CN1326943C - 用于结构指形接合的双组分聚氨基甲酸酯粘合剂及其方法 - Google Patents
用于结构指形接合的双组分聚氨基甲酸酯粘合剂及其方法 Download PDFInfo
- Publication number
- CN1326943C CN1326943C CNB028272773A CN02827277A CN1326943C CN 1326943 C CN1326943 C CN 1326943C CN B028272773 A CNB028272773 A CN B028272773A CN 02827277 A CN02827277 A CN 02827277A CN 1326943 C CN1326943 C CN 1326943C
- Authority
- CN
- China
- Prior art keywords
- diisocyanate
- alcohol
- isocyanate
- emulsion
- prepolymer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000000034 method Methods 0.000 title claims abstract description 23
- 230000001070 adhesive effect Effects 0.000 title claims abstract description 22
- 239000000853 adhesive Substances 0.000 title claims abstract description 21
- 210000001145 finger joint Anatomy 0.000 title description 12
- 239000004814 polyurethane Substances 0.000 title description 7
- 229920002635 polyurethane Polymers 0.000 title description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 72
- 239000000839 emulsion Substances 0.000 claims abstract description 46
- 239000000203 mixture Substances 0.000 claims abstract description 44
- 239000002023 wood Substances 0.000 claims abstract description 39
- 229920000642 polymer Polymers 0.000 claims abstract description 24
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 19
- 239000012948 isocyanate Substances 0.000 claims abstract description 17
- 239000005056 polyisocyanate Substances 0.000 claims abstract description 17
- 229920001228 polyisocyanate Polymers 0.000 claims abstract description 17
- 150000002513 isocyanates Chemical class 0.000 claims abstract description 16
- 229920005862 polyol Polymers 0.000 claims abstract description 9
- 150000003077 polyols Chemical class 0.000 claims abstract description 9
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims abstract description 5
- 239000003795 chemical substances by application Substances 0.000 claims description 49
- -1 alcohol radical Chemical class 0.000 claims description 25
- 238000006243 chemical reaction Methods 0.000 claims description 23
- 239000011230 binding agent Substances 0.000 claims description 22
- 238000009692 water atomization Methods 0.000 claims description 20
- 239000007788 liquid Substances 0.000 claims description 17
- 239000011118 polyvinyl acetate Substances 0.000 claims description 17
- 239000005057 Hexamethylene diisocyanate Substances 0.000 claims description 15
- RRAMGCGOFNQTLD-UHFFFAOYSA-N hexamethylene diisocyanate Chemical compound O=C=NCCCCCCN=C=O RRAMGCGOFNQTLD-UHFFFAOYSA-N 0.000 claims description 15
- 229920002689 polyvinyl acetate Polymers 0.000 claims description 15
- 150000002148 esters Chemical class 0.000 claims description 14
- 239000004816 latex Substances 0.000 claims description 13
- 229920000126 latex Polymers 0.000 claims description 13
- 239000000126 substance Substances 0.000 claims description 13
- 229920002554 vinyl polymer Polymers 0.000 claims description 10
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 9
- NIMLQBUJDJZYEJ-UHFFFAOYSA-N isophorone diisocyanate Chemical compound CC1(C)CC(N=C=O)CC(C)(CN=C=O)C1 NIMLQBUJDJZYEJ-UHFFFAOYSA-N 0.000 claims description 9
- 238000003475 lamination Methods 0.000 claims description 9
- 239000005058 Isophorone diisocyanate Substances 0.000 claims description 8
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims description 8
- 229920006389 polyphenyl polymer Polymers 0.000 claims description 8
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 7
- 229920000570 polyether Polymers 0.000 claims description 7
- 229920001519 homopolymer Polymers 0.000 claims description 6
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 5
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 5
- 239000002174 Styrene-butadiene Substances 0.000 claims description 5
- 239000002253 acid Substances 0.000 claims description 5
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 claims description 5
- 239000013530 defoamer Substances 0.000 claims description 5
- 229920001038 ethylene copolymer Polymers 0.000 claims description 5
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 5
- 239000011115 styrene butadiene Substances 0.000 claims description 5
- 229920003048 styrene butadiene rubber Polymers 0.000 claims description 5
- DVKJHBMWWAPEIU-UHFFFAOYSA-N toluene 2,4-diisocyanate Chemical compound CC1=CC=C(N=C=O)C=C1N=C=O DVKJHBMWWAPEIU-UHFFFAOYSA-N 0.000 claims description 5
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 5
- MTZUIIAIAKMWLI-UHFFFAOYSA-N 1,2-diisocyanatobenzene Chemical compound O=C=NC1=CC=CC=C1N=C=O MTZUIIAIAKMWLI-UHFFFAOYSA-N 0.000 claims description 4
- ALQLPWJFHRMHIU-UHFFFAOYSA-N 1,4-diisocyanatobenzene Chemical compound O=C=NC1=CC=C(N=C=O)C=C1 ALQLPWJFHRMHIU-UHFFFAOYSA-N 0.000 claims description 4
- ZEMPKEQAKRGZGQ-AAKVHIHISA-N 2,3-bis[[(z)-12-hydroxyoctadec-9-enoyl]oxy]propyl (z)-12-hydroxyoctadec-9-enoate Chemical compound CCCCCCC(O)C\C=C/CCCCCCCC(=O)OCC(OC(=O)CCCCCCC\C=C/CC(O)CCCCCC)COC(=O)CCCCCCC\C=C/CC(O)CCCCCC ZEMPKEQAKRGZGQ-AAKVHIHISA-N 0.000 claims description 4
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 4
- IIGAAOXXRKTFAM-UHFFFAOYSA-N N=C=O.N=C=O.CC1=C(C)C(C)=C(C)C(C)=C1C Chemical compound N=C=O.N=C=O.CC1=C(C)C(C)=C(C)C(C)=C1C IIGAAOXXRKTFAM-UHFFFAOYSA-N 0.000 claims description 4
- 239000004698 Polyethylene Substances 0.000 claims description 4
- 230000002152 alkylating effect Effects 0.000 claims description 4
- 239000000460 chlorine Substances 0.000 claims description 4
- 229910052801 chlorine Inorganic materials 0.000 claims description 4
- PAFZNILMFXTMIY-UHFFFAOYSA-N cyclohexylamine Chemical compound NC1CCCCC1 PAFZNILMFXTMIY-UHFFFAOYSA-N 0.000 claims description 4
- HZVOZRGWRWCICA-UHFFFAOYSA-N methanediyl Chemical compound [CH2] HZVOZRGWRWCICA-UHFFFAOYSA-N 0.000 claims description 4
- AYLRODJJLADBOB-QMMMGPOBSA-N methyl (2s)-2,6-diisocyanatohexanoate Chemical compound COC(=O)[C@@H](N=C=O)CCCCN=C=O AYLRODJJLADBOB-QMMMGPOBSA-N 0.000 claims description 4
- 150000004702 methyl esters Chemical class 0.000 claims description 4
- 229920000573 polyethylene Polymers 0.000 claims description 4
- 229920001451 polypropylene glycol Polymers 0.000 claims description 4
- GETQZCLCWQTVFV-UHFFFAOYSA-N trimethylamine Chemical compound CN(C)C GETQZCLCWQTVFV-UHFFFAOYSA-N 0.000 claims description 4
- 239000008096 xylene Substances 0.000 claims description 4
- PAPBSGBWRJIAAV-UHFFFAOYSA-N ε-Caprolactone Chemical compound O=C1CCCCCO1 PAPBSGBWRJIAAV-UHFFFAOYSA-N 0.000 claims description 4
- OTEKOJQFKOIXMU-UHFFFAOYSA-N 1,4-bis(trichloromethyl)benzene Chemical compound ClC(Cl)(Cl)C1=CC=C(C(Cl)(Cl)Cl)C=C1 OTEKOJQFKOIXMU-UHFFFAOYSA-N 0.000 claims 3
- MKZPMOFOBNHBSL-UHFFFAOYSA-N 1-isocyanato-1-methylcyclohexane Chemical class O=C=NC1(C)CCCCC1 MKZPMOFOBNHBSL-UHFFFAOYSA-N 0.000 claims 3
- HDONYZHVZVCMLR-UHFFFAOYSA-N N=C=O.N=C=O.CC1CCCCC1 Chemical compound N=C=O.N=C=O.CC1CCCCC1 HDONYZHVZVCMLR-UHFFFAOYSA-N 0.000 claims 3
- KXBFLNPZHXDQLV-UHFFFAOYSA-N [cyclohexyl(diisocyanato)methyl]cyclohexane Chemical compound C1CCCCC1C(N=C=O)(N=C=O)C1CCCCC1 KXBFLNPZHXDQLV-UHFFFAOYSA-N 0.000 claims 3
- 125000001931 aliphatic group Chemical group 0.000 claims 3
- 125000003118 aryl group Chemical group 0.000 claims 3
- 125000005442 diisocyanate group Chemical group 0.000 claims 3
- 239000000539 dimer Substances 0.000 claims 3
- ZFSLODLOARCGLH-UHFFFAOYSA-N isocyanuric acid Chemical compound OC1=NC(O)=NC(O)=N1 ZFSLODLOARCGLH-UHFFFAOYSA-N 0.000 claims 3
- 229920003009 polyurethane dispersion Polymers 0.000 claims 3
- 238000009998 heat setting Methods 0.000 claims 1
- 229920006395 saturated elastomer Polymers 0.000 claims 1
- 239000003595 mist Substances 0.000 abstract 1
- 238000012360 testing method Methods 0.000 description 33
- 101150001846 PUP2 gene Proteins 0.000 description 18
- 240000001416 Pseudotsuga menziesii Species 0.000 description 15
- 235000008572 Pseudotsuga menziesii Nutrition 0.000 description 15
- 238000004026 adhesive bonding Methods 0.000 description 13
- UKLDJPRMSDWDSL-UHFFFAOYSA-L [dibutyl(dodecanoyloxy)stannyl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)O[Sn](CCCC)(CCCC)OC(=O)CCCCCCCCCCC UKLDJPRMSDWDSL-UHFFFAOYSA-L 0.000 description 12
- 238000002156 mixing Methods 0.000 description 11
- 239000000463 material Substances 0.000 description 10
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 8
- 230000032798 delamination Effects 0.000 description 8
- 238000012545 processing Methods 0.000 description 6
- ZXSBYAWLZRAJJY-UHFFFAOYSA-N 2,6-dihydroxybenzaldehyde phenol Chemical compound C1(O)=C(C(O)=CC=C1)C=O.OC1=CC=CC=C1 ZXSBYAWLZRAJJY-UHFFFAOYSA-N 0.000 description 5
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Natural products NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 5
- 239000011248 coating agent Substances 0.000 description 5
- 238000000576 coating method Methods 0.000 description 5
- 238000010276 construction Methods 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 5
- 239000003973 paint Substances 0.000 description 5
- KXDHJXZQYSOELW-UHFFFAOYSA-M Carbamate Chemical compound NC([O-])=O KXDHJXZQYSOELW-UHFFFAOYSA-M 0.000 description 4
- 101150066014 PUP1 gene Proteins 0.000 description 4
- 241000351396 Picea asperata Species 0.000 description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 4
- 230000008901 benefit Effects 0.000 description 4
- 239000003292 glue Substances 0.000 description 4
- 238000012856 packing Methods 0.000 description 4
- 239000011541 reaction mixture Substances 0.000 description 4
- 230000003068 static effect Effects 0.000 description 4
- UPMLOUAZCHDJJD-UHFFFAOYSA-N 4,4'-Diphenylmethane Diisocyanate Chemical compound C1=CC(N=C=O)=CC=C1CC1=CC=C(N=C=O)C=C1 UPMLOUAZCHDJJD-UHFFFAOYSA-N 0.000 description 3
- OHJMTUPIZMNBFR-UHFFFAOYSA-N biuret Chemical compound NC(=O)NC(N)=O OHJMTUPIZMNBFR-UHFFFAOYSA-N 0.000 description 3
- 239000004202 carbamide Substances 0.000 description 3
- 235000013877 carbamide Nutrition 0.000 description 3
- 239000003054 catalyst Substances 0.000 description 3
- 238000004132 cross linking Methods 0.000 description 3
- 239000012975 dibutyltin dilaurate Substances 0.000 description 3
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 3
- 239000004615 ingredient Substances 0.000 description 3
- IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 description 3
- 230000007246 mechanism Effects 0.000 description 3
- 238000012986 modification Methods 0.000 description 3
- 230000004048 modification Effects 0.000 description 3
- 230000037452 priming Effects 0.000 description 3
- 238000012797 qualification Methods 0.000 description 3
- 239000000454 talc Substances 0.000 description 3
- 229910052623 talc Inorganic materials 0.000 description 3
- 235000012222 talc Nutrition 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 239000004908 Emulsion polymer Substances 0.000 description 2
- 229920013646 Hycar Polymers 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- 235000013431 Pinus clausa Nutrition 0.000 description 2
- 235000000773 Pinus glabra Nutrition 0.000 description 2
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 description 2
- 238000007596 consolidation process Methods 0.000 description 2
- 230000006378 damage Effects 0.000 description 2
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N diphenyl Chemical compound C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 239000000945 filler Substances 0.000 description 2
- 239000003205 fragrance Substances 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 2
- 230000008595 infiltration Effects 0.000 description 2
- 238000001764 infiltration Methods 0.000 description 2
- 238000010907 mechanical stirring Methods 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 239000004408 titanium dioxide Substances 0.000 description 2
- 239000005059 1,4-Cyclohexyldiisocyanate Substances 0.000 description 1
- JRQLZCFSWYQHPI-UHFFFAOYSA-N 4,5-dichloro-2-cyclohexyl-1,2-thiazol-3-one Chemical compound O=C1C(Cl)=C(Cl)SN1C1CCCCC1 JRQLZCFSWYQHPI-UHFFFAOYSA-N 0.000 description 1
- ZMSQJSMSLXVTKN-UHFFFAOYSA-N 4-[2-(2-morpholin-4-ylethoxy)ethyl]morpholine Chemical compound C1COCCN1CCOCCN1CCOCC1 ZMSQJSMSLXVTKN-UHFFFAOYSA-N 0.000 description 1
- CWLUHUDAJBSGQL-UHFFFAOYSA-N CN(C1CCCCC1)N=C=O Chemical compound CN(C1CCCCC1)N=C=O CWLUHUDAJBSGQL-UHFFFAOYSA-N 0.000 description 1
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 1
- 206010016334 Feeling hot Diseases 0.000 description 1
- XTUVJUMINZSXGF-UHFFFAOYSA-N N-methylcyclohexylamine Chemical compound CNC1CCCCC1 XTUVJUMINZSXGF-UHFFFAOYSA-N 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- DPDMMXDBJGCCQC-UHFFFAOYSA-N [Na].[Cl] Chemical compound [Na].[Cl] DPDMMXDBJGCCQC-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 229920006243 acrylic copolymer Polymers 0.000 description 1
- 125000003277 amino group Chemical group 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- KVBYPTUGEKVEIJ-UHFFFAOYSA-N benzene-1,3-diol;formaldehyde Chemical compound O=C.OC1=CC=CC(O)=C1 KVBYPTUGEKVEIJ-UHFFFAOYSA-N 0.000 description 1
- 239000004305 biphenyl Substances 0.000 description 1
- 235000010290 biphenyl Nutrition 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 150000007516 brønsted-lowry acids Chemical class 0.000 description 1
- 150000007528 brønsted-lowry bases Chemical class 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 230000001066 destructive effect Effects 0.000 description 1
- TXFOLHZMICYNRM-UHFFFAOYSA-N dichlorophosphoryloxybenzene Chemical compound ClP(Cl)(=O)OC1=CC=CC=C1 TXFOLHZMICYNRM-UHFFFAOYSA-N 0.000 description 1
- KIQKWYUGPPFMBV-UHFFFAOYSA-N diisocyanatomethane Chemical compound O=C=NCN=C=O KIQKWYUGPPFMBV-UHFFFAOYSA-N 0.000 description 1
- 239000004205 dimethyl polysiloxane Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- AEDZKIACDBYJLQ-UHFFFAOYSA-N ethane-1,2-diol;hydrate Chemical compound O.OCCO AEDZKIACDBYJLQ-UHFFFAOYSA-N 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 239000000499 gel Substances 0.000 description 1
- 230000009477 glass transition Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000007731 hot pressing Methods 0.000 description 1
- 239000012943 hotmelt Substances 0.000 description 1
- 125000004356 hydroxy functional group Chemical group O* 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 229920000831 ionic polymer Polymers 0.000 description 1
- 235000015110 jellies Nutrition 0.000 description 1
- 239000008274 jelly Substances 0.000 description 1
- 239000002075 main ingredient Substances 0.000 description 1
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Natural products C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 229920002587 poly(1,3-butadiene) polymer Polymers 0.000 description 1
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 229920000768 polyamine Polymers 0.000 description 1
- 229920000909 polytetrahydrofuran Polymers 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- 238000001612 separation test Methods 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 229960001866 silicon dioxide Drugs 0.000 description 1
- 239000000779 smoke Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 230000002194 synthesizing effect Effects 0.000 description 1
- 125000003396 thiol group Chemical group [H]S* 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- AVWRKZWQTYIKIY-UHFFFAOYSA-N urea-1-carboxylic acid Chemical compound NC(=O)NC(O)=O AVWRKZWQTYIKIY-UHFFFAOYSA-N 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/10—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B21/00—Layered products comprising a layer of wood, e.g. wood board, veneer, wood particle board
- B32B21/14—Layered products comprising a layer of wood, e.g. wood board, veneer, wood particle board comprising wood board or veneer
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/12—Layered products comprising a layer of synthetic resin next to a fibrous or filamentary layer
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J175/00—Adhesives based on polyureas or polyurethanes; Adhesives based on derivatives of such polymers
- C09J175/04—Polyurethanes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2666/00—Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
- C08L2666/02—Organic macromolecular compounds, natural resins, waxes or and bituminous materials
- C08L2666/04—Macromolecular compounds according to groups C08L7/00 - C08L49/00, or C08L55/00 - C08L57/00; Derivatives thereof
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2982—Particulate matter [e.g., sphere, flake, etc.]
- Y10T428/2991—Coated
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2982—Particulate matter [e.g., sphere, flake, etc.]
- Y10T428/2991—Coated
- Y10T428/2998—Coated including synthetic resin or polymer
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31511—Of epoxy ether
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31551—Of polyamidoester [polyurethane, polyisocyanate, polycarbamate, etc.]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31551—Of polyamidoester [polyurethane, polyisocyanate, polycarbamate, etc.]
- Y10T428/31591—Next to cellulosic
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31855—Of addition polymer from unsaturated monomers
- Y10T428/31909—Next to second addition polymer from unsaturated monomers
- Y10T428/31928—Ester, halide or nitrile of addition polymer
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Polyurethanes Or Polyureas (AREA)
- Veneer Processing And Manufacture Of Plywood (AREA)
- Laminated Bodies (AREA)
- Chemical And Physical Treatments For Wood And The Like (AREA)
Abstract
Description
MC% | 是否用水雾化处理 | 干燥 | 真空-压力 | 2-周期煮沸 | |||
PSI | Wf% | PSI | Wf% | PSI | Wf% | ||
10.8 | 否 | 2,164 | 65 | 616(136) | 3(3) | 193(105) | (8) |
10.5 | 是 | 2,122 | 85 | 917(59) | 29(4) | 599(58) | 29(7) |
7.5 | 否 | 1,852 | 10 | 583(12) | 2(3) | 132(170) | 3(4) |
7.1 | 是 | 2,408 | 70 | 868(105) | 41(11) | 531(168) | 55(16) |
比重 | MC% | 是否用水雾化处理 | 重量增长率(3层) | 最终循环脱层率(%) | ||
0.525 | 10.6 | 否 | 1.27 | 1.27 | 1.39 | 4.2 |
0.529 | 10.6 | 是 | 1.26 | 1.25 | 1.33 | 2.1 |
0.524 | 7.5 | 否 | 1.33 | 1.26 | 1.37 | 19.4 |
0.531 | 7.4 | 是 | 1.31 | 1.25 | 1.29 | 3.1 |
水雾化处理后的涂胶时间(分钟) | 干燥 | 真空-压力(7个试片的平均值) | ||
强度(psi) | 木材破坏率(%) | 强度(psi) | 木材破坏率(%) | |
0 | 1,776 | 95 | 824±110 | 60±16 |
5 | 1,749 | 90 | 815±77 | 50±19 |
10 | 1,658 | 50 | 643±132 | 30±15 |
15 | 1,605 | 60 | 665±182 | 26±7 |
20 | 1,461 | 40 | 638±115 | 29±6 |
40 | 1,208 | 10 | 559±171 | 18±12 |
水雾化处理后的涂胶时间(分钟) | 干燥 | 两个周期煮沸测试(7个试片的平均值) | ||
强度(psi) | 木材破坏率(%) | 强度(psi) | 木材破坏率(%) | |
0 | 1,776 | 95 | 550±110 | 61±7 |
5 | 1,749 | 90 | 591±140 | 46±11 |
10 | 1,658 | 50 | 529±169 | 36±8 |
15 | 1,605 | 60 | 500±276 | 26±17 |
20 | 1,461 | 40 | 495±203 | 29±7 |
40 | 1,208 | 10 | 333±144 | 14±8 |
测试编号 | 木材含水量% | 涂胶时间(分钟) | 强度(psi)7个试样的平均值 | 木材破坏率(%)7个试样的平均值 |
1 | <5 | 3 | 917±82 | 60±18 |
2 | <5 | 23 | 918±52 | 49±18 |
3 | 10-11 | 3 | 934±51 | 51±13 |
4 | 10-11 | 23 | 783±64 | 32±18 |
5 | >30 | 3 | 792±74 | 18±10 |
6 | 3>0 | 23 | 827±113 | 14±8 |
测试编号 | 木材含水量% | 涂胶时间(分钟) | 强度(psi)7个试样的平均值 | 木材破坏率(%)7个试样的平均值 |
1 | <5 | 3 | 740±117 | 69±19 |
2 | <5 | 23 | 635±243 | 58±28 |
3 | 10-11 | 3 | 712±70 | 63±8 |
4 | 10-11 | 23 | 399±101 | 27±10 |
5 | >30 | 3 | 431±122 | 19±6 |
6 | 3>0 | 23 | 200±106 | 15±8 |
种类 | 30分钟 | 24小时 | ||
无光墙壁涂料 | 3,207±865 | 19±14 | 8,417±1618 | 77±13 |
无光丙烯酸房屋涂料 | 2,403±940 | 10±11 | 7,752±965 | 80±26 |
木材外部底漆 | 496±102 | 4±3 | 7,521±936 | 65±10 |
Arolon 870 | 1,783±156 | 10±4 | 8,083±307 | 87±6 |
Airflex 7200 | 953±454 | 4±3 | 6,846±637 | 88±3 |
Aquathane AD 97950-00 | 4,434±598 | 43±19 | 6,591±679 | 88±3 |
Carbobond 26373 | 1,232±365 | 4±5 | 5,239±144 | 80±17 |
Hycar 26091乳液 | 5.334±1073 | 68±25 | 8,659±1513 | 90±5 |
Rhoplex N-619 | 449±388 | 1±3 | 3,255±184 | 12±3 |
Rhoplex TR-520 | 2,301±365 | 9±3 | 7,585±1238 | 85±9 |
TB-II | 3,750±861 | 33±9 | 8,805±1813 | 95±5 |
试样 | 固化时间 | 强度(psi) | 木材破坏率(%) |
1 | 30分钟 | 1,752 | 0 |
2 | 45分钟 | 2,038 | 0 |
3 | 45分钟 | 2,514 | 0 |
4 | 60分钟 | 4,610 | 0 |
5 | 24小时 | 8,810 | 100 |
6 | 24小时 | 9,048 | 100 |
T-12浓度(%) | 固化时间(分钟) | 强度(psi) | 木材破坏率(%) |
0.2 | 30 | 1,010 | 0 |
45 | 2,076 | 0 | |
45 | 1,771 | 0 | |
60 | 3,010 | 0 | |
24小时 | 7,448 | 100 | |
24小时 | 9,219 | 100 | |
0.4 | 30 | 1,790 | 0 |
30 | 1,518 | 0 | |
45 | 3,048 | 0 | |
45 | 2,648 | 0 | |
0.6 | 30 | 1,295 | 0 |
30 | 2,819 | 0 | |
45 | 4,229 | 10 | |
45 | 5,410 | 15 |
试样编号 | 固化时间(分钟) | 强度(psi) | 木材破坏率(%) |
1 | 15 | 1,067 | 0 |
2 | 30 | 2,286 | 0 |
3 | 45 | 3,790 | 0 |
4 | 60 | 5,029 | 25 |
5 | 120 | 7,586 | 45 |
试样编号* | 干燥 | 真空-压力 | 两个周期煮沸 | |||
强度(psi) | 木材破坏率(%) | 强度(psi) | 木材破坏率(%) | 强度(psi) | 木材破坏率(%) | |
C6079-165AC6079-172AC6079-172BC6079-174AC6079-174BC6079-174CC6079-174D | 1,884±1631,456±4041,479±1521,675±1041,704±1051,745±661,583±242 | 99±283±1673±1971±2474±1676±1776±17 | 1,030±68932±1031,070±25993±771,045±901,064±741,077±48 | 64±1951±2371±1544±1648±1653±2234±19 | 817±77743±90683±82827±46752±72854±72704±123 | 65±2759±3251±1546±2845±1650±1854±17 |
配方 | C-6079-161B | C-6079-164B |
预聚物+0.3%DMDEE预聚物AEP混合比CAT(分钟)OAT(分钟) | PUP2-ISOSET100080∶20立即<1 | -PUP2ISOSET100080∶20立即<1 |
每个胶层的脱层率% | ||
GL1* | 0.7636 | 0.6404 |
GL2 | 0.1568 | 2.5324 |
GL3 | 0.9904 | 0.3128 |
GL4 | 0.3416 | 0.7544 |
GL5 | 4.2568 | 0.8636 |
总脱层率% | 6.5092 | 5.1036 |
配方 | C-6079-169B |
预聚物+0.6%T-12AEP混合比CAT(分钟)OAT(分钟) | PUP2VinacXX-21080∶20立即<1 |
GL1* | 0.1972 |
GL2 | 0.1460 |
GL3 | 0.1352 |
GL4 | 0.4288 |
GL5 | 0.6880 |
总脱层率% | 1.5952 |
Claims (25)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US09/988,236 US6632873B2 (en) | 2001-11-19 | 2001-11-19 | Two-part polyurethane adhesives for structural finger joints and method therefor |
US09/988,236 | 2001-11-19 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN1628153A CN1628153A (zh) | 2005-06-15 |
CN1326943C true CN1326943C (zh) | 2007-07-18 |
Family
ID=25533956
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CNB028272773A Expired - Lifetime CN1326943C (zh) | 2001-11-19 | 2002-11-15 | 用于结构指形接合的双组分聚氨基甲酸酯粘合剂及其方法 |
Country Status (15)
Country | Link |
---|---|
US (3) | US6632873B2 (zh) |
EP (1) | EP1456303B1 (zh) |
JP (1) | JP4511180B2 (zh) |
KR (1) | KR100967730B1 (zh) |
CN (1) | CN1326943C (zh) |
AT (1) | ATE429465T1 (zh) |
AU (1) | AU2002366050B2 (zh) |
BR (1) | BR0214296A (zh) |
CA (1) | CA2467396C (zh) |
DE (1) | DE60232096D1 (zh) |
DK (1) | DK1456303T3 (zh) |
MX (1) | MXPA04004696A (zh) |
NO (1) | NO20042518L (zh) |
NZ (1) | NZ533512A (zh) |
WO (1) | WO2003044094A1 (zh) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101805514A (zh) * | 2010-03-17 | 2010-08-18 | 上海大学 | 蓖麻油型聚氨酯/丙烯酸树脂双组份阻尼材料及其制备方法 |
Families Citing this family (27)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2003093385A2 (en) * | 2002-05-03 | 2003-11-13 | Huntsman International Llc | Lignocellulosic composites, adhesive systems, and process |
US20050096411A1 (en) * | 2003-10-31 | 2005-05-05 | Illinois Tool Works Inc. | Polyurethane adhesive for masonry construction |
US8501828B2 (en) | 2004-08-11 | 2013-08-06 | Huntsman Petrochemical Llc | Cure rebond binder |
JP3770275B2 (ja) | 2004-08-19 | 2006-04-26 | 大日本インキ化学工業株式会社 | 水性プライマー組成物、それを用いた下地処理方法および積層構造体 |
CA2600281A1 (en) | 2004-11-01 | 2006-05-11 | Basf Corporation | Fast-drying, radiofrequency-activatable inkjet inks and methods and systems for their use |
WO2006071549A1 (en) * | 2004-12-23 | 2006-07-06 | Dow Global Technologies Inc. | An isocyanate composition comprising a vegetable oil and composites therefrom |
US7566406B2 (en) * | 2005-05-05 | 2009-07-28 | L&P Property Management Company | Bonded foam product manufactured with vegetable oil polyol and method for manufacturing |
US20070039159A1 (en) * | 2005-08-18 | 2007-02-22 | Robert Galbreath | Method of forming a cabinet assembly |
TWI310049B (en) * | 2005-09-27 | 2009-05-21 | Taiwan Textile Res Inst | A weather-resistive resin coating material and its manufacturing method |
JP2007119578A (ja) * | 2005-10-27 | 2007-05-17 | Hitachi Kasei Polymer Co Ltd | 反応性ホットメルト接着剤組成物 |
US20090162680A1 (en) * | 2005-11-08 | 2009-06-25 | Jun Zheng | Process for making wood laminates using fast setting adhesives at ambient temperature |
US20070102108A1 (en) * | 2005-11-08 | 2007-05-10 | Jun Zheng | Process for making wood laminates using fast setting adhesives at ambient temperature |
FR2898905B1 (fr) * | 2006-03-24 | 2008-05-09 | Rhodia Recherches & Tech | Composition polyisocyanate a proprietes anti-chocs ameliorees |
NO327019B1 (no) * | 2006-11-10 | 2009-04-06 | Dynea Oy | Forbedret fremgangsmate for liming |
US20080251182A1 (en) * | 2007-04-11 | 2008-10-16 | Huber Engineered Woods Llc | In line web treating and substrate forming method for overlaid products |
KR101166988B1 (ko) * | 2007-12-25 | 2012-07-24 | 어플라이드 머티어리얼스, 인코포레이티드 | 플라즈마 챔버의 전극에 대한 비대칭 rf 구동 |
US8273450B2 (en) * | 2008-08-08 | 2012-09-25 | Green David E | Thermoset polyurethane matrix fiber reinforced composite |
AT510651B1 (de) * | 2010-10-29 | 2016-03-15 | Mikowitsch Herbert | Klebstoff |
US8871891B2 (en) * | 2011-05-16 | 2014-10-28 | Ashland Licensing And Intellectual Property Llc | Two part polyurea-urethane adhesive with elevated high temperature storage modulus |
EP2562192A1 (de) * | 2011-08-26 | 2013-02-27 | Sika Technology AG | Härter für feuchtigkeitshärtende Zusammensetzungen |
US9540513B2 (en) * | 2012-11-21 | 2017-01-10 | Basf Se | Lignocellulosic article and method of producing same |
CN105131238B (zh) * | 2015-08-04 | 2018-06-01 | 航天材料及工艺研究所 | 一种聚氨酯材料及其应用 |
CN108410411A (zh) * | 2018-03-27 | 2018-08-17 | 安徽宝润环保节能建材有限公司 | 一种vae乳液与聚氨酯乳液共混改性的方法 |
US11519172B2 (en) | 2018-10-04 | 2022-12-06 | Covestro Llc | Modified foam wall structures with high racking strength and methods for their manufacture |
CN111918945B (zh) | 2019-03-07 | 2023-04-21 | 陶氏环球技术有限责任公司 | 无甲醛的粘合剂组合物 |
CN113149592B (zh) * | 2021-02-07 | 2022-04-29 | 杭州圣立新材料有限公司 | 一种早强土壤固化剂及其制备方法和应用 |
CN114456762A (zh) * | 2022-01-07 | 2022-05-10 | 万果新材料科技(上海)有限公司 | 一种微波引发固化的聚氨酯热熔胶及其制备方法和固化方法 |
Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4663377A (en) * | 1985-06-15 | 1987-05-05 | Bayer Aktiengesellschaft | Polyisocyanate preparation dispersible in water and their use as an additive for aqueous adhesives |
US5200489A (en) * | 1992-02-27 | 1993-04-06 | Miles Inc. | Water dispersible polyisocyanates |
US5252696A (en) * | 1991-11-07 | 1993-10-12 | Bayer Aktiengesellschaft | Water-dispersible polyisocyanate mixtures, a process for their preparation and their use in two-component aqueous compositions |
US5449559A (en) * | 1994-01-27 | 1995-09-12 | Air Products And Chemicals, Inc. | High performance vinyl laminating adhesive |
US5643983A (en) * | 1995-08-30 | 1997-07-01 | Ashland Inc. | Moisture curable 100% solids one component plywood adhesive |
US5717031A (en) * | 1995-06-21 | 1998-02-10 | Lord Corporation | Aqueous adhesive compositions |
US6225398B1 (en) * | 1997-03-25 | 2001-05-01 | Henkel Corporation | Aqueous dispersions of polymers |
US6280561B1 (en) * | 1996-09-06 | 2001-08-28 | Air Products And Chemicals, Inc. | Hot melt adhesives comprising low free monomer, low oligomer isocyanate prepolymers |
Family Cites Families (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CA991973A (en) * | 1973-03-27 | 1976-06-29 | Sumitomo Bakelite Company | Method for bonding wet woods |
US4035217A (en) * | 1973-05-24 | 1977-07-12 | Johnson & Johnson | Method of manufacturing absorbent facing materials |
JPS5018533A (zh) * | 1973-06-15 | 1975-02-27 | ||
DE3112117A1 (de) | 1981-03-27 | 1982-10-07 | Bayer Ag, 5090 Leverkusen | Verwendung von in wasser dispergierbaren polyisocyanat-zubereitungen als zusatzmittel fuer waessrige klebstoffe |
JPS5863434A (ja) * | 1981-10-14 | 1983-04-15 | Mitsui Toatsu Chem Inc | パ−テイクルボ−ド製造方法 |
JPS60255877A (ja) * | 1984-05-31 | 1985-12-17 | Nippon Urethane Service:Kk | 接着剤組成物 |
CA1314646C (en) * | 1987-10-28 | 1993-03-16 | Nobuo Kobayashi | Flame retardant for wood and flame resistant wood |
US5512323A (en) * | 1994-06-10 | 1996-04-30 | Lilly Industries, Inc. | Wood pretreatment for water-based finishing schedules |
US5730824A (en) * | 1994-11-10 | 1998-03-24 | American Excelsior Company | Method of extruding and bonding biodegradable structured packing |
US5723534A (en) * | 1996-10-11 | 1998-03-03 | Polyfoam Products, Inc. | Two part polyurethane-based adhesive system |
DE19718771A1 (de) * | 1997-05-03 | 1998-11-05 | Dieffenbacher Gmbh Maschf | Verfahren und Anlage zur Herstellung von Holzwerkstoffplatten |
DE19836823A1 (de) * | 1998-08-13 | 2000-02-17 | Dieffenbacher Gmbh Maschf | Verfahren, Anlage und kontinuierlich arbeitende Prägepresse zur Herstellung von Holzwerkstoffplatten mit strukturierten Oberflächen |
DE19929784A1 (de) * | 1999-06-29 | 2001-01-04 | Bayer Ag | Bindemittelkombination für wäßrige Beschichtungen |
DE19948004B4 (de) * | 1999-10-06 | 2006-05-11 | Basf Coatings Ag | Polyurethane und Pfropfmischpolymerisate auf Polyurethanbasis sowie ihre Verwendung zur Herstellung von Beschichtungsstoffen, Klebstoffen und Dichtungsmassen |
US20050281999A1 (en) * | 2003-03-12 | 2005-12-22 | Petritech, Inc. | Structural and other composite materials and methods for making same |
-
2001
- 2001-11-19 US US09/988,236 patent/US6632873B2/en not_active Expired - Lifetime
-
2002
- 2002-11-15 EP EP20020803621 patent/EP1456303B1/en not_active Expired - Lifetime
- 2002-11-15 JP JP2003545727A patent/JP4511180B2/ja not_active Expired - Lifetime
- 2002-11-15 CA CA 2467396 patent/CA2467396C/en not_active Expired - Lifetime
- 2002-11-15 CN CNB028272773A patent/CN1326943C/zh not_active Expired - Lifetime
- 2002-11-15 BR BR0214296A patent/BR0214296A/pt not_active Application Discontinuation
- 2002-11-15 MX MXPA04004696A patent/MXPA04004696A/es active IP Right Grant
- 2002-11-15 AU AU2002366050A patent/AU2002366050B2/en not_active Ceased
- 2002-11-15 NZ NZ533512A patent/NZ533512A/en unknown
- 2002-11-15 KR KR1020047007595A patent/KR100967730B1/ko active IP Right Grant
- 2002-11-15 DE DE60232096T patent/DE60232096D1/de not_active Expired - Lifetime
- 2002-11-15 WO PCT/US2002/036539 patent/WO2003044094A1/en active IP Right Grant
- 2002-11-15 AT AT02803621T patent/ATE429465T1/de not_active IP Right Cessation
- 2002-11-15 DK DK02803621T patent/DK1456303T3/da active
-
2003
- 2003-07-24 US US10/626,387 patent/US7419724B2/en active Active
-
2004
- 2004-06-16 NO NO20042518A patent/NO20042518L/no not_active Application Discontinuation
-
2008
- 2008-07-22 US US12/177,235 patent/US7655312B2/en not_active Expired - Lifetime
Patent Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4663377A (en) * | 1985-06-15 | 1987-05-05 | Bayer Aktiengesellschaft | Polyisocyanate preparation dispersible in water and their use as an additive for aqueous adhesives |
US5252696A (en) * | 1991-11-07 | 1993-10-12 | Bayer Aktiengesellschaft | Water-dispersible polyisocyanate mixtures, a process for their preparation and their use in two-component aqueous compositions |
US5200489A (en) * | 1992-02-27 | 1993-04-06 | Miles Inc. | Water dispersible polyisocyanates |
US5449559A (en) * | 1994-01-27 | 1995-09-12 | Air Products And Chemicals, Inc. | High performance vinyl laminating adhesive |
US5717031A (en) * | 1995-06-21 | 1998-02-10 | Lord Corporation | Aqueous adhesive compositions |
US5643983A (en) * | 1995-08-30 | 1997-07-01 | Ashland Inc. | Moisture curable 100% solids one component plywood adhesive |
US6280561B1 (en) * | 1996-09-06 | 2001-08-28 | Air Products And Chemicals, Inc. | Hot melt adhesives comprising low free monomer, low oligomer isocyanate prepolymers |
US6225398B1 (en) * | 1997-03-25 | 2001-05-01 | Henkel Corporation | Aqueous dispersions of polymers |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101805514A (zh) * | 2010-03-17 | 2010-08-18 | 上海大学 | 蓖麻油型聚氨酯/丙烯酸树脂双组份阻尼材料及其制备方法 |
CN101805514B (zh) * | 2010-03-17 | 2012-01-04 | 上海大学 | 蓖麻油型聚氨酯/丙烯酸树脂双组份阻尼材料及其制备方法 |
Also Published As
Publication number | Publication date |
---|---|
MXPA04004696A (es) | 2004-09-10 |
AU2002366050B2 (en) | 2008-04-03 |
BR0214296A (pt) | 2004-09-21 |
DE60232096D1 (de) | 2009-06-04 |
NO20042518L (no) | 2004-08-18 |
US7655312B2 (en) | 2010-02-02 |
ATE429465T1 (de) | 2009-05-15 |
US20030125449A1 (en) | 2003-07-03 |
CA2467396A1 (en) | 2003-05-30 |
DK1456303T3 (da) | 2009-07-13 |
US20090183827A1 (en) | 2009-07-23 |
EP1456303A4 (en) | 2005-02-02 |
JP4511180B2 (ja) | 2010-07-28 |
WO2003044094A1 (en) | 2003-05-30 |
US20040151916A1 (en) | 2004-08-05 |
KR20050044529A (ko) | 2005-05-12 |
NZ533512A (en) | 2005-01-28 |
JP2005509713A (ja) | 2005-04-14 |
CN1628153A (zh) | 2005-06-15 |
EP1456303A1 (en) | 2004-09-15 |
KR100967730B1 (ko) | 2010-07-05 |
CA2467396C (en) | 2010-04-13 |
EP1456303B1 (en) | 2009-04-22 |
US6632873B2 (en) | 2003-10-14 |
AU2002366050A1 (en) | 2003-06-10 |
US7419724B2 (en) | 2008-09-02 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN1326943C (zh) | 用于结构指形接合的双组分聚氨基甲酸酯粘合剂及其方法 | |
US6231985B1 (en) | Heat and radio frequency-curable two-pack soy protein-based polyurethane adhesive compositions | |
CA2734129C (en) | Rapid curing aldehyde resin-polyisocyanate composition and method for producing hybrid polymer | |
Grøstad et al. | Emulsion polymer isocyanates as wood adhesive: a review | |
CN118358014A (zh) | 木质纤维素复合制品 | |
CN105121584B (zh) | 用于制备木质纤维素复合材料的粘合剂体系 | |
CN105593260B (zh) | 用于具有高水平抽提物的木质纤维素基材的粘合剂体系 | |
JP2895421B2 (ja) | 通気性被着体用接着剤 | |
JP3274155B2 (ja) | サンドイッチ構造パネルの製造加工方法 | |
US6878795B2 (en) | Alternative moisture cure catalysts and cold curing polyisocyanate adhesives prepared therefrom | |
JP2895429B2 (ja) | 通気性被着体用接着剤及びこれを用いた接着方法 | |
WO2024123540A1 (en) | Mix on board application for wood product emulsion adhesives | |
CA2530700A1 (en) | Alternative moisture cure catalysts and cold curing polyisocyanate adhesives preparted therefrom | |
JPH09300313A (ja) | 木質成形材の製造方法 | |
JPS6032876A (ja) | 高含水率木材の接着方法 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
ASS | Succession or assignment of patent right |
Owner name: ASHLAND LICENSING AND INTELLECTUAL PROPERTY LTD. Free format text: FORMER OWNER: ASHLAND INC. Effective date: 20060818 |
|
C41 | Transfer of patent application or patent right or utility model | ||
TA01 | Transfer of patent application right |
Effective date of registration: 20060818 Address after: Ohio, USA Applicant after: ASHLAND LICENSING AND INTELLECTUAL PROPERTY LLC Address before: American Ohio Applicant before: Ashland Inc. |
|
C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
TR01 | Transfer of patent right |
Effective date of registration: 20220715 Address after: Colombes, France Patentee after: ARKEMA FRANCE Address before: Ohio, USA Patentee before: ASHLAND LICENSING AND INTELLECTUAL PROPERTY LLC |
|
TR01 | Transfer of patent right | ||
CX01 | Expiry of patent term | ||
CX01 | Expiry of patent term |
Granted publication date: 20070718 |