CN1220088A - 除草组合物 - Google Patents
除草组合物 Download PDFInfo
- Publication number
- CN1220088A CN1220088A CN98119431.1A CN98119431A CN1220088A CN 1220088 A CN1220088 A CN 1220088A CN 98119431 A CN98119431 A CN 98119431A CN 1220088 A CN1220088 A CN 1220088A
- Authority
- CN
- China
- Prior art keywords
- fields
- parts
- ethyl
- salt
- chloro
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 55
- 230000002363 herbicidal effect Effects 0.000 title claims abstract description 24
- 241000196324 Embryophyta Species 0.000 claims abstract description 27
- 150000003839 salts Chemical class 0.000 claims abstract description 18
- 239000004009 herbicide Substances 0.000 claims abstract description 15
- 238000000034 method Methods 0.000 claims abstract description 9
- -1 phosphonomethyl Chemical group 0.000 claims description 17
- YZHUMGUJCQRKBT-UHFFFAOYSA-M sodium chlorate Chemical compound [Na+].[O-]Cl(=O)=O YZHUMGUJCQRKBT-UHFFFAOYSA-M 0.000 claims description 7
- DHMQDGOQFOQNFH-UHFFFAOYSA-N Glycine Chemical compound NCC(O)=O DHMQDGOQFOQNFH-UHFFFAOYSA-N 0.000 claims description 6
- FKRCODPIKNYEAC-UHFFFAOYSA-N ethyl propionate Chemical compound CCOC(=O)CC FKRCODPIKNYEAC-UHFFFAOYSA-N 0.000 claims description 6
- 239000004471 Glycine Substances 0.000 claims description 3
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 3
- MLKCGVHIFJBRCD-UHFFFAOYSA-N ethyl 2-chloro-3-{2-chloro-5-[4-(difluoromethyl)-3-methyl-5-oxo-4,5-dihydro-1H-1,2,4-triazol-1-yl]-4-fluorophenyl}propanoate Chemical compound C1=C(Cl)C(CC(Cl)C(=O)OCC)=CC(N2C(N(C(F)F)C(C)=N2)=O)=C1F MLKCGVHIFJBRCD-UHFFFAOYSA-N 0.000 abstract description 21
- XDDAORKBJWWYJS-UHFFFAOYSA-N glyphosate Chemical compound OC(=O)CNCP(O)(O)=O XDDAORKBJWWYJS-UHFFFAOYSA-N 0.000 abstract description 14
- 240000007594 Oryza sativa Species 0.000 abstract description 6
- 235000007164 Oryza sativa Nutrition 0.000 abstract description 6
- 235000009566 rice Nutrition 0.000 abstract description 6
- 244000075850 Avena orientalis Species 0.000 abstract description 5
- 235000010469 Glycine max Nutrition 0.000 abstract description 5
- 244000068988 Glycine max Species 0.000 abstract description 5
- 240000005979 Hordeum vulgare Species 0.000 abstract description 5
- 235000007340 Hordeum vulgare Nutrition 0.000 abstract description 5
- 241000209140 Triticum Species 0.000 abstract description 5
- 235000021307 Triticum Nutrition 0.000 abstract description 5
- 240000008042 Zea mays Species 0.000 abstract description 5
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 abstract description 5
- 235000002017 Zea mays subsp mays Nutrition 0.000 abstract description 5
- 235000005822 corn Nutrition 0.000 abstract description 5
- 239000004480 active ingredient Substances 0.000 abstract 2
- 239000005492 Carfentrazone-ethyl Substances 0.000 description 20
- 239000005562 Glyphosate Substances 0.000 description 12
- 238000009472 formulation Methods 0.000 description 12
- 229940097068 glyphosate Drugs 0.000 description 12
- 238000009333 weeding Methods 0.000 description 10
- 230000000694 effects Effects 0.000 description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 9
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 8
- 240000003176 Digitaria ciliaris Species 0.000 description 8
- 235000017898 Digitaria ciliaris Nutrition 0.000 description 8
- 244000058871 Echinochloa crus-galli Species 0.000 description 8
- 239000001768 carboxy methyl cellulose Substances 0.000 description 8
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 8
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 8
- 244000025254 Cannabis sativa Species 0.000 description 7
- 241000207783 Ipomoea Species 0.000 description 7
- 230000012010 growth Effects 0.000 description 7
- 238000002360 preparation method Methods 0.000 description 7
- 244000036975 Ambrosia artemisiifolia Species 0.000 description 6
- 240000006122 Chenopodium album Species 0.000 description 6
- 235000009344 Chenopodium album Nutrition 0.000 description 6
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 6
- 240000003461 Setaria viridis Species 0.000 description 6
- 235000002248 Setaria viridis Nutrition 0.000 description 6
- 240000007218 Ipomoea hederacea Species 0.000 description 5
- 235000010086 Setaria viridis var. viridis Nutrition 0.000 description 5
- 241001251949 Xanthium sibiricum Species 0.000 description 5
- 150000001875 compounds Chemical class 0.000 description 5
- LRCFXGAMWKDGLA-UHFFFAOYSA-N dioxosilane;hydrate Chemical compound O.O=[Si]=O LRCFXGAMWKDGLA-UHFFFAOYSA-N 0.000 description 5
- 230000009969 flowable effect Effects 0.000 description 5
- 239000002245 particle Substances 0.000 description 5
- 229960004029 silicic acid Drugs 0.000 description 5
- 235000005478 southern crabgrass Nutrition 0.000 description 5
- 239000004563 wettable powder Substances 0.000 description 5
- 235000003129 Ambrosia artemisiifolia var elatior Nutrition 0.000 description 4
- 235000007319 Avena orientalis Nutrition 0.000 description 4
- 235000007558 Avena sp Nutrition 0.000 description 4
- 244000285790 Cyperus iria Species 0.000 description 4
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 4
- 235000014716 Eleusine indica Nutrition 0.000 description 4
- 244000025670 Eleusine indica Species 0.000 description 4
- 241000207890 Ipomoea purpurea Species 0.000 description 4
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 4
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 4
- 235000003484 annual ragweed Nutrition 0.000 description 4
- 235000006263 bur ragweed Nutrition 0.000 description 4
- 235000003488 common ragweed Nutrition 0.000 description 4
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 4
- 238000000227 grinding Methods 0.000 description 4
- 239000003921 oil Substances 0.000 description 4
- 235000019198 oils Nutrition 0.000 description 4
- 235000009736 ragweed Nutrition 0.000 description 4
- 239000000600 sorbitol Substances 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- 238000001238 wet grinding Methods 0.000 description 4
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 3
- WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 3
- 235000011999 Panicum crusgalli Nutrition 0.000 description 3
- 244000067505 Xanthium strumarium Species 0.000 description 3
- 239000012752 auxiliary agent Substances 0.000 description 3
- 239000004927 clay Substances 0.000 description 3
- 238000010790 dilution Methods 0.000 description 3
- 239000012895 dilution Substances 0.000 description 3
- 235000013399 edible fruits Nutrition 0.000 description 3
- ZEKANFGSDXODPD-UHFFFAOYSA-N glyphosate-isopropylammonium Chemical compound CC(C)N.OC(=O)CNCP(O)(O)=O ZEKANFGSDXODPD-UHFFFAOYSA-N 0.000 description 3
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 240000006995 Abutilon theophrasti Species 0.000 description 2
- 235000013479 Amaranthus retroflexus Nutrition 0.000 description 2
- 244000237956 Amaranthus retroflexus Species 0.000 description 2
- 235000003133 Ambrosia artemisiifolia Nutrition 0.000 description 2
- 241000208841 Ambrosia trifida Species 0.000 description 2
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 2
- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 241000207892 Convolvulus Species 0.000 description 2
- 244000108484 Cyperus difformis Species 0.000 description 2
- 235000018109 Cyperus longus Nutrition 0.000 description 2
- 244000150195 Cyperus longus Species 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- 241001553700 Euphorbia lathyris Species 0.000 description 2
- 241001289540 Fallopia convolvulus Species 0.000 description 2
- 241001476002 Gastridium ventricosum Species 0.000 description 2
- 244000020551 Helianthus annuus Species 0.000 description 2
- 235000003222 Helianthus annuus Nutrition 0.000 description 2
- 235000021506 Ipomoea Nutrition 0.000 description 2
- 244000214365 Ipomoea hederacea var. integriuscula Species 0.000 description 2
- 241000209510 Liliopsida Species 0.000 description 2
- 244000147162 Matricaria matricarioides Species 0.000 description 2
- 235000004589 Matricaria matricarioides Nutrition 0.000 description 2
- 235000007846 Papaver rhoeas Nutrition 0.000 description 2
- 240000004674 Papaver rhoeas Species 0.000 description 2
- 244000038248 Pennisetum spicatum Species 0.000 description 2
- 235000007195 Pennisetum typhoides Nutrition 0.000 description 2
- 240000006928 Persicaria lapathifolia Species 0.000 description 2
- 231100000674 Phytotoxicity Toxicity 0.000 description 2
- 244000292697 Polygonum aviculare Species 0.000 description 2
- 235000006386 Polygonum aviculare Nutrition 0.000 description 2
- 244000275012 Sesbania cannabina Species 0.000 description 2
- 241000533293 Sesbania emerus Species 0.000 description 2
- 235000017016 Setaria faberi Nutrition 0.000 description 2
- 241001355178 Setaria faberi Species 0.000 description 2
- 235000008515 Setaria glauca Nutrition 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 235000002594 Solanum nigrum Nutrition 0.000 description 2
- 244000062793 Sorghum vulgare Species 0.000 description 2
- 240000006694 Stellaria media Species 0.000 description 2
- 241000404538 Tripleurospermum maritimum subsp. inodorum Species 0.000 description 2
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 2
- 241001141210 Urochloa platyphylla Species 0.000 description 2
- 241000405217 Viola <butterfly> Species 0.000 description 2
- 239000000440 bentonite Substances 0.000 description 2
- 229910000278 bentonite Inorganic materials 0.000 description 2
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 2
- 235000010354 butylated hydroxytoluene Nutrition 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- 241001233957 eudicotyledons Species 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- 239000003337 fertilizer Substances 0.000 description 2
- 238000010413 gardening Methods 0.000 description 2
- QPPQHRDVPBTVEV-UHFFFAOYSA-N isopropyl dihydrogen phosphate Chemical compound CC(C)OP(O)(O)=O QPPQHRDVPBTVEV-UHFFFAOYSA-N 0.000 description 2
- 239000002689 soil Substances 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 239000004094 surface-active agent Substances 0.000 description 2
- UOCLXMDMGBRAIB-UHFFFAOYSA-N 1,1,1-trichloroethane Chemical class CC(Cl)(Cl)Cl UOCLXMDMGBRAIB-UHFFFAOYSA-N 0.000 description 1
- SCYULBFZEHDVBN-UHFFFAOYSA-N 1,1-Dichloroethane Chemical compound CC(Cl)Cl SCYULBFZEHDVBN-UHFFFAOYSA-N 0.000 description 1
- PAWQVTBBRAZDMG-UHFFFAOYSA-N 2-(3-bromo-2-fluorophenyl)acetic acid Chemical compound OC(=O)CC1=CC=CC(Br)=C1F PAWQVTBBRAZDMG-UHFFFAOYSA-N 0.000 description 1
- 244000215068 Acacia senegal Species 0.000 description 1
- 239000005995 Aluminium silicate Substances 0.000 description 1
- 241000561747 Amaranthus albus Species 0.000 description 1
- 239000004254 Ammonium phosphate Substances 0.000 description 1
- 241001645380 Bassia scoparia Species 0.000 description 1
- 241000143476 Bidens Species 0.000 description 1
- 241000498899 Bidens frondosa Species 0.000 description 1
- 235000010662 Bidens pilosa Nutrition 0.000 description 1
- DKPFZGUDAPQIHT-UHFFFAOYSA-N Butyl acetate Natural products CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 description 1
- 244000277285 Cassia obtusifolia Species 0.000 description 1
- 235000006719 Cassia obtusifolia Nutrition 0.000 description 1
- 244000201986 Cassia tora Species 0.000 description 1
- 235000014552 Cassia tora Nutrition 0.000 description 1
- 241001233914 Chelidonium majus Species 0.000 description 1
- 235000005918 Cirsium arvense Nutrition 0.000 description 1
- 240000001579 Cirsium arvense Species 0.000 description 1
- 244000074881 Conyza canadensis Species 0.000 description 1
- 235000004385 Conyza canadensis Nutrition 0.000 description 1
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 1
- 241000208296 Datura Species 0.000 description 1
- 240000008853 Datura stramonium Species 0.000 description 1
- 206010011878 Deafness Diseases 0.000 description 1
- ZAFNJMIOTHYJRJ-UHFFFAOYSA-N Diisopropyl ether Chemical compound CC(C)OC(C)C ZAFNJMIOTHYJRJ-UHFFFAOYSA-N 0.000 description 1
- 241000771421 Dinebra panicoides Species 0.000 description 1
- 241000508725 Elymus repens Species 0.000 description 1
- 241000132521 Erigeron Species 0.000 description 1
- 244000192024 Euphorbia helioscopia Species 0.000 description 1
- 235000012043 Euphorbia helioscopia Nutrition 0.000 description 1
- 235000014820 Galium aparine Nutrition 0.000 description 1
- 240000005702 Galium aparine Species 0.000 description 1
- 108010010803 Gelatin Proteins 0.000 description 1
- 229920000084 Gum arabic Polymers 0.000 description 1
- 241000110847 Kochia Species 0.000 description 1
- 235000009193 Lamium purpureum Nutrition 0.000 description 1
- 240000006503 Lamium purpureum Species 0.000 description 1
- 244000050255 Leptochloa filiformis Species 0.000 description 1
- 241001597008 Nomeidae Species 0.000 description 1
- 241001668545 Pascopyrum Species 0.000 description 1
- 241000978467 Persicaria pensylvanica Species 0.000 description 1
- 241000205407 Polygonum Species 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- 235000001855 Portulaca oleracea Nutrition 0.000 description 1
- 244000234609 Portulaca oleracea Species 0.000 description 1
- 240000006410 Sida spinosa Species 0.000 description 1
- 241000220261 Sinapis Species 0.000 description 1
- 229920002125 Sokalan® Polymers 0.000 description 1
- 244000061457 Solanum nigrum Species 0.000 description 1
- 240000002307 Solanum ptychanthum Species 0.000 description 1
- 235000007230 Sorghum bicolor Nutrition 0.000 description 1
- 240000002439 Sorghum halepense Species 0.000 description 1
- 244000046109 Sorghum vulgare var. nervosum Species 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 239000005864 Sulphur Substances 0.000 description 1
- 244000274883 Urtica dioica Species 0.000 description 1
- 235000009108 Urtica dioica Nutrition 0.000 description 1
- 235000000758 Veronica anagallis aquatica Nutrition 0.000 description 1
- 240000008320 Veronica anagallis aquatica Species 0.000 description 1
- 241001166549 Veronica hederifolia Species 0.000 description 1
- 240000005592 Veronica officinalis Species 0.000 description 1
- 241000990144 Veronica persica Species 0.000 description 1
- 235000009754 Vitis X bourquina Nutrition 0.000 description 1
- 235000012333 Vitis X labruscana Nutrition 0.000 description 1
- 240000006365 Vitis vinifera Species 0.000 description 1
- 235000014787 Vitis vinifera Nutrition 0.000 description 1
- 239000000205 acacia gum Substances 0.000 description 1
- 235000010489 acacia gum Nutrition 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 239000003905 agrochemical Substances 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 239000000783 alginic acid Substances 0.000 description 1
- 235000010443 alginic acid Nutrition 0.000 description 1
- 229920000615 alginic acid Polymers 0.000 description 1
- 229960001126 alginic acid Drugs 0.000 description 1
- 150000004781 alginic acids Chemical class 0.000 description 1
- 150000001346 alkyl aryl ethers Chemical class 0.000 description 1
- 150000008055 alkyl aryl sulfonates Chemical class 0.000 description 1
- 150000008051 alkyl sulfates Chemical class 0.000 description 1
- 150000008052 alkyl sulfonates Chemical class 0.000 description 1
- QPUYECUOLPXSFR-UHFFFAOYSA-N alpha-methyl-naphthalene Natural products C1=CC=C2C(C)=CC=CC2=C1 QPUYECUOLPXSFR-UHFFFAOYSA-N 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 235000019270 ammonium chloride Nutrition 0.000 description 1
- 229910000148 ammonium phosphate Inorganic materials 0.000 description 1
- 235000019289 ammonium phosphates Nutrition 0.000 description 1
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 1
- 229910052921 ammonium sulfate Inorganic materials 0.000 description 1
- 235000011130 ammonium sulphate Nutrition 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 239000003899 bactericide agent Substances 0.000 description 1
- 238000009395 breeding Methods 0.000 description 1
- 230000001488 breeding effect Effects 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- HCWYXKWQOMTBKY-UHFFFAOYSA-N calcium;dodecyl benzenesulfonate Chemical class [Ca].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 HCWYXKWQOMTBKY-UHFFFAOYSA-N 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 239000005018 casein Substances 0.000 description 1
- BECPQYXYKAMYBN-UHFFFAOYSA-N casein, tech. Chemical compound NCCCCC(C(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(CC(C)C)N=C(O)C(CCC(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(C(C)O)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(COP(O)(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(N)CC1=CC=CC=C1 BECPQYXYKAMYBN-UHFFFAOYSA-N 0.000 description 1
- 235000021240 caseins Nutrition 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- MNNHAPBLZZVQHP-UHFFFAOYSA-N diammonium hydrogen phosphate Chemical compound [NH4+].[NH4+].OP([O-])([O-])=O MNNHAPBLZZVQHP-UHFFFAOYSA-N 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 239000002552 dosage form Substances 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 238000012407 engineering method Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N ferric oxide Chemical compound O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 230000000855 fungicidal effect Effects 0.000 description 1
- 239000000417 fungicide Substances 0.000 description 1
- 229920000159 gelatin Polymers 0.000 description 1
- 239000008273 gelatin Substances 0.000 description 1
- 235000019322 gelatine Nutrition 0.000 description 1
- 235000011852 gelatine desserts Nutrition 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 150000008282 halocarbons Chemical class 0.000 description 1
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 1
- 239000002917 insecticide Substances 0.000 description 1
- WFKAJVHLWXSISD-UHFFFAOYSA-N isobutyramide Chemical compound CC(C)C(N)=O WFKAJVHLWXSISD-UHFFFAOYSA-N 0.000 description 1
- LRDFRRGEGBBSRN-UHFFFAOYSA-N isobutyronitrile Chemical compound CC(C)C#N LRDFRRGEGBBSRN-UHFFFAOYSA-N 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 239000003350 kerosene Substances 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 229920005610 lignin Polymers 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- 235000019713 millet Nutrition 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
- 235000010446 mineral oil Nutrition 0.000 description 1
- 150000002825 nitriles Chemical class 0.000 description 1
- 239000002420 orchard Substances 0.000 description 1
- 239000005648 plant growth regulator Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 239000004584 polyacrylic acid Substances 0.000 description 1
- 229920000151 polyglycol Polymers 0.000 description 1
- 239000010695 polyglycol Substances 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 229920001282 polysaccharide Polymers 0.000 description 1
- 239000005017 polysaccharide Substances 0.000 description 1
- 150000004804 polysaccharides Chemical class 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 1
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 1
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- APSBXTVYXVQYAB-UHFFFAOYSA-M sodium docusate Chemical compound [Na+].CCCCC(CC)COC(=O)CC(S([O-])(=O)=O)C(=O)OCC(CC)CCCC APSBXTVYXVQYAB-UHFFFAOYSA-M 0.000 description 1
- 239000003516 soil conditioner Substances 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 150000005846 sugar alcohols Chemical class 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 235000012222 talc Nutrition 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
- 229920003169 water-soluble polymer Polymers 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
- A01N43/647—Triazoles; Hydrogenated triazoles
- A01N43/653—1,2,4-Triazoles; Hydrogenated 1,2,4-triazoles
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Catching Or Destruction (AREA)
Abstract
本发明涉及一种除草组合物,其含有2－氯－3－[2－氯－4－氟－5－(4－二氟甲基－4,5－二氢－3－甲基－5－氧代－1H－1,2,4－***－1－基)苯基]丙酸乙酯;和N－(膦酰基甲基)甘氨酸或其盐为活性成分。该除草组合物用于有效控制玉米田,大豆田,小麦田,大麦田,燕麦田,黑麦田,稻田,或水稻田中多种杂草。也描述了通过用上述除草组合物叶处理来控制杂草的方法;以及上述活性成分的混合物作为叶处理除草剂的用途。
Description
本发明涉及一种除草组合物，更具体地说，涉及叶处理的除草组合物，以及涉及一种通过用该组合物对杂草叶处理来控制杂草的方法。
现今许多种除草剂是可以购买得到的，并且它们被广泛地应用。但是仍然有许多种要控制的杂草，并且它们的生长持续时间长。为此原因，需要的是具有高除草活性，早期出现除草效果，广谱杂草控制范围，以及对农作物安全的除草剂。
本发明人深入研究发现了极好的除草剂。作为结果，发现通过施用含有下面的活性成分的除草组合物能有效控制生长在农作物生长点或非农作物生长点的各种杂草，(a)2-氯-3-[2-氯-4-氟-5-(4-二氟甲基-4,5-二氢-3-甲基-5-氧代-1H-1,2,4-***-1-基)苯基]丙酸乙酯(通用名是carfentrazone-ethyl；此后文中称之为carfentrazone-ethyl)；和(b)N-(膦酰基甲基)甘氨酸(通用名草甘膦；此后文中称之为草甘膦)或其盐。
进一步发现，该组合物除草活性与独立使用这些活性成分的情况相比协同性提高，因此，这些除草组合物能以较低量施用；并且出现除草效果的时间缩短，杂草控制谱增大，能控制很多种杂草，特别是玉米田，大豆田，小麦田，大麦田，燕麦田，黑麦田，稻田，和水稻田中的杂草，就此完成本发明。
因此本发明提供含有carfentrazone-ethyl和草甘膦或其盐作为活性成分的除草组合物(此后文中称之为本发明组合物)；和用该组合物控制杂草的方法。
本发明组合物活性成分之一carfentrazone-ethyl是一种化合物，其描述于《农业化学新化合物汇总》(AG CHEM NEW COMPOUNDREVIEW)，第15卷，1997(由农业化学情报服务中心公布，1997),21页。
本发明组合物另一种活性成分草甘膦是一种化合物，其描述于《农业化学品手册》(Farm ChemcalsHandbook),1995(Meister,Publishing Co.,1995出版),C188页。本发明中“盐”指所有的农业可接受盐。
本发明组合物对于多种杂草有除草活性，并具有农作物选择性。本发明组合物在农业区或园艺区显示出极好的除草效果，所述的农业区或园艺区是例如一般的耕地，非耕地和果园，以及非农作物土地例如游乐场，运动场，空地，林地，铁路，路边，电应用区和公用道路。因此，本发明组合物是极好的除草组合物。
本发明组合物有效控制玉米田，大豆田，小麦田，大麦田，燕麦田，黑麦田或稻田中的主要杂草，例如双子叶植物，例如荞麦蔓(Polygonum convolvulus)，大马蓼(Polygonum lapathifolium，宾州蓼(Polygonum pensylvanicuum)，马齿苋(Portulaca oleracea)，藜(Chenopodium album)，反枝苋(Amaranthus retroflexus)，白苋(Sinapis aryensis)，大果田菁(Sesbania exaltata)，钝叶决明(Cassia obtusifolia)，苘麻(Abutilon theophrasti)，刺黄花稔(sida spinosa)，裂叶牵牛(Ipomoea hederacea)，圆叶牵牛(Ipomoeapurpurea),entireleaf morningglory(Ipomoea hederacea var.intergriuscula)，多洼牵牛(Ipomoea lacunosaL.)，曼陀罗(Daturastramonium，龙葵(Solanum nigrum)，苍耳(Xanthium strumarium)，向日葵(Helianthus annuus)，田旋花(Convolvulus aryensis)，泽漆(Euphorbia helioscopia)，光果鬼针草(Bidens frondosa)，美洲豚草(Ambrosia artemisiifolia)，德克萨斯三裂叶豚草(Ambrosiatrifida)，猪殃殃(Galium aparine)，常春藤叶婆婆纳(Veronicahederifolia)，地肤(Kochia scoparia)，田堇菜(Viola aryensis)，波斯水苦荬(Veronica persica)，田蓟(Crisium arvense)，繁缕(Stellaria media)，小野芝麻(Lamium purpureum)，宝盖草(Lamiumamplexicaure)，虞美人(Papaver rhoea),scentlesschamomile(Matricaria perforata)，香甘菊(Matricariamatricarioides)，和加拿大飞蓬(Erigeron canadensis)；和单子叶植物，例如稗草(Echinochloa crus-galli)，狗尾草(Setariaviridis)，费氏狗尾草(Setaria faberi)，金狗尾草(Setariaglauca),southern crabgrass(Digitaria ciliaris)，蟋蟀草(Eleusine indica)，阿刺伯高粱(Sorghum halepense)，葡萄冰草(Agropyron repens)，二色蜀黍(Sorghum bicolor)，多花千金子(Leptocbloa panicoides)，虮子草(Leptochloa filiformis)，阔叶臂形草(Brachiaria platyphylla)，异型莎草(Cyperus difformis)和碎米莎草(Cyperus iria)，而其对于象玉米，大豆，小麦，大麦，燕麦，黑麦和稻这些农作物没有明显的植物毒性。
当本发明组合物在水稻田中使用时，可以优选在浇灌之前施用于叶子。
本发明组合物有效控制水稻田中的杂草，例如双子叶植物，例如大果田菁(Sesbania exaltata)，裂叶牵牛(Ipomoea hederacea)，圆叶牵牛(Pharbitis purpurea),entireleaf morningglory(Ipomoeahederacea var.intergriuscula)，多洼牵牛(IPomoea lacunosaL.)，苍耳(Xanthium strumarium)，和宾州蓼(Polygonum pensylvanicum)；和单子叶植物，例如稗草(Echinochloa crus-galli),southerncrabgrass(Digitaria ciliaris)，蟋蟀草(Eleusine indica)，多花千金子(Leptochloa panicoides)，虮子草(Leptocbloa filiformis)，阔叶臂形草(Brachiaria platyphylla)，异型莎草(Cyperusdifformis)和碎米莎草(Cyperus iria)，而其对于稻没有明显的植物毒性。
农作物被理解为也指通过常规育种或基因工程方法使对除草剂或几类除草剂例如对于草甘膦有耐受性的那些农作物。
对草甘膦有耐受性的耕种植物农作物优选通过生物技术方法产生。产生这些对草甘膦有耐受性的植物的方法详细描述于国际专利申请WO92/04449,WO92/19719和WO92/00377，和美国专利5188642,4971908,5145783,5510471，和5633448。
在本发明组合物中，carfentrazone-ethyl与草甘膦或其盐的混合比例尽管可以随着要控制的杂草的种类，施用状况和条件以及其它因素而变化，但是通常在1∶5-500重量比范围内。
本发明组合物通常可以以一些制剂形式使用，例如乳油，可湿粉剂，流动制剂，或颗粒剂，其能通过将组合物与固体载体，液体载体，或其它增量剂混合，并且如果需要，向该混合物中加入表面活性剂或其它助剂来制备。在这样一种制剂中，通常以总量0.5-90wt％，优选1-80wt％含有carfentrazone-ethyl和草甘膦或其盐。
在制剂中使用的固体载体可以包括例如细粉或颗粒形式的下列物质：粘土(例如高岭土，硅藻土，合成的水合氧化硅，Fubasami粘土，膨润土，酸粘土)；滑石和其它无机物质(例如丝云母，粉末石英，粉末硫磺，活化碳，碳酸钙)；和化肥(例如硫酸铵，磷酸铵，硝酸铵，氯化铵，尿素)。液体载体可以包括例如水，醇类(例如甲醇，乙醇)；酮类(例如丙酮，甲基乙基酮，环己酮)；芳香烃(例如甲苯，二甲苯，乙基苯，甲基萘)；非芳香烃(例如环己烷，己烷，煤油)；酯类(例如乙酸乙酯，乙酸丁酯)；腈类(例如乙腈，异丁腈)；醚类(例如二噁烷，二异丙基醚)；酰胺(例如二甲基甲酰胺，二甲基乙酰胺)；和卤代烃(例如二氯乙烷，三氯乙烷)。
表面活性剂可以包括例如烷基硫酸酯；烷基磺酸盐；烷基芳基磺酸盐；烷基芳基醚及其聚氧乙烯衍生物；聚乙二醇醚；多元醇酯；和糖醇衍生物。
其它助剂可以包括例如粘合剂和分散剂，例如酪蛋白，明胶，多糖(例如粉末淀粉，***胶，纤维素衍生物，藻酸)，木质素衍生物，膨润土，和合成的水溶性聚合物(例如聚乙烯醇，聚乙烯吡咯烷酮，聚丙烯酸)；和稳定剂，例如PAP(磷酸氢异丙酯(isopropyl acidphosphate)),BHT(2,6-二叔丁基-4-甲基苯酚),BHA(2-/3-叔丁基-4-甲氧基苯酚)，植物油，矿物油，脂肪酸，和脂肪酸酯。
本发明组合物也可以通过用上述配制技术将活性成分加入到各制剂中后混合这些制剂来制备。
如此配制的组合物可以直接对植物施用，或者用水等稀释后施用。本发明组合物还可以以与其它除草剂的混合物使用，在这种情况下，预期除草活性会增强。用水稀释后的本发明组合物还可以以与助剂的混合物使用，在这种情况下，预期除草活性会增强。本发明组合物还可以与杀虫剂，杀细菌剂，杀真菌剂，植物生长调节剂，化肥，土壤改良剂，保护剂或其它试剂一起使用。
本发明组合物的施用量尽管随着活性成分化合物carfentrazone-ethyl和草甘膦或其盐的混合比例，天气状况，制剂类型，施用时间，施用方法，施用地点，要控制的杂草，以及要保护的农作物而不同，但是一般是在每公顷用100-4000g，优选500-1000g活性成分总量范围内。在乳油，可湿粉剂，流动剂或其它类似制剂情况下，通常对于每公顷，按其所述量用水稀释后以100-1000升的比例施用。
下面将详细描述制剂实施例，其中份数以重量计。
制剂实施例1
一份carfentrazone-ethyl,25份草甘膦或其盐，3份木素磺酸钙，2份月桂基硫酸钠，和69份合成的水合氧化硅充分磨成粉状并混合，得到各可湿粉剂。
制剂实施例2
0.4份carfentrazone-ethyl,40份草甘膦或其盐，3份木素磺酸钙，2份月桂基硫酸钠，和54.6份合成的水合氧化硅充分磨成粉状并混合，得到各可温粉剂。
制剂实施例3
10份carfentrazone-ethyl,40份草甘膦或其盐，3份木素磺酸钙，2份月桂基硫酸钠，和45份合成的水合氧化硅充分磨成粉状并混合，得到各可湿粉剂。
制剂实施例4
0.5份carfentrazone-ethyl,10份草甘膦或其盐，3份木素磺酸钙，2份月桂基硫酸钠，和84.5份合成的水合氧化硅充分磨成粉状并混合，得到各可湿粉剂。
制剂实施例5
一份carfentrazone-ethyl,25份草甘膦或其盐，3份聚氧乙烯山梨糖醇酐一油酸酯，3份CMC(羧甲基纤维素)，和68份水混合并湿磨成粉状，直到颗粒大小达到5微米或者更小，得到各流动剂。
制剂实施例6
0.4份carfentrazone-ethyl，40份草甘膦或其盐，3份聚氧乙烯山梨糖醇酐一油酸酯，3份CMC(羧甲基纤维素)，和53.6份水混合并湿磨成粉状，直到颗粒大小达到5微米或者更小，得到各流动剂。
制剂实施例7
10份carfentrazone-ethyl,40份草甘膦或其盐，3份聚氧乙烯山梨糖醇酐一油酸酯，3份CMC(羧甲基纤维素)，和44份水混合并湿磨成粉状，直到颗粒大小达到5微米或者更小，得到各流动剂。
制剂实施例8
0.5份carfentrazone-ethyl,10份草甘膦或其盐，3份聚氧乙烯山梨糖醇酐一油酸酯，3份CMC(羧甲基纤维素)，和83.5份水混合并湿磨成粉状，直到颗粒大小达到5微米或者更小，得到各流动剂。
下面将描述试验实施例。
评价标准
以11个等级评价除草活性，指定为0-10，即以数值“0”,“1”,“2”,“3”,“4”,“5”,“6”,“7”,“8”,“9”，或“10”表示，其中“0”指评价时，处理过的植物和未处理的植物之间萌芽或生长的程度没有差别或极少差别，而“10”指试验植物完全死亡或者其萌芽或生长被完全抑制。当等级是“7”,“8”,“9”，或“10”时，除草活性极好，但是当为“6”或更低时除草不充分。
试验实施例1
塑料小盆面积26.5×19cm2并且装入深7cm的高地土壤，然后种上费氏狗尾草(Setaria faberi)，稗草(Echinochloa crus-galli),southern crabgrass(Digitaria ciliaris)，藜(chenopodiumalbum)，美洲豚草(Ambrosia artemisiifolia)，苍耳(Xanthiumstrumarium)，和裂叶牵牛(Ipomoea hederacea)。在温室中，分别地，藜和美洲豚草生长28天，苍耳，裂叶牵牛，费氏狗尾草，和southerncrabgrass生长21天，稗草生长14天。
通过将10份carfentrazone-ethyl,14份聚氧乙烯苯乙烯基苯基醚，6份十二烷基苯磺酸钙，35份二甲苯，和35份环己酮充分混合获得的carfentrazone-ethyl乳油，草甘膦制剂产品(商品名，Roundup；销售商，Monsant Japan Limited；批发商，Sankyo Co.,Ltd.；其含有草甘膦异丙胺盐)，和carfentrazone-ethyl乳油和草甘膦制剂产品的混合物各自用水独立按其规定量稀释。用小喷雾器将各稀释液均匀喷雾到试验植物上。施药后，试验植物在温室中生长4天，然后测评除草活性。结果见表1。
表1
注：表1中的符号意义如下：
| 化合物 | 剂量(g/ha) | 除草活性 | ||||||
| G | B | S | L | R | C | I | ||
| Carfentrazone-ethyl | 20 | 3 | 3 | 2 | 6 | 6 | 6 | 6 |
| 草甘膦异丙胺盐 | 500 | 2 | 2 | 1 | 1 | 1 | 1 | 1 |
| Carfentrazone-ethyl+草甘膦异丙胺盐 | 20+500 | 8 | 7 | 9 | 9 | 9 | 10 | 10 |
G：费氏狗尾草 B：稗草
S：southern crabgrass L：藜
R：美洲豚草 C：苍耳
I：裂叶牵牛
本发明效果
玉米田，大豆田，小麦田，大麦田，燕麦田，黑麦田，稻田，或水稻田中多种杂草能被本发明组合物有效控制。
Claims (4)
1．除草组合物，其含有活性成分：
(a)2-氯-3-[2-氯-4-氟-5-(4-二氟甲基-4,5-二氢-3-甲基-5-氧代-1H-1,2,4-***-1-基)苯基]丙酸乙酯；和
(b)N-(膦酰基甲基)甘氨酸或其盐。
2．权利要求1的除草组合物，其中组分(a)与组分(b)的重量比是1∶5-500。
3．控制杂草的方法，包括通过叶处理对杂草施用有效量权利要求1或2的组合物。
4．一种混合物作为除草剂的用途，所述混合物含有：
(a)2-氯-3-[2-氯-4-氟-5-(4-二氟甲基-4,5-二氢-3-甲基-5-氧代-1H-1,2,4-***-1-基)苯基]丙酸乙酯；和
(b)N-(膦酰基甲基)甘氨酸或其盐。
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP274365/97 | 1997-10-07 | ||
| JP9274365A JPH11116408A (ja) | 1997-10-07 | 1997-10-07 | 除草剤組成物 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1220088A true CN1220088A (zh) | 1999-06-23 |
| CN1092927C CN1092927C (zh) | 2002-10-23 |
Family
ID=17540652
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN98119431A Expired - Lifetime CN1092927C (zh) | 1997-10-07 | 1998-10-05 | 除草组合物 |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US5935905A (zh) |
| JP (1) | JPH11116408A (zh) |
| CN (1) | CN1092927C (zh) |
| AR (1) | AR017288A1 (zh) |
| BR (1) | BR9803869A (zh) |
| FR (1) | FR2769176B1 (zh) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106804611A (zh) * | 2015-11-27 | 2017-06-09 | 吉林省白城市农业科学院 | 中国北方燕麦田间杂草防治技术及适用的除草剂 |
| CN107006512A (zh) * | 2017-05-23 | 2017-08-04 | 合肥星宇化学有限责任公司 | 一种除草组合物及其应用 |
| CN114052031A (zh) * | 2021-12-08 | 2022-02-18 | 山东坤牛植物保护有限公司 | 一种增效型除草农药组合物的制备方法 |
Families Citing this family (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6127318A (en) * | 1998-04-03 | 2000-10-03 | Monsanto Company | Combination of glyphosate and a triazolinone herbicide |
| KR100957897B1 (ko) | 1998-07-16 | 2010-05-13 | 바이엘 크롭사이언스 아게 | 제초제 |
| DE19836684A1 (de) * | 1998-08-13 | 2000-02-17 | Hoechst Schering Agrevo Gmbh | Herbizide Mittel für tolerante oder resistente Reiskulturen |
| US6506707B1 (en) * | 1999-03-05 | 2003-01-14 | Ecosmart Technologies, Inc. | Herbicidal compositions containing plant essential oils and mixtures or blends thereof |
| JP2001002516A (ja) * | 1999-06-22 | 2001-01-09 | Nissan Chem Ind Ltd | 液状除草剤組成物 |
| US6774087B1 (en) | 1999-06-22 | 2004-08-10 | Fmc Corporation | Liquid herbicide composition |
| US6713433B2 (en) | 1999-08-11 | 2004-03-30 | Monsanto Technology, Llc | Coformulation of an oil-soluble herbicide and a water-soluble herbicide |
| US6689719B2 (en) | 1999-08-11 | 2004-02-10 | Monsanto Technology Llc | Coformulation of carfentrazone-ethyl and glyphasate |
| AR030412A1 (es) * | 2000-03-22 | 2003-08-20 | Fmc Corp | Proceso novedoso para preparar formulaciones acuosas |
| ES2231509T3 (es) * | 2000-04-04 | 2005-05-16 | Basf Aktiengesellschaft | Mezclas herbicidas sinergicas. |
| US6441223B1 (en) | 2000-11-30 | 2002-08-27 | Monsanto Technology Llc | Method of making phosphorus-containing compounds and products thereof |
| AU2002354272A1 (en) * | 2001-12-25 | 2003-07-15 | Nihon Nohyaku Co., Ltd. | Herbicidal compositions and method of using the same |
| PL1722628T3 (pl) * | 2004-03-12 | 2011-07-29 | Fmc Corp | Kompozycja glifozatu |
| CN101022730B (zh) * | 2004-09-17 | 2010-05-05 | 石原产业株式会社 | 除草组合物 |
| US20100016159A1 (en) * | 2006-07-19 | 2010-01-21 | Syngenta Crop Protection, Inc. | Herbicidal composition and method of use thereof |
| AU2018402682B2 (en) * | 2018-01-17 | 2024-01-04 | Upl Ltd | Herbicidal combinations |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4165977A (en) * | 1974-11-14 | 1979-08-28 | Basf Aktiengesellschaft | Herbicidal compositions |
| DE2453908A1 (de) * | 1974-11-14 | 1976-05-26 | Basf Ag | Herbizide mischungen |
| CA1331463C (en) * | 1988-08-31 | 1994-08-16 | Kathleen Megan Poss | Herbicidal triazolinones |
| JP3799669B2 (ja) * | 1996-07-29 | 2006-07-19 | 日産化学工業株式会社 | 除草剤組成物 |
-
1997
- 1997-10-07 JP JP9274365A patent/JPH11116408A/ja active Pending
-
1998
- 1998-10-02 AR ARP980104928A patent/AR017288A1/es active IP Right Grant
- 1998-10-02 US US09/165,209 patent/US5935905A/en not_active Expired - Lifetime
- 1998-10-05 CN CN98119431A patent/CN1092927C/zh not_active Expired - Lifetime
- 1998-10-05 BR BR9803869-9A patent/BR9803869A/pt not_active Application Discontinuation
- 1998-10-05 FR FR9812428A patent/FR2769176B1/fr not_active Expired - Lifetime
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106804611A (zh) * | 2015-11-27 | 2017-06-09 | 吉林省白城市农业科学院 | 中国北方燕麦田间杂草防治技术及适用的除草剂 |
| CN107006512A (zh) * | 2017-05-23 | 2017-08-04 | 合肥星宇化学有限责任公司 | 一种除草组合物及其应用 |
| CN114052031A (zh) * | 2021-12-08 | 2022-02-18 | 山东坤牛植物保护有限公司 | 一种增效型除草农药组合物的制备方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1092927C (zh) | 2002-10-23 |
| AR017288A1 (es) | 2001-09-05 |
| US5935905A (en) | 1999-08-10 |
| FR2769176A1 (fr) | 1999-04-09 |
| FR2769176B1 (fr) | 2001-05-04 |
| BR9803869A (pt) | 2001-04-24 |
| JPH11116408A (ja) | 1999-04-27 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN1092927C (zh) | 除草组合物 | |
| JP6906658B2 (ja) | ４−アミノ−３−クロロ−５−フルオロ−６−（４−クロロ−２−フルオロ−３−メトキシフェニル）ピリジン−２−カルボン酸を含む除草組成物 | |
| KR102102423B1 (ko) | 4-아미노-3-클로로-5-플루오로-6-(4-클로로-2-플루오로-3-메톡시페닐)피리딘-2-카르복실산 또는 그의 유도체 및 특정 ps ii 억제제를 포함하는 제초 조성물 | |
| RU2241332C2 (ru) | Гербицидные средства для толерантных или резистентных культур сахарной свеклы, способ борьбы с сорняками | |
| US20110092466A1 (en) | Method for Protecting Soybeans from Being Infected by Fungi | |
| JP2013116865A (ja) | 除草用組成物 | |
| JP2009120503A (ja) | 除草剤 | |
| UA121737C2 (uk) | Суміш гербіцидів на основі карбамоїлтриазолінону та спосіб її застосування | |
| NO860188L (no) | Herbicide preparater. | |
| AU5881298A (en) | Herbicidal composition | |
| CA1253354A (en) | Herbicidal composition | |
| JP2003104808A (ja) | 除草剤組成物 | |
| JP4696663B2 (ja) | 除草用組成物 | |
| JP2003104809A (ja) | 除草剤組成物 | |
| CN1115960C (zh) | 除草剂组合物 | |
| CN1152610C (zh) | 除草组合物 | |
| JP4092455B2 (ja) | 除草剤組成物 | |
| CN1090452C (zh) | 除草组合物 | |
| JP4610783B2 (ja) | 除草剤 | |
| CN114145307A (zh) | 一种防治稻田杂草的除草组合物 | |
| CN106135217B (zh) | 一种除草组合物 | |
| CN1232612A (zh) | 除草剂组合物 | |
| JP4708053B2 (ja) | 除草用混合液剤 | |
| JP2021075477A (ja) | 除草剤組成物 | |
| CN115486460A (zh) | 一种含有Cyclopyranil和吡氟酰草胺的除草剂组合物 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CX01 | Expiry of patent term |
Granted publication date: 20021023 |
|
| CX01 | Expiry of patent term |