CN1332643C - Solid bathing agent composition - Google Patents
Solid bathing agent composition Download PDFInfo
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- CN1332643C CN1332643C CNB031533353A CN03153335A CN1332643C CN 1332643 C CN1332643 C CN 1332643C CN B031533353 A CNB031533353 A CN B031533353A CN 03153335 A CN03153335 A CN 03153335A CN 1332643 C CN1332643 C CN 1332643C
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- China
- Prior art keywords
- acid
- fumaric acid
- solid
- baths
- carbonate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
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- 239000000203 mixture Substances 0.000 title claims abstract description 34
- 239000007787 solid Substances 0.000 title claims abstract description 32
- 238000003287 bathing Methods 0.000 title description 31
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 claims abstract description 64
- 239000001530 fumaric acid Substances 0.000 claims abstract description 32
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 claims abstract description 32
- BJEPYKJPYRNKOW-UHFFFAOYSA-N alpha-hydroxysuccinic acid Natural products OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 claims abstract description 25
- 239000001630 malic acid Substances 0.000 claims abstract description 25
- 235000011090 malic acid Nutrition 0.000 claims abstract description 25
- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 claims abstract description 24
- 150000007524 organic acids Chemical class 0.000 claims abstract description 11
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims abstract description 9
- 239000003814 drug Substances 0.000 abstract 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 26
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 24
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 23
- 238000000034 method Methods 0.000 description 14
- 229910000029 sodium carbonate Inorganic materials 0.000 description 13
- 235000017550 sodium carbonate Nutrition 0.000 description 13
- 238000004519 manufacturing process Methods 0.000 description 12
- 235000017557 sodium bicarbonate Nutrition 0.000 description 12
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 12
- 235000013599 spices Nutrition 0.000 description 12
- 239000000049 pigment Substances 0.000 description 10
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 9
- 230000000052 comparative effect Effects 0.000 description 9
- 230000035807 sensation Effects 0.000 description 9
- 229910052938 sodium sulfate Inorganic materials 0.000 description 9
- 235000011152 sodium sulphate Nutrition 0.000 description 9
- 239000003921 oil Substances 0.000 description 8
- 235000019198 oils Nutrition 0.000 description 8
- KDYFGRWQOYBRFD-UHFFFAOYSA-N succinic acid Chemical compound OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 8
- 238000011156 evaluation Methods 0.000 description 7
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 6
- 229940093429 polyethylene glycol 6000 Drugs 0.000 description 6
- 238000007667 floating Methods 0.000 description 5
- 238000002360 preparation method Methods 0.000 description 5
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- 239000006260 foam Substances 0.000 description 4
- 229940073490 sodium glutamate Drugs 0.000 description 4
- 239000001384 succinic acid Substances 0.000 description 4
- 230000000694 effects Effects 0.000 description 3
- 229910052943 magnesium sulfate Inorganic materials 0.000 description 3
- 235000019341 magnesium sulphate Nutrition 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- OWEGMIWEEQEYGQ-UHFFFAOYSA-N 100676-05-9 Natural products OC1C(O)C(O)C(CO)OC1OCC1C(O)C(O)C(O)C(OC2C(OC(O)C(O)C2O)CO)O1 OWEGMIWEEQEYGQ-UHFFFAOYSA-N 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- GUBGYTABKSRVRQ-PICCSMPSSA-N Maltose Natural products O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@@H]1O[C@@H]1[C@@H](CO)OC(O)[C@H](O)[C@H]1O GUBGYTABKSRVRQ-PICCSMPSSA-N 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 239000000314 lubricant Substances 0.000 description 2
- HQKMJHAJHXVSDF-UHFFFAOYSA-L magnesium stearate Chemical compound [Mg+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O HQKMJHAJHXVSDF-UHFFFAOYSA-L 0.000 description 2
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 2
- 239000001103 potassium chloride Substances 0.000 description 2
- 235000011164 potassium chloride Nutrition 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 238000007493 shaping process Methods 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- 235000012239 silicon dioxide Nutrition 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 230000009182 swimming Effects 0.000 description 2
- 235000020357 syrup Nutrition 0.000 description 2
- 239000006188 syrup Substances 0.000 description 2
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 2
- 229920003169 water-soluble polymer Polymers 0.000 description 2
- ATRRKUHOCOJYRX-UHFFFAOYSA-N Ammonium bicarbonate Chemical compound [NH4+].OC([O-])=O ATRRKUHOCOJYRX-UHFFFAOYSA-N 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- UIIMBOGNXHQVGW-DEQYMQKBSA-M Sodium bicarbonate-14C Chemical compound [Na+].O[14C]([O-])=O UIIMBOGNXHQVGW-DEQYMQKBSA-M 0.000 description 1
- 229940024606 amino acid Drugs 0.000 description 1
- 235000001014 amino acid Nutrition 0.000 description 1
- 150000001413 amino acids Chemical class 0.000 description 1
- 239000001099 ammonium carbonate Substances 0.000 description 1
- 235000012501 ammonium carbonate Nutrition 0.000 description 1
- 239000000440 bentonite Substances 0.000 description 1
- 229910000278 bentonite Inorganic materials 0.000 description 1
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 description 1
- 239000001095 magnesium carbonate Substances 0.000 description 1
- 229910000021 magnesium carbonate Inorganic materials 0.000 description 1
- 235000014380 magnesium carbonate Nutrition 0.000 description 1
- 235000019359 magnesium stearate Nutrition 0.000 description 1
- 150000004701 malic acid derivatives Chemical class 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000003605 opacifier Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000011736 potassium bicarbonate Substances 0.000 description 1
- 235000015497 potassium bicarbonate Nutrition 0.000 description 1
- 229910000028 potassium bicarbonate Inorganic materials 0.000 description 1
- 229910000027 potassium carbonate Inorganic materials 0.000 description 1
- 235000011181 potassium carbonates Nutrition 0.000 description 1
- TYJJADVDDVDEDZ-UHFFFAOYSA-M potassium hydrogencarbonate Chemical compound [K+].OC([O-])=O TYJJADVDDVDEDZ-UHFFFAOYSA-M 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000009702 powder compression Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 229910000031 sodium sesquicarbonate Inorganic materials 0.000 description 1
- 235000018341 sodium sesquicarbonate Nutrition 0.000 description 1
- RSIJVJUOQBWMIM-UHFFFAOYSA-L sodium sulfate decahydrate Chemical compound O.O.O.O.O.O.O.O.O.O.[Na+].[Na+].[O-]S([O-])(=O)=O RSIJVJUOQBWMIM-UHFFFAOYSA-L 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 235000012424 soybean oil Nutrition 0.000 description 1
- 239000003549 soybean oil Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- WCTAGTRAWPDFQO-UHFFFAOYSA-K trisodium;hydrogen carbonate;carbonate Chemical compound [Na+].[Na+].[Na+].OC([O-])=O.[O-]C([O-])=O WCTAGTRAWPDFQO-UHFFFAOYSA-K 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
Landscapes
- Cosmetics (AREA)
Abstract
Provided is a solid bath medicine composition having good forming property and moisture feeling in use, and good surface state in a bath.The solid bath medicine composition contains an organic acid and a carbonate, and a mixture of malic acid and fumaric acid is used as the organic acid and the content of fumaric acid is 2-10 mass% of the total composition.
Description
Technical field
The present invention relates to the solid bath oil composition, specifically, relate to that the fumaric acid, the formability that contain carbonate and malic acid and 2～10 quality % are good, bathing sense with moistening, the solid bath oil composition of bathing water surface state excellence when producing foam.
Background technology
Known mixing in the past the effect of the solid bath oil composition of organic acid plus carbonate (below be called " solid baths ") by carbon dioxide can reach the effect that temperature is bathed, can increase bathing enjoyment by producing foam, and make various goods.As the organic acid that uses in this solid baths, known have a variety ofly, and wherein the formability of fumaric acid and succinic acid is good, but produce insoluble matter easily in bathing water when using fumaric acid, and succinic acid problem such as allow that user suffocates.
On the other hand, though malic acid has the bathing sense effect that can obtain being known as moistening, its formability is not fine, has the problem that is easy to generate obstacle when tabletting.Particularly when making the blocks of solid bath oil composition, use malic acid, make preparation stick to problem on the in bulk mechanical roller easily.
Though use lubricants such as polyethylene glycol 6000, Pulvis Talci, magnesium stearate to improve formability, prevented obstacle in the manufacture process generation of above-mentioned lamellar or blocks, but the solid baths that uses above-mentioned lubricant in putting into bathing water after, have on the surface of bathing water and blister occurs, and the problem that the phenomenon of floating insoluble matter occurs and allow user feel under the weather.
Summary of the invention
The solid baths that the purpose of this invention is to provide usability with excellent formability, moistening and good bathing water surface state.
Present inventors are in order to address the above problem, carried out careful research, discovery with malic acid and fumaric acid as the organic acid in the solid baths, and be used in combination according to a certain percentage, can obtain formability solid baths very excellent, that can give user moistening bathing sense, the apparent condition excellence of bathing water when producing foam, thereby finish the present invention.
Promptly the present invention relates to contain the solid bath oil composition of organic acid plus carbonate, the mixture that it is characterized by use malic acid and fumaric acid is as organic acid, and the content of fumaric acid is 2～10 quality % of total composition.
Solid baths of the present invention has good formability, the usability of moistening, and the bathing water surface is in good condition in use.
Concrete form of implementation
In this description, bulk is meant shapes such as pillow, prism-like, amygdaloidal, prism-shaped, bar-shaped, finger-like.These bulks can be carried out processing and forming with powder composition with pelletize machinery and be obtained.
In the solid baths of the present invention, the mixture that uses malic acid and fumaric acid is as the organic acid that carbonate is foamed in bathing.
Wherein the mean diameter that can select malic acid by sieve method is in the scope of 100 μ m～1mm, but considers its formability, in the scope particularly preferably in 300～500 μ m.The use amount of this malic acid is preferably 20～40 quality % (following simple for " % "), and more preferably 25～40%.The use amount of described malic acid is lower than the following of described scope can not provide wetness sensation in limited time, and surpasses going up in limited time of described scope, has the problem of stability.
In addition, the use amount of the fumaric acid in the solid baths of the present invention is 2～10%.If use amount exceeds the upper limit of described scope, described baths in putting into bathing water after, produce foamy strength fumaric acid is floated, the surface of bathing water be felt under the weather by can be allowed the bather by severe contamination.It is bigger to produce foamy strength when particularly baths is for bulk, and this phenomenon is more remarkable.In addition, if the use amount of fumaric acid is lower than the lower limit of described scope, preparation can takes place during manufacturing stick on the forming device, can not improve formability.In addition, when using 7～10% fumaric acid, formability is excellent especially.
Malic acid and fumaric acid can be by the scope proportionings of above-mentioned use amount, and preferably its proportioning is 20:1～2: 1, more preferably 5: 1～3: 1.
Also contain carbonate in the solid baths of the present invention.The carbonate that uses is had no particular limits, can enumerate sodium carbonate, sodium bicarbonate, sodium sesquicarbonate, potassium carbonate, potassium bicarbonate, magnesium carbonate, ammonium carbonate etc., wherein preferred especially sodium carbonate, sodium bicarbonate as preferred example.
With respect to the solid baths, the use amount of this carbonate is preferably 20～60%, and more preferably 30～50%.Use amount can not foam beyond described scope fully.
In the solid bath oil composition of the present invention, except that above-mentioned each composition, can also suitably add the selectivity composition as required, for example aminoacid, wetting agent, solvents etc. such as inorganic salts such as stabilizing agent such as plant component, silicon dioxide, spice, coloring agent, Natrii Sulfas, oiliness composition, opacifiers, NaAsp.
Shape to solid bath oil composition of the present invention has no particular limits, and can enumerate lamellar, bulk etc.Because required pressure is lower during block the shaping, can improve formability, so preferred especially block.
Be example below with the bulk, the manufacture method of solid baths of the present invention is described.
At first, fully mix, obtain mixture with organic acid (blended malic acid and fumaric acid), carbonate with according to the selectivity composition of purpose needs.Then, with this mixture by pelletize machinery with desirable shape, for example pillow, prism-like, Fructus Pruni shape, prism-shaped, bar-shaped, finger-like etc. are made about 0.01cm
3～20cm
3The bulk of volume.
In addition, pelletize machinery is a kind of dry type compression comminutor that utilizes 2 opposite roll shafts of identical speed, direction of rotation with the material powder compression forming, and the depression of block parent form is carved with on the surface of this roll shaft.By shape, the size that changes this depression, can obtain the blocks of difformity, size.Usually in the process of making blocks, obtain the plates of once-forming by the size of adjusting gap between the roll shaft, the pressure between the roll shaft, the pressure of feed screw.Blocks can obtain by the plates of further decomposition once-forming, and the plates of described once-forming are that several blocks of particles form flaky once-forming plates by connecting portion.
Embodiment
Below specifically describe the present invention based on embodiment, but the invention is not restricted to these embodiment.
Embodiment 1～4, comparative example 1～5
With the raw material 5kg mixing of multi-functional stirring mixer, make the block baths of 3～6mm then with in bulk machinery with prescription shown in following table 1 and the table 2.
Implement evaluation test as follows, to the block formability of these solid bathses, use its sensation of bathing water and the state of bathing water surface to estimate.Its result as shown in Table 1 and Table 2.
(evaluation of the formability of piece)
Perusal, preparation sticks to the degree on the piece shaping mechanical roller when making with 3 standard evaluations.
Evaluation content:
◎: do not adhere to zero: do not adhere to substantially, *: adhere to
Do not use the adhesion of comparative example 1～4 on roller of fumaric acid more as can be seen, use the embodiment 1～4 and the comparative example 5 of fumaric acid to have good formability.Particularly the formability of embodiment 1,4 and comparative example 5 is better.
(sensation of bathing water)
The about 30g of each solid baths is put in the 200L bathing water, by following standard evaluation use feeling.
Evaluation content
Zero: the sensation of moistening is arranged, *: the sensation that does not have moistening
Comparative example 5 does not have the sensation of moistening, and embodiment 1～4, comparative example 1～4 show good wet sensation.
(state of bathing water surface)
The about 30g of each solid baths is put in the 200L bathing water, and perusal is with the state of 3 standard evaluation bathing water surfaces.
◎: do not have floating thing, zero: floating thing is few, *: floating thing is many, produces uncomfortable feeling.
The comparative example 5 of the fumaric acid of use 15% can be seen a lot of floating things, and the apparent condition of bathing water is bad, and embodiment 1～4 and comparative example 1～4 have all shown good bathing water surface state.The better off of embodiment 2 and embodiment 3.
Embodiment 1～4 has good formability, and good bathing talent for swimming is felt and good bathing water surface state.
Table 1
| Embodiment | ||||
| Composition | 1 | 2 | 3 | 4 |
| Malic acid | 30 | 30 | 25 | 40 |
| Fumaric acid | 8 | 5 | 2 | 10 |
| Sodium bicarbonate | 31 | 25 | 16 | 37 |
| Sodium carbonate | 12 | 12 | 12 | 12 |
| Sodium sulfate | 18 | 27 | 44 | 0 |
| Spice | 1 | 1 | 1 | 1 |
| Pigment | Trace | Trace | Trace | Trace |
| Formability | ◎ | ○ | ○ | ◎ |
| Wet sensation | ○ | ○ | ○ | ○ |
| Bathing water surface state | ○ | ◎ | ◎ | ○ |
Table 2
| Comparative example | |||||
| Composition | 1 | 2 | 3 | 4 | 5 |
| Malic acid | 30 | 38 | 39 | 25 | 15 |
| Fumaric acid | - | - | 1 | - | 15 |
| Sodium bicarbonate | 18 | 29 | 31 | 12 | 22 |
| Sodium carbonate | 12 | 12 | 12 | 12 | 12 |
| Sodium sulfate | 39 | 20 | 16 | 50 | 35 |
| Spice | 1 | 1 | 1 | 1 | 1 |
| Pigment | Trace | Trace | Trace | Trace | Trace |
| Formability | × | × | × | × | ◎ |
| Wet sensation | ○ | ○ | ○ | ○ | × |
| Bathing water surface state | ○ | ○ | ○ | ○ | × |
Embodiment 5
Lamellar
With the raw material 5kg mixing of multi-functional stirring mixer, with single punch tablet machine this mixture is made the lamellar baths of diameter 50mm, thick 15mm then with following prescription.
Malic acid 34%
Fumaric acid 3
Sodium bicarbonate 28
Sodium carbonate 15
Sodium sulfate 16
Potassium chloride 3
Spice 1
The pigment trace
Embodiment 6
Block
Use following proportioning to form, obtain block baths by the manufacture method of embodiment 1.
Malic acid 34%
Fumaric acid 8
Sodium bicarbonate 31
Sodium carbonate 15
Magnesium sulfate 2
Sodium sulfate 7.5
L-sodium glutamate 1
Polyethylene glycol 6000 0.5
Spice 1
The pigment trace
Embodiment 7
Block
Use following proportioning to form, obtain block baths by the manufacture method of embodiment 1.
Malic acid 34%
Fumaric acid 5
Sodium bicarbonate 30
Sodium carbonate 15
Sodium sulfate 12
Reduction maltose syrups 3
Spice 1
The pigment trace
Embodiment 8
Lamellar
Use following proportioning to form, obtain the lamellar baths by the manufacture method of embodiment 5.
Malic acid 25%
Fumaric acid 8
Succinic acid 8
Sodium bicarbonate 31
Sodium carbonate 15
Magnesium sulfate 2
Sodium sulfate 8.2
L-sodium glutamate 1
Polyethylene glycol 6000 0.5
Silicon dioxide 0.3
Spice 1
The pigment trace
Embodiment 9
Block
Use following proportioning to form, obtain block baths by the manufacture method of embodiment 1.
Malic acid 25%
Fumaric acid 5
Sodium bicarbonate 20
Sodium carbonate 15
Sodium sulfate 31
Potassium chloride 3
Spice 1
The pigment trace
Embodiment 10
Block
Use following proportioning to form, obtain block baths by the manufacture method of embodiment 1.
Malic acid 29%
Fumaric acid 8
Succinic acid 3
Sodium bicarbonate 34
Sodium carbonate 15
Sodium chloride 5
L-sodium glutamate 2
Polyethylene glycol 6000 0.5
Titanium oxide water soluble polymer coating thing
*2.5
Soybean oil 0.3
Spice 0.7
The pigment trace
*Open the method preparation of clear 63-57516 number record according to the spy.
Embodiment 11
Block
Use following proportioning to form, obtain block baths by the manufacture method of embodiment 1.
Malic acid 30%
Fumaric acid 8
Sodium bicarbonate 30
Sodium carbonate 20
China clay 3
Bentonite 3
Titanium oxide water soluble polymer coating thing
*5
Polyethylene glycol 6000 0.5
Spice 0.5
*Open the method preparation of clear 63-57516 number record according to the spy.
Embodiment 12
Block
Use following proportioning to form, obtain block baths by the manufacture method of embodiment 1.
Malic acid 30%
Fumaric acid 3
Sodium bicarbonate 20
Sodium carbonate 15
Sodium sulfate 26
Reduction maltose syrups 5
Spice 1
The pigment trace
Embodiment 13
Block
Use following proportioning to form, obtain block baths by the manufacture method of embodiment 1.
Malic acid 39%
Fumaric acid 3
Sodium bicarbonate 31
Sodium carbonate 15
Magnesium sulfate 2
Sodium sulfate 7.5
L-sodium glutamate 1
Polyethylene glycol 6000 0.5
Spice 1
The pigment trace
The solid baths that embodiment 5～13 obtains (lamellar or bulk) has good formability, and good bathing talent for swimming is felt and good bathing water surface state.
Solid baths of the present invention has good formability during fabrication, and it gives the usability of skin moistening in use, and the apparent condition of bathing water is fine.Therefore, can be used as the solid baths is extensive use of.
Claims (3)
1. contain the solid bath oil composition of organic acid plus carbonate, it is characterized by, the mixture that uses malic acid and fumaric acid is as organic acid, and the content of fumaric acid is 2～10 quality % of total composition.
2. solid bath oil composition as claimed in claim 1, wherein the mixed proportion of malic acid and fumaric acid is 20: 1～2: 1.
3. solid bath oil composition as claimed in claim 1 or 2, said composition is a bar composition.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2002231421 | 2002-08-08 | ||
| JP231421/2002 | 2002-08-08 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1483396A CN1483396A (en) | 2004-03-24 |
| CN1332643C true CN1332643C (en) | 2007-08-22 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB031533353A Expired - Fee Related CN1332643C (en) | 2002-08-08 | 2003-08-07 | Solid bathing agent composition |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1332643C (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| TWI724994B (en) * | 2014-12-22 | 2021-04-21 | 日商花王股份有限公司 | Solid foaming bath agent for foot bath |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP5877778B2 (en) * | 2012-05-28 | 2016-03-08 | 株式会社ホットアルバム炭酸泉タブレット | Tablet manufacturing method and tablet |
| CN104771328A (en) * | 2015-04-02 | 2015-07-15 | 芜湖美的厨卫电器制造有限公司 | Carbonate spring tablet and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS56164110A (en) * | 1980-05-20 | 1981-12-17 | Mitsubishi Chem Ind Ltd | Foaming bath liquid |
| JPS5970609A (en) * | 1982-10-14 | 1984-04-21 | Kao Corp | Weakly acidic bathing agent |
| US5198144A (en) * | 1988-04-01 | 1993-03-30 | Kao Corporation | Bathing preparation |
| JPH05262691A (en) * | 1992-03-19 | 1993-10-12 | Nippon Shokubai Co Ltd | Production of fumaric acid |
-
2003
- 2003-08-07 CN CNB031533353A patent/CN1332643C/en not_active Expired - Fee Related
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS56164110A (en) * | 1980-05-20 | 1981-12-17 | Mitsubishi Chem Ind Ltd | Foaming bath liquid |
| JPS5970609A (en) * | 1982-10-14 | 1984-04-21 | Kao Corp | Weakly acidic bathing agent |
| US5198144A (en) * | 1988-04-01 | 1993-03-30 | Kao Corporation | Bathing preparation |
| JPH05262691A (en) * | 1992-03-19 | 1993-10-12 | Nippon Shokubai Co Ltd | Production of fumaric acid |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| TWI724994B (en) * | 2014-12-22 | 2021-04-21 | 日商花王股份有限公司 | Solid foaming bath agent for foot bath |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1483396A (en) | 2004-03-24 |
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