CN1243478C - Pesticide main agent for preventing and controlling coconut core chrysomelid and preparation made therefrom and using method - Google Patents
Pesticide main agent for preventing and controlling coconut core chrysomelid and preparation made therefrom and using method Download PDFInfo
- Publication number
- CN1243478C CN1243478C CN 200410026870 CN200410026870A CN1243478C CN 1243478 C CN1243478 C CN 1243478C CN 200410026870 CN200410026870 CN 200410026870 CN 200410026870 A CN200410026870 A CN 200410026870A CN 1243478 C CN1243478 C CN 1243478C
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- China
- Prior art keywords
- agent
- acid
- following compositions
- host
- powder
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
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- 239000002994 raw material Substances 0.000 description 5
- 210000000988 bone and bone Anatomy 0.000 description 4
- 210000000003 hoof Anatomy 0.000 description 4
- 239000002893 slag Substances 0.000 description 4
- 229920000247 superabsorbent polymer Polymers 0.000 description 4
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- 238000012360 testing method Methods 0.000 description 4
- 235000014643 Orbignya martiana Nutrition 0.000 description 3
- 244000021150 Orbignya martiana Species 0.000 description 3
- 244000269722 Thea sinensis Species 0.000 description 3
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- 241000251468 Actinopterygii Species 0.000 description 2
- 235000003276 Apios tuberosa Nutrition 0.000 description 2
- 235000010777 Arachis hypogaea Nutrition 0.000 description 2
- 235000010744 Arachis villosulicarpa Nutrition 0.000 description 2
- 239000005996 Blood meal Substances 0.000 description 2
- 244000056139 Brassica cretica Species 0.000 description 2
- 235000003351 Brassica cretica Nutrition 0.000 description 2
- 240000002791 Brassica napus Species 0.000 description 2
- 235000006008 Brassica napus var napus Nutrition 0.000 description 2
- 235000003343 Brassica rupestris Nutrition 0.000 description 2
- 235000003301 Ceiba pentandra Nutrition 0.000 description 2
- 244000146553 Ceiba pentandra Species 0.000 description 2
- 241000283153 Cetacea Species 0.000 description 2
- 235000005983 Crescentia cujete Nutrition 0.000 description 2
- 241000238557 Decapoda Species 0.000 description 2
- 241000287828 Gallus gallus Species 0.000 description 2
- 244000020551 Helianthus annuus Species 0.000 description 2
- 235000003222 Helianthus annuus Nutrition 0.000 description 2
- XUJNEKJLAYXESH-REOHCLBHSA-N L-Cysteine Chemical compound SC[C@H](N)C(O)=O XUJNEKJLAYXESH-REOHCLBHSA-N 0.000 description 2
- 240000007741 Lagenaria siceraria Species 0.000 description 2
- 235000009797 Lagenaria vulgaris Nutrition 0.000 description 2
- 235000004431 Linum usitatissimum Nutrition 0.000 description 2
- 240000006240 Linum usitatissimum Species 0.000 description 2
- 240000007594 Oryza sativa Species 0.000 description 2
- 235000007164 Oryza sativa Nutrition 0.000 description 2
- 235000003283 Pachira macrocarpa Nutrition 0.000 description 2
- 244000133018 Panax trifolius Species 0.000 description 2
- 240000002834 Paulownia tomentosa Species 0.000 description 2
- 241000382353 Pupa Species 0.000 description 2
- 235000004443 Ricinus communis Nutrition 0.000 description 2
- 244000057114 Sapium sebiferum Species 0.000 description 2
- 235000005128 Sapium sebiferum Nutrition 0.000 description 2
- 235000014364 Trapa natans Nutrition 0.000 description 2
- 240000001085 Trapa natans Species 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- QKSKPIVNLNLAAV-UHFFFAOYSA-N bis(2-chloroethyl) sulfide Chemical compound ClCCSCCCl QKSKPIVNLNLAAV-UHFFFAOYSA-N 0.000 description 2
- 239000002374 bone meal Substances 0.000 description 2
- 229940036811 bone meal Drugs 0.000 description 2
- 235000012970 cakes Nutrition 0.000 description 2
- 235000012343 cottonseed oil Nutrition 0.000 description 2
- 239000000428 dust Substances 0.000 description 2
- 238000003912 environmental pollution Methods 0.000 description 2
- 210000003746 feather Anatomy 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 235000004426 flaxseed Nutrition 0.000 description 2
- 235000012054 meals Nutrition 0.000 description 2
- 235000010460 mustard Nutrition 0.000 description 2
- 235000009566 rice Nutrition 0.000 description 2
- 235000009165 saligot Nutrition 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- HIEHAIZHJZLEPQ-UHFFFAOYSA-M sodium;naphthalene-1-sulfonate Chemical compound [Na+].C1=CC=C2C(S(=O)(=O)[O-])=CC=CC2=C1 HIEHAIZHJZLEPQ-UHFFFAOYSA-M 0.000 description 2
- 231100000820 toxicity test Toxicity 0.000 description 2
- 235000015099 wheat brans Nutrition 0.000 description 2
- 235000006226 Areca catechu Nutrition 0.000 description 1
- 244000080767 Areca catechu Species 0.000 description 1
- 235000000378 Caryota urens Nutrition 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- 240000000163 Cycas revoluta Species 0.000 description 1
- 235000008601 Cycas revoluta Nutrition 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 235000013878 L-cysteine Nutrition 0.000 description 1
- 239000004201 L-cysteine Substances 0.000 description 1
- 240000007163 Livistona chinensis Species 0.000 description 1
- 235000010103 Metroxylon rumphii Nutrition 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 229940077388 benzenesulfonate Drugs 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 238000012937 correction Methods 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- 239000002552 dosage form Substances 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 230000000857 drug effect Effects 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 230000008676 import Effects 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 231100000225 lethality Toxicity 0.000 description 1
- NALMPLUMOWIVJC-UHFFFAOYSA-N n,n,4-trimethylbenzeneamine oxide Chemical compound CC1=CC=C([N+](C)(C)[O-])C=C1 NALMPLUMOWIVJC-UHFFFAOYSA-N 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 239000011697 sodium iodate Substances 0.000 description 1
- 235000015281 sodium iodate Nutrition 0.000 description 1
- 229940032753 sodium iodate Drugs 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000001225 therapeutic effect Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 230000001018 virulence Effects 0.000 description 1
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The present invention relates to an agricultural chemical main agent for preventing and treating coconut leaf beetles, a preparation agent made of the agricultural chemical main agent and a use method. The main agent mainly contains the following weight ratio as a formula * the mixture of effective components: acetamiprid: monosultap or methomyl =1: 0.1 to 40*. The main agent is made into pesticides in a powder type, a wettable powder type, a soluble powder, a milk powder and a tablet type, and the pesticides has the advantages of good internal suction properties, high rapid effect properties, long effect keeping period and good prevention and treatment effect. The medicine is put in a water permeable packaging bag to be fixed on the upper parts of the base of a heart leaf of a palmae plant, rain water penetrated into the packaging bag or partial medicine dissolved by spraying water forms emulsion, and physic liquor flowing out of the bag wall flows in the position of the base of the heart leaf on the lower part along the heart leaf so as to kill pests colonized on the heart leaf and in the heart leaf. The method of the present invention has the advantages of convenient operation, strong medicine use target properties, high medicine utilization rate, long effect keeping period and good prevention and treatment effect.
Description
Technical field
The invention belongs to the agricultural chemicals host of control Brontispa longissima insect and with its preparation of making and using method.
Background technology
Brontispa longissima (Brontispa longissima) is a kind of insect on the babassu, mainly pierces in the lobus cardiacus of kind of Palmae economy surplus coconut palm, sago palm tree, betelnut tree, the light leaf California Chinese fan palm etc. 20 or ornamental plants, and the withered heart of plant is caused death.Former of Brontispa longissima is external, imports China in recent years into, and causes serious harm.At present, Brontispa longissima mainly based on chemical pesticide control, but be at home and abroad there is no the special effect agent of control Brontispa longissima at present, and after medicament executes on the plant leaf blade, be difficult to the insect in the lobus cardiacus is had an effect.
Summary of the invention
The technical problem to be solved in the present invention provides a kind of killing rate height, Brontispa longissima is had the agricultural chemicals host of special efficacy preventive and therapeutic effect and with its preparation of making and using method.
The technical scheme that addresses the above problem is:
The agricultural chemicals host of control Brontispa longissima is the composition that mainly comprises following mass ratio (m/m) active ingredient:
The pyrrole worm is clear: desinsection list or Methomyl=1: 0.1～40
The preferred version of above-mentioned host active ingredient mass ratio is:
The pyrrole worm is clear: desinsection list or Methomyl=1: 0.5～10
The selected pyrrole worm of host of the present invention is clear, desinsection list and Methomyl all have stronger interior absorption, the lobus cardiacus of inspiration babassu in being easy to, kill the Brontispa longissima in the lobus cardiacus that does not launch, the pyrrole worm is insoluble in water clearly, have slow and lasting effect, desinsection list or Methomyl are soluble in water, have quick-acting, and clear and desinsection list of pyrrole worm or Methomyl are mixed and can make agricultural chemicals all have fine control efficiency in a long time.
Be made up of host and assistant agent with the insecticide pulvis that above-mentioned host is made, its host active ingredient mass content is 0.1～70%, and preferred content is 5～50%, and the assistant agent of forming pulvis is the mixture that comprises following mass ratio (m/m) effective ingredient:
Anti-caking agent: water absorbing agent: antioxidant: anti-photodissociation agent: filler
＝1～20∶1～15∶3～20∶2～20∶10～70；
Described anti-caking agent is selected from one or more of following compositions: alkylbenzenesulfonate, naphthalene sulfonate, alkylnaphthalene sulfonate, the poly-ethyl ether sulfonate of alkyl phenol, fatty alcohol ethylene oxide adduct sulfonate, alkyl phenol, fatty alcohol ethylene oxide adduct phosphate, alkylamine salt, diisopropyl phosphate ester salt, isopropyl phosphoric acid ester;
Described water absorbing agent is selected from one or more of following compositions: Super absorbent polymers (SAP), Sodium Polyacrylate, polyacrylic acid-acrylonitrile, polyacrylic acid-vinyl acetate, polyvinyl alcohol graft copolymerized acrylic acid;
Described antioxidant is selected from one or more of following compositions: eugenol, sodium hydrogensulfite, ethoxyquin, L-cysteine, vitamin E, vitamin C, beta carotene, Tea Polyphenols, BHA, BHT, TBHQ, epoxidized soybean oil;
Described anti-photodissociation agent is selected from one or more of following compositions: aminobenzoic acid, Uvmul series, sudan black, silkworm chrysalis dry powder, citric acid, pyrogallic acid, paranitrobenzoic acid, fluorescent whitening agent VBL, VC, anisole, n-propyl gallate, oleic acid, Congo red, rhodamine, amaranth dyestuff, lignosulfonates, castor oil;
Described filler is selected from one or more of following compositions: potter's clay, attapulgite, kaolin, vermiculite, talcum, lime stone, calcite, diatomite, sandstone, float stone, mud coal, brown coal, winnofil, precipitated silicate calcium, white carbon, phosphorus ore tailing.
Be made up of host and assistant agent with the insecticide wetting powder that this host is made, the host active constituent content is 0.1～70%, and preferred content is 5～50%, and the assistant agent of forming wetting powder is to comprise following quality than mixing active ingredients thing:
Stabilizing agent: surfactant: filler=3～20: 3～20: 10～70;
Described stabilizing agent is selected from one or more of following compositions: eugenol, sodium hydrogensulfite, ethoxyquin, the L-cysteine, vitamin E, vitamin C, beta carotene, Tea Polyphenols, BHA, BHT, TBHQ, epoxidized soybean oil, aminobenzoic acid (PABA), Uvmul series, sudan black, silkworm chrysalis dry powder, citric acid, pyrogallic acid, paranitrobenzoic acid, fluorescent whitening agent VBL, VC, anisole, n-propyl gallate, oleic acid, Congo red, rhodamine, the amaranth dyestuff, lignosulfonates, castor oil;
Described surfactant is selected from one or more of following compositions: alkylaryl polyoxy ethyl ether, fatty alcohol polyoxy ethyl ether, alkylnaphthalene sulfonate, lignosulfonates;
Described filler is selected from one or more of following compositions: potter's clay, attapulgite, kaolin, vermiculite, talcum, lime stone, calcite, diatomite, sandstone, float stone, mud coal, brown coal, winnofil, precipitated silicate calcium, white carbon, phosphorus ore tailing.
Be made up of host and assistant agent with the insecticide soluble powder that this host is made, the host active constituent content is 0.1～70%, and preferred content is 5～50%, and the assistant agent of forming soluble powder is to comprise following quality than mixing active ingredients thing:
Stabilizing agent: surfactant: dispersant: filler=3～20: 3～20: 3～20: 10～70;
Described stabilizing agent is selected from one or more of following compositions: eugenol, sodium hydrogensulfite, ethoxyquin, the L-cysteine, vitamin E, vitamin C, beta carotene, Tea Polyphenols, BHA, BHT, TBHQ and epoxidized soybean oil, aminobenzoic acid (PABA), Uvmul series, sudan black, silkworm chrysalis dry powder, citric acid, pyrogallic acid, paranitrobenzoic acid, fluorescent whitening agent VBL, VC, anisole, n-propyl gallate, oleic acid, Congo red, rhodamine, the amaranth dyestuff, lignosulfonates, fatty alcohol, tall oil, triphenyl phosphate, alkylsulfonate, the diisopropyl phosphate, isopropyl phosphoric acid fat, castor oil;
Described surfactant is selected from one or more of following compositions: alkylaryl polyoxy ethyl ether, fatty alcohol polyoxy ethyl ether, alkylnaphthalene sulfonate, lignosulfonates;
Described dispersant is selected from one or more of following compositions: alkylsulfonate, alkyl phenol, fatty alcohol alkylene oxide addition product sulfonate, fatty alcohol alkylene oxide addition product phosphoric acid fat;
Described filler is selected from one or more of following compositions: potter's clay, diatomite, white carbon, calcite, flood peak slush, lightweight CaCO
3, sodium sulphate, rock phosphate.
Be made up of host and assistant agent with the insecticide milk powder that this host is made, host active ingredient mass content is 0.1～70%, and preferred content is 5～50%, and the assistant agent of forming milk powder is to comprise following quality than mixing active ingredients thing:
Antioxidant: anti-photodissociation agent: surfactant: dispersant=3～20: 2～20: 2～30: 5～60;
Described antioxidant is selected from one or more of following compositions: fatty alcohol, tall oil, triphenyl phosphate, eugenol, sodium hydrogensulfite, ethoxyquin, L-cysteine, vitamin E, vitamin C, beta carotene, Tea Polyphenols, BHA, BHT, TBHQ, epoxidized soybean oil;
Described anti-photodissociation agent is selected from one or more of following compositions: aminobenzoic acid, Uvmul series, sudan black, silkworm chrysalis dry powder, citric acid, pyrogallic acid, paranitrobenzoic acid, fluorescent whitening agent VBL, VC, anisole, n-propyl gallate, oleic acid, Congo red, rhodamine, amaranth dyestuff, lignosulfonates, castor oil;
Described surfactant is selected from one or more of following compositions: alkylaryl polyoxy ethyl ether, fatty alcohol polyoxy ethyl ether, alkylnaphthalene sulfonate, lignosulfonates;
Described dispersant is selected from one or more of following compositions: the dry powder that lignosulfite is made, soda pulping waste, Chinese honey locust, calcium chloride dihydrate, ammonium nitrate, niter cake, dibastic sodium phosphate, magnesium sulfate, ferric trichloride, animals and plants protein hydrolysate is (as the black soya bean cake, soybean cake, groundnut cake, the green soya bean cake, the calabash fiber crops, cottonseed cake, mustard seedcake, sunflower, colza cake, linseed meal, castor cake, kapok, coconut, the paulownia seed, wheat bran, blue or green benevolence cake, the rice bran dregs of fat, Chinese tallow tree seedcake, fish scale, the silkworm slag, hoof dry measure used in former times powder, ox pawl hoof, blood meal, chicken feather, water chestnut, Roll, the pupa slag, whale bone, flocking, tripe, dried small shrimp, fishbone dust, the bird bone, the crab shell, bone meal, the people sends out, nail, the protein hydrolysate of tea seed cake etc.).
Be made up of host and assistant agent with the insecticide tablet that this host is made, the host active constituent content is 0.1～70%, and preferred content is 5～50%, and the assistant agent of forming tablet is to comprise following quality than mixing active ingredients thing:
Antioxidant: anti-photodissociation agent: lubricant: adhesive: adsorbing filler is arranged
＝3～20∶2～20∶1～30∶1～40∶10～70；
Described antioxidant is selected from one or more of following compositions: fatty alcohol, tall oil, triphenyl phosphate, alkylsulfonate, diisopropyl phosphate, isopropyl phosphoric acid fat, eugenol, sodium hydrogensulfite, ethoxyquin, L-cysteine, vitamin E, vitamin C, beta carotene, Tea Polyphenols, BHA, BHT, TBHQ, epoxidized soybean oil;
Described anti-photodissociation agent is selected from one or more of following compositions: aminobenzoic acid, Uvmul series, sudan black, silkworm chrysalis dry powder, citric acid, pyrogallic acid, paranitrobenzoic acid, fluorescent whitening agent VBL, VC, anisole, n-propyl gallate, oleic acid, Congo red, rhodamine, amaranth dyestuff, lignosulfonates, castor oil;
Described lubricant is selected from one or more of following compositions: dolomol, talcum powder, stearic acid;
Described adhesive is selected from one or more of following compositions: plants starch, spent pulping liquor, carboxymethyl cellulose, polyvinyl alcohol, gelatin, gum Arabic, paraffin, stearic acid, rosin, tallow;
Described have adsorbing filler and be selected from one or more of following compositions: potter's clay, bentonite, talcum powder, gypsum, diatomite, white carbon, phosphate.
The using method of the above-mentioned preparation as insecticiding agent made from host of the present invention is:
Insecticide is contained in the packaging bag made from seepy material, this permeable medicine bag is fixed on the top at Palmae plant lobus cardiacus foundation position, utilize the rainwater that infiltrates packaging bag or spray water-soluble part medicine and/or the formation emulsion separated, make the satisfactory leaf of soup that flows out the bag wall flow to the lobus cardiacus foundation position of below, kill reside on the lobus cardiacus and lobus cardiacus in insect.
The present invention is directed to Brontispa longissima has selected for use interior absorption good to the harm characteristics of babassu, and the pyrrole worm that can bring into play long-acting or quick-acting effects respectively is clear, desinsection list or Methomyl are made host, the insecticide of made various formulations has good control efficiency to Brontispa longissima, various preparation provided by the invention is fixed dosage form, do not contain organic solvent, be difficult for causing environmental pollution, available spraying, injection, irritate method method control Brontispa longissimas such as root, the method that permeable packing medicine bag is fixed in lobus cardiacus foundation top provided by the present invention has easy to operate, the medication target is strong, environmental pollution is little, medicament availability height, cost is low, the slowly-releasing drug effect phase is long, the advantage that control efficiency is good.
Specific embodiments
Below in conjunction with embodiment technical solution of the present invention is described further
Embodiment 1,25% pyrrole worm be clear/the Methomyl pulvis
Each active ingredient mass ratio m/m of this routine host is:
The pyrrole worm is clear: Methomyl
＝10∶15
The various active ingredient mass ratio of assistant agent m/m is:
Anti-caking agent: water absorbing agent: antioxidant: anti-photodissociation agent: filler
=isopropyl phosphoric acid ester: Sodium Polyacrylate: eugenol: aminobenzoic acid: kaolin
＝5∶8∶10∶8∶44
Host and assistant agent active ingredient mass ratio m/m are:
Host: assistant agent=1: 3
With above-mentioned quality than raw materials of effective components be mixed the back make the insecticide pulvis with the preparation method of traditional pulvis.
Embodiment 2:25% pyrrole worm is clear/desinsection list pulvis
Each active ingredient mass ratio m/m of this routine host is:
The pyrrole worm is clear: desinsection list=10: 15
The various active ingredient mass ratioes of assistant agent are:
Anti-caking agent: water absorbing agent: antioxidant: anti-photodissociation agent: filler
=isopropyl phosphoric acid ester: Sodium Polyacrylate: Tea Polyphenols: anisole: potter's clay
＝5∶9∶9∶10∶42
Host and assistant agent active ingredient mass ratio are:
Host: assistant agent=1: 3
Embodiment 3:30% pyrrole worm is clear/the Methomyl pulvis
These routine various host active ingredient mass ratioes are:
The pyrrole worm is clear: Methomyl=10: 20
The various active ingredient mass ratioes of assistant agent are:
Anti-caking agent: water absorbing agent: antioxidant: anti-photodissociation agent: filler
=diisopropyl phosphate: polyacrylic acid-vinyl acetate: Tea Polyphenols: paranitrobenzoic acid: diatomite
＝5∶8∶10∶8∶39
Host and assistant agent active ingredient mass ratio are:
Host: assistant agent=3: 7
Embodiment 4:45% pyrrole worm is clear/desinsection list pulvis
These routine various host active ingredient mass ratioes are:
The pyrrole worm is clear: desinsection list=15: 30
The various active ingredient mass ratioes of assistant agent are:
Anti-caking agent: water absorbing agent: antioxidant: anti-photodissociation agent: filler
=isopropyl phosphoric acid ester: POLYPROPYLENE GLYCOL-acrylonitrile: epoxidized soybean oil: pyrogallic acid: white carbon
＝7∶10∶7∶6∶25
Host and assistant agent active ingredient mass ratio are:
Host: assistant agent=45: 55
Embodiment 5:40% pyrrole worm is clear/desinsection list wetting powder
These routine various host active ingredient mass ratioes are:
The pyrrole worm is clear: desinsection list=10: 30
The various active ingredient mass ratioes of assistant agent are:
Stabilizing agent: surfactant: filler
=Tea Polyphenols: sodium lignin sulfonate: talcum powder
＝11∶8∶41
Host and assistant agent active ingredient mass ratio are:
Host: assistant agent=4: 6
With above-mentioned quality than raw materials of effective components be mixed the back make insecticide with the preparation method of traditional wetting powder.
Embodiment 6:40% pyrrole worm is clear/the Methomyl wetting powder
These routine various host active ingredient mass ratioes are:
The pyrrole worm is clear: Methomyl=10: 30
The various active ingredient mass ratioes of assistant agent are:
Stabilizing agent: surfactant: filler
=castor oil: dodecyl sodium sulfate: diatomite
＝9∶7∶44
Host and assistant agent active ingredient mass ratio are:
Host: assistant agent=4: 6
Embodiment 7:30% pyrrole worm is clear/desinsection list wetting powder
These routine various host active ingredient mass ratioes are:
The pyrrole worm is clear: desinsection list=10: 20
The various active ingredient mass ratioes of assistant agent are:
Stabilizing agent: surfactant: filler
=paranitrobenzoic acid: neopelex: potter's clay
＝12∶10∶48
Host and assistant agent active ingredient mass ratio are:
Host: assistant agent=3: 7
Embodiment 8:40% pyrrole worm is clear/desinsection list soluble powder
These routine various host active ingredient mass ratioes are:
The pyrrole worm is clear: desinsection list=1: 3
The various active ingredient mass ratioes of assistant agent are:
Stabilizing agent: surfactant: dispersant: filler
=anisole: lignosulfonates: detergent alkylate sodium iodate: diatomite
＝7∶10∶8∶48
Host and assistant agent active ingredient mass ratio are:
Host: assistant agent=4: 6
With above-mentioned quality than raw materials of effective components be mixed the back make insecticide with the preparation method of traditional soluble powder.
Embodiment 9:45% pyrrole worm is clear/desinsection list milk powder insecticide
These routine various host active ingredient mass ratioes are:
The pyrrole worm is clear: desinsection list=10: 35
The various active ingredient mass ratioes of assistant agent are:
Antioxidant: anti-photodissociation agent: surfactant: dispersant
=Tea Polyphenols: castor oil: sodium lignin sulfonate: spent pulping liquor dry powder
＝7∶8∶10∶30
Host and assistant agent active ingredient mass ratio are:
Host: assistant agent=45: 55
With above-mentioned quality than raw materials of effective components be mixed the back make insecticide with the preparation method of traditional milk powder.
Embodiment 10:45% pyrrole worm is clear/agent of desinsection monolithic
The various active ingredient mass ratioes of this routine host are:
The pyrrole worm is clear: desinsection list=10: 35
The various active ingredient mass ratioes of assistant agent are:
Antioxidant: anti-photodissociation agent: lubricant: adhesive: adsorbing filler is arranged
=Tea Polyphenols: aminobenzoic acid: talcum powder: carboxymethyl cellulose: potter's clay
＝5∶4∶10∶7∶29
Host and assistant agent active ingredient mass ratio are:
Host: assistant agent=45: 55
With above-mentioned quality than raw materials of effective components be mixed the back make insecticide with the preparation method of conventional tablet.
Embodiment 11: the indoor synergy toxicity test of mixture
To not launch coconut lobus cardiacus stripping in flakes, and in soup, soak after 5 seconds and take out, and put into diameter 12cm after drying naturally in the cool, be lined with the culture dish of the filter paper of preserving moisture.Every ware inserts 50 Brontispa longissima adults with etherization.After disposing, culture dish is placed insectary (25 ± 2 ℃), 24 " Invest, Then Investigate " death condition.
Press Abbott formula calculation correction lethality, look into the probit value and the dosage logarithm value of corrected mortality.Carrying out toxicity regression with the Casiofx-3900 calculator calculates.The results are shown in Table 1:
The indoor synergy toxicity test of table 1 mixture
| Reagent agent | Virulence regression equation | LC 50Value (μ g/ml) | Correlation coefficient | Co-toxicity coefficient |
| The clear desinsection list of pyrrole worm Methomyl pyrrole worm is clear: desinsection list (2: 1, m/m) the pyrrole worm is clear: desinsection list (1: 2, m/m) the pyrrole worm is clear: desinsection list (1: 10, m/m) the pyrrole worm is clear: Methomyl (2: 1, m/m) the pyrrole worm is clear: Methomyl (1: 5, m/m) the pyrrole worm is clear: and Methomyl (1: 10, m/m) | Y＝4.4844+1.6186x Y＝4.1754+1.3725x Y＝4.6123+1.1548x Y＝4.7171+1.4550x Y＝4.5719+1.8361x Y＝4.3215+1.6591x Y＝4.8218+1.5499x Y＝4.7189+1.4404x Y＝4.6702+1.4896x | 2.08 3.99 2.17 1.56 1.71 2.56 1.30 1.57 1.66 | 0.9965 0.9944 0.9945 0.9870 0.9939 0.9900 0.9896 0.9768 0.9848 | 158.17 178.63 143.61 161.85 137.26 129.83 |
Embodiment 12: the mixed insecticide field control effectiveness test
With 25% pyrrole worm clear/Methomyl pulvis insecticide (example 1), 30% pyrrole worm is clear/Methomyl pulvis insecticide (example 3), 45% pyrrole worm is clear/desinsection list pulvis (example 4), 40% pyrrole worm is clear/desinsection list wetting powder (example 5), 40% pyrrole worm is clear/Methomyl wetting powder (example 6), 40%1 pyrrole worms are clear/desinsection list soluble powder (example 8), 45% pyrrole worm is clear/desinsection list milk powder (example 9), 45% pyrrole worm is clear/70mm * 40mm pouch-packaged that desinsection monolithic agent (example 10) is made with cotton gauze respectively, every bag of weight is 10g, if blank, the fixing new leaf base that does not launch is placed two cartridge bags on every tree, fixes with continuous yarn.Four repetitions of every processing, totally ten two coconut palms.
Weather condition: light rain was arranged in 5 days after the dispenser, drizzle or moderate rain was arranged behind the medicine in 10 days, 18 days.
Result of the test sees Table 2:
Table 2 mixture preparation is hung bag method control Brontispa longissima field control effectiveness test
| Handle and dosage g/ | Repeat | Insect population radix before the medicine | Behind the medicine 10 days | Behind the medicine 30 days | Behind the medicine 62 days | ||||||||||||
| Borer population (head) alive | The insect population rate (%) that goes down | The average population rate (%) that goes down | Preventive effect (%) | Average preventive effect (%) | Borer population (head) alive | The insect population rate (%) that goes down | The average population rate (%) that goes down | Preventive effect (%) | Average preventive effect (%) | Borer population (head) alive | The insect population rate (%) that goes down | The average population rate (%) that goes down | Preventive effect (%) | Average preventive effect (%) | |||
| Contrast | 1 2 3 4 | 201 152 164 121 | 225 167 186 130 | -11.94 -9.87 -13.41 -7.44 | -10.67 | 242 170 193 151 | -20.40 -11.84 -17.68 -24.79 | -18.68 | 250 184 202 167 | -24.38 -21.05 -23.17 -38.02 | -26.65 | ||||||
| 25% pyrrole worm is clear/Methomyl pulvis insecticide (example 1) 20 | 1 2 3 4 | 184 172 190 157 | 12 9 7 8 | 93.48 94.77 96.32 94.90 | 94.87 | 94.11 95.27 96.67 95.40 | 95.36 | 5 4 3 7 | 97.28 97.67 98.42 95.54 | 97.23 | 97.71 98.04 98.67 96.24 | 97.67 | 31 25 29 38 | 83.15 85.47 84.74 75.80 | 82.29 | 86.70 88.52 87.95 80.89 | 86.02 |
| 30% pyrrole worm is clear/Methomyl pulvis insecticide (example 3) 20 | 1 2 3 4 | 216 180 225 156 | 2 5 7 5 | 99.07 97.22 96.89 96.79 | 97.50 | 99.16 97.49 97.19 97.10 | 97.74 | 3 6 3 5 | 98.61 96.67 98.67 96.79 | 97.68 | 98.83 97.19 98.88 97.30 | 98.05 | 33 30 27 40 | 84.72 83.33 88.00 74.36 | 82.60 | 87.94 86.84 90.53 79.76 | 86.26 |
| 45% pyrrole worm is clear/desinsection list pulvis insecticide (example 4) 20 | 1 2 3 4 | 192 127 165 220 | 5 3 7 9 | 97.40 97.64 95.76 95.91 | 96.68 | 97.65 97.87 96.17 96.30 | 97.00 | 6 7 3 8 | 96.88 94.49 98.18 96.36 | 96.48 | 97.37 95.36 98.47 96.94 | 97.03 | 19 21 29 30 | 90.10 83.46 82.42 86.36 | 85.59 | 92.19 86.94 86.12 89.23 | 88.62 |
| 40% pyrrole worm is clear/desinsection list wetting powder (example 5) 20 | 1 2 3 4 | 178 149 205 166 | 2 5 4 3 | 98.88 96.64 98.05 98.19 | 97.94 | 98.98 96.97 98.24 98.37 | 98.14 | 3 2 4 6 | 98.31 98.66 98.05 96.39 | 97.85 | 98.58 98.87 98.36 96.95 | 98.19 | 22 28 34 18 | 87.64 81.21 83.41 89.16 | 85.35 | 90.24 85.16 86.91 91.44 | 88.44 |
| 40% pyrrole worm is clear/Methomyl wetting powder (example 6) 20 | 1 2 3 4 | 205 135 146 201 | 5 2 4 3 | 97.56 98.52 97.26 98.51 | 97.96 | 97.80 98.66 97.52 98.65 | 98.16 | 9 5 4 8 | 95.61 96.30 97.26 96.02 | 96.30 96.88 97.69 96.65 | 96.88 | 25 30 29 26 | 87.80 77.78 80.14 87.06 | 90.37 82.45 84.32 89.79 | 86.73 | ||
| 40% pyrrole worm is clear/desinsection list soluble powder (example 8) 20 | 1 2 3 4 | 133 151 207 150 | 8 9 7 6 | 93.98 94.04 96.62 96.00 | 95.16 | 94.56 94.61 96.94 96.39 | 95.63 | 10 5 6 8 | 92.48 96.69 97.10 94.67 | 95.23 | 93.66 97.21 97.56 95.51 | 95.98 | 35 31 36 39 | 73.68 79.47 82.61 74.00 | 77.44 | 79.22 83.79 86.27 79.47 | 82.19 |
| 45% pyrrole worm is clear/desinsection list milk powder (example 9) 20 | 1 2 3 4 | 211 128 164 187 | 5 2 3 7 | 97.630 98.438 98.171 96.257 | 97.62 | 97.859 98.588 98.347 96.618 | 97.853 | 5 6 9 10 | 97.63 95.31 94.51 94.65 | 95.53 | 98.00 96.05 95.38 95.49 | 96.23 | 28 31 27 36 | 86.73 75.78 83.54 80.75 | 81.70 | 89.52 80.88 87.00 84.80 | 85.55 |
| 45% pyrrole worm is clear/desinsection monolithic agent (example 10) 20 | 1 2 3 4 | 138 129 157 172 | 2 3 6 7 | 98.551 97.674 96.178 95.930 | 97.08 | 98.690 97.899 96.547 96.323 | 97.365 | 10 9 4 8 | 92.75 93.02 97.45 95.35 | 94.64 | 93.89 94.12 97.85 96.08 | 95.49 | 35 40 38 42 | 74.64 68.99 75.80 75.58 | 73.75 | 79.97 75.52 80.89 80.72 | 79.28 |
Embodiment 13-16 insecticide each active ingredient of pulvis and mass ratio tabulation
| Preferred span | Host active ingredient mass ratio (m/m) 1: 0.5～10 | Assistant agent active ingredient mass ratio (m/m) | Host mass content percentage |
| Anti-caking agent: water absorbing agent: antioxidant: anti-photodissociation agent: filler 1～20 1～15 3～20 2～20 10～70 | 5～50％ | ||
| Embodiment 13 | The pyrrole worm is clear: desinsection list=10: 10 | Sodium alkyl benzene sulfonate: Sodium Polyacrylate: sodium hydrogensulfite: sudan black: vermiculite=5: 8: 15: 5: 47 | 20％ |
| Embodiment 14 | The pyrrole worm is clear: Methomyl=10: 10 | Sodium naphthalene sulfonate: polyacrylic acid-acrylonitrile: ethoxyquin: silkworm chrysalis dry powder: talcum=7: 9: 7: 10: 47 | 20％ |
| Implement 15 | The pyrrole worm is clear: desinsection list=5: 15 | Sodium naphthalene sulfonate: Sodium Polyacrylate: L-cysteine: n-propyl gallate: brown coal=6: 12: 8: 6: 48 | 20％ |
| Embodiment 16 | The pyrrole worm is clear: Methomyl=5: 25 | Alkyl phenol: polyacrylic acid-acrylonitrile: vitamin E: anisole: white carbon=15: 12: 5: 15: 23 | 30％ |
Embodiment 13～16 obtains the implementation result that is similar to table 2 illustrated embodiment 1,3,4; With following compositions the span identical with embodiment 1,3,4,13～16 or on preferred mass shown in the table than span in corresponding composition in the alternate embodiment 1,3,4,13～16, also obtain propinquity effect:
Anti-caking agent: alkylnaphthalene sulfonate, the poly-ethyl ether sulfonate of alkyl phenol, fatty alcohol ethylene oxide adduct sulfonate, fatty alcohol ethylene oxide adduct phosphate, alkylamine salt;
Water absorbing agent: Super absorbent polymers (SAP);
Antioxidant: vitamin C, beta carotene, BHA, BHT, TBHQ;
Anti-photodissociation agent: Uvmul series, citric acid, fluorescent whitening agent VBL, VC, oleic acid, Congo red, rhodamine, amaranth dyestuff, lignosulfonates and castor oil;
Filler: potter's clay, attapulgite, lime stone, calcite, sandstone, float stone, mud coal, winnofil, precipitated silicate calcium, phosphorus ore tailing.
Each active ingredient of embodiment 17-20 wetting powder and mass ratio tabulation
| Preferred span | Host active ingredient mass ratio (m/m) 1: 0.5～10 | Assistant agent active ingredient mass ratio (m/m) | Host mass content percentage |
| Stabilizing agent: surfactant: filler 3～20: 3～20: 10～70 | 5～50％ | ||
| Embodiment 17 | The pyrrole worm is clear: desinsection list=10: 10 | Eugenol: alkylaryl polyoxy ethyl ether: diatomite=4: 17: 61 | 20％ |
| Embodiment 18 | The pyrrole worm is clear: Methomyl=10: 25 | Sodium hydrogensulfite: fatty alcohol polyoxy ethyl ether: precipitated silicate calcium=15: 15: 35 | 35％ |
| Embodiment 19 | The pyrrole worm is clear: desinsection list=10: 25 | Citric acid: lignosulfonates: attapulgite=10: 9: 46 | 35％ |
| Embodiment 20 | The pyrrole worm is clear: Methomyl=2: 10 | Paranitrobenzoic acid: alkylnaphthalene sulfonate: white carbon=15: 15: 48 | 12％ |
Embodiment 17～20 obtains the implementation result that is similar to table 2 illustrated embodiment 5,6; With following compositions the span identical with embodiment 5,6,17～20 or on preferred mass shown in the table than span in corresponding composition in the alternate embodiment 5,6,17～20, also obtain propinquity effect:
Stabilizing agent: ethoxyquin, L-cysteine, vitamin E, vitamin C, beta carotene, BHA, BHT, TBHQ, epoxidized soybean oil, aminobenzoic acid (PABA), Uvmul series, sudan black, silkworm chrysalis dry powder, pyrogallic acid, fluorescent whitening agent VBL, VC, anisole, n-propyl gallate, oleic acid, Congo red, rhodamine, amaranth dyestuff, lignosulfonates;
Filler: kaolin, vermiculite, lime stone, calcite, sandstone, float stone, mud coal, brown coal, precipitated silicate calcium, white carbon, phosphorus ore tailing.
Each active ingredient of embodiment 21-23 soluble powder and mass ratio tabulation
| Preferred span | Host active ingredient mass ratio (m/m) 1: 0.5～10 | Assistant agent active ingredient mass ratio (m/m) | Host mass content percentage |
| Stabilizing agent: surfactant: dispersant: filler=3～20: 3～20: 3～20: 10～70 | 5～50％ | ||
| Embodiment 21 | The pyrrole worm is clear: desinsection list=10: 15 | Citric acid: alkylaryl polyoxy ethyl ether: alkyl phenol: potter's clay=6: 17: 15: 37 | 25％ |
| Embodiment 22 | The pyrrole worm is clear: Methomyl=10: 20 | Congo red: alkyl naphthalene sulfonate: alkyl phenol: rock phosphate=14: 7: 10: 39 | 30％ |
| Embodiment 23 | The pyrrole worm is clear: desinsection list=4: 15 | Silkworm chrysalis dry powder: fatty alcohol polyoxy ethyl ether: native dialkyl group sodium sulfonate: flood peak slush=8: 4: 5: 64 | 19％ |
Embodiment 21～23 obtains the implementation result that is similar to table 2 illustrated embodiment 8; With following compositions the span identical with embodiment 8,21～23 or on preferred mass shown in the table than span in corresponding composition in the alternate embodiment 8,21～23, also obtain propinquity effect:
Stabilizing agent: eugenol, sodium hydrogensulfite, ethoxyquin, the L-cysteine, vitamin E, vitamin C, beta carotene, Tea Polyphenols, BHA, BHT, TBHQ and epoxidized soybean oil, aminobenzoic acid (PABA), Uvmul series, sudan black, pyrogallic acid, paranitrobenzoic acid, fluorescent whitening agent VBL, VC, n-propyl gallate, oleic acid, rhodamine, the amaranth dyestuff, lignosulfonates, fatty alcohol, tall oil, triphenyl phosphate, alkylsulfonate, PAP (diisopropyl phosphate, isopropyl phosphoric acid fat), castor oil;
Dispersant: fatty alcohol alkylene oxide addition product sulfonate, fatty alcohol ethylene oxide adduct phosphoric acid fat;
Filler: white carbon, calcite, lightweight CaCO
3, sodium sulphate.
Each active ingredient of embodiment 24-26 milk powder and mass ratio tabulation
| Preferred span | Host active ingredient mass ratio (m/m) 1: 0.5～10 | Assistant agent active ingredient mass ratio (m/m) | Host mass content percentage |
| Antioxidant: anti-photodissociation agent: surfactant: dispersant=3～20: 2～20: 2～30: 5～60 | 5～50％ | ||
| Embodiment 24 | The pyrrole worm is clear: desinsection list=20: 10 | Tall oil: Congo red: sodium lignin sulfonate: soda pulping waste=10: 15: 20: 25 | 30％ |
| Embodiment 25 | The pyrrole worm is clear: Methomyl=10: 25 | Eugenol: castor oil: alkylaryl polyoxy ethyl ether soybean cake protein hydrolysate=7: 5: 10: 43 | 35％ |
| Embodiment 26 | The pyrrole worm is clear: desinsection list=5: 25 | Epoxidized soybean oil: silkworm chrysalis dry powder: Negel: magnesium sulfate=15: 7: 5: 43 | 30％ |
Embodiment 24～26 obtains the implementation result that is similar to table 2 illustrated embodiment 9; With following compositions the span identical with embodiment 24～26 or 9 or on preferred mass shown in the table than span in corresponding composition in the alternate embodiment 24～26 or 9, also obtain propinquity effect:
Antioxidant: fatty alcohol, triphenyl phosphate, PAP (diisopropyl phosphate, isopropyl phosphoric acid fat), sodium hydrogensulfite, ethoxyquin, L-cysteine, vitamin E, vitamin C, beta carotene, BHA, BHT, TBHQ;
Anti-photodissociation agent: aminobenzoic acid (PABA), Uvmul series, sudan black, silkworm chrysalis dry powder, citric acid, pyrogallic acid, paranitrobenzoic acid, fluorescent whitening agent VBL, VC, anisole, n-propyl gallate, oleic acid, rhodamine, amaranth dyestuff, lignosulfonates;
Surfactant: alkylaryl polyoxy ethyl ether, fatty alcohol polyoxy ethyl ether, alkylnaphthalene sulfonate, lignosulfonates;
Dispersant: animals and plants protein hydrolysate (black soya bean cake, soybean cake, groundnut cake, the green soya bean cake, the calabash fiber crops, cottonseed cake, mustard seedcake, sunflower, colza cake, linseed meal, castor cake, kapok, coconut, the paulownia seed, wheat bran, blue or green benevolence cake, the rice bran dregs of fat, Chinese tallow tree seedcake, fish scale, the silkworm slag, hoof dry measure used in former times powder, ox pawl hoof, blood meal, chicken feather, water chestnut, Roll, the pupa slag, whale bone, flocking, tripe, dried small shrimp, fishbone dust, the bird bone, the crab shell, bone meal, the people sends out, nail, the protein hydrolysate of tea seed cake), Chinese honey locust, calcium chloride dihydrate, ammonium nitrate, niter cake, dibastic sodium phosphate, ferric trichloride.
Each active ingredient of embodiment 27-30 tablet and mass ratio tabulation
| Preferred span | Host active ingredient mass ratio (m/m) 1: 0.5～10 | Assistant agent active ingredient mass ratio (m/m) | Host mass content percentage |
| Antioxidant: anti-photodissociation agent: lubricant: adhesive: adsorbing filler=3～20 are arranged: 2～20: 1～30: 1～40: 10～70; | 5～50％ | ||
| Embodiment 27 | The pyrrole worm is clear: desinsection list=10: 25 | Eugenol: sudan black: talcum powder: paraffin: diatomite=8: 8: 10: 5: 34 | 35％ |
| Embodiment 28 | The pyrrole worm is clear: Methomyl=20: 10 | Tall oil: castor oil: dolomol: plants starch: gypsum=15: 9: 14: 10: 22 | 30％ |
| Embodiment 29 | The pyrrole worm is clear: desinsection list=4: 8 | Ethoxyquin: n-propyl gallate: stearic acid: gum Arabic: talcum powder=9: 7: 5: 10: 57 | 8％ |
| Embodiment 30 | The pyrrole worm is clear: desinsection list=2: 20 | Epoxidized soybean oil: anisole: talcum powder: polyvinyl alcohol: white carbon=5: 18: 8: 24: 23 | 22％ |
Embodiment 27～30 obtains the implementation result that is similar to table 2 illustrated embodiment 10; With following compositions the span identical with embodiment 27～30 or 10 or on preferred mass shown in the table than span in corresponding composition in the alternate embodiment 27～30 or 10, also obtain propinquity effect:
Antioxidant: fatty alcohol, triphenyl phosphate, alkylsulfonate, PAP (diisopropyl phosphate, isopropyl phosphoric acid fat), sodium hydrogensulfite, L-cysteine, vitamin E, vitamin C, beta carotene, BHA, BHT, TBHQ:
Anti-photodissociation agent: Uvmul series, silkworm chrysalis dry powder, citric acid, pyrogallic acid, paranitrobenzoic acid, fluorescent whitening agent VBL, VC, oleic acid, Congo red, rhodamine, amaranth dyestuff, lignosulfonates;
Adhesive: spent pulping liquor, gelatin, stearic acid, rosin, tallow;
Has adsorbing filler: bentonite, phosphate.
Each active ingredient of embodiment 31-34 wetting powder and mass ratio tabulation
| Preferred span | Host active ingredient mass ratio (m/m) 1: 0.5～10 | Assistant agent active ingredient mass ratio (m/m) | Host mass content percentage |
| Stabilizing agent: surfactant: filler 3～20: 3～20: 10～70 | 5～50％ | ||
| Embodiment 31 | The pyrrole worm is clear: desinsection list=1: 0.3 | Eugenol: alkylaryl polyoxy ethyl ether: diatomite=4: 17: 61 | 20％ |
| Embodiment 32 | The pyrrole worm is clear: Methomyl=1: 40 | Sodium hydrogensulfite: fatty alcohol polyoxy ethyl ether: precipitated silicate calcium=15: 15: 35 | 35％ |
| Embodiment 33 | The pyrrole worm is clear: desinsection list=1: 30 | Citric acid: lignosulfonates: attapulgite=10: 9: 46 | 35％ |
| Embodiment 34 | The pyrrole worm is clear: Methomyl=1: 25 | Paranitrobenzoic acid: alkyl tea sulfonate: white carbon=8: 6: 36 | 50％ |
Embodiment 31～34 except that host active ingredient quality than the span difference, other data are with embodiment 17～20, through test, the desinsection control efficiency of embodiment 17～20 is better than embodiment 31～34.
Claims (13)
1, the agricultural chemicals host of control Brontispa longissima is characterized in that: be mainly to comprise following quality than mixing active ingredients thing:
The pyrrole worm is clear: desinsection list or Methomyl=1: 0.1～40.
2, the agricultural chemicals host of control Brontispa longissima according to claim 1 is characterized in that: be mainly to comprise following quality than mixing active ingredients thing:
The pyrrole worm is clear: desinsection list or Methomyl=1: 0.5～10.
3, the insecticide pulvis of making according to claim 1 or 2 described hosts, it is characterized in that: be made up of host and assistant agent, its host active ingredient mass content is 0.1～70%, the assistant agent of forming pulvis is to comprise the mixture of following quality than effective ingredient:
Anti-caking agent: water absorbing agent: antioxidant: anti-photodissociation agent: filler
＝1～20∶1～15∶3～20∶2～20∶10～70。
4, insecticide pulvis according to claim 3 is characterized in that:
Described anti-caking agent is selected from one or more of following compositions: alkylbenzenesulfonate, naphthalene sulfonate, alkylnaphthalene sulfonate, the poly-ethyl ether sulfonate of alkyl phenol, fatty alcohol ethylene oxide adduct sulfonate, alkyl phenol, fatty alcohol ethylene oxide adduct phosphate, alkylamine salt, diisopropyl phosphate ester salt, isopropyl phosphoric acid ester;
Described water absorbing agent is selected from one or more of following compositions: SAP, Sodium Polyacrylate, polyacrylic acid-acrylonitrile, polyacrylic acid-vinyl acetate, polyvinyl alcohol graft copolymerized acrylic acid;
Described antioxidant is selected from one or more of following compositions: eugenol, sodium hydrogensulfite, ethoxyquin, L-cysteine, vitamin E, vitamin C, beta carotene, Tea Polyphenols, BHA, BHT, TBHQ, epoxidized soybean oil;
Described anti-photodissociation agent is selected from one or more of following compositions: aminobenzoic acid, Uvmul series, sudan black, silkworm chrysalis dry powder, citric acid, pyrogallic acid, paranitrobenzoic acid, fluorescent whitening agent VBL, VC, anisole, n-propyl gallate, oleic acid, Congo red, rhodamine, amaranth dyestuff, lignosulfonates, castor oil;
Described filler is selected from one or more of following compositions: potter's clay, attapulgite, kaolin, vermiculite, talcum, lime stone, calcite, diatomite, sandstone, float stone, mud coal, brown coal, winnofil, precipitated silicate calcium, white carbon, phosphorus ore tailing.
5, the insecticide wetting powder of making according to claim 1 or 2 described hosts, it is characterized in that: form by host and assistant agent, its host active constituent content is 0.1～70%, and the assistant agent of forming wetting powder is to comprise following quality than mixing active ingredients thing:
Stabilizing agent: surfactant: filler=3～20: 3～20: 10～70.
6, insecticide wetting powder according to claim 5 is characterized in that:
Described stabilizing agent is selected from one or more of following compositions: eugenol, sodium hydrogensulfite, ethoxyquin, the L-cysteine, vitamin E, vitamin C, beta carotene, Tea Polyphenols, BHA, BHT, TBHQ, epoxidized soybean oil, aminobenzoic acid, Uvmul series, sudan black, silkworm chrysalis dry powder, citric acid, pyrogallic acid, paranitrobenzoic acid, fluorescent whitening agent VBL, VC, anisole, n-propyl gallate, oleic acid, Congo red, rhodamine, the amaranth dyestuff, lignosulfonates, castor oil;
Described surfactant is selected from one or more of following compositions: alkylaryl polyoxy ethyl ether, fatty alcohol polyoxy ethyl ether, alkylnaphthalene sulfonate, lignosulfonates;
Described filler is selected from one or more of following compositions: potter's clay, attapulgite, kaolin, vermiculite, talcum, lime stone, calcite, diatomite, sandstone, float stone, mud coal, brown coal, winnofil, precipitated silicate calcium, white carbon, phosphorus ore tailing.
7, the insecticide soluble powder of making according to claim 1 or 2 described hosts, it is characterized in that: form by host and assistant agent, its host active constituent content is 0.1～70%, and the assistant agent of forming soluble powder is to comprise following quality than mixing active ingredients thing:
Stabilizing agent: surfactant: dispersant: filler=3～20: 3～20: 3～20: 10～70.
8, insecticide soluble powder according to claim 7 is characterized in that:
Described stabilizing agent is selected from one or more of following compositions: eugenol, sodium hydrogensulfite, ethoxyquin, the L-cysteine, vitamin E, vitamin C, beta carotene, Tea Polyphenols, BHA, BHT, TBHQ, epoxidized soybean oil, aminobenzoic acid, Uvmul series, sudan black, silkworm chrysalis dry powder, citric acid, pyrogallic acid, paranitrobenzoic acid, fluorescent whitening agent VBL, VC, anisole, n-propyl gallate, oleic acid, Congo red, rhodamine, the amaranth dyestuff, lignosulfonates, fatty alcohol, tall oil, triphenyl phosphate, alkylsulfonate, the diisopropyl phosphate, isopropyl phosphoric acid fat, castor oil;
Described surfactant is selected from one or more of following compositions: alkylaryl polyoxy ethyl ether, fatty alcohol polyoxy ethyl ether, alkylnaphthalene sulfonate, lignosulfonates;
Described dispersant is selected from one or more of following compositions: alkylsulfonate, alkyl phenol, fatty alcohol alkylene oxide addition product sulfonate, fatty alcohol alkylene oxide addition product phosphoric acid fat;
Described filler is selected from one or more of following compositions: potter's clay, diatomite, white carbon, calcite, flood peak slush, lightweight CaCO
3, sodium sulphate, rock phosphate.
9, the insecticide milk powder of making according to claim 1 or 2 described hosts, it is characterized in that: be made up of host and assistant agent, its host active constituent content is 0.1～70%, the assistant agent of forming milk powder is to comprise following quality than mixing active ingredients thing:
Antioxidant: anti-photodissociation agent: surfactant: dispersant=3～20: 2～20: 2～30: 5～60.
10, insecticide milk powder according to claim 9 is characterized in that:
Described antioxidant is selected from one or more of following compositions: fatty alcohol, tall oil, triphenyl phosphate, eugenol, sodium hydrogensulfite, ethoxyquin, L-cysteine, vitamin E, vitamin C, beta carotene, Tea Polyphenols, BHA, BHT, TBHQ, epoxidized soybean oil;
Described anti-photodissociation agent is selected from one or more of following compositions: aminobenzoic acid, Uvmul series, sudan black, silkworm chrysalis dry powder, citric acid, pyrogallic acid, paranitrobenzoic acid, fluorescent whitening agent VBL, VC, anisole, n-propyl gallate, oleic acid, Congo red, rhodamine, amaranth dyestuff, lignosulfonates, castor oil;
Described surfactant is selected from one or more of following compositions: alkylaryl polyoxy ethyl ether, fatty alcohol polyoxy ethyl ether, alkylnaphthalene sulfonate, lignosulfonates;
Described dispersant is selected from one or more of following compositions: the dry powder that lignosulfite is made, soda pulping waste, Chinese honey locust, calcium chloride dihydrate, ammonium nitrate, niter cake, dibastic sodium phosphate, magnesium sulfate, ferric trichloride, animals and plants protein hydrolysate.
11, the insecticide tablet of making according to claim 1 or 2 described hosts, it is characterized in that: be made up of host and assistant agent, its host active constituent content is 0.1～70%, the assistant agent of forming tablet is to comprise following quality than mixing active ingredients thing:
Antioxidant: anti-photodissociation agent: lubricant: adhesive: adsorbing filler is arranged
＝3～20∶2～20∶1～30∶1～40∶10～70。
12, insecticide tablet according to claim 11 is characterized in that:
Described antioxidant is selected from one or more of following compositions: fatty alcohol, tall oil, triphenyl phosphate, alkylsulfonate, diisopropyl phosphate, isopropyl phosphoric acid fat, eugenol, sodium hydrogensulfite, ethoxyquin, L-cysteine, vitamin E, vitamin C, beta carotene, Tea Polyphenols, BHA, BHT, TBHQ, epoxidized soybean oil;
Described anti-photodissociation agent is selected from one or more of following compositions: aminobenzoic acid, Uvmul series, sudan black, silkworm chrysalis dry powder, citric acid, pyrogallic acid, paranitrobenzoic acid, fluorescent whitening agent VBL, VC, anisole, n-propyl gallate, oleic acid, Congo red, rhodamine, amaranth dyestuff, lignosulfonates, castor oil;
Described lubricant is selected from one or more of following compositions: dolomol, talcum powder, stearic acid;
Described adhesive is selected from one or more of following compositions: plants starch, spent pulping liquor, carboxymethyl cellulose, polyvinyl alcohol, gelatin, gum Arabic, paraffin, stearic acid, rosin, tallow;
Described have adsorbing filler and be selected from one or more of following compositions: potter's clay, bentonite, talcum powder, gypsum, diatomite, white carbon, phosphate.
13, according to the arbitrary described utilization of pesticides method of claim 3-12, it is characterized in that: insecticide is contained in the packaging bag made from seepy material, this permeable medicine bag is fixed on the top at Palmae plant lobus cardiacus foundation position, utilize the rainwater that infiltrates packaging bag or spray water-soluble part medicine and/or the formation emulsion separated, make the satisfactory leaf of soup that flows out the bag wall flow to the lobus cardiacus foundation position of below, kill reside on the lobus cardiacus and lobus cardiacus in insect.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200410026870 CN1243478C (en) | 2004-04-16 | 2004-04-16 | Pesticide main agent for preventing and controlling coconut core chrysomelid and preparation made therefrom and using method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200410026870 CN1243478C (en) | 2004-04-16 | 2004-04-16 | Pesticide main agent for preventing and controlling coconut core chrysomelid and preparation made therefrom and using method |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1561731A CN1561731A (en) | 2005-01-12 |
| CN1243478C true CN1243478C (en) | 2006-03-01 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 200410026870 Expired - Lifetime CN1243478C (en) | 2004-04-16 | 2004-04-16 | Pesticide main agent for preventing and controlling coconut core chrysomelid and preparation made therefrom and using method |
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| Country | Link |
|---|---|
| CN (1) | CN1243478C (en) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1957709B (en) * | 2006-11-17 | 2011-05-18 | 珠海旺世有限公司 | Medication composition of preventing and curing chrysomelid beetles of coconut cardio, and preparation method |
| CN102239881A (en) * | 2011-07-28 | 2011-11-16 | 广州甘蔗糖业研究所 | Insecticidal compound preparation for sugarcane |
| CN104996456A (en) * | 2015-06-18 | 2015-10-28 | 周波香 | Acaricide composition |
| CN112790199A (en) * | 2019-11-14 | 2021-05-14 | 兰州大学 | Botanical insecticide for preventing and treating corn weevil and preparation process thereof |
| CN111903674B (en) * | 2020-08-05 | 2022-07-12 | 马保臣 | Potassium hydrogen persulfate composite powder with uniform and stable quality and preparation process thereof |
| CN112998010A (en) * | 2021-03-03 | 2021-06-22 | 成都嘉佑美康新材料科技有限公司 | Special auxiliary agent for unmanned aerial vehicle plant protection and flying prevention and preparation method and application thereof |
| WO2024032778A1 (en) * | 2022-08-12 | 2024-02-15 | Adama Makhteshim Ltd. | Liquid pesticidal composition |
| CN116250541A (en) * | 2023-03-16 | 2023-06-13 | 海南利蒙特生物科技有限公司 | Medicament for preventing and treating areca-nut coconut leaf beetles and application thereof |
-
2004
- 2004-04-16 CN CN 200410026870 patent/CN1243478C/en not_active Expired - Lifetime
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| Publication number | Publication date |
|---|---|
| CN1561731A (en) | 2005-01-12 |
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