CN1348933A - Light wall material and its production process - Google Patents

Light wall material and its production process Download PDF

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Publication number
CN1348933A
CN1348933A CN01131564A CN01131564A CN1348933A CN 1348933 A CN1348933 A CN 1348933A CN 01131564 A CN01131564 A CN 01131564A CN 01131564 A CN01131564 A CN 01131564A CN 1348933 A CN1348933 A CN 1348933A
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CN
China
Prior art keywords
parts
magnesium chloride
water
formaldehyde resin
magnesium oxide
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Granted
Application number
CN01131564A
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Chinese (zh)
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CN1159253C (en
Inventor
黄开云
黄浩峰
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Individual
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Individual
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Priority to CNB011315644A priority Critical patent/CN1159253C/en
Publication of CN1348933A publication Critical patent/CN1348933A/en
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Publication of CN1159253C publication Critical patent/CN1159253C/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/30Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing magnesium cements or similar cements
    • C04B28/32Magnesium oxychloride cements, e.g. Sorel cement
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/40Porous or lightweight materials
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/91Use of waste materials as fillers for mortars or concrete

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)

Abstract

A high-wt. wall element consists of the following materials in wt. ratio (portions): magnesium oxide 80-120, magnesium chloride 35-45, talcum powder 3-6, water-proofing powder 3-6, urea formaldehyde resin 0.4-0.8, filler 40-80 and additive 0.5; and the filler being saw dust, crushed rice straw or crop stems. Its making method is as follows: the magnesium oxide, filler, etc. are weighed according to wt. proportion and are uniformly mixed; the magnesium chloride is further dissolved by adding water, and the dissolved urea formaldehyde resin and addtiive are further added; then magnesium chloride mixed solution is poured into the dry material and stirred to make a slurry, and the slurry is injected into a mould, tamped to formation, demoulded after hardening, then is trimmed and inspected to obtain the product. Advantages are stable crystalline structure, no strength decrease during soaking in water, and long-term stability.

Description

Light wall material and manufacture method
Technical field
The present invention relates to a kind of light wall material, also relate to the manufacture method of this materials for wall.
Background technology
Infilled wall in the construction work or in the building frame uses clay brick or concrete grey sanded brick for many years, and silica-magnesia panel is promoted in examination now.Fire clay brick and destroy arable land, consumes energy, and body of wall is heavy, the framework load is big, building cost is high, so clay solid brick is forbidden in 160 cities, the Ministry of Construction explicit order whole nation in limited time.In recent years, came the substitute for clay brick with holllow building block gradually, the holllow building block that wherein useful slag, flyash are made as stopping composition, also useful light sandwich Taibai panel is made infilled wall.Though wall weight reduces, but still has some problems, slag holllow building block intensity is relatively poor, and lightweight Taibai panel production investment is huge, unfavorable promoting the use of.Disclosed 94,110,824 1 kinds of light-weight hollow building block mades in the Chinese patent literature are that aggregate accounts for total raw material 41-48% with the mixture of ground silica or magnesium oxide, magnesium chloride, and with wood sawdust, to pulverize straw etc. be stopping composition, accounts for 50-55%, other adds jelling agent 2-4%.The magnesium oxide consumption accounts for the 23-27% of building block batching total amount, and the magnesium chloride consumption accounts for the 2-4% of total amount.This material, though in light weight, draw materials easily, easy to make, there is a deadly defect, anti-halogen phenomenon is serious under moist situation, and along with the prolongation of time, its intensity progressively reduces simultaneously.The like product that examination is in China at present promoted all has this phenomenon.
Summary of the invention
To be the anti-halogen phenomenon that exists of materials for wall that main raw material is made and to prolong the problem that reduces intensity in time in order to solve with magnesium oxide, magnesium chloride, stopping composition etc., through the repetition test research of more than ten years, develop a kind of more satisfactory light wall material and manufacture method finally.
Light wall material of the present invention is characterized in that, is made up of the raw material of following weight part:
Magnesium oxide 80-120 part, magnesium chloride 35-45 part,
Talcum powder 3-6 part, water-proofing powder 3-6 part,
Urea-formaldehyde resin 0.4-0.8 part, stopping composition 40-80 part,
0.5 part of additive, additive is made up of the following raw materials according weight part:
Sodium pyrosulfate, ferrous sulfate, sodium hydroxide, each 0.08-0.15 part of Sodium Silicofluoride, potassium permanganate 0.06-0.12 part.
Stopping composition is wood sawdust, pulverizing straw or straw and agricultural crop straw etc.
The making method of light wall material of the present invention is:
It is even to take by weighing magnesium oxide, talcum powder, water-proofing powder, stopping composition mixing dry mixing by weight; Again magnesium chloride is dissolved in water, adds the urea-formaldehyde resin mixing again, take by weighing additive raw material more by weight and pour in the magnesium chloride mixture solution with water dissolution; Then the magnesium chloride mixed solution is poured into and stirred into wet slurry in the siccative; Wet slurry is injected mould, and building block adds glass cloth or silk, the compaction moulding that vibrates when big, sclerosis back form removal, finishing, check finished product.
Product of the present invention has the following advantages: 1. because chemical reaction is arranged, product produces stable crystal phase structure in process of setting, thereby makes product not anti-halogen in wet environment, does not also reduce intensity during water logging; 2. the destruction of having contained crystal phase structure in the product with leach, product can be in steady state for a long time; 3. can produce solid slab, cored slab, little medium-sized building block and the building and ornament materials of various models by national standard.With other material of construction good adhesive effect is arranged; 4. product weight is light, intensity is high, anticorrosive, ageing-resistant, do not burn; 5. can suitably reduce construction costs, improve operating efficiency; 6. raw material 30% is to adopt worker, agriculture production waste, can turn waste into wealth.
Embodiment
Embodiment 1
1, as required, prepare mould.
2, raw material is prepared, and takes by weighing raw material according to proportioning
Magnesium oxide (content 85%) 100kg, talcum powder 5kg, water-proofing powder 4kg, stopping composition (wood sawdust or pulverizing straw) are 50kg, and it is even to mix dry mixing.Also available crop stalk of stopping composition or industrial slags, the increase and decrease of stopping composition can be adjusted the intensity and the toughness of product.
3, magnesium chloride (content 65%) 40kg is added the 6kg water dissolution, add the 0.6kg urea-formaldehyde resin again and mix thoroughly, pour the 0.5kg additive in magnesium chloride solution mixing.Additive is prepared by following raw materials according: sodium pyrosulfate, ferrous sulfate, each 0.11kg of hydrogen-oxygen sodium Sodium Silicofluoride, potassium permanganate 0.06kg.
The crystal phase structure that the adding of additive increases product strength, maintenance items does not destroy, improves water resistance, product can be in steady state for a long time, guarantees quality product and work-ing life.
4, the magnesium chloride mixed solution is poured in the siccative of mixing gradually stirred into wet slurry.
5, wet slurry is poured in the mould vibrate, compaction moulding.
As make bulk sheet material, suitably add glass cloth or glass silk.
6, sclerosis back form removal, finishing, check get product.
Embodiment 2
Substantially with embodiment 1, proportioning raw materials changes into step:
Magnesium oxide 120kg, magnesium chloride 35kg,
Talcum powder 6kg, water-proofing powder 3kg,
Urea-formaldehyde resin 0.4kg, stopping composition 40kg
The different content of magnesium oxide, magnesium chloride can be adjusted as required.
Embodiment 3 proportioning raw materials are:
Magnesium oxide 80kg, magnesium chloride 45kg,
Talcum powder 3kg, water-proofing powder 5kg
Urea-formaldehyde resin 0.8kg, stopping composition 70kg,
Additive 0.6kg.

Claims (4)

1. a light wall material is characterized in that, it is made up of the raw material of following weight part:
Magnesium oxide (content is more than 85%) 80-120 part, magnesium chloride 35-45 part,
Talcum powder 3-6 part, water-proofing powder 3-6 part,
Urea-formaldehyde resin 0.4-0.8 part, stopping composition 40-80 part,
Stopping composition is that wood sawdust, pulverizing straw or straw and crop stalk serve as.
2. materials for wall according to claim 1 is characterized in that the additive that comprises that also the following raw materials according weight part is formed:
Sodium pyrosulfate, ferrous sulfate, sodium hydroxide, each 0.08-0.15 part of Sodium Silicofluoride, potassium permanganate 0.06-0.12 part.
3. materials for wall according to claim 2 is characterized in that, it is made up of the raw material of following weight part:
100 parts in magnesium oxide, 40 parts in magnesium chloride, 5 parts of talcum powder,
4 parts of water-proofing powder, 0.6 part of urea-formaldehyde resin, 50 parts of stopping composition,
0.5 part of additive.
4. the manufacture method of light wall material is characterized in that:
A. take by weighing 100 parts in magnesium oxide, 5 parts of talcum powder, 4 parts of water-proofing powder, 50 parts of stopping composition, it is even to mix dry mixing;
B. magnesium chloride is added 6 parts of water dissolution for 40 parts, add urea-formaldehyde resin again and stir for 0.6 part; With 0.5 part of additive with pouring into after the water dissolution in the magnesium chloride solution;
C. the magnesium chloride mixed solution is poured in the siccative of mixing gradually and stirred into wet slurry;
D. wet slurry is poured in the mould vibrate, compaction moulding, as making bulk sheet material, suitably add glass silk or glass cloth;
E. sclerosis back form removal, finishing, check warehouse-in.
CNB011315644A 2001-11-22 2001-11-22 Light wall material and its production process Expired - Fee Related CN1159253C (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CNB011315644A CN1159253C (en) 2001-11-22 2001-11-22 Light wall material and its production process

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CNB011315644A CN1159253C (en) 2001-11-22 2001-11-22 Light wall material and its production process

Publications (2)

Publication Number Publication Date
CN1348933A true CN1348933A (en) 2002-05-15
CN1159253C CN1159253C (en) 2004-07-28

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Family Applications (1)

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CNB011315644A Expired - Fee Related CN1159253C (en) 2001-11-22 2001-11-22 Light wall material and its production process

Country Status (1)

Country Link
CN (1) CN1159253C (en)

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2007112652A1 (en) * 2006-03-31 2007-10-11 Guangwei Yang An environment protecting power-saving fire retardant synthetic lumber and manufacturing method thereof
CN100389941C (en) * 2006-07-07 2008-05-28 杨光伟 Multilayer flame-retardant composite wood and method for producing same
CN101423368B (en) * 2008-11-26 2011-06-15 丁志强 Light wall board and manufacturing technology thereof
CN102555013A (en) * 2012-01-11 2012-07-11 杨光伟 Inflaming retarding plant fiber composition and preparation method of member thereof
CN102807352A (en) * 2012-08-10 2012-12-05 乐山市恒达建筑材料厂 Making process of anti-ultraviolet fireproof energy-saving insulation board
CN103568104A (en) * 2012-08-01 2014-02-12 长沙创远环保科技有限公司 Preparation method for novel rice straw fiber board
CN103921334A (en) * 2014-04-09 2014-07-16 赤峰润得建筑有限公司 Brick building construction method of ecological insulation wall
CN104929304A (en) * 2015-05-27 2015-09-23 四川省劲腾环保建材有限公司 Production method of light-weight partition wall board
CN106673590A (en) * 2016-09-13 2017-05-17 内蒙古博大新型墙体材料研究所 Novel heat preservation and isolation wall body material and preparation method thereof

Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2007112652A1 (en) * 2006-03-31 2007-10-11 Guangwei Yang An environment protecting power-saving fire retardant synthetic lumber and manufacturing method thereof
CN100389941C (en) * 2006-07-07 2008-05-28 杨光伟 Multilayer flame-retardant composite wood and method for producing same
CN101423368B (en) * 2008-11-26 2011-06-15 丁志强 Light wall board and manufacturing technology thereof
CN102555013A (en) * 2012-01-11 2012-07-11 杨光伟 Inflaming retarding plant fiber composition and preparation method of member thereof
CN103568104A (en) * 2012-08-01 2014-02-12 长沙创远环保科技有限公司 Preparation method for novel rice straw fiber board
CN102807352A (en) * 2012-08-10 2012-12-05 乐山市恒达建筑材料厂 Making process of anti-ultraviolet fireproof energy-saving insulation board
CN102807352B (en) * 2012-08-10 2014-04-02 乐山市恒达建筑材料厂 Making process of anti-ultraviolet fireproof energy-saving insulation board
CN103921334A (en) * 2014-04-09 2014-07-16 赤峰润得建筑有限公司 Brick building construction method of ecological insulation wall
CN103921334B (en) * 2014-04-09 2016-02-10 赤峰润得建筑有限公司 Ecological heat insulating wall brick masonry construction method
CN104929304A (en) * 2015-05-27 2015-09-23 四川省劲腾环保建材有限公司 Production method of light-weight partition wall board
CN106673590A (en) * 2016-09-13 2017-05-17 内蒙古博大新型墙体材料研究所 Novel heat preservation and isolation wall body material and preparation method thereof

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Publication number Publication date
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Granted publication date: 20040728