CN1324065C - 可自乳化的醇酸树脂及其制备方法 - Google Patents
可自乳化的醇酸树脂及其制备方法 Download PDFInfo
- Publication number
- CN1324065C CN1324065C CNB2004100185555A CN200410018555A CN1324065C CN 1324065 C CN1324065 C CN 1324065C CN B2004100185555 A CNB2004100185555 A CN B2004100185555A CN 200410018555 A CN200410018555 A CN 200410018555A CN 1324065 C CN1324065 C CN 1324065C
- Authority
- CN
- China
- Prior art keywords
- acid
- resin
- self
- preparation
- emulsified
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 229920005989 resin Polymers 0.000 title claims abstract description 28
- 239000011347 resin Substances 0.000 title claims abstract description 28
- 239000002253 acid Substances 0.000 title claims description 26
- 230000001476 alcoholic effect Effects 0.000 title claims description 12
- 238000000034 method Methods 0.000 title description 3
- 238000007639 printing Methods 0.000 claims abstract description 20
- 238000002360 preparation method Methods 0.000 claims abstract description 18
- 239000000203 mixture Substances 0.000 claims abstract description 11
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 9
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 18
- -1 polyoxyethylene Polymers 0.000 claims description 10
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 9
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims description 9
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical group C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 claims description 8
- 150000002632 lipids Chemical class 0.000 claims description 8
- 239000004593 Epoxy Substances 0.000 claims description 6
- 150000007520 diprotic acids Chemical class 0.000 claims description 6
- 229920001223 polyethylene glycol Polymers 0.000 claims description 6
- 229910052799 carbon Inorganic materials 0.000 claims description 5
- 229940059574 pentaerithrityl Drugs 0.000 claims description 5
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 claims description 5
- 229920000647 polyepoxide Polymers 0.000 claims description 4
- 238000010792 warming Methods 0.000 claims description 4
- 238000006243 chemical reaction Methods 0.000 claims description 3
- 239000003822 epoxy resin Substances 0.000 claims description 3
- 230000032050 esterification Effects 0.000 claims description 3
- 238000005886 esterification reaction Methods 0.000 claims description 3
- KMOUUZVZFBCRAM-OLQVQODUSA-N (3as,7ar)-3a,4,7,7a-tetrahydro-2-benzofuran-1,3-dione Chemical compound C1C=CC[C@@H]2C(=O)OC(=O)[C@@H]21 KMOUUZVZFBCRAM-OLQVQODUSA-N 0.000 claims description 2
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 claims description 2
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 claims description 2
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 claims description 2
- 229920000742 Cotton Polymers 0.000 claims description 2
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical group C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims description 2
- OYHQOLUKZRVURQ-HZJYTTRNSA-N Linoleic acid Chemical compound CCCCC\C=C/C\C=C/CCCCCCCC(O)=O OYHQOLUKZRVURQ-HZJYTTRNSA-N 0.000 claims description 2
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 claims description 2
- 239000005642 Oleic acid Substances 0.000 claims description 2
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 claims description 2
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 claims description 2
- 229960004232 linoleic acid Drugs 0.000 claims description 2
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 claims description 2
- 230000035484 reaction time Effects 0.000 claims description 2
- LKOVPWSSZFDYPG-WUKNDPDISA-N trans-octadec-2-enoic acid Chemical compound CCCCCCCCCCCCCCC\C=C\C(O)=O LKOVPWSSZFDYPG-WUKNDPDISA-N 0.000 claims description 2
- QXJQHYBHAIHNGG-UHFFFAOYSA-N trimethylolethane Chemical compound OCC(C)(CO)CO QXJQHYBHAIHNGG-UHFFFAOYSA-N 0.000 claims description 2
- 239000002904 solvent Substances 0.000 abstract description 13
- 229920000180 alkyd Polymers 0.000 abstract description 7
- 239000002994 raw material Substances 0.000 abstract description 5
- 239000003995 emulsifying agent Substances 0.000 abstract description 4
- 239000003513 alkali Substances 0.000 abstract description 3
- 238000004519 manufacturing process Methods 0.000 abstract description 3
- 125000002887 hydroxy group Chemical group [H]O* 0.000 abstract description 2
- 150000007524 organic acids Chemical class 0.000 abstract description 2
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 abstract 1
- 238000004945 emulsification Methods 0.000 abstract 1
- 125000003700 epoxy group Chemical group 0.000 abstract 1
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- 239000003921 oil Substances 0.000 description 5
- 235000019198 oils Nutrition 0.000 description 5
- 235000014113 dietary fatty acids Nutrition 0.000 description 4
- 239000000194 fatty acid Substances 0.000 description 4
- 229930195729 fatty acid Natural products 0.000 description 4
- 150000004665 fatty acids Chemical class 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- 238000007598 dipping method Methods 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000012467 final product Substances 0.000 description 2
- UHOVQNZJYSORNB-UHFFFAOYSA-N monobenzene Natural products C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 2
- 239000012188 paraffin wax Substances 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- 229920003987 resole Polymers 0.000 description 2
- 238000009736 wetting Methods 0.000 description 2
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 206010009866 Cold sweat Diseases 0.000 description 1
- 229910010413 TiO 2 Inorganic materials 0.000 description 1
- UWHZIFQPPBDJPM-FPLPWBNLSA-M Vaccenic acid Natural products CCCCCC\C=C/CCCCCCCCCC([O-])=O UWHZIFQPPBDJPM-FPLPWBNLSA-M 0.000 description 1
- 235000021322 Vaccenic acid Nutrition 0.000 description 1
- 150000001335 aliphatic alkanes Chemical class 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 150000001555 benzenes Chemical class 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 235000012343 cottonseed oil Nutrition 0.000 description 1
- 239000002385 cottonseed oil Substances 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000001804 emulsifying effect Effects 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 238000005227 gel permeation chromatography Methods 0.000 description 1
- 238000001879 gelation Methods 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 150000002924 oxiranes Chemical group 0.000 description 1
- 229920001568 phenolic resin Polymers 0.000 description 1
- 239000005011 phenolic resin Substances 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 239000010773 plant oil Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- UWHZIFQPPBDJPM-BQYQJAHWSA-N trans-vaccenic acid Chemical compound CCCCCC\C=C\CCCCCCCCCC(O)=O UWHZIFQPPBDJPM-BQYQJAHWSA-N 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
Landscapes
- Inks, Pencil-Leads, Or Crayons (AREA)
- Epoxy Resins (AREA)
Abstract
Description
Mn | Mw | Mz | d | Mz/Mw | Mz/Mn |
1780 | 21564 | 123270 | 12.11 | 5.72 | 11.09 |
Claims (5)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CNB2004100185555A CN1324065C (zh) | 2004-05-21 | 2004-05-21 | 可自乳化的醇酸树脂及其制备方法 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CNB2004100185555A CN1324065C (zh) | 2004-05-21 | 2004-05-21 | 可自乳化的醇酸树脂及其制备方法 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN1580093A CN1580093A (zh) | 2005-02-16 |
CN1324065C true CN1324065C (zh) | 2007-07-04 |
Family
ID=34581841
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CNB2004100185555A Expired - Lifetime CN1324065C (zh) | 2004-05-21 | 2004-05-21 | 可自乳化的醇酸树脂及其制备方法 |
Country Status (1)
Country | Link |
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CN (1) | CN1324065C (zh) |
Families Citing this family (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102311543A (zh) * | 2010-07-06 | 2012-01-11 | 河北晨阳工贸集团有限公司 | 一种液晶环氧改性水性醇酸树脂及其制备方法 |
CN104231253B (zh) * | 2014-09-16 | 2016-03-16 | 上海金兆节能科技有限公司 | 自乳化聚酯及其制备方法和用该聚酯制备的微量润滑剂 |
CN108559371A (zh) * | 2018-02-25 | 2018-09-21 | 李嘉顺 | 一种水性自乳化环氧改性醇酸树脂及其防腐涂料 |
CN108484891B (zh) * | 2018-03-12 | 2020-05-08 | 吉林乾仁新材料有限公司 | 自组装自乳化自稳定聚酯型高性能纤维界面改性助剂的制备及产品和应用 |
CN109796583B (zh) * | 2019-01-29 | 2021-04-20 | 衡水新光新材料科技有限公司 | 酚醛树脂改性水性醇酸树脂及制备工艺和应用 |
CN116622263A (zh) * | 2023-05-22 | 2023-08-22 | 中国印钞造币集团有限公司 | 一种低voc高稳定性环保型雕刻凹印油墨及其制备方法 |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0341916A2 (en) * | 1988-05-11 | 1989-11-15 | Crown Berger Limited | Solvent-based alkyd paints |
CN1095394A (zh) * | 1993-05-16 | 1994-11-23 | 吴荣根 | 以植物油残渣的脂肪酸为原料的醇酸树脂及其相关涂料 |
-
2004
- 2004-05-21 CN CNB2004100185555A patent/CN1324065C/zh not_active Expired - Lifetime
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0341916A2 (en) * | 1988-05-11 | 1989-11-15 | Crown Berger Limited | Solvent-based alkyd paints |
CN1095394A (zh) * | 1993-05-16 | 1994-11-23 | 吴荣根 | 以植物油残渣的脂肪酸为原料的醇酸树脂及其相关涂料 |
Also Published As
Publication number | Publication date |
---|---|
CN1580093A (zh) | 2005-02-16 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
ASS | Succession or assignment of patent right |
Owner name: CHINA BANKNOTE PRINTING AND MINTING CORP.; ZHONGC Free format text: FORMER OWNER: CHINA BANKNOTE PRINTING AND MINTING CORP. Effective date: 20081031 |
|
C41 | Transfer of patent application or patent right or utility model | ||
EE01 | Entry into force of recordation of patent licensing contract |
Assignee: CHINA BANKNOTE INK Co.,Ltd. Assignor: CHINA BANKNOTE PRINTING AND MINTING Corp. Contract fulfillment period: 2007.8.10 to 2017.8.10 Contract record no.: 2008310000054 Denomination of invention: Self-emulsified alcoholic acid resin and its preparing method Granted publication date: 20070704 License type: Exclusive license Record date: 20080918 |
|
LIC | Patent licence contract for exploitation submitted for record |
Free format text: EXCLUSIVE LICENCE; TIME LIMIT OF IMPLEMENTING CONTACT: 2007.8.10 TO 2017.8.10 Name of requester: ZHONGCHAO PRINTING INK CO., LTD. Effective date: 20080918 |
|
TR01 | Transfer of patent right |
Effective date of registration: 20081031 Address after: 143, West Straight Gate Street, Xicheng District, Beijing, a: zip code: 100044 Co-patentee after: CHINA BANKNOTE INK Co.,Ltd. Patentee after: CHINA BANKNOTE PRINTING AND MINTING Corp. Address before: Beijing city Xicheng District Xizhimen Street No. 143 zip code: 100053 Patentee before: CHINA BANKNOTE PRINTING AND MINTING Corp. |
|
CP01 | Change in the name or title of a patent holder |
Address after: 143A, Xizhimenwai Street, Xicheng District, Beijing 100044 Patentee after: China Banknote Printing and Minting Group Co.,Ltd. Patentee after: CHINA BANKNOTE INK Co.,Ltd. Address before: 143A, Xizhimenwai Street, Xicheng District, Beijing 100044 Patentee before: CHINA BANKNOTE PRINTING AND MINTING Corp. Patentee before: CHINA BANKNOTE INK Co.,Ltd. |
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CP01 | Change in the name or title of a patent holder | ||
CX01 | Expiry of patent term |
Granted publication date: 20070704 |