CN1237562A - Anti-oxidizing agent for carbon-contained fireproof material - Google Patents
Anti-oxidizing agent for carbon-contained fireproof material Download PDFInfo
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- CN1237562A CN1237562A CN 99107800 CN99107800A CN1237562A CN 1237562 A CN1237562 A CN 1237562A CN 99107800 CN99107800 CN 99107800 CN 99107800 A CN99107800 A CN 99107800A CN 1237562 A CN1237562 A CN 1237562A
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- powder
- carbon containing
- zinc
- containing refractory
- silicon
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- 239000000463 material Substances 0.000 title description 7
- 230000003064 anti-oxidating effect Effects 0.000 title description 2
- 239000007800 oxidant agent Substances 0.000 title 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 58
- 229910052799 carbon Inorganic materials 0.000 claims abstract description 57
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims abstract description 42
- 239000000843 powder Substances 0.000 claims abstract description 41
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims abstract description 22
- 239000003963 antioxidant agent Substances 0.000 claims abstract description 19
- 230000003078 antioxidant effect Effects 0.000 claims abstract description 19
- 239000004411 aluminium Substances 0.000 claims abstract description 14
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 14
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims abstract description 14
- 229910052581 Si3N4 Inorganic materials 0.000 claims abstract description 9
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 claims abstract description 9
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 claims abstract description 9
- 239000011777 magnesium Substances 0.000 claims description 21
- 229910052749 magnesium Inorganic materials 0.000 claims description 19
- 239000011701 zinc Substances 0.000 claims description 19
- 229910052725 zinc Inorganic materials 0.000 claims description 18
- 239000000203 mixture Substances 0.000 claims description 15
- 229910000838 Al alloy Inorganic materials 0.000 claims description 11
- 229910010271 silicon carbide Inorganic materials 0.000 claims description 11
- OSMSIOKMMFKNIL-UHFFFAOYSA-N calcium;silicon Chemical compound [Ca]=[Si] OSMSIOKMMFKNIL-UHFFFAOYSA-N 0.000 claims description 9
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 8
- -1 norbide Substances 0.000 claims description 8
- 239000010703 silicon Substances 0.000 claims description 8
- 229910052710 silicon Inorganic materials 0.000 claims description 8
- 239000002994 raw material Substances 0.000 claims description 2
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 abstract description 18
- 230000003647 oxidation Effects 0.000 abstract description 16
- 238000007254 oxidation reaction Methods 0.000 abstract description 16
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract description 12
- 239000011449 brick Substances 0.000 abstract description 11
- 239000011819 refractory material Substances 0.000 abstract description 11
- 239000000395 magnesium oxide Substances 0.000 abstract description 9
- 235000013312 flour Nutrition 0.000 abstract description 6
- 239000000377 silicon dioxide Substances 0.000 abstract description 6
- 230000015572 biosynthetic process Effects 0.000 abstract description 2
- 238000005262 decarbonization Methods 0.000 abstract description 2
- 238000003723 Smelting Methods 0.000 abstract 2
- 229910052580 B4C Inorganic materials 0.000 abstract 1
- 229910001051 Magnalium Inorganic materials 0.000 abstract 1
- INAHAJYZKVIDIZ-UHFFFAOYSA-N boron carbide Chemical compound B12B3B4C32B41 INAHAJYZKVIDIZ-UHFFFAOYSA-N 0.000 abstract 1
- 235000013339 cereals Nutrition 0.000 abstract 1
- 238000007664 blowing Methods 0.000 description 8
- 239000007789 gas Substances 0.000 description 6
- 229910000831 Steel Inorganic materials 0.000 description 5
- 239000000654 additive Substances 0.000 description 5
- 239000010959 steel Substances 0.000 description 5
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 230000007246 mechanism Effects 0.000 description 4
- 229910052751 metal Inorganic materials 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- 239000000758 substrate Substances 0.000 description 4
- 230000003245 working effect Effects 0.000 description 4
- RWDBMHZWXLUGIB-UHFFFAOYSA-N [C].[Mg] Chemical compound [C].[Mg] RWDBMHZWXLUGIB-UHFFFAOYSA-N 0.000 description 3
- 230000000996 additive effect Effects 0.000 description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 239000010439 graphite Substances 0.000 description 3
- 229910002804 graphite Inorganic materials 0.000 description 3
- 239000001095 magnesium carbonate Substances 0.000 description 3
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 description 3
- 235000014380 magnesium carbonate Nutrition 0.000 description 3
- 229910000021 magnesium carbonate Inorganic materials 0.000 description 3
- 229910052760 oxygen Inorganic materials 0.000 description 3
- 239000001301 oxygen Substances 0.000 description 3
- 239000011575 calcium Substances 0.000 description 2
- 229910002091 carbon monoxide Inorganic materials 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 238000009792 diffusion process Methods 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- 238000007711 solidification Methods 0.000 description 2
- 230000008023 solidification Effects 0.000 description 2
- 238000010998 test method Methods 0.000 description 2
- 239000011800 void material Substances 0.000 description 2
- 239000011787 zinc oxide Substances 0.000 description 2
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
- 235000003140 Panax quinquefolius Nutrition 0.000 description 1
- 240000005373 Panax quinquefolius Species 0.000 description 1
- 229910004298 SiO 2 Inorganic materials 0.000 description 1
- RQMIWLMVTCKXAQ-UHFFFAOYSA-N [AlH3].[C] Chemical compound [AlH3].[C] RQMIWLMVTCKXAQ-UHFFFAOYSA-N 0.000 description 1
- 239000010426 asphalt Substances 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- 230000005587 bubbling Effects 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 238000005261 decarburization Methods 0.000 description 1
- 238000010891 electric arc Methods 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000004907 flux Effects 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 230000010534 mechanism of action Effects 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 239000012071 phase Substances 0.000 description 1
- 239000005011 phenolic resin Substances 0.000 description 1
- 229920001568 phenolic resin Polymers 0.000 description 1
- 150000003016 phosphoric acids Chemical class 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 238000009991 scouring Methods 0.000 description 1
- 238000009628 steelmaking Methods 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Landscapes
- Compositions Of Oxide Ceramics (AREA)
Abstract
The antioxidant of carbonaceous refractory material is formed from (wt%) 0.15-10% of zinc dust or zinc dust and at least one kind of aluminium powder, magnesium powder, silica flour, rankinite powder, silicon carbide powder, boron carbide powder, magnalium powder and silicon nitride, in which the zinc dust content is greater than or equal to 0.15%, and its grain size is less than 0.5 mm. Said invention can raise the oxidation resistance of the refractory material of magnesia carbon brick, etc., and can inhibite the formation of decarbonization layer, and can prolong the service life of smelting furnace lining, and can reduce loss of refractory material and steel-smelting cost.
Description
The present invention relates to a kind of antioxidant of carbonaceous refractory materials, particularly a kind of carbon containing refractory.
Magnesia carbon brick, aluminum-carbon brick, Al2O3MgOC Bricks, carbon containing refractories such as magnesia-calcium-carbon brick are generally as electric arc furnace, converter, the furnace lining of metallurgical furnaces such as ladle, the one of the main reasons of these refractory corrosions is oxidations at high temperature, promptly before these metallurgical furnaces use, all to carry out long baker, furnace lining contacts with air for a long time, cause the furnace lining oxidation to form thicker zone of oxidation, in the baker process, to form the Decarburized layer of about 30mm as converter, this Decarburized layer is no intensity, porous does not have carbon-coating, when containing molten steel, can be fallen by molten steel scouring, the general every refining one heat steel of converter furnace lining will be etched 0.2～0.6mm, therefore owing to making, the baker oxidation reduces nearly 100 heats the work-ing life of furnace lining, the non-Sheng molten steel time of these metallurgical furnaces in operation process has had a strong impact on the work-ing life of carbon containing refractory because the furnace lining oxidation also can cause the quick erosion when containing steel simultaneously.In order to improve the work-ing life of carbon containing refractory, carried out big quantity research in the prior art, normally in carbon containing refractory, add strong reducible agents such as metallic aluminium powder, magnesium aluminum-alloy powder, silica flour and carborundum powder, thereby improved the oxidation-resistance of carbon containing refractory.For example to disclose a kind of " not burning magnesia carbon brick " be at graphite 5～50% to the clear 61-215250 of Japanese Patent Application Laid-Open, 2～10% 1 kinds of the refractory materials addings or the phosphoric acid salt additive more than 2 kinds of electrosmelted magnesite clinker 50～95% are polyphenoils, but the reaction of the wedding agent carbon of this antioxidant and carbon containing refractory descends the mechanical behavior under high temperature of refractory materials.
The objective of the invention is to obtain a kind of antioxidant of carbon containing refractory, can improve its oxidation-resistance and the not influence of the mechanical behavior under high temperature of refractory materials.
For achieving the above object, the technical solution of the present invention's proposition is:
A kind of antioxidant of carbon containing refractory, by zinc, or at least a composition in zinc and aluminium, magnesium, silicon, silicon calcium powder, silicon carbide, norbide, magnesium aluminum-alloy powder, the silicon nitride powder.
Above-mentioned raw materials is Powdered.
The granularity of zinc powder is less than 0.5mm.
The granularity of zinc powder is less than 0.15mm.
The zinc powder of carbon containing refractory 0.15～10% (weight), the perhaps mixture of at least a composition in the zinc of carbon containing refractory 0.15～10% and aluminium, magnesium, silicon, silicon calcium powder, silicon carbide, norbide, magnesium aluminum-alloy powder, the silicon nitride powder, wherein zinc powder 〉=0.15%.
Account for the zinc powder of carbon containing refractory 0.15～4%, perhaps account for the mixture of at least a composition in the zinc of carbon containing refractory 0.15～6% and aluminium, magnesium, silicon, silicon calcium powder, silicon carbide, norbide, magnesium aluminum-alloy powder, the silicon nitride powder, wherein zinc powder 〉=0.15%.
Below the present invention is done and be described in further detail.
The antioxidant of the carbon containing refractory that the present invention obtains, its key problem in technology are that the mixture that adopts metal zinc or zinc and other component to form is an antioxidant, and wherein each components contents and the mechanism of action are:
Zinc powder: 0.15～10% (weight, as follows), because zinc can be under the metallurgical furnace storing temperature, be gasificated into the gas of high partial pressures, zinc is not very strong to the avidity of oxygen simultaneously, this vapor diffusion that can make it is to Decarburized layer, and because it has certain avidity to oxygen, this will make at Decarburized layer and be oxidized to ZnO; Zinc oxide is dystectic oxide compound, so it does not reduce the anti-corrode performance of material, and the price comparison of zinc is low.
The mixture of at least a composition in zinc and aluminium, magnesium, silicon, silicon calcium powder, silicon carbide, norbide, magnesium aluminum-alloy powder, the silicon nitride powder: 0.15～10%, zinc powder 〉=0.15% wherein.Add acting as of other component: when further guaranteeing its oxidation-resistance, improve the mechanical behavior under high temperature of refractory materials, wherein aluminium powder, silica flour, silicon calcium powder, magnesium aluminum-alloy powder also can improve its resistance to fouling.
Optimal components of the present invention is: the zinc powder of carbon containing refractory 0.15～4% (weight), the perhaps mixture of at least a composition in the zinc of carbon containing refractory 0.15～6% and aluminium, magnesium, silicon, silicon calcium powder, silicon carbide, norbide, magnesium aluminum-alloy powder, the silicon nitride powder, wherein zinc powder 〉=0.15%.
Prior art is normally added strong reducible agents such as metallic aluminium powder, magnesium aluminum-alloy powder, silica flour and carborundum powder in carbon containing refractory, thereby has improved the oxidation-resistance of carbon containing refractory.Mechanism that it is generally acknowledged these antioxidants is: compares with carbon, and the easier oxidation of these additives, and generate more volume after the oxidation, stop up pore, thereby improved the oxidation-resistance of carbon containing refractory.But this oxidation-resistance mechanism can not be explained CaO and water in air reaction generation comparatively large vol Ca (OH) in the magnesia-calcium brick
2The time, the void content that not only can not reduce product increases the fact of void content on the contrary.The present invention has studied its oxidation-resistance mechanism, and the result shows: in carbon-containing bed, these additives and carbon effect generate the very low Al of dividing potential drop
2O, SiO, Mg gas, these strong reducing gass will oxidation generate high temperature solid-state MgO, Al to external diffusion at the Decarburized layer than strong oxidizing property atmosphere
2O
3, SiO
2, these oxide compounds are deposited in from gas phase on the gas passage, have stopped up gas passage, have improved the oxidation-resistance of carbon containing refractory.Because, Al
2The dividing potential drop of O, SiO is very low, thus metallic aluminium powder, silica flour, carborundum powder to be used for the antioxidant effect of carbon containing refractory unsatisfactory.For the magnesium powder, though the evaporation dividing potential drop of Mg is very high, the avidity of it and oxygen is strong especially again, does not become gas toward contact and just has been oxidized to MgO, and the oxidation-resistance of carbon containing refractory of therefore adding MAGNESIUM METAL is also undesirable.
For the carbon containing refractory that adds boron glass, make the apparent porosity reduction and oxidation-protective effect is preferably arranged though in carbon containing refractory, become liquid phase, because it is the flux of material of main part, the anti-corrode of material is obviously descended.
For the antioxidant that obtains to guarantee the oxidation-resistance of carbon containing refractory and do not reduce anti-corrode performance, the present invention is by making the research of the antioxidation mechanism of carbon containing refractory to additive, and fusing point, the boiling point of all metals and oxide compound thereof compared analysis, they and C, CO, CO
2And O
2The thermodynamics free energy of reaction is analyzed, and finds out the antioxidant that metallic zinc is only carbon containing refractory.
Introduce embodiments of the invention below in conjunction with effect.
Embodiment 1
Electrosmelted magnesite clinker with 88%, 10% natural flaky graphite, 2% metal zinc (granularity is less than 0.5mm), 5% modifying asphalt resin system bonded proportioning are carried out batch mixing, it is 36mm, high 36mm base substrate that mixed material becomes diameter with the pressure forming of 240MPa, this base substrate carries out the oxidation-resistance simultaneous test with the magnesia carbon brick that does not add zinc powder after 200 ℃ of solidification treatment.
Test method is: said sample is placed in the resistance furnace, with 260 liters/speed at one hour rating bubbling air, starts resistance furnace and heat up in stove, be warmed up to 1000 ℃ in 1 hour, be incubated blowing out after 2 hours.Continued blowing air 3 hours after the blowing out, at this moment furnace temperature is reduced to 500 ℃.Stop blowing air and take out sample, after the cooling, sample is cut from the centre, measure oxidated layer thickness.The result shows, the magnesium carbon sample zone of oxidation that adds zinc powder is 0.6mm only, and the magnesium carbon sample zone of oxidation of not adding zinc powder is 4.7mm.Because the storing temperature of metallurgical furnace such as ladle is about 1000 ℃, so, in magnesia carbon brick, add metal zinc and form big Decarburized layer when preventing to toast fabulous effect is arranged.
Embodiment 2
Prescription by table 1 carries out batch mixing, and it is 50mm, high 50mm base substrate that mixed material becomes diameter with the pressure forming of 200MPa.This base substrate carries out the oxidation-resistance simultaneous test after 200 ℃ of solidification treatment.
Test method is: said sample is placed in the resistance furnace, with the logical people's air of 240 liters/speed at one hour rating, starts resistance furnace and heat up in stove, be warmed up to 900 ℃ in 1 hour, be incubated blowing out after 4.5 hours.Continued blowing air 3 hours after the blowing out, at this moment furnace temperature is reduced to 500 ℃.Stop blowing air, naturally cool to room temperature, and take out sample, after the cooling, sample is cut from the centre, with the carbon-containing bed diameter of kind of calliper, calculating oxidation area percent.The results are shown in Table 1, the result shows that the magnesium carbon sample that adds zinc powder is at non-metallic aluminium powder, al-mg powder, norbide and the silica flour of being often better than of 900 ℃ oxidation-resistance.Therefore, in carbon containing refractories such as magnesia carbon brick, add the antioxidant zinc powder, can significantly reduce the practical decarburized depth of the carbon containing refractory of 900～1000 ℃ of oxidations, will significantly improve the work-ing life of carbon containing refractory.
Compared with prior art, the antioxidant that obtains of the present invention can the establishment oxidation and decarbonization The formation of layer can improve the non-oxidizability of the refractory materials such as magnesia carbon brick, makes the carbon containing fire proofed wood The oxidation rate of material is reduced to original below 20%, the decarburization that causes during the elimination baking Layer significantly improves service life, minimizing refractory wear and the reduction steel-making of metallurgical furnace lining Cost with carbon containing refractory.
Table 1
| Numbering | Fused magnesite | Additive | The thermosetting phenolic resin bond | Graphite | Oxidation area (%) | Oxidated layer thickness (mm) |
| 1 | 90 | Al:3 | 4.5 | 10 | 28.7 | 3.97 |
| 2 | 90 | Zn:2 | 4.5 | 10 | 1.12 | 0.14 |
| 3 | 90 | AlMg:4 | 4.5 | 10 | 18.8 | 2.52 |
| 4 | 90 | B 4C:2Si:2 | 4.5 | 10 | 3.2 | 0.41 |
Claims (6)
1. the antioxidant of a carbon containing refractory is characterized in that: by zinc, or at least a composition in zinc and aluminium, magnesium, silicon, silicon calcium powder, silicon carbide, norbide, magnesium aluminum-alloy powder, the silicon nitride powder.
2. the antioxidant of carbon containing refractory according to claim 1, it is characterized in that: described raw material is Powdered.
3. the antioxidant of carbon containing refractory according to claim 1 and 2, it is characterized in that: the granularity of described zinc powder is less than 0.5mm.
4. the antioxidant of carbon containing refractory according to claim 1 and 2, its feature is levied and is: the granularity of described zinc powder is less than 0.15mm.
5. the antioxidant of carbon containing refractory according to claim 1, it is characterized in that: the zinc powder that accounts for carbon containing refractory 0.15～10% (weight), the perhaps mixture of at least a composition in the zinc of carbon containing refractory 0.15～10% and aluminium, magnesium, silicon, silicon calcium powder, silicon carbide, norbide, magnesium aluminum-alloy powder, the silicon nitride powder, wherein zinc powder 〉=0.15%.
6. the antioxidant of carbon containing refractory according to claim 1, it is characterized in that: the zinc powder that accounts for carbon containing refractory 0.15～4%, perhaps account for the mixture of at least a composition in the zinc of carbon containing refractory 0.15～6% and aluminium, magnesium, silicon, silicon calcium powder, silicon carbide, norbide, magnesium aluminum-alloy powder, the silicon nitride powder, wherein zinc powder 〉=0.15%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 99107800 CN1237562A (en) | 1999-02-25 | 1999-05-31 | Anti-oxidizing agent for carbon-contained fireproof material |
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN99100838.3 | 1999-02-25 | ||
| CN99100838 | 1999-02-25 | ||
| CN 99107800 CN1237562A (en) | 1999-02-25 | 1999-05-31 | Anti-oxidizing agent for carbon-contained fireproof material |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1237562A true CN1237562A (en) | 1999-12-08 |
Family
ID=25744985
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 99107800 Pending CN1237562A (en) | 1999-02-25 | 1999-05-31 | Anti-oxidizing agent for carbon-contained fireproof material |
Country Status (1)
| Country | Link |
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| CN (1) | CN1237562A (en) |
Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100366582C (en) * | 2006-04-27 | 2008-02-06 | 鞍山科技大学 | Magnesia brick containing antioxidant C-TiN composite powder and method for preparing the same |
| CN102173837A (en) * | 2011-01-27 | 2011-09-07 | 无锡成博科技发展有限公司 | Lubricating coating of high-temperature oxidation resistant sliding plate and preparation process thereof |
| CN102180685A (en) * | 2011-03-10 | 2011-09-14 | 濮阳濮耐高温材料（集团）股份有限公司 | Air-permeable brick for converter |
| CN102329142A (en) * | 2011-07-22 | 2012-01-25 | 郑州京华耐火材料实业有限公司 | Aluminum silicon carbide carbon brick and preparation method thereof |
| CN102408244A (en) * | 2011-08-24 | 2012-04-11 | 江苏苏嘉集团新材料有限公司 | Processing method of carbon-containing refractory product |
| CN102463347A (en) * | 2010-11-16 | 2012-05-23 | 河南黄河旋风股份有限公司 | Composite deoxidizing agent |
| CN102649645A (en) * | 2011-02-23 | 2012-08-29 | 武汉武钢维苏威高级陶瓷有限公司 | Refractory material |
| CN102757250A (en) * | 2012-08-02 | 2012-10-31 | 江苏苏嘉集团新材料有限公司 | Antioxidant used for refractory material |
| CN106810274A (en) * | 2015-12-01 | 2017-06-09 | 镇江市润州金山金属粉末厂 | A kind of carbon zinc refractory material |
| CN111875357A (en) * | 2020-07-30 | 2020-11-03 | 海城市金福锋科技有限公司 | Anti-oxidation high-fracture-resistance hearth castable and production method thereof |
| CN112062586A (en) * | 2020-09-24 | 2020-12-11 | 山东柯信新材料有限公司 | Production method of environment-friendly carbon-containing brick |
| CN112500130A (en) * | 2020-12-07 | 2021-03-16 | 海城利尔麦格西塔材料有限公司 | Silicon-calcium-barium complex phase combined silicon carbide magnesia-carbon brick and manufacturing method thereof |
-
1999
- 1999-05-31 CN CN 99107800 patent/CN1237562A/en active Pending
Cited By (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100366582C (en) * | 2006-04-27 | 2008-02-06 | 鞍山科技大学 | Magnesia brick containing antioxidant C-TiN composite powder and method for preparing the same |
| CN102463347A (en) * | 2010-11-16 | 2012-05-23 | 河南黄河旋风股份有限公司 | Composite deoxidizing agent |
| CN102173837A (en) * | 2011-01-27 | 2011-09-07 | 无锡成博科技发展有限公司 | Lubricating coating of high-temperature oxidation resistant sliding plate and preparation process thereof |
| CN102173837B (en) * | 2011-01-27 | 2013-06-19 | 无锡成博科技发展有限公司 | Lubricating coating of high-temperature oxidation resistant sliding plate and preparation process thereof |
| CN102649645A (en) * | 2011-02-23 | 2012-08-29 | 武汉武钢维苏威高级陶瓷有限公司 | Refractory material |
| CN102180685A (en) * | 2011-03-10 | 2011-09-14 | 濮阳濮耐高温材料（集团）股份有限公司 | Air-permeable brick for converter |
| CN102329142A (en) * | 2011-07-22 | 2012-01-25 | 郑州京华耐火材料实业有限公司 | Aluminum silicon carbide carbon brick and preparation method thereof |
| CN102408244A (en) * | 2011-08-24 | 2012-04-11 | 江苏苏嘉集团新材料有限公司 | Processing method of carbon-containing refractory product |
| CN102408244B (en) * | 2011-08-24 | 2012-12-19 | 江苏苏嘉集团新材料有限公司 | Processing method of carbon-containing refractory product |
| CN102757250A (en) * | 2012-08-02 | 2012-10-31 | 江苏苏嘉集团新材料有限公司 | Antioxidant used for refractory material |
| CN106810274A (en) * | 2015-12-01 | 2017-06-09 | 镇江市润州金山金属粉末厂 | A kind of carbon zinc refractory material |
| CN111875357A (en) * | 2020-07-30 | 2020-11-03 | 海城市金福锋科技有限公司 | Anti-oxidation high-fracture-resistance hearth castable and production method thereof |
| CN112062586A (en) * | 2020-09-24 | 2020-12-11 | 山东柯信新材料有限公司 | Production method of environment-friendly carbon-containing brick |
| CN112500130A (en) * | 2020-12-07 | 2021-03-16 | 海城利尔麦格西塔材料有限公司 | Silicon-calcium-barium complex phase combined silicon carbide magnesia-carbon brick and manufacturing method thereof |
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