Summary of the invention
The technical problem to be solved in the present invention provides a kind of killing rate height, Brontispa longissima is had the agricultural chemicals host of special efficacy preventive and therapeutic effect and with its preparation of making and using method.
The technical scheme that addresses the above problem is:
The agricultural chemicals host of control Brontispa longissima is the composition that mainly comprises following mass ratio (m/m) active ingredient:
The pyrrole worm is clear: desinsection list or Methomyl=1: 0.1~40
The preferred version of above-mentioned host active ingredient mass ratio is:
The pyrrole worm is clear: desinsection list or Methomyl=1: 0.5~10
The selected pyrrole worm of host of the present invention is clear, desinsection list and Methomyl all have stronger interior absorption, the lobus cardiacus of inspiration babassu in being easy to, kill the Brontispa longissima in the lobus cardiacus that does not launch, the pyrrole worm is insoluble in water clearly, have slow and lasting effect, desinsection list or Methomyl are soluble in water, have quick-acting, and clear and desinsection list of pyrrole worm or Methomyl are mixed and can make agricultural chemicals all have fine control efficiency in a long time.
Be made up of host and assistant agent with the insecticide pulvis that above-mentioned host is made, its host active ingredient mass content is 0.1~70%, and preferred content is 5~50%, and the assistant agent of forming pulvis is the mixture that comprises following mass ratio (m/m) effective ingredient:
Anti-caking agent: water absorbing agent: antioxidant: anti-photodissociation agent: filler
=1~20∶1~15∶3~20∶2~20∶10~70;
Described anti-caking agent is selected from one or more of following compositions: alkylbenzenesulfonate, naphthalene sulfonate, alkylnaphthalene sulfonate, the poly-ethyl ether sulfonate of alkyl phenol, fatty alcohol ethylene oxide adduct sulfonate, alkyl phenol, fatty alcohol ethylene oxide adduct phosphate, alkylamine salt, diisopropyl phosphate ester salt, isopropyl phosphoric acid ester;
Described water absorbing agent is selected from one or more of following compositions: Super absorbent polymers (SAP), Sodium Polyacrylate, polyacrylic acid-acrylonitrile, polyacrylic acid-vinyl acetate, polyvinyl alcohol graft copolymerized acrylic acid;
Described antioxidant is selected from one or more of following compositions: eugenol, sodium hydrogensulfite, ethoxyquin, L-cysteine, vitamin E, vitamin C, beta carotene, Tea Polyphenols, BHA, BHT, TBHQ, epoxidized soybean oil;
Described anti-photodissociation agent is selected from one or more of following compositions: aminobenzoic acid, Uvmul series, sudan black, silkworm chrysalis dry powder, citric acid, pyrogallic acid, paranitrobenzoic acid, fluorescent whitening agent VBL, VC, anisole, n-propyl gallate, oleic acid, Congo red, rhodamine, amaranth dyestuff, lignosulfonates, castor oil;
Described filler is selected from one or more of following compositions: potter's clay, attapulgite, kaolin, vermiculite, talcum, lime stone, calcite, diatomite, sandstone, float stone, mud coal, brown coal, winnofil, precipitated silicate calcium, white carbon, phosphorus ore tailing.
Be made up of host and assistant agent with the insecticide wetting powder that this host is made, the host active constituent content is 0.1~70%, and preferred content is 5~50%, and the assistant agent of forming wetting powder is to comprise following quality than mixing active ingredients thing:
Stabilizing agent: surfactant: filler=3~20: 3~20: 10~70;
Described stabilizing agent is selected from one or more of following compositions: eugenol, sodium hydrogensulfite, ethoxyquin, the L-cysteine, vitamin E, vitamin C, beta carotene, Tea Polyphenols, BHA, BHT, TBHQ, epoxidized soybean oil, aminobenzoic acid (PABA), Uvmul series, sudan black, silkworm chrysalis dry powder, citric acid, pyrogallic acid, paranitrobenzoic acid, fluorescent whitening agent VBL, VC, anisole, n-propyl gallate, oleic acid, Congo red, rhodamine, the amaranth dyestuff, lignosulfonates, castor oil;
Described surfactant is selected from one or more of following compositions: alkylaryl polyoxy ethyl ether, fatty alcohol polyoxy ethyl ether, alkylnaphthalene sulfonate, lignosulfonates;
Described filler is selected from one or more of following compositions: potter's clay, attapulgite, kaolin, vermiculite, talcum, lime stone, calcite, diatomite, sandstone, float stone, mud coal, brown coal, winnofil, precipitated silicate calcium, white carbon, phosphorus ore tailing.
Be made up of host and assistant agent with the insecticide soluble powder that this host is made, the host active constituent content is 0.1~70%, and preferred content is 5~50%, and the assistant agent of forming soluble powder is to comprise following quality than mixing active ingredients thing:
Stabilizing agent: surfactant: dispersant: filler=3~20: 3~20: 3~20: 10~70;
Described stabilizing agent is selected from one or more of following compositions: eugenol, sodium hydrogensulfite, ethoxyquin, the L-cysteine, vitamin E, vitamin C, beta carotene, Tea Polyphenols, BHA, BHT, TBHQ and epoxidized soybean oil, aminobenzoic acid (PABA), Uvmul series, sudan black, silkworm chrysalis dry powder, citric acid, pyrogallic acid, paranitrobenzoic acid, fluorescent whitening agent VBL, VC, anisole, n-propyl gallate, oleic acid, Congo red, rhodamine, the amaranth dyestuff, lignosulfonates, fatty alcohol, tall oil, triphenyl phosphate, alkylsulfonate, the diisopropyl phosphate, isopropyl phosphoric acid fat, castor oil;
Described surfactant is selected from one or more of following compositions: alkylaryl polyoxy ethyl ether, fatty alcohol polyoxy ethyl ether, alkylnaphthalene sulfonate, lignosulfonates;
Described dispersant is selected from one or more of following compositions: alkylsulfonate, alkyl phenol, fatty alcohol alkylene oxide addition product sulfonate, fatty alcohol alkylene oxide addition product phosphoric acid fat;
Described filler is selected from one or more of following compositions: potter's clay, diatomite, white carbon, calcite, flood peak slush, lightweight CaCO
3, sodium sulphate, rock phosphate.
Be made up of host and assistant agent with the insecticide milk powder that this host is made, host active ingredient mass content is 0.1~70%, and preferred content is 5~50%, and the assistant agent of forming milk powder is to comprise following quality than mixing active ingredients thing:
Antioxidant: anti-photodissociation agent: surfactant: dispersant=3~20: 2~20: 2~30: 5~60;
Described antioxidant is selected from one or more of following compositions: fatty alcohol, tall oil, triphenyl phosphate, eugenol, sodium hydrogensulfite, ethoxyquin, L-cysteine, vitamin E, vitamin C, beta carotene, Tea Polyphenols, BHA, BHT, TBHQ, epoxidized soybean oil;
Described anti-photodissociation agent is selected from one or more of following compositions: aminobenzoic acid, Uvmul series, sudan black, silkworm chrysalis dry powder, citric acid, pyrogallic acid, paranitrobenzoic acid, fluorescent whitening agent VBL, VC, anisole, n-propyl gallate, oleic acid, Congo red, rhodamine, amaranth dyestuff, lignosulfonates, castor oil;
Described surfactant is selected from one or more of following compositions: alkylaryl polyoxy ethyl ether, fatty alcohol polyoxy ethyl ether, alkylnaphthalene sulfonate, lignosulfonates;
Described dispersant is selected from one or more of following compositions: the dry powder that lignosulfite is made, soda pulping waste, Chinese honey locust, calcium chloride dihydrate, ammonium nitrate, niter cake, dibastic sodium phosphate, magnesium sulfate, ferric trichloride, animals and plants protein hydrolysate is (as the black soya bean cake, soybean cake, groundnut cake, the green soya bean cake, the calabash fiber crops, cottonseed cake, mustard seedcake, sunflower, colza cake, linseed meal, castor cake, kapok, coconut, the paulownia seed, wheat bran, blue or green benevolence cake, the rice bran dregs of fat, Chinese tallow tree seedcake, fish scale, the silkworm slag, hoof dry measure used in former times powder, ox pawl hoof, blood meal, chicken feather, water chestnut, Roll, the pupa slag, whale bone, flocking, tripe, dried small shrimp, fishbone dust, the bird bone, the crab shell, bone meal, the people sends out, nail, the protein hydrolysate of tea seed cake etc.).
Be made up of host and assistant agent with the insecticide tablet that this host is made, the host active constituent content is 0.1~70%, and preferred content is 5~50%, and the assistant agent of forming tablet is to comprise following quality than mixing active ingredients thing:
Antioxidant: anti-photodissociation agent: lubricant: adhesive: adsorbing filler is arranged
=3~20∶2~20∶1~30∶1~40∶10~70;
Described antioxidant is selected from one or more of following compositions: fatty alcohol, tall oil, triphenyl phosphate, alkylsulfonate, diisopropyl phosphate, isopropyl phosphoric acid fat, eugenol, sodium hydrogensulfite, ethoxyquin, L-cysteine, vitamin E, vitamin C, beta carotene, Tea Polyphenols, BHA, BHT, TBHQ, epoxidized soybean oil;
Described anti-photodissociation agent is selected from one or more of following compositions: aminobenzoic acid, Uvmul series, sudan black, silkworm chrysalis dry powder, citric acid, pyrogallic acid, paranitrobenzoic acid, fluorescent whitening agent VBL, VC, anisole, n-propyl gallate, oleic acid, Congo red, rhodamine, amaranth dyestuff, lignosulfonates, castor oil;
Described lubricant is selected from one or more of following compositions: dolomol, talcum powder, stearic acid;
Described adhesive is selected from one or more of following compositions: plants starch, spent pulping liquor, carboxymethyl cellulose, polyvinyl alcohol, gelatin, gum Arabic, paraffin, stearic acid, rosin, tallow;
Described have adsorbing filler and be selected from one or more of following compositions: potter's clay, bentonite, talcum powder, gypsum, diatomite, white carbon, phosphate.
The using method of the above-mentioned preparation as insecticiding agent made from host of the present invention is:
Insecticide is contained in the packaging bag made from seepy material, this permeable medicine bag is fixed on the top at Palmae plant lobus cardiacus foundation position, utilize the rainwater that infiltrates packaging bag or spray water-soluble part medicine and/or the formation emulsion separated, make the satisfactory leaf of soup that flows out the bag wall flow to the lobus cardiacus foundation position of below, kill reside on the lobus cardiacus and lobus cardiacus in insect.
The present invention is directed to Brontispa longissima has selected for use interior absorption good to the harm characteristics of babassu, and the pyrrole worm that can bring into play long-acting or quick-acting effects respectively is clear, desinsection list or Methomyl are made host, the insecticide of made various formulations has good control efficiency to Brontispa longissima, various preparation provided by the invention is fixed dosage form, do not contain organic solvent, be difficult for causing environmental pollution, available spraying, injection, irritate method method control Brontispa longissimas such as root, the method that permeable packing medicine bag is fixed in lobus cardiacus foundation top provided by the present invention has easy to operate, the medication target is strong, environmental pollution is little, medicament availability height, cost is low, the slowly-releasing drug effect phase is long, the advantage that control efficiency is good.
Specific embodiments
Below in conjunction with embodiment technical solution of the present invention is described further
Embodiment 1,25% pyrrole worm be clear/the Methomyl pulvis
Each active ingredient mass ratio m/m of this routine host is:
The pyrrole worm is clear: Methomyl
=10∶15
The various active ingredient mass ratio of assistant agent m/m is:
Anti-caking agent: water absorbing agent: antioxidant: anti-photodissociation agent: filler
=isopropyl phosphoric acid ester: Sodium Polyacrylate: eugenol: aminobenzoic acid: kaolin
=5∶8∶10∶8∶44
Host and assistant agent active ingredient mass ratio m/m are:
Host: assistant agent=1: 3
With above-mentioned quality than raw materials of effective components be mixed the back make the insecticide pulvis with the preparation method of traditional pulvis.
Embodiment 2:25% pyrrole worm is clear/desinsection list pulvis
Each active ingredient mass ratio m/m of this routine host is:
The pyrrole worm is clear: desinsection list=10: 15
The various active ingredient mass ratioes of assistant agent are:
Anti-caking agent: water absorbing agent: antioxidant: anti-photodissociation agent: filler
=isopropyl phosphoric acid ester: Sodium Polyacrylate: Tea Polyphenols: anisole: potter's clay
=5∶9∶9∶10∶42
Host and assistant agent active ingredient mass ratio are:
Host: assistant agent=1: 3
Embodiment 3:30% pyrrole worm is clear/the Methomyl pulvis
These routine various host active ingredient mass ratioes are:
The pyrrole worm is clear: Methomyl=10: 20
The various active ingredient mass ratioes of assistant agent are:
Anti-caking agent: water absorbing agent: antioxidant: anti-photodissociation agent: filler
=diisopropyl phosphate: polyacrylic acid-vinyl acetate: Tea Polyphenols: paranitrobenzoic acid: diatomite
=5∶8∶10∶8∶39
Host and assistant agent active ingredient mass ratio are:
Host: assistant agent=3: 7
Embodiment 4:45% pyrrole worm is clear/desinsection list pulvis
These routine various host active ingredient mass ratioes are:
The pyrrole worm is clear: desinsection list=15: 30
The various active ingredient mass ratioes of assistant agent are:
Anti-caking agent: water absorbing agent: antioxidant: anti-photodissociation agent: filler
=isopropyl phosphoric acid ester: POLYPROPYLENE GLYCOL-acrylonitrile: epoxidized soybean oil: pyrogallic acid: white carbon
=7∶10∶7∶6∶25
Host and assistant agent active ingredient mass ratio are:
Host: assistant agent=45: 55
Embodiment 5:40% pyrrole worm is clear/desinsection list wetting powder
These routine various host active ingredient mass ratioes are:
The pyrrole worm is clear: desinsection list=10: 30
The various active ingredient mass ratioes of assistant agent are:
Stabilizing agent: surfactant: filler
=Tea Polyphenols: sodium lignin sulfonate: talcum powder
=11∶8∶41
Host and assistant agent active ingredient mass ratio are:
Host: assistant agent=4: 6
With above-mentioned quality than raw materials of effective components be mixed the back make insecticide with the preparation method of traditional wetting powder.
Embodiment 6:40% pyrrole worm is clear/the Methomyl wetting powder
These routine various host active ingredient mass ratioes are:
The pyrrole worm is clear: Methomyl=10: 30
The various active ingredient mass ratioes of assistant agent are:
Stabilizing agent: surfactant: filler
=castor oil: dodecyl sodium sulfate: diatomite
=9∶7∶44
Host and assistant agent active ingredient mass ratio are:
Host: assistant agent=4: 6
Embodiment 7:30% pyrrole worm is clear/desinsection list wetting powder
These routine various host active ingredient mass ratioes are:
The pyrrole worm is clear: desinsection list=10: 20
The various active ingredient mass ratioes of assistant agent are:
Stabilizing agent: surfactant: filler
=paranitrobenzoic acid: neopelex: potter's clay
=12∶10∶48
Host and assistant agent active ingredient mass ratio are:
Host: assistant agent=3: 7
Embodiment 8:40% pyrrole worm is clear/desinsection list soluble powder
These routine various host active ingredient mass ratioes are:
The pyrrole worm is clear: desinsection list=1: 3
The various active ingredient mass ratioes of assistant agent are:
Stabilizing agent: surfactant: dispersant: filler
=anisole: lignosulfonates: detergent alkylate sodium iodate: diatomite
=7∶10∶8∶48
Host and assistant agent active ingredient mass ratio are:
Host: assistant agent=4: 6
With above-mentioned quality than raw materials of effective components be mixed the back make insecticide with the preparation method of traditional soluble powder.
Embodiment 9:45% pyrrole worm is clear/desinsection list milk powder insecticide
These routine various host active ingredient mass ratioes are:
The pyrrole worm is clear: desinsection list=10: 35
The various active ingredient mass ratioes of assistant agent are:
Antioxidant: anti-photodissociation agent: surfactant: dispersant
=Tea Polyphenols: castor oil: sodium lignin sulfonate: spent pulping liquor dry powder
=7∶8∶10∶30
Host and assistant agent active ingredient mass ratio are:
Host: assistant agent=45: 55
With above-mentioned quality than raw materials of effective components be mixed the back make insecticide with the preparation method of traditional milk powder.
Embodiment 10:45% pyrrole worm is clear/agent of desinsection monolithic
The various active ingredient mass ratioes of this routine host are:
The pyrrole worm is clear: desinsection list=10: 35
The various active ingredient mass ratioes of assistant agent are:
Antioxidant: anti-photodissociation agent: lubricant: adhesive: adsorbing filler is arranged
=Tea Polyphenols: aminobenzoic acid: talcum powder: carboxymethyl cellulose: potter's clay
=5∶4∶10∶7∶29
Host and assistant agent active ingredient mass ratio are:
Host: assistant agent=45: 55
With above-mentioned quality than raw materials of effective components be mixed the back make insecticide with the preparation method of conventional tablet.
Embodiment 11: the indoor synergy toxicity test of mixture
To not launch coconut lobus cardiacus stripping in flakes, and in soup, soak after 5 seconds and take out, and put into diameter 12cm after drying naturally in the cool, be lined with the culture dish of the filter paper of preserving moisture.Every ware inserts 50 Brontispa longissima adults with etherization.After disposing, culture dish is placed insectary (25 ± 2 ℃), 24 " Invest, Then Investigate " death condition.
Press Abbott formula calculation correction lethality, look into the probit value and the dosage logarithm value of corrected mortality.Carrying out toxicity regression with the Casiofx-3900 calculator calculates.The results are shown in Table 1:
The indoor synergy toxicity test of table 1 mixture
Reagent agent | Virulence regression equation | LC
50Value (μ g/ml)
| Correlation coefficient | Co-toxicity coefficient |
The clear desinsection list of pyrrole worm Methomyl pyrrole worm is clear: desinsection list (2: 1, m/m) the pyrrole worm is clear: desinsection list (1: 2, m/m) the pyrrole worm is clear: desinsection list (1: 10, m/m) the pyrrole worm is clear: Methomyl (2: 1, m/m) the pyrrole worm is clear: Methomyl (1: 5, m/m) the pyrrole worm is clear: and Methomyl (1: 10, m/m) | Y=4.4844+1.6186x Y=4.1754+1.3725x Y=4.6123+1.1548x Y=4.7171+1.4550x Y=4.5719+1.8361x Y=4.3215+1.6591x Y=4.8218+1.5499x Y=4.7189+1.4404x Y=4.6702+1.4896x | 2.08 3.99 2.17 1.56 1.71 2.56 1.30 1.57 1.66 | 0.9965 0.9944 0.9945 0.9870 0.9939 0.9900 0.9896 0.9768 0.9848 | 158.17 178.63 143.61 161.85 137.26 129.83 |
Embodiment 12: the mixed insecticide field control effectiveness test
With 25% pyrrole worm clear/Methomyl pulvis insecticide (example 1), 30% pyrrole worm is clear/Methomyl pulvis insecticide (example 3), 45% pyrrole worm is clear/desinsection list pulvis (example 4), 40% pyrrole worm is clear/desinsection list wetting powder (example 5), 40% pyrrole worm is clear/Methomyl wetting powder (example 6), 40%1 pyrrole worms are clear/desinsection list soluble powder (example 8), 45% pyrrole worm is clear/desinsection list milk powder (example 9), 45% pyrrole worm is clear/70mm * 40mm pouch-packaged that desinsection monolithic agent (example 10) is made with cotton gauze respectively, every bag of weight is 10g, if blank, the fixing new leaf base that does not launch is placed two cartridge bags on every tree, fixes with continuous yarn.Four repetitions of every processing, totally ten two coconut palms.
Weather condition: light rain was arranged in 5 days after the dispenser, drizzle or moderate rain was arranged behind the medicine in 10 days, 18 days.
Result of the test sees Table 2:
Table 2 mixture preparation is hung bag method control Brontispa longissima field control effectiveness test
Handle and dosage g/ | Repeat | Insect population radix before the medicine | Behind the medicine 10 days | Behind the medicine 30 days | Behind the medicine 62 days |
Borer population (head) alive | The insect population rate (%) that goes down | The average population rate (%) that goes down | Preventive effect (%) | Average preventive effect (%) | Borer population (head) alive | The insect population rate (%) that goes down | The average population rate (%) that goes down | Preventive effect (%) | Average preventive effect (%) | Borer population (head) alive | The insect population rate (%) that goes down | The average population rate (%) that goes down | Preventive effect (%) | Average preventive effect (%) |
Contrast | 1 2 3 4 | 201 152 164 121 | 225 167 186 130 | -11.94 -9.87 -13.41 -7.44 | -10.67 | | | 242 170 193 151 | -20.40 -11.84 -17.68 -24.79 | -18.68 | | | 250 184 202 167 | -24.38 -21.05 -23.17 -38.02 | -26.65 | | |
25% pyrrole worm is clear/Methomyl pulvis insecticide (example 1) 20 | 1 2 3 4 | 184 172 190 157 | 12 9 7 8 | 93.48 94.77 96.32 94.90 | 94.87 | 94.11 95.27 96.67 95.40 | 95.36 | 5 4 3 7 | 97.28 97.67 98.42 95.54 | 97.23 | 97.71 98.04 98.67 96.24 | 97.67 | 31 25 29 38 | 83.15 85.47 84.74 75.80 | 82.29 | 86.70 88.52 87.95 80.89 | 86.02 |
30% pyrrole worm is clear/Methomyl pulvis insecticide (example 3) 20 | 1 2 3 4 | 216 180 225 156 | 2 5 7 5 | 99.07 97.22 96.89 96.79 | 97.50 | 99.16 97.49 97.19 97.10 | 97.74 | 3 6 3 5 | 98.61 96.67 98.67 96.79 | 97.68 | 98.83 97.19 98.88 97.30 | 98.05 | 33 30 27 40 | 84.72 83.33 88.00 74.36 | 82.60 | 87.94 86.84 90.53 79.76 | 86.26 |
45% pyrrole worm is clear/desinsection list pulvis insecticide (example 4) 20 | 1 2 3 4 | 192 127 165 220 | 5 3 7 9 | 97.40 97.64 95.76 95.91 | 96.68 | 97.65 97.87 96.17 96.30 | 97.00 | 6 7 3 8 | 96.88 94.49 98.18 96.36 | 96.48 | 97.37 95.36 98.47 96.94 | 97.03 | 19 21 29 30 | 90.10 83.46 82.42 86.36 | 85.59 | 92.19 86.94 86.12 89.23 | 88.62 |
40% pyrrole worm is clear/desinsection list wetting powder (example 5) 20 | 1 2 3 4 | 178 149 205 166 | 2 5 4 3 | 98.88 96.64 98.05 98.19 | 97.94 | 98.98 96.97 98.24 98.37 | 98.14 | 3 2 4 6 | 98.31 98.66 98.05 96.39 | 97.85 | 98.58 98.87 98.36 96.95 | 98.19 | 22 28 34 18 | 87.64 81.21 83.41 89.16 | 85.35 | 90.24 85.16 86.91 91.44 | 88.44 |
40% pyrrole worm is clear/Methomyl wetting powder (example 6) 20 | 1 2 3 4 | 205 135 146 201 | 5 2 4 3 | 97.56 98.52 97.26 98.51 | 97.96 | 97.80 98.66 97.52 98.65 | 98.16 | 9 5 4 8 | 95.61 96.30 97.26 96.02 | | 96.30 96.88 97.69 96.65 | 96.88 | 25 30 29 26 | 87.80 77.78 80.14 87.06 | | 90.37 82.45 84.32 89.79 | 86.73 |
40% pyrrole worm is clear/desinsection list soluble powder (example 8) 20 | 1 2 3 4 | 133 151 207 150 | 8 9 7 6 | 93.98 94.04 96.62 96.00 | 95.16 | 94.56 94.61 96.94 96.39 | 95.63 | 10 5 6 8 | 92.48 96.69 97.10 94.67 | 95.23 | 93.66 97.21 97.56 95.51 | 95.98 | 35 31 36 39 | 73.68 79.47 82.61 74.00 | 77.44 | 79.22 83.79 86.27 79.47 | 82.19 |
45% pyrrole worm is clear/desinsection list milk powder (example 9) 20 | 1 2 3 4 | 211 128 164 187 | 5 2 3 7 | 97.630 98.438 98.171 96.257 | 97.62 | 97.859 98.588 98.347 96.618 | 97.853 | 5 6 9 10 | 97.63 95.31 94.51 94.65 | 95.53 | 98.00 96.05 95.38 95.49 | 96.23 | 28 31 27 36 | 86.73 75.78 83.54 80.75 | 81.70 | 89.52 80.88 87.00 84.80 | 85.55 |
45% pyrrole worm is clear/desinsection monolithic agent (example 10) 20 | 1 2 3 4 | 138 129 157 172 | 2 3 6 7 | 98.551 97.674 96.178 95.930 | 97.08 | 98.690 97.899 96.547 96.323 | 97.365 | 10 9 4 8 | 92.75 93.02 97.45 95.35 | 94.64 | 93.89 94.12 97.85 96.08 | 95.49 | 35 40 38 42 | 74.64 68.99 75.80 75.58 | 73.75 | 79.97 75.52 80.89 80.72 | 79.28 |
Embodiment 13-16 insecticide each active ingredient of pulvis and mass ratio tabulation
Preferred span | Host active ingredient mass ratio (m/m) 1: 0.5~10 | Assistant agent active ingredient mass ratio (m/m) | Host mass content percentage |
Anti-caking agent: water absorbing agent: antioxidant: anti-photodissociation agent: filler 1~20 1~15 3~20 2~20 10~70 | 5~50% |
Embodiment 13 | The pyrrole worm is clear: desinsection list=10: 10 | Sodium alkyl benzene sulfonate: Sodium Polyacrylate: sodium hydrogensulfite: sudan black: vermiculite=5: 8: 15: 5: 47 | 20% |
Embodiment 14 | The pyrrole worm is clear: Methomyl=10: 10 | Sodium naphthalene sulfonate: polyacrylic acid-acrylonitrile: ethoxyquin: silkworm chrysalis dry powder: talcum=7: 9: 7: 10: 47 | 20% |
Implement 15 | The pyrrole worm is clear: desinsection list=5: 15 | Sodium naphthalene sulfonate: Sodium Polyacrylate: L-cysteine: n-propyl gallate: brown coal=6: 12: 8: 6: 48 | 20% |
Embodiment 16 | The pyrrole worm is clear: Methomyl=5: 25 | Alkyl phenol: polyacrylic acid-acrylonitrile: vitamin E: anisole: white carbon=15: 12: 5: 15: 23 | 30% |
Embodiment 13~16 obtains the implementation result that is similar to table 2 illustrated embodiment 1,3,4; With following compositions the span identical with embodiment 1,3,4,13~16 or on preferred mass shown in the table than span in corresponding composition in the alternate embodiment 1,3,4,13~16, also obtain propinquity effect:
Anti-caking agent: alkylnaphthalene sulfonate, the poly-ethyl ether sulfonate of alkyl phenol, fatty alcohol ethylene oxide adduct sulfonate, fatty alcohol ethylene oxide adduct phosphate, alkylamine salt;
Water absorbing agent: Super absorbent polymers (SAP);
Antioxidant: vitamin C, beta carotene, BHA, BHT, TBHQ;
Anti-photodissociation agent: Uvmul series, citric acid, fluorescent whitening agent VBL, VC, oleic acid, Congo red, rhodamine, amaranth dyestuff, lignosulfonates and castor oil;
Filler: potter's clay, attapulgite, lime stone, calcite, sandstone, float stone, mud coal, winnofil, precipitated silicate calcium, phosphorus ore tailing.
Each active ingredient of embodiment 17-20 wetting powder and mass ratio tabulation
Preferred span | Host active ingredient mass ratio (m/m) 1: 0.5~10 | Assistant agent active ingredient mass ratio (m/m) | Host mass content percentage |
Stabilizing agent: surfactant: filler 3~20: 3~20: 10~70 | 5~50% |
Embodiment 17 | The pyrrole worm is clear: desinsection list=10: 10 | Eugenol: alkylaryl polyoxy ethyl ether: diatomite=4: 17: 61 | 20% |
Embodiment 18 | The pyrrole worm is clear: Methomyl=10: 25 | Sodium hydrogensulfite: fatty alcohol polyoxy ethyl ether: precipitated silicate calcium=15: 15: 35 | 35% |
Embodiment 19 | The pyrrole worm is clear: desinsection list=10: 25 | Citric acid: lignosulfonates: attapulgite=10: 9: 46 | 35% |
Embodiment 20 | The pyrrole worm is clear: Methomyl=2: 10 | Paranitrobenzoic acid: alkylnaphthalene sulfonate: white carbon=15: 15: 48 | 12% |
Embodiment 17~20 obtains the implementation result that is similar to table 2 illustrated embodiment 5,6; With following compositions the span identical with embodiment 5,6,17~20 or on preferred mass shown in the table than span in corresponding composition in the alternate embodiment 5,6,17~20, also obtain propinquity effect:
Stabilizing agent: ethoxyquin, L-cysteine, vitamin E, vitamin C, beta carotene, BHA, BHT, TBHQ, epoxidized soybean oil, aminobenzoic acid (PABA), Uvmul series, sudan black, silkworm chrysalis dry powder, pyrogallic acid, fluorescent whitening agent VBL, VC, anisole, n-propyl gallate, oleic acid, Congo red, rhodamine, amaranth dyestuff, lignosulfonates;
Filler: kaolin, vermiculite, lime stone, calcite, sandstone, float stone, mud coal, brown coal, precipitated silicate calcium, white carbon, phosphorus ore tailing.
Each active ingredient of embodiment 21-23 soluble powder and mass ratio tabulation
Preferred span | Host active ingredient mass ratio (m/m) 1: 0.5~10 | Assistant agent active ingredient mass ratio (m/m) | Host mass content percentage |
Stabilizing agent: surfactant: dispersant: filler=3~20: 3~20: 3~20: 10~70 | 5~50% |
Embodiment 21 | The pyrrole worm is clear: desinsection list=10: 15 | Citric acid: alkylaryl polyoxy ethyl ether: alkyl phenol: potter's clay=6: 17: 15: 37 | 25% |
Embodiment 22 | The pyrrole worm is clear: Methomyl=10: 20 | Congo red: alkyl naphthalene sulfonate: alkyl phenol: rock phosphate=14: 7: 10: 39 | 30% |
Embodiment 23 | The pyrrole worm is clear: desinsection list=4: 15 | Silkworm chrysalis dry powder: fatty alcohol polyoxy ethyl ether: native dialkyl group sodium sulfonate: flood peak slush=8: 4: 5: 64 | 19% |
Embodiment 21~23 obtains the implementation result that is similar to table 2 illustrated embodiment 8; With following compositions the span identical with embodiment 8,21~23 or on preferred mass shown in the table than span in corresponding composition in the alternate embodiment 8,21~23, also obtain propinquity effect:
Stabilizing agent: eugenol, sodium hydrogensulfite, ethoxyquin, the L-cysteine, vitamin E, vitamin C, beta carotene, Tea Polyphenols, BHA, BHT, TBHQ and epoxidized soybean oil, aminobenzoic acid (PABA), Uvmul series, sudan black, pyrogallic acid, paranitrobenzoic acid, fluorescent whitening agent VBL, VC, n-propyl gallate, oleic acid, rhodamine, the amaranth dyestuff, lignosulfonates, fatty alcohol, tall oil, triphenyl phosphate, alkylsulfonate, PAP (diisopropyl phosphate, isopropyl phosphoric acid fat), castor oil;
Dispersant: fatty alcohol alkylene oxide addition product sulfonate, fatty alcohol ethylene oxide adduct phosphoric acid fat;
Filler: white carbon, calcite, lightweight CaCO
3, sodium sulphate.
Each active ingredient of embodiment 24-26 milk powder and mass ratio tabulation
Preferred span | Host active ingredient mass ratio (m/m) 1: 0.5~10 | Assistant agent active ingredient mass ratio (m/m) | Host mass content percentage |
Antioxidant: anti-photodissociation agent: surfactant: dispersant=3~20: 2~20: 2~30: 5~60 | 5~50% |
Embodiment 24 | The pyrrole worm is clear: desinsection list=20: 10 | Tall oil: Congo red: sodium lignin sulfonate: soda pulping waste=10: 15: 20: 25 | 30% |
Embodiment 25 | The pyrrole worm is clear: Methomyl=10: 25 | Eugenol: castor oil: alkylaryl polyoxy ethyl ether soybean cake protein hydrolysate=7: 5: 10: 43 | 35% |
Embodiment 26 | The pyrrole worm is clear: desinsection list=5: 25 | Epoxidized soybean oil: silkworm chrysalis dry powder: Negel: magnesium sulfate=15: 7: 5: 43 | 30% |
Embodiment 24~26 obtains the implementation result that is similar to table 2 illustrated embodiment 9; With following compositions the span identical with embodiment 24~26 or 9 or on preferred mass shown in the table than span in corresponding composition in the alternate embodiment 24~26 or 9, also obtain propinquity effect:
Antioxidant: fatty alcohol, triphenyl phosphate, PAP (diisopropyl phosphate, isopropyl phosphoric acid fat), sodium hydrogensulfite, ethoxyquin, L-cysteine, vitamin E, vitamin C, beta carotene, BHA, BHT, TBHQ;
Anti-photodissociation agent: aminobenzoic acid (PABA), Uvmul series, sudan black, silkworm chrysalis dry powder, citric acid, pyrogallic acid, paranitrobenzoic acid, fluorescent whitening agent VBL, VC, anisole, n-propyl gallate, oleic acid, rhodamine, amaranth dyestuff, lignosulfonates;
Surfactant: alkylaryl polyoxy ethyl ether, fatty alcohol polyoxy ethyl ether, alkylnaphthalene sulfonate, lignosulfonates;
Dispersant: animals and plants protein hydrolysate (black soya bean cake, soybean cake, groundnut cake, the green soya bean cake, the calabash fiber crops, cottonseed cake, mustard seedcake, sunflower, colza cake, linseed meal, castor cake, kapok, coconut, the paulownia seed, wheat bran, blue or green benevolence cake, the rice bran dregs of fat, Chinese tallow tree seedcake, fish scale, the silkworm slag, hoof dry measure used in former times powder, ox pawl hoof, blood meal, chicken feather, water chestnut, Roll, the pupa slag, whale bone, flocking, tripe, dried small shrimp, fishbone dust, the bird bone, the crab shell, bone meal, the people sends out, nail, the protein hydrolysate of tea seed cake), Chinese honey locust, calcium chloride dihydrate, ammonium nitrate, niter cake, dibastic sodium phosphate, ferric trichloride.
Each active ingredient of embodiment 27-30 tablet and mass ratio tabulation
Preferred span | Host active ingredient mass ratio (m/m) 1: 0.5~10 | Assistant agent active ingredient mass ratio (m/m) | Host mass content percentage |
Antioxidant: anti-photodissociation agent: lubricant: adhesive: adsorbing filler=3~20 are arranged: 2~20: 1~30: 1~40: 10~70; | 5~50% |
Embodiment 27 | The pyrrole worm is clear: desinsection list=10: 25 | Eugenol: sudan black: talcum powder: paraffin: diatomite=8: 8: 10: 5: 34 | 35% |
Embodiment 28 | The pyrrole worm is clear: Methomyl=20: 10 | Tall oil: castor oil: dolomol: plants starch: gypsum=15: 9: 14: 10: 22 | 30% |
Embodiment 29 | The pyrrole worm is clear: desinsection list=4: 8 | Ethoxyquin: n-propyl gallate: stearic acid: gum Arabic: talcum powder=9: 7: 5: 10: 57 | 8% |
Embodiment 30 | The pyrrole worm is clear: desinsection list=2: 20 | Epoxidized soybean oil: anisole: talcum powder: polyvinyl alcohol: white carbon=5: 18: 8: 24: 23 | 22% |
Embodiment 27~30 obtains the implementation result that is similar to table 2 illustrated embodiment 10; With following compositions the span identical with embodiment 27~30 or 10 or on preferred mass shown in the table than span in corresponding composition in the alternate embodiment 27~30 or 10, also obtain propinquity effect:
Antioxidant: fatty alcohol, triphenyl phosphate, alkylsulfonate, PAP (diisopropyl phosphate, isopropyl phosphoric acid fat), sodium hydrogensulfite, L-cysteine, vitamin E, vitamin C, beta carotene, BHA, BHT, TBHQ:
Anti-photodissociation agent: Uvmul series, silkworm chrysalis dry powder, citric acid, pyrogallic acid, paranitrobenzoic acid, fluorescent whitening agent VBL, VC, oleic acid, Congo red, rhodamine, amaranth dyestuff, lignosulfonates;
Adhesive: spent pulping liquor, gelatin, stearic acid, rosin, tallow;
Has adsorbing filler: bentonite, phosphate.
Each active ingredient of embodiment 31-34 wetting powder and mass ratio tabulation
Preferred span | Host active ingredient mass ratio (m/m) 1: 0.5~10 | Assistant agent active ingredient mass ratio (m/m) | Host mass content percentage |
Stabilizing agent: surfactant: filler 3~20: 3~20: 10~70 | 5~50% |
Embodiment 31 | The pyrrole worm is clear: desinsection list=1: 0.3 | Eugenol: alkylaryl polyoxy ethyl ether: diatomite=4: 17: 61 | 20% |
Embodiment 32 | The pyrrole worm is clear: Methomyl=1: 40 | Sodium hydrogensulfite: fatty alcohol polyoxy ethyl ether: precipitated silicate calcium=15: 15: 35 | 35% |
Embodiment 33 | The pyrrole worm is clear: desinsection list=1: 30 | Citric acid: lignosulfonates: attapulgite=10: 9: 46 | 35% |
Embodiment 34 | The pyrrole worm is clear: Methomyl=1: 25 | Paranitrobenzoic acid: alkyl tea sulfonate: white carbon=8: 6: 36 | 50% |
Embodiment 31~34 except that host active ingredient quality than the span difference, other data are with embodiment 17~20, through test, the desinsection control efficiency of embodiment 17~20 is better than embodiment 31~34.