CN1281503A - Process for making liquid fabric softening composition - Google Patents

Process for making liquid fabric softening composition Download PDF

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Publication number
CN1281503A
CN1281503A CN 98811994 CN98811994A CN1281503A CN 1281503 A CN1281503 A CN 1281503A CN 98811994 CN98811994 CN 98811994 CN 98811994 A CN98811994 A CN 98811994A CN 1281503 A CN1281503 A CN 1281503A
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alkyl
composition
nonionic
acid
chain
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H·J·M·德梅耶雷
J·德波尔特雷
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Procter and Gamble Ltd
Procter and Gamble Co
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Procter and Gamble Ltd
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    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005—Other compounding ingredients characterised by their effect
    • C11D3/001—Softening compositions
    • C11D3/0015—Softening compositions liquid
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/74—Carboxylates or sulfonates esters of polyoxyalkylene glycols
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/835—Mixtures of non-ionic with cationic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D11/00—Special methods for preparing compositions containing mixtures of detergents
    • C11D11/0094—Process for making liquid detergent compositions, e.g. slurries, pastes or gels
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/40—Dyes ; Pigments
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38—Cationic compounds
    • C11D1/52—Carboxylic amides, alkylolamides or imides or their condensation products with alkylene oxides
    • C11D1/526—Carboxylic amides (R1-CO-NR2R3), where R1, R2 or R3 are polyalkoxylated
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38—Cationic compounds
    • C11D1/62—Quaternary ammonium compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/72—Ethers of polyoxyalkylene glycols

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Detergent Compositions (AREA)

Abstract

There is provided a process for preparing a liquid softening composition comprising a fabric softener, a nonionic alkoxylated stabilising agent, and a dye component, whereby the resulting softening composition exhibits effective freeze-thaw recovery properties and good dye homogeneity.

Description

The method for preparing liquid fabric softening composition
Invention field
The present invention relates to have the preparation method of the soft compound that contains dyestuff that effectively freezes molten recovery properties
Background of invention
The fabric sofetening product is known in the prior art, is used for providing effective soft effect to handled fabric.Yet existing problem is at low temperatures, and promptly product freezes when 0 ℃ of following temperature is stored, and causes product can not return to the homogeneous dispersion with acceptable flowability matter when being placed on comparatively high temps following time.
Therefore, the purpose of this invention is to provide to have and effectively freeze the molten fabric sofetening product that recovers.
Satisfy a kind of solution of these needs and describe in GB-1098793, it uses the vitriol of aliphatic amide in fabric sofetening composition.
Another solution is described in EP-A-0507478, and it provides mixes cationic fabric softener and melt with nonionic stabiliser, subsequently it is dispersed in the water.Yet the existing problem of this method is to need processing unit, high-shear mixer for example, thus increased preparation cost.
Therefore, another purpose of the present invention provides only needs the fabric sofetening of minimum processing unit product.
It is found that and not use high-shear in the fabric sofetening product processing, the formation of dyestuff color spot increases, and uses high-shear, has avoided forming in the fabric sofetening product not dispersive dye granule.
Therefore, the makers-up of soft compound has good dyestuff homogeneity in the face of preparation, and does not need the double challenge of the soft compound of high shear mixing equipment.
The applicant finds that now adding dye component with the nonionic alkoxy-based surface-active agent in final cold flexible products has satisfied this needs.
In fact, can dyestuff and the oxyalkylated tensio-active agent of nonionic be added in the cold the finished product by simple the mixing.The composition that is obtained obtains uniform dispersion.
The invention has the advantages that the fabric sofetening product of the dilute form by the inventive method preparation with by mixed goods softening agent and nonionogenic tenside, in water, disperse the product of preparation to compare subsequently and need less mechanical shearing.Although do not want to be limited to theory, we think that nonionogenic tenside makes dyestuff become micella, form mictocystis with the softening agent active substance subsequently.Dyestuff disperses effectively by this way, and product obtains the good molten recovery properties of freezing.
Summary of the invention
The present invention relates to prepare the method for liquid fabric softening composition, it comprises the steps:
A)-mix and heating fabric softener and selective additives to form melts;
B)-melts is dispersed in the water;
C)-before adding dyestuff and nonionic alkoxylate stablizer, the dispersion that obtains is cooled under the Krafft temperature of softening agent active substance.
On the other hand, present invention resides in the purposes that molten restorative is frozen in the conduct of nonionic alkoxylate stablizer in the liquid fabric softening composition.
Also have on the one hand, the present invention includes the purposes of nonionic alkoxylate stablizer homogenizing dyestuff in liquid fabric softening composition.
The detailed description nonionic alkoxy-based surface-active agent of invention
Nonionic alkoxylate surface of stability promoting agent is the main ingredient of present method invention.Be used for suitable ionic surfactant pack of the present invention and draw together the adduct of oxyethane and Fatty Alcohol(C12-C14 and C12-C18), lipid acid, aliphatic amide etc.Optionally also can use the adduct of propylene oxide and Fatty Alcohol(C12-C14 and C12-C18), lipid acid, aliphatic amide etc.
Suitable compound is the tensio-active agent of following general formula:
R 2-Y-(C 2H 4O) z-C 2H 4OH is R wherein 2Be selected from primary, the second month in a season and branched-chain alkyl and/or acyl group alkyl; The primary, the second month in a season and branched-chain alkenyl alkyl; With primary, the phenol alkyl of the second month in a season and branched-chain alkyl and alkenyl substituted; Described alkyl preferably has 8 to 20, the alkyl chain length of preferred 10 to 18 carbon atoms.More preferably the alkyl chain length is 12 to 18 carbon atoms.In the general formula of the nonionogenic tenside of ethoxylation of the present invention, Y is-O-,-C (O) O-,-C (O) N (R)-or-C (O) N (R) R-, wherein when existing, R is R 2Or hydrogen and z be at least 5, preferably at least 8.
Nonionogenic tenside of the present invention is characterised in that HLB (hydrophile-lipophile balance value) is 7 to 20, preferred 8 to 15.Certainly, by determining R 2With the number of ethoxylate group, determine the HLB of tensio-active agent usually.Yet, it should be noted, be used for nonionic ethoxylated surfactant of the present invention and contain relative long-chain R 2Group and be the relative height ethoxylation.Although have the HLB that the shorter alkyl chain tensio-active agent of short ethoxylation group can have to be needed, they are not effective in the present invention.
The example of nonionogenic tenside is as follows.Nonionogenic tenside of the present invention is not restricted to these examples.In example, the number of oxyethyl group (EO) in the integer definition molecule.
A. straight chain primary alcohol alcoxylates
Three of dodecanol and tetradecanol-, five-, seven-ethoxylate is useful tensio-active agent in the scope of the invention.Blended ethoxylate natural or synthol also can be used for the present invention in " coconut " chain length scope.The Genapol  that the commercial available straight chain that is used for this paper, primary alconol alcoxylates are obtained by Huls with trade(brand)name Marlipal  24/70, Marlipal  24/100, Marlipal  24/150 and obtained by Hoechst.
B. linear secondary alcoxylates
Three of 3-cetyl alcohol, 2-Stearyl alcohol, 4-eicosanol and 5-eicosanol-, five-, seven-ethoxylate is useful tensio-active agent in the scope of the invention.Being used for the obtainable linear secondary ethoxylate of commerce of the present invention is the material of being sold with trade(brand)name Tergitol 15-S-7 by Union Carbide, and it contains the secondary alcohol of the average alkyl chain length with 11-15 carbon atom and the mixture of the average 7 moles of ethylene oxide condensations of every molar equivalent alcohol.
C. alkylphenol alcoxylates
Suitable alkyl phenolic alkoxy thing is the polyethylene oxide condensation compound of alkylphenol, for example have contain 6-20 carbon atom primary, secondary or a chain configuration, the alkylphenol of the alkyl or alkenyl of preferred 8-12 carbon atom and the condensation product of oxyethane, described oxyethane preferably equal the quantity that 3-is less than 9 moles of ethylene oxide with every mole of alkylphenol and exist.Alkyl substituent can be obtained by polymeric propylene, diisobutylene, octane and nonane in this compound.
The example of this class nonionogenic tenside comprises the ﹠amp by Rohm; The TritonN-57  that Haas obtains, the Lutensol  AP6 of the Dowfax  9N5 of nonyl phenol ethoxylate (5EO), Dow and BASF.
D. olefinic alcoxylates
Can be corresponding to above-mentioned those the alkenyl alcohol of primary and secondary and thiazolinyl phenol by ethoxylation, as tensio-active agent.
The commercial available olefinic alcoxylates that is used for this paper is obtained with trade(brand)name Genapol 0-050 by Hoechst.
E. branched alkoxylates
Improving available side chain primary and secondary alcohol by known " OXO " method or its can be by ethoxylation.Especially preferred uncle OXO alcohol ethoxylate be by BASF with title Lutensol or by Shell Chemicals, U.K., the tensio-active agent that LTD sells with Dobanol.Preferred Dobanol is the alkyl with 9-15 carbon atom, mainly has the primary alconol of the alkyl of 13 carbon atoms.Especially preferably have 3 to being less than 9, the Dobanol of preferred average 5 average degree of ethoxylation.
The example of this class material is the fatty alcohol ethylene oxide condensate, and wherein every mole of fatty alcohol contains 3-and is less than 9 moles of ethylene oxide, and fatty alcohol partly contains 9-14 carbon atom.Other example of this class nonionogenic tenside comprises that some is by Dobanol , the Neodol  of Shell sale or the Lutensol  of BASF.For example Dobanol  23.5 (C12-13EO5), Dobanol  91.5 (C9-11EO5) and Neodol  45E5.
Other suitable nonionic alkoxy-based surface-active agent is with at least 5 alkoxyl group part alkoxylated alkyl group amine.Typical this compounds is the tensio-active agent that oxyethane and the condensation of hydrophobic alkyl amine product obtain.Preferred hydrophobic alkyl contains 6-22 carbon atom.Alkylamine preferably with 10-40, more preferably 20-30 alkoxyl group part alkoxylate.
The example of this class nonionogenic tenside is the commercial alkylamine ethoxylate that is obtained with trade(brand)name Genamin by Hoechst.The suitable example that is used for this paper is GenaminC-100, Genamin 0-150 and Genamin S-200.
Other adequate types in this class nonionogenic tenside is N, N ', and N '-polyoxyethylene (12)-N-butter 1,3 diaminopropanes is obtained with Synprolam with trade(brand)name Ethoduomeen T22 with by ICI by Akzo.
Above-mentioned ethoxylated non-ionic surface active agent is used for present method invention separately or in combination, and term " nonionogenic tenside " comprises the blended nonionogenic tenside.
The preferred nonionic that is used for this paper is the commercial nonionogenic tenside that obtains with trade(brand)name Marlipal  24/100, Marlipal  24/150, Genapol 0-050 and Dobanol91.5.
Nonionogenic tenside is preferably in by final fabric sofetening composition weight 0.05%-5%, and the amount of preferred 0.1%-0.5% by weight adds.Dye component
Dyestuff is a main ingredient of the present invention.Therefore, by mixing colouring agent and nonionic alkoxy-based surface-active agent, subsequently it is added in the cold the finished product, can observe by the formation that dyestuff is added the dyestuff color spot that occurs in the fusion fabric sofetening product and be suppressed by method of the present invention and/or reduce.
Preferred dye component is a water-soluble dye, for example describes in EP754749.
The preferably water miscible dye system of dyestuff is characterized in that dye system contains to be selected from following dyestuff:
1. the quinoline yellow 70 of Colour index number 47005;
2. the Tartrazol yellow XX90 of Colour index number 19140;
3. the orange RGL90 of Colour index number 15985;
4. the ponceau 4R C82 of Colour index number 16255;
5. the blue AE85 of Colour index number 42090;
6. the patent blue V 85/V50 of Colour index number 42051; With
7. their mixture.
Dyestuff is preferably in by final fabric sofetening composition weight 1ppm-200ppm, and the quantity of preferred 5ppm-100ppm by weight adds.
Final fabric sofetening composition contains cationic fabric softener and optional additive usually.Fabric softener
The common add-on of softening compound thing is for pressing composition weight meter 1%-80%, preferred 5%-75%, more preferably 15%-70%, more preferably 19%-65% in soft compound.
Fabric softener compound is preferably selected from positively charged ion, nonionic, both sexes or negatively charged ion fabric sofetening component.The soft component of positively charged ion is quaternary ammonium compound or its amine precursor as giving a definition normally.A)-the soft active compound of the preferred quaternary ammonium fabric of the soft active compound of quaternary ammonium fabric (1) has following formula: Or formula:
Figure 9881199400081
Wherein Q is the carbonyl unit of following formula:
Figure 9881199400082
Each R unit is hydrogen, C independently 1-C 6Alkyl, C 1-C 6Hydroxyalkyl and their mixture, preferable methyl or hydroxyalkyl; Each R 1The unit is straight or branched C independently 11-C 22Alkyl, straight or branched C 11-C 22Thiazolinyl and their mixture, R 2Be hydrogen, C 1-C 4Alkyl, C 1-C 4Hydroxyalkyl and their mixture; X is the negatively charged ion compatible with auxiliary component with fabric softener active matter matter; Subscript m is 1-4, preferred 1; Subscript n is 1-4, preferred 2.
The example of preferred fabric softener active matter matter is the mixture of the quaternary ammonium of following formula: R methyl preferably wherein; R 1Be to contain at least 11 atoms, the straight or branched alkyl or alkenyl chain of preferred at least 15 atoms.In above-mentioned fabrics softening agent example, unit-O 2CR 1The fatty acyl group unit that expression is obtained by the triglyceride level source usually.The triglyceride level source is preferably by butter, partially hydrogenated butter, lard, partially hydrogenated lard, vegetables oil and/or partially hydrogenated vegetables oil, and for example Tower rape oil, Thistle oil, peanut oil, sunflower oil, Semen Maydis oil, soybean oil, Yatall MA, rice bran wet goods and these oily mixtures obtain.
The soft active substance of preferred fabric of the present invention is diester and/or diamide quaternary ammonium (DEQA) compound, and diester and diamide have following formula:
Figure 9881199400091
Wherein R, R 1, X and n be the identical definition that has as in following formula (1) and (2), Q has following formula:
Figure 9881199400092
Or
Figure 9881199400093
These preferred fabric sofetening active substances by amine and fatty acyl group unit process to form the amine intermediate of following formula:
Figure 9881199400094
R methyl preferably wherein, Q and R 1Be as defined above; Quaternary ammonium turns to final softening agent active substance subsequently.
The unrestricted example that is used to form the preferred amines of DEQA fabric sofetening active substance of the present invention comprises the methyl two of following formula (2-hydroxyethyl) amine: The methyl two of following formula (2-hydroxypropyl) amine:
Figure 9881199400096
The methyl of following formula (3-aminopropyl) (2-hydroxyethyl) amine:
Figure 9881199400101
The methyl diethylenetriamine of following formula:
Figure 9881199400102
The trolamine of following formula: Two (2-amino-ethyl) thanomin of following formula:
Above-mentioned counter ion X (-)Can be the compatible negatively charged ion of any softening agent, the negatively charged ion of preferred strong acid, for example muriate, bromide, Methylsulfate, sulfovinate, vitriol, nitrate etc., more preferably muriate or Methylsulfate.Negatively charged ion is all right, but not too preferred, has double charge, wherein X (-)Represent group half.
Butter and Tower rape oil are to be suitable as R of the present invention 1Unitary convenience of unitary fatty acyl group and cheap source.Following is the unrestricted example that is applicable to the quaternary ammonium compound of composition of the present invention.The term " tallow base " that is used for this paper is meant R 1The unit is obtained by butter triglyceride level source, is the unitary mixture of fatty acyl group.Equally, term canola oil base (canolyl) is meant the unitary mixture of the fatty acyl group that is obtained by Tower rape oil.
Table II fabric softener active matter matter
N, N-two (tallow base-oxygen base-ethyl)-N, N-alkyl dimethyl ammonium chloride;
N, N-two (canola oil base-oxygen base-ethyl)-N, N-alkyl dimethyl ammonium chloride;
N, N-two (tallow base-oxygen base-ethyl)-N-methyl, N-(2-hydroxyethyl) ammonium chloride;
N, N-two (canola oil base-oxygen base-ethyl)-N-methyl, N-(2-hydroxyethyl) ammonium chloride;
N, N-two (2-tallow base oxygen base-2-oxo-ethyl)-N, N-alkyl dimethyl ammonium chloride;
N, N-two (2-canola oil base oxygen base-2-oxo-ethyl)-N, N-alkyl dimethyl ammonium chloride;
N, N-two (2-tallow base oxygen base ethyl ketonic oxygen base ethyl)-N, N-alkyl dimethyl ammonium chloride;
N, N-two (2-canola oil base oxygen base ethyl ketonic oxygen base ethyl)-N, N-alkyl dimethyl ammonium chloride;
N-(2-tallow base oxygen base-2-ethyl)-N-(2-tallow base oxygen base-2-oxo-ethyl)-N, the N-alkyl dimethyl ammonium chloride;
N-(2-canola oil base oxygen base-2-ethyl)-N-(2-canola oil base oxygen base-2-oxo-ethyl)-N, the N-alkyl dimethyl ammonium chloride;
N, N, N-three (tallow base-oxygen base-ethyl)-N-ammonio methacrylate;
N, N, N-three (canola oil base-oxygen base-ethyl)-N-ammonio methacrylate;
N-(2-tallow base oxygen base-2-oxoethyl)-N-(tallow base)-N, the N-alkyl dimethyl ammonium chloride;
N-(2-canola oil base oxygen base-2-oxoethyl)-N-(canola oil base)-N, the N-alkyl dimethyl ammonium chloride;
1,2-two tallow base oxygen base-3-N, N, N-trimethyl ammonium propane chloride; With
1,2-two canola oil base oxygen base-3-N, N, N-trimethyl ammonium propane chloride;
Mixture with above-mentioned active substance.
Other example of quaternary ammonium softening compound thing is methyl two (tallow base amido ethyl) (2-hydroxyethyl) ammonium methyl sulphate and methyl two (hydrogenated-tallow group amido ethyl) (2-hydroxyethyl) ammonium methyl sulphate; These materials are obtained with trade(brand)name Varisoft  222 and Varisoft  110 by Witco Chemical Company respectively.
Especially preferred N, N-two (tallow base-oxygen base-ethyl)-N, the N-alkyl dimethyl ammonium chloride, wherein the tallow chain is undersaturated to small part.
The unsaturated content of tallow, Tower rape oil or other fatty acyl group cellular chain is measured by the iodine number (IV) of corresponding lipid acid, and under situation of the present invention, it should be preferably 5-100, and two kinds of famous compounds have and are below or above 25 IV.
In fact, for the compound of the following formula that obtains by tallow fatty acids:
Figure 9881199400121
When IV is 5-25, during preferred 15-20, can find cis/trans isomer weight ratio greater than about 30/70, be preferably greater than approximately 50/50, provide best concentrating capacity more preferably greater than about 70/30.
Surpassed the compound of 25 tallow fatty acids preparation by IV for this class, the ratio of cis and trans-isomer(ide) is found to be not too crucial, unless the very high concentration of needs.
Other suitable example of fabric softener active matter matter is obtained by fatty acyl group; wherein the term in the foregoing description " tallow base " and " canola oil base " are replaced by term " coco group, palmityl, lauryl, oil base, castor oil-base, stearyl, palmityl ", and it is corresponding to obtaining the unitary triglyceride level of fatty acyl group source.These other fatty acyl group sources can be contained fully saturated or preferably to the undersaturated chain of small part.
As mentioned above, the R unit is methyl preferably, yet suitable fabric softener active matter matter is by describing with the term " methyl " in the above-mentioned example in the above-mentioned table II of unit " ethyl, oxyethyl group, propyl group, propoxy-, sec.-propyl, butyl, isobutyl-and the tertiary butyl " displacement.
In the example of table II, counter ion X can be replaced by bromide, Methylsulfate, formate, vitriol, nitrate and composition thereof suitably.In fact, negatively charged ion X only exists as the counter ion of positive charge quaternary ammonium compound.Scope of the present invention is not restricted to any concrete negatively charged ion.
For above-mentioned ester fabric softener, the pH of this paper composition is an important parameter of the present invention.In fact, especially it influences the stability of quaternary ammonium or amine precursor compound under long storage requirement.
Ding Yi pH uses pure composition measuring down at 20 ℃ in the present invention.For the optimum hydrolysis stability of these compositions, in the time of can operating under these compositions are being lower than about 6.0 pH, the pure pH of Ce Dinging is must be preferably about 5 at about 2.0-under these conditions, preferred 2.5-4.5, preferably about 2.5-about 3.5.The pH of these compositions can regulate by adding Bronsted acid.
The example of suitable acid comprises inorganic mineral acid, carboxylic acid, especially lower molecular weight (C 1-C 5) carboxylic acid and alkylsulphonic acid.Suitable mineral acid comprises hydrochloric acid, sulfuric acid, nitric acid and phosphoric acid.Appropriate organic comprises formic acid, acetate, citric acid, methylsulfonic acid and ethyl sulfonic acid.Preferred acid is citric acid, hydrochloric acid, phosphoric acid, formic acid, methylsulfonic acid and phenylformic acid.
When the explanation diester, it will comprise the monoesters that exists usually in preparation in this article.For softness, the percentage ratio of carrying monoesters under the laundry situation at nothing/low washing composition secretly should be low as much as possible, preferably is no more than about 2.5%.Yet, to carry secretly under the laundry situation at high washing composition, some monoesters is preferred.The overall ratio of diester and monoesters is about 100: about 2: 1 of 1-, preferred about 50: about 5: 1 of 1-, more preferably from about 13: about 8: 1 of 1-.Carry secretly under the condition at high washing composition, two/monoesters ratio is preferably about 11: 1.Existing monoester content can be controlled in the softener compound preparation process.
But the mixture of the active substance of preparation formula (1) and (2) also.2)-other suitable quaternary ammonium fabric softening compound thing of being used for this paper is to contain two or more long-chains not have cyclic aliphatic C 8-C 22The positively charged ion of alkyl or a described group and an aralkyl contains nitrogen salt, and it can use separately or as the part of mixture, and it is selected from:
(ⅰ) acyclic quaternary ammonium salt of following formula:
Figure 9881199400131
R wherein 4Be no cyclic aliphatic C 8-C 22Alkyl, R 5Be C 1-C 4Saturated alkyl or hydroxyalkyl, R 8Be selected from R 4And R 5Group, A -It is negatively charged ion as defined above;
(ⅱ) the diamino alkoxy quaternary ammonium salt of following formula: Wherein to equal 1-about 5 for n, R 1, R 2, R 5And A -Be as defined above;
(ⅲ) their mixture.
The example that the positively charged ion of mentioned kind contains nitrogen salt is known dialkyl dimethyl ammonium salt, and for example Varisoft DHT, two tallow base dimethyl methyl ammonium sulfate, two (hydrogenated-tallow group) alkyl dimethyl ammonium chloride, VARISOFT TA100, two docosyl alkyl dimethyl ammonium chlorides, two (hydrogenated-tallow group) alkyl dimethyl ammonium chlorides and Varisoft DHT are preferred.The example that is used for commercial available dialkyl dimethyl ammonium salt of the present invention is two (hydrogenated-tallow group) alkyl dimethyl ammonium chloride (commodity are called Adogen  442), (commodity are called Adogen  470 to Varisoft DHT, Praepagen  3445), VARISOFT TA100 (commodity are called Arosurf  TA-100), obtain by Witco ChemicalCompany.Two docosyl alkyl dimethyl ammonium chlorides are sold with trade(brand)name Kemamine Q-2802C by Humko ChemicalDivision of Witco Chemical Corporation.Dimethyl stearyl benzyl ammonium chloride is sold with trade(brand)name Ammonyx  490 with trade(brand)name Varisoft  SDC with by Onyx Chemical Company by Witco Chemical Company.B)-amine fabric sofetening active compound
The suitable amine fabric soft compound that is used for this paper that can be amine form or cationic form is selected from as follows:
(ⅰ)-reaction product of higher fatty acid and the polyamine that is selected from hydroxyalkyl Alkylenediamine and two alkylene triamine and their mixture.In view of the polyfunctional group structure of polyamine, these reaction product are mixtures of some compounds.
Preferred ingredients (ⅰ) is a nitrogenous compound, and it is selected from the component of some selection of mixture of reaction products or mixture.
A kind of preferred ingredients (ⅰ) is the compound of imidazolinium compounds that is selected from the replacement of following formula: R wherein 7Be no cyclic aliphatic C 15-C 21Alkyl and R 8Be divalence C 1-C 3Alkylidene group.
Component (ⅰ) material is commercial to can be used as following material and obtains: the Mazamide  6 that is sold by Mazer Chemicals or by Sandoz Colors ﹠amp; The Ceranine  HC that Chemicals sells; By Alkaril Chemicals, the stearyl hydroxyethyl tetrahydroglyoxaline that Inc. sells with trade(brand)name Alkazine  ST or by Scher Chemicals, the Schercozoline  S that Inc. sells; N, N "-two tallow base alkyloyl diethylenetriamine; 1-tallow amido ethyl-2-tallow tetrahydroglyoxaline (R in said structure wherein 1Be aliphatic C 15-C 17Alkyl and R 8Be the divalence ethylidene).
Some component (ⅰ) can also at first be dispersed in the pKa value and be no more than in about 4 the Bronsted acid dispersing auxiliary; Its prerequisite is that the pH of final composition is no more than about 6.Some preferred dispersing auxiliary is hydrochloric acid, phosphoric acid or methylsulphonic acid.
N; N "-two tallow base alkyloyl diethylenetriamine and 1-tallow base (amido ethyl)-2-tallow tetrahydroglyoxaline all are reaction product of tallow fatty acids and diethylenetriamine; the precursor that is cationic fabric softener methyl isophthalic acid-tallow amido ethyl-2-tallow imidazoles Methylsulfate is (referring to " as the cats product of fabric softener "; R.R.Egan; Journalof the American Oil Chemicals ' Society; in January, 1978, the 118-121 page or leaf).N, N "-two tallow base alkyloyl diethylenetriamine and 1-tallow base amido ethyl-2-tallow tetrahydroglyoxaline all can obtain as the experimental chemistry product by Witco Chemical Company.Methyl isophthalic acid-tallow amido ethyl-2-tallow imidazoles Methylsulfate is sold with trade(brand)name Varisoft  475 by WitcoChemical Company.
(ⅱ) softening agent of following formula:
Figure 9881199400161
Each R wherein 2Be C 1-6Alkylidene group, preferred ethylidene; With G be Sauerstoffatom or-the NR-group; Each R, R 1, R 2And R 5Have as above definition and A -Has as above X -Definition.
The example of compound (ⅱ) is 1-oil base amido ethyl-2-oil base imidazolium chloride, wherein R 1Be no cyclic aliphatic C 15-C 17Alkyl, R 2Be ethylidene, G is the NH group, R 5Be methyl and A -It is cl anion.
(ⅲ)-softening agent of following formula: Wherein R, R 1, R 2And A -Be as defined above.
The example of compound (ⅲ) is the compound of following formula: R wherein 1Obtain by oleic acid.
Other fabric softener that is used for this paper is at promulgation on April 28th, 1987 Toan Trinh, Errol H.Wahl, the US4661269 of Donald M.Swartley and Ronald L.Hemingway; The US4439335 of the Burns of promulgation on March 27th, 1984; And US3861870, Edwards and Diehl; 4308151, Cambre; 3886075, Bernardino; 4233164, Davis; 4401578, Verbruggen; 3974076, Wiersema and Rieke; 4237016, Rudkine, Clint and Young; And EP472178, Yamamura etc., all above-mentioned documents are classified this paper reference as.
Certainly, term " soft active substance " also can comprise the soft promoting agent of mixing.
The preferred kind of the above-mentioned disclosed softener compound of this paper is the soft active substance compound (DEQA) of diester or diamido quaternary ammonium fabric.
The conventional optional ingredient of other of described liquid fabric softening composition is a liquid vehicle.Suitable liquid vehicle is selected from water, organic solvent and their mixture.The liquid vehicle that is used for the present composition preferably at least mainly is a water, and this is because its low cost, relative available, security and Environmental compatibility.The content of water counts at least 50% by vehicle weight in liquid vehicle, and more preferably at least 60%.Water and lower molecular weight, organic solvent for example＜200, low-molecular-weight alcohol for example, for example the mixture of ethanol, propyl alcohol, Virahol or butanols is a useful carrier liquid.Low-molecular-weight alcohol comprises monohydroxy, dihydroxyl (ethylene glycol etc.), trihydroxy-(glycerine etc.) and senior poly-hydroxy (polyvalent alcohol) alcohol.Optional ingredient
Composition also optionally contains annexing ingredient, for example pH regulator agent, spices, sequestrant, the cats product concentrated assistant, the ionogen concentrated assistant, thickening material, stablizer, for example known antioxidant and reductive agent, soil release polymer, emulsifying agent, sterilant, colorant, sanitas, white dyes, anti-ionization agent, defoamer, enzyme, dye-fixing agent, poly quaternary ammonium compound (Sandofix WE56 for example for example, obtain by Hoechst, or Rewin SFR, obtain by CHT R.Beitlich), poly-amino-functional polymers, disclosed material in the application EP97201488.0 that does not examine for example, dispersible polyolefin, for example the Velustrol  that in the application PCT/US97/01644 that does not examine, describes etc.
The typical amounts of this optional ingredient is by weight 0%-15%.Spices
Term spices comprises the composition of one perfume composition and perfume composition.The selection of any spices is only based on the consideration of aesthetics.
Spices in perfume composition or perfume composition composition can be any odoriferous material or any as the material of eliminating stench reagent.Spices at room temperature mostly is liquid greatly, but also can be the solid of liquefaction, various camphor sample spices for example known in the prior art.Spices can be simple relatively in composition, maybe can contain the very complicated dense mixture of natural or synthetic chemical composition, and all are selected so that any required smell to be provided.
Useful spices is the odoramentum that is deposited in laundry processes on the fabric and is perceived by the normal olfactory organ of human.Many perfume compositions and their smell correction agent and their physics and chemical property are at " spices and flavor chemistry product (aromachemicals) (Perfume andFlavor chemicals (aroma chemicals)) ", Stephen Arctender, volume I and II, Aurthor, Montclair, H.J. with the Merck Index, the 8th edition, Merck ﹠amp; Co., Inc.Rahway provides among the N.J.Perfume composition and composition also can find in the prior art, for example US4145184,4152272,4209417 or 4515705.
The various chemical that are used for the spices purposes are known, comprise for example aldehyde, ketone, ester etc.More generally be, containing the plant and animal oil of natural generation of complex mixture of various chemical compositions and exudate is known as the purposes of spices, this material can be used for herein.Typical spices can contain the wooden/soil property base-material that for example contains foreign matter, for example santal oil, clever civetta and patchouli oil.This spices can also be the light floral odor material, for example rose or violet extract.In addition, can prepare spices so that required fruit aroma to be provided, for example limette, lemon or orange.
The useful perfume composition and the specific examples of mixture are: methyl allylphenol, phenyl aldehyde, jasmal, benzylalcohol, benzyl formate, the acetate iso-bornyl ester, amphene, cis citral (neral), geranial, geraniol, citronellyl acetate, p-cymene, capraldehyde, the dihydro linalool, dihydromyrcenol, dimethylphenyl carbinol, eucalyptus alcohol, geranic acid, Geraniol, acetate spiceleaf alcohol ester, geranonitrile, acetate is suitable-3-hexenyl ester, laurine, the d-limonene, linalool, Linalool oxide, linalyl acetate, propionic acid linalool ester, methyl oaminobenzoate, the Alpha-Methyl ionone, methyl nonyl acetaldehyde, acetate methyl phenyl carbinol ester, left-handed menthyl acetate, piperitone, isomenthone, myrcene, acetate myrcenyl ester, myrcenol, vernol, neryl acetate, acetate nonyl ester, phenylethyl alcohol, α-Pai Xi, beta-pinene, γ-terpinene, α-terpinol, β-terpinol, tirpinyl acetate, acetate is right-tertiary butyl cyclohexyl (acetate right-tert-butylcyclohexyl ester), cinnamic aldehyde in the amyl group, Whitfield's ointment isopentyl ester, β-caryophyllene, cedrene, styryl carbinol, tonka bean camphor, acetate dimethylbenzylcarbinol ester, vanillal, oxymethoxyallylbenzene, isoeugenol, the flower acetic ester, heliotropine, Whitfield's ointment 3-is suitable-the hexenyl ester, hexyl salicylate, Ling Lanquan (right-tertiary butyl-the Alpha-Methyl hydrocinnamic aldehyde), γ-irone, nerolidol, patchouli alcohol, phenyl hexanol, β-selinene, acetate trichloromethyl phenyl methyl alcohol ester, triethyl citrate, Vanillin, veratryl aldehyde, α-Xue Songxi, β-cedrene, C 15H 24Sesquiterpene, benzophenone, benzyl salicylate, brazilic acid ethylidene ester, Jiale muskiness (1,3,4,6,7,8-six hydrogen-4,6,6,7,8,8-hexamethyl-ring penta-γ-2-chromene), hexyl cinnamic aldehyde, lyral (4-(4-hydroxy-4-methyl amyl group)-3-tetrahydrobenzene-10-formaldehyde), vertofix coeur, methyl dihydrojasmonate, methyl-betanaphthyl ketone, musk ambrette, muskidanone, muskone, musk tibetene, xylol Moschus, aurantiol and phenylacetic acid phenethyl ester.
Spices can be by final composition weight 0%-10%, preferred 0.1%-5%, and more preferably the content of 0.2%-3% exists.Fabric softener composition of the present invention provides the fabric spices that improves deposition.Additional component concentrated assistant
According to other component, concentrate composition of the present invention can need organic and/or inorganic concentrated assistant to obtain higher concentration and/or to satisfy higher stability criterion.The tensio-active agent concentrated assistant is selected from the single-long-chain alkyl cats product usually; Nonionogenic tenside; Amine oxide; Lipid acid; Or their mixture, usually the content with the 0-15% of composition uses.Inorganic viscosity/dispersed the control agent that also can be used as or increase tensio-active agent concentrated assistant effect equally comprises water-soluble ionizable salt, and they also optionally add in the composition of the present invention.Can use various ionizable salt.The example of suitable salt is the halogenide of periodic table of elements I A and II A family metal, for example calcium chloride, magnesium chloride, sodium-chlor, Potassium Bromide and lithium chloride.Ionizable salt, is particularly useful in the required viscosity process obtaining preparing composition of the present invention at blending ingredients.The usage quantity of ionizable salt can be regulated according to prescription teacher's needs according to the quantitative changeization of the activeconstituents that uses in composition.The common content that is used for the salt of control combination thing viscosity is by per approximately 1,000,000 part 20 to 20000 parts (ppm) of composition weight meter, is preferably about 20 to about 11000ppm.
Except or replace the above-mentioned water-soluble ionogenic salt, can in composition, add the poly-ammonium salt of alkylidene group with control viscosity.In addition, these reagent can be used as scavenging agent, and are brought by main washing process, and the anionic detergent with on the fabric in rinse cycle forms ion pair, can improve softness.Compare with inorganic electrolyte, these reagent can be in wide temperature range, especially at low temperatures stable viscosity.
The specific examples of the poly-ammonium salt of alkylidene group comprises 1-Methionin mono-hydrochloric salts and 1,5-two ammonium 2-methylpentane dihydrochlorides.Enzyme
Composition of the present invention optionally adopts one or more enzymes, for example lipase, proteolytic enzyme, cellulase, amylase and peroxidase.Being used for preferred enzyme of the present invention is cellulase.In fact, this fermentoid also provides the color nursing efficacy to the processing fabric.Be used for cellulase of the present invention and comprise bacterium and fungal cellulase, they preferably have the pH optimum value between the 5-9.5.US4435307 has disclosed by Humicola insolens or humicola lanuginosa strain DSM 1800 or has belonged to the suitable fungal cellulase that the fungi of the generation cellulase 212 of Aeromonas obtains, and gives birth to the cellulase that the hepatopancreas of soft material Dolabella Auricula Solander extracts from the sea.GB-A-2075028, GB-A-2095275 and DE-OS-2247832 have also disclosed suitable cellulase.CAREZYME  and CELLUZYME  (Novo) are useful especially.Other suitable cellulase is open in WO91/17243, WO96/34092, WO96/34945 and the EP-A-0739982 of Novo.In the practical commercial preparation, typical content is the as many as 5mg (wt) of every gram detergent composition, and more common is the 0.01mg-3mg organized enzyme.In other words, composition of the present invention will contain 0.001%-5% by weight usually, preferred 0.01%-1% commercial enzyme preparation.The activity of zymin can define in particular cases in addition therein, for example for cellulase, and preferred corresponding activity unit (for example CEVU or cellulase viscosity unit of equal value).Composition for example of the present invention can be equivalent to the active content of about 0.5-1000CEVU/ gram composition and contain cellulase.The cellulase preparation that is used to prepare the present composition has the activity of 1000-10000CEVU/ gram usually when liquid form, about 1000CEVU/ restrains when solid form.Stain remover
In the present invention, bringing Selection In property stain remover.Adding stain remover can combine with pre-mixing, combines with acid/water base body, carry out before or after ionogen adds or after the final composition preparation.Soft compound by method preparation of the present invention can contain 0%-10%, the stain remover of preferred 0.2%-5%.This stain remover is polymkeric substance preferably.
The known any polymerization stain remover of those skilled in the art optionally is used for composition of the present invention.The polymerization stain remover is characterised in that to contain simultaneously to be useful on and makes hydrophobic fiber, the hydrophilic segment of polyester and nylon surface hydrophilic and being deposited on the hydrophobic fiber for example, after finishing, whole washing and rinse cycle keep adhering on the fiber, thereby as the hydrophobic fragment of the fixing agent of hydrophilic segment.This can guarantee with easier removing in the spot washing process afterwards of detergent-treatment.
If use, it is about 10.0% that stain remover accounts for about 0.01%-of detergent composition weight of the present invention usually, and it is about 5% typically to be about 0.1%-, preferably about 0.2%-about 3.0%.
Following this paper reference has been described and has been applicable to soil release polymer of the present invention.The US3959230 of the Hays of promulgation on May 25th, 1976; The US3893929 of the Basadur of promulgation on July 8th, 1975; The US4000093 of the Nicol of promulgation on December 28th, 1976 etc.; The US4702857 of the Gosselink of promulgation on October 27th, 1987; The US4968451 of the Scheibel of promulgation on November 6 etc.; The US4702857 of the Gosselink of promulgation on October 27th, 1987; The US4711730 of the Gosselink of promulgation on December 8th, 1987 etc.; The US4721580 of the Gosselink of promulgation on January 26th, 1988; The US4877896 of the Maldonado of promulgation on October 31st, 1989 etc.; The US4956447 of the Gosselink of promulgation on September 11 nineteen ninety etc.; The US5415807 of the Gosselink of promulgation on May 16 nineteen ninety-five etc.; April in 1987 disclosed Kud on the 22nd etc. EP0219048.
Other suitable stain remover is described in following this paper reference: the US4201824 of Violland etc.; The US4240918 of Lagasse etc.; The US4525524 of Tung etc.; The US4579681 of Ruppert etc.; US4240918; US4787989; US4525524; The EP279134A of Rhone-PoulencChemie, 1988; The EP457205A of BASF (1991); With the DE2335044 of UnileverN.V., 1974.
Commercially available stain remover comprises the METOLOSE SM100 that is produced by Shin-etsu Kagaku Kogyo K.K., METOLOSE SM200, SOKALAN class material, for example SOKALAN HP-22, obtain ZELCON 5126 (Dupont) and MILEASE T (ICI) by BASF (Germany).
These stain removers also can be used as the scum dispersion agent.Stablizer
In composition of the present invention, can there be stablizer.The term " stablizer " that the present invention uses comprises antioxidant and reductive agent.The amount of these reagent is for to press composition weight meter 0% to about 2%, for antioxidant, be preferably by composition weight meter about 0.01% to about 0.2% more preferably from about 0.035% to about 0.1%, for reductive agent, more preferably press composition weight meter about 0.01% to 0.2%.For composition and the compound stored with the fusion form, this has guaranteed good odor stable under long storage requirement.For low perfumed product (few spices), it is especially crucial using antioxidant and reductive agent stablizer.
The example that can add the antioxidant of the present composition comprises the mixture of xitix, Quicifal, Propylgallate, and by Eastman Chemical Products, Inc. obtains with trade name Tenox  PG and Tenox  S-1; The mixture of BHT (Yoshinox BHT), BHA (butylated hydroxyanisol), Propylgallate and citric acid, by Eastman Chemical Products, Inc. obtains with trade name Tenox-6 ; Yoshinox BHT is obtained with trade name Sustane  BHT by UOP Process Division; Tertiary butylated hydroquinone, by Eastman Chemical Products, Inc. obtains with trade name Tenox  TBHQ; Natural tocopherol, by Eastman Chemical Products, Inc. obtains with trade name Tenox  GT-1/GT-2; And butylated hydroxyanisol, by Eastman Chemical Products, Inc. obtains with trade name BHA ; Long-chain ester (the C of gallic acid 8-C 22), gallic acid dodecyl ester for example; Irganox  1010; Irganox  1035; Irganox  B1171; Irganox  1425; Irganox  3114; Irganox  3125; With their mixture; Preferred Irganox  3125, Irganox  1425, Irganox  3114 and their mixture; More preferably independent Irganox  3125 or with citric acid and/or other sequestrant mixing of citric acid isopropyl esters for example, Dequest  2010, by Monsanto with chemical name 1-hydroxy ethylene-1,1-di 2 ethylhexyl phosphonic acid (hydroxyl second (fork two) phosphoric acid) obtains, Tiron , by Kodak by chemical name 4, the 5-dihydroxyl--Phenylsulfonic acid/sodium salt obtains, EDDS and DTPA , obtain with the chemical name diethylene triaminepentaacetic acid(DTPA) by Aldrich.Chemical name and CAS numbering for some aforementioned stable agent are listed in the following table II.
The table II
Chemical name Irganox  1010 6683-19-8 four that antioxidant CAS numbering federal regulations code uses ((3,5-di-t-butyl-4-hydroxyl phenylpropionic acid
The methylene radical ester)) methane Irganox  1035 41484-35-9 two (3,5-di-t-butyl-4-hydroxyl phenylpropionic acid)
Sulfo-diethylidene ester Irganox  1098 23128-74-7 N, two (3,5-di-t-butyl-4-hydroxyl hydrocinnamamide) the Irganox  B117 31570-04-4 Irganox  1098 of N '-hexa-methylene and Irgafos  168 1: 1
Two ((3, the 5-di-tert-butyl-4-hydroxyl benzyl) phosphonic acids of 1 23128-74-7 mixture Irganox , 1425 65140-91-2
Mono ethyl ester) two ((3, the 5-di-tert-butyl-4-hydroxyl benzyl) phosphonic acids of calcium Irganox  3114 65140-91-2
Mono ethyl ester) calcium Irganox  3125 34137-09-2 3,5-di-t-butyl-4-hydroxyl phenylpropionic acid three esters
With 1,3,5-three (2-hydroxyethyl)-s-triazine-
2,4,6-(1H, 3H, 5H) triketone Irgafos  168 31570-04-4 three (2, the 4-di-tert-butyl-phenyl) phosphite
The example of reductive agent comprises sodium borohydride, Hypophosporous Acid, 50, Irgafos  168 and their mixture.Method
The method for preparing liquid fabric softening composition of the present invention comprises the steps:
A)-mix and heating fabric softener active matter matter and selective additives to form melts;
B)-melts is dispersed in the water;
C)-before adding dyestuff and nonionic stabiliser, the dispersion that obtains is cooled under the Krafft temperature of softening agent active substance.
The Krafft temperature is meant the temperature the when solubleness of tensio-active agent equals micelle-forming concentration (CMC), and CMC is at M.J ROSEN, tensio-active agent and surface phenomenon (Surfactants andinterfacial phenomena), definition in 1988,215 pages.
Usually product is cooled to and is lower than 25 ℃.
The mixing step of the inventive method preferably carried out 2 minutes with boats and ships type mixing homogenizer.
The dispersion of the step b of method was carried out 10 minutes with 100rpm with the flat blade turbine homogenizer easily, viscosity Brookfield LVT viscometer determining.
C) cooling step of definition uses flat plate heat exchanger (alpha levels) to carry out under about 30 tons/hour with positive-displacement pump easily in.
Dyestuff and nonionic stabiliser are used in the boats and ships type mixing homogenizer cooled product.
Another aspect of the present invention, it provides the described nonionic ethoxylation stablizer purposes that molten restorative is frozen in conduct in liquid fabric softening composition.
" freeze molten restorative " and be meant that the product that obtains still shows effective disperse properties after the freezing-temperature of fusion of long-time experience.
On the other hand, the present invention includes nonionic alkoxylate stablizer and be used for purposes at the liquid fabric softening composition even dye.
The present invention illustrates that with following unrestricted embodiment wherein all percentage ratios are weight basis, except as otherwise noted.
In an embodiment, the component symbol of abbreviation has following implication: DEQA: two (tallow base-oxygen base-ethyl) alkyl dimethyl ammonium chloride DTDMAC: Varisoft DHT lipid acid: tallow fatty acids, IV=18 ionogen: calcium chloride PEG: Macrogol 4000 IPA: Virahol nonionogenic tenside: Marlipal 24/100 is commercially got by Huls
Arrive
Embodiment
Be prepared as follows present method inventive composition:
Component A B C D E
DTDMAC - - - - 4.5
DEQA(85％IPA) 2.6 5.1 6.35 4.12 -
Lipid acid - - - 0.2 -
Nonionogenic tenside 0.1 0.25 0.3 0.35 0.25
Hydrochloric acid 0.02 0.02 0.02 0.02 0.02
Spices 0.10 0.15 0.21 0.28 0.25
Silicone suds suppressor 0.005 0.005 0.005 0.005 0.01
Dyestuff (ppm) 10 10 5 5 10
Water and small number of groups balance-dividing amount to 100

Claims (8)

1. method for preparing liquid fabric softening composition, it comprises the steps:
A)-mix and heating fabric softener active matter matter and optionally additive with the formation melts;
B)-melts is dispersed in the water;
C)-before adding dyestuff and nonionic stabiliser, the dispersion that obtains is cooled under the Krafft temperature of softening agent active substance.
2. according to the process of claim 1 wherein that described nonionic stabiliser is selected from:
R 2-Y-(C 2H 4O) z-C 2H 4OH is R wherein 2Be selected from primary, the second month in a season and branched-chain alkyl and/or acyl group alkyl; The primary, the second month in a season and branched-chain alkenyl alkyl; With primary, the phenol alkyl of the second month in a season and branched-chain alkyl and alkenyl substituted; Wherein Y be-O-,-C (O) O-,-C (O) N (R)-or-C (O) N (R) R-; Wherein z is at least 5.
3. according to the method for claim 2, the alkyl of wherein said nonionic stabiliser has 8 to 20, the chain length of preferred 10 to 18 carbon atoms.
4. according to one of any method of claim 1-3, wherein said nonionic stabiliser is selected from straight chain primary alcohol alcoxylates, linear secondary alcoxylates, alkylphenol alcoxylates, olefinic alcoxylates, branched alkoxylates and their mixture.
5. according to one of any method of claim 1-4, wherein said nonionic alkoxylate stablizer adds in the cold final fabric sofetening composition in the content by liquid soft compound weight 0.05%-5%.
6. according to one of any method of claim 1-5, wherein spices is added in the cold the finished product.
Among claim 1-5 one of any the nonionic alkoxylate stablizer of definition in liquid fabric softening composition as the purposes of freezing molten restorative.
8. the nonionic alkoxylate stablizer of definition is used for purposes at the liquid fabric softening composition even dye among claim 1-5 one of any.
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CN102712877B (en) * 2010-01-13 2014-08-20 宝洁公司 Method of producing a fabric softening composition
CN103154223A (en) * 2010-10-22 2013-06-12 荷兰联合利华有限公司 Improvements relating to fabric conditioners
CN103154223B (en) * 2010-10-22 2015-12-16 荷兰联合利华有限公司 Relate to the improvement of fabric conditioner
CN106167983A (en) * 2016-07-01 2016-11-30 潘明华 A kind of antibiotic antistatic medicated clothing softening agent and preparation method thereof

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