CN1225975C - Dingminiao and abamectin containing insecticide and acaricide composition - Google Patents
Dingminiao and abamectin containing insecticide and acaricide composition Download PDFInfo
- Publication number
- CN1225975C CN1225975C CN 200410002174 CN200410002174A CN1225975C CN 1225975 C CN1225975 C CN 1225975C CN 200410002174 CN200410002174 CN 200410002174 CN 200410002174 A CN200410002174 A CN 200410002174A CN 1225975 C CN1225975 C CN 1225975C
- Authority
- CN
- China
- Prior art keywords
- avermectin
- butyl ether
- ether urea
- abamectin
- urea
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000005660 Abamectin Substances 0.000 title claims abstract description 60
- 239000000203 mixture Substances 0.000 title claims abstract description 12
- IBSREHMXUMOFBB-JFUDTMANSA-N 5u8924t11h Chemical compound O1[C@@H](C)[C@H](O)[C@@H](OC)C[C@@H]1O[C@@H]1[C@@H](OC)C[C@H](O[C@@H]2C(=C/C[C@@H]3C[C@@H](C[C@@]4(O3)C=C[C@H](C)[C@@H](C(C)C)O4)OC(=O)[C@@H]3C=C(C)[C@@H](O)[C@H]4OC\C([C@@]34O)=C/C=C/[C@@H]2C)/C)O[C@H]1C.C1=C[C@H](C)[C@@H]([C@@H](C)CC)O[C@]11O[C@H](C\C=C(C)\[C@@H](O[C@@H]2O[C@@H](C)[C@H](O[C@@H]3O[C@@H](C)[C@H](O)[C@@H](OC)C3)[C@@H](OC)C2)[C@@H](C)\C=C\C=C/2[C@]3([C@H](C(=O)O4)C=C(C)[C@@H](O)[C@H]3OC\2)O)C[C@H]4C1 IBSREHMXUMOFBB-JFUDTMANSA-N 0.000 title abstract description 9
- 229950008167 abamectin Drugs 0.000 title abstract description 9
- 230000000895 acaricidal effect Effects 0.000 title description 4
- 239000002917 insecticide Substances 0.000 title description 2
- 239000000642 acaricide Substances 0.000 title 1
- 239000000575 pesticide Substances 0.000 claims abstract description 5
- RRZXIRBKKLTSOM-XPNPUAGNSA-N avermectin B1a Chemical compound C1=C[C@H](C)[C@@H]([C@@H](C)CC)O[C@]11O[C@H](C\C=C(C)\[C@@H](O[C@@H]2O[C@@H](C)[C@H](O[C@@H]3O[C@@H](C)[C@H](O)[C@@H](OC)C3)[C@@H](OC)C2)[C@@H](C)\C=C\C=C/2[C@]3([C@H](C(=O)O4)C=C(C)[C@@H](O)[C@H]3OC\2)O)C[C@H]4C1 RRZXIRBKKLTSOM-XPNPUAGNSA-N 0.000 claims description 52
- KDGQGEKLPWYCGO-UHFFFAOYSA-N 1-butoxybutane;urea Chemical compound NC(N)=O.CCCCOCCCC KDGQGEKLPWYCGO-UHFFFAOYSA-N 0.000 claims description 49
- 239000004480 active ingredient Substances 0.000 claims description 3
- ZFUKERYTFURFGA-UHFFFAOYSA-N Avermectin B1b Natural products O1C(C)C(O)C(OC)CC1OC1C(OC)CC(OC2C(=CCC3CC(CC4(O3)C=CC(C)C(C(C)C)O4)OC(=O)C3C=C(C)C(O)C4OCC(C34O)=CC=CC2C)C)OC1C ZFUKERYTFURFGA-UHFFFAOYSA-N 0.000 claims description 2
- RRZXIRBKKLTSOM-UHFFFAOYSA-N avermectin B1a Natural products C1=CC(C)C(C(C)CC)OC11OC(CC=C(C)C(OC2OC(C)C(OC3OC(C)C(O)C(OC)C3)C(OC)C2)C(C)C=CC=C2C3(C(C(=O)O4)C=C(C)C(O)C3OC2)O)CC4C1 RRZXIRBKKLTSOM-UHFFFAOYSA-N 0.000 claims description 2
- ZFUKERYTFURFGA-PVVXTEPVSA-N avermectin B1b Chemical compound O1[C@@H](C)[C@H](O)[C@@H](OC)C[C@@H]1O[C@@H]1[C@@H](OC)C[C@H](O[C@@H]2C(=C/C[C@@H]3C[C@@H](C[C@@]4(O3)C=C[C@H](C)[C@@H](C(C)C)O4)OC(=O)[C@@H]3C=C(C)[C@@H](O)[C@H]4OC\C([C@@]34O)=C/C=C/[C@@H]2C)/C)O[C@H]1C ZFUKERYTFURFGA-PVVXTEPVSA-N 0.000 claims description 2
- 238000009825 accumulation Methods 0.000 claims 1
- 239000000843 powder Substances 0.000 claims 1
- 239000000375 suspending agent Substances 0.000 claims 1
- 238000009736 wetting Methods 0.000 claims 1
- 241000607479 Yersinia pestis Species 0.000 abstract description 3
- 241000238876 Acari Species 0.000 abstract 3
- 241000500441 Plutellidae Species 0.000 abstract 1
- WOWBFOBYOAGEEA-UHFFFAOYSA-N diafenthiuron Chemical compound CC(C)C1=C(NC(=S)NC(C)(C)C)C(C(C)C)=CC(OC=2C=CC=CC=2)=C1 WOWBFOBYOAGEEA-UHFFFAOYSA-N 0.000 abstract 1
- NYPJDWWKZLNGGM-UHFFFAOYSA-N fenvalerate Chemical compound C=1C=C(Cl)C=CC=1C(C(C)C)C(=O)OC(C#N)C(C=1)=CC=CC=1OC1=CC=CC=C1 NYPJDWWKZLNGGM-UHFFFAOYSA-N 0.000 description 15
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Natural products NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 14
- 239000004202 carbamide Substances 0.000 description 13
- 239000003814 drug Substances 0.000 description 13
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 13
- 239000002131 composite material Substances 0.000 description 12
- 239000007921 spray Substances 0.000 description 12
- 241000500437 Plutella xylostella Species 0.000 description 11
- 241000238631 Hexapoda Species 0.000 description 10
- 241001454293 Tetranychus urticae Species 0.000 description 10
- 241000344246 Tetranychus cinnabarinus Species 0.000 description 9
- 230000002195 synergetic effect Effects 0.000 description 9
- 238000000034 method Methods 0.000 description 8
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 7
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 6
- 239000003995 emulsifying agent Substances 0.000 description 6
- 238000012545 processing Methods 0.000 description 6
- 125000002914 sec-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 6
- 230000035945 sensitivity Effects 0.000 description 6
- 238000005507 spraying Methods 0.000 description 6
- 238000011160 research Methods 0.000 description 5
- 230000000694 effects Effects 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- 239000003905 agrochemical Substances 0.000 description 3
- 230000008485 antagonism Effects 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 238000010790 dilution Methods 0.000 description 3
- 239000012895 dilution Substances 0.000 description 3
- 239000004495 emulsifiable concentrate Substances 0.000 description 3
- 238000005286 illumination Methods 0.000 description 3
- 230000000749 insecticidal effect Effects 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 230000007774 longterm Effects 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 230000003449 preventive effect Effects 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 230000004083 survival effect Effects 0.000 description 3
- 231100000820 toxicity test Toxicity 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- 238000009395 breeding Methods 0.000 description 2
- 230000001488 breeding effect Effects 0.000 description 2
- 239000003153 chemical reaction reagent Substances 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 238000007619 statistical method Methods 0.000 description 2
- UMGDCJDMYOKAJW-UHFFFAOYSA-N thiourea Chemical compound NC(N)=S UMGDCJDMYOKAJW-UHFFFAOYSA-N 0.000 description 2
- 241001124076 Aphididae Species 0.000 description 1
- 240000007124 Brassica oleracea Species 0.000 description 1
- 235000003899 Brassica oleracea var acephala Nutrition 0.000 description 1
- 235000011301 Brassica oleracea var capitata Nutrition 0.000 description 1
- 235000001169 Brassica oleracea var oleracea Nutrition 0.000 description 1
- 235000010149 Brassica rapa subsp chinensis Nutrition 0.000 description 1
- 235000000536 Brassica rapa subsp pekinensis Nutrition 0.000 description 1
- 241000499436 Brassica rapa subsp. pekinensis Species 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- 241000594033 Liriomyza bryoniae Species 0.000 description 1
- 239000005916 Methomyl Substances 0.000 description 1
- 206010034133 Pathogen resistance Diseases 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 241000255969 Pieris brassicae Species 0.000 description 1
- 241000985245 Spodoptera litura Species 0.000 description 1
- 235000010724 Wisteria floribunda Nutrition 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 238000012271 agricultural production Methods 0.000 description 1
- 150000004657 carbamic acid derivatives Chemical class 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 231100000636 lethal dose Toxicity 0.000 description 1
- 239000003120 macrolide antibiotic agent Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- UHXUZOCRWCRNSJ-QPJJXVBHSA-N methomyl Chemical compound CNC(=O)O\N=C(/C)SC UHXUZOCRWCRNSJ-QPJJXVBHSA-N 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- SNICXCGAKADSCV-UHFFFAOYSA-N nicotine Chemical compound CN1CCCC1C1=CC=CN=C1 SNICXCGAKADSCV-UHFFFAOYSA-N 0.000 description 1
- ATROHALUCMTWTB-OWBHPGMISA-N phoxim Chemical compound CCOP(=S)(OCC)O\N=C(\C#N)C1=CC=CC=C1 ATROHALUCMTWTB-OWBHPGMISA-N 0.000 description 1
- 229950001664 phoxim Drugs 0.000 description 1
- 235000021110 pickles Nutrition 0.000 description 1
- 239000002728 pyrethroid Substances 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- 230000001018 virulence Effects 0.000 description 1
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
Description
Handle | LC50(PPM) | Resistance index | Co-toxicity coefficient |
Butyl ether urea 10+ Avermectin 1 (S) | 3.5 | 94.7 | |
Butyl ether urea 15+ Avermectin 1 (S) | 4.9 | 91.9 | |
Butyl ether urea 20+ Avermectin 1 (S) | 5.4 | 103.1 | |
Butyl ether urea 25+ Avermectin 1 (S) | 7.2 | 91.1 | |
Butyl ether urea 30+ Avermectin 1 (S) | 6.9 | 108.2 | |
Butyl ether urea 10+ Avermectin 1 (R) | 6.7 | 365.0 | |
Butyl ether urea 15+ Avermectin 1 (R) | 7.5 | 334.3 | |
Butyl ether urea 20+ Avermectin 1 (R) | 6.9 | 368.4 | |
Butyl ether urea 25+ Avermectin 1 (R) | 9.0 | 285.1 | |
Butyl ether urea 30+ Avermectin 1 (R) | 9.2 | 279.3 | |
Avermectin (S) | 0.3 | ||
Butyl ether urea (S) | 25.3 | - | |
Avermectin (R) | 14.9 | 50 | |
Butyl ether urea (R) | 26.3 | - | |
Sumicidin (R) | 317.2 | 167 | |
Sumicidin (S) | 1.9 | ||
Butyl ether urea 0.25+ sumicidin 1 (R) | 94.8 | 104.1 | |
Butyl ether urea 0.5+ sumicidin 1 (R) | 56.3 | 120.2 | |
Butyl ether urea 1+ sumicidin 1 (R) | 47.5 | 102.1 | |
Butyl ether urea 1.5+ sumicidin 1 (R) | 35.8 | 115.9 | |
Butyl ether urea 2.0+ sumicidin 1 (R) | 30.6 | 123.6 | |
Butyl ether urea 0.25+ sumicidin 1 (S) | 2.1 | 110.8 | |
Butyl ether urea 0.5+ sumicidin 1 (S) | 2.6 | 102.8 | |
Butyl ether urea 1+ sumicidin 1 (S) | 3.0 | 117.9 | |
Butyl ether urea 1.5+ sumicidin 1 (S) | 4.0 | 105.4 | |
Butyl ether urea 2.0+ sumicidin 1 (S) | 4.3 | 113.9 |
Handle | LC50(PPM) | Resistance index | Co-toxicity coefficient |
Butyl ether urea 104+ Avermectin 1 (S) | 1.40 | 108.2 | |
Butyl ether urea 15+ Avermectin 1 (S) | 1.93 | 110.3 | |
Butyl ether urea 20+ Avermectin 1 (S) | 2.62 | 102.4 | |
Butyl ether urea 25+ Avermectin 1 (S) | 3.29 | 97.6 | |
Butyl ether urea 30+ Avermectin 1 (S) | 3.96 | 93.2 | |
Butyl ether urea 10+ Avermectin 1 (R) | 3.27 | 439.2 | |
Butyl ether urea 15+ Avermectin 1 (R) | 3.14 | 456.1 | |
Butyl ether urea 20+ Avermectin 1 (R) | 2.49 | 572.9 |
Butyl ether urea 25+ Avermectin 1 (R) | 3.70 | 385.3 | |
Butyl ether urea 30+ Avermectin 1 (R) | 3.58 | 397.8 | |
Avermectin (S) | 0.15 | ||
Butyl ether urea (S) | 17.4 | ||
Avermectin (R) | 16.3 | 108 | |
Butyl ether urea (R) | 14.2 | - |
Handle | LC50(PPM) | Resistance index | Co-toxicity coefficient |
Butyl ether urea 10+ Avermectin 1 (S) | 1.26 | 98.0 | |
Butyl ether urea 15+ Avermectin 1 (S) | 1.61 | 107.5 | |
Butyl ether urea 20+ Avermectin 1 (S) | 2.19 | 100.7 | |
Butyl ether urea 25+ Avermectin 1 (S) | 2.21 | 120.1 | |
Butyl ether urea 30+ Avermectin 1 (S) | 2.36 | 130.0 | |
Butyl ether urea 10+ Avermectin 1 (R) | 3.22 | 432.9 | |
Butyl ether urea 15+ Avermectin 1 (R) | 2.77 | 502.3 | |
Butyl ether urea 20+ Avermectin 1 (R) | 2.92 | 476.5 | |
Butyl ether urea 25+ Avermectin 1 (R) | 2.73 | 510.2 | |
Butyl ether urea 30+ Avermectin 1 (R) | 3.52 | 395.7 | |
Avermectin (S) | 0.12 | ||
Butyl ether urea (S) | 16.9 | ||
Avermectin (R) | 14.5 | 120 | |
Butyl ether urea (R) | 13.9 | - |
Claims (4)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN 200410002174 CN1225975C (en) | 2004-01-14 | 2004-01-14 | Dingminiao and abamectin containing insecticide and acaricide composition |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN 200410002174 CN1225975C (en) | 2004-01-14 | 2004-01-14 | Dingminiao and abamectin containing insecticide and acaricide composition |
Publications (2)
Publication Number | Publication Date |
---|---|
CN1557158A CN1557158A (en) | 2004-12-29 |
CN1225975C true CN1225975C (en) | 2005-11-09 |
Family
ID=34350685
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN 200410002174 Expired - Lifetime CN1225975C (en) | 2004-01-14 | 2004-01-14 | Dingminiao and abamectin containing insecticide and acaricide composition |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN1225975C (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN100355342C (en) * | 2006-08-18 | 2007-12-19 | 中国农业大学 | Pesticide composition |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101176465B (en) * | 2005-08-26 | 2010-06-02 | 沈阳化工研究院 | Composition of insect disinfestations and miticide |
CN100399900C (en) * | 2006-09-19 | 2008-07-09 | 东莞市农业科学研究中心 | Pesticide composition containing avermectin and butyl ether urea and its application |
CN101731251B (en) * | 2010-01-21 | 2013-11-06 | 广西田园生化股份有限公司 | Electrostatic oil agent of abamectin and diafenthiuron binary composition |
CN106879624A (en) * | 2017-04-10 | 2017-06-23 | 安徽省益农化工有限公司 | A kind of herbicide pesticide agent |
-
2004
- 2004-01-14 CN CN 200410002174 patent/CN1225975C/en not_active Expired - Lifetime
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN100355342C (en) * | 2006-08-18 | 2007-12-19 | 中国农业大学 | Pesticide composition |
Also Published As
Publication number | Publication date |
---|---|
CN1557158A (en) | 2004-12-29 |
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Legal Events
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C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
C56 | Change in the name or address of the patentee |
Owner name: SHENZHEN CITY NUOPUXIN AGRICULTURAL CHEMICALS CO., Free format text: FORMER NAME OR ADDRESS: NUOPUXIN AGRICULTURAL CHEMICAL CO LTD, SHENZHEN CITY |
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CP03 | Change of name, title or address |
Address after: 518102 No. 113 Reservoir Road, Baoan District, Guangdong, Shenzhen, Xixiang Patentee after: Shenzhen nuopuxin agrochemical Limited by Share Ltd. Address before: 518126 two layers, nine courtyards, West Town Forestry Institute, Shenzhen, Baoan District, Guangdong Patentee before: NUOPUXIN AGRICULTURAL CHEMICAL |
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C56 | Change in the name or address of the patentee |
Owner name: SHENZHEN NUOPUXIN AGRICULTURAL CO., LTD. Free format text: FORMER NAME OR ADDRESS: SHENZHEN CITY NUOPUXIN AGRICULTURAL CHEMICALS CO., LTD. |
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CP01 | Change in the name or title of a patent holder |
Address after: No. 113, Xixiang Reservoir Road, Shenzhen, Guangdong, Baoan District Patentee after: SHENZHEN NOPOSION AGROCHEMICALS Co.,Ltd. Address before: No. 113, Xixiang Reservoir Road, Shenzhen, Guangdong, Baoan District Patentee before: Shenzhen nuopuxin agrochemical Limited by Share Ltd. |
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EE01 | Entry into force of recordation of patent licensing contract |
Assignee: SHAANXI BIOGEN CROP SCIENCE Co.,Ltd. Assignor: SHENZHEN NOPOSION AGROCHEMICALS Co.,Ltd. Contract fulfillment period: 2007.9.20 to 2021.7.10 Contract record no.: 2009610000042 Denomination of invention: Dingminiao and abamectin containing insecticide and acaricide composition Granted publication date: 20051109 License type: Exclusive license Record date: 20091124 |
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LIC | Patent licence contract for exploitation submitted for record |
Free format text: EXCLUSIVE LICENSE; TIME LIMIT OF IMPLEMENTING CONTACT: 2007.9.20 TO 2021.7.10; CHANGE OF CONTRACT Name of requester: SHANXI BIAOZHENG CROP SCIENCE CO., LTD. Effective date: 20091124 |
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