CN1394904A - Method for making plastic track by using nano material modified rubber elastic body - Google Patents
Method for making plastic track by using nano material modified rubber elastic body Download PDFInfo
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- CN1394904A CN1394904A CN 01114894 CN01114894A CN1394904A CN 1394904 A CN1394904 A CN 1394904A CN 01114894 CN01114894 CN 01114894 CN 01114894 A CN01114894 A CN 01114894A CN 1394904 A CN1394904 A CN 1394904A
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Abstract
The method for making plastic track by using nano material modified rubber elastomer is characterized by that it adopts nano calcium carbonate, nano barium carbonate and nano silicon dioxide materials, and utilizes a certain technological process and adds the above-mentioned materials into the rubber mixed body together with other materials so as to obtain the invented product. It can raise the physical mechanical performance of said elastomer, can increase its service time by 2-3 times, and the service life of said plastic track can be prolonged over 20 years.
Description
The present invention relates to rubber elastomer and make the method for plastic track by using, particularly adopt the method for making plastic track by using nano material modified rubber elastic body.
The shortcoming that adopts rubber elastomer to make plastic track by using is both at home and abroad: the cost height, and physical and mechanical properties is low, and not ageing-resistant, uvioresistant is poor, and not fire-retardant, abrasion performance is poor, while complete processing complexity, work-ing life is short.
The objective of the invention is at above-mentioned shortcoming, a kind of method that adopts making plastic track by using nano material modified rubber elastic body is provided, can make cost reduce by 10～30%, save elastomerics consumption 10～25%, improved this elastomeric physical and mechanical properties, improved 2～3 times of work-ing lifes, made the plastic cement race track life-span reach 20 years.
The object of the present invention is achieved like this:
1, material mixture ratio of the present invention (per-cent meter by weight) is as follows:
Take by weighing 10～50% terpolymer EP rubbers or cis-1,4-polybutadiene rubber, chloroprene rubber, natural gum, nitrile rubber; styrene-butadiene rubber(SBR); above-mentioned rubber can be that the 1-3 kind is mixed with terpolymer EP rubber; add 1～3% rubber accelerator then: cyclohexyl benzo thiazole time yellow acid amides (CZ); dibenzothiazyl disulfide (DM); six tetramethyl-tetramines (H); ziram (ZDMC); 0.01～0.4% UV light absorber: benzophenone (UV-9); 0.1～0.5% oxidation inhibitor: 4 hydroxyls-3.5 tert-butyl-phenyl propionic acid pentaerythritol tetrathioglycollate; 2～26% tenderizer: white factice; chlorinated paraffin; aromatic hydrocarbon oil; machine oil 20#; 0.1～25% nano material: nano-calcium carbonate (CCR; NCR); nano barium carbonate; nano silicon; 0.01～5% jointing material: petroleum resin; terpine resin; rubber ingredients: 0.01～10% zinc oxide; 0.1～6% sulphur; 0.01～5% hard ester acid, 5～20% additive: talcum powder.Simultaneously, prepare 0.1～5% pigment rubber master batch in addition: red iron oxide, rubber are bright red, the husky Huang of the Chinese, phthalein viridescent, the blue or green basket of phthalein, sea product basket, network are green, permanent yellow, forever solid orange, consolidate the mixture of orange one or more forever.
2, with above-mentioned pigment at first by rolling the rubber master batch of refining into various pigment, and then mix with material of main part and to roll refining, through slightly refining, carefully refine into the work in-process film, film condensation material becomes elastomerics through baking, being cut into 1～8 millimeter nano modification Ethylene Propylene Terpolymer through pulverizer is fire-resistant anti-skid micelle main body and other rubber mix, is used for the casting type plastic cement race track.Make various figuratum offset plates by drum vulcanizer simultaneously, directly be bonded on the concrete pedestal or make the non-granule plastic rubber runway on the asphalt concrete basis, the pavement material of basket, volleyball court, tennis court, court etc. gets final product with tackiness agent, and tackiness agent is the nano material modified polyurethane tackiness agent.
Adopt the product of the present invention's making and the product performance of usual way making to be compared as follows:
| Project | State quota | Usual production | Product of the present invention |
| Hardness | ????45～60 | ????52 | ????58 |
| Tensile strength at yield MPA | ????0.7 | ????1.0 | ????3.6 |
| Draw elongation % | ????90 | ????120 | ????450 |
| Rebound value % | ????20 | ????30 | ????36～40 |
| Flame retardant rating | ????1 | ????1 | ????1 |
| Nontoxic level (TDI content standard) | ????＞0.5 | ????＞0.8 | ????≤0 |
| Compression demobilization rate | ????≤95 | ????≤95 | ????≥99 |
| 70 ℃ * 168h coefficient | ????≤0.8 | ????≤0.83 | ????≥0.98 |
Owing to adopt the present invention, not only reduce product cost, the technology that simplifies the operation, every technical indicator all meets or exceeds national standard.
In conjunction with the embodiments, further describe prescription of the present invention and technical process:
Embodiment 1: make no particle prefabrication type plastic cement race track
1, takes by weighing 2.5 kilograms terpolymer EP rubber, 2 kilograms of butadiene-styrene rubbers, 0.15 kilogram of promotor, 0.1 kilogram of oxidation inhibitor, 0.4 kilogram of clorafin, 0.6 kilogram of aromatic hydrocarbon oil, 3 kilograms of nano-calcium carbonates, 2 kilograms of talcum powder, 0.1 kilogram of sulphur, 0.05 kilogram of stearic acid, 0.15 kilogram of anti-aging agent, 0.05 kilogram of benzophenone, 0.05 kilogram of terpine resin, 3 kilograms of red iron oxides.
2, above-mentioned ethylene-propylene diene copolymer and butadiene-styrene rubber are cut into piece, become masterbatch through mixing even back, treat that the masterbatch temperature is reduced to normal temperature after, mixing roll is together put in above-mentioned other material agent that takes by weighing is carried out mixing to evenly.
3, uniform material is directly gone out into sheet material by mixing roll, vulcanize preformation plastic cement race track work in-process through drum vulcanizer.
4, use the nano material modified polyurethane adhesives on the asphalt concrete basis ready-formed work in-process, draw and go up gauge wire, make the plastic cement race track of nano modification terpolymer EP rubber elastic composite.
Embodiment 2: make not threshing plastic cement race track
1, takes by weighing 1 kilogram terpolymer EP rubber, 2 kilograms of butadiene-styrene rubbers, 1 kilogram of natural rubber, 0.15 kilogram of promotor, 0.1 kilogram of oxidation inhibitor, 0.15 UV light absorber, 0.6 kilogram of clorafin, 0.6 kilogram of white factice, 0.6 kilogram of hydrocarbon ils, 4 kilograms of talcum powder, 1 kilogram of nano-calcium carbonate, 0.2 kilogram of sulphur, 0.07 stearic acid, 0.1 kilogram of zinc oxide, 0.3 kilogram of ziram, 1 kilogram of red iron oxide.
2, above-mentioned ethylene-propylene diene copolymer and butadiene-styrene rubber are cut into piece, become masterbatch through mixing even back, treat that the masterbatch temperature is reduced to normal temperature after, more above-mentioned other material agent that takes by weighing is together put into mixing roll and carries out mixing evenly, make film.
3, film is put into vulcanizing boiler and taken out sheet material after high temperature vulcanized 15 minutes, sheet material is ground into the random particle of 2～6 millimeters particle diameters with pulverizer.
4, on the casting type plastic cement race track primer of 10 mm thick that laid, the nano material modified polyurethane tackiness agent that blade coating one deck is 0.5～2 millimeter is sprinkling upon spontaneous curing above the tackiness agent with above-mentioned particle.Wipe floating unnecessary particle off, apply the nano material modified polyurethane tackiness agent of 0.1～1 millimeter of one deck more in the above, after the tackiness agent spontaneous curing, on runway, draw gauge wire, promptly make nano modification terpolymer EP rubber elastic anti-slip particle casting type plastic cement race track.
Claims (11)
1, the method for making plastic track by using nano material modified rubber elastic body is characterized in that:
A, material mixture ratio of the present invention (per-cent meter by weight) are as follows:
Take by weighing 10～50% terpolymer EP rubbers or cis-1,4-polybutadiene rubber, chloroprene rubber, natural gum, nitrile rubber, styrene-butadiene rubber(SBR), above-mentioned rubber can be that the 1-3 kind is mixed with terpolymer EP rubber, adds 1～3% rubber accelerator, 0.1～0.5% oxidation inhibitor, 2～26% tenderizer, 0.1～25% nano material, 0.01～5% jointing material, 0.1～6% rubber ingredients, 5～20% additive then;
B, prepare 0.1～5% pigment rubber master batch in addition;
C, with above-mentioned pigment at first by rolling the rubber master batch of refining into various pigment, and then mix with material of main part and to roll refining, through slightly refining, carefully refine into the work in-process film;
D, the film that above-mentioned mixing roll is rolled into are put into vulcanizing boiler and are taken out sheet material after high temperature vulcanized 15 minutes, sheet material are ground into the random particle of 2～6 millimeters particle diameters with pulverizer;
E, on the casting type plastic cement race track primer of 3～30 mm thick that laid, the nano material modified polyurethane tackiness agent that blade coating one deck is 0.1～5 millimeter, above-mentioned particle is sprinkling upon spontaneous curing above the tackiness agent, wipe floating unnecessary particle off, apply the tackiness agent of 0.1～1.5 millimeter of one deck more in the above, after the spontaneous curing, on runway, draw gauge wire, promptly make nano modification terpolymer EP rubber elastic anti-slip particle casting type plastic cement race track;
F, make sheet material by mixing roll, vulcanize, be prefabricated into the plastic cement race track work in-process through drum vulcanizer with above-mentioned;
G, with above-mentioned ready-formed work in-process with adhesives on the asphalt concrete basis, draw and go up gauge wire, make the plastic cement race track of nano modification terpolymer EP rubber elastic composite.
2, method according to claim 1 is characterized in that: above-mentioned promotor is cyclohexyl benzo thiazole time yellow acid amides (CZ), dibenzothiazyl disulfide (DM), six tetramethyl-tetramines (H), ziram (ZDMC).
3, method according to claim 1 is characterized in that: above-mentioned UV light absorber is benzophenone (UV-9).
4, method according to claim 1 is characterized in that: above-mentioned oxidation inhibitor is 4 hydroxyls-3.5 tert-butyl-phenyl propionic acid pentaerythritol tetrathioglycollate.
5, method according to claim 1 is characterized in that: above-mentioned tenderizer is white factice, chlorinated paraffin, aromatic hydrocarbon oil, machine oil 20#.
6, method according to claim 1 is characterized in that: above-mentioned nano material is nano-calcium carbonate (CCR, NCR), nano barium carbonate, nano silicon.
7, method according to claim 1 is characterized in that: above-mentioned jointing material is petroleum resin, terpine resin.
8, method according to claim 1 is characterized in that: above-mentioned rubber ingredients are: zinc oxide, sulphur, hard ester acid.
9, method according to claim 1 is characterized in that: above-mentioned pigment is that red iron oxide, rubber are bright red, the husky Huang of the Chinese, phthalein viridescent, the blue or green basket of phthalein, sea product basket, network are green, permanent yellow, forever solid orange, forever consolidate orange.
10, method according to claim 1 is characterized in that: above-mentioned additive is: talcum powder.
11, method according to claim 1 is characterized in that: above-mentioned tackiness agent is: the nano material modified polyurethane tackiness agent.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 01114894 CN1129636C (en) | 2001-07-09 | 2001-07-09 | Method for making plastic track by using nano material modified rubber elastic body |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 01114894 CN1129636C (en) | 2001-07-09 | 2001-07-09 | Method for making plastic track by using nano material modified rubber elastic body |
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| Publication Number | Publication Date |
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| CN1394904A true CN1394904A (en) | 2003-02-05 |
| CN1129636C CN1129636C (en) | 2003-12-03 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 01114894 Expired - Fee Related CN1129636C (en) | 2001-07-09 | 2001-07-09 | Method for making plastic track by using nano material modified rubber elastic body |
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Cited By (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100363418C (en) * | 2006-03-09 | 2008-01-23 | 郑志伟 | Material special for plastic track |
| CN101263085B (en) * | 2005-07-13 | 2012-01-04 | 萨克特本化学有限责任公司 | Labeled inorganic additive |
| CN102634046A (en) * | 2012-04-26 | 2012-08-15 | 邹德荣 | Vulcanization method for improving bonding quality of adhesive |
| CN103304865A (en) * | 2013-05-23 | 2013-09-18 | 杭州宝力物资再生利用有限公司 | Thermal-optical energy EPDM (Ethylene-Propylene-Diene Monomer) granular material |
| CN103397586A (en) * | 2013-08-08 | 2013-11-20 | 常熟市中腾塑胶有限公司 | Preparation method of environment-friendly nano-grade PU plastic track |
| CN104404855A (en) * | 2014-12-29 | 2015-03-11 | 苏州奥莱鑫建材有限公司 | Anti-skid plastic track |
| CN105600711A (en) * | 2016-01-05 | 2016-05-25 | 高艺松 | Corrosion-resistant lifting climbing vehicle |
| CN105856784A (en) * | 2016-05-03 | 2016-08-17 | 清远川奥高新材料有限公司 | Multifunctional elastic rubber blanket and manufacturing method thereof |
| CN105924803A (en) * | 2016-05-16 | 2016-09-07 | 天津纽威特橡胶制品股份有限公司 | Plastic track material composition |
| CN106243525A (en) * | 2016-08-27 | 2016-12-21 | 潍坊市宏源防水材料有限公司 | High wear-resistance anti-static type EPDM waterproof rolled sheet and preparation method thereof |
| CN106675369A (en) * | 2016-12-28 | 2017-05-17 | 芜湖普乐士新型建筑材料配套有限公司 | Waterborne polyurethane track material |
| CN106675368A (en) * | 2016-12-28 | 2017-05-17 | 芜湖普乐士新型建筑材料配套有限公司 | Waterborne polyurethane rubber track material |
| CN106751030A (en) * | 2016-12-20 | 2017-05-31 | 墨宝股份有限公司 | A kind of environment-friendly type plastic rubber slurry of sports field and preparation method thereof |
| CN106854431A (en) * | 2016-12-28 | 2017-06-16 | 芜湖普乐士新型建筑材料配套有限公司 | Aqueous polyurethane track material |
| CN106854397A (en) * | 2016-12-28 | 2017-06-16 | 芜湖普乐士新型建筑材料配套有限公司 | A kind of aqueous polyurethane rubber track material |
| CN107141550A (en) * | 2017-07-01 | 2017-09-08 | 南京市雨花台区绿宝工业设计服务中心 | A kind of preparation method of modified rubber particle |
| CN108162521A (en) * | 2018-01-11 | 2018-06-15 | 湖南盛亚体育实业有限公司 | A kind of release anion microporous foam rubber track coiled material and preparation method thereof |
| CN110358163A (en) * | 2019-08-08 | 2019-10-22 | 厦门市金汤橡塑有限公司 | A kind of rubber composition and stud-farm rubber channel |
| CN111621098A (en) * | 2019-06-18 | 2020-09-04 | 道一高分子聚合物(宁波)有限公司 | Foaming type plastic track granular material and preparation method thereof |
| CN113637264A (en) * | 2021-07-23 | 2021-11-12 | 广东领跑新材料科技有限公司 | EPR prefabricated motion field surface layer material and preparation method thereof |
-
2001
- 2001-07-09 CN CN 01114894 patent/CN1129636C/en not_active Expired - Fee Related
Cited By (25)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101263085B (en) * | 2005-07-13 | 2012-01-04 | 萨克特本化学有限责任公司 | Labeled inorganic additive |
| CN100363418C (en) * | 2006-03-09 | 2008-01-23 | 郑志伟 | Material special for plastic track |
| CN102634046A (en) * | 2012-04-26 | 2012-08-15 | 邹德荣 | Vulcanization method for improving bonding quality of adhesive |
| CN103304865A (en) * | 2013-05-23 | 2013-09-18 | 杭州宝力物资再生利用有限公司 | Thermal-optical energy EPDM (Ethylene-Propylene-Diene Monomer) granular material |
| CN103397586A (en) * | 2013-08-08 | 2013-11-20 | 常熟市中腾塑胶有限公司 | Preparation method of environment-friendly nano-grade PU plastic track |
| CN104404855A (en) * | 2014-12-29 | 2015-03-11 | 苏州奥莱鑫建材有限公司 | Anti-skid plastic track |
| CN104404855B (en) * | 2014-12-29 | 2016-05-18 | 苏州奥莱鑫建材有限公司 | A kind of plastic anti-skid runway |
| CN105600711A (en) * | 2016-01-05 | 2016-05-25 | 高艺松 | Corrosion-resistant lifting climbing vehicle |
| CN105856784B (en) * | 2016-05-03 | 2018-09-18 | 广东川奥高新科技有限公司 | A kind of Multifunctional elastic rubber pad and preparation method thereof |
| CN105856784A (en) * | 2016-05-03 | 2016-08-17 | 清远川奥高新材料有限公司 | Multifunctional elastic rubber blanket and manufacturing method thereof |
| CN105924803A (en) * | 2016-05-16 | 2016-09-07 | 天津纽威特橡胶制品股份有限公司 | Plastic track material composition |
| CN106243525A (en) * | 2016-08-27 | 2016-12-21 | 潍坊市宏源防水材料有限公司 | High wear-resistance anti-static type EPDM waterproof rolled sheet and preparation method thereof |
| CN106751030A (en) * | 2016-12-20 | 2017-05-31 | 墨宝股份有限公司 | A kind of environment-friendly type plastic rubber slurry of sports field and preparation method thereof |
| CN106675369A (en) * | 2016-12-28 | 2017-05-17 | 芜湖普乐士新型建筑材料配套有限公司 | Waterborne polyurethane track material |
| CN106675368A (en) * | 2016-12-28 | 2017-05-17 | 芜湖普乐士新型建筑材料配套有限公司 | Waterborne polyurethane rubber track material |
| CN106854431A (en) * | 2016-12-28 | 2017-06-16 | 芜湖普乐士新型建筑材料配套有限公司 | Aqueous polyurethane track material |
| CN106854397A (en) * | 2016-12-28 | 2017-06-16 | 芜湖普乐士新型建筑材料配套有限公司 | A kind of aqueous polyurethane rubber track material |
| CN107141550B (en) * | 2017-07-01 | 2018-11-23 | 湖南优冠体育材料有限公司 | A kind of preparation method of modified rubber particle |
| CN107141550A (en) * | 2017-07-01 | 2017-09-08 | 南京市雨花台区绿宝工业设计服务中心 | A kind of preparation method of modified rubber particle |
| CN108162521A (en) * | 2018-01-11 | 2018-06-15 | 湖南盛亚体育实业有限公司 | A kind of release anion microporous foam rubber track coiled material and preparation method thereof |
| CN111621098A (en) * | 2019-06-18 | 2020-09-04 | 道一高分子聚合物(宁波)有限公司 | Foaming type plastic track granular material and preparation method thereof |
| CN110358163A (en) * | 2019-08-08 | 2019-10-22 | 厦门市金汤橡塑有限公司 | A kind of rubber composition and stud-farm rubber channel |
| CN110358163B (en) * | 2019-08-08 | 2021-09-07 | 厦门市金汤橡塑有限公司 | Rubber composition and rubber passage of horse race |
| CN113637264A (en) * | 2021-07-23 | 2021-11-12 | 广东领跑新材料科技有限公司 | EPR prefabricated motion field surface layer material and preparation method thereof |
| CN113637264B (en) * | 2021-07-23 | 2023-08-08 | 广东领跑新材料科技有限公司 | EPR prefabricated athletic field surface layer material and preparation method thereof |
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| Publication number | Publication date |
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| CN1129636C (en) | 2003-12-03 |
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Granted publication date: 20031203 Termination date: 20120709 |