CN1235944A - Multi-element long-acting organic compound fertilizer and preparation method thereof - Google Patents

Multi-element long-acting organic compound fertilizer and preparation method thereof Download PDF

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CN1235944A
CN1235944A CN 99113036 CN99113036A CN1235944A CN 1235944 A CN1235944 A CN 1235944A CN 99113036 CN99113036 CN 99113036 CN 99113036 A CN99113036 A CN 99113036A CN 1235944 A CN1235944 A CN 1235944A
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parts
kilograms
compound fertilizer
dyhard
organic compound
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徐忱修
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    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05GMIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G1/00Mixtures of fertilisers belonging individually to different subclasses of C05

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Abstract

A long-acting multi-element organic compound fertilizer is prepared from dicyandiamide (1-43% of pure nitrogen) through adding dicyandiamide to the compound fertilizer whose total nitrogen (phosphorus) and potassium (K) are = 6.64-37.6: 4.7-14.96: 2.8-16. The preparation method of the invention is that 18 percent of ammonium bicarbonate is added into lignite sieved by a 80-mesh sieve, and the mixture is evenly stirred and placed for half a month at the temperature of more than 15 ℃ to obtain the component A. Mixing the component A with dicyandiamide to obtain a component B. And mixing the component B with ammonium bicarbonate or urea to obtain the component C. Mixing the rest of phosphate fertilizer, potash fertilizer, trace fertilizer and the like with the component C. The product of the invention has simple preparation process, no need of additional fertilizer in the growing period of crops and obvious yield increasing effect.

Description

Polyary long acting organic compound fertilizer and preparation method thereof
The present invention relates to a kind of chemical fertilizer and preparation method thereof.
At present the kind of chemical fertilizer is a lot, and wherein long-acting ammonium bicarbonate is relatively to be subjected to one of fertilizer that the peasant welcomes.It mainly is to be added with Dyhard RU 100 in bicarbonate of ammonia.Promptly once apply fertilizer to the subsoil though it can change traditional fertilising custom, no longer topdress breeding time, also has many deficiencies: 1. nitrogen only be provided, lack phosphorus, potassium and in trace element, can not satisfy the demand of crop to various nutrition; 2. added Dyhard RU 100 must be to add when producing bicarbonate of ammonia in the bicarbonate of ammonia, complex process, and quality also be difficult to guarantee, 3. the peasant must join when using long-acting ammonium bicarbonate and executes other element, not only the amount of executing is difficult to grasp, and also increases many troubles; If 4. administering long-lasting bicarbonate of ammonia consumption is big, arid was easily burnt and was planted spring, burnt seedling.
The object of the present invention is to provide a kind of preparation technology simply, directly use, nutrition is complete, the polyary long acting organic compound fertilizer that has no side effect.
Purpose of the present invention can realize by following measure: a kind of polyary long acting organic compound fertilizer, and it is to be added with Dyhard RU 100 in simple substance fertilizer that contains nitrogen, phosphorus, potassium and composite fertilizer, it is characterized in that:
A, total nitrogen: total phosphorus content: general potassium amount=6.64~37.6: 4.7~14.96: 2.8~16,
B, Dyhard RU 100 consumption are 1~43% of pure nitrogen levels.
The preparation method of above-mentioned polyary long acting organic compound fertilizer is characterized in that:
1. brown coal were pulverized 80 mesh sieves, and in brown coal, added bicarbonate of ammonia, and their weight ratio is a bicarbonate of ammonia: brown coal=18: 100, the back that stirs is placed about two weeks and is got the A component in the physical environment of temperature more than 15 ℃,
2. A component and Dyhard RU 100 uniform mixing are got the B component,
3. B component and bicarbonate of ammonia or urea uniform mixing are got the C component,
4. phosphate fertilizer, potash fertilizer, little fertilizer and other composition and the C component with remainder mixes, and stirs promptly to obtain mixing powder type product of the present invention.
Preparation particulate state product of the present invention also needs
1. each feed particulate material is pulverized, is crossed 80 mesh sieves,
2. add in the tablets press after the mixture of each raw material that will obtain and talcum powder and the mixes with small amount of water, wherein mixture and talcous weight ratio are as follows: each raw mix: talcum powder=100: 14~18.
Corn is as follows with the composition weight ratio of mixing powder type composite fertilizer: 5.0~25 parts in urea, 16~28 parts of Secondary ammonium phosphates, 3.5~11.5 parts of calcium superphosphate, 1.5~7.0 parts of ammonium chlorides, 25~50 parts in bicarbonate of ammonia, 1.5~7.0 parts in ammonium sulfate, 5.0~13 parts in Repone K, 0.15~0.4 part of Dyhard RU 100,0.5~2.0 part in zinc sulfate, 2.0~4.0 parts in brown coal.
Corn is as follows with the composition weight ratio of granular compound fertilizer: 30~45 parts in urea, 15~30 parts of Secondary ammonium phosphates, 5.0~12 parts in Repone K, Dyhard RU 100 0.3~1.0,0.5~2.0 part in zinc sulfate, brown coal 2.0~4.0.
Corn is as follows with the composition weight ratio of granular compound fertilizer: 2~6 parts in 30~70 parts in urea, 15~30 parts of Secondary ammonium phosphates, 5~12 parts in Repone K, 0.5~1.5 part of Dyhard RU 100, zinc sulfate 0.5~2.0, brown coal.
Paddy rice is as follows with the composition weight ratio of granular compound fertilizer: 8~20 parts in urea, 8~20 parts of Secondary ammonium phosphates, 17~30 parts of calcium superphosphate, 15~30 parts of ammonium chlorides, 5~12 parts in Repone K, 0.3~0.6 part of Dyhard RU 100,0.5~2.0 part in zinc sulfate, 2~6 parts in brown coal, 0.2~0.6 part of Butachlor technical 92,0.1~0.5 part of molinate.
Soybean is as follows with the composition weight ratio of granular compound fertilizer: 28~38 parts in urea, 12~25 parts of Secondary ammonium phosphates, 12~20 parts in Repone K, 0.3~0.8 part of Dyhard RU 100,1~6 part in brown coal.
Grape or peach are as follows with the composition weight ratio of mixing powder type composite fertilizer: 10~20 parts in urea, 5~15 parts of Secondary ammonium phosphates, 20~30 parts of calcium superphosphate, 5~15 parts in bicarbonate of ammonia, 2~10 parts in ammonium sulfate, 2~10 parts in Repone K, 0.2~0.6 part of two cyanogen ammonium, 2~6 parts in brown coal, 2~5 parts in zeolite, 2~5 parts of magnesium salts, 15~20 parts of vitriolate of tartar.
Apple tree is as follows with the composition weight ratio of mixing powder type composite fertilizer: 5~12 parts in urea, 15~26 parts of Secondary ammonium phosphates, 17~25 parts of ammonium chlorides, 3~6 parts of ammonium chlorides, 2~6 parts in bicarbonate of ammonia, 20~35 parts in ammonium sulfate, 3~7 parts in Repone K, 0.1~0.5 part of Dyhard RU 100,0.3~0.7 part in zinc sulfate, 2~6 parts in brown coal, 0.4~0.8 part of borax, 4~8 parts of vitriolate of tartar, 0.1~0.5 part in ferrous sulfate.
Spring wheat is as follows with the composition weight ratio of mixing powder type composite fertilizer: 16~36 parts in urea, 10~26 parts of Secondary ammonium phosphates, 5~14 parts of calcium superphosphate, 2~5 parts of ammonium chlorides, 25~40 parts in bicarbonate of ammonia, 2~6 parts in ammonium sulfate, 7~13 parts in Repone K, 0.4~0.9 part of Dyhard RU 100,0.5~2.0 part in zinc sulfate, 1~4 part in brown coal.
Winter wheat is as follows with the composition weight ratio of granular compound fertilizer: 30~50 parts in urea, 15~25 parts of Secondary ammonium phosphates, 5~25 parts in Repone K, 0.3~1.0 part of Dyhard RU 100,0.5~2.0 part in zinc sulfate, 2~8 parts in brown coal.
Vegetables are as follows with the composition weight ratio of mixing powder type composite fertilizer: 5~16 parts in urea, 8~17 parts of Secondary ammonium phosphates, 10~20 parts of calcium superphosphate, 10~20 parts in bicarbonate of ammonia, 6~18 parts in ammonium sulfate, 3~8 parts in Repone K, 0.23~0.76 part of Dyhard RU 100,0.6~2.0 part in zinc sulfate, 5~15 parts in brown coal, 2~5 parts of vitriolate of tartar.
The present invention is added with the Dyhard RU 100 nitrification inhibitor in simple substance fertilizer that contains nitrogen, phosphorus, potassium and composite fertilizer.
In the raw material of the present invention, nitrogen is to select suitable nitrogen form according to different soils and crop.It mainly adopts urea, Secondary ammonium phosphate, also can adopt ammonium chloride, bicarbonate of ammonia, ammonium sulfate etc.The plain main consideration of phosphorus is water-soluble, also will be according to the annual and suitable collocation of perennial crop.It mainly adopts Secondary ammonium phosphate, also can adopt calcium superphosphate.According to the sensitivity of crop to different physiological acidic fertilizers, the plain main Repone K that adopts of potassium also can adopt vitriolate of tartar.Also have organic matter in the raw material, as ammonium humate, brown coal, the peat composed of rotten mosses etc., it promptly is that organic fertilizer is again the tracer material of Dyhard RU 100 among the preparation technology.Middle in addition trace element is according to Different Crop the reaction of trace element in the difference suitably to be arranged in pairs or groups.It mainly adopts zinc sulfate, also can adopt magnesium salts, inorganicss such as (as sal epsom or magnesiumcarbonate) and ferrous sulfate, borax, zeolite.Indivedual crops also are added with herbicides such as Butachlor technical 92, molinate.
Total nitrogen in the raw material of the present invention (the nitrogen content sum in each nitrogenous compound is in purity nitrogen), (the phosphorus content sum in each P contained compound is with P for total phosphorus content 2O 5The meter) and general potassium amount (the potassium content sum in each potassium-containing compound is with K 2The O meter) though because of their some variation of ratio of crop difference, they include in following ranges, i.e. total nitrogen: total phosphorus content: general potassium amount=6.64~37.6: 4.7~14.96: 2.8~16.
Adopt Dyhard RU 100 (molecular formula C among the present invention 2N 4H 4) suppress the nitrated of soil ammonium-state, strengthen the nitrogen thermostability, make nitrogenous fertilizer long-actingization.Therefore its consumption is relevant with total pure nitrogen level in the composite fertilizer.Also different according to different its consumptions of crop in addition, summary is got up, and the Dyhard RU 100 consumption is 1~4.3% of total pure nitrogen level, if consumption is less than 1% DeGrain, if not only cost is high but also can have side effects to crop greater than 4.3% for consumption, be about to that nitrogen is fixing can not to be discharged.
The preparation method of product of the present invention
1, mixes the preparation method of powder type product
1. brown coal are pulverized, crossed 80 mesh sieves.In brown coal, add bicarbonate of ammonia, and their weight ratio is a bicarbonate of ammonia: brown coal=18: 100.The back about two weeks of placement in the physical environment of temperature more than 15 ℃ that stirs makes it reaction, so brown coal substantially all change ammonium humate into, it is the A component.
2. the A component is mixed with Dyhard RU 100 and stir the B component.
3. be that bicarbonate of ammonia or urea mix and makes it long-actingization with the B component with containing the nitrogen material, stir the C component.
4. phosphate fertilizer, potash fertilizer, little fertilizer and other composition and the C component with remainder mixes, and stirs and promptly obtains gray product of the present invention.
2, the preparation method of granular product
1. earlier each feed particulate material such as urea, Secondary ammonium phosphate are pulverized, crossed 80 mesh sieves.
2. repeat to mix the preparation method of powder type product.
3. add granulation in the tablets press after the mixture of each raw material that will obtain and talcum powder and the mixes with small amount of water.Wherein each raw mix and talcous weight ratio are as follows: each raw mix: talcum powder=100: 14~18.
The present invention has following advantage compared to existing technology:
Product of the present invention includes unit and polynary fertilizer and Dyhard RU 100 nitrification inhibitors such as nitrogen, phosphorus, potassium and trace element, therefore 1. can make long-actingization of nitrogen, prolong the nitrogen fertilizer efficiency period more than one times, when bottom application ensuing crop breeding time no longer with topdressing, the saving of labor, save time.2. it is about about 12% to have improved the utilization ratio of chemical fertilizer, has solved the limiting factor of minimum nutrient, improved between each element connection should with add effect mutually.3. nutrient is complete in the fertilizer, needn't join other fertilizer again, removes many troubles from.4. fertilizer is with strong points, can reasonably prepare the demand relation of nutritive element according to soil crop, fertilizer etc., and the nutrient balance relation of coordinating between the three satisfies the demand of each breeding time to various elements.5. obvious effect of increasing production: use this fertilizer and on average can produce more food more than 20%, volume increase fruit about 15~25%.6. preparation technology is simple, can broadcast with machine sowing according to the people and make mixed powdery or particulate state.
Example 1
Brown coal (Hollington gol City, Inner Mongol company limited in a steady stream produces) were pulverized 80 mesh sieves.Get the bicarbonate of ammonia that 30 kilograms of brown coal powders add 5.4 kilograms, mechanical stirring behind the mixing covered it in 5 minutes, places two weeks and get the A component in the physical environment more than 15 ℃.The A component that obtains is above mixed with 6.7 kilograms of Dyhard RU 100s, and mechanical stirring made it evenly in 4 minutes, got the B component.The B component that obtains is above mixed with 390 kilograms of bicarbonate of ammonia, and mechanical stirring made it the even C component that gets in 5 minutes.Behind 163.5 kilograms of urea and 30 kilograms of ammonium chloride mixings, again itself and 5 kilograms of zinc sulfate, 30 kilograms of ammonium sulfate, 200 kilograms of Secondary ammonium phosphates, 75 kilograms of calcium superphosphate, 84 kilograms of Repone K and C component are mixed together, mechanical stirring ten minutes, can obtain grey color contamination powder type product, it is the polyary long acting organic compound fertilizer that the corn artificial broadcast uses.
Example 2
Repeat the operation of example 1, wherein 35 kilograms of 160 kilograms of 1.5 kilograms in 5 kilograms in 15 kilograms of 50 kilograms in 25 kilograms in 5.4 kilograms of 3.6 kilograms in bicarbonate of ammonia, Dyhard RU 100s, bicarbonate of ammonia, urea, ammonium chlorides, zinc sulfate, ammonium sulfate, Secondary ammonium phosphates, calcium superphosphate, 50 kilograms in the Repone K of 20 kilograms in brown coal and its adapted, the mixed powder type product that obtains is the polyary long acting organic compound fertilizer that the corn artificial broadcast uses.
Example 3
Repeat the operation of example 1, wherein 40 kilograms in brown coal are the polyary long acting organic compound fertilizer that the corn artificial broadcast uses with 130 kilograms in 115 kilograms of 280 kilograms of 70 kilograms in 20 kilograms in 70 kilograms of 250 kilograms in 500 kilograms in 12.7 kilograms of 7.2 kilograms in bicarbonate of ammonia, Dyhard RU 100s, bicarbonate of ammonia, urea, ammonium chlorides, zinc sulfate, ammonium sulfate, Secondary ammonium phosphates, calcium superphosphate, the Repone K of its adapted, the mixed powder type product that obtains.
Example 4
Repeat the operation of example 1, wherein 20 kilograms in brown coal, with 40 kilograms of 4 kilograms of 30 kilograms in 170 kilograms of 150 kilograms of 200 kilograms in 3 kilograms in 30 kilograms of 50 kilograms in 20 kilograms in 1 kilogram of 3.6 kilograms in bicarbonate of ammonia, Dyhard RU 100, bicarbonate of ammonia, urea, ammonium chlorides, zinc sulfate, ammonium sulfate, Secondary ammonium phosphates, calcium superphosphate, Repone K, boraxs, vitriolate of tartar, 1 kilogram in the ferrous sulfate of its adapted, the mixed powder type product that obtains is the polyary long acting organic compound fertilizer that the apple tree artificial broadcast uses.
Example 5
Repeat the operation of example 1, wherein 40 kilograms in brown coal, with 60 kilograms of 6 kilograms of 50 kilograms in 230 kilograms of 210 kilograms of 280 kilograms in 5 kilograms in 48 kilograms of 81 kilograms in 40 kilograms in 3 kilograms of 7.2 kilograms in bicarbonate of ammonia, Dyhard RU 100s, bicarbonate of ammonia, urea, ammonium chlorides, zinc sulfate, ammonium sulfate, Secondary ammonium phosphates, calcium superphosphate, Repone K, boraxs, vitriolate of tartar, 3 kilograms in the ferrous sulfate of its adapted, the mixed powder type product that obtains is the polyary long acting organic compound fertilizer that the apple tree artificial broadcast uses.
Example 6
Repeat the operation of example 1, wherein 60 kilograms in brown coal, with 80 kilograms of 8 kilograms of 70 kilograms in 250 kilograms of 260 kilograms of 350 kilograms in 7 kilograms in 60 kilograms of 60 kilograms in 5 kilograms of 10.8 kilograms in bicarbonate of ammonia, Dyhard RU 100s, bicarbonate of ammonia, urea 120 kg, ammonium chlorides, zinc sulfate, ammonium sulfate, Secondary ammonium phosphates, calcium superphosphate, Repone K, boraxs, vitriolate of tartar, 5 kilograms in the ferrous sulfate of its adapted, the mixed powder type product that obtains is the polyary long acting organic compound fertilizer that the apple tree artificial broadcast uses.
Example 7
Repeat the operation of example 1, wherein 10 kilograms in brown coal, with 50 kilograms of 100 kilograms of 20 kilograms in 5 kilograms in 20 kilograms of 160 kilograms in 250 kilograms in 4 kilograms of 1.8 kilograms in bicarbonate of ammonia, Dyhard RU 100s, bicarbonate of ammonia, urea, ammonium chlorides, zinc sulfate, ammonium sulfate, Secondary ammonium phosphates, calcium superphosphate, 70 kilograms in the Repone K of its adapted, the mixed powder type product that obtains is the polyary long acting organic compound fertilizer that the spring wheat artificial broadcast uses.
Example 8
Repeat the operation of example 1, wherein 22.2 kilograms in brown coal, with 90 kilograms of 174 kilograms of 40 kilograms in 5 kilograms in 34.4 kilograms of 218 kilograms in 309 kilograms in 7.4 kilograms of 4 kilograms in bicarbonate of ammonia, Dyhard RU 100s, bicarbonate of ammonia, urea, ammonium chlorides, zinc sulfate, ammonium sulfate, Secondary ammonium phosphates, calcium superphosphate, 100 kilograms in the Repone K of its adapted, the mixed powder type product that obtains is the polyary long acting organic compound fertilizer that the spring wheat artificial broadcast uses.
Example 9
Repeat the operation of example 1, wherein 40 kilograms in brown coal, with 140 kilograms of 260 kilograms of 60 kilograms in 20 kilograms in 50 kilograms of 260 kilograms in 400 kilograms in 9 kilograms of 7.2 kilograms in bicarbonate of ammonia, Dyhard RU 100s, bicarbonate of ammonia, urea, ammonium chlorides, zinc sulfate, ammonium sulfate, Secondary ammonium phosphates, calcium superphosphate, 130 kilograms in the Repone K of its adapted, the mixed powder type product that obtains is the polyary long acting organic compound fertilizer that the spring wheat artificial broadcast uses.
Example 10
Repeat the operation of example 1, wherein 40 kilograms in brown coal, with 100 kilograms of 80 kilograms of 60 kilograms in 6 kilograms in 50 kilograms in 100 kilograms in 2.3 kilograms of 9 kilograms in bicarbonate of ammonia, Dyhard RU 100s, bicarbonate of ammonia, urea, zinc sulfate, ammonium sulfate, Secondary ammonium phosphates, calcium superphosphate, 30 kilograms in the Repone K of its adapted, 20 kilograms of vitriolate of tartar, the mixed powder type product that obtains is the polyary long acting organic compound fertilizer that the vegetables artificial broadcast uses.
Example 11
Repeat the operation of example 1, wherein 100 kilograms in brown coal, with 169 kilograms of 130 kilograms of 128 kilograms in 6 kilograms in 110 kilograms in 150 kilograms in 4.4 kilograms of 18 kilograms in bicarbonate of ammonia, Dyhard RU 100s, bicarbonate of ammonia, urea, zinc sulfate, ammonium sulfate, Secondary ammonium phosphates, calcium superphosphate, 50 kilograms in the Repone K of its adapted, 30 kilograms of vitriolate of tartar, the mixed powder type product that obtains is the polyary long acting organic compound fertilizer that the vegetables artificial broadcast uses.
Example 12
Repeat the operation of example 1, wherein 150 kilograms in brown coal, with 200 kilograms of 200 kilograms of 180 kilograms in 20 kilograms in 160 kilograms in 200 kilograms in 7.56 kilograms of 27 kilograms in bicarbonate of ammonia, Dyhard RU 100s, bicarbonate of ammonia, urea, zinc sulfate, ammonium sulfate, Secondary ammonium phosphates, calcium superphosphate, 80 kilograms in the Repone K of its adapted, 50 kilograms of vitriolate of tartar, the mixed powder type product that obtains is the polyary long acting organic compound fertilizer that the vegetables artificial broadcast uses.
Example 13
Repeat the operation of example 1, wherein 20 kilograms in brown coal, with 200 kilograms of 50 kilograms of 20 kilograms in 100 kilograms in 50 kilograms in 2 kilograms of 3.6 kilograms in bicarbonate of ammonia, Dyhard RU 100s, bicarbonate of ammonia, urea, ammonium sulfate, Secondary ammonium phosphates, calcium superphosphate, 20 kilograms in the Repone K of its adapted, 100 kilograms of vitriolate of tartar, 20 kilograms in sal epsom, 20 kilograms in zeolite (Jilin, Jilin Fei Jin factory product), the mixed powder type product that obtains are the polyary long acting organic compound fertilizer that grape and peach artificial broadcast use.
Example 14
Repeat the operation of example 1, wherein 37.4 kilograms in brown coal, with 240 kilograms of 114 kilograms of 60 kilograms in 150 kilograms in 115 kilograms in 4.3 kilograms of 6.7 kilograms in bicarbonate of ammonia, Dyhard RU 100s, bicarbonate of ammonia, urea, ammonium sulfate, Secondary ammonium phosphates, calcium superphosphate, 60 kilograms in the Repone K of its adapted, 150 kilograms of vitriolate of tartar, 35 kilograms in sal epsom, 37 kilograms in zeolite (Jilin, Jilin Fei Jin factory product), the mixed powder type product that obtains are the polyary long acting organic compound fertilizer that grape and peach artificial broadcast use.
Example 15
Repeat the operation of example 1, wherein 60 kilograms in brown coal, with 300 kilograms of 150 kilograms of 100 kilograms in 200 kilograms in 150 kilograms in 6 kilograms of 10.8 kilograms in bicarbonate of ammonia, Dyhard RU 100s, bicarbonate of ammonia, urea, ammonium sulfate, Secondary ammonium phosphates, calcium superphosphate, 100 kilograms in the Repone K of its adapted, 200 kilograms of vitriolate of tartar, 50 kilograms in sal epsom, 50 kilograms in zeolite (Jilin, Jilin Fei Jin factory product), the mixed powder type product that obtains are the polyary long acting organic compound fertilizer that grape and peach artificial broadcast use.
Example 16
Brown coal were pulverized 80 mesh sieves.Get the bicarbonate of ammonia that 30 kilograms of brown coal powders add 5.4 kilograms, mechanical stirring behind the mixing covered it in 5 minutes, places two weeks and get the A component in the physical environment more than 15 ℃.The A component that obtains is mixed with 6.7 kilograms of Dyhard RU 100s, and mechanical stirring made it evenly in 4 minutes, got the B component.The B component is mixed with 340 kilograms of urea through pulverizing and cross 80 mesh sieves, and mechanical stirring made it evenly in 5 minutes, must the C component.218 kilograms of ammonium hydrogen phosphates and 84 kilograms in Repone K, 5 kilograms in zinc sulfate and the above-mentioned C component of pulverizing and cross 80 mesh sieves of learning from else's experience mixes, and it is even that mechanical stirring made it in 10 minutes.With mixture and the 109.4 kilograms of talcum powder uniform mixing that obtain, add again after the suitable quantity of water and drop in the tablets press, the grizzled particle shape product that obtains is the polyary long acting organic compound fertilizer that the corn machine sowing is used.
Example 17
Repeat the operation of example 16, wherein 20 kilograms in brown coal, with 3.6 kilograms in the bicarbonate of ammonia of its adapted, 3 kilograms of Dyhard RU 100s, 300 kilograms in urea, 150 kilograms of Secondary ammonium phosphates, 50 kilograms in Repone K, 5 kilograms in zinc sulfate, the mixture that obtains is mixed with 73.92 kilograms of talcum powder, and the granular disintegration that finally obtains is the polyary long acting organic compound fertilizer that the corn machine sowing is used.
Example 18
Repeat the operation of example 16, wherein 40 kilograms in brown coal, with 7.2 kilograms in the bicarbonate of ammonia of its adapted, 20 kilograms of 10 kilograms of Dyhard RU 100s, 450 kilograms in urea, 300 kilograms of Secondary ammonium phosphates, Repone K 120 kg, zinc sulfate, the mixture that obtains is mixed with 169.2 kilograms of talcum powder, and the granular disintegration that finally obtains is the polyary long acting organic compound fertilizer that the corn machine sowing is used.
Example 19
Repeat the operation of example 16, wherein 20 kilograms in brown coal, with 3.6 kilograms in the bicarbonate of ammonia of its adapted, 5 kilograms of Dyhard RU 100s, 300 kilograms in urea, 150 kilograms of Secondary ammonium phosphates, 50 kilograms in Repone K, 5 kilograms in zinc sulfate, the mixture that obtains is mixed with 74.2 kilograms of talcum powder, and the granular disintegration that finally obtains is the polyary long acting organic compound fertilizer that the corn machine sowing is used.
Example 20
Repeat the operation of example 16, wherein 40 kilograms in brown coal, with 7.2 kilograms in the bicarbonate of ammonia of its adapted, 11 kilograms of Dyhard RU 100s, 600 kilograms in urea, 218 kilograms of Secondary ammonium phosphates, 84 kilograms in Repone K, 5 kilograms in zinc sulfate, the mixture that obtains is mixed with 153.3 kilograms of talcum powder, and the granular disintegration that finally obtains is the polyary long acting organic compound fertilizer that the corn machine sowing is used.
Example 21
Repeat the operation of example 16, wherein 60 kilograms in brown coal, with 10.8 kilograms in the bicarbonate of ammonia of its adapted, 20 kilograms of 15 kilograms of Dyhard RU 100s, 700 kilograms in urea, 300 kilograms of Secondary ammonium phosphates, Repone K 120 kg, zinc sulfate, the mixture that obtains is mixed with 218.7 kilograms of talcum powder, and the granular disintegration that finally obtains is the polyary long acting organic compound fertilizer that the corn machine sowing is used.
Example 22
Repeat the operation of example 16, wherein 10 kilograms in brown coal, with 1.8 kilograms in the bicarbonate of ammonia of its adapted, 3 kilograms of Dyhard RU 100s, 280 kilograms in urea, Secondary ammonium phosphate 120 kg, Repone K 120 kg, the mixture that obtains is mixed with 84 kilograms of talcum powder, the granular disintegration that finally obtains is the polyary long acting organic compound fertilizer that the soybean machine sowing is used.
Example 23
Repeat the operation of example 16, wherein 28.6 kilograms in brown coal, with 51.5 kilograms in the bicarbonate of ammonia of its adapted, 6.4 kilograms of Dyhard RU 100s, 324 kilograms in urea, 174 kilograms of Secondary ammonium phosphates, 167 kilograms in Repone K, the mixture that obtains is mixed with the 105 kg talcum powder, the granular disintegration that finally obtains is the polyary long acting organic compound fertilizer that the soybean machine sowing is used.
Example 24
Repeat the operation of example 16, wherein 60 kilograms in brown coal, with 10.8 kilograms in the bicarbonate of ammonia of its adapted, 8 kilograms of Dyhard RU 100s, 380 kilograms in urea, 250 kilograms of Secondary ammonium phosphates, 200 kilograms in Repone K, the mixture that obtains is mixed with 180 kilograms of talcum powder, the granular disintegration that finally obtains is the polyary long acting organic compound fertilizer that the soybean machine sowing is used.
Example 25
Repeat the operation of example 16, wherein 20 kilograms in brown coal, with 36 kilograms in the bicarbonate of ammonia of its adapted, 3 kilograms of Dyhard RU 100s, 300 kilograms in urea, 150 kilograms of Secondary ammonium phosphates, 5 kilograms in Repone K, 5 kilograms in zinc sulfate, the mixture that obtains mixes with 73.9 kilograms of talcum powder, and the granular disintegration that finally obtains is the polyary long acting organic compound fertilizer that the winter wheat machine sowing is used.
Example 26
Repeat the operation of example 16, wherein 50 kilograms in brown coal, with 9 kilograms in the bicarbonate of ammonia of its adapted, 7 kilograms of Dyhard RU 100s, 402 kilograms in urea, 196 kilograms of Secondary ammonium phosphates, 100 kilograms in Repone K, 5 kilograms in zinc sulfate, the mixture that obtains mixes with 129.2 kilograms of talcum powder, and the granular disintegration that finally obtains is the polyary long acting organic compound fertilizer that the winter wheat machine sowing is used.
Example 27
Repeat the operation of example 16, wherein 80 kilograms in brown coal, with 144 kilograms in the bicarbonate of ammonia of its adapted, 10 kilograms of Dyhard RU 100s, 500 kilograms in urea, 250 kilograms of Secondary ammonium phosphates, 250 kilograms in Repone K, 20 kilograms in zinc sulfate, the mixture that obtains mixes with 207 kilograms of talcum powder, and the granular disintegration that finally obtains is the polyary long acting organic compound fertilizer that the winter wheat machine sowing is used.
Example 28
Repeat the operation of example 16, wherein 20 kilograms in brown coal, with 3.6 kilograms in the bicarbonate of ammonia of its adapted, 3 kilograms of Dyhard RU 100s, 80 kilograms in urea, 80 kilograms of Secondary ammonium phosphates, 50 kilograms in Repone K, 50 kilograms in zinc sulfate, 170 kilograms of calcium superphosphate, 150 kilograms of ammonium chlorides, 2 kilograms of Butachlor technical 92s, 1 kilogram of molinate, the mixture that obtains mixes with 78.5 kilograms of talcum powder, and the granular disintegration that finally obtains is the polyary long acting organic compound fertilizer that the paddy rice machine sowing is used.
Example 29
Repeat the operation of example 16, wherein 40 kilograms in brown coal, with 7.2 kilograms in the bicarbonate of ammonia of its adapted, 4.5 kilograms of Dyhard RU 100s, urea 120 kg, 130 kilograms of Secondary ammonium phosphates, 84 kilograms in Repone K, 10 kilograms in zinc sulfate, 250 kilograms of calcium superphosphate, 20 kilograms of ammonium chlorides, 4 kilograms of Butachlor technical 92s, 3 kilograms of molinates, the mixture that obtains mixes with 135.3 kilograms of talcum powder, and the granular disintegration that finally obtains is the polyary long acting organic compound fertilizer that the paddy rice machine sowing is used.
Example 30
Repeat the operation of example 16, wherein 60 kilograms in brown coal, with 10.8 kilograms in the bicarbonate of ammonia of its adapted, 6.0 kilograms of Dyhard RU 100s, 200 kilograms in urea, 200 kilograms of Secondary ammonium phosphates, Repone K 120 kg, 20 kilograms in zinc sulfate, 30 kilograms of calcium superphosphate, 30 kilograms of ammonium chlorides, 6 kilograms of Butachlor technical 92s, 5 kilograms of molinates, the mixture that obtains mixes with 219 kilograms of talcum powder, and the granular disintegration that finally obtains is the polyary long acting organic compound fertilizer that the paddy rice machine sowing is used.
Following table is the result that big pool, Pulandian City, Liaoning Province agrotechnical station compares the corn fertilizer of product of the present invention and the production of other factory test:
Project is handled Plant height (cm) Spike length (cm) Fringe thick (cm) Per mu yield (kilogram) Mu increases (kilogram) Gaining rate (%) Precedence Drop into (unit) The output value (unit) Income (unit) Increase income (unit)
Corn of the present invention polyary long acting organic compound fertilizer 50kg ?276 ?21.0 ?5.7 ?542.6 ?127.7 ?30.8 ????1 ?90.0 ?651.1 ?561.1 ?132.7
The fertile 35kg of Dalian morning twilight corn ?271 ?20.0 ?5.8 ?475.2 ?60.3 ?14.5 ????3 ?66.5 ?570.2 ?503.7 ?75.3
The fertile 50kg of Dalian sweet spring water corn ?274 ?17.0 ?4.9 ?329.8 ?-85.1 -20.5 ????6 ?65.0 ?395.7 ?330.7 ?-97.7
The fertile 50kg of Jinzhou black earth corn ?273 ?20.0 ?5.7 ?517.8 ?102.9 ?24.8 ????2 ?90.0 ?621.4 ?531.4 ?103.0
The fertile 50kg of Wa Shi chemical plant corn ?263 ?18.1 ?5.4 ?457.5 ?42.6 ?10.3 ????4 ?75.0 ?549.0 ?474.0 ?45.6
Contrast (Secondary ammonium phosphate 5kg urea 30kg) ?271 ?20.0 ?5.4 ?414.9 ?0 ?0 ????5 ?69.5 ?497.9 ?428.4 ?0

Claims (13)

1, a kind of polyary long acting organic compound fertilizer, it is to be added with Dyhard RU 100 in simple substance fertilizer that contains nitrogen, phosphorus, potassium and composite fertilizer, it is characterized in that:
A, total nitrogen: total phosphorus content: general potassium amount=6.64~37.6: 4.7~14.96: 2.8~16,
B, Dyhard RU 100 consumption are 1~4.3% of pure nitrogen levels.
2, the preparation method of above-mentioned polyary long acting organic compound fertilizer is characterized in that:
1. brown coal were pulverized 80 mesh sieves, and in brown coal, added bicarbonate of ammonia, and their weight ratio is a bicarbonate of ammonia: brown coal=18: 100, the back that stirs is placed about two weeks and is got the A component in the physical environment of temperature more than 15 ℃,
2. A component and Dyhard RU 100 uniform mixing are got the B component,
3. B component and bicarbonate of ammonia or urea uniform mixing are got the C component,
4. phosphate fertilizer, potash fertilizer, little fertilizer and other composition and the C component with remainder mixes, and stirs promptly to obtain mixing powder type product of the present invention.
3, the preparation method of polyary long acting organic compound fertilizer according to claim 2 is characterized in that: preparation particulate state product of the present invention also needs
1. each feed particulate material is pulverized, is crossed 80 mesh sieves,
2. add in the tablets press after the mixture of each raw material that will obtain and talcum powder and the mixes with small amount of water, wherein mixture and talcous weight ratio are as follows: each raw mix: talcum powder=100: 14~18.
4, polyary long acting organic compound fertilizer according to claim 1 is characterized in that: corn is as follows with the composition weight ratio of mixing powder type composite fertilizer: 5.0~25 parts in urea, 16~28 parts of Secondary ammonium phosphates, 3.5~11.5 parts of calcium superphosphate, 1.5~7.0 parts of ammonium chlorides, 25~50 parts in bicarbonate of ammonia, 1.5~7.0 parts in ammonium sulfate, 5.0~13 parts in Repone K, 0.15~0.4 part of Dyhard RU 100,0.5~2.0 part in zinc sulfate, 2.0~4.0 parts in brown coal.
5, polyary long acting organic compound fertilizer according to claim 1 is characterized in that: corn is as follows with the composition weight ratio of granular compound fertilizer: 30~45 parts in urea, 15~30 parts of Secondary ammonium phosphates, 5.0~12 parts in Repone K, Dyhard RU 100 0.3~1.0,0.5~2.0 part in zinc sulfate, brown coal 2.0~4.0.
6, polyary long acting organic compound fertilizer according to claim 1 is characterized in that: corn is as follows with the composition weight ratio of granular compound fertilizer: 2~6 parts in 30~70 parts in urea, 15~30 parts of Secondary ammonium phosphates, 5~12 parts in Repone K, 0.5~1.5 part of Dyhard RU 100, zinc sulfate 0.5~2.0, brown coal.
7, polyary long acting organic compound fertilizer according to claim 1 is characterized in that: paddy rice is as follows with the composition weight ratio of particulate state type composite fertilizer: 8~20 parts in urea, 8~20 parts of Secondary ammonium phosphates, 17~30 parts of calcium superphosphate, 15~30 parts of ammonium chlorides, 5~12 parts in Repone K, 0.3~0.6 part of Dyhard RU 100,0.5~2.0 part in zinc sulfate, 2~6 parts in brown coal, 0.2~0.6 part of Butachlor technical 92,0.1~0.5 part of molinate.
8, polyary long acting organic compound fertilizer according to claim 1 is characterized in that: soybean is as follows with the composition weight ratio of granular compound fertilizer: 28~38 parts in urea, 12~25 parts of Secondary ammonium phosphates, 12~20 parts in Repone K, 0.3~0.8 part of Dyhard RU 100,1~6 part in brown coal.
9, polyary long acting organic compound fertilizer according to claim 1 is characterized in that: grape or peach are as follows with the composition weight ratio of mixing powder type composite fertilizer: 10~20 parts in urea, 5~15 parts of Secondary ammonium phosphates, 20~30 parts of calcium superphosphate, 5~15 parts in bicarbonate of ammonia, 2~10 parts in ammonium sulfate, 2~10 parts in Repone K, 0.2~0.6 part of two cyanogen ammonium, 2~6 parts in brown coal, 2~5 parts in zeolite, 2~5 parts of magnesium salts, 15~20 parts of vitriolate of tartar.
10, polyary long acting organic compound fertilizer according to claim 1 is characterized in that: apple tree is as follows with the composition weight ratio of mixing powder type composite fertilizer: 5~12 parts in urea, 15~26 parts of Secondary ammonium phosphates, 17~25 parts of ammonium chlorides, 3~6 parts of ammonium chlorides, 2~6 parts in bicarbonate of ammonia, 20~35 parts in ammonium sulfate, 3~7 parts in Repone K, 0.1~0.5 part of Dyhard RU 100,0.3~0.7 part in zinc sulfate, 2~6 parts in brown coal, 0.4~0.8 part of borax, 4~8 parts of vitriolate of tartar, 0.1~0.5 part in ferrous sulfate.
11, polyary long acting organic compound fertilizer according to claim 1 is characterized in that: spring wheat is as follows with the composition weight ratio of mixing powder type composite fertilizer: 16~36 parts in urea, 10~26 parts of Secondary ammonium phosphates, 5~14 parts of calcium superphosphate, 2~5 parts of ammonium chlorides, 25~40 parts in bicarbonate of ammonia, 2~6 parts in ammonium sulfate, 7~13 parts in Repone K, 0.4~0.9 part of Dyhard RU 100,0.5~2.0 part in zinc sulfate, 1~4 part in brown coal.
12, polyary long acting organic compound fertilizer according to claim 1 is characterized in that: winter wheat is as follows with the composition weight ratio of granular compound fertilizer: 30~50 parts in urea, 15~25 parts of Secondary ammonium phosphates, 5~25 parts in Repone K, 0.3~1.0 part of Dyhard RU 100,0.5~2.0 part in zinc sulfate, 2~8 parts in brown coal.
13, polyary long acting organic compound fertilizer according to claim 1 is characterized in that: vegetables are as follows with the composition weight ratio of mixing powder type composite fertilizer: 5~16 parts in urea, 8~17 parts of Secondary ammonium phosphates, 10~20 parts of calcium superphosphate, 10~20 parts in bicarbonate of ammonia, 6~18 parts in ammonium sulfate, 3~8 parts in Repone K, 0.23~0.76 part of Dyhard RU 100,0.6~2.0 part in zinc sulfate, 5~15 parts in brown coal, 2~5 parts of vitriolate of tartar.
CN 99113036 1999-06-18 1999-06-18 Multi-element long-acting organic compound fertilizer and preparation method thereof Pending CN1235944A (en)

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CN100381404C (en) * 2004-12-24 2008-04-16 中国科学院沈阳应用生态研究所 Dedicated fertilizer for soybean and application
CN102557791A (en) * 2010-12-22 2012-07-11 施可丰化工股份有限公司 Special fertilizer for maize grown in black soil in cold area and application thereof
CN102674971A (en) * 2012-05-28 2012-09-19 昆明学院 Field crop base fertilizer
CN102875220A (en) * 2012-09-11 2013-01-16 中国科学院沈阳应用生态研究所 Special formula fertilizer for northern mowing grasslands and use method of special formula fertilizer
CN103058751A (en) * 2012-12-26 2013-04-24 施可丰化工股份有限公司 Preparation method for special slow-release long-acting compound fertilizer for corn
CN103058757A (en) * 2012-12-26 2013-04-24 施可丰化工股份有限公司 Preparation method for special slow-release long-acting compound fertilizer for vegetable
CN103058761A (en) * 2012-12-26 2013-04-24 施可丰化工股份有限公司 Slow release compound fertilizer applicable to plantation of wheat
CN103058752A (en) * 2012-12-26 2013-04-24 施可丰化工股份有限公司 Preparation method for special slow-release long-acting compound fertilizer for paddy rice
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CN103058754A (en) * 2012-12-26 2013-04-24 施可丰化工股份有限公司 Slow-release compound fertilizer applicable to plantation of corn
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WO2016166010A1 (en) * 2015-04-14 2016-10-20 Tischmacher Heinz Fertilizer containing ammonium hydrogen carbonate
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CN100381404C (en) * 2004-12-24 2008-04-16 中国科学院沈阳应用生态研究所 Dedicated fertilizer for soybean and application
CN102557791A (en) * 2010-12-22 2012-07-11 施可丰化工股份有限公司 Special fertilizer for maize grown in black soil in cold area and application thereof
CN102674971A (en) * 2012-05-28 2012-09-19 昆明学院 Field crop base fertilizer
CN102875220A (en) * 2012-09-11 2013-01-16 中国科学院沈阳应用生态研究所 Special formula fertilizer for northern mowing grasslands and use method of special formula fertilizer
CN103058751A (en) * 2012-12-26 2013-04-24 施可丰化工股份有限公司 Preparation method for special slow-release long-acting compound fertilizer for corn
CN103058757A (en) * 2012-12-26 2013-04-24 施可丰化工股份有限公司 Preparation method for special slow-release long-acting compound fertilizer for vegetable
CN103058761A (en) * 2012-12-26 2013-04-24 施可丰化工股份有限公司 Slow release compound fertilizer applicable to plantation of wheat
CN103058752A (en) * 2012-12-26 2013-04-24 施可丰化工股份有限公司 Preparation method for special slow-release long-acting compound fertilizer for paddy rice
CN103058759A (en) * 2012-12-26 2013-04-24 施可丰化工股份有限公司 Slow release compound fertilizer applicable to plantation of paddy rice
CN103058754A (en) * 2012-12-26 2013-04-24 施可丰化工股份有限公司 Slow-release compound fertilizer applicable to plantation of corn
CN103058762A (en) * 2012-12-26 2013-04-24 施可丰化工股份有限公司 Slow-release compound fertilizer suitable for fruit tree planting
CN103351205A (en) * 2012-12-26 2013-10-16 施可丰化工股份有限公司 Preparation method of special controlled-release long-acting composite fertilizer for fruit trees
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CN103351205B (en) * 2012-12-26 2015-04-22 施可丰化工股份有限公司 Preparation method of special controlled-release long-acting composite fertilizer for fruit trees
CN103058754B (en) * 2012-12-26 2015-04-22 施可丰化工股份有限公司 Slow-release compound fertilizer applicable to plantation of corn
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WO2016166010A1 (en) * 2015-04-14 2016-10-20 Tischmacher Heinz Fertilizer containing ammonium hydrogen carbonate
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CN109553483A (en) * 2019-01-18 2019-04-02 北京市土肥工作站 Sweet potato special-purpose control-release fertilizer
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