CN1207031A - Hair colorant and application mixture for coloring human hair - Google Patents
Hair colorant and application mixture for coloring human hair Download PDFInfo
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- CN1207031A CN1207031A CN 96199496 CN96199496A CN1207031A CN 1207031 A CN1207031 A CN 1207031A CN 96199496 CN96199496 CN 96199496 CN 96199496 A CN96199496 A CN 96199496A CN 1207031 A CN1207031 A CN 1207031A
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Abstract
Solid hair colorants in powder or granulate form, containing at least one oxidation colorant intermediate product, and oxidising agent and usual cosmetic additives, which also neutrally contain at least one direct-dyeing vegetable colorant or henna, are characterized by excellent dyeing results with complete coverage of greying while caring for the hair. The agent is applied to the hair in the form of application mixtures prepared by mixing it with water.
Description
The use intermixture of the hair dyeing usefulness that the present invention relates to the solid hair dye and prepare thus.
As everyone knows, available vegetable colour in hair dye.At for example FR-OS 1,583,606, BE-OS 900,219, and GB-OS 2,190,104 and DE-PS 3829102 in the new development of above-mentioned hair dye is disclosed.By Germany Patent document DE-A1 4233874 as can be known, a kind of granulous hair toner wherein contains the vegetable colour that combines with synthetic direct dyes.
But there are some shortcomings in this known stain based on vegetable colour, and its gray covering power is unsatisfactory in many cases.
On the other hand, one skilled in the art will appreciate that available so-called oxidation dye dyeing.Infiltrating hair by the oxidation dye intermediate dyes.Wherein, oxidant and itself or react with other oxidation dye intermediate and generate real dyestuff.Like this, fine persistent tone can be obtained and also grizzled hair can be covered satisfactorily.Yet, owing to used oxidant, particularly continually under the operating position, can cause adverse influence to hair structure, even the infringement hair.
Task according to the present invention both provided can cover grizzled hair satisfactorily, can not cause the hair dye of adverse effect again to hair structure.
Be surprisingly found out that,, when containing a kind of direct vegetable colour or plant product neutrality mignonettetree simultaneously, gratifying coloration just can be provided and cover grizzled hair, simultaneously hair structure is had no adverse effects based on the stain of oxidation dye intermediate.
The purpose of this invention is to provide powdery or granulous solid hair dye, it contains a kind of oxidation dye intermediate at least, and the additive of a kind of oxidant and the usefulness of improving looks usually is characterized in that it at least also contains a kind of direct vegetable colour or neutral mignonettetree.
Though product of the present invention is specially adapted to hair dyeing.But it also is applicable in other dyeing fields in principle.For example, also be applicable to textile fabric or woolen dyeing.
Hair dye according to the present invention is a powdery or granular, and it contains the oxidation dye intermediate of forcing component as first.
According to one embodiment of the invention, hair dye of the present invention only contains a kind of oxidation dye intermediate of developer type.
Used developer composition according to the present invention is uncle's aromatic amine or assorted arylamine, and other functional group is wherein arranged in its para-position.For example, right-the phenyl diamidogen, right-toluenediamine, para-aminophenol, 3-methyl-4-amino-phenol, 2-(2-ethoxy)-1,4-aminobenzene, 2,4,5,6-tetraminopyrimidine, 2-hydroxyl-4,5,6-Triaminopyrimidine, 2,5-diamino-pyridine and derivant thereof.According to the present invention, they can also have described other, contain one or more as OH base, NH
2The base, NHR is basic or NR
1R
2The chemical compound of the functional group of base, R wherein, R
1With R
2Can represent the alkyl substituent that contains the 1-4 carbon atom independently of each other.
Preferably also contain at least a coupling agent composition according to hair dye of the present invention.According to hair dye of the present invention, preferably contain more than one developer composition and more than one coupling agent composition.
According to the present invention preferred coupling agent composition be alpha-Naphthol, resorcinol, 4-chloro resorcinol, 2-methylresorcinol ,-amino-phenol ,-phenylenediamine, meta-toluenediamine, 1,5-or 1, the derivant of 7-dihydroxy naphthlene, 5-amino-2-methyl phenol, 6-amino-2-methyl phenol or above-claimed cpd.Above-mentioned coupling agent composition both can use separately, also can be used in combination with above-mentioned or well known by persons skilled in the art other coupling agent compositions.
According to the present invention, above-mentioned amino developer composition and the coupling agent composition of containing also can be with the form of its salt, especially its hydrochlorate and sulfate and used.
The mandatory composition of another of hair dye of the present invention is an oxidant.
As oxidant, can select the additive compound of hydrogen peroxide and carbamide, melamine, potassium perborate and Dexol for use, and the mixture of forming by above-mentioned hydrogen peroxide additive compound and potassium persulfate, sodium persulfate or ammonium peroxydisulfate.
According to the present invention, potassium perborate, particularly Dexol can use separately, and use also can combine with other oxidant.
By one embodiment of the invention, hair dye also contains a kind of direct vegetable colour.The latter generally is powdery, and it is normally by with different plant parts, as stem, flower, leaf, root, fruit and seed grind and sieve after make.The plant material that is suitable for of the present invention is, Chamomile, late autumn Herba Tagetis Patulae, Flos Hibisci, Flos Carthami, Flos Helianthi, Folium Juglandis, mignonettetree, the blue leaves of Chinese scholartree, Fructus rhois chinensis, Ramulus Sambuci Williamsii, Rubiaceae root (Radix Rubiae, Asperula orientalis, Herba Galii Teneri), Curcuma root, LIANGEN and big xanthorrhiza, Semen adenantherae pavoninae, Lignum Sappan, brasiletto, Caesalpinia echinata wood, alder, Strawberry Tree and sumac bark, Folium seu Cortex Nerii seed, Stigma Croci chapiter, Rhizoma Curcumae Longae rhizome piece and Rhizoma Curculiginis grass roots, sloe fruit, goldspink spray and yellow mignonette, lichens and Herba Solidaginis whole plant.
The most suitable vegetable colour is the mignonettetree dyestuff.Red mignonettetree is made up of the leaves of white mignonettetree (Lawsonia alba), sour jujube shape mignonettetree (Laiosonia spinosa) and/or stingless mignonettetree (Lawsoniainermis) plant of drying, pulverizing.So-called black mignonettetree is from Isatis indigotica Fort. (painted Isatis indigotica Fort. (Isatistimctoria)) leaf, and is to mix with mignonettetree to use and obtain low key tone in the red color range.
In addition, other preferred vegetable colour is selected from that Endocarpium Juglandis, Chinese scholartree indigo plant, Chamomile, logwood and black alder bark make.
Neutral mignonettetree also can be used as the substitute of above-mentioned vegetable colour.
Above-mentioned neutral mignonettetree is leaves and/or the bark by powdered ear shape Acacia farnesiana Willd. (Cassia auriculata), and it also can be to be made by the leaf of lotus plant.
Though a kind of vegetable colour or neutral mignonettetree must be arranged in the hair dye of the present invention, and the present invention also comprises the stain that contains these two kinds of compositions.
Hair dye of the present invention can also contain the synthetic direct dyes as random composition, so that make color change.
The preferred synthetic direct dyes of the present invention, be red 3 (the HC Red No3) of 4-hydroxyl third amino-3-nitro phenol, HC, N, N '-two-(2-ethoxy)-2-nitro-p-phenylenediamine, HC indigo plant 2 (HC Blue No2), HC Huang 2 (HC Yellow No2), HC Huang 12 (HC YellowNo12), HC indigo plant 2 (HC Blue No 12) and 2-amino-6-chloro-4-nitrophenol.
The oxidant intermediate content that contains in the hair dye of the present invention based on total solid hair dye, is preferably 1-10% (weight).
Contained oxygenate content in the hair dye of the present invention also based on total solid hair dye, is preferably 10-35% (weight).
The contained powdered plant content that contains dyestuff based on total solid hair dye, can be 3-25% (weight) in the hair dye of the present invention, is preferably 5-25% (weight), or 5-15% (weight) preferably.
The content of the neutral mignonettetree in the hair dye in the related embodiment of the present invention based on total solid hair dye, is at least 25% (weight).Yet the percentage composition of neutral mignonettetree must not surpass 70% (weight).The preferable range of above-mentioned mignonettetree content is 40-65% (weight), and 50-60% (weight) preferably.
If hair dye of the present invention is when existing with powdery, because the character of each composition just may form undesirable dust scattering.This will not only have problem when use level, and the working condition of hair salon is also had problem.
In the preferable embodiment of the present invention, can carry out specific dust in conjunction with processing to hair dye of the present invention.
This can implement by spraying a kind of inert organic compound.Described chemical compound can at room temperature be fluid, or even is solid chemical compound in room temperature.Can fluidisation as long as it heats under Moderate High Temperature.Usually, select for use and have the solid compounds that is lower than 50 ℃ of fusing points.
For in conjunction with dust, the inertia organic substance preferably is sprayed onto on the powdered hair dye.
As above-mentioned dust bonding agent can be paraffin, vegetable oil, animal oil or artificial oil, for example low-melting wax.Other compositions that are suitable for can also comprise triglyceride and aliphatic alcohol.The most suitable dust bonding agent be paraffin oil, fusing point be 40-50 ℃ paraffin, polysiloxanes, as dimethyl polysiloxane, octyl group-capric acid-triglyceride, octyldodecanol and Cera Flava.
The oil in the hair dye of the present invention or the content of wax based on the hair dye total amount, are 1-30% (weight), especially 7-15% (weight).
Hair dye of the present invention can also contain melon ear powder, sodium alginate, arabic gum, guar gum or the card as thickening agent in addition as cling to (caraba) glue, pectin, cellulose derivative, as methylcellulose and hydroxy methocel, hydroxyl-propyl methocel, carboxymethyl cellulose and various polymer, particularly acrylic acid derivative.Can also use inorganic thickening agent, as Bentonite and/or silicic acid.The content of this thickening agent based on the hair dye total amount, is 0.1-5% (weight), especially 0.5-3% (weight).
Above-mentioned hair dye can also contain positive and amphoteric polymer, film forming anionic property and nonionic polymer, and surfactant or its mixture, and its every kind content is 0.1-5% (weight).
Above-mentioned surfactant can be the alkylphenol of soap, benzene sulfonamide acid esters, alkyl naphthalene sulfonic acid ester, fatty alcohol sulfate or aliphatic ether sulfuric ester and aliphatic alcohol sulphonic acid ester, quaternary ammonium compound, fatty diglycollic amide, polyethoxylated or polyglycereol esterification.The content of the surfactant in the hair dye of the present invention based on the hair dye total amount, is 0.1-25% (weight).Be preferably 0.1-15% (weight).
At last, hair dye of the present invention also can add any other additive that is common to hair dye.Particularly infiltrate agent, separating medium (Sesquestroermittel), antioxidant, buffer agent and flavouring agent.
Another object of the present invention is the method for preparing powdery or granular hair dye.Wherein, oxidation dye intermediate, oxidant, vegetable colour and/or neutral mignonettetree are mixed fully, in case of necessity, can add the additive that is common to hair dye.And under constantly stirring, on the pulverulent mixture of above-mentioned gained, spray inert organic compound, make latter's fluidisation by heating in case of necessity.Then, make the pulverulent mixture of above-mentioned gained granular.
Before use, by adding an amount of water, be called the use intermixture by hair dye of the present invention to form the pasty state dyestuff.
Above-mentioned use intermixture preferably is made up of the hair dye of the present invention of 15-25% (weight) and the water of 75-85% (weight).In a preferable embodiment of the present invention, be adjusted in the pH of existing acid in the hair dye or alkali to 5.0-12.0 by suitable interpolation acid or alkali.For this reason, can use the carbonate or the alkali-metal silicate of acid, hydroxide, alkali metal or the alkaline-earth metal of organic or inorganic.
Above-mentioned use mixture can be coated on wet or dried.According to the present invention, preferably be coated in to do and send out.
Embodiment
1. the application of hair dye of the present invention
Make the hair dye of the present invention of 80 grams and 320 milliliters hot water be mixed into the paste of easily smearing and make a kind of use mixture.Then, with hairbrush fast and fully from the root to the termination, be coated in driedly, do not wash in advance, on the tippet long hair immediately above-mentioned hair dyeing paste.And in the fine just coating thinly at last of temples.Wherein, have to be noted that promptly and must apply whole hairs well fully with above-mentioned hair dyeing paste.Then, with the cover medicated cap hair cover cap is lived, the profile so that the cover medicated cap links closely, and fixing like this makes it can landing.(about 40 ℃) make and stay dying of sending out and apply paste and covered 30 minutes like this under heating condition.After this, will cover medicated cap and unload, and use tap water (30 ℃) will stay hair dyeing paste cleaning down on the hair then.Last shampoo hair, and water flushing make hair and scalp clean fully.
2. preparation embodiment
2.1 powdered hair dye
0.10kg resorcinol
0.10kg 1-hydroxyl-3-aminobenzene
0.15kg 2-amino-3-pyridone
0.10kg 4-hydroxyl third amino-3-nitre phenol
0.15kgHC yellow 12
0.35kg 2-methylresorcinol
1.20kg 2,5-diaminotoluene sulphuric acid ester
1.00kg it is indigo
2.00kg Endocarpium Juglandis
4.00kg red mignonettetree
54.85kg neutral mignonettetree
23.00kg Dexol
5.00kg carboxymethyl cellulose.
92.00 kilograms said mixture is put into a blender (for example Lodige (Lodge) blender) mix, then spray 8.00 kilograms paraffin oil (35mPa*s is 20 ℃ of measurements) to it.
The warm water (40-50 ℃) of the hair dye of 40 grams with 160 grams is mixed, to form the paste that to smear.Then, under 40 ℃, the gained mixture is coated in 50% with hairbrush and is greyish white last 30 minute of light brown hair.Rinse out the paste of staying on the hair then, shampoo is sent out and drying.After the processing, make and contain 50% gray light brown hair originally and dye the brown tone of uniform weak coffee.
2.2 powdered hair dye
0.15kg resorcinol
0.10kg 1-hydroxyl-3-aminobenzene
0.15kg 2-amino-3-pyridone
0.15kg 4-hydroxypropyl amino-3-nitro phenol
0.10kg HC Huang 12
0.30kg 2-methylresorcinol
1.25kg 2,5-diaminotoluene sulphonic acid ester
1.00kg Chamomile
1.50kg black mignonettetree
2.50kg red mignonettetree
60.80kg neutral mignonettetree
20.00kg Dexol
5.00kg carboxymethyl cellulose.
93.00 kilograms said mixture is put into a blender (as the Lodge blender) mix, spray 7.00 kilograms paraffin oil (15mPa*s is 20 ℃ of measurements) then to it.
The warm water (40 °-50 ℃) of the hair dye of 40 grams with 160 grams is fully mixed, to form the intermixture of easily smearing of using.Then, under 40 ℃, intermixture is coated in it with hairbrush and accounted for for 50% gray dark golden yellow hair last 30 minute.Rinse out the application mixture of staying on the hair then, shampoo is sent out, and dry.After the processing, contained 50% gray dark golden yellow hair originally and dyed uniform chestnut color tone.
2.3 powdered hair dye
0.30kg resorcinol
0.10kg 1-hydroxyl-3-aminobenzene
0.15kg 2-amino-3-pyridone
0.15kg HC Huang 12
0.45kg 2-methylresorcinol
2.00kg 2,5-diaminotoluene sulphonic acid ester
1.50kg Chamomile
2.00kg black alder bark
3.50kg red mignonettetree
52.85kg neutral mignonettetree
22.00kg Dexol
5.00kg carboxy methyl cellulose.
A blender is put in 90.00 kilograms above-mentioned mixing to mix as (Lodge blender).Spray octyl group-capric acid triglyceride of 10.00 kilograms then to it.
The warm water (40-50 ℃) that the hair dyes of 40 grams and 160 are restrained fully mix, the paste that is easy to smear with formation.Then,, under 40 ℃, this mixture is coated in accounted for for 50% gray burnt umber hair last 30 minute with hairbrush.Then, rinse out the paste of staying on the hair, shampoo is sent out, and dry.After the processing, making has 50% gray burnt umber hair to dye the brown tone of uniform dark brown originally.
3.4 powdery hair dye
0.35kg resorcinol
0.10kg 1-hydroxyl-3-aminobenzene
0.25kg 2-amino-3-pyridone
0.30kg 4-hydroxypropyl amino-3-nitro phenol
0.10kgHC yellow 12
0.45kg 2-methylresorcinol
2.25kg 2,5-diaminotoluene sulphuric acid ester
1.00kg Lignum Sappan
1.00kg it is indigo
1.00kg Endocarpium Juglandis
57.20kg neutral mignonettetree
22.00kg Dexol
5.00kg carboxymethyl cellulose.
The 91.00kg said mixture is put into a blender (Lodge blender) to mix.Spray the 9.00kg octyldodecanol to it then.
The warm water (40-50 ℃) of the hair dye of 40 grams with 160 grams is fully mixed, to form the paste of easily smearing.Then,, under 40 ℃, said mixture is coated in grizzled hair accounts for last 30 minute of light brown hair of 50% with hairbrush.Then, rinse out the paste of staying on the hair, shampoo is sent out and is dry.After the processing, make to contain 50% gray light brown hair originally and dye uniform dark bay tone.
3.5 powdery hair dye
0.2kg resorcinol
0.15kg 1-hydroxyl-3-aminobenzene
0.01kg 4-hydroxypropyl amino-3-nitro phenol
0.05kg 2-amino-6-chloro-4-nitrophenol
0.40kg 2-methylresorcinol
0.90kg 2,5-diaminotoluene sulphuric acid ester
1.50kg Lignum Sappan
1.00kg Chamomile
6.00kg red mignonettetree
56.29kg neutral mignonettetree
21.00kg Dexol
5.00kg carboxymethyl cellulose
92.50 kilograms said mixture is put into a blender (Lodge blender) to mix.Spray dimethyl-polysiloxanes of 7.50 kilograms then to it.
The warm water (40-50 ℃) of the hair dye of 40 grams with 160 grams is fully mixed, to form the paste of easily smearing.Then, under 40 ℃, mixture is coated in grizzled hair with hairbrush and accounts for last 30 minute of medium golden yellow hair of 80%.Then, rinse out the paste of staying on the hair, shampoo is sent out, and dry.After the processing, make to contain 80% gray medium golden yellow hair originally, dye uniform medium golden yellow tone.
3.6 powdery hair dye
0.10kg resorcinol
0.10kg 1-hydroxyl-3-aminobenzene
0.15kg 2-amino-3-pyridone
0.10kg4-hydroxypropyl amino-3-nitro phenol
0.15kgHC yellow 12
0.35kg 2-methylresorcinol
1.20kg 2,5-diaminotoluene sulphuric acid ester
61.85kg neutral mignonettetree
23.00kg Dexol
5.00kg carboxymethyl cellulose
92.00 kilograms said mixture is put into a blender (Lodge blender) to mix.Spray 8.00 kilograms paraffin oil (35mPas. is 20 ℃ of measurements) then to it.
The warm water (40-50 ℃) of the hair dye of 40 grams with 160 grams is fully mixed, to form the paste of easily smearing.Then, under 40 ℃, mixture is coated in grizzled hair with hairbrush and accounts for last 30 minute of light brown hair of 50%.Then, rinse out the paste of staying on the hair, shampoo is sent out, and dry.After the processing, make to contain 50% gray light brown hair originally and dye the brown tone of uniform light cigarettes.
3.7 powdery hair dye
0.15kg resorcinol
0.10kg 1-hydroxyl-3-aminobenzene
0.15kg 2-amino-3-pyridone
0.15kg 4-hydroxypropyl amino-3-nitro phenol
0.10kg HC Huang 12
0.30kg 2-methylresorcinol
1.25kg 2,5-diaminotoluene sulphuric acid ester
65.80kg neutral mignonettetree
20.00kg Dexol
5.00kg carboxymethyl cellulose
93.00 kilograms said mixture is put into a blender (Lodge blender) to mix.Spray 7.00 kilograms paraffin oil (15mPas is 20 ℃ of measurements) then to it.
The warm water (40-50 ℃) of the hair dye of 40 grams with 160 grams is fully mixed, to form the paste of easily smearing.Then, under 40 ℃, mixture is coated in grizzled hair with hairbrush and accounts for last 30 minute of medium golden yellow hair of 50%.Then, rinse out the paste of staying on the hair, shampoo is sent out, and dry.After the processing, make to contain 50% gray medium golden yellow hair originally, dye uniform chestnut color tone.
3.8 powdery hair dye
0.30kg resorcinol
0.10kg 1-hydroxyl-3-aminobenzene
0.15kg 2-amino-3-pyridone
0.15kg HC Huang 12
0.45kg 2-methylresorcinol
2.00kg 2,5-diaminotoluene sulphuric acid ester
59.85kg neutral mignonettetree
22.00kg Dexol
5.00kg carboxymethyl cellulose
90.00 kilograms said mixture is put into a blender (Lodge blender) mix, spray octyl group-capric acid triglyceride of 10.00 kilograms then to it.
The warm water (40-50 ℃) of the hair dye of 40 grams with 160 grams is fully mixed, to form the paste of easily smearing.Then,, under 40 ℃, mixture is coated in grizzled hair accounts for last 30 minute of burnt umber hair of 50% with hairbrush.Then, rinse out the paste of staying on the hair, shampoo is sent out, and dry.After the processing, make to contain 50% gray burnt umber hair originally and dye uniformly dark cocoa tone.
3.9 powdery hair dye
0.50kg resorcinol
0.20kg 1-hydroxyl-3-aminobenzene
0.10kg 2-amino-3-pyridone
0.45kg 2-methylresorcinol
2.25kg 2,5-diaminotoluene sulphuric acid ester
60.50kg neutral mignonettetree
22.00kg Dexol
5.00kg carboxymethyl cellulose
91.00 kilograms said mixture is put into a blender (Lodge blender) mix, spray 9.00 kilograms octyldodecanol then to it.
The warm water (40-50 ℃) of the hair dye of 40 grams with 160 grams is fully mixed, to form the paste that to smear.Then,, under 40 ℃, mixture is coated in grizzled hair accounts for last 30 minute of light brown hair of 50% with hairbrush.Then, rinse out the paste of staying on the hair, shampoo is sent out, and dry.After the processing, make to contain 50% gray light brown hair originally and dye uniform burnt umber tone.
3.10 powdery hair dye
0.20kg resorcinol
0.15kg 1-hydroxyl-3-aminobenzene
0.10kg 4-hydroxypropyl amino-3-nitro phenol
0.05kg 2-amino-6-chloro-4 nitrophenols
0.40kg 2-methylresorcinol
0.90kg 2,5-diaminotoluene sulphuric acid ester
64.79kg neutral mignonettetree
21.00kg Dexol
5.00kg carboxymethyl cellulose
92.50 kilograms said mixture is put into a blender (Lodge blender) to mix.Spray dimethyl-polysiloxanes of 7.50 kilograms then to it.
The warm water (40-50 ℃) of the hair dye of 40 grams with 160 grams is fully mixed, to form the paste that to smear.Then,, under 40 ℃, mixture is coated in grizzled hair accounts for last 30 minute of light golden rod yellow hair of 80% with hairbrush.Then, rinse out the paste of staying on the hair, shampoo is sent out and is dry.After the processing, make to contain 80% gray light golden rod yellow hair originally and dye uniform medium golden yellow tone.
Powdery or granular solid hair dye contain a kind of oxidation dye intermediate at least, a kind of oxidant and be common to the adjuvant of beauty treatment, and in addition, it has a kind of direct vegetable colour or neutral mignonettetree at least.It has the Color that with flying colors grizzled hair is covered fully, and hair is had higher nursing.Stain is to be coated on the hair with the form of mixing made use intermixture by water and preparation.
Claims (17)
1. powdery or granulous solid hair dye contain a kind of oxidation dye intermediate at least, and a kind of oxidant and be common to the adjuvant of beauty treatment is characterized in that it contains a kind of direct vegetable colour or neutral mignonettetree at least.
2. according to the hair dye of claim 1, it is characterized in that, contain at least a color composition and at least a coupling agent as the oxidation dye intermediate.
3. according to the hair dye of claim 1 or 2, it is characterized in that above-mentioned developer can be selected from p-phenylenediamine (PPD), to toluenediamine, 2-(2-ethoxy)-1,4-diaminobenzene, para-aminophenol, 3-methyl-4-amino-phenol, 2,4,5,6-tetraminopyrimidine and 2-hydroxyl-4,5, the 6-Triaminopyrimidine.
4. according to the hair dye of claim 2 or 3, it is characterized in that, above-mentioned coupling agent can be phenol between alpha-Naphthol, resorcinol, 4-chlorine, 2-methylresorcinol ,-amino-phenol, m-diaminobenzene., toluylenediamine, 1,5 or 1,7-dihydroxy naphthlene, 5-amino-2-methyl phenol or 6-amino-2 methylphenol.
According to one of among the claim 1-4 hair dye, it is characterized in that above-mentioned oxidant is a Dexol.
6. according to the hair dye one of among the claim 1-5, it is characterized in that above-mentioned vegetable colour can be red mignonettetree, black mignonettetree, Endocarpium Juglandis, Chinese scholartree indigo plant, Chamomile, Lignum Sappan and black alder.
7. according to the hair dye one of among the claim 1-6, it is characterized in that it also contains a kind of synthetic direct dyes.
8. according to the hair dye of claim 7, it is characterized in that, above-mentioned synthetic direct dyes is selected from red 3, the N of 4-hydroxyl third amino-3-nitro phenol, HC, N '-two-(2-ethoxy)-2-nitro-p-phenylenediamine, HC indigo plant 2, HC Huang 2, HC Huang 12, HC blue 12 and 2-amino-6-chloro-4-nitrophenol.
9. according to the hair dye one of among the claim 1-8, it is characterized in that, based on the content of solid hair dye total amount oxidation dye intermediate, is 1-10% (weight).
10. according to the hair dye one of among the claim 1-9, it is characterized in that based on solid hair dye total amount, the content of oxidant is 10-35% (weight).
11. the hair dye according to one of among the claim 1-10 is characterized in that based on solid hair dye total amount, the content of vegetable colour is 5-20% (weight).
12. the hair dye according to one of among the claim 1-11 is characterized in that based on solid hair dye total amount, the content of neutral mignonettetree is 40-65% (weight), and is advisable with 50-60% (weight).
13. the hair dye according to one of among the claim 1-12 is characterized in that it contains the inert organic compound that a kind of fusing point is lower than 50 ℃, its content based on solid hair dye total amount, is 1-30% (weight).
14. the hair dye according to claim 13 is characterized in that, above-mentioned inert organic compound can be selected from paraffin oil, triglyceride, aliphatic alcohol and polysiloxanes.
15. the use intermixture according to being used to have hair dyed is characterized in that, hair dye that one of contains among the claim 1-14 of 15-25% weight and the water of 85-75% (weight).
16. the use intermixture according to claim 15 is characterized in that, its pH value is 5.0-12.0.
17. according to the powdery one of among the claim 1-14 or the preparation method of granular hair dye, it is characterized in that, with the oxidation dye intermediate, oxidant, vegetable colour and/or neutral mignonettetree, and in case of necessity and the additive that is common to beauty treatment fully mix together.Then, under constantly stirring, in above-mentioned pulverulent mixture, spray a kind of inert organic compound, heat the latter in case of necessity and make its fluidisation and change into the gained pulverulent mixture granular where necessary.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 96199496 CN1207031A (en) | 1996-01-05 | 1996-12-19 | Hair colorant and application mixture for coloring human hair |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19600221.4 | 1996-01-05 | ||
| CN 96199496 CN1207031A (en) | 1996-01-05 | 1996-12-19 | Hair colorant and application mixture for coloring human hair |
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| Publication Number | Publication Date |
|---|---|
| CN1207031A true CN1207031A (en) | 1999-02-03 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 96199496 Pending CN1207031A (en) | 1996-01-05 | 1996-12-19 | Hair colorant and application mixture for coloring human hair |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103919705A (en) * | 2014-04-29 | 2014-07-16 | 张显文 | Composite hair dyeing powder prepared from indigofera tinctoria plant |
| CN104146911A (en) * | 2008-11-28 | 2014-11-19 | 株式会社太平洋 | Composition for oxidative dyeing of keratin fibers |
| CN104800108A (en) * | 2014-11-20 | 2015-07-29 | 折改梅 | Preparation of constituents of cortex juglandis mandshuricae and manufacturing method of different-colored hair dyes |
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1996
- 1996-12-19 CN CN 96199496 patent/CN1207031A/en active Pending
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104146911A (en) * | 2008-11-28 | 2014-11-19 | 株式会社太平洋 | Composition for oxidative dyeing of keratin fibers |
| CN104127332B (en) * | 2008-11-28 | 2017-04-12 | 株式会社太平洋 | Composition for oxidative dyeing containing natural materials |
| CN103919705A (en) * | 2014-04-29 | 2014-07-16 | 张显文 | Composite hair dyeing powder prepared from indigofera tinctoria plant |
| CN104800108A (en) * | 2014-11-20 | 2015-07-29 | 折改梅 | Preparation of constituents of cortex juglandis mandshuricae and manufacturing method of different-colored hair dyes |
| CN104800108B (en) * | 2014-11-20 | 2018-04-10 | 折改梅 | The preparation of pericarpium juglandis pigment composition and its preparation method of multi-color system hair dye |
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