CN1247725C - Environment-friendly all-purpose adhesive and production method thereof - Google Patents
Environment-friendly all-purpose adhesive and production method thereof Download PDFInfo
- Publication number
- CN1247725C CN1247725C CN 200410037322 CN200410037322A CN1247725C CN 1247725 C CN1247725 C CN 1247725C CN 200410037322 CN200410037322 CN 200410037322 CN 200410037322 A CN200410037322 A CN 200410037322A CN 1247725 C CN1247725 C CN 1247725C
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- environment
- rosin
- production method
- friendly
- universal glue
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- Expired - Fee Related
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- 238000004519 manufacturing process Methods 0.000 title claims description 20
- 230000001070 adhesive effect Effects 0.000 title abstract description 16
- 239000000853 adhesive Substances 0.000 title abstract description 14
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 claims abstract description 38
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 claims abstract description 38
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 claims abstract description 38
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 claims abstract description 36
- 239000011347 resin Substances 0.000 claims abstract description 31
- 229920005989 resin Polymers 0.000 claims abstract description 31
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 claims abstract description 25
- 239000002904 solvent Substances 0.000 claims abstract description 22
- 239000003208 petroleum Substances 0.000 claims abstract description 18
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 claims abstract description 12
- 238000003756 stirring Methods 0.000 claims description 42
- 239000003292 glue Substances 0.000 claims description 19
- 239000002994 raw material Substances 0.000 claims description 15
- WSLDOOZREJYCGB-UHFFFAOYSA-N 1,2-Dichloroethane Chemical compound ClCCCl WSLDOOZREJYCGB-UHFFFAOYSA-N 0.000 claims description 13
- 238000000034 method Methods 0.000 claims description 2
- 230000000694 effects Effects 0.000 abstract description 8
- 239000004033 plastic Substances 0.000 abstract description 5
- 229920003023 plastic Polymers 0.000 abstract description 5
- 231100000331 toxic Toxicity 0.000 abstract description 4
- 230000002588 toxic effect Effects 0.000 abstract description 4
- 244000184861 Juglans nigra Species 0.000 abstract description 2
- 235000013740 Juglans nigra Nutrition 0.000 abstract description 2
- SCYULBFZEHDVBN-UHFFFAOYSA-N 1,1-Dichloroethane Chemical compound CC(Cl)Cl SCYULBFZEHDVBN-UHFFFAOYSA-N 0.000 abstract 1
- YJTKZCDBKVTVBY-UHFFFAOYSA-N 1,3-Diphenylbenzene Chemical group C1=CC=CC=C1C1=CC=CC(C=2C=CC=CC=2)=C1 YJTKZCDBKVTVBY-UHFFFAOYSA-N 0.000 abstract 1
- 239000010985 leather Substances 0.000 abstract 1
- 238000002360 preparation method Methods 0.000 abstract 1
- 150000003505 terpenes Chemical class 0.000 abstract 1
- 235000007586 terpenes Nutrition 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
- 239000000463 material Substances 0.000 description 17
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 9
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 9
- 239000003921 oil Substances 0.000 description 9
- 239000003795 chemical substances by application Substances 0.000 description 6
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 3
- 238000004090 dissolution Methods 0.000 description 3
- 230000007613 environmental effect Effects 0.000 description 3
- 239000008096 xylene Substances 0.000 description 3
- 238000009472 formulation Methods 0.000 description 2
- 231100000053 low toxicity Toxicity 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 239000002939 oilproofing Substances 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 238000004078 waterproofing Methods 0.000 description 2
- 239000004821 Contact adhesive Substances 0.000 description 1
- 239000004831 Hot glue Substances 0.000 description 1
- 206010033307 Overweight Diseases 0.000 description 1
- 238000004026 adhesive bonding Methods 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 231100000957 no side effect Toxicity 0.000 description 1
- 239000012454 non-polar solvent Substances 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 230000001473 noxious effect Effects 0.000 description 1
- 235000020825 overweight Nutrition 0.000 description 1
- 231100000572 poisoning Toxicity 0.000 description 1
- 230000000607 poisoning effect Effects 0.000 description 1
- 239000002798 polar solvent Substances 0.000 description 1
- 239000005060 rubber Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 229920003048 styrene butadiene rubber Polymers 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
The invention discloses an environment-friendly all-purpose adhesive which is prepared from SBS, petroleum resin, polymerized rosin, terpene resin, cyclohexane, dichloromethane, ethyl acetate, No. 6 solvent oil and dichloroethane. The invention also discloses a preparation method of the environment-friendly all-purpose adhesive. The all-purpose adhesive provided by the invention does not contain triphenyl, has no toxic or side effect, is high in bonding strength, short in curing time, water-resistant and oil-resistant and convenient to construct. It is especially suitable for adhering fireproof plate, aluminum-plastic plate, black walnut panel, etc. and may be also used in adhering cabinet, furniture, sedan, handicraft, various decorative door plate, plastic and leather products, etc.
Description
Technical field
The present invention relates to a kind of tackiness agent, is a kind of environment-friendly universal glue of benzene-free and low toxic, also relates to the production method of this kind multi-purpose adhesive.
Background technology
Multi-purpose adhesive is a kind of tackiness agent commonly used, is widely used in the numerous areas such as production of home decoration, family property manufacturing, car manufacturing, leatherware, mainly bonding as between the differing materials.Multi-purpose adhesive mainly is made of base-material, the solvent of macromolecular material, also is added with various fillers according to what different purposes had.Different polymer base-materials is determining the performance of tackiness agent bonded joint, is the principal element that influences the tackiness agent quality; Solvent for use then influences the workability of tackiness agent, also has influence on its adhesiveproperties simultaneously; And the effect of auxiliary agent is to improve the physical and mechanical properties and the cost of product.
Present multi-purpose adhesive generally contains benzene,toluene,xylene etc., and " triphen " content is severe overweights all generally, and this type organic all has toxicity, in use or use these objectionable impuritiess of back constantly to evaporate, can cause various harm to people's health.At present, the poisoning of the benzene,toluene,xylene that causes because of multi-purpose adhesive etc. happens occasionally, and has caused bigger harm for victim's health, spirit and family.
But; raising along with people's living standard; when people's living environment, living facilities, living condition are constantly improved; there is not glue paste very difficult in contact adhesive or life on every side, the Working environment; so exploitation environment-friendly type tackiness agent nontoxic or low toxicity is a needs of society, also meets the national environmental protection policy.
Summary of the invention
The object of the present invention is to provide a kind of environment-friendly universal glue that has no side effect, this all-purpose adhesive does not only have toxic side effect, and with low cost, adhesiveproperties good, applied widely.
Environment-friendly universal glue provided by the invention comprises following components by part by weight:
SBS (thermoplastic styrene butadiene rubber) 88-380
Petroleum resin 15-35
Polymerized rosin 8-16
Rosin 15-25
Terpine resin 140-280
Hexanaphthene 1-6
Methylene dichloride 1-8
Ethyl acetate 80-180
6# solvent oil 230-530.
The superfine multi-purpose adhesive of above-mentioned environment-friendly type can also contain an amount of ethylene dichloride.
The preferable consumption of described ethylene dichloride is 40-280 part.
According to concrete service requirements, also can add a little auxiliary.
This multi-purpose adhesive of the present invention does not contain noxious solvents such as benzene,toluene,xylene, so this environment-friendly universal glue of the present invention does not have toxic side effect, and compliance with environmental protection requirements.Multi-purpose adhesive of the present invention is main base-material with SBS, terpine resin, and the SBS surface energy is low, cohesive strength is high, certain elasticity is arranged, so be easy to wettingly by the sticky object surface, and very high bonding strength is arranged; Terpine resin then is a hot melt adhesive base-material preferably, and with an amount of petroleum resin, polymerized rosin, rosin tackify, the cementability of not only this environment-friendly universal glue is good, bonding force is strong, Waterproofing/oilproofing, also have applied widelyly, characteristics that can bonding multiple material are a kind of real " omnipotent " glue.With 6# solvent oil and ethyl acetate, ethylene dichloride is a primary solvent, and be equipped with an amount of hexanaphthene, methylene dichloride, reasonably polar solvent mixes use with non-polar solvent, not only solute effect is good, make the molecule of polymer base-material be easy to stretch and move, improved the cohesive strength of multi-purpose adhesive, make its bonding strength and stripping strength height, and because the volatility difference of all kinds of SOLVENTS, make the evaporation rate of solvent more reasonable, not only be easy to the gluing operation, and the dewfall phenomenon that is not prone to dry hide or causes because of solvent evaporates is too fast, not only use conveniently, and guarantee bonding quality.
So this environment-friendly universal glue provided by the invention has the advantage of environmental protection low toxicity, superb bond strength, and set time weak point, Waterproofing/oilproofing, easy construction.Be particularly suitable for finishing material such as bonding PLASTIC LAMINATED, aluminium-plastic panel, black walnut panel skin, the bonding and various door trim panels that also can be used for bonding cabinet and family property production, Car Manufacturing, artwork are bonding, plastics and leatherware bonding etc.Environment-friendly universal glue of the present invention, the bonding back of aluminium-rubber stripping strength in the time of 24 hours reaches 4.7N/mm.
The present invention also provides a kind of production method of above-mentioned environment-friendly universal glue, and this method comprises the steps:
(1) gets the raw materials ready: smash into polymerized rosin, petroleum resin, rosin to pieces homogeneous bulky earlier, or wear into broken end;
(2) the 6# solvent oil is added in the stirring tank; If there is ethylene dichloride also will add simultaneously in the stirring tank;
(3) petroleum resin and rosin are added respectively in the stirring tank, again SBS and terpine resin are added in the stirring tank, build and stir the kettle cover mouth, start motor then and stir after 3 hours, stop motor;
(4) add methylene dichloride and ethyl acetate, hexanaphthene, polymerized rosin again, start motor once more, be continuously stirring to that raw material dissolves fully in the still, stop operating;
(5) test pH value 〉=5.1 o'clock can go out finished product.
This production method provided by the invention, the arranging raw material scientific and reasonable according to the solubility property between used base-material and coordinative solvent adds order, so the speed that each base-material is dissolved in the solvent is very fast, compare with raw material directly being added stir together in the still, with short production cycle, and compound initial driving force viscosity is low in the still, and the stir current of stirring tank is little, can save electric energy.
Embodiment
Below in conjunction with specific embodiment environment-friendly universal glue of the present invention and production method thereof are specified, to help understanding content of the present invention.
Equipment used comprises one of the electronic whipping device of stainless steel cauldron, one of 2 of material loading fire proof motor mateiral pumps and artificial stamp mill.
Embodiment 1
Raw materials used prescription is:
SBS90kg, petroleum resin 17kg, polymerized rosin 16kg, rosin 25kg, terpine resin 140kg, hexanaphthene 2.7kg, methylene dichloride 1.9kg, ethyl acetate 84kg, 6# solvent oil 313.4kg, ethylene dichloride 43.3kg.
Its production method is: get the raw materials ready (1): will smash into the homogeneous bulky that diameter is approximately 50mm to pieces with artificial stamp mill by polymerized rosin, petroleum resin, rosin that prescription is weighed at normal temperatures, and can wear into broken last better effects if, and dissolve more piece.(2) with in the 6# solvent oil and ethylene dichloride suction stirring tank of mateiral pump with the described weight of above-mentioned prescription, spill outward, reduce the danger that environmental pollution was wasted and caused to material, and reduce labour intensity to avoid manually toppling over the material that causes.(3) by the described weight of prescription petroleum resin and rosin are poured into respectively in the stirring tank, again SBS and terpine resin are added in the stirring tank by the formulation weight requirement, build and stir the kettle cover mouth, start motor then and stir after 3 hours, stop motor.(4) open and stir the kettle cover mouth, this moment material dissolution such as rosin a part, add methylene dichloride and ethyl acetate, hexanaphthene, polymerized rosin by formulation weight again, start motor once more, continuously stirring 4 hours makes that raw material dissolves fully in the still, stops operating.(5) open and stir the kettle cover mouth, test pH value 〉=5.1 o'clock can go out finished product.
Embodiment 2
Raw materials usedly be:
SBS338.4kg, petroleum resin 34kg, polymerized rosin 9kg, rosin 17kg, terpine resin 270kg, hexanaphthene 5kg, methylene dichloride 8kg, ethyl acetate 170kg, 6# solvent oil 530kg, ethylene dichloride 58.7kg.
Its production method is: get the raw materials ready (1): smash into polymerized rosin, petroleum resin, the rosin of above-mentioned weight to pieces homogeneous bulky that diameter is approximately 50mm at normal temperatures, can wear into broken last better effects if, dissolve more piece.(2) with in the 6# solvent oil and ethylene dichloride suction stirring tank of mateiral pump with above-mentioned weight.(3) petroleum resin and the rosin of above-mentioned weight are poured into respectively in the stirring tank, again SBS and terpine resin are added in the stirring tank by above-mentioned weight, build and stir the kettle cover mouth, start motor then and stir after 3 hours, stop motor.(4) open and stir the kettle cover mouth, this moment material dissolution such as rosin a part, add methylene dichloride and ethyl acetate, hexanaphthene, polymerized rosin by above-mentioned weight again, start motor once more, continuously stirring 4 hours makes that raw material dissolves fully in the still, stops operating.(5) open and stir the kettle cover mouth, test pH value 〉=5.1 o'clock can go out finished product.
Embodiment 3
Raw materials usedly be:
SBS192.1kg, petroleum resin 25kg, polymerized rosin 11kg, rosin 20kg, terpine resin 180.2kg, hexanaphthene 4kg, methylene dichloride 5kg, ethyl acetate 155.6kg, 6# solvent oil 416.6kg, ethylene dichloride 55.5kg.
Its production method is: get the raw materials ready (1): smash into polymerized rosin, petroleum resin, the rosin of above-mentioned weight to pieces homogeneous bulky that diameter is approximately 50mm at normal temperatures, can wear into broken last better effects if, dissolve more piece.(2) with in the 6# solvent oil and ethylene dichloride suction stirring tank of mateiral pump with above-mentioned weight.(3) petroleum resin and the rosin of above-mentioned weight are poured into respectively in the stirring tank, again SBS and terpine resin are added in the stirring tank by above-mentioned weight, build and stir the kettle cover mouth, start motor then and stir after 3 hours, stop motor.(4) open and stir the kettle cover mouth, this moment material dissolution such as rosin a part, add methylene dichloride and ethyl acetate, hexanaphthene, polymerized rosin by above-mentioned weight again, start motor once more, continuously stirring 4 hours makes that raw material dissolves fully in the still, stops operating.(5) open and stir the kettle cover mouth, test pH value 〉=5.1 o'clock can go out finished product.
Claims (8)
1, a kind of environment-friendly universal glue comprises following components by part by weight:
SBS 88-380
Petroleum resin 15-35
Polymerized rosin 8-16
Rosin 15-25
Terpine resin 140-280
Hexanaphthene 1-6
Methylene dichloride 1-8
Ethyl acetate 80-180
6# solvent oil 230-530.
2, environment-friendly universal glue as claimed in claim 1 also contains the ethylene dichloride of 40-280 weight part in the said components.
3, the production method of the described environment-friendly universal glue of a kind of claim 1, this method comprises the steps:
(1) gets the raw materials ready: smash into polymerized rosin, petroleum resin, rosin to pieces homogeneous bulky earlier, or wear into broken end;
(2) the 6# solvent oil is added in the stirring tank;
(3) petroleum resin and rosin are added respectively in the stirring tank, again SBS and terpine resin are added in the stirring tank, build and stir the kettle cover mouth, start motor then and stir after 3 hours, stop motor;
(4) add methylene dichloride and ethyl acetate, hexanaphthene, polymerized rosin again, start motor once more, be continuously stirring to that raw material dissolves fully in the still, stop operating;
(5) test pH value 〉=5.1 o'clock can go out finished product.
4, polymerized rosin, petroleum resin, rosin are all smashed into the homogeneous bulky of 50mm to pieces in the production method of environment-friendly universal glue as claimed in claim 3, described step (1).
5, the production method of environment-friendly universal glue as claimed in claim 3, described step (4) the continuously stirring time is 4 hours.
6, the production method of environment-friendly universal glue as claimed in claim 3 also adds ethylene dichloride simultaneously in the described step (2).
7, the production method of environment-friendly universal glue as claimed in claim 6, described step (2) solvent oil and ethylene dichloride adopt the mateiral pump suction stirring tank of band fire proof motor.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200410037322 CN1247725C (en) | 2004-04-27 | 2004-04-27 | Environment-friendly all-purpose adhesive and production method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200410037322 CN1247725C (en) | 2004-04-27 | 2004-04-27 | Environment-friendly all-purpose adhesive and production method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1570006A CN1570006A (en) | 2005-01-26 |
| CN1247725C true CN1247725C (en) | 2006-03-29 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 200410037322 Expired - Fee Related CN1247725C (en) | 2004-04-27 | 2004-04-27 | Environment-friendly all-purpose adhesive and production method thereof |
Country Status (1)
| Country | Link |
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| CN (1) | CN1247725C (en) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101503601B (en) * | 2009-02-25 | 2013-05-08 | 山东常青树化工有限公司 | Preparation technique of solid universal glue |
| CN101608104B (en) * | 2009-07-21 | 2010-08-11 | 上海工程技术大学 | Inorganic whisker modified SBS segmented copolymer adhesive and preparation method thereof |
| CN104710954A (en) * | 2015-04-10 | 2015-06-17 | 广东东方树脂有限公司 | Nail-free all-purpose adhesive and preparation method thereof |
| CN107286882A (en) * | 2016-04-13 | 2017-10-24 | 沈阳天狗装饰材料有限公司 | A kind of flame-retarding |
| CN106893330A (en) * | 2017-04-05 | 2017-06-27 | 合肥悦兰信息技术有限公司 | A kind of liquid explosion-proof lamp for electric elements |
| CN106832431A (en) * | 2017-04-05 | 2017-06-13 | 合肥悦兰信息技术有限公司 | A kind of preparation method of liquid explosion-proof lamp |
-
2004
- 2004-04-27 CN CN 200410037322 patent/CN1247725C/en not_active Expired - Fee Related
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| Publication number | Publication date |
|---|---|
| CN1570006A (en) | 2005-01-26 |
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Granted publication date: 20060329 Termination date: 20140427 |