CN1294105C - Slag sintered aggregate and preparation method thereof - Google Patents
Slag sintered aggregate and preparation method thereof Download PDFInfo
- Publication number
- CN1294105C CN1294105C CNB021342733A CN02134273A CN1294105C CN 1294105 C CN1294105 C CN 1294105C CN B021342733 A CNB021342733 A CN B021342733A CN 02134273 A CN02134273 A CN 02134273A CN 1294105 C CN1294105 C CN 1294105C
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- CN
- China
- Prior art keywords
- slag
- admixtion
- haydite
- rotary kiln
- preparation
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/91—Use of waste materials as fillers for mortars or concrete
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- Processing Of Solid Wastes (AREA)
Abstract
The present invention relates to slag haydite and a preparation method thereof. The slag haydite is characterized in that slag discharged from a coal-fired furnace is used as base materials, 30 to 50% of compounding materials are added, then the mixtures are fired in a rotary kiln to obtain the slag haydite, and the compounding materials are composed of foaming materials and binding materials. The preparation method of the slag haydite comprises the following steps: 1) treating the slag and preparing the compounding materials; 2) measuring and compounding; 3) mixing materials; 4) rolling and balling; 5) drying and calcining in the rotary kiln; 6) expanding; 7) cooling; 8) screening; and 9) manufacturing the finished products of the slag haydite. Because of the adoption of the slag discharged from the coal-fired furnace and used as principal raw materials, the present invention solves the problems of the occupation of placement field for large amounts of the slag, environmental pollution, etc. in the process of industrial production on the one hand, and on the other hand, the present invention changes waste into valuables and produces haydite which has good properties and is applicable to various fields.
Description
Technical field
The present invention relates to a kind of slag sintered aggregate and preparation method thereof, belong to granule type material of construction and industrial production technology field thereof.
Background technology
Haydite is a kind of inorganic light-weight aggregate, is mainly used in insulation, heat insulation in the construction work, and lightweight body of wall, light aggregate concrete, structure also are used for fields such as environmental protection filtration, agricultural planting and building decoration with aspects such as concrete.By retrieval, the patent of relevant haydite and preparation method thereof is a lot, mainly is to be main raw material with clay, shale, flyash, colliery overburden, loess, mud etc., adds expanding material and is prepared from.Because excavation clay, shale, loess, mud etc. can cause soil erosion, environmental pollution, destroy the eubiosis, therefore, are not suitable for applying.With flyash or colliery overburden is the haydite that basic raw material is made, and the density of haydite and intensity are all undesirable.
Summary of the invention
The technical issues that need to address of the present invention are to overcome prior art to utilize clay for raw material is made haydite, caused soil erosion, the shortcoming of environmental pollution, and a kind of slag sintered aggregate and preparation method thereof is provided.
Another technical problem that the present invention need solve is to turn waste into wealth, and the waste slag that coal-fired stove is discharged is made haydite for building.
Technical problem of the present invention can solve by taking following measure: slag sintered aggregate is characterized in: the slag of being discharged by coal-fired stove is a base-material, adds 30%~50% admixtion, adopts rotary kiln to fire and forms; Described admixtion is made up of foam material and matrix material; Described matrix material is a viscosity clay preferably, and described foam material is the Powdered waste residue that produces in marble, artificial marble or ceramic tile, the porcelain plate sanding and polishing process.
The Chemical Composition content of described slag is: Fe
2O
33%~8%, CaO 0.5%~1.2%, Na
2O+K
2O 0.4%~0.6%, Al
2O
314%~25%, SiO
251%~64%, TiO
230%~50%, MgO 0.5%~0.9%, SO
30.3%~0.5%, loss on ignition 3.7%~5.2%.
The Chemical Composition of described admixtion is: Fe
2O
3, CaCO
3, Na
2O, K
2O, SiC, Al
2O
3, SiO
2, TiO
2, MgCO
3, SO
3
The preparation method of foregoing slag sintered aggregate is characterized in: make by following program: 1) slag treatment, admixtion preparation, 2) batching, 3) batch mixing, 4) balling-up, 5) rotary kiln drying, roasting, 6) expanded, 7) cooling, 8) screening, 9) make the slag sintered aggregate finished product, concrete steps are as follows:
1) slag treatment, admixtion preparation:
Slag treatment: remove the foreign material in bulk that boiler discharges, granular, the powdered cinder, and carry out drying, the grinding homogenizing is handled;
Admixtion is handled and preparation: admixtion mainly is made up of foam material and matrix material, removes and carries out drying, grinding, mixing and homogenizing processing in the foam material behind the foreign material, handles carrying out the grinding homogenizing after the matrix material oven dry; Foam material and matrix material after handling are allocated in proportion, and wherein foam material accounts for 40%~80%, and matrix material accounts for 60%~20%;
2) batch mixing: the base-material after will handling, deployed admixtion, allocate by setting weight per-cent, and place mixer to mix until evenly; In compound, add about 15% water, with the old volt of compound, deposited 4~5 hours;
3) balling-up: adopt rotary conveyor that the compound of Chen Fuhou is delivered to the balling-up of roller press type nodulizer, the formation diameter is 5~15 millimeters a spherical particle;
4) rotary kiln drying, roasting: aforementioned spherical particle (pellet) is delivered to rotary kiln with conveyor, utilizing waste heat supply temperature earlier is that 400 ℃ tail gas is dried, the inner chamber that pellet is sent into rotary kiln from the kiln tail carries out roasting then, and firing time is 45~55 minutes;
5) expanded: by expanded, expanded top temperature is 1150~1200 ℃ to pellet in the rotary kiln baking process;
6) cooling: be transported to the cooler cooling or send into the cooler cooling by the discharge port of kiln hood by lifting truck through roasting, the haydite that burns till after expanded;
7) cooled haydite is rejected unacceptable product and is formed the finished product slag sintered aggregate through screening, separation.
The slag sintered aggregate that preceding method is made, its density are 400~1000Kg/m
3, cylindrical compress strength is 2~12Kpa, water-intake rate 3~8%.
The present invention has following beneficial effect:
What 1, the present invention adopted is that the waste residue (being commonly called as slag) that coal-fired stove is discharged be a main raw material, has solved on the one hand that a large amount of slags takies problems such as stacking place, contaminate environment in the Industrial processes, turns waste into wealth on the other hand, produces the haydite of better performances.
2, because the component content of main raw material slag of the present invention is different with other waste residues, so finished product haydite and manufacture method difference all, finished product haydite light weight, water-intake rate is little, intensity good, and the technical indicator of finished product haydite of the present invention is: density is 400~1000Kg/m
3, cylindrical compress strength is 1.5~15Mpa, water-intake rate is 5~15%.
3, because the present invention need not excavate clay, shale, loess, mud etc., therefore energy conserve water soil resource, protection environment help the eubiosis.
Embodiment
Slag sintered aggregate of the present invention, the slag of being discharged by coal-fired stove is a base-material, adds 30%~50% admixtion, adopts rotary kiln to fire and forms.Its preparation method is following seven steps: 1) slag treatment, admixtion preparation, 2) batching, 3) batch mixing, 4) balling-up, 5) rotary kiln drying, roasting, 6) expanded, 7) cooling, screening, the finished product slag sintered aggregate; Wherein:
1) slag treatment, admixtion preparation:
Slag treatment: remove the foreign material in bulk that boiler discharges, granular, the powdered cinder, and carry out drying, the grinding homogenizing is handled;
Admixtion is handled and preparation: admixtion mainly is made up of expanding material and matrix material, removes and carries out drying, grinding, mixing and homogenizing processing in the expanding material behind the foreign material, handles carrying out the grinding homogenizing after the matrix material oven dry; Expanding material and matrix material after handling are allocated in proportion, and wherein expanding material accounts for 40%~80%, and matrix material accounts for 60%~20%;
2) batch mixing: the base-material after will handling, deployed admixtion, allocate by setting weight per-cent, and place mixer to mix until evenly; In compound, add about 15% water, with the old volt of compound, deposited 4~5 hours;
3) balling-up: adopt rotary conveyor that the compound of Chen Fuhou is delivered to the balling-up of roller press type nodulizer, the formation diameter is 5~15 millimeters a spherical particle;
4) rotary kiln drying, roasting: aforementioned spherical particle (pellet) is delivered to rotary kiln with conveyor, utilizing waste heat supply temperature earlier is that 400 ℃ tail gas is dried, the inner chamber that pellet is sent into rotary kiln from the kiln tail carries out roasting then, and firing time is 45~55 minutes;
5) expanded: by expanded, expanded top temperature is 1150~1200 ℃ to pellet in the rotary kiln baking process;
6) cooling: be transported to the cooler cooling or send into the cooler cooling by the discharge port of kiln hood by lifting truck through roasting, the haydite that burns till after expanded;
7) cooled haydite is rejected unacceptable product and is formed the finished product slag sintered aggregate through screening, separation.
Provide the raw material percentage composition of three embodiment below:
Embodiment 1: the percentage amount of selling of slag, admixtion is: slag 70%, admixtion 30%, and admixtion is made up of the binding material and the material that expands, and wherein: binding material accounts for 10, the material that expands accounts for 20%.
Embodiment 2: the percentage amount of selling of slag, admixtion is: slag 60%, admixtion 40%, and admixtion is made up of the binding material and the material that expands, and wherein: binding material accounts for 15, the material that expands accounts for 25%.
Embodiment 3: the percentage amount of selling of slag, admixtion is: slag 50%, admixtion 50%, and admixtion is made up of the binding material and the material that expands, and wherein: binding material accounts for 10, the material that expands accounts for 40%.
According to the stove matter haydite that preceding method is made, the finished product of each embodiment is made pottery and is expected that its density is 400~1000Kg/m
3, cylindrical compress strength is 2~12Kpa, water-intake rate 3~8%.
The Chemical Composition content of the described slag of each embodiment is: Fe
2O
33%~8%, CaO 0.5%~1.2%, Na
2O+K
2O 0.4%~0.6%, Al
2O
314%~25%, SiO
251%~64%, TiO
230%~50%, MgO 0.5%~0.9%, SO
30.3%~0.5%, loss on ignition 3.7%~5.2%.
The Chemical Composition of the described admixtion of each embodiment is: Fe
2O
3, CaCO
3, Na
2O, K
2O, SiC, Al
2O
3, SiO
2, TiO
2, MgCO
3, SO
3
The used matrix material of each embodiment is a viscosity clay preferably, is foam material with the Powdered waste residue that produces in marble, artificial marble and ceramic tile, the porcelain plate sanding and polishing process.
Claims (3)
1, slag sintered aggregate is characterized in that: the slag of being discharged by coal-fired stove is a base-material, adds 30%~50% admixtion, adopts rotary kiln to fire and forms; Described admixtion is made up of foam material and matrix material; Described matrix material is a viscosity clay preferably, and described foam material is the Powdered waste residue that produces in marble, artificial marble or ceramic tile, the porcelain plate sanding and polishing process.
2, slag sintered aggregate as claimed in claim 1 is characterized in that: described admixtion is made by foam material and matrix material, and its Chemical Composition is: Fe
2O
3, CaCO
3, Na
2O, K
2O, SiC, Al
2O
3, SiO
2, TiO
2, MgCO
3, SO
3
3, as the preparation method of the described slag sintered aggregate of the arbitrary claim of claim 1 to 2, it is characterized in that: make: 1) slag treatment, admixtion preparation by following program, 2) batching, 3) batch mixing, 4) the roll-in balling-up, 5) rotary kiln drying, roasting, 6) expanded, 7) cooling, 8) screening, 9) make the slag sintered aggregate finished product, concrete steps are as follows:
1) slag treatment, admixtion preparation:
Slag treatment: remove the foreign material in bulk that boiler discharges, granular, the powdered cinder, and carry out drying, the grinding homogenizing is handled;
Admixtion is handled and preparation: admixtion mainly is made up of foam material and matrix material, removes and carries out drying, grinding, mixing and homogenizing processing in the foam material behind the foreign material, handles carrying out the grinding homogenizing after the matrix material oven dry; Foam material and matrix material after handling are allocated in proportion, and wherein foam material accounts for 40%~80%, and matrix material accounts for 60%~20%;
2) batch mixing: the base-material after will handling, deployed admixtion, allocate by setting weight per-cent, and place mixer to mix until evenly; In compound, add about 15% water, with the old volt of compound, deposited 4~5 hours;
3) balling-up: adopt rotary conveyor that the compound of Chen Fuhou is delivered to the balling-up of roller press type nodulizer, the formation diameter is 5~15 millimeters a spherical particle;
4) rotary kiln drying, roasting: with aforementioned spherical particle, promptly pellet is delivered to rotary kiln with conveyor, and utilizing waste heat supply temperature earlier is that 400 ℃ tail gas is dried, and the inner chamber that pellet is sent into rotary kiln from the kiln tail carries out roasting then; Firing time is 45~55 minutes;
5) expanded: by expanded, expanded top temperature is 1150~1200 ℃ to pellet in the rotary kiln baking process:
6) cooling: be transported to the cooler cooling or send into the cooler cooling by the discharge port of kiln hood by lifting truck through roasting, the haydite that burns till after expanded;
7) cooled haydite is rejected unacceptable product and is formed the finished product slag sintered aggregate through screening, separation.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CNB021342733A CN1294105C (en) | 2002-06-28 | 2002-06-28 | Slag sintered aggregate and preparation method thereof |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CNB021342733A CN1294105C (en) | 2002-06-28 | 2002-06-28 | Slag sintered aggregate and preparation method thereof |
Publications (2)
Publication Number | Publication Date |
---|---|
CN1467178A CN1467178A (en) | 2004-01-14 |
CN1294105C true CN1294105C (en) | 2007-01-10 |
Family
ID=34145726
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CNB021342733A Expired - Fee Related CN1294105C (en) | 2002-06-28 | 2002-06-28 | Slag sintered aggregate and preparation method thereof |
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Families Citing this family (12)
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---|---|---|---|---|
CN102295471B (en) * | 2011-06-17 | 2014-04-23 | 甘伟 | Foaming ceramics material prepared through adopting polishing ceramic slags as main raw material, and preparation method thereof |
CN102372496A (en) * | 2011-08-18 | 2012-03-14 | 陕西延长石油(集团)有限责任公司研究院 | Material formula for preparing gasification furnace slag ceramisite and production method of ceramisite |
CN104649648B (en) * | 2015-03-03 | 2016-10-05 | 成都理工大学 | A kind of method preparing granular permutite for raw material with black shale |
CN105732076A (en) * | 2016-01-20 | 2016-07-06 | 沈阳理工大学 | Preparation method of sludge-furnace slag haydite |
CN106542755B (en) * | 2016-10-24 | 2019-01-22 | 盐城申兴实业有限公司 | Clinker light particle wraps up in shell baking-free ceramicite and preparation method thereof |
CN108863428B (en) * | 2018-07-27 | 2021-04-02 | 广州大学 | Preparation method of medium-granularity ceramic polishing slag ceramsite, prepared ceramic polishing slag ceramsite and application thereof |
CN109627016A (en) * | 2019-02-25 | 2019-04-16 | 广州大学 | A kind of Circulating Fluidized Bed Ash haydites of book structure and preparation method thereof |
CN110229014A (en) * | 2019-06-27 | 2019-09-13 | 上海大学 | A kind of lightweight aggregate and preparation method thereof being prepared using steel mill's sludge |
CN111618069B (en) * | 2020-05-26 | 2021-11-05 | 北京天地丰源环保科技有限公司 | Method for preparing regenerated soil by adopting municipal sludge and agricultural and forestry wastes |
CN112341246A (en) * | 2020-10-08 | 2021-02-09 | 内蒙古建能兴辉陶瓷有限公司 | Raw material and method for manufacturing foamed ceramic based on coal mine stripping layer |
CN112250335A (en) * | 2020-11-02 | 2021-01-22 | 赵生荣 | Energy-saving recovery-based method for manufacturing inert filler balls of waste slag |
CN113461434A (en) * | 2021-07-23 | 2021-10-01 | 大唐同舟科技有限公司 | High-strength ceramsite fired by using coal-fired solid waste and preparation method thereof |
Citations (4)
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---|---|---|---|---|
CN1069254A (en) * | 1992-05-20 | 1993-02-24 | 蒋里军 | A kind of nothing batching production method and haydite and application of porous matter haydite |
CN1102171A (en) * | 1993-10-30 | 1995-05-03 | 井侠 | Ceramics made from coal cinder |
CN1184086A (en) * | 1996-11-29 | 1998-06-10 | 昆明煤炭科学研究所 | Light high-strength haydite and its preparation |
CN1188753A (en) * | 1998-01-10 | 1998-07-29 | 赵光瑞 | Coal cinder ceramsite and preparation method thereof |
-
2002
- 2002-06-28 CN CNB021342733A patent/CN1294105C/en not_active Expired - Fee Related
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1069254A (en) * | 1992-05-20 | 1993-02-24 | 蒋里军 | A kind of nothing batching production method and haydite and application of porous matter haydite |
CN1102171A (en) * | 1993-10-30 | 1995-05-03 | 井侠 | Ceramics made from coal cinder |
CN1184086A (en) * | 1996-11-29 | 1998-06-10 | 昆明煤炭科学研究所 | Light high-strength haydite and its preparation |
CN1188753A (en) * | 1998-01-10 | 1998-07-29 | 赵光瑞 | Coal cinder ceramsite and preparation method thereof |
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CN1467178A (en) | 2004-01-14 |
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Granted publication date: 20070110 Termination date: 20170628 |