CN1222568A - Detergent composition - Google Patents

Abstract

An aqueous cleansing and oily soil removing composition comprising a surface active agent and an agent for removing oily soil from skin, in which the surface active agent and agent for removing oily soil are separate but combinedly dispensable from a single packaging means as discrete domains, preferably in a predetermined ratio. Separating the agent for removing oily soil from the surface active agent results in improved removal of oily soil from skin, and a clean, fresh feel which is appreciated by the consumer.

Description

Detergent composition

The present invention relates to detergent composition, this detergent composition is applicable to topical application, to clean and to remove the grease of human body, particularly is applicable to the makeup of removing on skin, lip, hair and the nail.More particularly, the present invention relates to such composition, promptly Pei Zhi said composition is to be used for effectively removing makeup, makes skin that pure and fresh sensation is arranged simultaneously, and these benefits are relevant with the clean-out system of foaming usually.

It is well-known being used for removing makeup institute composition prepared from skin.A large amount of solvents is contained in general they, greasepaint for example, and they can effectively permeate and disperse the wax of formation makeup dirt and the oil reservoir of granules of pigments.Can design such makeup detergent compositions and for example can wipe with cotton cleaning brush, maybe can design water and wash, under these circumstances, they also can contain tensio-active agent, so that common emulsification cosmetic base-material and solvent oil.

But, it is found that usually Pei Zhi the emulsion makeup washing agent that resembles oil or water/oil or oil/water type is stayed like this oily sensation on the skin.They in the process of rinsing also often be non-foaming or the end of bubble seldom is provided.What the human consumer liked mainly is the sensation that pure and fresh skin is arranged after cleaning.Particularly when thick makeup have been used up,, just usually need following dual cleaning way in order to reach such result.

Conventional foaming clean-out system for example soap slab, cleansing milk, bathing agents, shampoo and shower gels is well-known, and they produce a large amount of bubble ends with the water blended time, remove light dirt (for example sebum) from skin surface, make skin that pure and fresh sensation be arranged.But such product often remove weight resemble makeup dirty aspect effect be on duty mutually.

In recent years, a kind of novel " 2 close 1 " sanitising agent occurred, the advantage of the product that it is claimed is effectively to remove makeup, has easy rinsing performance and goes to steep performance, and making usually has the skin feel relevant with foamed cleanser.It is the consequence of having taken all factors into consideration the preparation for preparing them that these products are not significantly won the market.Therefore, known foaming preparation deutero-" 2 the close 1 " sanitising agent of washing one's face by routine can not be removed makeup fully, can not be obtained the advantage of the sensation aspect relevant with complete pure and fresh skin simultaneously by makeup washing agent preparation deutero-" 2 the close 1 " sanitising agent of routine.

People also know " 2 close 1 " product of the advantage that the cleaning and the aspect that moisturizes are provided of the other type of preparation.For example WO96/02230 discloses a kind of composition that contains tensio-active agent and favourable composition (benefit agengt), wherein tensio-active agent and favourable composition separate, but can be with single packaging facilities with the predetermined combined dispersion of ratio to separate.It is said that favourable composition and tensio-active agent separate the feasible deposition of improving favourable composition.But WO96/02230 relates to a kind of electrodeposition substance on skin, and the present invention is opposite, reach from skin remove this material effect.

One of problem that generally may run into so double-acting composition is that they contain the washing agent component in shortage or the effective quantity not sufficient of active ingredient in use.

With such double-acting cleaning with to moisturize or remove another relevant problem of the composition of dirt be unstable.According to WO94/03152, it relates to the shower gels that contains nonsoap detergent, silicone oil and cationic polymers, if keep the stability of product, the size of the average droplet of the maximum of operable silicone oil is 2 microns.

We have found that a kind of such method for compositions of preparing, effectively removed grease, the advantage of the sensation aspect relevant with foamed cleanser still is provided simultaneously to such an extent as to they can reach.

In addition, we have found that dual clean and remove the stability of product of dirt and the conveying of remover and validity can by a kind of wherein cleaning component is provided and remove component be separately but used pack equipment improve with the combined dispersive composition that separates.

Therefore, according to a first aspect of the invention, provide the liquid composition of a kind of cleaning and removal grease, said composition comprises:

A) a kind of contain one or more tensio-active agents that are selected from negatively charged ion, nonionic, amphoteric, zwitter-ion and cats product, soap and their mixture contain water (domain); With

B) a kind of moisture or water-free phase that contains one or more reagent of removing grease, said moisture or water-free be with emulsive state not mutually;

Wherein, the size of these phases is greater than 1000 microns, and separates, but the combined dispersion of available single packaging facilities to separate.

Said composition is applicable to cleans skin fully.For example remove makeup in order to remove grease, in said composition, comprise washing agent from skin.

The present invention also provides a kind of and improves the method that gets on and remove grease from skin by the composition that uses above-mentioned cleaning and removal grease, and this method comprises:

ⅰ) by packaging facilities scatter table surface-active agent and the reagent of removing grease;

ⅱ) reagent of tensio-active agent and removal grease is used on the human body; With

ⅲ) by remove grease and the sanitising agent in the mixture that forms with water rinse.

In another embodiment, the present invention also provides a kind of cleaning compositions of packing of topical application.Be used in the preferably multistage comparting packaging of suitable packing of this embodiment of the present invention, for example the two-stage comparting packaging.

An advantage of the invention is the feasible performance of removing grease of improving of aqueous liquid composition that contains tensio-active agent by use.In said composition, tensio-active agent and washing agent separate, even can directly not contact each other in said composition.This latter event has been avoided between two kinds of components disadvantageous interaction taking place, and this disadvantageous interaction may cause the invalid effect of washing agent.

Do not want to be subjected to the restriction of theoretical side, it is believed that this washing agent is dispersed into bigger drop in the process of said composition use friction, these drops are easy to get on to remove grease from skin, for example makeup.By washing agent separately and moisture foaming surfactant mutually, contain at the former under the situation of component of water immiscibility, it does not need to use emulsifying technology to prepare this initial composition.Think in the process of the use of said composition friction, to form on the spot that the promoted bigger drop of dispersion institute by removing phase as the grease of single phase is more effective than smaller emulsion droplet in the removal grease.Remove makeup by this effective agents being transported to impel on the makeup film that is in high density.Then, because the rubbing effect in the process of using, this bigger drop in use volume just reduces, therefore, impel aqueous surfactant that they are dissolved in composition as disperse phase mutually in.

The invention provides the other advantage that does not need to relate to effectiveness, but also relate to the unstable of avoiding preparation and bring the human consumer problem of other benefit, it comprises:

(a) uncompatibility of formulation component, it may cause unstable and separate in the process that stores, and becomes different phases by cutting apart these components, can avoid the uncompatibility of formulation component; For example when high-load the polyoxyethylene glycol preferably component of washing agent the time, the removal grease by all or most polyoxyethylene glycol being formulated into other mutually in can avoid being separated of aqueous surfactant;

(b) can use two kinds of structural systems that best product viscosity, human consumer's sensation and outward appearance are provided mutually for each, these two kinds of structural systems adapt to the needs of every kind of phase more closely;

(c) can use two kinds of protective systems that best stability is provided mutually for each, use these two kinds of protective systems to adapt to the needs of every kind of phase more closely;

(d) similarly, can use two kinds of dyes/pigments systems to give the human consumer benefit mutually for each, for example, strengthen such notion, promptly this product is effectively and is real 2 to close 1 product;

(e) can react when obtaining the appreciable sensation of a kind of human consumer and for example producing the change of heat, viscosity or outward appearance aspect when formulation component, formulation component can remain on separately up to use;

(f) the light activated material of any UV can only remain in the cell with UV filtration capacity, makes thus to filter and package cost saving aspect the quality at such UV; With

(g) use multicell packing rather than single chamber packing can reduce the path length of light, therefore improved apparent transparency by product.

The tensio-active agent that contains aqueous phase that is included in the said composition can be selected from the tensio-active agent that any known part is used for human body.Flexible tensio-active agent does not promptly damage the stratum corneum of skin, outer field tensio-active agent is particularly preferred.

The fatty acyl group isethionate that a kind of preferred anionic surfactants clean-out system is a following formula:

RCO ₂CH ₂CH ₂SO ₃M

Wherein R is the alkyl or alkenyl of 7-21 carbon atom, and M is soluble positively charged ion, for example the ammonium of sodium, potassium, ammonium or replacement.Preferably at least 3/4 RCO group has 12-18 carbon atom, and can obtain from the mixture of coconut, palm or coconut/palm.

Another kind of preferred anionic surfactants clean-out system is the sulfated alkyl ether of following formula:

RO(CH ₂CH ₂O) _nSO ₃M

Wherein R is the alkyl of 8-22 carbon atom, and n is 0.5-10,1.5-8 particularly, and M is a soluble positively charged ion as previously described.

Other can with the negatively charged ion clean-out system comprise the phosphoric acid salt of alkyl glycerol base ether sulfate, sulfosuccinate, taurate, sarcosinate, sulfosalicylic acetate, phosphoric acid salt, phosphoric acid ester and ethoxylation; Acyl-lactate, glycinate, L-Ala salt and glutaminate; With their mixture.

Sulfosuccinate can be that to have formula be R ⁵O ₂CCH ₂CH (SO ₃M) CO ₂The monoalkyl sulfosuccinate of M; Formula is R ⁵CONHCH ₂CH ₂O ₂CCH ₂CH (SO ₃M) CO ₂The amide group of M-MEA sulfosuccinate; R wherein ⁵Be C ₈-C ₂₀Alkyl, preferred C ₁₂-C ₁₅Alkyl M is soluble positively charged ion.

Sarcosinate general by formula R ⁵CON (CH ₃) CH ₂CO ₂M represents, wherein R ⁵Be C ₈-C ₂₀Alkyl, preferred C ₁₂-C ₁₅Alkyl M is soluble positively charged ion.

Taurate general by formula R ⁵CONR ⁶CH ₂CH ₂SO ₃M represents, wherein R ⁵Be C ₈-C ₂₀Alkyl, preferred C ₁₂-C ₁₅Alkyl, R ⁶Be C ₁-C ₄Alkyl, M are soluble positively charged ions.

Amino acid surfactant comprises acyl group L-Ala salt, acylglycine salt and the acyl glutamate of being represented by following formula, L-Ala salt; Wherein R is the alkyl or the alkenyl of 7-21 carbon atom, and M is soluble positively charged ion, for example the ammonium of sodium, potassium, ammonium or replacement.Acyl group L-Ala salt can be by spreading out property of L L-Ala:

Or derive by beta Alanine:

Glycinate:

Wherein R is the alkyl or the alkenyl of 7-21 carbon atom, and M is soluble positively charged ion, for example the ammonium of sodium, potassium, ammonium or replacement.Glutaminate Wherein R is the alkyl or the alkenyl of 7-21 carbon atom, and M is soluble positively charged ion, for example the ammonium of sodium, potassium, ammonium or replacement.

Uneven surface promoting agent for example uncle's alkane sulfonate or alkylbenzene sulfonate generally will be avoided using.

If tensio-active agent comprises soap, this soap is preferably by having C ₈-C ₂₂Basically the saturated carbon chains deutero-preferably has C ₁₂-C ₁₈The potash soap of carbochain or trolamine soap.

Suitable ionic surfactant pack is drawn together alkyl polysaccharide, lactic acid acid amides, glycol ester, glycerol monoethers, polyhydroxy amides (glucamide), primary and secondary alcohol ethoxylate, and particularly every mol of alcohol on average has the C of 1-20 moles of ethylene oxide ₈-C ₂₀Aliphatic alcohol ethoxylate.

Suitable amphoterics comprises the derivative of alkyl hydroxyethyl imidazoline, for example by formula:

With

Alkyl both sexes acetate, alkyl both sexes propionic salt, alkyl both sexes diacetin and the alkyl both sexes dipropionate of expression, wherein R is the alkyl or the alkenyl of 8-20 carbon atom, and n is 1 or 2, and M is soluble positively charged ion, for example the ammonium of sodium, potassium, ammonium or replacement.

Also can use above-mentioned surfactant mixtures arbitrarily.

The amount of the tensio-active agent that exists in total composition is 5-40 (weight) %, more preferably 10-25 (weight) % at least preferably.

Also preferably said composition comprises the cosurfactant of the advantage of auxiliary foaming of having of 1-10% (weight) or soft skin.Suitable material is to have the alkyl of 7-18 carbon atom or alkenyl and according to the zwitter-ion clean-out system of following total structural formula:

Wherein R1 is alkyl or the alkenyl with 7-18 carbon atom, and R2 and R3 independently are alkyl, hydroxyalkyl or the carboxyalkyl of 1-3 carbon atom separately; M is 2-4; N is 0 or 1; X is the alkylidene group of 1-3 carbon atom being replaced by hydroxyl arbitrarily; With y be-CO ₂ ^-Or-SO ₃ ^-

Zwitter-ion clean-out system with above-mentioned general formula comprises the simple trimethyl-glycine of following formula:

With the amido betaine with following formula:

Wherein m is 2 or 3.

In two formulas, R ¹, R ²And R ³As top definition.Specifically, R ¹Be C by coconut derived ₁₂-C ₁₄The mixture of alkyl, thus at least half, preferred at least 3/4 R ¹10-14 carbon atom arranged.R ²And R ³Methyl preferably.

Possible in addition is the sultaine with following formula:

Or

Wherein m is 2 or 3, or wherein-(CH ₂) ₃SO ₃By displaced those the mutation of following formula:

R in these formulas ¹, R ²And R ³As top definition.

The washing agent that uses in composition of the present invention can comprise straight or branched hydrocarbon (mineral oil for example, isohexadecane), ester (for example palmitinic acid isopropyl esters), siloxanes (for example cyclomethicone), natural or synthetic glycerine three acid esters (for example Viscotrol C, sunflower oil, macadamia nut oil, glyceryl three (2-ethylhexanoate)) and plant milk extract (for example hamamelis extract, Minor centaury extract).

But preferably this washing agent can comprise:

A) polymerized polyalcohol polyoxyethylene glycol (for example PEG 200-600) for example;

B) for example propylene glycol, glycerol and Sorbitol Powder of polyvalent alcohol;

C) size is greater than 10 microns the solid particulate matter for example polyethylene or the silica of micronization;

D) solvent ethanol for example;

E) nonionogenic tenside of HLB value＜10; With

F) their mixture.

Particularly preferred washing agent comprises BEG-400 and glycerol.

The phase that contains washing agent also can contain water, and its amount is 0-70%.It also can contain one or more hydrophilic tensio-active agents, comprises that hydrophilic tensio-active agent helps to form O/w emulsion in last rinse step, condition be such emulsion be not present in preparation mutually in.

In total composition, the preferred amount of washing agent is 1-70% (weight), most preferably 5-50% (weight).

Other component that can choose wantonly comprises structural agent or thickening material, can be added to mutually or in the two-phase of said composition to its door, so that keep stability in the process that stores, and provides suitable viscosity in disperseing and using.

The material of the moisture foaming surfactant phase of suitable formation comprises ionogen, and it can cause the change of the size or the geometrical shape of tensio-active agent micell; Water-soluble polymkeric substance surfactant-tolerant; With inorganic substance for example clay or amorphous silica.

Depend on that this is aqueous or water-free mutually, (for example it is oil or polynary alcohol radical) for the second preferential mutually thickening material of selecting that contains this washing agent.The thickening material that is suitable for moisture or polynary alcohol radical phase comprises hydrophilic polymer; Inorganics and their mixture.The thickening material that is suitable for the oil base phase comprises polymkeric substance, wax and the inorganics, particularly those of hydrophobically modified that oil is molten.

In addition, provide in the example of structural agent and the thickening material dictionary below: Internatinal CosmeticIngredient Dictionary, the 5th edition, 1993, CTFA publishes (The Cosmetic, Toiletry﹠Fragrance Association), and the document is classified reference as at this.

The typical component of other of such composition preferably can comprise opalizer, preferred 0.05-0.5% (weight); Sanitas, preferred 0.05-1.0% (weight); And spices, preferred 0.1-0.5% (weight).

About the physical appearance of composition of the present invention, essential characteristic of the present invention is that the deoil solution and the moisture foaming surfactant solution of dirt separates, but with packaging facilities dispersion capable of being combined.Usually the latter can be one packaging facilities.Such packaging facilities comprises the system that those comprise two or more other compartments of branch.Various such packaging facilities are known in the art, comprise twoly every pump decollator and two-tube, and they can be each other mutually by configuration or the configuration in the middle of another of compartment.Special example is included in U.S.P5, the multi-cavity dispersion cup of introducing in 020,694 and at U.S.P4, the multi-lumen tube of introducing in 964,539.

Preferred aqueous surfactant and washing agent all be can be from one packaging facilities dispersive, for example according to the ratios diverge of the composition that will use to be scheduled to.The benefit of disperseing this tensio-active agent and washing agent in said composition is that it is avoided and must mix the inconvenience of these two kinds of components in the back.The component of separating when composition need be mixed so that this is particularly advantageous when reaching needed effect with accurate ratio.

Though this individual packaging equipment can comprise two compartments under this preferred situation, wherein divide other that aqueous surfactant is housed and the dirty agent of deoiling, the compartment of greater number is fine, even it is contemplated that the compartment system of an integral body.

For example, in the compartment system of an integral body, the bar that separates that can think tensio-active agent and washing agent mutually that separates of the present composition, or think that a kind of reagent is suspended in the droplet in the another kind of reagent, optional is the form of microcapsule.

Guarantee tensio-active agent and washing agent be other method separately comprise with coextrusion or inject said composition separate be filled to mutually in the single chamber packing bag, like this, the droplet that produce to suspend or the product of strip, wherein each or droplet or contain tensio-active agent or contain washing agent.

Composition of the present invention can be formulated as the product of washed skin, the composition that for example washes one's face or wash one's hands; Bathing or shower gels; Or the product of hair washing.

What composition of the present invention was general is liquid or semiliquid, example gel or the paste that can topple over.

With reference now to following indefiniteness, embodiment carries out a step explanation to the present invention.Embodiment 1

Prepare two kinds of following preparations, constitute two phases of this cleaning combination:

(a) water phase surfactant mixture

(except as otherwise noted, raw material is 100% actives)

Chemical name	Trade(brand)name/supplier	wt％
			The KMAP/DAP+ accessory constituent	Prori B300D (29% activeconstituents+9% is a small amount of)/Kao	99.95
Dyes/pigments	Patent?Blau?V80/Hoechst	0.0001
			5-chloro-2-methyl-4-isothiazoline-3-ketone and 2-methyl-4-isothiazoline-3-ketone (1.5% aqueous solution)	Kathon CG/Rohm and Hass	0.05

Preparation: at first in Priori B-300D, add sanitas and mixing.Add dyes/pigments and mixing then.

(b) the dirty agent of deoiling

Chemical name	Trade(brand)name/supplier	wt％
			Monoisopropanolamine dodecyl sulphate (2EO)	Zetesol?856/Zschimmer＆Schwarz	16.00
Laureth-4	Brij?30/Sigma	6.00
			The coconut single ethanol amide	Empilan CME/A1bright and Wilson	5.50
Sedimentary silica	Sorbosil?TC15/Crosfield	12.OO
			Spices	Phoenix?3000?OPTFM/Givaudan	0.10
5-chloro-2-methyl-4-isothiazoline-3-ketone and 2-methyl-4-isothiazoline-3-ketone (1.5% solution)	Kathon CG/Rohm and Hass	0.05
			Titanium dioxide	Tiona?AG/SCM	2.00
Macadamia nut oil	Macadamia?Nut?Oil/Jan?Dekker	58.35

Preparation: at first Macadamia Nut Oil, Brij 30 and Zetesol 856 mixed and be heated to 80 ℃.Under vacuum, add Sorbosil TC15 and mixing.The Empilan CME of fritting is added from the top and be blended in wherein.Add titanium dioxide and mixing then.Perfuming and sanitas and be mixed into wherein after the cool to room temperature.

With packing in this embodiment is at U.S.P5, two compartment pumps dispersion types of introducing in 020,694, and the document is classified reference as at this.Such decollator comprises two chambeies and the parallel cylinder that separates, they generally have an end closure, the other end is scalable, and two parallel pistons of slide control, piston is along the inwall parallel sealing of said cylinder, so that wherein the product liquid that is contained flows to first end of said cylinder under the relative compression of cylinder and piston.This cylinder has the exit passageway that is communicated with outlet device, and outlet device has the exit opening that closes on, and makes this product liquid at exit opening mobile equipment each other, so that form the unmixed product logistics of single band shape.Water phase surfactant mixture is filled in the parallel chamber of decollator with the solution of the dirt that deoils, and makes in this decollator total composition contain washing agent solution and 50% (volume) water phase surfactant mixture of 50% (volume).Embodiment 2

(a) water phase surfactant mixture (except as otherwise noted, raw material is about 100% actives)

The chemistry name of an article	Trade(brand)name/supplier	Weight %
			Lauryl MAP/DAP (78/22)	Phosten?HLP/Nikkol	26.70
Trolamine	A-900/Shell	13.30
			Spices	Pheonix300 OPTFW/Givaudan?Roure	0.20
5-chloro-2-methyl-4-isothiazoline-3-ketone and 2-methyl-4-isothiazoline-3-ketone (1.5% aqueous solution)	Kathon?CG/Rohm＆Hass	0.05
			Water		59.75

Preparation: water and lauryl phosphoric acid are mixed, and be heated to 80 ℃.Neutralize this acid to pH 7.0 with trolamine.Behind the cool to room temperature, add spices and sanitas and mixing.(b) the dirty agent of deoiling

The chemistry name of an article	Trade(brand)name/supplier	Weight %
			Poly(oxyethylene glycol) 400	PEG400/Sanyo?Kasei	90.00
5-chloro-2-methyl 4-isothiazoline-3-ketone and 2-methyl-4-isothiazoline-3-ketone (1.5% aqueous solution)	Kathon?CG/Rohm＆Hass	0.05
			Water		9.95

Preparation: water and PEG400 are mixed.Adding preservative agent and mixing then.

The phase of preparation (a) with (b) be filled to respectively in the chamber of two compartment pump decollators of the foregoing description 1 said type, so that final composition contains isopyknic water phase surfactant mixture and deoils dirty agent mutually.

When phase (a) and (b) mixing with equal portions, this total preparation be blur and because flocculation and viscosity reduction are separated soon.But when formulation component during with its maintenance mutually that separates, has just been avoided stability problem in dual compartment package, and the material in two chambers keeps transparent.Embodiment 3

(a) water phase surfactant mixture (except as otherwise noted, raw material is about 100% actives)

The chemistry name of an article	Trade(brand)name/supplier	Weight %
			K lauryl MAP/DAP+ accessory constituent	Priori B300D (29% active ingredient+9% accessory constituent)/Kao	88.85
Sedimentary silica	Sorbosil?TC15/Crosfield	11.00
			Spices	Pheonix?300?OPTFM/Givaudan?Roure	0.10
5-chloro-2-methyl-4-isothiazoline-3-ketone and 2-methyl 4-isothiazoline-3-ketone (1.5% aqueous solution)	Kathon?CG/Rohm＆Hass	0.05

Preparation: be added to Sorbosil TC15 among the Priori B300D and mixing under reduced pressure.Perfuming and sanitas then.

(b) the dirty agent of deoiling

The chemistry name of an article	Trade(brand)name/supplier	Weight %
			Poly(oxyethylene glycol) 400	PEG400/SanyoKasei	30.00
Glycerol	MarukoRG/NOF	30.00
			Carbomer	Carbopol?ETD2020/Goodrich	1.33
Trolamine	A-900/Shell	0.38
			5-chloro-2-methyl-4-isothiazoline-3-ketone and 2-methyl 2-isothiazoline-3-ketone (1.5% aqueous solution)	Kathon?CG/Rohm＆Hass	0.05
Water		38.24

Preparation: under high shear mixing, Carbopol ETD2020 is dispersed in the water.Add PEG 400, glycerol and sanitas and mixing then.Under stirring, decompressing and continuous neutralizes this solution to pH 7.0 then with three ethanol peace.

The phase of preparation (a) with (b) be filled to respectively in the chamber of two compartment pump decollators of the foregoing description 1 said type, so that final composition contains isopyknic water phase surfactant mixture and deoils dirty agent mutually.

When the phase (a) of preparation and (b) mixing with equal portions, this total preparation be blur and because flocculation and viscosity reduction are separated soon.But when formulation component during with its maintenance mutually that separates, has just been avoided stability problem in dual compartment package, and the material in chamber (b) keeps transparent, and the material in chamber (a) is opaque.

According to method of the present invention, test existing " 2 close 1 " clean-out system contrast on the preparation dispersive products and marketing that uses embodiment 1,2 and 3.Composition of the present invention provides the performance of removing makeup from skin of obvious increase, and gives the suitable pure and fresh sensation of human consumer.Embodiment 4

(a) water phase surfactant mixture (except as otherwise noted, raw material is about 100% actives)

The chemistry name of an article	Trade(brand)name/supplier	Weight %
			The KMAP/DAP+ accessory constituent	Priori B300D (29% active ingredient+9% accessory constituent)/Kao	55.75
Poly(oxyethylene glycol) 400	Peg400/Fisher	16.00
			Sedimentary silica	Neosil?CT15/Crosfield	12.00
Glycerol	Maruko?RG/NOF	16.00
			Spices	Pheonix3000?OPTFM/Givaudan Roure	0.20
5-chloro-2-methyl-4-isothiazoline-3-ketone and 2-methyl-4-isothiazoline-3-ketone (1.5% aqueous solution)	Kathon?CG/Rohm＆Hass	0.05

Preparation: Priori B300D, PEG 400 and glycerol are mixed.Add Neosil CT15 then, and under reduced pressure mix.Last perfuming and sanitas also mix.

(b) the dirty agent of deoiling

The chemistry name of an article	Trade(brand)name/supplier	Weight %
			Carboxy vinyl polymer	Carbopol?Ultrez?10/Goodrich	0.50
Poly(oxyethylene glycol) 400	PEG400/Sanyo?Kasei	16.00
			Glycerol	Maruko?RG/NOF	16.00
The different thiophene thiophene quinoline of 5-chloro-2-methyl-4-isothiazole-3-ketone and 2-methyl-4--3-ketone (1.5% aqueous solution)	Kathon?CG/Rohm＆Hass	0.05
			Trolamine (90%)	A-900/Shell	0.55
Water	Distilled water	66.90

Preparation: under high shear mixing, at first Carbopol is dispersed in the water.Under agitation add glycerol, PEG 400 and sanitas then, form uniform dispersion liquid.Continue to mix in decompression then, neutralize this solution to pH7.0 with trolamine.

The phase of preparation (a) with (b) be filled to respectively in the chamber of two compartment pump decollators of the foregoing description 1 said type, so that final composition contains isopyknic water phase surfactant mixture and deoils dirty agent mutually.

According to method of the present invention, use in addition that existing " 2 close 1 " clean-out system compares test on the preparation dispersive products and marketing of embodiment 4.Composition of the present invention provides the performance of removing makeup from skin of obvious increase, and gives the suitable pure and fresh sensation of human consumer.

Claims (14)

1. composition that cleans and remove grease, it comprises:

A) a kind of water that contains that contains one or more tensio-active agents that are selected from negatively charged ion, nonionic, amphoteric, zwitter-ion and cats product, soap and their mixture; With

B) a kind of moisture or water-free phase that contains one or more reagent of removing grease, said water-free be with emulsive state not mutually;

Wherein, the size of these phases is greater than 1000 microns, and separates, but the combined dispersion of available single packaging facilities to separate.

2. according to the composition of claim 1, wherein individual packaging equipment comprises two compartments that separate.

3. according to the composition of claim 1 or 2, one of them is the form with microcapsule mutually.

4. according to the composition of aforementioned arbitrary claim, wherein be mutually with predetermined ratio combination dispersive.

5. according to the composition of aforementioned arbitrary claim, the reagent of wherein removing grease is selected from polymerized polyalcohol, polyvalent alcohol, size greater than 10 microns solid particulate matter, solvent, the nonionogenic tenside of HLB value＜10 and their mixture.

6. according to the composition of aforementioned arbitrary claim, wherein remove the reagent thickening material thickening of grease.

7. according to the composition of aforementioned arbitrary claim, it comprises 1-70 (weight) %, the reagent of removing grease of preferred 5-50 (weight) %.

8. according to the composition of aforementioned arbitrary claim, wherein grease is makeup.

9. according to the composition of aforementioned arbitrary claim, what wherein contain tensio-active agent contains water thickening material thickening.

One kind by using aforementioned arbitrary claim cleaning and the liquid composition of removing grease improve the method for removing grease from skin, this method comprises:

ⅰ) from packaging facilities scatter table surface-active agent and the reagent of removing grease;

ⅱ) tensio-active agent and the reagent of removing grease are used on the human body; With

ⅲ) pass through the water rinse except that grease and clean-out system in the mixture that forms.

11. according to the method for claim 10, wherein said composition is disperseed by one packaging facilities.

12. according to the method for claim 10 or 11, wherein tensio-active agent is to be disperseed by packaging facilities with predetermined ratio with the reagent of removing grease.

13. the form with suitable dispersion packing contains the topical composition of packing of arbitrary cleaning combination of root a tree name claim 1-9.

14. according to the packaged composition of claim 13, wherein this packing has two or more compartments.