CN1293207C - Heat pressing burnt carbon brick for lining and hearth of iron smelting blast furnace - Google Patents

Heat pressing burnt carbon brick for lining and hearth of iron smelting blast furnace Download PDF

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Publication number
CN1293207C
CN1293207C CNB2005100484903A CN200510048490A CN1293207C CN 1293207 C CN1293207 C CN 1293207C CN B2005100484903 A CNB2005100484903 A CN B2005100484903A CN 200510048490 A CN200510048490 A CN 200510048490A CN 1293207 C CN1293207 C CN 1293207C
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Prior art keywords
forming mould
carbon brick
molding
brick
brick fuel
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CN1752218A (en
Inventor
白周成
向左良
刘欣荣
宋木森
白周京
白海钦
白小丽
孟瑞杰
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Henan Crossing Ocean New Materials Technology Co ltd
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GONGYI SHENLONG REFRACTORIES CO Ltd
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Abstract

The present invention discloses a heat-pressing burnt carbon brick for a lining and a hearth of an iron smelting blast furnace, which is prepared from 20 wt% to 50 wt% of electric-calcined anthracite, 10 wt% to 30 wt% of natural graphite, 10 wt% to 30 wt% of artificial graphite, 1 wt% to 5 wt% of metallic silicon, 1 wt% to 5 wt% of silicon oxide, 3 wt% to 10 wt% of aluminum oxide and 10 wt% to 20 wt% of high-temperature asphalt in the following preparation steps: step one, the raw materials are mixed and compounded after being crushed and pulverized; step two, mixed powder obtained in step one is put in a forming mould after being mixed and kneaded and then is kept for 1 to 2 min under the pressure of 3 to 7Mpa, and then a carbon brick formed by prepressing is obtained; step three, the carbon brick formed by prepressing in step two is electrically heated to 800 DEG C to 1100 DEG C in the forming mould, is simultaneously pressurized into 30 to 50Mpa and then is taken out after being kept for 8 to 10 min, and then the heat-pressing burnt carbon brick is obtained through processing and forming in the conventional method. The present invention has the advantages that the profiling burnt step and the calcining burnt step in the traditional producing technology are integrated so that the burnt time is shortened within 10 minutes, and then the production energy consumption of the carbon brick is greatly reduced.

Description

The heat pressing burnt carbon brick that is used for ironmaking blast furnace lining, cupola well
Technical field
The present invention relates to a kind of refractory materials, especially relate to a kind of heat pressing burnt carbon brick that is used for ironmaking blast furnace lining, cupola well.
Background technology
The brick fuel that is used for ironmaking blast furnace lining, cupola well now makes into the of low quality of brick because sintering technology is limit, and the thermal conductivity of its finished product is generally 14W/ (m.k) (600 ℃), Gas permeability is 10mDa, has directly caused the longevity of iron-smelting blast furnace thus; And traditional sintering technology be basically according to: choosing raw material-fragmentation-abrasive dust-batching-mix to pinch-die mould-roasting burn till-processes, burn till in these two technological processs in die mould-roasting, spend for up to more than 20 days, therefore improved energy-output ratio greatly, and production efficiency is low, the production cost height.
Summary of the invention
The object of the present invention is to provide the heat pressing burnt carbon brick that is used for ironmaking blast furnace lining, cupola well that a kind of process period is short, final product quality is high.
For achieving the above object, the present invention can take following technical proposals:
The heat pressing burnt carbon brick that is used for ironmaking blast furnace lining, cupola well of the present invention, it is to be prepared from according to following weight per distribution ratio and step by raw material electric calcined anthracite, natural graphite, synthetic graphite, Pure Silicon Metal, silicon oxide, aluminum oxide, hard pitch:
A, weight percent proportioning:
Electric calcined anthracite 20-50, natural graphite 10-30, synthetic graphite 10-30, Pure Silicon Metal 1-5, silicon oxide 1-5, aluminum oxide 3-10, hard pitch 10-20;
B, preparation process:
The first step will be carried out mix behind above-mentioned raw materials fragmentation, the abrasive dust;
In second step, the mixed powder of getting the first step gained in the forming mould of packing into, under the pressure of 3-7MPa, kept 1-2 minute after mixed pinching, and obtained the brick fuel of pre-molding;
In the 3rd step, the brick fuel of the second step pre-molding switch in forming mould is forced into 30-50MPa when being heated to 800-1100 ℃, keeps after 8-10 minute, and taking-up shapes promptly according to a conventional method.
Described heat pressing burnt carbon brick can be prepared from according to following weight per distribution ratio and step:
A, weight percent proportioning:
Electric calcined anthracite 20, natural graphite 30, synthetic graphite 30, Pure Silicon Metal 1, silicon oxide 1, aluminum oxide 3, hard pitch 15;
B, preparation process:
The first step will be carried out mix behind above-mentioned raw materials fragmentation, the abrasive dust;
In second step, the mixed powder of getting the first step gained in the forming mould of packing into, under the pressure of 3MPa, kept 1 minute after mixed pinching, and obtained the brick fuel of pre-molding;
In the 3rd step, the brick fuel of the second step pre-molding switch in forming mould is forced into 30MPa when being heated to 800 ℃, keeps after 8 minutes, and taking-up shapes promptly according to a conventional method.
Described heat pressing burnt carbon brick also can be prepared from according to following weight per distribution ratio and step:
A, weight percent proportioning:
Electric calcined anthracite 50, natural graphite 20, synthetic graphite 10, Pure Silicon Metal 2, silicon oxide 3, aluminum oxide 5, hard pitch 10;
B, preparation process:
The first step will be carried out mix behind above-mentioned raw materials fragmentation, the abrasive dust;
In second step, the mixed powder of getting the first step gained in the forming mould of packing into, under the pressure of 5MPa, kept 1.5 minutes after mixed pinching, and obtained the brick fuel of pre-molding;
In the 3rd step, the brick fuel of the second step pre-molding switch in forming mould is forced into 40MPa when being heated to 1000 ℃, keeps after 9 minutes, and taking-up shapes promptly according to a conventional method.
Described heat pressing burnt carbon brick also can be prepared from according to following weight per distribution ratio and step:
A, weight percent proportioning:
Electric calcined anthracite 30, natural graphite 10, synthetic graphite 20, Pure Silicon Metal 5, silicon oxide 5, aluminum oxide 10, hard pitch 20;
B, preparation process:
The first step will be carried out mix behind above-mentioned raw materials fragmentation, the abrasive dust;
In second step, the mixed powder of getting the first step gained in the forming mould of packing into, under the pressure of 7MPa, kept 2 minutes after mixed pinching, and obtained the brick fuel of pre-molding;
In the 3rd step, the brick fuel of the second step pre-molding switch in forming mould is forced into 50MPa when being heated to 1100 ℃, keeps after 10 minutes, and taking-up shapes promptly according to a conventional method.
The invention has the advantages that the brick fuel proportioning that has adopted science, and these two steps are burnt till in the die mould-roasting in the traditional processing technology integrate, promptly adopt on the basis behind the pre-molding directly to brick fuel energising heating and pressurization simultaneously, make product under high pressure high temperature burn till fast, firing time was shortened in 10 minutes, this has not only shortened the production cycle that charcoal changes greatly, and makes the energy consumption of producing brick fuel reduce greatly.And the percentage of open area and the air penetrability of finished product brick fuel have been reduced, improved the thermal conductivity of brick fuel, the thermal conductivity and the Gas permeability of the finished product brick fuel of producing according to the present invention are respectively 26W/ (m.k) (600 ℃) and 2.97mDa, and the thermal conductivity of existing finished product brick fuel and Gas permeability are respectively 14W/ (m.k) (600 ℃) and 10mDa.Therefore make the quality of finished product brick fuel be greatly improved, prolonged the work-ing life of iron-smelting blast furnace.
Embodiment
Embodiment 1:
Heat pressing burnt carbon brick of the present invention can be prepared from according to following weight per distribution ratio and step:
A, weight percent proportioning:
Electric calcined anthracite 20, natural graphite 30, synthetic graphite 30,
Pure Silicon Metal 1, silicon oxide 1, aluminum oxide 3, hard pitch 15;
B, preparation process:
The first step will be carried out mix behind above-mentioned raw materials fragmentation, the abrasive dust;
In second step, the mixed powder of getting the first step gained in the forming mould of packing into, under the pressure of 3MPa, kept 1 minute after mixed pinching, and obtained the brick fuel of pre-molding;
In the 3rd step, the brick fuel of the second step pre-molding switch in forming mould is forced into 30MPa when being heated to 800 ℃, keeps after 8 minutes, and taking-up shapes promptly according to a conventional method.
Embodiment 2:
Heat pressing burnt carbon brick of the present invention also can be prepared from according to following weight per distribution ratio and step:
A, weight percent proportioning:
Electric calcined anthracite 50, natural graphite 20, synthetic graphite 10,
Pure Silicon Metal 2, silicon oxide 3, aluminum oxide 5, hard pitch 10;
B, preparation process:
The first step will be carried out mix behind above-mentioned raw materials fragmentation, the abrasive dust;
In second step, the mixed powder of getting the first step gained in the forming mould of packing into, under the pressure of 5MPa, kept 1.5 minutes after mixed pinching, and obtained the brick fuel of pre-molding;
In the 3rd step, the brick fuel of the second step pre-molding switch in forming mould is forced into 40MPa when being heated to 1000 ℃, keeps after 9 minutes, and taking-up shapes promptly according to a conventional method.
Embodiment 3:
Heat pressing burnt carbon brick of the present invention also can be prepared from according to following weight per distribution ratio and step:
A, weight percent proportioning:
Electric calcined anthracite 30, natural graphite 10, synthetic graphite 20,
Pure Silicon Metal 5, silicon oxide 5, aluminum oxide 10, hard pitch 20;
B, preparation process:
The first step will be carried out mix behind above-mentioned raw materials fragmentation, the abrasive dust;
In second step, the mixed powder of getting the first step gained in the forming mould of packing into, under the pressure of 7MPa, kept 2 minutes after mixed pinching, and obtained the brick fuel of pre-molding;
In the 3rd step, the brick fuel of the second step pre-molding switch in forming mould is forced into 50MPa when being heated to 1100 ℃, keeps after 10 minutes, and taking-up shapes promptly according to a conventional method.

Claims (4)

1, a kind of heat pressing burnt carbon brick that is used for ironmaking blast furnace lining, cupola well is characterized in that: it is to be prepared from according to following weight per distribution ratio and step by raw material electric calcined anthracite, natural graphite, synthetic graphite, Pure Silicon Metal, silicon oxide, aluminum oxide, hard pitch:
A, weight percent proportioning:
Electric calcined anthracite 20-50, natural graphite 10-30, synthetic graphite 10-30, Pure Silicon Metal 1-5, silicon oxide 1-5, aluminum oxide 3-10, hard pitch 10-20;
B, preparation process:
The first step will be carried out mix behind above-mentioned raw materials fragmentation, the abrasive dust;
In second step, the mixed powder of getting the first step gained in the forming mould of packing into, under the pressure of 3-7MPa, kept 1-2 minute after mixed pinching, and obtained the brick fuel of pre-molding;
In the 3rd step, the brick fuel of the second step pre-molding switch in forming mould is forced into 30-50MPa when being heated to 800-1100 ℃, keeps after 8-10 minute, and taking-up shapes promptly according to a conventional method.
2, heat pressing burnt carbon brick according to claim 1 is characterized in that: be prepared from according to following weight per distribution ratio and step:
A, weight percent proportioning:
Electric calcined anthracite 20, natural graphite 30, synthetic graphite 30, Pure Silicon Metal 1, silicon oxide 1, aluminum oxide 3, hard pitch 15;
B, preparation process:
The first step will be carried out mix behind above-mentioned raw materials fragmentation, the abrasive dust;
In second step, the mixed powder of getting the first step gained in the forming mould of packing into, under the pressure of 3MPa, kept 1 minute after mixed pinching, and obtained the brick fuel of pre-molding;
In the 3rd step, the brick fuel of the second step pre-molding switch in forming mould is forced into 30MPa when being heated to 800 ℃, keeps after 8 minutes, and taking-up shapes promptly according to a conventional method.
3, heat pressing burnt carbon brick according to claim 1 is characterized in that: be prepared from according to following weight per distribution ratio and step:
A, weight percent proportioning:
Electric calcined anthracite 50, natural graphite 20, synthetic graphite 10, Pure Silicon Metal 2, silicon oxide 3, aluminum oxide 5, hard pitch 10;
B, preparation process:
The first step will be carried out mix behind above-mentioned raw materials fragmentation, the abrasive dust;
In second step, the mixed powder of getting the first step gained in the forming mould of packing into, under the pressure of 5MPa, kept 1.5 minutes after mixed pinching, and obtained the brick fuel of pre-molding;
In the 3rd step, the brick fuel of the second step pre-molding switch in forming mould is forced into 40MPa when being heated to 1000 ℃, keeps after 9 minutes, and taking-up shapes promptly according to a conventional method.
4, heat pressing burnt carbon brick according to claim 1 is characterized in that: be prepared from according to following weight per distribution ratio and step:
A, weight percent proportioning:
Electric calcined anthracite 30, natural graphite 10, synthetic graphite 20, Pure Silicon Metal 5, silicon oxide 5, aluminum oxide 10, hard pitch 20;
B, preparation process:
The first step will be carried out mix behind above-mentioned raw materials fragmentation, the abrasive dust;
In second step, the mixed powder of getting the first step gained in the forming mould of packing into, under the pressure of 7MPa, kept 2 minutes after mixed pinching, and obtained the brick fuel of pre-molding;
In the 3rd step, the brick fuel of the second step pre-molding switch in forming mould is forced into 50MPa when being heated to 1100 ℃, keeps after 10 minutes, and taking-up shapes promptly according to a conventional method.
CNB2005100484903A 2005-11-03 2005-11-03 Heat pressing burnt carbon brick for lining and hearth of iron smelting blast furnace Active CN1293207C (en)

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102992805B (en) * 2012-11-27 2014-12-10 方大炭素新材料科技股份有限公司 High-thermal conductivity ultramicropore carbon brick and preparation method thereof
CN103613393B (en) * 2013-11-11 2017-06-16 中冶南方邯郸武彭炉衬新材料有限公司 A kind of blast furnace lining brick fuel and preparation method thereof
CN103880446A (en) * 2014-03-03 2014-06-25 河南远洋新材料技术有限公司 Anti-erosion high-temperature molded carbon brick
CN103951440B (en) * 2014-03-03 2018-01-05 河南远洋新材料技术有限公司 High heat conduction hot press moulding brick fuel
CN110015898A (en) * 2018-01-09 2019-07-16 东洋炭素(浙江)有限公司 A kind of graphite sealing material and preparation method thereof
CN110395985A (en) * 2019-07-26 2019-11-01 石嘴山市长城碳素有限公司 A kind of carbon furnace lining material production technology
CN110423097B (en) * 2019-09-06 2021-12-28 西北工业大学 Method for rapidly preparing building block without furnace at normal temperature
CN115504786A (en) * 2022-08-29 2022-12-23 浙江工业大学 High-strength hydrophilic porous graphite material and preparation method thereof

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS63100056A (en) * 1986-10-16 1988-05-02 黒崎窯業株式会社 Manufacture of alumina carbon brick for melting portion of metal melting furnace
JPH0380154A (en) * 1989-08-22 1991-04-04 Kawasaki Refract Co Ltd Carbon brick
JPH03205362A (en) * 1989-12-28 1991-09-06 Kawasaki Refract Co Ltd Graphite-silicon carbide refractory brick and production thereof
JP3080154B2 (en) * 1997-08-28 2000-08-21 日本電気株式会社 Magnetic disk drive
CN1290755A (en) * 2000-10-18 2001-04-11 叶乐 High corrosion resistant porous baked carbon brick for lining of blast furnace
JP3205362B2 (en) * 1991-11-01 2001-09-04 ワイケイケイ株式会社 High strength, high toughness aluminum-based alloy
CN1683280A (en) * 2004-04-15 2005-10-19 兰州海龙新材料科技股份有限公司 High heat conductivity carbon brick for blast furnace and its producing method

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS63100056A (en) * 1986-10-16 1988-05-02 黒崎窯業株式会社 Manufacture of alumina carbon brick for melting portion of metal melting furnace
JPH0380154A (en) * 1989-08-22 1991-04-04 Kawasaki Refract Co Ltd Carbon brick
JPH03205362A (en) * 1989-12-28 1991-09-06 Kawasaki Refract Co Ltd Graphite-silicon carbide refractory brick and production thereof
JP3205362B2 (en) * 1991-11-01 2001-09-04 ワイケイケイ株式会社 High strength, high toughness aluminum-based alloy
JP3080154B2 (en) * 1997-08-28 2000-08-21 日本電気株式会社 Magnetic disk drive
CN1290755A (en) * 2000-10-18 2001-04-11 叶乐 High corrosion resistant porous baked carbon brick for lining of blast furnace
CN1683280A (en) * 2004-04-15 2005-10-19 兰州海龙新材料科技股份有限公司 High heat conductivity carbon brick for blast furnace and its producing method

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Address after: Luo Zhen Miao Gongyi city of Henan Province in 451251

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Address after: Luo Zhen Miao village in Gongyi City, Henan Province, 451251 *

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Denomination of invention: Hot pressed fired carbon bricks for ironmaking blast furnace lining and hearth

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