CN1300355C - 铝青铜合金及其制备方法 - Google Patents

铝青铜合金及其制备方法 Download PDF

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CN1300355C
CN1300355C CNB2003101222203A CN200310122220A CN1300355C CN 1300355 C CN1300355 C CN 1300355C CN B2003101222203 A CNB2003101222203 A CN B2003101222203A CN 200310122220 A CN200310122220 A CN 200310122220A CN 1300355 C CN1300355 C CN 1300355C
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rare earth
aluminium
bronze alloy
alloy
preparation
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CN1629350A (zh
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路阳
王智平
李文生
苏义祥
许建林
金玉花
朱小武
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Lanzhou University of Technology
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Lanzhou University of Technology
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Abstract

铝青铜合金及其制备方法，按重量百分比计量其成分为：Cu75∽82%，Al13∽16%，Mn0.8∽2.5%，Fe2.5∽5.0%，Co0.2∽2.0%，Ni0.4∽2.0%，Zn0.4∽1.2%，稀土0.2∽2.5%，杂质≤1.0%。本发明的制备方法是按上述成分进行配料，将配好的原材料装入电炉中，在大气气氛中进行熔化，熔清后送入惰性气体进行预精炼，在1250℃保温，进行化学精炼并加入纯稀土进行终脱氧，含气量检验合格后加入覆盖剂，在1260℃保温3-5分钟，在1160-1200℃之间进行浇注。

Description

铝青铜合金及其制备方法
技术领域
本发明涉及合金及其制备方法。
背景技术
目前，用于加工大型板式换热器片、炊饮具、家用电器制品中的一些镜面不锈钢板和钛钢板等的模具一般采用Cr12、Cr12MoV、T10A、Cr15、Cr-Ni等合金钢制造。由于铁基材料相互粘着倾向严重，在拉伸、压延不锈钢坯料时易发生粘模、划伤工件等现象，产品表面滑痕、划伤较重，需要后续抛光工序来对工件进行表面处理，模具损耗严重，修模次数较多。
发明内容
本发明的目的是减少不锈钢及钛钢镜面板片工件生产过程中的滑痕、划伤，提高产品的一级品率，减少模具损耗，提高生产效率。
铝青铜合金，按重量百分比计量其成分为：Cu75～82％，Al13～16％，Mn0.8～2.5％，Fe2.5～5.0％，Co0.2～2.0％，Ni0.4～2.0％，Zn0.4～1.2％，稀土0.2～2.5％，杂质≤1.0％；
上述铝青铜合金的制备方法为：按上述Cu75～82％，Al13～16％，Mn0.8～2.5％，Fe2.5～5.0％，Co0.2～2.0％，Ni0.4～2.0％，Zn0.4～1.2％，杂质≤1.0％的成分进行配料，将配好的原材料装入电炉中在大气气氛中进行熔化，留少量的铝作为预脱氧剂，熔清后吹气预精炼，加入预脱氧剂预进行脱氧，在1250℃保温，进行化学精炼并加入0.2～2.5％的纯稀土进行终脱氧，除渣，含气量检验合格后加入覆盖剂，在1260℃保温3～5分钟，除净渣子，在1160～1200℃之间进行浇注。
本发明的有益效果为：其成分中的铝和铁能提高合金材料的硬度、耐磨性，铜基合金中加入过量(超过固溶度)的铝、铁可以在合金中生成硬质的K相质点，细化合金晶粒，提高合金的硬度和耐磨、减磨性能。加入纯稀土可以净化合金、细化晶粒、强化钢铝固溶体，提高了合金的耐磨和耐腐蚀性能，并有脱氧和排渣能力。镍和钻为铜基合金有效的固溶强化元素，有效地提高了合金的强韧性。合金在铸态时由于成分偏析严重，需要固溶时效热处理后可使其性能满足加工和模具使用要求。发明用于加工大型板式换热器片、炊饮具、家用电器制品中的一些镜面不锈钢板和钛钢板的模具，充分发挥其导热性好、与不锈钢材料的抗粘着性好、良好的耐磨、减磨和耐腐蚀性能以及精细的纹理结构等优点，产品表面质量达到要求，可省去产品的后续抛光工序，产品破损率为外风。模具损耗少，生产20000件修模一次。
具体实施方式
本发明的高强耐磨铝青铜合金，按重量百分比计量其成分为：Cu75～82％，Al13～16％，Mn0.8～2.5％，Fe2.5～5.0％，Co0.2～2.0％，Ni0.4～2.0％，Zn0.4～1.2％，稀土0.2～2.5％，杂质≤1.0％；
按上述合金成分进行配料，将配好的原材料纯电解铜板，电解铝、电解镍、电解锰、电解锌、铁(选用光洁度较好的去油铁丝或铁钉)、电解钴等一次性装入中频电炉中在大气气氛中进行熔化(留少量的铝作为预脱氧剂)，熔清后吹入氮等惰性气体预精炼，加入预脱氧剂预脱氧，在1250℃保温，进行化学精炼并加入0.2～2.5％的纯稀土进行终脱氧，进行化学精炼，然后加入稀土进行终脱氧，耙尽渣子，含气量检验合格后加入覆盖剂保温，1260℃静置3～5分钟，扒净渣子，在1160～1200℃之间进行浇注。
铸件经过固溶时效热处理，加工后可以直接作为模具使用。

Claims (2)

1、铝青铜合金，其特征在于按重量百分比计量其成分为：Cu75～82％，Al13～16％，Mn0.8～2.5％，Fe2.5～5.0％，Co0.2～2.0％，Ni0.4～2.0％，Zn0.4～1.2％，稀土0.2～2.5％，杂质≤1.0％。
2、铝青铜合金的制备方法，其特征在于按权利要求1所述Cu75～82％，Al13～16％，Mn0.8～2.5％，Fe2.5～5.0％，Co0.2～2.0％，Ni0.4～2.0％，Zn0.4～1.2％，杂质≤1.0％的成分进行配料，将配好的原材料装入电炉中，在大气气氛中进行熔化，留少量的铝作为预脱氧剂，熔清后吹气预精炼，加入预脱氧剂预进行脱氧，在1250℃保温，进行化学精炼并加入0.2～2.5％的纯稀土进行终脱氧，含气量检验合格后加入覆盖剂，在1260℃保温3～5分钟，在1160～1200℃之间进行浇注。
CNB2003101222203A 2003-12-16 2003-12-16 铝青铜合金及其制备方法 Expired - Fee Related CN1300355C (zh)

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US9239099B2 (en) 2007-02-16 2016-01-19 Fallbrook Intellectual Property Company Llc Infinitely variable transmissions, continuously variable transmissions, methods, assemblies, subassemblies, and components therefor
US9249880B2 (en) 2007-12-21 2016-02-02 Fallbrook Intellectual Property Company Llc Automatic transmissions and methods therefor
US9273760B2 (en) 2007-04-24 2016-03-01 Fallbrook Intellectual Property Company Llc Electric traction drives
US9279482B2 (en) 2009-04-16 2016-03-08 Fallbrook Intellectual Property Company Llc Continuously variable transmission
US9291251B2 (en) 2010-11-10 2016-03-22 Fallbrook Intellectual Property Company Llc Continuously variable transmission
US9328807B2 (en) 2007-02-01 2016-05-03 Fallbrook Intellectual Property Company Llc Systems and methods for control of transmission and/or prime mover
US9341246B2 (en) 2005-11-22 2016-05-17 Fallbrook Intellectual Property Company Llc Continuously variable transmission
US9360089B2 (en) 2010-03-03 2016-06-07 Fallbrook Intellectual Property Company Llc Infinitely variable transmissions, continuously variable transmissions, methods, assemblies, subassemblies, and components therefor
US9365203B2 (en) 2008-08-05 2016-06-14 Fallbrook Intellectual Property Company Llc Systems and methods for control of transmission and/or prime mover
US9371894B2 (en) 2007-02-12 2016-06-21 Fallbrook Intellectual Property Company Llc Continuously variable transmissions and methods therefor
US9528561B2 (en) 2008-06-23 2016-12-27 Fallbrook Intellectual Property Company Llc Continuously variable transmission
US9574642B2 (en) 2008-10-14 2017-02-21 Fallbrook Intellectual Property Company Llc Continuously variable transmission

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CN101307419B (zh) * 2008-05-29 2010-06-23 燕山大学 一种铝青铜合金晶粒细化的方法
CN103128242A (zh) * 2011-12-01 2013-06-05 胡遐秋 铝青铜半连续铸锭工艺
CN102925733B (zh) * 2012-11-13 2014-09-10 宁波兴业盛泰集团有限公司 一种适用于引线框架用铜合金的多功能覆盖剂
CN103042220A (zh) * 2012-12-14 2013-04-17 浦江汇凯粉体科技有限公司 一种水雾化制备铝青铜粉末的方法
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CN103320644A (zh) * 2013-06-18 2013-09-25 浙江朋诚科技有限公司 一种锥套铝青铜合金
CN103397222A (zh) * 2013-07-01 2013-11-20 安徽三联泵业股份有限公司 不锈钢拉深模具铜合金及其制备方法
CN104607630A (zh) * 2014-11-17 2015-05-13 兰州理工大学 粉末烧结磷光粒子指示复合涂层
CN106048302B (zh) * 2016-08-09 2018-01-02 苏州天兼新材料科技有限公司 一种应用于核电和风电的铸造材料及其制作方法
CN110669958A (zh) * 2018-07-03 2020-01-10 沈阳兴工铜业有限公司 滚压法制备波纹管的辊压轮
CN109706341B (zh) * 2019-01-18 2021-02-12 沈阳金科有色产品研制有限公司 一种含钴高强度高硬度耐磨铜合金及其制备方法

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Cited By (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9341246B2 (en) 2005-11-22 2016-05-17 Fallbrook Intellectual Property Company Llc Continuously variable transmission
US9328807B2 (en) 2007-02-01 2016-05-03 Fallbrook Intellectual Property Company Llc Systems and methods for control of transmission and/or prime mover
US9371894B2 (en) 2007-02-12 2016-06-21 Fallbrook Intellectual Property Company Llc Continuously variable transmissions and methods therefor
US9239099B2 (en) 2007-02-16 2016-01-19 Fallbrook Intellectual Property Company Llc Infinitely variable transmissions, continuously variable transmissions, methods, assemblies, subassemblies, and components therefor
US9273760B2 (en) 2007-04-24 2016-03-01 Fallbrook Intellectual Property Company Llc Electric traction drives
US9574643B2 (en) 2007-04-24 2017-02-21 Fallbrook Intellectual Property Company Llc Electric traction drives
US9249880B2 (en) 2007-12-21 2016-02-02 Fallbrook Intellectual Property Company Llc Automatic transmissions and methods therefor
US9528561B2 (en) 2008-06-23 2016-12-27 Fallbrook Intellectual Property Company Llc Continuously variable transmission
US9365203B2 (en) 2008-08-05 2016-06-14 Fallbrook Intellectual Property Company Llc Systems and methods for control of transmission and/or prime mover
US9574642B2 (en) 2008-10-14 2017-02-21 Fallbrook Intellectual Property Company Llc Continuously variable transmission
US9279482B2 (en) 2009-04-16 2016-03-08 Fallbrook Intellectual Property Company Llc Continuously variable transmission
US9360089B2 (en) 2010-03-03 2016-06-07 Fallbrook Intellectual Property Company Llc Infinitely variable transmissions, continuously variable transmissions, methods, assemblies, subassemblies, and components therefor
US9291251B2 (en) 2010-11-10 2016-03-22 Fallbrook Intellectual Property Company Llc Continuously variable transmission

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