CN1216111A - Measurement device for determining properties of liquid - Google Patents

Measurement device for determining properties of liquid Download PDF

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Publication number
CN1216111A
CN1216111A CN97193773.7A CN97193773A CN1216111A CN 1216111 A CN1216111 A CN 1216111A CN 97193773 A CN97193773 A CN 97193773A CN 1216111 A CN1216111 A CN 1216111A
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CN
China
Prior art keywords
sensor
measuring instrument
sleeve portion
data recorder
described measuring
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Granted
Application number
CN97193773.7A
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Chinese (zh)
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CN1144043C (en
Inventor
埃德加·鲍斯
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ELBAGU MESS- und REGELUNGSTECHNIK GmbH
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ELBAGU MESS- und REGELUNGSTECHNIK GmbH
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    • GPHYSICS
    • G01MEASURING; TESTING
    • G01LMEASURING FORCE, STRESS, TORQUE, WORK, MECHANICAL POWER, MECHANICAL EFFICIENCY, OR FLUID PRESSURE
    • G01L19/00Details of, or accessories for, apparatus for measuring steady or quasi-steady pressure of a fluent medium insofar as such details or accessories are not special to particular types of pressure gauges
    • G01L19/14Housings
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01DMEASURING NOT SPECIALLY ADAPTED FOR A SPECIFIC VARIABLE; ARRANGEMENTS FOR MEASURING TWO OR MORE VARIABLES NOT COVERED IN A SINGLE OTHER SUBCLASS; TARIFF METERING APPARATUS; MEASURING OR TESTING NOT OTHERWISE PROVIDED FOR
    • G01D11/00Component parts of measuring arrangements not specially adapted for a specific variable
    • G01D11/24Housings ; Casings for instruments
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01DMEASURING NOT SPECIALLY ADAPTED FOR A SPECIFIC VARIABLE; ARRANGEMENTS FOR MEASURING TWO OR MORE VARIABLES NOT COVERED IN A SINGLE OTHER SUBCLASS; TARIFF METERING APPARATUS; MEASURING OR TESTING NOT OTHERWISE PROVIDED FOR
    • G01D9/00Recording measured values
    • G01D9/005Solid-state data loggers
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N33/00Investigating or analysing materials by specific methods not covered by groups G01N1/00 - G01N31/00
    • G01N33/18Water
    • G01N33/1886Water using probes, e.g. submersible probes, buoys
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N27/00Investigating or analysing materials by the use of electric, electrochemical, or magnetic means
    • G01N27/26Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating electrochemical variables; by using electrolysis or electrophoresis
    • G01N27/28Electrolytic cell components
    • G01N27/283Means for supporting or introducing electrochemical probes
    • G01N27/286Power or signal connectors associated therewith

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  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Food Science & Technology (AREA)
  • Medicinal Chemistry (AREA)
  • Analytical Chemistry (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Immunology (AREA)
  • Pathology (AREA)
  • Testing Or Calibration Of Command Recording Devices (AREA)
  • Measuring Fluid Pressure (AREA)

Abstract

The invention concerns a measurement device connected by electric leads to a power supply and a data-processing unit and designed to be immersed in a liquid, for instance ground water, to determine chemical and/or physical properties of the liquid. The device includes, housed in an essentially cylindrical casing, sensors and a data logger (5), the casing being made up of sections connected so that they can be detached from each other in the axial direction (3), viz: at one end of the casing, a section (2) housing the data logger (5), at the other end a pressure-measurement section (4) and, between them, a middle section (3) housing a sensor unit and fitted with through-flow openings (18). Either the pressure-measurement section (4) or the middle section (3) can be attached directly to the section (2) housing the data logger to make a liquidtight seal.

Description

Be used to find out the measuring instrument of liquid vehicle state parameter
This invention relates to is one and can immerses in liquid medium fully, and by electric wire can same supply unit and data treating apparatus connect together in order to the chemistry of finding out liquid vehicle and/or the measuring instrument of physical state parameter.
On a kind of measuring instrument (DE-94 04 359.0 U1), a measuring probe has a columniform detection body, is inserted into an adapter at its tail end.This adapter is special formed as the support of survey sensor, and making is that columniform survey sensor inserts its rearward end in the adapter equally.Its front end and measuring head are given prominence to downwards and are surrounded by a catch net through adapter and cover tube edge on the contrary.
This arrangement has a shortcoming, is very little measurement requirement on the one hand promptly, almost can only survey hydraulic pressure and water level, if reduce the expense of measuring probe at this point, can not bear generally speaking.On the other hand, when measuring 5 or more systematic parameter if desired, this measuring probe can't adapt to higher measurement requirement.
DE-25 31 784 C2 disclose the device of measuring a kind of pressure and temperature of medium in a small bore, wherein for measuring temperature the resistance with its resistance value of temperature change are installed, for gaging pressure is installed a pressure detector.They connect together with being located at the outer analytic unit of boring by measurement signal line.This device only is suitable for obtaining the measured value of temperature and pressure, as wants to measure 5 or more systematic parameter, and this device and its adaptive faculty are to satisfy high measurement.
DE 80 26 460U1 disclose a kind of comprehensive survey instrument, in order to measure the waste gas that produces with the oil heating with vapour, bivalve pipe and a thermopair with inner casing, shell has been installed on it, and this detection instrument is not suitable for finding out any one measured value in the liquid medium.
Task of the present invention provides an instrument of measuring the liquid vehicle state parameter, and it can expand to the measuring instrument of the complete various parameters of measurement from a cheap as far as possible measurement hydraulic pressure probe.
Task of the present invention is solved by the scheme that claim 1 limited, and improving of other will be illustrated in claim 2 to 18.
Be directly installed on the sleeve portion that has received data recorder or be installed under the middle circuit of encircling sensor unit by the pressure survey sleeve portion that device for pressure measurement selectively will be housed and make this measuring instrument reach very high dirigibility.
Because the pressure measurement sleeve portion can directly be contained on the sleeve portion that has received data recorder, under the situation that only needs gaging pressure,-normally connect together with measuring temperature, just can provide a fundamental measurement instrument dirt-cheap, and it can be extended at any time.
Its special benefits also is, can be equipped with a plurality of sensors in the sensor unit.They all appear its sensor head at a measurement plane.Wherein installable number of sensors and the arrangement in sensor unit are variable.
This measuring instrument can be a polymeter by a pressure-measuring device enlarging not only thus, and the measurement form can also adapt to user's requirement at any time.
If sensor has been equipped with storage chip, the operation check and correction of each survey sensor is determined to pass to data recorder with self-, the simply property extended of this measuring instrument and dirigibility have also obtained support extraly.So just, can abandon check and correction on the spot to sensor.
Be to reduce user's expense, sensor can be disassembled after replacement, make the potential electrode that consumed from its mechanical bracket with separate and load onto a last new potential electrode of putting forward electronics is connected.
Other advantage is presented in the description and accompanying drawing of back:
Fig. 1: an xsect that echos the measuring instrument of invention has the pressure survey and the sensor unit of its sleeve portion that is assembled with each other and installation.
Fig. 2: the xsect that has received the sleeve portion of data recorder.
Fig. 3: the xsect of intermediate casing part.
Fig. 4: the xsect of pressure survey sleeve portion.
Fig. 5: the xsect of pressure measurement range.
Fig. 6: the xsect that intermediate casing part and sensor unit are not installed in order to the measuring instrument of gaging pressure and temperature.
Fig. 7: received data recorder, had the xsect of sleeve portion of the pressure measurement range of the sensor unit of insertion and assembling, do not comprised intermediate casing part and pressure survey sleeve portion.
Fig. 8: the details on the last top of the sensor unit of an xsect is described.
Specifically, this measuring instrument 1 comprises that 12,1 of sleeve portion that are used to receive data recorder 5 is used for intermediate casing part 3 and 1 pressure survey sleeve portion 4 that is used to receive pressure measurement range 7 of receiving sensor unit 6.Sleeve portion 2 has one and the intermediate casing part 3 lower limb 9 similar terminals at oneself at oneself lower limb 8, make pressure survey sleeve portion 4 promptly can be installed on the lower limb 8 of the sleeve portion 2 that has received data recorder 5, also can be installed on the lower limb 9 of the intermediate casing part 3 that has received sensor unit 6.
Data recorder sleeve pipe 2 it and on the cable of outwards drawing connects together the top loaded onto a top and loaded onto a terminal cap 11; this cap is seated on the coboundary 10 of the sleeve portion 2 that has received data recorder 5, and provides reliable protection by a seal 14 for preventing that liquid from immersing.Seal 14 has two sealing sockets 12 and 13.They have been filled out O-shape ring respectively and have from then on been played the close effect of necessary envelope.Exist an insert 15 in the centre of seal 14, be used to install and outwards draw, at this cable that does not draw.This cable is on the one hand as data conductor, on the other hand as the power supply suppling wire of measuring instrument 1.
Cable can be with instrument casting together, with the reduction expense with play tight effect, perhaps also can insert wherein as situation about pointing out at this, makes cable different length can according to circumstances be installed and exchange each other.The power supply supply very practicably is in the outside of measuring instrument, can be used as power brick and together drops under the face of land, and the situation of measuring instrument that sinks to water level pipe when coexisting subsurface water measurement is the same.
Data recorder 5 itself is a columniform assembly.An important analog-digital converter is arranged in its body, the data-switching that enters as aanalogvoltage that it will be received becomes the digital measurement signal, as the intermediate storage of the digitized data of preservation, the data that stored can be passed to once more the computing machine of connecting outside again.Carrying out the desired element of writing name, address and control of process of measurement and conduction measurement data or with hardware or with the form of software writes for 5 li in data recorder.In addition, 1 unit can be installed in order to calculate also operational remaining power supply-1 battery that can take out or accumulator in data recorder 5.
1 prolongation that is positioned at lower limb 8 is arranged in order to assembling intermediate casing part 3 and pressure survey cannula portion 4 on the scope side of avoiding plug 15 of the sleeve portion 2 that has received data recorder 5.The connection of each sleeve portion is such as finishing by a screw thread, each sleeve portion must be reversed when mounted relatively, perhaps by a fixture, each sleeve portion is stayed on the fixture to stationkeeping each other, such as female or other form of being familiar with, a plurality of tube sections are fixed with each other by a thumb screw.
Because instrument often is used in and measures the channel of ground water diameter is in 2 ' the water level pipe, thus be necessary to allow the outer dia of measuring instrument as much as possible little, and in joint sleeve part 2,3 with considered this point at 4 o'clock.
Intermediate casing part 3 demonstrates an internal thread 16 at its end that faces data recorder.The external thread 8 ' that it is all the sleeve portion 2 that receives data recorder 5 installations connects together.The same external thread 17 of external thread 8 ' that a size and sleeve portion 2 are arranged at an end of the intermediate casing part 3 of having avoided data recorder.Intermediate casing part 3 indicates inflow entrance 18 in addition.They are microscler, and its major axis is parallel to the major axis of cylindrical measuring instrument.The inlet 19 that its body encloses that is distributed in that some circles are arranged near intermediate casing part 3 places in addition.
The external thread 17 that pressure survey sleeve portion 4 is expressed 1 internal thread 21 it and intermediate casing part 3 is in the top installed and has been connected intermediate casing part 3.Pressure survey sleeve pipe 4 connects together with the sleeve portion 2 that has received data recorder 5 through the external thread 8 ' of sleeve portion 2.
In addition, pressure survey sleeve portion 4 demonstrates an outlet 22 in its bottom surface, by this outlet medium and the pressure measurement range 7 that should measure are got in touch.
Pressure measurement range 7 has comprised a pressure detector 23 of forming with piezoelectric principle usually especially.It is positioned in the complete assemblies 24, connects together by a seam 25 and a flange 26 waterproofly.Flange 26 has two fluid- tight sealing sockets 27 and 28 that fill up with O-shape ring.For the air pressure measurement that makes the outside becomes possibility, can together a pressure equilibrium cable be introduced pressure measurement range 4 with cable, the other end of cable is connected with the air of ground surface.
Illustrated at Fig. 6, pressure measurement range 7 is how to be assembled in 4 li of pressure survey sleeve portions and how directly to link together with the sleeve portion 2 around data recorder 5.The internal thread 21 of sleeve pipe aspect pressure survey sleeve portion 4 is tightened with the external threads 8 ' that received the sleeve portion 2 of data recorder, and the pressure measurement range 7 in the sleeve pipe is pressed into a hermetic unit 29 similar to the seal 14 that is positioned at measuring instrument 1 top with its flange 26.Sealing wherein is guaranteed by the O-shape ring that is positioned in sealing socket 27 and 28.The wall one side that hermetic unit 29 faces sleeve portion 2 is to play waterproof effect by the O-shape ring that is positioned at sealing socket 30 and 31 equally.For the length that stops hermetic unit 29 to slip, in the installed inside of sleeve portion 2 one apart from bobbin 32, its side is with the lower end of data recorder 5, opposite side is tightened respectively with hermetic unit 29, to such an extent as to no matter be, or hermetic unit 29 or pressure measurement range 7 all has fixing seat in sleeve pipe separately apart from bobbin 32.Hermetic unit 29 directly can certainly be supported in the lower end of data recorder 5 and dwindle dangling of sleeve portion 2.
A MIN measuring instrument has been described in one as the arrangement introduced in Fig. 6, wherein in pressure survey sleeve portion 4 hygrosensor can also be installed extraly.In addition, can not in this arrangement, be equipped with other sensor.A pure broken floodometer is provided thus, its relative price advantage and very little casing size CS have been arranged.
For such floodometer is changed into a multiduty measuring instrument, at first back out pressure survey sleeve portion 4, then take off pressure measurement range 7 and its flange 26 from the extruding seat, take out hermetic unit 29 and apart from bobbin 32, make the measuring appliance part of a top, describe as Fig. 2, for the part that receives other is used.The sensor unit 6 of downside is inserted in the sleeve portion 2, thereby and connects the other socket of installing of the data recorder that coexists with oneself socket and coincide and guarantee the connection of sensor battery 6.The pressure measurement range 4 of lower end is inserted into one 34 li of the other receivers of casting shape of sensor battery 6 by means of its flange 26, describes as Fig. 7.It is to finish by introduce in the tubule of sensor unit 6 36 cable waterproofly that the electricity of pressure measurement range 4 is connected.Cable can be through a central socket that does not mark separately when carrying out the instrument reconstruction.
Inserting sensor unit 6 that motion injects data recorder lower end socket by one, to have reached sleeve portion 2 by two O-shapes rings in sealing socket 37 and 38 waterproof in the effect of data recorder.Sensor unit 6 is independent of intermediate casing part 3 and is mounted.The measuring instrument that is in the reconstruction of Fig. 7 is intactly surrounded by intermediate casing part 3 and pressure survey sleeve portion 4 in Fig. 1.
Sensor unit is introduced at Fig. 8 particularly 6.It consists essentially of at least one object 38.It supports sensor 39 waterproofly and is fitted into sleeve portion 2 by its outside seal seat 36 and 37 waterproofly.Settled one on the object 38 apart from pin 40, it has played the effect of baffle plate when sensor unit 6 inserts data recorder 5 lower ends.
Sensor unit 6 comprises a plurality of sensors 39.They are adjacent to be assembled in the object 38 of sensor unit 6.Size is the same so can be a measurement plane job basically for they, even form a sensor unit by two objects 38, crouches relatively, and the measuring head of the sensor of assigning is located substantially on the measurement plane.
Sensor 39 can be changed at every turn one by one, so just can bear owing to the different expenses that cause of support, has alleviated maintenance.Except, sensor 39 can also be assigned with hope, so just makes the seat of each sensor fixing, and each needed sensor 39 of arrangement that only needs.Can temporarily stop its use for the unwanted sensor of each concrete measurement.
It mainly is assembly dimerous that those independent sensors 39 demonstrate one.It can make original potential electrode 42 break away from a bobbin 43 around its neck, thereby can change potential electrode 42.Bobbin 43 has window 45 in its neck scope, it makes towards the passage of electrode 42 power supplys and becomes possibility, and helps the intermediate space between bobbin 43 and potential electrode 42 to inject sealing and support ointment.Potential electrode 42 is not only waterproof but also supported abreast in bobbin 43 like this.For distributing sealing better and supporting ointment, an inlet 45 ' has been installed in the side.In addition, the effect of window 45 also is, takes out sealing block once more, and is in medium admission impact electrode 42 under the pressure and the intermediate space between the bobbin 43 through window 45 usefulness, thereby drive sealing block out of, get ready for bobbin 43 receives new potential electrode 42.
After new potential electrode 42 is placed in bobbin 43, should be at first before inserting sealing block the electronics resistance welding of bobbin 42 be received on continuous group 33 ' of socket 33 by window 45 by window 45.Just there is no need to destroy whole sensor 39 after use by this method of work, only need use several weeks such as PH-acidity value measured sensor, but those are more expensive, major part directly comes into operation once more for the bobbin of metal.
Bobbin 43 makes sensor 39 waterproof in the object 38 of sensor unit 6 by the O-type ring that is placed in sealing socket 46 and 47, thereby has accomplished do not have liquid can flow into plug junction 33.
Individual other sensor 39 can also be equipped with a temperature survey extraly, and it only causes a very little additional expense, has special hope to be easy to be met.
For the use that makes sensor 39 has big as far as possible dirigibility, a storage chip can be installed in the scope of the window 45 of bobbin 43.It not only passes to data recorder the form of sensor and with the parameter that it should be measured at every turn, and successively win the operation calibration data.These data were passed to data recorder 5 and by it each measured value are sorted out as correcting the factor before the beginning of a measurement series, so just saved the necessity of calibrating on the spot.In addition, insert or newly add sensor 39 in changing of data recorder 5 and just need not to carry out any change one and comprise software.
For helping special accurate measurement, the influence each other that data recorder 5 can the recognition system state parameter and correct consequent measurement mistake, such as, thereby the too high density that can change of the nitrate content in the underground water changes measured pressure.Because the data that produced by gaging pressure have just hinted the up-set condition of water, so the correction factor that is adapted to high nitrate content has been installed.
If those concrete sensors 39 are not to be connected with data recorder 5 through socket 33, thereby but measurement data is united device through an inductance contactlessly transmits, it will more have advantage.Like this, data recorder is sent a carrier wave.The change of carrier wave is carried out analysis and utilization by the signal of being sent by sensor 39 as measuring-signal.
Not only ion-selective electrode 42 uses for sensor 39, particularly measuring nitrate, oxygen content, chloride, ammonium (base), when calcium and other earth alkali metal, can replenish at any time when needing more electrode 42 for the ion of measuring other, and measure battery and also be prepared as at any time and find out vectorial redox potentiality, electric conductivity and turbidity and serve.Might give in power supply in addition and arrange 1 optical conductor in the cable of measuring instrument 1, thereby and prove corresponding molecule with this vibration of thorn laser rays stimulation molecule or rotation by its power supply.This technology is specially adapted to prove hydrocarbon, especially as benzene, and toluene, polycyclic aromatic hydrocarbon such as xylol.They occur in the saturated with water of the refuse landfill of being everlasting, so its proof has very high importance.
Because measuring instrument 1 not only is applied to underground water, in spring or the circulating water, and be applied to the infiltration water field of refuse landfill, that is to say in the very mordant medium, so whole measuring instrument must be made to such an extent that have a corrosion resistivity.The high-alloy steel that contains high chromium and nickelic composition and titanium, molybdenum potpourri has been used in the instrument manufacturing.Use composition probably to be X6CrNiMoTi17122 (material number: 1.4571).Importantly, the associated parts of all except that sensor and medium are made by so erosion-resisting sturdy material fully.Because sleeve pipe must satisfy very high mechanical requirement, thus should make firmly as much as possible, and be subjected to being positioned at the support of the sensor 39 on a plane.In addition, whole measuring instrument is subjected to explosive-proof protector.
Certainly the flexible and changeable property of surveying instrument 1 not only is confined to sensor can have different quantity and carry out different arrangements, and process of measurement can select with hope, such as the examination time with measure at interval and can regulate by the program of organized data register 5 for each sensor 39 as required.

Claims (18)

1. one kind can immerse fully in the liquid medium and can link to each other with a data treating apparatus with a supply unit by electric wire, be used to measure the chemistry of liquid medium and/or the measuring instrument of physical state parameter, have and be integrated in a sensor and a data register (5) that is essentially in the columniform sleeve pipe, described sleeve pipe axially has at it can divide three parts that can join each other, the sleeve portion (2) that promptly holds data recorder (5) at the one end, pressure survey sleeve portion (4) and one are around sensor unit and the intermediate casing part of inflow entrance (18) is arranged, wherein, can selectively pressure survey sleeve portion (4) or intermediate casing partly be directly installed on the sleeve portion (2) that holds data recorder (5) to (3) hydraulic seal.
2. measuring instrument as claimed in claim 1 is characterized in that, described sensor unit can insert described intermediate casing part, and by means of the sealing between realization of the ring of the O shape in the sealing socket and data recorder.
3. measuring instrument as claimed in claim 1 or 2, it is characterized in that, described pressure survey sleeve portion both can seal and be installed in the sleeve portion that holds data recorder and also can seal and be installed in the intermediate casing part, and its electrical connection is to realize by the cable of sealably introducing the intermediate casing part.
4. as each described measuring instrument in the claim 1 to 3, it is characterized in that the pressure survey sleeve portion also comprises a hygrosensor, it is similar to pressure survey and is connected.
5. as each described measuring instrument among the claim 1-4, it is characterized in that, the intermediate casing part can not rely on sensor ground and installs, and connects together by the same screw thread of casting in the sleeve portion side of holding data recorder of the screw thread of a cast.
6. as each described measuring instrument among the claim 1-5, it is characterized in that it has a plurality of sockets connections of introducing data recorder hermetically, and a sensor unit comprises a plurality of sensors that can insert a measurement plane effectively.
7. measuring instrument as claimed in claim 6 is characterized in that, insertable sensor has a storage chip respectively, and it stores the measurement data correction factor that is obtained by manufacturer's calibration at least, and sends it to data recorder, the initialization that is used to measure.
8. as claim 6 or 7 described measuring instruments, it is characterized in that described memory chip stores is useful on the identification sensor kind and treats the data set of measured value kind.
9. as each described measuring instrument in the claim 6 to 8, it is characterized in that the layout of sensor in sensor unit is variable.
10. as each described measuring instrument in the claim 6 to 9, it is characterized in that, the sensor that number does not wait can be installed in sensor unit.
11., it is characterized in that sensor can be distinguished replacing individually as each described measuring instrument in the claim 6 to 10.
12. as each described measuring instrument in the claim 1 to 11, it is characterized in that, sensor has a cylinder-shaped sleeve that is fixedly linked with its Connection Element respectively, and around a potential electrode, this potential electrode hermetically but be removably mounted in the sleeve pipe in the mode of scope for this sleeve pipe.
13. measuring instrument as claimed in claim 12 is characterized in that, the potential electrode in the sleeve pipe is supported in the sealing block, and outside of sleeve has at least one and is installed on O shape ring in the sealing socket.
14. as each described measuring instrument in the claim 6 to 13, it is characterized in that, sleeve pipe has a neck that has window, and window wherein is used as welding potential electrode terminals, inserts and take out the passage of sealing block, and with being subjected to piezodielectric to impact the import of the sealing block of inserting.
15. as each described measuring instrument in the claim 6 to 14, it is characterized in that, sensor unit has two inserting surfaces that are used to insert sensor respect to one another at its end regions, and wherein the potential electrode of the sensor of settling relatively is located substantially in the same measurement face.
16., it is characterized in that data recorder is proofreaied and correct measured value according to influencing each other between the different conditions parameter of medium as each described measuring instrument in the claim 1 to 15.
17. as each described measuring instrument in the claim 6 to 16, it is characterized in that, sensor is equipped with ion-selective electrode, be used to measure the content of content, water hardness and other ionized particles of the positive ion of pH value, nitrate content, oxygen content, chloride ion content, ammonium ion content, calcium, in addition, sensor also is equipped with the measuring unit that is used for determining oxidation-reduction potential, conductivity and turbidity, and the molecular excitation that can cause by the energy that utilizes the exciting light definition is finished measurement.
18. as each described measuring instrument in the claim 6 to 17, it is characterized in that, can realize in contactless mode by inductive coupling with being electrically connected of sensor.
CNB971937737A 1996-03-15 1997-03-14 Measurement device for determining properties of liquid Expired - Lifetime CN1144043C (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE19610167.0 1996-03-15
DE19610167A DE19610167C1 (en) 1996-03-15 1996-03-15 Measuring device for determining state variables of a liquid medium

Publications (2)

Publication Number Publication Date
CN1216111A true CN1216111A (en) 1999-05-05
CN1144043C CN1144043C (en) 2004-03-31

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CNB971937737A Expired - Lifetime CN1144043C (en) 1996-03-15 1997-03-14 Measurement device for determining properties of liquid

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EP (1) EP0886777A1 (en)
CN (1) CN1144043C (en)
DE (1) DE19610167C1 (en)
WO (1) WO1997035190A1 (en)

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CN102197292B (en) * 2008-10-24 2013-11-06 恩德莱斯和豪瑟尔两合公司 Measuring device
CN108474758A (en) * 2015-12-18 2018-08-31 雷迪奥米特医学公司 Hybrid ionic carrier ion electrodes selective for improving the detection of the urea in blood
US11079352B2 (en) 2015-12-18 2021-08-03 Radiometer Medical Aps Mixed ionophore ion-selective electrode for the improved detection of urea in blood
US12038404B2 (en) 2015-12-18 2024-07-16 Radiometer Medical Aps Mixed ionophore ion-selective electrode for the improved dectection of urea in blood
CN107621276A (en) * 2016-07-15 2018-01-23 特斯托欧洲股份两合公司 The application of two metal wall regions of the housing of data logger and data logger

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CN1144043C (en) 2004-03-31
WO1997035190A1 (en) 1997-09-25
EP0886777A1 (en) 1998-12-30

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