CN1297858A - Clinker cement producing process adding steel slag firstly - Google Patents

Clinker cement producing process adding steel slag firstly Download PDF

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Publication number
CN1297858A
CN1297858A CN99112574A CN99112574A CN1297858A CN 1297858 A CN1297858 A CN 1297858A CN 99112574 A CN99112574 A CN 99112574A CN 99112574 A CN99112574 A CN 99112574A CN 1297858 A CN1297858 A CN 1297858A
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CN
China
Prior art keywords
slag
cement
cement clinker
steel slag
clinker
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN99112574A
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Chinese (zh)
Other versions
CN1121356C (en
Inventor
高振民
邵书东
王书喜
焉立来
张军文
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
CEMENT MILL SHANGDONG TAISHAN IRON & STEEL CORP
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CEMENT MILL SHANGDONG TAISHAN IRON & STEEL CORP
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Publication date
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Priority to CN99112574A priority Critical patent/CN1121356C/en
Publication of CN1297858A publication Critical patent/CN1297858A/en
Application granted granted Critical
Publication of CN1121356C publication Critical patent/CN1121356C/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B7/00Hydraulic cements
    • C04B7/14Cements containing slag
    • C04B7/147Metallurgical slag
    • C04B7/153Mixtures thereof with other inorganic cementitious materials or other activators
    • C04B7/17Mixtures thereof with other inorganic cementitious materials or other activators with calcium oxide containing activators
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P40/00Technologies relating to the processing of minerals
    • Y02P40/10Production of cement, e.g. improving or optimising the production methods; Cement grinding

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)

Abstract

In the clinker cement producing process, the cement raw material includes limestone 68-71 wt%, clay 10-11.5 wt%, anthracite 9.5-11 wt%, steel slag 9-12 wt% and fluorite 0.5-0.8 wt%. Compared with available process of clinker cement producing process utilizing steel slag, the process of the present invention is simple, less in investment, easy in operation and low in cost, and can produce cement with stable performance reaching grade 525.

Description

The preposition method production of slag has the method for cement clinker
The present invention relates to utilize slag production that the method for cement clinker is arranged, the preposition method production of particularly a kind of slag has the method for cement clinker.
To be mineral substance such as clay, Wingdale, hard coal, sulfate slag, fluorite be calcined to after fragmentation mixes traditional cement production process again generates cement clinker about 1400 ℃, cement clinker generates the back common grinding of interpolation part blended material and forms cement, because the Chemical Composition of slag is similar to the cement clinker composition, slag is able to widespread use in manufacture of cement.At present, utilize slag production to have the method for cement clinker to have three kinds: a kind of method is slag directly to be mixed to produce as blended material and cement clinker cement clinker is arranged, adopt the cement clinker that has of this kind method production, its shortcoming is: the cement performance instability, cement early strength and later strength are not good enough, can only produce the following cement of 425# label.Another kind method is that slag directly with after cement clinker mixes is added the part activity excitant again as blended material, adopt the cement clinker that has of this kind method production, because the activity excitant that uses needs special reaction conditions and device, strengthened facility investment, and activity excitant cost height, improved production cost.To also have a kind of method be slag with after cement slurry mixes in rotary kiln again calcination become to have cement clinker, adopt the production of this kind method that cement clinker is arranged, slag and cement slurry need to enter the rotary kiln from two opening for feeds, need special device in the production process, complex process, operation easier is big, and the application investment is also bigger.
The object of the present invention is to provide a kind of production technique simply, need not add the method that activity excitant, less investment, cement performance are stable, the preposition method production of slag that cement mark can reach 525# has cement clinker.
The present invention is achieved in that the preposition method production of this slag has the method for cement clinker, adopt Wingdale, clay, hard coal, slag, fluorite to proportion into raw material, the per-cent of the shared gross weight of its each component is respectively: Wingdale 68-71%, clay 10-11.5%, hard coal 9.5-11%, slag 9-12%, fluorite 0.5-0.8%; Fe in the slag 2O 3Content between 20-40%, slag granularity≤15mm, MgO content≤8.0% in the slag.Its production technique is mainly joining day of slag and prepositionly is the cement slurry mixed processes, at first slag is detected, concentrate stand-by to the slag that meets the employing standard, and then and Wingdale, clay, hard coal, fluorite require combined grinding in proportion, after calcination becomes cement clinker again, add blended material and carry out grinding and produced cement clinker.
The invention has the advantages that: utilize slag production to have the method for cement clinker to compare with existing, production technique is simple, less investment, easy to operate, cement performance stable, production cost is low, cement mark can reach 525#, has high social and economic benefit.
Embodiment 1:
The screening slag is to Fe in the slag 2O 3Content be 20%, slag granularity≤4mm, MgO content is that 4.26% slag is concentrated stand-by in the slag, take by weighing Wingdale 9120kg, clay 1500kg, hard coal 1480kg, slag 1210kg, fluorite 110kg, behind the combined grinding again calcination become cement clinker, add the common grinding of blended material for cement clinker is arranged.This cement clinker performance is after tested as following table one:
Table one
Intensity (Mpa) Mgo SO 3 Specific surface area (m 2/kg) Time of coagulation
3 days 28 days Initial set Final set
Anti-folding Resistance to compression Anti-folding Resistance to compression 2.42 1.02 400 1∶03 2∶32
5.2 38.2 9.1 61.4
Embodiment 2:
The screening slag is to Fe in the slag 2O 3Content be 30%, slag granularity≤6mm, MgO content is that 5.6% slag is concentrated stand-by in the slag, take by weighing Wingdale 9210kg, clay 1410kg, hard coal 1340kg, slag 1410kg, fluorite 70kg, behind the combined grinding again calcination become cement clinker, add the common grinding of blended material for cement clinker is arranged.This cement clinker performance is after tested as following table two:
Table two
Intensity (Mpa) Mgo SO 3 Specific surface area (m 2/kg) Time of coagulation
3 days 28 days Initial set Final set
Anti-folding Resistance to compression Anti-folding Resistance to compression 2.35 1.40 410 0∶54 1∶05
5.5 39 8.9 60.1
Embodiment 3:
The screening slag is to Fe in the slag 2O 3Content be 40%, slag granularity≤8mm, MgO content is that 8.0% slag is concentrated stand-by in the slag, take by weighing Wingdale 9120kg, clay 1340kg, hard coal 1200kg, slag 1610kg, fluorite 68kg, behind the combined grinding again calcination become cement clinker, add the common grinding of blended material for cement clinker is arranged.This cement clinker performance is after tested as following table three:
Table three
Intensity (Mpa) MgO SO 3 Specific surface area (m 2/kg) Time of coagulation
3 days 28 days Initial set Final set
Anti-folding Resistance to compression Anti-folding Resistance to compression 2.1 1.2 400 1:20 2:50
5.3 37 9.0 60.8

Claims (2)

1. the preposition method production of slag has the method for cement clinker, it is characterized in that: each component of cement slurry is: Wingdale, clay, hard coal, slag, fluorite, the per-cent of the shared gross weight of each component is respectively: Wingdale 68-71%, clay 10-11.5%, hard coal 9.5-11%, slag 9-12%, fluorite 0.5-0.8%.
2. the preposition method production of slag according to claim 1 has the method for cement clinker, it is characterized in that: the joining day of slag is preposition to be the cement slurry mixed processes, and slag need be by selected, Fe in its slag 2O 3Content be 20%-40%, slag granularity≤15mm, MgO content≤8.0% in the slag.
CN99112574A 1999-11-25 1999-11-25 Clinker cement producing process adding steel slag firstly Expired - Fee Related CN1121356C (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN99112574A CN1121356C (en) 1999-11-25 1999-11-25 Clinker cement producing process adding steel slag firstly

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN99112574A CN1121356C (en) 1999-11-25 1999-11-25 Clinker cement producing process adding steel slag firstly

Publications (2)

Publication Number Publication Date
CN1297858A true CN1297858A (en) 2001-06-06
CN1121356C CN1121356C (en) 2003-09-17

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Family Applications (1)

Application Number Title Priority Date Filing Date
CN99112574A Expired - Fee Related CN1121356C (en) 1999-11-25 1999-11-25 Clinker cement producing process adding steel slag firstly

Country Status (1)

Country Link
CN (1) CN1121356C (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103601379A (en) * 2013-11-15 2014-02-26 武汉理工大学 Phase-separated clinker calcination process for outside-thrown high-calcium granulated slag
CN114105510A (en) * 2021-12-31 2022-03-01 山东泰山钢铁集团有限公司 Method for producing cement additive by utilizing metallurgical solid waste

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103601379A (en) * 2013-11-15 2014-02-26 武汉理工大学 Phase-separated clinker calcination process for outside-thrown high-calcium granulated slag
CN103601379B (en) * 2013-11-15 2015-09-30 武汉理工大学 A kind of outer high calcium slag sand of throwing calcines phase-splitting grog technique
CN114105510A (en) * 2021-12-31 2022-03-01 山东泰山钢铁集团有限公司 Method for producing cement additive by utilizing metallurgical solid waste

Also Published As

Publication number Publication date
CN1121356C (en) 2003-09-17

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