CN1207317C - 在稳定的自由基和聚合引发剂存在下由乙烯基芳族单体聚合得到的抗冲击乙烯基芳族聚合物 - Google Patents
在稳定的自由基和聚合引发剂存在下由乙烯基芳族单体聚合得到的抗冲击乙烯基芳族聚合物 Download PDFInfo
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- CN1207317C CN1207317C CNB998093564A CN99809356A CN1207317C CN 1207317 C CN1207317 C CN 1207317C CN B998093564 A CNB998093564 A CN B998093564A CN 99809356 A CN99809356 A CN 99809356A CN 1207317 C CN1207317 C CN 1207317C
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- particle
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F279/00—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00
- C08F279/02—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00 on to polymers of conjugated dienes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L51/04—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to rubbers
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Graft Or Block Polymers (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
实 例 号 | ||||||
1(对比) | 2 | 3 | 4 | 5 | ||
不规则球粒分布 | 单峰 | 双峰 | 双峰 | 双峰 | 单峰 | |
当量直径为0.1~1μm的颗粒 | 面积% | 49 | 22 | 47 | 50 | 100 |
形态 | 胶囊+色拉米香肠 | 胶囊+色拉米香肠 | 胶囊+洋葱+迷宫 | 胶囊+洋葱+迷宫 | 胶囊 | |
当量直径为1~1.6μm的颗粒 | 面积% | 28 | 9 | 16 | 8 | - |
形态 | 色拉米香肠 | 色拉米香肠 | 洋葱+迷宫 | 洋葱+迷宫 | - | |
当量直径大于1.6μm的颗粒 | 面积% | 23 | 69 | 37 | 42 | - |
形态 | 色拉米香肠 | 色拉米香肠 | 迷宫 | 迷宫 | - |
Claims (45)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR98/06940 | 1998-06-03 | ||
FR9806940A FR2779437B1 (fr) | 1998-06-03 | 1998-06-03 | Polymere vinylaromatique choc par polymerisation d'un monomere vinylaromatique en presence d'un radical libre stable et d'un amorceur de polymerisation |
Publications (2)
Publication Number | Publication Date |
---|---|
CN1311804A CN1311804A (zh) | 2001-09-05 |
CN1207317C true CN1207317C (zh) | 2005-06-22 |
Family
ID=9526957
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CNB998093564A Expired - Fee Related CN1207317C (zh) | 1998-06-03 | 1999-05-31 | 在稳定的自由基和聚合引发剂存在下由乙烯基芳族单体聚合得到的抗冲击乙烯基芳族聚合物 |
Country Status (13)
Country | Link |
---|---|
US (1) | US6815500B1 (zh) |
EP (1) | EP1091988A1 (zh) |
JP (1) | JP4497392B2 (zh) |
KR (1) | KR100547453B1 (zh) |
CN (1) | CN1207317C (zh) |
AU (1) | AU3833299A (zh) |
CA (1) | CA2334096C (zh) |
FR (1) | FR2779437B1 (zh) |
HU (1) | HU227587B1 (zh) |
MX (1) | MXPA00011888A (zh) |
PL (1) | PL344449A1 (zh) |
TW (1) | TWI237644B (zh) |
WO (1) | WO1999062975A1 (zh) |
Families Citing this family (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
TW546311B (en) * | 1999-11-25 | 2003-08-11 | Ciba Sc Holding Ag | Composition and method for color improvement of nitroxyl containing polymers |
TWI225492B (en) * | 2000-09-25 | 2004-12-21 | Ciba Sc Holding Ag | Composition and process for enhancing controlled free radical polymerization |
CN101006112B (zh) * | 2003-02-05 | 2010-05-26 | 陶氏环球技术公司 | 由本体聚合方法生产的高光泽橡胶改性单亚乙烯基芳族聚合物 |
DE602004029138D1 (de) * | 2003-02-05 | 2010-10-28 | Dow Global Technologies Inc | Steuerung von teilchengrösse und morphologie in kautschukmodifizierten monovinylidenaromat-polymeren |
TW200602413A (en) * | 2003-12-24 | 2006-01-16 | Dow Global Technologies Inc | Thermally-reversible crosslinking of polymers |
ITMI20040752A1 (it) * | 2004-04-16 | 2004-07-16 | Polimeri Europa Spa | Procedimento per la preparazione di co polimeri vinilaromatici aggraffati su elastometro in modo controllato |
ITMI20042401A1 (it) * | 2004-12-16 | 2005-03-16 | Polimeri Europa Spa | Procedimento per la preparazione di co-polimeri vinilaromatici antiurto aggraffati su elastomero |
US20100125122A1 (en) * | 2007-04-25 | 2010-05-20 | Bouquet Gilbert C E | Process for the production of a (co)polymer composition by mediated free radical chain growth polymerization |
CN102532422B (zh) * | 2011-12-13 | 2013-12-25 | 江门市德山复合材料科技有限公司 | 用于不饱和树脂的不饱和酸酐改性液体丁腈橡胶增韧剂及其制备方法 |
TW202330677A (zh) | 2021-12-10 | 2023-08-01 | 義大利商佛沙里斯股份有限公司 | 橡膠強化的乙烯芳香族(共)聚合物及其製備方法 |
Family Cites Families (22)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE294493C (zh) | ||||
US4070419A (en) | 1975-12-01 | 1978-01-24 | Cosden Technology, Inc. | Polymerization of styrene |
US4146589A (en) | 1978-05-19 | 1979-03-27 | Monsanto Company | Method for preparing a monoalkenyl aromatic polyblend having a dispersed rubber phase as particles with a bimodal particle size distribution |
DE3035570A1 (de) | 1980-09-20 | 1982-05-06 | Basf Ag, 6700 Ludwigshafen | Schlagfeste thermoplastische formmasse |
US4334039A (en) | 1981-03-23 | 1982-06-08 | Monsanto Company | Process for preparing polymeric polyblends having a rubber phase as particles with a bimodal particle size distribution |
US4581429A (en) | 1983-07-11 | 1986-04-08 | Commonwealth Scientific And Industrial Research Organization | Polymerization process and polymers produced thereby |
DE3627639A1 (de) * | 1986-08-14 | 1988-02-18 | Basf Ag | Schlagfeste thermoplastische formmasse |
FR2629085B1 (fr) * | 1988-03-24 | 1992-09-04 | Atochem | Procede de fabrication de polybutadiene et preparation de resine vinylaromatique choc a partir de polybutadiene |
GB8920574D0 (en) | 1989-09-12 | 1989-10-25 | Dow Benelux | Monovinylidene aromatic polymers with improved properties and a process for their preparation |
US5264492A (en) | 1989-09-12 | 1993-11-23 | The Dow Chemical Company | Monovinylidene aromatic polymers with improved properties |
DD294493A5 (de) * | 1990-05-21 | 1991-10-02 | Buna Ag,De | Verfahren zur herstellung von thermoelastoplastischen materialien |
DE4018230A1 (de) | 1990-06-07 | 1991-12-12 | Basf Ag | Thermoplastische formmassen |
US5322912A (en) * | 1992-11-16 | 1994-06-21 | Xerox Corporation | Polymerization processes and toner compositions therefrom |
US5428106A (en) | 1993-09-02 | 1995-06-27 | The Dow Chemical Company | Rubber modified polystyrene |
DE4440675A1 (de) | 1994-11-14 | 1996-05-15 | Basf Ag | Verfahren zur Herstellung von kautschukmodifizierten Formmassen mittels in den Kautschuk eingebauten, bei thermischer Zersetzung Radikale bildenden Gruppen |
FR2730241B1 (fr) * | 1995-02-07 | 1997-02-28 | Atofina | Procede de fabrication d'une composition comprenant un polymere vinylaromatique et un caoutchouc par polymerisation en presence d'un radical libre stable |
US5627248A (en) | 1995-09-26 | 1997-05-06 | The Dow Chemical Company | Difunctional living free radical polymerization initiators |
US5775430A (en) | 1996-01-23 | 1998-07-07 | Mija Industries, Inc. | Electroluminescent signalling fire extinguisher |
EP0889918B1 (en) * | 1996-03-29 | 2000-03-22 | The Dow Chemical Company | In situ block copolymer formation during polymerization of a vinyl aromatic monomer |
CN1198750A (zh) * | 1996-06-04 | 1998-11-11 | 埃勒夫阿托化学有限公司 | 通过在稳定的自由基存在下进行1,3-二烯的控制的自由基聚合制备1,3-二烯的遥爪低聚物的方法 |
DE19637368A1 (de) * | 1996-09-13 | 1998-03-19 | Basf Ag | Flammgeschützte thermoplastische Formmassen |
FR2768739B1 (fr) * | 1997-09-19 | 2004-08-06 | Atochem Elf Sa | Polymere vinylaromatique choc obtenu a partir d'un caoutchouc porteur d'un groupement generateur d'un radical libre stable |
-
1998
- 1998-06-03 FR FR9806940A patent/FR2779437B1/fr not_active Expired - Fee Related
-
1999
- 1999-05-25 TW TW088108551A patent/TWI237644B/zh not_active IP Right Cessation
- 1999-05-31 MX MXPA00011888A patent/MXPA00011888A/es not_active IP Right Cessation
- 1999-05-31 JP JP2000552181A patent/JP4497392B2/ja not_active Expired - Fee Related
- 1999-05-31 AU AU38332/99A patent/AU3833299A/en not_active Abandoned
- 1999-05-31 EP EP99920946A patent/EP1091988A1/fr not_active Withdrawn
- 1999-05-31 CA CA002334096A patent/CA2334096C/fr not_active Expired - Fee Related
- 1999-05-31 HU HU0102303A patent/HU227587B1/hu not_active IP Right Cessation
- 1999-05-31 WO PCT/FR1999/001272 patent/WO1999062975A1/fr active IP Right Grant
- 1999-05-31 PL PL99344449A patent/PL344449A1/xx not_active Application Discontinuation
- 1999-05-31 CN CNB998093564A patent/CN1207317C/zh not_active Expired - Fee Related
- 1999-05-31 US US09/701,831 patent/US6815500B1/en not_active Expired - Fee Related
- 1999-05-31 KR KR1020007013609A patent/KR100547453B1/ko not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
TWI237644B (en) | 2005-08-11 |
MXPA00011888A (es) | 2002-04-24 |
US6815500B1 (en) | 2004-11-09 |
WO1999062975A8 (fr) | 2000-03-02 |
FR2779437A1 (fr) | 1999-12-10 |
EP1091988A1 (fr) | 2001-04-18 |
HUP0102303A2 (hu) | 2001-10-28 |
JP4497392B2 (ja) | 2010-07-07 |
CN1311804A (zh) | 2001-09-05 |
KR100547453B1 (ko) | 2006-02-01 |
HU227587B1 (en) | 2011-08-29 |
KR20010071372A (ko) | 2001-07-28 |
FR2779437B1 (fr) | 2004-10-15 |
JP2002517532A (ja) | 2002-06-18 |
PL344449A1 (en) | 2001-11-05 |
HUP0102303A3 (en) | 2002-06-28 |
WO1999062975A1 (fr) | 1999-12-09 |
CA2334096C (fr) | 2007-04-03 |
AU3833299A (en) | 1999-12-20 |
CA2334096A1 (fr) | 1999-12-09 |
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Address after: French pitot Patentee after: ARKEMA Address before: French Maputo Patentee before: ATOFINA |
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