CN1343746A - Antibacterial antimildew surface decorative material and its application method - Google Patents
Antibacterial antimildew surface decorative material and its application method Download PDFInfo
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- CN1343746A CN1343746A CN 01128990 CN01128990A CN1343746A CN 1343746 A CN1343746 A CN 1343746A CN 01128990 CN01128990 CN 01128990 CN 01128990 A CN01128990 A CN 01128990A CN 1343746 A CN1343746 A CN 1343746A
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- antiseptic
- material according
- agent
- antibacterial
- wear resistance
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- 239000000463 material Substances 0.000 title claims abstract description 42
- 230000000844 anti-bacterial effect Effects 0.000 title claims abstract description 35
- 238000000034 method Methods 0.000 title claims description 10
- 229920005989 resin Polymers 0.000 claims abstract description 21
- 239000011347 resin Substances 0.000 claims abstract description 21
- 239000000945 filler Substances 0.000 claims abstract description 18
- 239000003242 anti bacterial agent Substances 0.000 claims abstract description 5
- 238000002156 mixing Methods 0.000 claims abstract description 5
- 230000002421 anti-septic effect Effects 0.000 claims description 20
- 239000000203 mixture Substances 0.000 claims description 15
- 239000000843 powder Substances 0.000 claims description 14
- 229920002521 macromolecule Polymers 0.000 claims description 13
- 239000011159 matrix material Substances 0.000 claims description 13
- 239000003795 chemical substances by application Substances 0.000 claims description 9
- 150000002500 ions Chemical class 0.000 claims description 9
- 229910052709 silver Inorganic materials 0.000 claims description 9
- 239000004332 silver Substances 0.000 claims description 9
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 8
- 239000012752 auxiliary agent Substances 0.000 claims description 8
- 229910010271 silicon carbide Inorganic materials 0.000 claims description 8
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 7
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 claims description 7
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 6
- JPVYNHNXODAKFH-UHFFFAOYSA-N Cu2+ Chemical compound [Cu+2] JPVYNHNXODAKFH-UHFFFAOYSA-N 0.000 claims description 6
- 238000005034 decoration Methods 0.000 claims description 6
- -1 silver ions Chemical class 0.000 claims description 5
- 229910021536 Zeolite Inorganic materials 0.000 claims description 4
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical group O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 4
- 239000006185 dispersion Substances 0.000 claims description 4
- 238000011049 filling Methods 0.000 claims description 4
- 239000004408 titanium dioxide Substances 0.000 claims description 4
- 239000010457 zeolite Substances 0.000 claims description 4
- 229910052581 Si3N4 Inorganic materials 0.000 claims description 3
- 239000003054 catalyst Substances 0.000 claims description 3
- 239000007822 coupling agent Substances 0.000 claims description 3
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 claims description 3
- KZHJGOXRZJKJNY-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Si]=O.O=[Al]O[Al]=O.O=[Al]O[Al]=O.O=[Al]O[Al]=O KZHJGOXRZJKJNY-UHFFFAOYSA-N 0.000 claims description 3
- 239000000975 dye Substances 0.000 claims description 3
- 229910052588 hydroxylapatite Inorganic materials 0.000 claims description 3
- 239000003112 inhibitor Substances 0.000 claims description 3
- 239000011021 lapis lazuli Substances 0.000 claims description 3
- 229910052901 montmorillonite Inorganic materials 0.000 claims description 3
- 229910052863 mullite Inorganic materials 0.000 claims description 3
- 230000003647 oxidation Effects 0.000 claims description 3
- 238000007254 oxidation reaction Methods 0.000 claims description 3
- XYJRXVWERLGGKC-UHFFFAOYSA-D pentacalcium;hydroxide;triphosphate Chemical compound [OH-].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O XYJRXVWERLGGKC-UHFFFAOYSA-D 0.000 claims description 3
- 150000003016 phosphoric acids Chemical class 0.000 claims description 3
- 239000003504 photosensitizing agent Substances 0.000 claims description 3
- 239000000049 pigment Substances 0.000 claims description 3
- 239000000741 silica gel Substances 0.000 claims description 3
- 229910002027 silica gel Inorganic materials 0.000 claims description 3
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 claims description 3
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims description 3
- 239000006096 absorbing agent Substances 0.000 claims description 2
- 239000012628 flowing agent Substances 0.000 claims description 2
- 241000894006 Bacteria Species 0.000 abstract description 11
- 238000000576 coating method Methods 0.000 abstract description 5
- 239000011248 coating agent Substances 0.000 abstract description 2
- 230000003115 biocidal effect Effects 0.000 description 11
- 238000009408 flooring Methods 0.000 description 8
- 238000001723 curing Methods 0.000 description 6
- 239000000126 substance Substances 0.000 description 6
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 5
- 244000005700 microbiome Species 0.000 description 5
- 230000036299 sexual function Effects 0.000 description 5
- 230000001954 sterilising effect Effects 0.000 description 5
- 238000004659 sterilization and disinfection Methods 0.000 description 5
- 241000233866 Fungi Species 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 4
- 210000004027 cell Anatomy 0.000 description 4
- 238000007598 dipping method Methods 0.000 description 4
- 230000005923 long-lasting effect Effects 0.000 description 4
- BSWGGJHLVUUXTL-UHFFFAOYSA-N silver zinc Chemical compound [Zn].[Ag] BSWGGJHLVUUXTL-UHFFFAOYSA-N 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- 238000009395 breeding Methods 0.000 description 3
- 230000001488 breeding effect Effects 0.000 description 3
- 239000013078 crystal Substances 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000005755 formation reaction Methods 0.000 description 3
- 230000006870 function Effects 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 229920000642 polymer Polymers 0.000 description 3
- 230000005855 radiation Effects 0.000 description 3
- 238000001228 spectrum Methods 0.000 description 3
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical group [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- 229910019142 PO4 Inorganic materials 0.000 description 2
- YTPLMLYBLZKORZ-UHFFFAOYSA-N Thiophene Chemical compound C=1C=CSC=1 YTPLMLYBLZKORZ-UHFFFAOYSA-N 0.000 description 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 2
- 229920003180 amino resin Polymers 0.000 description 2
- 230000000845 anti-microbial effect Effects 0.000 description 2
- 229940064004 antiseptic throat preparations Drugs 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 239000010949 copper Substances 0.000 description 2
- 238000010894 electron beam technology Methods 0.000 description 2
- 238000009998 heat setting Methods 0.000 description 2
- 230000005764 inhibitory process Effects 0.000 description 2
- 229910052500 inorganic mineral Inorganic materials 0.000 description 2
- 229910021645 metal ion Inorganic materials 0.000 description 2
- 239000011707 mineral Substances 0.000 description 2
- 235000010755 mineral Nutrition 0.000 description 2
- 230000002688 persistence Effects 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 2
- 239000010452 phosphate Substances 0.000 description 2
- 102000004169 proteins and genes Human genes 0.000 description 2
- 108090000623 proteins and genes Proteins 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- 235000012239 silicon dioxide Nutrition 0.000 description 2
- 229910001923 silver oxide Inorganic materials 0.000 description 2
- NDVLTYZPCACLMA-UHFFFAOYSA-N silver oxide Substances [O-2].[Ag+].[Ag+] NDVLTYZPCACLMA-UHFFFAOYSA-N 0.000 description 2
- 125000004646 sulfenyl group Chemical group S(*)* 0.000 description 2
- 150000003672 ureas Chemical class 0.000 description 2
- 229910052725 zinc Inorganic materials 0.000 description 2
- 239000011701 zinc Substances 0.000 description 2
- 229940123208 Biguanide Drugs 0.000 description 1
- 229920001661 Chitosan Polymers 0.000 description 1
- 241000195493 Cryptophyta Species 0.000 description 1
- 102000004190 Enzymes Human genes 0.000 description 1
- 108090000790 Enzymes Proteins 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- 241000588724 Escherichia coli Species 0.000 description 1
- 229920000877 Melamine resin Polymers 0.000 description 1
- 241000191967 Staphylococcus aureus Species 0.000 description 1
- 229920001807 Urea-formaldehyde Polymers 0.000 description 1
- 241000700605 Viruses Species 0.000 description 1
- 238000002679 ablation Methods 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 229920006243 acrylic copolymer Polymers 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 229910021431 alpha silicon carbide Inorganic materials 0.000 description 1
- 125000003368 amide group Chemical group 0.000 description 1
- 230000001580 bacterial effect Effects 0.000 description 1
- 150000004283 biguanides Chemical class 0.000 description 1
- 238000001354 calcination Methods 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 210000000170 cell membrane Anatomy 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 150000001879 copper Chemical class 0.000 description 1
- 229910001431 copper ion Inorganic materials 0.000 description 1
- 230000008878 coupling Effects 0.000 description 1
- 238000010168 coupling process Methods 0.000 description 1
- 238000005859 coupling reaction Methods 0.000 description 1
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- 230000007812 deficiency Effects 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 239000000645 desinfectant Substances 0.000 description 1
- 230000003670 easy-to-clean Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- IVJISJACKSSFGE-UHFFFAOYSA-N formaldehyde;1,3,5-triazine-2,4,6-triamine Chemical compound O=C.NC1=NC(N)=NC(N)=N1 IVJISJACKSSFGE-UHFFFAOYSA-N 0.000 description 1
- 125000002485 formyl group Chemical class [H]C(*)=O 0.000 description 1
- 230000002538 fungal effect Effects 0.000 description 1
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- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 150000002460 imidazoles Chemical class 0.000 description 1
- 229910017053 inorganic salt Inorganic materials 0.000 description 1
- 239000010985 leather Substances 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 230000010534 mechanism of action Effects 0.000 description 1
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- 229910052751 metal Inorganic materials 0.000 description 1
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- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 230000000813 microbial effect Effects 0.000 description 1
- 125000000896 monocarboxylic acid group Chemical group 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 125000002524 organometallic group Chemical group 0.000 description 1
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- ODGAOXROABLFNM-UHFFFAOYSA-N polynoxylin Chemical compound O=C.NC(N)=O ODGAOXROABLFNM-UHFFFAOYSA-N 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 150000003222 pyridines Chemical class 0.000 description 1
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 229910000108 silver(I,III) oxide Inorganic materials 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
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Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
- Laminated Bodies (AREA)
- Floor Finish (AREA)
Abstract
An antibacterial anti-mildew surface decorating material contains high-molecular basic resin, antibacterial agent, antiwear filler, and assistant through proportional mixing. It is applied by coating it on the surface of the object to be decorated and then solidifying. It can effectively suppress and kill the bacteria on the surface of the said object.
Description
Technical field:
The present invention is relevant with combination with decorative surfaces material and using method thereof, and especially with antibacterial antimildew surface decorative material and on the floor, kitchen cabinet is relevant with the using method on the dining table plane materiel.
Technical background:
The performance that can suppress bacterial growth and growth is called antibiotic, killing bacteria or be called sterilization near the performance of sterile state; Can grow, breed by mould fungus inhibition, thereby prevent that microorganism from causing mould performance and being called mildew-resistant; Material with antibiotic or sterilizing function is called the antibacterial and mouldproof material.Before the present invention, popular laminated flooring, kitchen cabinet and dining table on the domestic market generally do not possess the function of antibiotic, sterilization and mildew-resistant.
Existing antimildew disinfectant mainly is to utilize copper bearing inorganic salt or organic salt, acid, solvent and auxiliary agent thereof to be mixed with the solution of copper ions, utilizes cupric ion contained in the solution to carry out fungus and mildew resistance, can be used for leather, the fungus and mildew resistance of building and ornament materials.Add solvent during use and brush at the architectural decoration material surface, antibacterial effect is limited, and persistence is poor.
The content of invention:
It is good to the purpose of this invention is to provide a kind of antibacterial effect, antibiotic wide spectrum, long-acting, safe, as not influence surfacing colour stability, the antibacterial antimildew surface decorative material of good decorating effect and using method thereof.
The present invention is achieved in that
Antibacterial antimildew surface decorative material of the present invention comprises following component and consumption: weight part
A: macromolecule matrix resin 100
B: antiseptic-germicide 0.1～5
C: wear resistance filler: 0～70
D: auxiliary agent 0～10
Antiseptic-germicide of the present invention comprises inorganic antiseptic, and its component and consumption are: weight part inorganic antiseptic 70～100
Organic antibacterial agent 0～30.
Inorganic antiseptic of the present invention is that independent silver ions is carried on the inorganic matter carrier and the powder of making.
Inorganic antiseptic of the present invention comprises also that zine ion or cupric ion are carried on the inorganic matter carrier and the powder of making.
Silver ions of the present invention, zine ion, cupric ion is a coordination ion, and the carrier of antiseptic-germicide is zeolite, phosphoric acid salt, hydroxyapatite, silica gel, soluble glass, montmorillonite, in the titanium dioxide one or more mix use, and the median size of carrier is 0.1～10 μ m; Preferred median size is 10～2000nm.
Macromolecule matrix resin of the present invention is curable macromolecule resin.
Wear resistance filler of the present invention is one or more mixtures in aluminium sesquioxide, lapis amiridis, mullite, silicon carbide, the silicon nitride.
Wear resistance filler of the present invention is that one or both mixing in aluminium sesquioxide, the silicon carbide are used, and its median size is 5～100 μ m, preferred 10～500nm.
Auxiliary agent D of the present invention is one or more in solidifying agent, curing catalyst, pigment, dyestuff, releasing agent, coupling agent, dispersion agent, stream auxiliary agent, photosensitizers, UV light absorber, the oxidation inhibitor.
The using method of antibacterial antimildew surface decorative material of the present invention comprises the steps:
(1) each component of surface decoration material is mixed;
(2) above-mentioned materials is flooded/coats decorated surface;
(3) decorated surface is solidified.
The present invention also comprises the following step of implementing at first:
Elder generation loads on the wear resistance uniform filling and forms abrasion-proof paper on the paper, then other component of material is evenly flooded/is coated on to form bond paper on the abrasion-proof paper.Carrying out above-mentioned three steps then.
Advantage of the present invention is as follows:
The present invention is directed to China and strengthen wood floors at present, kitchen cabinet and dining table production technology and the deficiency of using present situation, the combination with decorative surfaces material with antibacterial and mouldproof characteristic that adopts antibacterial and mouldproof sexual function filler filled high polymer matrix resin to be constituted is made the antibacterial and mouldproof laminated flooring, kitchen cabinet and dining table plane materiel, do not influencing existing laminated flooring, the surperficial high-wearing feature of kitchen cabinet and dining table, the anti-calcination in surface, natural woody texture is ornamental (does not promptly influence its surface color on the surface, pattern stability) and on the basis of comprehensive physical and chemical performance, give common laminated flooring, kitchen cabinet and dining table surface are efficient, wide spectrum, for a long time, the mildew-resistant of safety, antibiotic and bactericidal property, thereby can will stain on the floor, the lip-deep bacterium of kitchen cabinet and dining table, microorganisms such as mould (was standard with contact in 24 hours) within a certain period of time kill or suppress its propagation, keep self clean state, with the chemistry and the physical disinfection method (sterilizing agent that use routine, ray or high temperature) compare, not only economy but also convenient, and can avoid the floor, the secondary pollution on kitchen cabinet and dining table surface.
Antiseptic-germicide commonly used generally can be divided into organic anti-bacterial and inorganic antiseptic two big classes.Organic antibacterial agent has quaternary ammonium salts, biguanides, alcohols, phenols, organo-metallic class, pyridines, imidazoles, thiophene-based etc., its mechanism of action mainly is to combine with the surface of cell membrane negatively charged ion of bacterium and mould, or react with sulfenyl, destroy the synthesis system of albuminous cell film, suppress the breeding of bacterium and mould.The sterilization of organic antibacterial agent short-term, fungistatic effect are obvious, but duration of efficacy weak point, facile hydrolysis and temperature tolerance are poor, generally 200 ℃ with interior use, easy decomposition failure to the high temperature that makes it at many macromolecular materials, high pressure, the high-shear processing conditions, its degradation production even poisonous, life-time service has and phenomenon such as melts, separate out, therefore have toxicity, security is relatively poor, can produce microorganism resistance rerum natura, poor chemical stability, shortcomings such as poor heat resistance.Equally, natural organic class antiseptic-germicide (chitosan) just begins charing at 150～180 ℃ and decomposes, and range of application is narrow.
Consider that from processibility, ageing and security inorganic antiseptic has bigger application space.Inorganic antiseptic mainly is will the silver of human body safety, copper, zinc etc. itself to be had the metal of antibacterial ability or metal ion are carried on (as zeolite, phosphoric acid salt, hydroxyapatite, silica gel, soluble glass, montmorillonite, titanium dioxide etc.) on some inorganic matter carrier and the inorganic antibiosis powder made is antibiotic long-lasting to improve by the slow releasing function of carrier.Therefore, inorganic antiseptic has long-lasting (can accomplish with the work-ing life of goods synchronous), security, do not produce advantage such as resistance rerum natura, and outstanding especially is thermotolerance very good (＞600 ℃), but work range is wide.When the inorganic antiseptic powder is dispersed in the macromolecule matrix, can constantly move to product surface lentamente, the contained antibacterial metal ions that comes out by the carrier slowly-releasing comes the growth and breeding of contact sterilization or inhibition bacterium.Its anti-microbial effect mechanism is: when antibiotic ion from carrier after the stripping, with sulfenyl (SH), the amido (NH in bacterium or the fungal cell
2), (the organized enzyme loss of activity that some bacteriums are depended on for existence is had an effect in reaction such as COOH) to hydroxyl with the intravital protein of cell, impede protein matter synthetic carries out and energy derive, and then metabolism is obstructed, suppress the breeding of cell, and and then killing bacteria.In above-mentioned mineral ion, the antimicrbial power of silver ions is the strongest, but its chemical property is active, easily changes brown silver suboxide into or is reduced into the simple substance silver of black through ultraviolet catalytic, has not only reduced germ resistance, but also will influence the outward appearance of goods.
The present invention is according to above-mentioned material compositing formula and prepared novel antibacterial mildew-resistant laminated flooring, kitchen cabinet and the dining table plane materiel etc. of manufacturing process, remove antibacterial and mouldproof and have efficiently, wide spectrum, long-acting (persistence is good), nontoxic, free from extraneous odour, environment is not had outside the characteristics such as influence, the coupling of selected antiseptic-germicide and macromolecule matrix and other filler, consistency are good, do not influence colour stability, curing characteristic and light, heat and the chemical stability etc. of this surfacing; The workability of the antibacterial and mouldproof material that is obtained is good, and has than nominal price; The performance of the finished product reaches corresponding national standards or company standard.
Description of drawings:
Fig. 1 is the long-lasting test chart of antibacterial and mouldproof.
Embodiment:
Floor, kitchen cabinet and dining table surfacing with antibacterial and mouldproof characteristic of the present invention is made of antibacterial and mouldproof sexual function filler filled high polymer matrix resin.Particularly, this surfacing with antibacterial and mouldproof characteristic contains macromolecule matrix Resin A, antibacterial and mouldproof sexual function filler B, wear resistance filler C and other auxiliary agent D.Its prescription is as shown in the table: embodiment 1 composition A1 B1 C D
Consumption (part) 100 0.5 35 1.8 embodiment 2 composition A1 B2 C D
Consumption (part) 100 1.0 45 1.0 embodiment 3 composition A1 B3 C D
Consumption (part) 100 2.0 65 0.5 embodiment 4 composition A1 B4 C D
Consumption (part) 100 4.5 25 1.8 embodiment 5 composition A1 B5 C D
Consumption (part) 100 1.5 36 1.8 embodiment 6 composition A1 B6 C D
Consumption (part) 100 1.0 36 6.5 embodiment 7 composition A1 B7 C D
Consumption (part) 100 1.0 36 1.8 embodiment 8 composition A1 B3 C D
Consumption (part) 100 1.5 25 0.5 is annotated: embodiment 1～7 adopts the 1st kind of dipping/coating method, and embodiment 8 adopts the 2nd kind of dipping/coating method.
The present invention does not have particular restriction to the macromolecule matrix resin, as long as can (comprise that thermofixation, chemosetting, photocuring, electron beam irradiation solidify, Co by solidifying
60Hardening with radiation, ultrasonic irradiation curing etc.) and the macromolecule resin of making the combination with decorative surfaces material all can adopt.Macromolecule matrix resin commonly used has: aminoresin, as pure melamine-formaldehyde impregnating resin, cyanurotriamide modified phenolic impregnated resin, urea-modified carbamide solvent impregnated resin, phenol-modified urea solvent impregnated resin, urea-formaldehyde impregnating resin etc.; Urethane resin, Resins, epoxy, (methyl) acrylic copolymer resin, unsaturated polyester etc.
The macromolecule matrix resin properties is as follows in this example:
The free aldehyde of essential property numbering kind name of an article solids content viscosity
(%) (20 ℃, cps) the polymer-based aminoresin 30 of content (%) A1～60 10～150＜1.0
The body resin
Antibacterial and mouldproof sexual function filler is called antiseptic-germicide again, is meant the material that can kill microorganism or suppress microbial reproduction.These microorganisms comprise bacterium, fungi, mould, pure female bacterium and algae and virus etc.Its kind is as shown in the table:
Antibacterial and mouldproof sexual function filling property
The main antibiotic body physical condition median size silver content of matrix properties numbering kind
(% by weight) B1 antiseptic zinc, copper/inorganic salts white fluffy powder 2～4 μ m-B2 antiseptics silver zinc/phosphate pale yellow powder 30nm-B3 antiseptic silver zinc/zeolite white powder 30nm～2 μ m-B4 antiseptics silver zinc/phosphate white powder 1.3 μ m 3.0B5 antiseptic silver/silicon dioxide white powder＜90nm 3.4B6 antiseptic silver/silicon dioxide white powders＜80nm 2.0B7 antiseptic silver zinc/titanium dioxide white powder＜0.4 μ m-
The wear resistance filler is mainly given high-wearing feature, high rigidity (scratch resistance trace), anti-ablation (resistance incendivity), chemical resistance (easy to clean) of laminated flooring, kitchen cabinet and dining table surface decoration material etc.Wear resistance powder filler commonly used mainly contains aluminium sesquioxide and (comprises α-Al
2O
3And r-Al
2O
3Two kinds of crystal formations), lapis amiridis (contains α-Al
2O
3Measure high mineral), (composition is xAl to mullite
2O
3YSiO
2), silicon carbide (claim silicon carbide again, comprise two kinds of crystal formations of α-SiC and β-SiC), silicon nitride (comprises α-Si
3N
4And β-Si
3N
4Two kinds of crystal formations) etc.Preferably select aluminium sesquioxide and silicon carbide for use, its median size is divided into 5～100 μ m, two class of 10～500 μ m.Above-mentioned wear resistance filler can use separately, but also two or more mix use.
In the present invention, except above-mentioned various components, can also add an amount of other auxiliary agent D, as solidifying agent, curing catalyst, pigment or dyestuff, releasing agent, coupling agent, dispersion agent, flowing agent, photosensitizers, ultraviolet radiation absorption is outer, oxidation inhibitor waits comprehensive adjustment material of the present invention processing or use properties.
It is (to comprise that laminated mold pressing thermofixation, ultraviolet light polymerization, electron beam irradiation solidify, Co by above-mentioned antibacterial and mouldproof combination with decorative surfaces material compositions through mixing (dispersion), dipping/coating (comprising spraying, roller coat and showering), dry (Procuring), curing molding that combination with decorative surfaces material with antibacterial and mouldproof of the present invention is applied to antibacterial and mouldproof laminated flooring, kitchen cabinet and dining table plane materiel
60Hardening with radiation, ultrasonic irradiation curing etc.) etc. step and finish using method.Wherein, difference according to wear resistance filler component addition manner, follow-up dipping/coating process can be divided into again: (1) loads on the wear resistance uniform filling earlier and forms so-called abrasion-proof paper on the overlay paper, then other component of antibacterial and mouldproof combination with decorative surfaces material is evenly flooded/is coated on this abrasion-proof paper, form wear-resisting bond paper; (2) will comprise all components uniform mixing of the antibacterial and mouldproof combination with decorative surfaces material of wear resistance filler component earlier, and then it evenly be flooded/be coated on decorated the surface.
The long-lasting test-results of antibacterial and mouldproof of the present invention as shown in Figure 1.
The present invention and the surface decoration material that does not contain antiseptic-germicide (other component is identical, reference examples 1:A1:100, and C:45, performance synopsis D:1.8) is as follows:
The present invention is as follows as the performance of laminated flooring, kitchen cabinet and dining table surface decoration material:
The anti-variable color of anti-microbial property experiment escherichia coli and staphylococcus aureus fungicidal properties surface surface sample colony number antibiotic rate colony number antibiotic rate (mildew grade) wear resistance
(* 10
3Cfu/ml) (%) (* 10
3Cfu/ml) (%) (turn to) shallow white embodiment 80 100 0 100 0＞6000 nondiscolourings of reference examples 1 425-206-2＞6000 nondiscolouring embodiment 1 149 64.9 29 85.9 1＞6000 nondiscolouring embodiment 21 99.8 0 100 1＞6000 nondiscolouring embodiment 30 100 0 100 0＞6000 nondiscolouring embodiment 4------silver black embodiment 5------brownish black embodiment 6------taupe embodiment 7------
Claims (11)
1, antibacterial antimildew surface decorative material is characterized in that comprising following component and consumption: weight part
A: macromolecule matrix resin 100
B: antiseptic-germicide 0.1～5
C: wear resistance filler: 0～70
D: auxiliary agent: 0～10
2, material according to claim 1 is characterized in that said antiseptic-germicide comprises inorganic antiseptic, and its component and consumption are: weight part
Inorganic antiseptic 70～100
Organic antibacterial agent 0～30.
3, material according to claim 1 and 2 is characterized in that said inorganic antiseptic is that independent silver ions is carried on the inorganic matter carrier and the powder of making.
4, material according to claim 3 is characterized in that inorganic antiseptic comprises also that zine ion or cupric ion are carried on the inorganic matter carrier and the powder of making.
5, material according to claim 4, it is characterized in that silver ions, zine ion, cupric ion is a coordination ion, the carrier of antiseptic-germicide is zeolite, phosphoric acid salt, hydroxyapatite, silica gel, soluble glass, montmorillonite, in the titanium dioxide one or more mix use, and the median size of carrier is 0.1～10 μ m; Preferred median size is 10～2000nm.
6, material according to claim 1 and 2 is characterized in that said macromolecule matrix resin is curable macromolecule resin.
7, material according to claim 1 is characterized in that the wear resistance filler is the multiple mixture of a kind of formula in aluminium sesquioxide, lapis amiridis, mullite, silicon carbide, the silicon nitride.
8, material according to claim 7 is characterized in that the wear resistance filler is one or both mixing uses in aluminium sesquioxide, the silicon carbide, and its median size is 5～100 μ m, preferred 10-500nm.
9, material according to claim 1 is characterized in that auxiliary agent D is one or more in solidifying agent, curing catalyst, pigment, dyestuff, releasing agent, coupling agent, dispersion agent, flowing agent, photosensitizers, UV light absorber, the oxidation inhibitor.
10, the using method of antibacterial antimildew surface decorative material comprises the steps:
(1) each component of surface decoration material is mixed;
(2) above-mentioned materials is flooded/coats decorated surface;
(3) decorated surface is solidified.
11, using method according to claim 10 is characterized in that also comprising the following step of implementing at first:
(1) elder generation loads on the wear resistance uniform filling and forms abrasion-proof paper on the paper,
(2) then other component of material is evenly flooded/is coated on and form bond paper on the abrasion-proof paper, described decorated body is a bond paper.
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| CN 01128990 CN1118525C (en) | 2001-10-25 | 2001-10-25 | Antibacterial antimildew surface decorative material and its application method |
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|---|---|---|---|
| CN 01128990 CN1118525C (en) | 2001-10-25 | 2001-10-25 | Antibacterial antimildew surface decorative material and its application method |
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| CN1118525C CN1118525C (en) | 2003-08-20 |
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| CN100374519C (en) * | 2005-07-29 | 2008-03-12 | 西南交通大学 | Antibacterial surface decorative material and its preparation method |
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| CN104804361A (en) * | 2014-01-28 | 2015-07-29 | 深圳齐心集团股份有限公司 | Antibacterial resin composite material and preparation method thereof |
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| CN110330693A (en) * | 2019-07-30 | 2019-10-15 | 安徽正合雅聚新材料科技有限公司 | The antibacterial polymer and preparation method thereof of one metal ion species enhancing |
| CN110527329A (en) * | 2019-08-08 | 2019-12-03 | 深圳航天科技创新研究院 | A kind of anti-algae zinc-rich anti-corrosive paint of inorganic graphite alkene antibacterial and preparation method thereof |
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| CN111040477A (en) * | 2019-11-27 | 2020-04-21 | 惠州学院 | Dry powder coating with lasting antibacterial and mildew-proof effects and preparation method thereof |
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