane, preparation method therefor, and use thereof in reinforcing concrete |
| CN112739774A (en) * | 2018-06-28 | 2021-04-30 | 日东电工株式会社 | Anti-fouling polymer composite |
Also Published As
| Publication number | Publication date |
|---|---|
| AU783970B2 (en) | 2006-01-12 |
| EP1275672B1 (en) | 2005-11-09 |
| CN1260263C (en) | 2006-06-21 |
| DE60207154T2 (en) | 2006-08-10 |
| US6646092B2 (en) | 2003-11-11 |
| EP1275672A1 (en) | 2003-01-15 |
| JP2003012760A (en) | 2003-01-15 |
| AU5067702A (en) | 2003-01-02 |
| MXPA02006419A (en) | 2004-08-12 |
| US20030088041A1 (en) | 2003-05-08 |
| BR0203347A (en) | 2003-05-27 |
| DE60207154D1 (en) | 2005-12-15 |
| JP4688351B2 (en) | 2011-05-25 |
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