CN1198581C

CN1198581C - Cleansing articles for skin and/or hair which also deposits skin care actives

Info

Publication number: CN1198581C
Application number: CNB998054186A
Authority: CN
Inventors: L·D·阿巴卡瑞斯; D·M·穆卡提; G·E·戴克尼尔
Original assignee: Procter and Gamble Ltd
Current assignee: Procter and Gamble Ltd; Procter and Gamble Co
Priority date: 1998-04-24
Filing date: 1999-04-12
Publication date: 2005-04-27
Anticipated expiration: 2019-04-12
Also published as: AU756691B2; BR9909629A; AU2952499A; CA2332948A1; KR20010043002A; KR100450333B1; WO1999055303A1; CN1298293A; EP1071396A1; JP2002512944A

Abstract

The present invention relates to a substantially dry, disposable, personal cleansing article useful for both cleansing the skin or hair and delivering skin care actives onto the skin or hair. These articles are used by the consumer by (i) wetting the dry article with water and (ii) generating lather by subjecting the wetted article to mechanical forces, e.g., rubbing. The article comprises a water insoluble substrate, a lathering surfactant, and a skin care active component. Preferably, the articles of the present invention further comprise a deposition aid and/or a conditioning component.

Description

Be used for cleaning skin and/or hair and the skin care activity thing is deposited on cleaning article on skin and/or the hair

Affiliated field

The present invention relates to can cleaning skin or hair the skin care activity thing can be transported to disposable personal cleansing articles on skin or the hair, substantially dry again.Need with this dried product of water-wet when the user uses this based article, and produce foam, skin and this are produced foamy goods contact, method cleaning skin routinely.Comprise water-insoluble substrate in these goods, at least a foaming surface active agent and at least a skin care activity thing.

Adopt substrate can promote the foaming characteristic of low level of surfactant, promote sanitary characteristics and Exfoliating Scrub effect, optimize the conveying and the deposition of skin care activity composition, and required characteristic such as Density, thickness and volume can be provided.Therefore, the present invention adopts substrate with desirable characteristics, the surfactant (thereby zest is low) of using low content just can provide excellence is transported to the skin care activity thing effect on skin or the hair.

The present invention also comprises and contains the multiple goods that are used for being transported to the skin conditioning agent of skin or hair.

The present invention also comprises skin care activity thing sedimentary method of concordance on skin or hair.

The present invention also comprises and adopts goods of the present invention cleaning skin or hair and the skin care activity thing is transported to the method for skin or hair simultaneously, also comprises the method for making this based article.

Background technology

Conventional commercially available personal cleansing articles can be multiple dosage form, as soap bar, cream frost, water preparation and gel.This class cleaning formulation need satisfy multiple standards to reach user's requirement.These standards comprise cleaning efficacy, skin usability, to the mildness and the foam number of skin, hair and eye mucosa.Ideal personal cleansing articles is cleaning skin or hair leniently, can or can not cause stimulation substantially, can not make skin or hair over-drying because of frequent the use.

But there is intrinsic problem in these conventional dosage forms of personal cleansing articles, i.e. cleaning efficacy and the equilibrium problem that skin-care effect is provided.A kind of solution of this problem is to divide usefulness with cleaning and skin care.But this generally is inconvenience or unpractical, and many users more are willing to adopt the single product that skin-care effect can cleaning skin can be provided again.Be difficult to skin care ingredient is added in the general Cleasing compositions,, can produce disadvantageous uneven mixture because many skin care activity things and surfactant are incompatible.For can adopt skin care ingredient make uniform mixture, and for preventing skin care ingredient in presedimentary loss, for example emulsifying agent, thickening agent and gellant are used for skin care ingredient is suspended in surfactant mixture often to adopt supplementary element.This generally can make aesthetic pleasant homogeneous mixture, but the deposition of skin care ingredient is often relatively poor, because the skin protection component through emulsifying, can not effectively deposit in cleaning course.Many skin care ingredients also have the shortcoming that presses down bubble.Pressing down bubble property is a problem, because many users wish that cleaning article can provide abundant, satiny and a large amount of foams.

This shows that surfactant and the shared conventional cleaning article of skin care ingredient are had surfactant and the incompatible inherent defect of skin care ingredient.Clearly, the cleaning system that needs development can effectively clean and have the single product form of enough concordance skin care effects.

Also be starved of by a kind of disposable single product cleaning and skin care effect are provided.Disposable product is very convenient, because of it can avoid carrying the personal care product of heavy bottle, soap bar, jar, pipe and other form.Adopt disposable product also than adopting sponge, towel or other cleaning appliance health of repeatedly using,, produce abnormal flavour or have other unfavorable characteristic relevant with repeated use because those apparatus have bacteria breed.

The present invention be surprised to find that can develop can effectively clean with concordance carry the skin care activity thing easily, disposable personal cleansing articles cheap, health, it has required towel characteristic.The invention provides easily, need not goods that cleaning and skin protection are separated.The present invention is very easy to use, because these goods are exsiccant basically, and moistening before use.

The present invention relates to a kind of exsiccant, disposable personal cleansing articles, be applicable to cleaning skin or hair and the skin care activity thing is transported to skin or hair.Consumer can be by using dried product with water-wet.Goods of the present invention consist of water-insoluble substrate, at least a foaming surface active agent and at least a skin care activity thing.In some embodiments, these goods also comprise deposition aid.Without being limited by theory, it is believed that substrate can strengthen bubbling under low surfactant content, strengthen cleaning and Exfoliating Scrub effect, and make the transmission of skin care ingredient reach the best with consistent the deposition.Therefore, the invention provides a kind of effective cleaning product, wherein use the surfactant of low content, thereby stimulation is very little, and good concordance skin protection performance can be provided.Find these goods simultaneously in cleaning course, various conditioning ingredients can be delivered on skin or the hair.

Therefore, the purpose of this invention is to provide the towel formula goods of the substantially dry that is used for cleaning skin or hair and the skin care activity thing is transported to skin or hair, need when these goods are used to combine with water.

Another object of the present invention provides the disposable product of disposal type.

Another object of the present invention provides the goods to skin and hair gentleness.

Another object of the present invention provides the goods that are suitable in cleaning course carrying to skin or hair conditioner.

Another object of the present invention provides the goods that can deposit to concordance skin care activity thing and other conditioner on skin or hair.

Another object of the present invention provides the method that cleaning skin or hair and concordance ground are transported to the skin care activity thing in skin or hair.

Another object of the present invention provides the method for preparing goods of the present invention.

By following description, these purposes of the present invention and other purpose all will be conspicuous.

Summary of the invention

The present invention relates to the disposable personal care cleaning and the conditioning goods of disposal type, wherein comprise: (A) water-insoluble substrate, (B) be added on the substrate or immerse at least a lathering surfactant of substrate, (C) skin protection component, this component comprise at least a skin care activity thing that is selected from water solublity skin care activity thing, oil-soluble skin care active matter and composition thereof.This skin care activity thing component also is added on the substrate or immerses in the substrate.These goods are exsiccant before use substantially.But the average foam volume that these goods produce after moistening can be more than or equal to about 30ml.

In another embodiment, goods of the present invention also contain and are added on the substrate or immerse at least a deposition aid in the substrate.

In an embodiment again, the method that the present invention relates to produce this class disposal type disposable personal care cleaning article.This method may further comprise the steps: (A) add on water-insoluble substrate respectively or simultaneously or immerse (i) foaming characteristic surfactant and (ii) skin care activity component; (B) substrate after the dried basically.The average foam volume that resulting product produces is more than or equal to about 30ml.

In an embodiment again, the present invention relates to adopt above-mentioned personal cleansing articles to come cleaning skin or hair simultaneously and the skin care activity thing is transported to the method for skin or hair.

In an embodiment again, the present invention relates to the consistent method that deposits the skin care activity thing on skin or hair.

Unless otherwise indicated, all percentage ratios of Cai Yonging and ratio and are all measured down at 25 ℃ all by weight here.The present invention can comprise the described solvent of the application and non-essential component and described component, also can be made up of it, or be made up of it substantially.

Detailed Description Of The Invention

Personal cleansing articles of the present invention can be used for cleaning skin or hair very effectively, has the effect that effectively the skin care activity thing is deposited to skin or hair simultaneously.These goods also can contain the conditioner that can be deposited on skin and the hair.

Bound by theory not, but it is generally acknowledged that substrate obviously helps to bubble and skin care activity thing and other conditioner to the deposition of skin or hair.Think that the enhancement of barbotage and deposition is because the surface action of substrate and skin or hair.Therefore can adopt the gentle and obvious surfactant that reduces consumption.Think that the reduction of consumption of required surfactant is relevant with the exsiccant reduction of skin that is caused by surfactant or hair.In addition, the minimizing of dosage of surfactant can significantly lower surfactant to the skin care activity thing to skin or the sedimentary inhibitory action of hair (for example by emulsification or directly by the surfactant eccysis).

Bound by theory not it is generally acknowledged that substrate can also promote the deposition of skin care activity composition and conditioner.Because the present invention is a dried forms, the present invention need not to suppress the emulsifying agent of skin care activity thing and conditioning agent deposit.In addition, because skin care activity thing composition and skin conditioning agent add on substrate or immerse therebetween, they can contact with skin surface by the goods of moistening and be delivered directly on skin or the hair.

Substrate can also promote cleaning action.Each face of substrate can have different quality, for example matsurface and shiny surface.Substrate can be used as effective foaming and Exfoliating Scrub apparatus.Contact by the physics with skin or hair, substrate obviously helps cleaning and removes dirt, color make-up, dead bark or other chip.

Term " lathering surfactant " is meant and combines with water and can produce foamy surfactant through mechanical friction.Preferred this class surfactant should be gentle, and promptly this class surfactant has enough cleanings or cleaning function, but can not make skin or hair over-drying (being natural oil content of excessive eccysis and/or humidification composition), and can satisfy above-mentioned foaming standard.

Here the term of Cai Yonging " disposal type " or " disposable " are meant the goods of promptly abandoning or abandoning after once using according to its ordinary meaning.

The term that this class adopts " plays brewage " or " having played the goods of bubble " is meant that these goods contain the surfactant of described here the producing of capacity 〉=30ml foam volume (seeing foam volume test of the present invention).This class A foam A stereometry is carried out under middle hardness water (8-10 grain/gallon), 95 ℃ of conditions.

Here the term of Cai Yonging " water activation " is meant that goods of the present invention are dried forms when offering the user, needs to use after moistening.Find to bubble or to claim " being activated " when this based article contacts with water, need goods are further applied mechanical stress (as friction).

Here the term of Cai Yonging " substantially dry " is meant that goods are not moisture substantially before use, and general sensory drying when touching.Therefore the water content of goods of the present invention generally is less than about 10% (weight), preferably is lower than about 5% (weight), and more preferably less than about 1% (weight), the mensuration of water content (under for example low appropriate condition) under dry environment is carried out.Those of ordinary skill in the art can determine the water content in the goods, and goods for example of the present invention can be according to the relative humiditys of environment and be different.

Here the term that relates to lathering surfactant and goods of the present invention of Cai Yonging " gentleness " is meant that goods of the present invention have and the synthetic suitable mildness of soap of the gentleness that contains alkyl glyceryl ether sulfonate (AGS) surfactant.Contain the mildness of surfactant goods or relative irritating assay method based on skin sealing coat failure test.In this test, surfactant is gentle more, and the destructiveness of skin sealing coat is low more.By measuring water (3H-H through radioactive label (through tritiated) ₂O) enter the relative quantity that is contained in the physiologic buffer that oozes out liquid chamber from detected solution by epidermis and measure the destruction of skin sealing coat.This test sees T.J.Franz at " Dermatology research magazine " (J.Invest.Dermatol., 1975,64, the 190-195 page or leaf) and United States Patent (USP) 4673525 (people such as Small, authorized on June 16th, 1987), described content is all in conjunction with in the present invention as a reference.The test method that other is well known by persons skilled in the art to can be used for measuring the surfactant mildness also is suitable for.

Here the term of Cai Yonging " the consistent deposition " is meant no matter how user's preparation is used or actual this cleaning article (for example making the one side that has the skin care activity thing on the substrate bubble bubbles with respect to the one side that makes belt surface activating agent on the substrate) that uses, and wherein the deposition of skin care activity thing is all constant relatively.The deposition unanimity degree of goods of the present invention is approximately greater than 60%, preferably approximately greater than 65%, more preferably from about greater than 70%, most preferably from about greater than 75%.The mensuration that deposits consistent degree is by the deposition of when using " foaming of imperfect mode and " the skin care activity thing quotient divided by the deposition of when using " foaming of ideal style and " skin care activity thing.Here the imperfect mode of saying is bubbled and is meant that friction goods contains the surface or rub relative with contact surface of skin care activity thing, will contact with skin and hair with one side then.This can cause the deposition deficiency of skin care activity thing, because some skin care activity thing can be by surfactant emulsifying.Here the ideal foaming of saying is meant that friction contains that surfactant does not contain the one side of skin care activity thing or with its rubs relative with contact surface, the one side that will contain the skin care activity thing then contacts with skin and hair.This viewpoint all also is suitable for (deposition after the blistered one side that for example contains emulsive skin care activity thing and the contact skin is with respect to the deposition after the non-blistered one side that contains not emulsive skin care activity thing and the contact skin) with the goods that the skin care activity thing is handled for the substrate two sides.The hardness of skin care activity component can reach maximum deposition unanimity degree greater than about 0.02kg.

Personal care product of the present invention comprises the component of following necessity: (A) water-insoluble substrate (B) is added on the substrate or immerses at least a lathering surfactant of substrate and (C) at least a skin care activity thing.Also contain at least a deposition aid in the goods of the present invention.

Water-insoluble substrate

Goods of the present invention contain water-insoluble substrate." water-insoluble ", be meant that matrix impregnation is in water after, do not dissolve yet be difficult for broken.Water-insoluble substrate is that foaming surface active agent of the present invention and skin care activity thing are delivered to apparatus on skin or the hair.Without being limited by theory, it is believed that as transmitting mechanical force to produce the article that stir that substrate can provide the foam nucleus formation, and helps the skin care activity thing to deposit on skin and/or the hair.

There are many materials can be used as substrate.Below non-limiting characteristics expect: enough wet strength when (i) using, (ii) enough wear intensities, (iii) enough bulk and holes, (iv) enough thickness and (v) Shi Yi size.

The non-limitative example that meets the suitable water-insoluble substrate of above-mentioned standard has nonwoven substrate, textile substrates, water spray entwine substrate, gas blowout entwine substrate, natural sponge, synthetic sponge, high score subnet or the like.Because nonwoven substrate economy and be easy to obtain from many raw materials is used nonwoven substrate in the preferred embodiment.The meaning of nonwoven is that this layer is made of fiber, and fiber is not to be woven into fabric, but forms a thin slice, pad or laying.Fiber can be irregular (promptly arranging brokenly), also can pass through combing (being that combing is orientated it on a main direction).Nonwoven substrate can be made of the combination layer of irregular fiber and carded fiber in addition.

Nonwoven substrate can be by comprising that natural and synthetic many materials constitute.The natural meaning is the side-product of material source in plant, animal, insecticide or plant, animal and insecticide.The synthetic meaning is that material is mainly derived from various artificial materials or the natural material through further processing.Traditional basic parent material is generally fleece, wherein contains any common synthetic or natural textile fiber, or its mixture.

The non-limitative example of the natural material that is suitable among the present invention has silk fiber, keratin fiber and cellulose fibre.The non-limitative example of keratin fiber has the fiber that is selected from wool fiber, camel-hair fiber or the like.The non-limitative example of cellulose fibre has the fiber that is selected from wood pulp cellulose, cotton fiber, hemp, tossa, flax fiber and composition thereof.

The non-limitative example of the synthetic material that is suitable among the present invention has the fiber that is selected from acetate fiber, polyacrylic acid series fiber, cellulose ester fiber, improvement polyacrylic acid series fiber, Fypro, polyester fiber, polyolefine fiber, vinal, rayon fiber, polyurethane foam and composition thereof.These exemplary synthetic material have acrylic compounds, as Acrilan, Creslan and acrylonitrile group fiber-Orlon; Cellulose ester fiber is as cellulose acetate, A Nier and A Xier; Polyamide is as nylon (as nylon 6, nylon 66, NYLON610 or the like); Polyester is as fortrel, Ke Daier and dacron fibre-terylene; Polyolefin is as polypropylene, polyethylene; The polyvinyl acetate ester fiber; Polyurethane foam and composition thereof.Fiber that Zhi Bei these and other is suitable and non-woven material are at Riedel " nonwoven associated methods and material ", " the nonwoven world " (Nonwoven World) (1987) thus; " America encyclopedia " (The Encyclopedia Americana) rolled up (147-153 page or leaf) and the 26th volume (566-581 page or leaf) in 1984 the 11st; Authorizing January 2 nineteen ninety in No. 4,891,228, people's such as Thaman No. 4,891,227, United States Patent (USP) and the United States Patent (USP) has describe, in general terms, quotes as a reference in this integral body.

By the nonwoven substrate that natural material makes, normally net and the thin slice of being made on the fine metal silk screen plate by the suspension of fiber constitutes.See people such as C.A.Hampel " chemistry encyclopedia " 1973 the 3rd edition (793-795 page or leaf); " America encyclopedia " rolled up " paper pulp and the paper technical manual " of (376-383 page or leaf) and G.A.Smook in 1984 the 21st, and paper pulp and paper industrial technology association (1986) quote as a reference in this integral body.

By being applicable to that the substrate that natural material of the present invention makes can obtain from many industrial sources.The non-limitative example of the suitable industrial ply of paper that herein is suitable for has Airtex ^R, embossing air lay cellulose layer, basic weight is about 71gsy, can be from James River (Green Bay, WI) acquisition; Walkisoft ^R, embossing air lay cellulose, basic weight is about 75gsy, can be from WalkisoftU.S.A. (Mount Holly, NC) acquisition.

The method for preparing nonwoven substrate is well known in the art.Usually, these nonwoven substrate can become net, melt ejection, molding simultaneously, spun-bond process or carding method preparation by air lay, current, wherein fiber or long filament at first are cut into the length that needs from long thigh, by current or air-flow, be deposited on then on the web plate, the air-flow or the current that are full of fiber pass through this web plate.No matter its production method or composition, final layer will experience a kind of in several at least bonding operations, so that the fiber individuality is fixed together, forms self-holding net.Among the present invention, nonwoven layers can be passed through prepared in various methods, and these methods have that water spray is entwined, the combination of heat bonding and these methods.In addition, substrate of the present invention can be made of single or multiple lift.In addition, multilamellar substrate can comprise thin film and other non-fibrous material.

The nonwoven substrate that is made by the synthetic material that is suitable among the present invention also can obtain from many industrial sources.The non-limitative example of the suitable nonwoven layers material of Shi Yonging has HEF 40-047 herein, and the water with holes that contains have an appointment 50% artificial silk and 50% polyester sprays the material of entwining, and basic weight is about every square yard (gsy) of 43 grams, can be from Veratec, and (Walpole MA) obtains Inc.; HEF 140-102, the water with holes that contains have an appointment 50% artificial silk and 50% polyester sprays the material of entwining, and basic weight is about 56gsy, can be from Veratec, (Walpole MA) obtains Inc.; Novonet ^R149-616 contains the 100% polyacrylic heat bonding grid grain material of having an appointment, and basic weight is about 50gsy, can be from Veratec, and (Walpole MA) obtains Inc.; Novonet ^R149-801 contains the heat bonding grid grain material of 69% artificial silk of having an appointment, about 25% polypropylene and about 6% cotton, and basic weight is about 75gsy, can be from Veratec, and (Walpole MA) obtains Inc.; Novonet ^R149-191 contains the heat bonding grid grain material of 69% artificial silk of having an appointment, about 25% polypropylene and about 6% cotton, and basic weight is about 100gsy, can be from Veratec, and (Walpole MA) obtains Inc.; HEF Nubtex ^R149-801, the fritter water with holes that contains 100% polyester of having an appointment sprays the material of entwining, and basic weight is about 70gsy, can be from Veratec, (Walpole MA) obtains Inc.; Keybak ^R951V contains the drying and moulding material with holes of 75% artificial silk of having an appointment, about 25% acrylic fiber, and basic weight is about 43gsy, can (New Brunswick NJ) obtains from Chicopee; Keybak ^R1368, contain the material with holes of 75% artificial silk of having an appointment, about 25% polyester, basic weight is about 39gsy, can (New Brunswick NJ) obtains from Chicopee; Duralace ^R1236, the water with holes that contains 100% artificial silk of having an appointment sprays the material of entwining, and basic weight arrives about 115gsy for about 40gsy, can be from Chicopee (New Brunswick, NJ) acquisition; Duralace ^R5904, the water with holes that contains 100% polyester of having an appointment sprays the material of entwining, and basic weight arrives about 115gsy for about 40gsy, can be from Chicopee (New Brunswick, NJ) acquisition; Chicopee ^R5763, the water spray that contains the combing of 70% artificial silk of having an appointment, about 30% polyester and the nonessential latex adhesive (EVA) that the is no more than about 5%w/w material (8 * 6 holes of per inch) of entwining, basic weight arrives about 63gsy for about 75gsy, can be from Chicopee (New Brunswick, NJ) acquisition; Chicopee ^R9900 series (Chicopee 9931-52gsy for example, 50/50 rayon/polyester, with Chicopee 9950-42gsy, 50/50 rayon/polyester), the water spray of combing that contains the fiber composition of 50% artificial silk, 50% to 100% the polyester material of entwining, basic weight arrives about 70gsy for about 30gsy, can be from Chicopee (New Brunswick, NJ) acquisition; Sontaro 8868, and the water that contains have an appointment 50% cellulose and about 50% polyester sprays the material of entwining, and basic weight is about 60gsy, can obtain from Dupont Chemical Corp..

In addition, water-insoluble substrate can be the high score subnet sponge of narration on March 27th, 1996 disclosed European patent EP 702550 A1 numbers, and integral body is quoted as a reference herein.Contain multilamellar in the macromolecule sponge and extrude tubular reticulum, tubular reticulum is by the high resiliency polymer, as the addition polymers preparation of olefinic monomer and polycarboxylic acid polyamide.Although these macromolecule sponge designs are together used with liquid cleaner, these sponges can be used as water-insoluble substrate of the present invention.

Substrate can be made different shape, and smooth liner, thick liner, thin slice, spherical apparatus, irregularly shaped apparatus are arranged, and is of a size of about 1 square inch to hundreds of approximately square inches with the surface area representative.Accurate dimension will be decided on use needs and products characteristics.Square, circular, rectangle or oval liner are arranged especially easily, surface area is about 1 square inch to about 144 square inches, preferably about 10 square inches to about 120 square inches, more preferably about 30 square inches to about 80 square inches, thickness is that about 1 mil is to about 500 mils, preferably about 5 mils are to about 250 mils, and more preferably about 10 mils are to about 100 mils.

Water-insoluble substrate of the present invention can comprise two-layer or multilamellar, and every layer has different quality, abrasiveness and extensibility.Not being both of quality owing to the material that uses various combination or owing to the different production method of use, or the two has concurrently.The advantage that the substrate of dual quality can provide is, the one side that has more abrasive action is arranged, and is used to the effect of stripping off; Also have more soft, absorbent one side, be used for gentle cleaning.In addition, substrate can be the two-layer laminated material with DIFFERENT WET extensibility.The example of this lamination substrate is referring to U. S. application serial number 09/013,640 application on January 26th, 1998, common pending trial, and this application is introduced for reference in full.In addition, the respective layer of substrate can be made the face of different colours, helps user further to distinguish different surfaces.In addition, wish that substrate of the present invention has fillet.This feature can prevent the trend that moisture gathers on the angle of the square substrate of non-fillet.

Lathering surfactant

Goods of the present invention comprise the lathering surfactant of capacity, make foam volume (95 ℃ of following medium hardness water) 〉=30ml (adopting foam volume test described here to measure) of these goods.Preferred goods of the present invention contain the lathering surfactant that accounts for water-insoluble substrate weight 0.5-40% (weight), are more preferably 0.75-12.5% (weight), are most preferably 1-11% (weight).

Lathering surfactant is meant and combines with water and can produce foamy surfactant through mechanical friction.Preferred this class surfactant should be gentle, i.e. this class surfactant or its combination has enough cleanings or cleaning function, but can not make skin or hair over-drying, and can satisfy above-mentioned foaming standard.

Multiple lathering surfactant is applicable to this, comprising anion lathering surfactant, nonionic lathering surfactant, both sexes lathering surfactant, and their mixture.Lathering surfactant generally can the appreciable impact conditioner deposition, for example be water miscible substantially, and the HLB value is generally greater than 10.Cationic surfactant also can be used as non-essential composition, and condition is that they can not have a negative impact to the whole bubbling character of required lathering surfactant.

The anion lathering surfactant

The non-limiting example that is applicable to the anion lathering surfactant of the present composition is " detergent and emulsifying agent " (the North America version 1986, is published by Allured publishing company) that sees McCutcheon; " functional materials " of McCutcheon (North America version, 1992); United States Patent (USP) 3929678 (people such as Laughlin, December was authorized on the 30th in 1975) is all in conjunction with in the present invention as a reference.

Multiple anion lathering surfactant is applicable to this.The non-limiting example of anion lathering surfactant comprises sarcosinate, sulfate, isethionate, taurate, phosphate, lactate, glutamate, Glu, and their mixture.Preferred alkanoyl isethionate in the isethionate, preferred alkyl sulfate and alkyl ether sulfate in the sulfate.The alkanoyl isethionate is generally suc as formula shown in the RCO-OCH2CH2SO3M, and wherein R is the alkyl or alkenyl that contains 10-30 carbon atom approximately, and M is a water-soluble cationic, as ammonium, sodium, potassium and triethanolamine.The non-limiting example of these isethionates comprises the alkanoyl isethionate, is selected from cocoyl isethionic acid ammonium, cocoyl hydroxyethyl sulfonate, lauroyl hydroxyethyl sulfonate, and their mixture.

Generally suc as formula shown in ROSO3M and formula RO (C2H4O) xSO3M, wherein R is the alkyl or alkenyl that contains 10-30 carbon atom approximately for alkyl sulfate and alkyl ether sulfate, and x is about 1-10, and M is a water-soluble cationic, as ammonium, sodium, potassium and triethanolamine.The anion surfactant that other type is suitable for is the water soluble salt of organic sulfur acid reaction product, and general formula is:

R1--SO3--M

Wherein R1 is selected from the radical of saturated aliphatic alkyl of the straight or branched that contains 8-24 carbon atom approximately, preferably contains 10-16 carbon atom approximately; M is a cation.Another kind of anion synthetic surfactant comprises the type of regulation, contains succinamate, the alkene sulfonate of 12-24 carbon atom according to appointment, and b-alkoxy alkane sulfonate.The example of this constituents has lauryl sulfate and ammonium lauryl sulfate.

Other anion component that is suitable for has fatty acid soaps (be alkali metal salt, for example sodium salt or potassium salt), and it generally contains 8-24 carbon atom approximately, preferably contains 10-20 carbon atom approximately.The fatty acid that is applicable to soapmaking can be from natural source, for example the glyceride of plant and animal material (for example Petiolus Trachycarpi oil, Oleum Cocois, soybean oil, Oleum Ricini, Adeps Bovis seu Bubali, Adeps Sus domestica etc.).Fatty acid also can make through synthetic.The detailed description of soap class is referring to above drawing exhausted United States Patent (USP) 4557853.

Other anion component comprises phosphate, as monoalkyl, dialkyl group and trialkyl phosphate.

Other anion component comprises the alkanoyl sarcosinate shown in formula RCON (CH3) CH2CH2CO2M; wherein R is the alkyl or alkenyl that contains 10-20 carbon atom; M is a water-soluble cationic; as ammonium, sodium, potassium and alkanolamine (for example triethanolamine), preferred examples is sodium N-lauroyl sarcosinate, cocoyl sodium sarcosinate, lauroyl sarcosine ammonium and myristoyl sodium sarcosinate.The triethanolamine salt of sarcosine also is suitable for.

Taurate also is suitable for, and it is also referred to as the 2-aminoethane sulphonic acid based on taurine.Particularly suitable be the taurate that contains the C8-C16 carbochain.The example of taurate comprises the N-alkyl taurine, makes as the method reaction that is proposed according to United States Patent (USP) 2658072 (combining in the present invention as a reference in full) by dodecyl amine and hydroxyethyl sulfonate.Other non-limiting example comprises ammonium salt, sodium salt, potassium salt and alkanolamine (for example triethanolamine) salt of lauroyl N-methyltaurine, myristoyl N-methyltaurine and cocoyl N-methyltaurine.

Lactate also is suitable for, and particularly contains the lactate of C8-C16 carbochain.Lactated non-limiting example comprises ammonium salt, sodium salt, potassium salt and alkanolamine (for example triethanolamine) salt of lauroyl lactic acid, cocoyl lactic acid and caproyl lactic acid.

The anion surfactant that is applicable to this also has glutamate, Glu, particularly contains the glutamate, Glu of C8-C16 carbochain.The non-limiting example of glutamate, Glu comprises ammonium salt, sodium salt, potassium salt and alkanolamine (for example triethanolamine) salt of lauroyl glutamate, myristoyl glutamic acid and cocoyl glutamic acid.

The non-limiting example that is applicable to this preferred anionic surfactants lathering surfactant comprises: sodium lauryl sulfate; ammonium lauryl sulfate; Zetesol AP; sodium laureth sulfate; the tridecyl ether sodium sulfate; cetyl ammonium sulfate; cetyl sodium sulfate; cocoyl isethionic acid ammonium; the lauroyl hydroxyethyl sulfonate; the lauroyl sodium lactate; lauroyl lactic acid triethanolamine; the caproyl sodium lactate; sodium N-lauroyl sarcosinate; the myristoyl sodium sarcosinate; the cocoyl sodium sarcosinate; lauroyl N-methyltaurine sodium; cocoyl N-methyltaurine sodium; sodium lauroyl glutamate; the myristoyl sodium glutamate; with the cocoyl sodium glutamate, and their mixture.

What especially preferably be applicable to this is ammonium lauryl sulfate, Zetesol AP, sodium N-lauroyl sarcosinate, cocoyl sodium sarcosinate, myristoyl sodium sarcosinate, lauroyl sodium lactate and lauroyl lactic acid triethanolamine.

The nonionic lathering surfactant

Be applicable to that the example of the nonionic lathering surfactant of the present composition sees McCutcheon " detergent and emulsifying agent " (the North America version 1986, is published by allured publishing company); " functional materials " of McCutcheon (North America version, 1992) is all in conjunction with in the present invention as a reference.

The nonionic lathering surfactant that is applicable to this is selected from alkyl polyglucoside, alkyl poly glucoside, polyhydroxy fatty acid amide, alkoxy fatty acid ester, foaming sucrose ester, amine oxide, and their mixture.

Alkyl polyglucoside and alkyl poly glucoside are applicable to this, can be defined as widely long-chain alcohol (for example C8-30 alcohol) and sugar or starch or with the condensation product of glycopolymers or starch polymer (as glucosides or polysaccharide glycosides).This compounds is suc as formula shown in (S) n-O-R, and R is glycosyl part such as glucose, fructose, mannose and galactose; N is the integer of about 1-1000, and R is the C8-30 alkyl.The example that derives the long-chain alcohol of alkyl comprises decanol, spermol, stearyl alcohol, lauryl alcohol, myristyl alcohol, oleyl alcohol etc.S is a glucose moiety in the preferred embodiment of this class surfactant, and R is the C8-20 alkyl, and n is the integer of about 1-9.The commercial examples of this class surfactant comprises: decyl polysaccharide glycosides (available from APG 325 CS of Henkel), and lauryl polysaccharide glycosides (available from APG 600CS and the 625CS of Henkel).The sucrose ester surfactant also is suitable for, as coconut oil sucrose ester and lauric acid sucrose ester.

Other ionic surfactant pack that is suitable for is drawn together polyhydroxy fatty acid amide surfactant, and instantiation comprises glucamide, and structural formula is as follows:

Wherein R1 is H, C1-C4 alkyl, 2-ethoxy, 2-hydroxypropyl, and preferably the C1-C4 alkyl is more preferably methyl or ethyl, most preferably is methyl; R2 is the C5-C31 alkyl or alkenyl, and preferably the C7-C19 alkyl or alkenyl is more preferably the C9-C17 alkyl or alkenyl, most preferably the C11-C15 alkyl or alkenyl; Z is the polyhydroxy alkyl part that contains the straight chain hydrocarbon chain, wherein contains 3 hydroxyls that directly link to each other with hydrocarbon chain on the hydrocarbon chain at least, or its alkoxy derivative (preferably ethoxylate or propoxylate).Z is glycosyl part preferably, is selected from glucose, fructose, maltose, lactose, galactose, mannose, xylose, and their mixture.Particularly preferred surfactant corresponding to above structural formula is cocos nucifera oil alkyl N-methylglycoside amide (promptly R2CO-part wherein is derived from fatty acid distribution of coconut oil).The preparation of compositions method that contains polyhydroxy fatty acid amide for example sees british patent specification 809060, and (February 18 nineteen fifty-nine is open, Thomas Heldy; Co., Ltd); United States Patent (USP) 2965576 (E.R.Wilson, the mandate on the 20th of nineteen sixty December); United States Patent (USP) 2703798 (A.M.Schwartz, authorize March 8 nineteen fifty-five); And United States Patent (USP) 1985424 (Piggott, December was authorized on the 25th in 1934); All in conjunction with in the present invention as a reference.

Other example of non-ionic surface active agent comprises amine oxide.The general formula of amine oxide is R1R2R3NO, wherein R1 comprises alkyl, thiazolinyl or monohydroxy alkyl, wherein contain 8-18 carbon atom, about 0-10 ethylene oxide part and about 1 the glyceryl part of 0-approximately, R2 and R3 contain 1-3 carbon atom and about 1 hydroxyl of 0-, for example methyl, ethyl, propyl group, ethoxy or hydroxypropyl approximately.Arrow in the formula is the conventional representation of semi-polar bond.The example that is applicable to amine oxide of the present invention comprises dimethyl oxidation dodecyl amine, oil base two (2-ethoxy) amine oxide, dimethyl oxidation octylame, dimethyl oxidation decyl amine, dimethyl oxidation tetradecylamine, 3,6,9-trioxa heptadecyl diethyl amine oxide, two (2-ethoxy)-oxidation tetradecylamines, 2-dodecyloxy ethyl dimethyl amine oxide, 3-dodecyloxy-2-hydroxypropyl two (3-hydroxypropyl) amine oxide, dimethyl oxidation cetylamine.

The non-limiting example that is applicable to this preferred nonionic is selected from C8-C14 glucamide, C8-C14 alkyl poly glucoside, coconut oil sucrose ester, lauric acid sucrose ester, oxidation dodecyl amine, oxidation coco amine, and their mixture.

The both sexes lathering surfactant

Here the term of Cai Yonging " both sexes lathering surfactant " comprises that also zwitterionic surfactant, zwitterionic surfactant are the subclassification of amphoteric surfactant well known to those skilled in the art.

The present composition can adopt multiple amphoteric surfactant.Particularly suitable be the aliphatic secondary amine and the tertiary amines derived thing of generalized definition, preferred N atom wherein is cation, wherein aliphatic group can be a straight or branched, and wherein one of group contains the water solublity ionogen, for example carboxylate radical, sulfonate radical, sulfate radical or phosphonate radical.

Be applicable to that the non-limiting example of the amphoteric surfactant of the present composition sees McCutcheon " detergent and emulsifying agent " (the North America version 1986, is published by allured publishing company); " functional materials " of McCutcheon (North America version, 1992) is all in conjunction with in the present invention as a reference.

The non-limiting example of both sexes or zwitterionic surfactant is selected from betanin, sulfobetaines, hydroxyl sulfo betaine, alkyl imino-acetic acid salt, imino-diacetic alkyl salt, aminoalkyl salt, and their mixture.

The example of betanin comprises the senior alkyl betanin, as the coco dimethyl carboxymethyl betaine, the lauryl dimethyl carboxymethyl betaine, lauryl dimethyl α-carboxyethyl betanin, cetyl dimethyl carboxymethyl betaine, cetyl dimethyl betaine (available from the Lonzaine 16SP of Lonza company), lauryl is two-(2-ethoxy) carboxymethyl betaine, oil base dimethyl r-carboxylic CAB, lauryl is two-(2-hydroxypropyl) α-carboxyethyl betanin, the cocoyl dimethyl sulfopropyl betaine, lauryl dimethyl sulfoethyl betanin, lauryl is two-(2-ethoxy) azochlorosulfonate propyl lycine, amido betaines and acylamino-sulfobetaines (wherein RCONH (CH2) 3 groups link to each other with N atom on the betanin), oil-based betaine (available from the both sexes Velvetex OLB-50 of Henkel), and cocoamidopropyl (available from both sexes Velvetex BK-35 and the BA-35 of Henkel).

The example of sulfobetaines and hydroxyl sulfo betaine comprises as cocos nucifera oil acylamino-propyl hydroxy sulfonate (available from the Mirataine CBS of Rhone-Poulenc).

What preferably be applicable to this is the amphoteric surfactant shown in the following structural formula:

Wherein R1 is unsubstituted saturated or undersaturated, the straight or branched alkyl that contains 9-20 carbon atom approximately.Preferred R1 contains 11-18 carbon atom approximately; More preferably from about contain 12-18 carbon atom; More preferably from about contain the 14-18 carbon atom; M is 1 to about 3 integer, is more preferably 2-3, is more preferably 3; N is 0 or 1; Preferably 1; R2 and R3 are independently from each other not replacement or through mono-substituted 1 alkyl to about 3 carbon atoms that contains of hydroxyl, preferred R2 and R3 are CH3; X is selected from CO ₂, SO ₃And SO ₄Group; R4 is selected from not and replaces or through mono-substituted 1 saturated or undersaturated, the straight or branched alkyl to about 5 carbon atoms that contain of hydroxyl.X is CO ₂The time, R4 preferably contains 1 or 3 carbon atom, more preferably contains 1 carbon atom.X is SO ₃Or SO ₄The time, R4 preferably contains 2-4 carbon atom approximately, more preferably 3 carbon atoms.

Examples of amphoteric surfactants comprises following chemical compound among the present invention:

Cetyl dimethyl betaine (the CTFA called after cetyl betaine of this composition)

Cocoamidopropyl

Wherein R contains 9-13 carbon atom approximately

Cocos nucifera oil acylamino-propyl hydroxy sulfobetaines

Wherein R contains 9-13 carbon atom approximately,

Other amphoteric surfactant that is suitable for has suc as formula RN[(CH2) mCO2M] 2 and RNH (CH2) mCO2M shown in alkyl imines acetate and imino-diacetic alkyl salt and aminoalkyl salt, wherein m is 1-4, R is the C8-C22 alkyl or alkenyl, and M is H, alkali metal, alkaline-earth metal, ammonium or alkanolamine.Also comprise imidazolinium compounds and ammonium derivative.The instantiation of the amphoteric surfactant that is suitable for comprises: 3-dodecyl-alanine sodium, 3-dodecyl amino propane sulfonic acid sodium, N-senior alkyl aspartic acid are prepared (combination in the present invention as a reference in full) as the method that proposes according to United States Patent (USP) 2438091; And it is described with trade name " Miranol " product sold (combination in the present invention as a reference in full) at United States Patent (USP) 2528378.Other examples of amphoteric surfactants that is suitable for comprises two acid phosphates, as cocos nucifera oil acylamino-propyl group PG-dimethyl chlorination ammonium phosphate (available from the MonaquatPTC of Mona company).The both sexes acetate also is suitable for, as lauroyl both sexes oxalic acid disodium, lauroyl both sexes sodium acetate, and their mixture.

The lathering surfactant that preferably is applicable to this is as follows: wherein the anion lathering surfactant is selected from lauroyl sarcosine ammonium, three decyl ethers sodium sulfate, sodium N-lauroyl sarcosinate, Zetesol AP, sodium laureth sulfate, ammonium lauryl sulfate, sodium lauryl sulfate, cocoyl isethionic acid ammonium, cocoyl hydroxyethyl sulfonate, lauroyl hydroxyethyl sulfonate, cetyl sodium sulfate, lauroyl sodium lactate, lauroyl lactic acid triethanolamine, and their mixture; Wherein the nonionic lathering surfactant is selected from oxidation dodecyl amine, oxidation coco amine, the poly-glucose of decyl, the poly-glucose of lauryl, coconut oil sucrose ester, C12-14 glucamide, lauric acid sucrose ester, and their mixture; Wherein both sexes lathering surfactant is selected from lauroyl both sexes oxalic acid disodium, lauroyl both sexes sodium acetate, cetyl dimethyl betaine, cocoamidopropyl, cocos nucifera oil acylamino-propyl hydroxy sulfobetaines, and their mixture.

Foam volume test

Goods of the present invention comprise the lathering surfactant of capacity, so that the average foam volume that is produced is greater than about 30 milliliters, more preferably greater than about 50 milliliters, more preferably greater than about 75 milliliters, most preferably greater than about 150 milliliters.Adopt foam volume test to measure average foam volume.This test can be carried out concordance to the foam volume that goods of the present invention produced and measure.The foam volume test scheme is as described below:

Wash one's hands with the Ivory fancy soap before testing.This step is used for the dirt that removal can influence accuracy of measurement.

(2) launch tested goods by less important hands, its edge is rolled.

(3) on tested goods, add 10 milliliters 95 ℃ water (medium hardness is about 8-10 grain/gallon) with 10 milliliters of syringes or Brinkmann pipet.

(4) then with main hands with palm with middle pressure (for example 4 ounces) the friction foaming 6 seconds (2 circle/second) of tested goods of looping, agglomerating when goods rub between palm.

(5) launch tested goods with less important hands then, 10 milliliters of syringes of reuse or Brinkmann pipet add 10 milliliters 95 ℃ water (medium hardness is about 8-10 grain/gallon) on tested goods.Use main hands through the goods of moistening, to make tested goods agglomerating between palm once more with middle pressure (4 ounces) friction (3 circle).

(6) launch tested goods then, hand-held goods one end, another hand-held other end is looped, and further activation barbotage rubs 5 times.

(7) the tested goods that overturn are with the heavy-handed multiple step 6 of another.

(8) on the other hand cup-shapedly hold tested goods, the another hands scrapes the foam on the tested goods, notes only scraping foam from tested goods.Place enough splendid attires to produce foamy graduated cylinder or measuring cup the foam of tested goods.Repeat this program 5 times on same tested goods, the foam of each repeated collection is placed in same graduated cylinder or the measuring cup.Foam total amount through collecting repeatedly is called as foam volume.

(9) for reaching consistent result, adopt 3 parts of sample repeating step 1-8, average foam volume is its meansigma methods.

The skin care activity component

Personal cleansing articles of the present invention must comprise the skin care activity component of safe and effective amount, and this component comprises at least a skin care activity thing, is selected from water solublity skin care activity thing, oil-soluble skin care active matter, the acceptable salt of medicine and composition thereof.The term here " skin care activity thing " refers to can be used for to skin and/or hair is carried and produce the personal care actives that the following stated is nursed one's health benefit usually.The term here " safety and effective dose " refers to be enough to the consumption that improves pending situation or bring required skin protection benefit, but this consumption is low to moderate and is enough to avoid serious adverse, produces suitable benefit and risk ratio in the normal determination range of drug world.The art here " skin protection benefit " refers to and handles associated treatment, prevention and/or the long-term effect of particular condition with one or more skin care activity things here.The safe and effective amount of skin care activity composition is with the ability of concrete skin care activity thing, active matter transdermal, age, health status and the skin of user, and other factor and deciding.Goods of the present invention preferably comprise water-insoluble substrate weight about 0.001% to about 50%, and more preferably from about 0.01% to about 25%, and preferred about 0.05% to about 10% again, most preferably 0.1% to about 5% skin care activity component.

Skin care activity component of the present invention can comprise: water solublity skin care activity thing; The oil-soluble skin care active matter; Facial treatment milk; Or three's any combination or the mixture of arrangement.The oil-soluble skin care active matter is selected from one or more oil-soluble skin care active matters, makes the weighted arithmetic mean of oil-soluble skin care active matter solubility parameter be less than or equal to 10.5.Water solublity skin care activity thing is selected from one or more water solublity skin care activity things, makes the weighted arithmetic mean of water solublity skin care activity thing solubility parameter greater than 10.5.Solubility parameter based on this mathematical definition, for example when the skin care activity thing contains two or more chemical compound, wherein a kind of independent solubility parameter of chemical compound is greater than 10.5, can obtain the weighted arithmetic mean of the solubility parameter of required skin care activity thing, promptly be less than or equal to 10.5.On the contrary, when the skin care activity thing contained two or more chemical compound, wherein a kind of independent solubility parameter of chemical compound was less than or equal to 10.5, can obtain the weighted arithmetic mean of the solubility parameter of required skin care activity thing, promptly greater than 10.5.

Solubility parameter is that the common formulator in this area is known, and is used as in the process for preparation of being everlasting and is specified to the branch compatibility and deliquescent guidance.The definition of the solubility parameter δ of chemical compound is the square root of this chemical compound cohesion energy density.The solubility parameter of vague generalization compound is to be calculated according to following equation by the list value of additive group to compound component heat of evaporation and molal volume contribution:

δ = {[\frac{\underset{i}{Σ} E_{i}}{\underset{i}{Σ} m_{i}}]}^{1 / 2}

Wherein: ∑ i Ei=additive group to heat of evaporation contribution and, and

∑ i mi=additive group to molal volume contribution and

Various atoms and atomic group to the standard value table of the additive group of heat of evaporation and molal volume contribution referring to Barton, A.F.M. " solubility parameter handbook (CRC publishing house, the 6th chapter, table 3,64-66 page or leaf (1985)), the full content combination in the present invention as a reference.Above-mentioned solubility parameter equation sees Fedors, " method of estimation liquid solubility parameter and molal volume " " polymer technology and the science " of R.F., and volume 14, numbers 2,147-154 page or leaf (in February, 1974) is incorporated herein by reference.

Solubility parameter is followed the mixture rule, and therefore the solubility parameter of various constituents mixts is the weighted arithmetic mean (being weighted mean) of each components dissolved degree parameter of mixture.See that " chemistry and physics handbook the 57th edition (publication of CRC publishing house, C-726 page or leaf (1976-1977)) are in conjunction with in the present invention as a reference.

The chemistry formulator lists and when using solubility parameter, unit is (a card/cubic centimetre) 1/2.In that " the listed additive group of solubility parameter handbook is a kj/mol to the unit of the list value of heat of evaporation contribution.But the relation of knowing below can adopting easily changes into card/mole with the list value of these evaporation calorific values:

1 Jiao/mole=0.239006 card/mole and 1000 Jiao=1 kilojoule

See Gordon, people such as A.J. " chemist's guide " (John Wiley ﹠amp; Sons, 456-463 page or leaf) (1972) are in conjunction with in the present invention as a reference.Various chemical constituents have also been carried out the solubility parameter tabulation.The solubility parameter tabulation sees above-mentioned " solubility parameter handbook.Also can be referring to " the dissolubility effect in product, packing, infiltration and the preservation ", C.D.Vaughan, " cosmetics and washing goods " (rolling up in October, 103,1988, the 47-69 page or leaf) is in conjunction with in the present invention as a reference.

Use above-mentioned information, the common formulator in this area can determine the solubility parameter of following skin care activity composition.

Binding mode by its therapeutic effect or its hypothesis is classified to skin care activity composition used herein.But, think that the active component here can produce in some cases more than a kind of curative effect or by playing a role more than a kind of pattern.Therefore, the classification here is not to be that the qualification active component is listed special-purpose for convenience's sake.In addition, the pharmaceutically acceptable salt of these active component also can use at this.Following active component is used for the present composition.

Here can use multiple skin care activity composition, comprise being selected from these following compositions: anti-acne active matter, crease-resistant and anti-skin atrophy actives, skin barrier repair aids, the comfortable auxiliary agent of cosmetics, local anesthetic, artificial suntan and promoter, skin whitener, antimicrobial and antifungal actives, sunscreen actives thing, sebum stimulant, sebum inhibitor and composition thereof.

The anti-acne active matter:

The anti-acne active matter can be handled common acne, pilosebaceous long-term wadding disorderly effectively.Thereby this situation relates to pilosebaceous inflammation produces damage, comprises pimple, pustule, cyst, blackhead and serious cicatrix.Acne rod bacillus and staphylococcus epidermidis antibacterial are present in the pustule content usually.

The limiting examples of the anti-acne active matter that is suitable for comprises keratolytic such as salicylic acid (oxybenzoic acid), salicyclic acid derivatives such as 5-MEXORYL SAM and 4-methoxyl group salicylic acid, and resorcinol; Retinoid mixture such as tretinoin and derivant thereof (for example cis and trans); Sulfur-bearing D or L aminoacid and their derivant and salt specifically are its N-acetyl derivatives, and its preferred embodiment is N-acetyl group-L-cysteine; Thioctic acid, antibiotic and antimicrobial, as benzoyl peroxide, Octopirox, tetracycline, 2,4,4 '-three chloro-2 '-hydroxy diphenyl ether, 3,4,4 '-trichloro-symmetrical diphenyl urea, Azelaic Acid and derivant, phenoxyethanol, benzene oxygen propanol, benzene oxygen isopropyl alcohol, ethyl acetate, clindamycin and meclocycline; Sebum inhibitor such as flavonoid and bioflavonoids; And bile salts such as sulphuric acid scymnol ester and derivant, dexycholate and cholate; Rosin acid; Adapalene; Allantoin; Aloe extract; Hemicentrotus seu Strongylocentrotus acid (arbietic acid) and salt thereof; ASEBIOL (available from Laboratoriesserobiologiques, is positioned at Somerville, N.J.); Azaleic acid; The berberis extract; Arctostaphylos ura-ursi extract; China's Rhizoma Belamcandae; Benzoquinone; Berberine; BIODERMINE (available from Sederma, is positioned at Brooklyn, NY); Bisabolol; The S-Carbocisteine; Radix Dauci Sativae extract; Oleum Cinnamomi (cassin oil), Flos Caryophylli extract, citral, citronellal, CREMOGENM82 (available from Dragoco, are positioned at Totowa, N.J); Fructus Cucumidis sativi extract; Dehydroacetic acid and salt thereof; Dehydroepoandrosterone salicylate (dehydroeplandersterone salicylate); Dichlorobenzene base imidazoles dioxolanes, its commercially available product are that COMPLETECH MBAC-OS (available from Lipo, is positioned at Paterson, NJ); DL valine and ester thereof; DMDM Hydantoin; Erythromycin; Esciorcin (escinol); Ethylhexyl list glycerin ether; Undecanoic acid ethyl 2-hydroxy ester; Farnesol; Farnesyl acetate; Geraniol; Glabrene. (glabridin); Gluconic acid, gluconolactone, monocaprin; Glycolic; Semen Vitis viniferae extract; Gugu fat; Hesperidin; Hinokitol; Flos lupuli (Flos Humuli Lupuli) extract; Foral; 10 hydroxydecanoic acids; Ichthyol; The interleukin-11 alpha-2 antagonists; Ketoconazole; Lactic acid; Indian oil of verbena; Linoleic acid; LIPACIDE C8CO (, being positioned at Paris, FRA) available from Seppic; Its spit of fland is cut down in the Lip river; Metronidazole; Minocycline; Caulis Hederae Sinensis element (mukurossi); Margosa oil; Vitamin B3 compounds (nicotiamide and nicotinic acid); Nisin; Octopirox; Panthenol; The 1-pentadecanol; Radix Paeoniae Alba extract; The Mentha arvensis L. syn.M.haplocalyxBrig extract; Water cress extract; 2-phenyl-benzothiophene derivative; Phloretin; PHLOROGINE (available from Secma); Phosphatidylcholine; Protease, quercetin, Lignum pterocarpi indici extract, Herba Rosmarini Officinalis extract, rutin, sage extract, sinciput extract, siber hegner extract, Siberia Herba Saxifragae, silicol, sodium lauryl sulfate; Sulfo group acetamide sodium; Sorbic acid; Sulfur; Sunder vati extract; Tea tree oil; Tetracycline; The tetrahydrochysene rosin acid; Thymi Serpylli Herba extract; Tioxolone (tioxolone); Tocopherol; Trehalose 6-undecylenate; 3-tridecylene-2-alcohol; Tropolone; UNITRIENOL T27 (, being positioned at Dutch Gouda) available from Unichem; Vitamin D3 and analog thereof; White thyme oil; Wogonin; The blue essence of clothing; Glyceric acid zinc; Zinc linoleate; Zinc oxide; Zinc pyrrole sulfur; Zinc sulfate, and their mixture.

Antimicrobial and antifungal actives:

Antimicrobial and antifungal actives can prevent breeding and the growth of antibacterial and fungus effectively.The limiting examples of antimicrobial and antifungal activity composition comprises: the beta-lactam medicine, quinolone medicine, encircle the third fluorine chloromycetin, norfloxacin, tetracycline, erythromycin, amikacin, 2,4,4 '-three chloro-2 '-hydroxy diphenyl ether, 3,4,4 '-trichloro-symmetrical diphenyl urea, phenyl phenol, phenoxypropanol, the phenoxy group isopropyl alcohol, doxycycline, capreomycin, chlohexidine, chlortetracycline, oxytetracycline, clindamycin, ethambutol, hexamidine isethionate, metronidazole, penta amidine is fixed, gentamycin, kanamycin, the line mycin, methacycline, hexamethylenamine, dimethylamine four promise ring elements, neomycin, netilmicin, paromomycin, streptomycin, tobramycin, miconazole, quadracycline, erythromycin, erythromycin zinc, erythromycin propionate lauryl sulfate, erythromycin octadecanoate, amikacin sulfate, doxycycline hydrochloride, Capreomycin Sulphate, chlorhexidine gluconate, chlorhexidine dihydrochloride, chlortetracycline hydrochloride, tetramycin hydrochloride, Luijiemycin Hydrochloride, the hydrochloric acid ethambutol, the hydrochloric acid metronidazole, hydrochloric acid penta amidine is fixed, gentamycin sulfate, kanamycin sulfate, hydrochloric acid line mycin, methacycline hydrochloride, methenamine hippu, hexamine mandelate, minocycline hydrochloride, polygynax, netilmicin sulfate, paromomycin sulfate, streptomycin sulfate, tobramycin sulfate, the sulphuric acid miconazole, hydrochloric acid amanfadine, sulphuric acid amanfadine, Octopirox, parachlorometaxylenol, nystatin, tinea is moved back, 2-mercaptopyridine zinc oxide and clotrimazole; The Ledum Palustre L.var.dilatatum Wahl. lactone; Different Ledum Palustre L.var.dilatatum Wahl. lactone; Alkanet extract (alaninin); Fructus Anisi Stellati; Arnica tincture extract (acetic acid helenalin and 11,13-dihydro helenalin); Brocade horse extract (extract that contains root bark, lucinol); Berberis extract (berberine hydrochloride); The sweet extract of bay tree; Bayberry peel extract (myricetrin); Benzalkonium chloride; Benzethonium chloride; Benzoic acid and salt thereof; Benzoinum; Benzylalcohol; The blessing Ji; The Pseudobulbus Bletillae (Rhizoma Bletillae); Bloodroot; Bois derose oil; Fructus Arctii; Butyl p-hydroxybenzoate; The thorn juniper oil; CAE (available from Ajinomoto, is positioned at Teaneck, NJ); Cortex Melaleucae leucadendrae oil; Rhizoma Atractylodis; Caraway oil; Cascarilla (available from the product of merchant ESSENTIAL OIL by name); Cedar leaves oil; Chamomile; Chaparral; SY 1007; Siccolam (chlorophenesin); Chloroxylenol; Oleum Cinnamomi; Citronella oil; Oleum Caryophylli; Dehydroacetic acid and salt thereof; Dill seed oil, DOWICIL 200 (available from Dow Chemical, are positioned at Midland, MI); SONGGUOJU; Elenaic acid. (elenolic acid); Herba Epimedii; Ethylparaben; Fo-Ti; Galbanum; Radix Sanguisorbae; GERMALL 115 and GERMALLII (available from ISP-Sutton Labs, are positioned at Wayne, NJ); German chamomile oil; Rhizoma Polygoni Cuspidati; GLYDANT (available from Lonza, is positioned at Fairlawn, NJ); GLYDANT PLUS (available from Lonza); Glucose seed oil; The own oxygen amidine of two isethionic acids is fixed; Hinokitol; Honey; Flos Lonicerae; Flos lupuli (Flos Humuli Lupuli); Amaranth; Iodine propinyl Butylurea (available from Lonza); P-Hydroxybenzoic acid isobutyl ester; P-Hydroxybenzoic acid isopropyl ester; JM ACTICARE (, being positioned at Nottingham NG) available from Microbial Systems International; The Juniperus rigida Sieb.et Zucc. fruit; KATHON CG is (available from Rohm ﹠amp; Haas is positioned at Philadelphia, PA); Labdanum; Garden lavender; The NINGMENGXIANG lubricate; Lemon grass (Cymbopogon citratus); Methyl parahydroxybenzoate; Herba Menthae; Prunus mume (sieb.) sieb.et zucc. (mume); Caulis et Folium Brassicae junceae; Myrrha; Margosa oil; O-phenyl phenol; Folium olive; Parsley; Herba Pogostemonis oil; Root of Paeonia suffruticosa Ardr.; PHENONIP (available from Nipa Labs, is positioned at Wilmington, DE); Phenyl phenol; Pinke needle oil; PLANSERVATIVE (available from CampoResearch); Propyl p-hydroxybenzoate; Herba Portulacae; Quillaia saponaria (quillaira); Radix Et Rhizoma Rhei; The Flos Rosae Multiflorae Flos Pelargonii oil; Herba Rosmarini Officinalis; Salvia japonica Thunb.; Salicylic acid; Yellow Camphor tree; Savoury; The river Radix Angelicae Sinensis; Sodium acid sulfite; Sodium sulfite; SOPHOLIANCE (available from Soliance, being positioned at Compiegne, France); Sorbic acid and salt thereof; Folium Stevlae Rebaudianae; Styrax; Tannic acid; Tea; Tea tree oil (Cortex Melaleucae leucadendrae oil); Herba thymi vulgaris; Triclosan; Triclocarban; Tropolone (tropolone); Oleum Terebinthinae; Umbelliferone (antifungal); Y. flaccida Haw.; The 2 hydroxy pyrimidine zinc oxide; And their mixture.

Crease-resistant and anti-skin atrophy actives:

Epidermal area can be recovered or rebuild to crease-resistant and anti-skin atrophy actives effectively.These active matters provide these required skin effects by the natural process that promotes or keep decortication to consider to be worth doing usually.Limiting examples crease-resistant and anti-skin atrophy actives comprises: tretinoin and derivant thereof (for example cis and trans); Retinol; Retinal; Retinol ester such as retinol acetate, retinyl palmitate and propanoic acid retinol ester; Vitamin B3 compounds (as nicotiamide and nicotinic acid), salicylic acid and derivant thereof (as the 5-MEXORYL SAM, heptan oxygen base-4-salicylic acid, 4-methoxyl group salicylic acid and 5-decoyl salicylic acid); Sulfur-bearing D or L aminoacid and their derivant and salt, especially its N-acetyl derivative, its preferred embodiment are N-acetyl group-L-cysteine; Mercaptan, for example second alkanethiol; Hydroxy acid, phytic acid; Thioctic acid, lysophosphatidic acid, and exfoliant (for example phenol etc.); Adapalene; Ademetionine (ademethionine); Adenosine; The false aloe extract; Derived from aloetic hemagglutinin; 3-aminopropyl dihydrogen phosphoric acid ester; The Pimpinella anisum Linn. extract; AOSINE (available from Secma); ASC III (, being positioned at German Darmstadt) available from E.Merck; Ascorbic acid; Palmic acid ascorbyl ester; Asiatic acid; Asiaticoside; ARLAMOL GEO ^TM(, be positioned at Wilmington, DE) available from ICI; Azaleic acid; Benzoic acid derivative; The bertholletia extract; Belulinic acid Betulinic acid; BIOCHANIN A AND BIOPEPTIDECL (available from Sederm, is positioned at Brooklyn, NY); BIOPEPTIDE EL (available from Sederma); The blackberry bark extract; The blackberry Bulbus Lilii extract; Black Cohosh P.E; The bytyry belulinic acid Betulinic acid; Citrate; The Vitex extract; Herba Trifolii Pratentis extract; Daidzein; Debrominate (laurinterol); 1-capryl-glyceryl phosphonic acids; Dehydrocholesterol; Dehydrogenation dicreosol; Dehydrogenation dieugenol; Dehydroepiandrosterone; DERMOLECTINE (available from Sederma); Hydroascorbic acid; The dehydroepiandrosterone sulfuric ester; Two anethole; 2, the 4-resorcylic acid; Diosgenin; The ascorbyl disodium hydrogen phosphate; Dodecanedioic acid; Estrogen and derivant thereof; Ethocyn; ELESERYLSH (available from Laboratories Serobiologiques, is positioned at Somerville, N.J); ENDONUCLEINE (available from Laboratories Serobiologiques); Ergosterol; Eythrobic acid; Fructus Foeniculi extract; The fenugreek seed extract; FIBRASTIL (available from Sederma); FIBROSTIMULINES S and P (available from Sederma); FIRMOGEN LS8445 (available from Laboratories Serobiologiques); Formononetin; The Fructus Forsythiae extract; Epicatechol gallate; γ-Ding Suan; GATULINE RC (, being positioned at French Priest) available from Gattlefosse; Genistein; Genisteine; Dyestuff wood acid (genistic acid); Semen Ginkgo extrac; Radix Ginseng extract; Ginsenoside (R ₀, R _6-1, R _6-2, R _6-3, R _C, R _D, R _E, R _F, R _F-2, R _G-1, R _G-2); Glucose pyrans glycosyl-l-acid ascorbyl ester; Glutathion and ester thereof; Six hydrogen curcumins; The HMG-CoA-reductase inhibitors; Flos lupuli (Flos Humuli Lupuli) extract; 11 hydroxyl hendecanoic acids; 10 hydroxydecanoic acids; The 25-hydroxycholesterol oxycholesterol; Kinetins; L-2-oxygen-Thiazolidine-4-carboxylate; The lactic dehydrogenase enzyme inhibitor; The l-lauryl; LYSO-PHOSPHATIDYLCHOLINE LYSOPC; Radix Glycyrrhizae extract; Lumisterol; Luteolin; The ascorbyl magnesium phosphate; Melatonin; Inhibitors of metalloproteinase; Methoprene (methoprene); Methopterin (methoprenic acid); MPC COMPLEX (available from CLR); N methyl serine; The N N-methyltaurine; N, two (lactyl) cysteamines of N1-; Naringenin; Neotigogenin; Oleanolic acid; Light anethole ketone (photoanethone); Intacellin; Pratensein; Pregnenolone, pregnenolone acetas; Pregnenolone succinate; Premarin; Raloxifene; REPAIR FACTOR 1 and REPAIR FACTOR FCP (all available from Sederma); Retinol ester (C2-C20 alcohol ester); The glucuronic acid retinol ester; The linoleic acid retinol ester; The S-Carbocisteine; SEANAMINE FP (available from Laboratories Serobiologiques); Soybean extract; Spleen extract; Tachysterol; Tazarotene; Thymulen; Thymic extract; Tigogenin; The tretinoin tocopherol; 1-decene-1; Choline citrate; Trifoside; Ursolic acid; Vitamin D3 and analog thereof; Rhizoma Dioscoreae extract; Administration's Chinese yam glycosides part; Zeatin; And their mixture.

Skin sealing coat repairing activity thing:

Skin sealing coat repairing activity thing is to help epidermis natural moisture preserving isolation features to repair and regenerated skin care activity composition.Skin sealing coat repairing activity thing comprises brassicasterol; Caffeine; Campesterol; The deutero-sterol of low erucic acid rapeseed oil; CERAMAX (, being positioned at Britain Ashford) available from Quest; CERAMIDE 2 and CERAMIDE HO3 ^TM(all available from Sederma); CERAMIDE II and CERAMIDE III (available from Quest); IIIB (, being positioned at Dutch Deft) available from Cosmoferm; CERAMIDE LS 3773 (available from LaboratoriesSerobiologiques); CERAMINOL (available from Inocosm); Cholesterol; The hydroxy stearic acid cholesterol ester; The isostearic acid cholesterol ester; 7 dehydrocholesterols; DERMATEIN BRC and DERMATEIN GSL (all available from Hormel); ELDEW CL 301 and ELDEW PS 203 (all available from Ajinomoto); The glycerol serine amides; Lactic acid; Lanolin alcohol; Lanosterol; Lauric acid N lauryl glucosan amide; Thioctic acid; The N-acetyl-cysteine; The N-acetyl-L-serine; N methyl-L-serine; Vitamin b 3 compound (as nicotiamide and nicotinic acid); Palmic acid; Pantothenylol; Pantethine (panthetine); Phosphodiesterase inhibitor; PHYTO/CER (available from Intergen); Semen setariae plant sugar ester extract (available from BarnetProducts Distributer, is positioned at Englewood, NJ); PHYTOSPHINGOSINE (available from Gist Brocades, is positioned at King of Prussia, PA); PSENDOFILAGGRIN (available from Brooks Industries, is positioned at South Plainfield, NJ); QUESTAMIDE H (available from Quest); Serine, σ sterol; Sitosterol; Sterol derived from Semen sojae atricolor; Sphingosine; S-lactyl glutathion; Stearic acid; SUPER STEROL ESTERS (available from Croda); Thioctic acid; THSC CERAMIDE OIL (available from Campo Research); Trimethyl glycine; Tocopheryl nicotinate; Vitamin D3; Y2 (available from Ocean Pharmaceutical); And their mixture.

On-steroidal beauty treatment skin moistening active matter

Beauty treatment skin moistening active matter can effectively be prevented and treated scytitis.Among the present invention, the skin moistening active component can promote skin appearance, and for example this constituents can make the colour of skin more even pleasant.The consumption of antiinflammatory will be decided on the antiinflammatory of concrete application in the present composition, because the potency difference of this class antiinflammatory.The non-limiting example of beauty treatment emollient comprises following all kinds of: propanoic derivatives; Acetogenin; Fenamic acid derivatives; The diphenyl carboxylic acid derivates; And oxicams.All these beauty treatment skin moistening active component all fully are disclosed in United States Patent (USP) 4985459 people such as (, on January 15th, 1991 is open) Sunshine, in full in conjunction with in the present invention as a reference.The non-limiting example of the beauty treatment skin moistening active component that is suitable for comprises aspirin, ibuprofen, naproxen Ben Evil third sweet smell, flurbiprofen, phenoxy propionic acid, fenbufen, the ketone benzenpropanoic acid, indoprofen, Pirprofen, carprofen oxaprazine, Pranoprofen, miroprofen Tioxaprofen, suprofen, alminoprofen, Artiflam, the fluorobenzene propanoic acid, the bucloxic acid, Common Wormwood oil, Acacia farnesiana Willd., aescine, alder waythorn extract, allantoin, Lu Yun, APT (available from Centerchem), arnica tincture, the astragali plant, astragali plant roots extract, azulenes, Baikal is stuck with paste Radix Scutellariae, the Rhizoma Atractylodis Macrocephalae, Canada balsam, bee pollen, BIOPHYTEX (available from Laboratores Serobiologiques), bisabolol, Radix vernoniae asperae, Black Cohosh P.E, blue cohoss, the blue cohoss extract, Euphatorium Perfoliatum, borage oil, the borage, pinguinain, Flos Inulae, Flos Inulae extract, candelilla wax, Rhizoma Atractylodis, the low erucic acid rapeseed oil plant sterol, Fructus Capsici, carboxypeptidase, celery seed, the stem of celery extract, CENTAURIUM (available from Sederma), the Centaurea cyanus extract, Flos Matricariae chamomillae Austria, Flos Chrysanthemi, the Flos Chrysanthemi extract, chaparral, Herba Viticis Cannabifoliae, the Herba Viticis Cannabifoliae extract, Herba stellariae mediae, root of Herba Cichorii, chicory root extract, Chiretta, Radix Paeoniae Rubra (chishao), Aveeno Bath, Radix Arnebiae (Radix Lithospermi), Radix Arnebiae extract, CROMOIST CM GLUCAN (available from Croda), the dehurian Radix Angelicae Sinensis, cockspur, divalent metal is (as magnesium, strontium and manganese), Fructus Evodiae grass (doggrass), Fructus Corni, Chinese mugwort pomegranate (eleuthero), ELHIBIN (available from Pentapharm), ENTELINE 2 (available from Secma), the Herba Ephedrae arrow, Herba Epimedii, Radix Oenotherae erythrosepalae, Herba Euphrasiae Regelii, Radix Saposhnikoviae, feverfew, ficin, the Fructus Forsythiae fruit, Ganoderma, Rhizoma Ligustici, Radix Gentianae, the germanium extract, Semen Ginkgo, the Ginkgo plant, Radix Ginseng extract, groundraspberry, the Ge Erge extract, the gotu cola, Fructus Vitis viniferae extract, guaiac wood oil, the guggal extract, the helenalin ester, mignonettetree, Flos Lonicerae, the Herba lagopsis supinae extract, buckeye, Herba Equiseti Arvinsis, Rhizoma Polygoni Cuspidati, hypericum, ichthyol, amaranth, hippo, Semen Coicis, Fructus Jujubae, the cola extract, LANACHRYS 28 (available from Lana Tech), Fructus Citri Limoniae oil, Fructus Forsythiae, Radix Glycyrrhizae, Rhizoma Ligustici, Fructus Ligustri Lucidi, the levisticum officinale root, Fructus Luffae, the Semen Myristicae skin, Flos Magnoliae Liliflorae, Fructus Viticis (manjistha) extract, margasipidin (margaspidin), matricin, MICROAT IRC (available from Nurture), Herba Menthae, Herba Visci, Moschus, oat extract, Fructus Citri tangerinae, panthenol, papain, Cortex Moutan, root of Paeonia suffruticosa Ardr., Herba Portulacae, QUENCHT (available from Centerchem), soapbark, Radix Salviae Miltiorrhizae, Radix Rehmanniae, Radix Et Rhizoma Rhei, Herba Rosmarini Officinalis, rosmarinic acid, Lac regis apis, Folium Symplocoris Caudatae, rutin, sandalwood, Radix Notoginseng, Rhizoma Smilacis Chinensis, the saw palmetto, SENSILINE (available from Silab), SIEGESBECKIA (available from Sederma), the stearic alcohol ester of enoxolone, Styrax, birch oil, sweet Asperula orientalis, Flos Tagetis Erectae, tea extract, Thymi Serpylli Herba extract, the Tianshan Mountains Radix Ginseng, tocopherol, tocopherol acetate, Rhizoma Curcumae Longae, urimei, maloic acid, the kahikatea skin, Radix Hamamelidis Mollis, Flos Magnoliae, yarrow, yeast extract, Y. flaccida Haw., and their mixture.

Artificial suntan and promoter:

Artificial tanned active matter can be by promoting dermal melanin or making skin have the outward appearance that melanin increases, to simulate natural Exposure to Sunlight.The non-limiting example of artificial suntan and promoter comprises: dihydroxy acetone; Tyrosine; Tyrosine ester is as tyrosine ethyl ester and tyrosine glucose ester; Acetyl Tyrosine; Phospho DOPA, brazilin; Caffeine; Coffee-extract; Dihydroxy acetone; Dna segment; Isobutyl methylxanthine; Methylxanthine; Prostaglandin; Tea extract; Theophylline; UNIPERTAN P2002 and UNIPERTAN P27 (all available from Unichem); And their mixture.

The skin whitening composition:

The skin whitening composition can reduce melanic content in the skin really, or reaches this effect by other mechanism.The skin whitening composition that is applicable to this see common unsettled series application 08/479935 (application on June 7 nineteen ninety-five, Hillebrand), corresponding PCT application is the U.S.95/07432 (applying date: 6/12/95); Common unsettled series application 08/390152 (application on February 24 nineteen ninety-five, Kalla L.Kvalnes, Mitchell A.DeLong, BartonJ.Bradbury, Curtis B.Motley, and John.D.Carter), corresponding PCT application is U.S.95/02809 (applying date: 3/1/95, open day 9/8/95); All in conjunction with in the present invention as a reference.The non-limiting example that is applicable to this skin whitening active component comprises: adapalene; Aloe extract; DL-Lactic acid ammonium salt.; the anethole derivant; Fructus Mali pumilae extract; arbutin; ascorbic acid; the Palmic acid ascorbyl; Azelaic Acid; bamboo extract; Arctostaphylos ura-ursi extract; Pseudobulbus Bletillae (Rhizoma Bletillae) extract; Radix Bupleuri extract; Radix Sangusorbae extract; Butylated hydroxyanisole; butylated hydroxytoluene; Rhizoma Chuanxiong; Radix Angelicae Sinensis; deoxyarbutin; 1; the 3-diphenyl propane derivative; 2; 5-resorcylic acid and derivant thereof; 2-(4-ethoxyl phenenyl)-1; 3-Di Sen; 2-(4-hydroxyphenyl)-1; 3-Di Sen; ellagic acid; esciorcin; the estragole derivant; FADEOUT (available from Pentapharm); Radix Saposhnikoviae; Fructus Foeniculi extract; Ganoderma extract; Rhizoma Ligustici; GATULINE WHITENING (available from Gattlefosse); dyestuff wood acid and derivant thereof; glabrene. and derivant thereof; glucose pyrans glycosyl-l-acid ascorbyl ester; gluconic acid; glycolic; green tea extract; 4-hydroxy-5-methyl base-3[2H] furanone; hydroquinone; 4-BHA and derivant thereof; the 4-hydroxybenzoic acid derivative; Hydroxycaprylic acid; the ascorbic acid mesoinositol; kojic acid; lactic acid; citron extract; linoleic acid; the ascorbyl magnesium phosphate; MELAWHITE (available from Pentapharm); the Mulberry extract; the mulberry root extract; nicotiamide; the 5-MEXORYL SAM; parsley extract; the phellinuslinteus extract; the pyrogallol derivant; tretinoin; retinol; retinol ester (acetas; propionic ester; cetylate; linoleate); 2; the 4-resorcinol derivant; 3; the 5-resorcinol derivatives; the Rosehips extract; salicylic acid; the Song-Yi extract; 3; 4; 5-trihydroxy benzyl derivative; tranamic acid; vitamin D3 and analog, and their mixture.

The sunscreen actives thing:

The sunscreen actives thing also is applicable to this.All kinds of sunscreen see United States Patent (USP) 5087445 (people such as Haffey, on February 11st, 1992 authorized); United States Patent (USP) 5073372 (people such as Turner, December was authorized on the 17th in 1991); United States Patent (USP) 5073371 (people such as Turner, December was authorized on the 17th in 1991); And people such as Segarin is in 189 pages of following contents of " cosmetics science and technology " the 8th chapter, and they are all in conjunction with in the present invention as a reference.The non-limiting example that is applicable to the sunscreen of the present composition is selected from: p-methoxycinnamic acid 2-Octyl Nitrite, N, N-dimethyl para-amino benzoic acid 2-Octyl Nitrite, para-amino benzoic acid, 2-Phenylbenzimidazole-5-sulfonic acid, octocrilene, oxybenzone, the high menthol ester of salicylic acid, ethylhexyl salicylate, 4,4 '-methoxyl group normal-butyl dibenzoyl methane, 4-isopropyl diphenyl formyl methane, 3-benzylidene camphor, 3-(4-methyl benzal) Camphora, titanium dioxide, zinc oxide, silicon dioxide, ferrum oxide, and their mixture.Other sunscreen that is suitable for sees United States Patent (USP) 4937370 people such as (, authorize June 26 nineteen ninety) Sabatelli; United States Patent (USP) 4999186 (people such as Sabatelli, on March 12nd, 1991 authorized); These two pieces of documents are all in conjunction with in the present invention as a reference; Other useful sunscreen comprises amino benzoic Acid (PABA); the two benzoyl methane of butyl methoxyl group; diethanolamine p-methoxycinnamic acid ester; dioxybenzone; ethyl dihydroxypropyl (PABA); glyceryl aminobenzoate; the high menthol ester of salicylic acid; isopropyl diphenyl formoxyl methane; 2-hydroxyl-1, the 4-naphthoquinone; the 2-hydroxypropanone-; the ortho-aminobenzoic acid menthol ester; methyl 2-aminobenzoate; octocrilene; octyldimethyl (PABA); octyl methoxycinnamate; 2-Phenylbenzimidazole-5-sulfonic acid; red vaseline; sulisobenzone; triethanolamine salicylate and composition thereof.The example of particularly preferred sunscreen is selected from: 4-N, 2 of N-(2-ethylhexyl) methylamino benzoic acid, 4-dihydroxy benzophenone ester, 4-N, the ester of N-(2-ethylhexyl) methylamino benzoic acid and 4-hydroxy benzophenone acyl methane, 4-N, the ester of 2-hydroxyl-4-(2-hydroxyl-oxethyl) benzophenone of N-(2-ethylhexyl) methylamino benzoic acid, 4-N, the ester of N-(2-ethylhexyl) methylamino benzoic acid and 4-(2-hydroxy ethoxy) dibenzoyl methane, and their mixture.

The definite consumption of sunscreen is according to selected sunscreen and the required sun protection factor that reaches (SPF) and different.SPF is the parameter that is usually used in weighing the anti-sunlight function of the anti-erythematous response of sunscreen.Referring to Federal Register, volume 43, numbers 166, the 38206-38269 page or leaf, on August 25th, 1978, full content is in conjunction with in the present invention as a reference.

The sebum stimulant:

The sebum stimulant can promote the generation of sebum in the sebaceous gland.This class skin care activity composition is specially adapted to the insufficient situation of postmenopausal women sebum.The non-limiting example of sebum stimulating activity composition comprises: bryonolic acid (bryonolic acid), dehydrogenation etiandrosterone (being also referred to as DHEA), orizanol and their mixture.

Sebum inhibitor:

Sebum inhibitor can reduce the generation of sebum in the sebaceous gland.The non-limiting example that sebum suppresses active component comprises: ASEBIOL (available from Laboratories Serobiologiques), BIODERMINE (available from Sederma), COMPLETECH MBAC-OS (available from Lipo), Fructus Cucumidis sativi extract, dehydroacetic acid and salt thereof, Dichlorobenzene base imidazoles dioxolanes, nicotiamide, phloretin, PHLOROGINE (available from Secma), S-Carbocisteine, tioxolone, tocopherol, UNITRIENOL T27 (available from Unichem), and their mixture.

The preferred embodiment that is applicable to this active matter comprises: salicylic acid; benzoyl peroxide; the 3-hydroxy benzoic acid; glycolic; lactic acid; the 4-hydroxy benzoic acid; aspirin; nicotiamide; cis-retinoic acid; trans retinoic acid; retinol; retinyl palmitate; the 2-hydroxybutyric acid; the 2-hydroxypentanoic acid; the 2-hydroxycaproic acid; phytic acid; N-acetyl group-L-cysteine; thioctic acid; Azelaic Acid; arachidonic acid; tetracycline; ibuprofen; naproxen; hydrocortisone; acetamide phenol (acetominophen); resorcinol; phenyl phenol; phenoxypropanol; the phenoxy group isopropyl alcohol; 2; 4; 4 '-three chloro-2 '-hydroxy diphenyl ether; 3; 4; 4 '-trichloro-symmetrical diphenyl urea; Octopirox; lidocaine hydrochloride; clotrimazole; miconazole; polygynax; p-methoxycinnamic acid 2-Octyl Nitrite; oxybenzone; 2-Phenylbenzimidazole-5-sulfonic acid; dihydroxy acetone; pantothenylol; lactic acid; arbutin; kojic acid; allantoin; cholesterol; C10-30 cholesterol/lanosterol ester; tocopherol; tocopherol acetate, and their mixture.

Skin care activity component of the present invention also comprises facial treatment milk, and being used for provides the skin protection benefit to skin or hair.The term here " facial treatment milk " refers to the combination that discontinuous phase is sealed by continuous phase, and discontinuous phase comprises aqueous components, and continuous phase comprises oil-soluble constitents.Water-soluble component comprises and is selected from following chemical compound: water, following water solublity skin care activity thing, water solublity skin conditioning agent, and composition thereof.Oil-soluble constitents comprises and is selected from following chemical compound: following oil-soluble skin care active matter, oil-soluble skin conditioning agent, and composition thereof.In preferred embodiments, facial treatment milk also comprises emulsifying agent.Facial treatment milk be described water-insoluble substrate about 0.25% to about 150%, preferred about 0.5% to about 100%, more preferably from about 1% to about 50% weight.

Although contain the emulsifying agent that can form discontinuous phase and continuous phase emulsion among preferred the present invention, generally acknowledge in the skin care formulation field and do not adopt emulsifying agent also water solublity skin care activity thing can be encapsulated in the oil-soluble skin care active matter.As long as water solublity skin care activity thing sealed by oil-soluble reagent, thus prevent its in cleaning process by eccysis, described compositions belongs to scope of the present invention.

Can not necessarily contain not other water solublity or the water-dispersible composition that can have a negative impact to facial treatment milk stability in the discontinuous phase.The such composition of one class is the water solublity electrolyte.Dissolved electrolysis mass-energy prevents to be present in the composition of fat in mutually to greatest extent and also is soluble in the aqueous phase.Can adopt any electrolyte that can make inner phase have ionic strength.The electrolyte that is suitable for comprise water-soluble mono-, two-or trivalent inorganic salt, as water-soluble halide, for example halogenide of alkali metal, alkaline-earth metal, nitrate and sulfate.This electrolytelike example comprises sodium chloride, calcium chloride, sodium sulfate, magnesium sulfate and sodium bicarbonate.Electrolytical concentration generally accounts for the 1-20% (weight) of discontinuous phase.

Other is applicable to that the water solublity of discontinuous phase or water-dispersible composition comprise thickening agent and viscosity modifier.The thickening agent and the viscosity modifier that are suitable for comprise: water-soluble polypropylene acids or hydrophobically modified polyacrylic resin, as Carbopol and Pemulen, starch such as corn starch, potato starch, tapioca, gummy as guar gum, Radix Acaciae senegalis, cellulose ether such as hydroxypropyl cellulose, hydroxyethyl-cellulose, carboxymethyl cellulose etc.The concentration of this class thickening agent and viscosity modifier generally accounts for the 0.05-0.5% (weight) of discontinuous phase.

Other water solublity or water-dispersible composition that can be used for discontinuous water comprises the polycationic polymer that is used to make water-oily interface steric stabilization, and the non-ionic polymers that is used for the water-in-oil emulsion stabilisation.The polycationic polymer that is suitable for comprises Reten 201, Kymene557H  and Acco 7112.The non-ionic polymers that is suitable for comprises that Polyethylene Glycol (PEG) is as Carbowax.The concentration of this class polycation and non-ionic polymers generally accounts for the 0.1-1.0% of discontinuous phase.

The facial treatment milk that contains the emulsifying agent that can form described discontinuous phase and continuous phase emulsion in the preferred embodiment of the invention.In emulsion of the present invention, emulsifying agent is an effective dose." effective dose " will be decided on multiple factor, comprising the factors such as content of impurity in the type of the consumption of each oil-soluble constitents, used emulsifying agent, the emulsifying agent.Emulsifying agent generally accounts for the 0-20% (weight) of facial treatment milk, preferably is about 0.01-10% (weight), is more preferably 0.1-6% (weight).

Be applicable to that emulsifying agent of the present invention generally is oil-soluble, or emulsifying agent that can be miscible with continuous phase component (particularly under the fused temperature conditions of oil-soluble composition).Its HLB value also should be lower.The HLB value that is applicable to emulsifying agent of the present invention generally is about 1-7, and can comprise the mixture of different emulsifiers.The HLB value of preferred this class emulsifying agent is about 1.5-6, is more preferably 2-5.

The present invention can adopt numerous emulsifiers, comprising Isosorbide Dinitrate, glyceride, polyglycerin ester, methyl glucose ester, sucrose ester, ethoxylized fatty alcohol, castor oil hydrogenated ethoxylate, Isosorbide Dinitrate ethoxylate, polymer emulsifier and silicone emulsifiers, but be not limited only to this.

Isosorbide Dinitrate is applicable to the present invention.Preferred C16-C22 is saturated, the Isosorbide Dinitrate of undersaturated branched chain fatty acid.Because its conventional preparation method, generally contain in this class Isosorbide Dinitrate single-, two-, ester mixture such as three-ester.The instantiation of the Isosorbide Dinitrate that is suitable for comprises Arlacel-80 (for example SPAN  80), Arlacel-83 (for example Arlacel  83), anhydro sorbitol list isostearate (for example CRILL  6 of Croda product), sorbitan monostearate (for example SPAN  60), sorbitan trioleate (for example SPAN  85), Arlacel-65 (for example SPAN  65), anhydro sorbitol dipalmitate (for example SPAN  40), and the anhydro sorbitol isostearate.The particularly preferred emulsifying agent of the present invention is anhydro sorbitol list isostearate and Arlacel-83.

Other is applicable to that emulsifying agent of the present invention comprises monoglyceride, preferred C16-C22 is saturated, the monoglyceride of undersaturated branched chain fatty acid, as olein, glyceryl monostearate, monopalmitin, Dan behenic acid glyceride, and their mixture; C16-C22 is saturated, the polyglycerin ester of undersaturated branched chain fatty acid, as polyglycereol-4 isostearate, polyglycereol-3-oleate, single oleic acid two sweet esters, single oleic acid four sweet esters, and their mixture; Methyl glucose ester, preferred C16-C22 is saturated, the methyl glucose ester of undersaturated branched chain fatty acid, as two oleic acid methyl glucose esters, sesquialter isostearic acid methyl glucose ester, and their mixture; Sucrose fatty acid ester, preferred saturated, the undersaturated branched chain fatty acid sucrose ester of C12-C22, as stearic acid sucrose ester, three lauric acid sucrose ester, distearyl acid sucrose ester (for example Crodesta  F10), and their mixture; The C12-C22 ethoxylized fatty alcohol, as oleyl ether-2, oleyl ether-3, stearyl ether-2, and their mixture; Castor oil hydrogenated ethoxylate such as PEG-7 castor oil hydrogenated; Isosorbide Dinitrate ethoxylate such as the full oleate of PEG-40 anhydro sorbitol (peroleate), poly-Isosorbide Dinitrate-80, and their mixture; Polymer emulsifier such as ethoxylation dodecyl diol copolymer; And silicone emulsifiers, as lauryl methyl polysiloxanes polyol, cetyl dimethyl polysiloxane, dimethicone copolyol, and their mixture, but be not limited only to this.

Except that these main emulsifying agents, also can not necessarily contain coemulsifier in the present composition, in order to additional water-fat liquor stability to be provided.The coemulsifier that is suitable for comprises phosphatidylcholine and contains the compositions such as the lecithin of phosphatidyl choline; Long-chain C16-C22 soap such as sodium stearate; Long-chain C16-C22 two aliphatic series, short chain C1-C4 two aliphatic quaternary ammonium salts are as Varisoft DHT and two Adeps Bovis seu Bubali base dimethyl methyl ammonium sulfate; Long-chain C16-C22 two alkanoyls (enoyl-)-2-ethoxy, short chain C1-C4 two aliphatic quaternary ammonium salts are as two Adeps Bovis seu Bubali acyl group-2-hydroxyethyl dimethyl ammonium chloride; Long-chain C16-C22 two aliphatic imidazoline quaternary ammonium salts are as methyl isophthalic acid-Adeps Bovis seu Bubali acylamino-ethyl-2-Adeps Bovis seu Bubali imidazoline Methylsulfate and methyl isophthalic acid-oil base acylamino-ethyl-2-oil-based imidazoline Methylsulfate; Short chain C1-C4 two aliphatic series, long-chain C16-C22 monoester family benzyl quaternary ammonium salt, as dimethyl stearyl benzyl ammonium chloride, and synthetic phospholipid, as the amino propyl group pg dimonium chloride (available from the phospholipid PTS of Mona Industries) of stearoyl.

Deposition aid

Goods of the present invention also comprise based on water-insoluble substrate weight about 0.01% to about 10%, and preferred about 0.05% to about 7%, and more preferably from about 0.10% to about 5%, most preferably from about 0.15% to about 2% deposition aid.Preferably, deposition aid is a water dispersible." water dispersible " be meant deposition aid 25 ℃ with 0.1%, preferred 0.5%, more preferably in 1.0% the concentration water-soluble (distillatory or suitable).Though not necessarily, the preferred embodiment of the invention comprises deposition aid, when especially using water solublity skin care activity thing.

Bound by theory is not thought that deposition aid has strengthened in the cleaning course water solublity conditioner to the deposition of skin or hair, and is helped water solublity conditioner adhesiveness to skin and hair surface in rinse cycle.Usually, think that also these deposition aids are partially or even wholly by following mechanism generation effect: electrostatic attraction (mammalian skin is electronegative); Hydrophobic captivation (because skin is than water hydrophobic more); With in the presence of surfactant for water dispersible but in rinse cycle, become water-insoluble material.One or more deposition aids used herein can be respectively or are combined with surfactant or water solublity conditioner and to add to or immerse in the substrate.Deposition aid can be cationic, anionic, non-ionic or zwitterionic, and preferred cationic or non-ionic is more preferably cationic.Suitable deposition aid used herein is described in the United States Patent (USP) 5,588,752 of authorizing people such as Turner on November 8th, 1997; People's such as mandate on April 29th, 1997 Coffindaffer United States Patent (USP) 5624666; People's such as mandate on June 3rd, 1997 Fowler United States Patent (USP) 5635469; People's such as JIUYUE in 1997 mandate on the 30th Behrens United States Patent (USP) 5672576; Authorized Glenn, people's such as Jr. United States Patent (USP) 5716920 on February 10th, 1998; Authorized the United States Patent (USP) 5,720,964 of Murray on February 24th, 1998; With the United States Patent (USP) 5714446 of authorizing people such as Bartz on February 3rd, 1998; All documents are incorporated herein by reference in full.

" CTFA cosmetic composition handbook the 2nd edition (1992) is incorporated herein for reference, and it has described a large amount of deposition aids that are applicable to this.The limiting examples of the deposition aid that is suitable for comprises cationic polymer, non-ionic polymers, zeolite, clay and composition thereof.Cationic polymer especially is suitable for the deposition aid of making goods of the present invention, because think that they have the ability of electronegative skin surface of associating, thereby helps the various components in the prescription are remained in skin surface.In addition, think that cationic polymer and anion surfactant form agglomerate (as water-insoluble complex).

Its weight average molecular weight of this cationic polymer is generally at least about 5,000, usually at least about 10,000, and is lower than about 1,000 ten thousand.Preferable weight-average molecular weight is about 100,000 to about 500 ten thousand, more preferably from about 200,000 to about 200 ten thousand.Cationic polymer has the cation nitrogen moiety, as quaternary ammonium or cation amino part, or its mixture.Suitable cationic polymer is described in the United States Patent (USP) 5672576 that JIUYUE in 1997 was authorized people such as Behrens on the 30th; Authorized 5720964, two pieces of documents of United States Patent (USP) of Murray all to be incorporated herein for referencial use on February 24th, 1998.

Usually the cation nitrogen moiety can be used as the part existence of the substituent group or the total monomer units of cation hair-conditioning polymer.Therefore, cationic polymer can comprise monomeric unit that quaternary ammonium or cationic amine replace with here as the unitary bipolymer of unitary other non-cationic of spacer monomers, terpolymer etc.This base polymer is well known in the art, and (Estrin, Crosley and Haynes edit " CTFA cosmetic ingredient dictionary " the 3rd edition, cosmetics, washing goods and fragrance association company limited, Washington D.C., 1982) in can find a variety of.

Cation electrodeposition density is preferably at least about 0.3meq/g, more preferably at least about 0.6meq/g, more preferably at least about 1.0meq/g, most preferably at least about 1.2meq/g.The about usually 4meq/g of cation electrodeposition density or lower, more generally about 3meq/g or lower.The cation electrodeposition density of cationic polymer can be measured by the Kjeldahl method.The electric density that those skilled in the art will recognize that amido polymer in the final products changes with pH and amino isoelectric point, IP.Electric density should be in above-mentioned scope under the final pH value of using.

Any anionic counter-ion is applicable to this cationic polymer, as long as satisfy the water-soluble standard.The counter ion counterionsl gegenions that are suitable for comprise halogen ion (as Cl, Br, I or F, preferred Cl, Br or I), sulfate radical and methylsulfate.Other counter ion counterionsl gegenions also are suitable for, and should not be exclusiveness for example.

As mentioned above, this cationic polymer is a water dispersible.But this does not also mean that when goods moistening of the present invention and stirs and it must become soluble when producing foam.But preferably, cationic polymer is a dispersibility when spuming when goods moistening of the present invention and through stirring, perhaps handles water-insoluble substrate with cationic polymer mutually with the pre-complex coacervation that anionic species forms.This complex coacervation can be added to separately or be immersed in the substrate mutually, or is added to or immerses in the substrate with lathering surfactant or water solublity conditioner.The complex coacervate of cationic polymer can form with the anionic polymer (for example kayexalate) of the essential adding goods of anion surfactant inclusive NAND.It is generally acknowledged that complex coacervate is easier to the water solublity conditioning agent deposit on skin or hair.Therefore in the general preferred goods of the present invention/on cationic polymer exist mutually with complex coacervation, or can form condensed phase during through moistening and fricative foaming at the dilution goods.If cationic polymer does not form condensed phase in goods of the present invention or on the goods, the preferred cationic polymer exists with complex coacervation phase form when dilution.

Coacervate formulation depends on various standards, as ratio, ionic strength (comprise the ionic strength improvement, for example add salt), cation and anionic charge density, the pH of molecular weight, concentration and interaction ion component, and temperature.The effect of coacervated system and these parameters is known.For example referring to people such as J.Caelles " anion and cationic compound in the mixed system ", " cosmetics and washing goods " roll up in April, 106,1991, the 49-54 page or leaf; " cohesion, complex coacervation and the flocculation " of Van Oss, " dispersion science and technology ", volume 9 (5,6), 1988-89,561-573 page or leaf; " proximate analysis of complex coacervation system " of D.J.Burgess, " colloid and interface science ", volume 140, No.1, November nineteen ninety, 227-238 page or leaf; And United States Patent (USP) 5716920 (people such as Glenn Jr., on February 10th, 1998 authorized); All these documents all are incorporated herein by reference.

It is known in the art being used to analyze the technology that complex coacervate forms.For example can adopt foam (in selected arbitrarily dilution stage) micro analysis to determine whether to have formed condensed phase.This class condensed phase will determine it is additional emulsifying phase, can adopt dyestuff that condensed phase is distinguished mutually with insoluble in other is scattered in foam.

Nonionic that the present invention uses and cationic polymer comprise natural in synthetic.In natural polymer, very preferred derived from cellulose and proteinic those.In synthetic polymer, preferred polyethylene imine based and polyacrylamide.The common type of the deposition aid that uses in the goods of the present invention comprise natural gum, hydrophilic colloid and derivant thereof, biopolymer and derivant thereof, synthetic polymer, polyethers, protein and derivant thereof, quaternary ammonium compound, condensation product, and composition thereof.Below be the non-limiting of cation used herein and nonionic deposition aid

Embodiment.

Natural gum, hydrophilic colloid, biopolymer and proteinAnd composition thereof applicable to this as deposition aid.The limiting examples of these compositions comprises carboxymethyl hydroxyethyl cellulose, carboxy-methyl hydroxy propyl guar gum, carrageenin, cellulose gum, gelatin, guar gum, guar hydroxypropyl trimonium chloride, hydroxyethyl-cellulose, hydroxypropyl cellulose, hydroxypropyl emthylcellulose, methylcellulose, xanthan gum, chitin, chitosan, hydroxypropyl chitosan, potato starch, avenin, lactoprotein, cocoyl hydrolytic collagen, cocoyl hydrolysis of keratin, Hydroxyproyl Trimethyl ammonium gelatin, and their mixture.

Derived from cellulosic polymerBe applicable to that also this is as deposition aid.Here saidly be meant the polymer of cellulose main chain, promptly contain the polysaccharide main chain of glucose repeat units derived from cellulosic polymer.This class is derived from the cellulosic polymer, and the hydroxyl of cellulosic polymer forms the hydroxyalkylation cellulose through hydroxyalkylation (preferably through hydroxyethylation or hydroxypropylation), and it is through cation quaternary ammonium salt or the further modification of protonated ammonium.Preferably contain a C10-C20 alkyl chain at least, and on nitrogen-atoms, contain two short alkyl chains (being C1 or C2) through cation-modified group.Substituent group on the cellulosic polymer can be expressed as-(X) NRR ' R "; wherein X be hydroxyalkyl (preferably-OCH2CH2-or-OCH2CHOHCH2-); R and R ' are methyl or ethyl, and R " is C10-20 alkyl [preferred lauryl, stearyl or cocoyl the alkyl mixture of Oleum Cocois (promptly derived from)].In other alternative structure, find " also can obtain useful fiber element polymer when being methyl when (trimethyl ammonium group) as R, R ' and R.In an alternative structure again, cationic substituent on the cellulose contains ethoxy and hydroxypropyl simultaneously, for example can be expressed as-(OCH2CH20)-CH2CHOHCH2NRR ' R "; wherein R, R ' and R " are methyl or ethyl, " be C10-20 alkyl [preferred lauryl, stearyl or cocoyl the alkyl mixture of Oleum Cocois (promptly derived from)], perhaps wherein R, R ' and R " are methyl (being the trimethyl ammonium group) to and R.

Commercially availablely comprise through cation-modified cellulose: (wherein X is-OCH2CH2-lauryl dimethyl ammonium hydroxyethyl-cellulose in the following formula, R and R ' are methyl, and R " be lauryl); stearyl Dimethyl Ammonium hydroxyethyl-cellulose (wherein X is-OCH2CH2-in the following formula; R, R ' they are methyl and R " be stearyl), and cocoyl Dimethyl Ammonium hydroxyethyl-cellulose (wherein X is-OCH2CH2-in the following formula, and R and R ' they are methyl, and R " be cocoyl).The trade name of known these three kinds of compositions is respectively Crodacel QL, Crodacel QS, Crodacel QM, available from Croda company.The cationic cellulose of another kind of particularly suitable be lauryl dimethyl ammonium hydroxypropyl oxygen ethyl cellulose (wherein in the cellulose modification group be-(OCH2CH20)-CH2CHOHCH2NRR ' R "; wherein R and R ' they are methyl; R " be lauryl), it is the CRODACEL QLSPECIAL product available from Croda company.Other cationic cellulose that is suitable for can be available from Amerchol company (Edison, N.J., polymer JR USA) ^TN, LR ^TNAnd LK ^TNSeries polymer is the salt that the reaction of hydroxyethyl-cellulose and trimethyl ammonium substituted epoxide obtains, and (CTFA) is called polyquaternary ammonium salt 10 on the industry; Cation cellulose ether sees United States Patent (USP) 3816616,4272515, is the product available from the commodity Polymer Jr. by name of Union Carbide company; And the polyquaternary ammonium salt that obtains of hydroxyethyl-cellulose and lauryl dimethyl ammonium substituted epoxide reaction, (CTFA) is called polyquaternary ammonium salt 24 on the industry, is can be available from Amerchol company (Edison, N.J., the product of the polymer LM-200 by name of commodity USA).

Other is applicable to that this cationic polymer comprises the cationic guar gum derivant, and as disclosed cationic polygalactomannan gum derivative in United States Patent (USP) 4298494, commodity are called JAGUAR; The Hydroxyproyl Trimethyl ammonium derivative of guar gum, can trade name JAGUAR C-13-S and JAGUAR C-17 (CTFA called after guar hydroxypropyl trimonium chloride) be purchased; Hydroxypropylation cationic guar gum derivant is called JAGUAR C-16 (available from the Jaguar  series of Celanese company).Other composition comprises the plain ether of quaternized nitrogen-containing fiber (for example see United States Patent (USP) 3962418, in conjunction with in the present invention as a reference), and the copolymer of etherified cellulose and starch (for example see United States Patent (USP) 3958581, in conjunction with in the present invention as a reference).Particularly preferred cationic polymer comprises polyquaternary ammonium salt 10.

Relevant with the plain polymer of this fibrid is contains composition derived from other sugared main chain (or its acid of being correlated with, alcohol, amine etc.), for example galactose, mannose, arabinose, xylose, fucose, fructose, glycosamine, galactosamine, glucuronic acid, galacturonic acid, 5 or 6 yuan of cyclopolyols, and their mixture.

Derived from proteinic polymerIt is the derivant of another kind of suitable natural origin polymer.What be applicable to this can be derived from multiple proteins derived from proteinic polymer.But preferably it is derived from hydrolyzed protein (promptly resolving into the pulsating protein of the about 1000-5000 low-molecular-weight of weight average molecular weight).Hydrolyzed protein also is the chemicals that is applicable to cosmetics that those of ordinary skills know, and can adopt the standard synthetic technology to make, as adopts acid, alkali or enzyme that the multiple proteins source is hydrolyzed.Used protein source can determine the final aminoacid of gained hydrolyzed protein to form.Be useful in this non-limiting example and be selected from caseinhydrolysate, hydrolytic collagen, hydrolysis conchiolin, hydrolysis zein, elastin hydrolysis, hydrolysis fibronectin (fibronectin), hydrolysis hair-keratin, hydrlyzed human placental protein, hydrolysis of keratin, hydrolysis Rhizoma Solani tuber osi albumen, hydrolysed rice albumen, hydrolyzed silk protein, hydrolyzed soybean protein, hydrolyzed vegetable protein, hydrolysis wood albumen, hydrolyzed wheat protein as the aminosal of polymer, and their mixture.This class hydrolyzed protein see " the international cosmetic composition handbook of CTFA, 1991, the 246-249 page or leaf is in full in conjunction with in the present invention as a reference.

Discovery is made polymer of the present invention through cation-modified hydrolyzed protein particularly suitable.Can adopt the known synthetic technology of the various chemical field those of ordinary skill nitrogen-atoms hydroxyalkylation that this class hydrolyzed protein is amino acid contained (preferred hydroxyethylation or hydroxypropylation), to form the hydroxyalkylation protein hydrolysate, then through cation quaternary ammonium salt or the further modification of protonated ammonium group.Preferred cation modification group is the group that contains a C10-20 alkyl chain and two short-chain alkyls (being C1 or C2) on nitrogen-atoms at least.Substituent group on the hydrolyzed protein can be expressed as-(X) NRR ' R "; wherein X be hydroxyalkyl (preferably-OCH2CH2-or-OCH2CHOHCH2-); R and R ' are methyl or ethyl, and R " is C10-20 alkyl [preferred lauryl, stearyl or cocoyl the alkyl mixture of cocoa butter (promptly derived from)].In another alternative structure of the present invention, find " the cation hydrolysis albumen that also can obtain being suitable for when (trimethyl ammonium group) when being methyl as R, R ' and R.Commercially available cation-modified hydrolyzed protein comprises Hydroxyproyl Trimethyl ammonium caseinhydrolysate, Hydroxyproyl Trimethyl ammonium hydrolytic collagen, Hydroxyproyl Trimethyl ammonium hydrolysis of keratin, Hydroxyproyl Trimethyl ammonium hydrolyzed silk protein, Hydroxyproyl Trimethyl ammonium hydrolyzed soybean protein, Hydroxyproyl Trimethyl ammonium hydrolyzed vegetable protein, and Hydroxyproyl Trimethyl ammonium hydrolyzed wheat protein, on these protein hydrolysates-" in the substituent group; X is-OCH2CHOHCH2-, and R and R ' and R " are methyl for (X) NRR ' R.These hydrolyzed proteins see " the international cosmetic composition handbook of CTFA, 1991, the 254-255 page or leaf is in full in conjunction with in the present invention as a reference.Other commercially available cation-modified protein hydrolysate comprises lauryl dimethyl ammonium hydroxypropyl hydrolytic collagen, lauryl dimethyl ammonium hydroxypropyl hydrolysis of keratin, lauryl dimethyl ammonium hydroxypropyl hydrolyzed silk protein, lauryl dimethyl ammonium hydroxypropyl hydrolyzed soybean protein, stearyl Dimethyl Ammonium hydroxypropyl casein, stearyl Dimethyl Ammonium hydroxypropyl hydrolytic collagen, stearyl Dimethyl Ammonium hydroxypropyl hydrolysis of keratin, stearyl dimethyl hydroxypropyl ammonium rice protein, stearyl Dimethyl Ammonium hydroxypropyl hydrolyzed silk protein, stearyl Dimethyl Ammonium hydroxypropyl hydrolyzed vegetable protein, stearyl Dimethyl Ammonium hydroxypropyl hydrolyzed wheat protein, cocoyl Dimethyl Ammonium hydroxypropyl caseinhydrolysate, cocoyl Dimethyl Ammonium hydroxypropyl hydrolytic collagen, cocoyl Dimethyl Ammonium hydroxypropyl hydrolysis of keratin, cocoyl Dimethyl Ammonium hydroxypropyl hydrolysed rice albumen, cocoyl Dimethyl Ammonium hydroxypropyl hydrolyzed silk protein, cocoyl Dimethyl Ammonium hydroxypropyl hydrolyzed soybean protein, cocoyl Dimethyl Ammonium hydroxypropyl hydrolyzed wheat protein, on these protein hydrolysates-(X) NRR ' R " in the substituent group; X is-OCH2CHOHCH2-; and R and R ' be methyl, R " is lauryl or stearyl or cocoyl.These hydrolyzed proteins see " the international cosmetic composition handbook of CTFA, 1991,112-113,293-294,586 pages are in full in conjunction with in the present invention as a reference.Preferred lauryl dimethyl ammonium hydroxypropyl hydrolytic collagen, lauryl dimethyl ammonium hydroxypropyl hydrolysis of keratin, lauryl dimethyl ammonium hydroxypropyl hydrolyzed silk protein, lauryl dimethyl ammonium hydroxypropyl hydrolyzed soybean protein in these cation hydrolysis albumen, and their mixture.

Polymer etherAlso be applicable to this as deposition aid, as long as its number of repeat unit is greater than 50.This constituents is known Polyethylene Glycol and polypropylene glycol (CTFA is called after PEG and PPG respectively).The non-limiting example of this constituents comprises PEG 25M, PEG 75, PEG 90, PEG 100, PEG 2M, PEG 7M, PEG 14M and their mixture.

Synthetic cationic polymers and copolymerBe applicable to that also this is as deposition aid.The cationic polymer that is suitable for comprises for example ethylene monomer copolymer, wherein have cationic amine or quaternary ammonium functional group and water solublity spacer monomers, spacer monomers such as acrylamide, Methacrylamide, alkyl and dialkyl group acrylamide, alkyl and dialkyl methyl acrylamide, alkyl acrylate, alkyl methacrylate, vinyl caprolactone, vinyl pyrrolidone.The monomer that replaces through alkyl and dialkyl group preferably contains C1-C7 alkyl, more preferably C1-C3 alkyl.Other spacer monomers that is suitable for comprises vinyl esters, vinyl alcohol (making through the hydrolysis of polyvinyl acetate base ester), maleic anhydride, propylene glycol and ethylene glycol.

Cationic amine can be primary, the second month in a season or tertiary amine, decides on the concrete kind and the pH of shampoo.General preferred secondary amine and tertiary amine, particularly tertiary amine.

The vinyl monomer that amine replaces can amine the form polymerization, can not necessarily change into ammonium salt then through quaterisation.Also can after making polymer, carry out similar quaternized to amine.For example the reactant salt of tertiary amine functional group and formula R ' X can be carried out quaternizedly, wherein R ' is a short-chain alkyl, and preferably the C1-C7 alkyl is more preferably the C1-C3 alkyl, and X is the anion that can form water soluble salt with quaternary ammonium salt.

The cation amino and the quaternary ammonium salt monomer that are suitable for for example comprise: by propenoic acid dialkyl aminoalkyl ester; the methacrylic acid dialkyl aminoalkyl ester; acrylic acid alkyl monosubstituted amino Arrcostab; methacrylic acid alkyl monosubstituted amino Arrcostab; trialkyl methacryl oxyalkyl ammonium salt; trialkyl acryloyl group oxyalkyl ammonium salt; the vinyl compound that diallyl quaternary ammonium salt and vinyl quaternary ammonium salt monomer replace; therein ethylene based quaternary ammonium salt monomer contains the cationic nitrogenous ring structure; as pyridine; imidazoline; and quaternized ketopyrrolidine, for example alkyl vinyl imidazoline; alkylvinylpyridines; alkyl vinyl ketopyrrolidine salt.These monomer moieties are low alkyl group preferably, as the C1-C3 alkyl, is more preferably the C1-C2 alkyl.

The vinyl monomer that is applicable to this amine replacement comprises propenoic acid dialkyl aminoalkyl ester, methacrylic acid dialkyl aminoalkyl ester, dialkyl aminoalkyl acrylamide, and dialkyl aminoalkyl Methacrylamide, wherein alkyl C1-C7 alkyl preferably is more preferably the C1=C3 alkyl.

The cationic polymer here can contain derived from amine-and/or the monomer that replaces of quaternary ammonium salt and/or mixture of the monomeric monomeric unit of compatible spacer.

The synthetic cationic polymers that is suitable for for example comprises: the copolymer of l-vinyl-2-pyrrolidone and 1-vinyl-3-Methylimidazole. quinoline salt (for example chloride salt) (being called polyquaternary ammonium salt-16 by cosmetics, washing goods and fragrance association " CTFA " on industry), this series products can be available from the BASF Wyandotte (Parsippany of company, N.J., the product (for example Luviquat FC 370) of the Luviquat by name of commodity USA); The copolymer (being called polyquaternary ammonium salt-11 on the CTFA industry) of l-vinyl-2-pyrrolidone and dimethylaminoethyl acrylate methyl base amino-ethyl ester, for example see the description of United States Patent (USP) 4080310, and can be available from (the Wayne of ISP company, N.J., USA) commodity are called the product of Gafquat (for example, Gafquat 755 and 755N); The polymer of cation diallyl quaternary ammonium salt for example comprises the dimethyl diallyl ammonium chloride homopolymer, and the copolymer of acrylamide and dimethyl diallyl ammonium chloride (being called polyquaternary ammonium salt 6 and polyquaternary ammonium salt 7 on the CTFA industry); Contain the inorganic acid salt of the amino-Arrcostab of the unsaturated carboxylic acid homopolymer of 3-5 carbon atom or copolymer, see United States Patent (USP) 4009256; Contain the grafting cation copolymer of N-vinyl pyrrolidone, dimethylaminoethyl acrylate methyl base amino-ethyl ester and Polyethylene Glycol, see United States Patent (USP) 4048301; The etherification starch polymer sees United States Patent (USP) 3186911; The PAMC constituents sees UK Patent Application 94031565.4; Macromolecule cation polymer, CTFA called after quaternary ammonium salt-40 (high electric charge cation dimethyl diallyl ammonium chloride homopolymer) and quaternary ammonium salt-41 (the high electric charge cation copolymer of being made by dimethyl diallyl ammonium chloride and acrylamide) are can be available from Merck ﹠amp; Com., the product of the commodity of Inc. MERQUAT 100 by name and MERQUAT 550; And their mixture.The non-limiting example of the synthetic polymer that other is suitable for comprises acrylate/acrylic acid C10-30 alkyl ester cross-linked polymer, acrylate copolymer, acrylate/PVP copolymer, acrylate/VA copolymer, butylation polyoxymethylene urea, butylation PVP, carbopol, ethoxy PEI-1000, the methyl methacrylate cross linked polymer, PEI-1000, PEI-1500, PEI-2500, polybutene, polyacrylamide, polyacrylic acid, polyethylene, polyisobutylene, polymethyl methacrylate, polystyrene, polyvinyl alcohol, PVP, PVP/ eicosylene copolymer, the PVP/VA copolymer, sodium acrylate copolymer, carbopol sodium copolymer, sodium polyacrylate, sodium polymethacrylate, styrene/PVP copolymer, triethanolamine carbopol, and their mixture.

Other polymer:Other polymer that is suitable for comprises polyvinyl pyrrolidone and vinylpyrrolidone copolymer, as contain the composition of vinyl-acetic ester, dimethylaminoethyl acrylate methyl base amino-ethyl ester, and the quaternized form of they and Methylsulfate, and the polymer of vinyl alcohol and vinyl-acetic ester and copolymer.The polymer of other particularly suitable is the protonated form of poly-piperazine.Poly-piperazine is formed by the piperazine polymerization.The molecular weight that is applicable to this protonated poly-piperazine polymer preferably is about 500,000-750,000, there is the side chain form, wherein primary, the ratio of the second month in a season and uncle's nitrogen is about 1: 2: 1, average every approximately 3-3.5 atom has uncle's nitrogen to occur, and charge density is about 20meq/g under the pH4.5 condition, and density is about 1070kg/m ³, viscosity should be 17,000-28,000 milli handkerchief.The protonated poly-piperazine polymer that meets this standard is can be available from the product of the POLYMIN P by name of BASF AG.

Cationic surfactant (non-polymeric type)Also can be used as the deposition aid here, as long as these materials do not disturb the whole frothing capacity of required lathering surfactant.The cationic surfactant here contains amino or quaternary ammonium hydrophilic segment, is positively charged when it is dissolved in the Aquo-composition of the present invention.Cationic surfactant used herein is disclosed in the following document, and all documents are incorporated herein for reference: " detergent of McCutcheon and the emulsifying agent " of M.C.Publishing Co., North America version, 1979; People's such as Schwartz " surfactant and chemistry thereof and technology ", New York, Interscience Publishers, 1949; Authorized the United States Patent (USP) 3155591 of Hilfer on November 3rd, 1964; People's such as December in 1975 mandate on the 30th Laughlin United States Patent (USP) 3929678; People's such as mandate on May 25th, 1976 Bailey United States Patent (USP) 3959461; People's such as mandate on June 23rd, 1981 Nachtigal United States Patent (USP) 4275055; Authorize Bolich, the United States Patent (USP) 4387090 of Jr. June 7 nineteen eighty-three; People's such as mandate on November 3rd, 1987 Oh United States Patent (USP) 4704272; People's such as mandate on July 23rd, 1991 Duvel United States Patent (USP) 5034218; People's such as JIUYUE in 1993 mandate on the 14th Raleigh United States Patent (USP) 5393452; People's such as JIUYUE in 1997 mandate on the 30th Behrens United States Patent (USP) 5672576; People's such as mandate on February 3rd, 1998 Bartz United States Patent (USP) 5714446.

The cationic surfactant that contains quaternary ammonium among the present invention comprises following material:

Wherein R1-R4 independently is selected from aromatic group, aryl, alkoxyl, polyoxy alkylidene, alkylamidoalkyl, hydroxyalkyl or the alkaryl of hydrogen, the aliphatic group of the about C22 of about C1-, the about C22 of about C1-; X is an anion, is selected from halogen ion, acetate, phosphate radical, nitrate anion, sulfate radical, alkyl sulfate (as methylsulfate and ethyl sulphate), tosylate, lactate, citrate, glycol acid radical.Except carbon and hydrogen atom, also can contain ehter bond in the aliphatic group in addition, or as hydroxyl or amino substituent other group (for example can contain Polyethylene Glycol and polypropylene glycol structure division in the alkyl).Long-chain aliphatic group (for example containing 12 carbon atoms or more of having an appointment) can be saturated or unsaturated.

More preferably R1 is the alkyl that contains 12-18 carbon atom approximately; R2 is selected from hydrogen or contains the alkyl of 1-18 carbon atom approximately; R3 and R4 are independently from each other hydrogen or contain the alkyl of 1-3 carbon atom approximately; X definition is as described in the preceding paragraph.

Most preferably R1 is the alkyl that contains 12-18 carbon atom approximately; R2, R3 and R4 are selected from hydrogen or contain the alkyl of 1-3 carbon atom approximately; X definition is as described in the preceding paragraph.

Other cationic surfactant that is suitable for also comprises: amino amides, and wherein R1 also can be R5CO-(CH2) n-in the said structure formula, and wherein R5 is the alkyl that contains 12-22 carbon atom approximately, and n is the integer of about 2-6, is more preferably 2-4, is most preferably 2-3.The non-limiting example of this cationoid emulsifying agent comprises: the amino propyl group PG-of stearoyl dimethyl chlorination ammonium phosphate, the amino propyl group ethyl of stearoyl Dimethyl Ammonium ethyl-sulfate, amino propyl-dimethyl (the acetic acid Semen Myristicae alcohol ester) ammonium chloride of stearoyl, the amino propyl-dimethyl spermaceti of stearoyl-stearyl ammonium tosylate, the amino propyl-dimethyl ammonium chloride of stearoyl, the amino propyl-dimethyl DL-Lactic acid ammonium salt. of stearoyl, and their mixture.

The non-limiting example of quaternary cationics comprises: cetyl ammonium chloride, cetyl bromination ammonium, lauryl chlorination ammonium, lauryl bromination ammonium, stearyl chlorination ammonium, the stearyl ammonium bromide, the cetyl alkyl dimethyl ammonium chloride, cetyl dimethyl ammonium bromide, lauryl dimethyl ammonium chloride, the lauryl dimethyl ammonium bromide, the stearyl alkyl dimethyl ammonium chloride, stearyl dimethyl ammonium bromide, the cetyl trimethyl ammonium chloride, the cetyl trimethylammonium bromide, lauryl trimethyl ammonium chloride, the lauryl trimethylammonium bromide, the stearyl trimethyl ammonium chloride, the stearyl trimethylammonium bromide, stearyl dimethyl cetyl Varisoft DHT, two cetyl ammonium chloride, two cetyl bromination ammoniums, dilauryl ammonium chloride, the dilauryl ammonium bromide, distearyl ammonium chloride, the distearyl ammonium bromide, two cetyl ammonio methacrylates, two cetyl methyl ammonium bromide, the dilauryl ammonio methacrylate, dilauryl methyl ammonium bromide, the distearyl ammonio methacrylate, VARISOFT TA100, distearyl methyl ammonium bromide and their mixture.Other quaternary ammonium salt comprises that wherein C12-22 carbon atom carbochain is derived from tallow fatty acids or fatty acid distribution of coconut oil.Term " Adeps Bovis seu Bubali " is meant the alkyl (generally being hydrogenated tallow fatty acid) derived from tallow fatty acids, generally is the mixture of C16-C18 alkyl chain.Term " cocos nucifera oil " is meant the alkyl derived from fatty acid distribution of coconut oil, generally is the mixture of C12-C14 alkyl chain.Example derived from the quaternary ammonium salt of Adeps Bovis seu Bubali and cocos nucifera oil comprises two tallow dimethyl ammonium chlorides, two Adeps Bovis seu Bubali dimethyl methyl ammonium sulfate, two (hydrogenated tallow) alkyl dimethyl ammonium chloride, two (hydrogenated tallow) dimethyl acetic acid ammonium, two Adeps Bovis seu Bubali dipropyl ammonium phosphate, two Adeps Bovis seu Bubali dimethyl ammonium nitrates, two (cocos nucifera oil alkyl) alkyl dimethyl ammonium chloride, two (cocos nucifera oil alkyl) dimethyl ammonium bromide, Adeps Bovis seu Bubali ammonium chloride, cocos nucifera oil ammonium chloride, the amino propyl chloride PG of stearoyl dimethyl ammonium phosphate, the amino propyl group ethyl of stearoyl Dimethyl Ammonium ethyl-sulfate, amino propyl-dimethyl (the acetic acid Semen Myristicae alcohol ester) ammonium chloride of stearoyl, the amino propyl-dimethyl spermaceti of stearoyl-stearyl ammonium tosylate, the amino propyl-dimethyl ammonium chloride of stearoyl, the amino propyl-dimethyl DL-Lactic acid ammonium salt. of stearoyl, and their mixture.

The preferred cationic surfactant that is applicable to this comprises: dilauryl alkyl dimethyl ammonium chloride, VARISOFT TA100, myristyl alkyl dimethyl ammonium chloride, two palmityl alkyl dimethyl ammonium chlorides, VARISOFT TA100, and their mixture.

Be applicable in this cationic polymer, hydroxyethyl-cellulose preferably, hydroxypropyl cellulose, lauryl dimethyl ammonium hydroxypropyl oxygen ethyl cellulose, lauryl dimethyl amine hydroxyethyl-cellulose, stearyl Dimethyl Ammonium hydroxyethyl-cellulose, cocoyl Dimethyl Ammonium hydroxyethyl-cellulose, the hydroxypropyl hydrolytic collagen, lauryl dimethyl ammonium hydroxypropyl hydrolysis of keratin, lauryl dimethyl ammonium hydroxypropyl hydrolysis of keratin, lauryl dimethyl ammonium hydroxypropyl hydrolyzed silk protein, lauryl dimethyl ammonium hydroxypropyl hydrolyzed soybean protein, protonated poly-piperazine, polyquaternary ammonium salt 10, and their mixture.More preferably lauryl dimethyl ammonium hydroxypropyl hydrolytic collagen, lauryl dimethyl ammonium hydroxypropyl oxygen ethyl cellulose, and their mixture.Preferred deposition aid is selected from hydroxyalkyl cellulose ether and cationic guar gum derivant.Particularly preferred deposition aid is JAGUAR C13S, and its cationic charge density is 0.8meq/g.Other particularly preferred composition comprises JAGUAR C15, JAGUAR C17, JAGUAR C16, JAGUAR C162, polyquaternary ammonium salt 10, and their mixture.Polyquaternary ammonium salt 10 (for example polymer JR400 and polymer JR30M) most preferably.

Be applicable to selective hydrolysis casein, hydrolytic collagen, hydrolyzed vegetable protein, guar gum, polyvinyl pyrrolidone, PEG 14M in this non-ionic polymers, and their mixture.More preferably PEG 14M and caseinhydrolysate.

Weight ratio and percetage by weight

The weight ratio of lathering surfactant and skin care activity thing is about 1000: 1 to about 1: 1 among the present invention, preferred about 800: 1 to about 2: 1, and more preferably from about 500: 1 to about 3: 1.

Other composition

Goods of the present invention can comprise a large amount of nonessential compositions.In these compositions some are listed in this in more detail.What especially be suitable for is the various active composition that various conditioning benefit are provided in cleaning course.In these compositionss, goods also are used for providing these conditioning ingredients to skin or hair.

Conditioning component

Can optionally comprise conditioning component in the goods of the present invention, this conditioning component can provide conditioning benefit as skin or hair when using goods of the present invention.Here " conditioning benefit " described a kind of ability the material (as chemical compound or compositions), promptly improves the outward appearance and/or the sensation of mammal skin by following one or more mechanism (as rinsing and pat dry the back) a part or whole part ground after local application: humidification, hydration, softening, lubricated and inaccessible pore.The limiting examples of suitably following the material of these mechanism be described in " CTFA cosmetic composition handbook, the 2nd edition, 1992, be incorporated herein for reference.Comprise the 0.05-99% (weight) that accounts for water-insoluble substrate in the goods of the present invention, preferably be about 0.1-50% (weight), be more preferably the conditioning component of 1-25% (weight).

Conditioning component of the present invention can comprise: the water solublity conditioner; The oil-soluble conditioner; Conditioning emulsion; Or three's any combination or arrangement.Conditioning emulsion is meant the conditioner that appears in the above-mentioned facial treatment milk, for example appears in water solublity discontinuous phase or the oil-soluble continuous phase.The oil-soluble conditioner is selected from one or more oil-soluble conditioners, makes the weighted arithmetic mean of oil-soluble conditioner solubility parameter be less than or equal to 10.5.The water solublity conditioner is selected from one or more water solublity conditioners, makes the weighted arithmetic mean of water solublity conditioner solubility parameter greater than 10.5.Solubility parameter based on this mathematical definition, for example when conditioner contains two or more chemical compound, wherein a kind of independent solubility parameter of chemical compound can obtain the weighted arithmetic mean of the solubility parameter of required conditioner greater than 10.5, promptly is less than or equal to 10.5.On the contrary, when conditioner contained two or more chemical compound, wherein a kind of independent solubility parameter of chemical compound was less than or equal to 10.5, can obtain the weighted arithmetic mean of the solubility parameter of required conditioner, promptly greater than 10.5.The solubility parameter of conditioner can be determined by the method for describing in skin care activity component part.

The non-limiting example that is suitable for the conditioner of making the oil-soluble conditioner comprises mineral oil, vaseline, the C7-C40 branched-chain hydrocarbons, the C1-C30 alcohol ester of C1-C30 fatty acid, the C1-C30 alcohol ester of C2-C30 dicarboxylic acids, C1-C30 carboxylic acid monoglyceride, C1-C30 carboxylic acid two sweet esters, C1-C30 carboxylic acid triglyceride, C1-C30 carboxylic acid ethylene glycol ester, C1-C30 carboxylic acid ethylene glycol diester, C1-C30 carboxylic acid propylene glycol monoester, C1-C30 carboxylic acid propylene glycol diesters, C1-C30 carboxylic acid sugar monoesters and sugared polyester, polydialkysiloxane, poly-diaromatic siloxane, poly-alkaryl siloxanes, the cyclohexyl methyl polysiloxanes that contains 3-9 silicon atom, vegetable oil, hydrogenated vegetable oil, polypropylene glycol C4-C20 alkyl ether, two C8-C30 alkyl ethers, and their mixture.

Mineral oil is also referred to as liquid petrolatum, is the liquid hydrocarbon mixture that is obtained by oil.Referring to " Merck index " the 10th edition, 7048,1033 pages (nineteen eighty-three) and " 415-417 page or leaf (1997) is in conjunction with in the present invention as a reference for international cosmetic composition handbook the 5th edition, volume 1.

Vaseline is also referred to as mineral jelly, is the colloidal state system of non-straight chain solid hydrocarbons and high-melting-point liquid hydrocarbon, and wherein most liquid hydrocarbons are retained in micelle inside.Referring to " Merck index " the 10th edition, 7047,1033 pages (nineteen eighty-three); " medicine and the cosmetics industry " of Shindler, 89,36-37,76,78-80,82 (1961); " international cosmetic composition handbook the 5th edition is rolled up 1,537 page (1993), in conjunction with in the present invention as a reference.

The straight or branched alkane that contains 7-40 carbon atom approximately is applicable to the present invention.The non-limiting example of this class hydrocarbon materials comprises dodecane, Fancol ID, squalane, cholesterol, Parleam, docosane (promptly, the C22 hydrocarbon), hexadecane, 2-Methylpentadecane (commercially available hydrocarbon, available from Presperse (South Plainfield, Permethyl  101A NJ)).The C7-C40 isoparaffin also is suitable for, and it is the C7-C40 branched paraffin.

The C1-C30 alcohol ester of C1-C30 carboxylic acid and the C1-C30 alcohol ester of C2-C30 dicarboxylic acids also are suitable for, and comprise straight chain and side chain and aromatic derivative.C1-C30 carboxylic acid monoglyceride, C1-C30 carboxylic acid two sweet esters, C1-C30 carboxylic acid triglyceride, C1-C30 carboxylic acid ethylene glycol ester, C1-C30 carboxylic acid ethylene glycol diester, C1-C30 carboxylic acid propylene glycol monoester, C1-C30 carboxylic acid propylene glycol diesters also are suitable for.In straight chain, side chain and aryl carboxylic acid are also included within.The propoxylation of these compositions and ethoxylated derivative also are suitable for.Its non-limiting example comprises Dermol DIPS, diisopropyl adipate, isopropyl myristate, isopropyl palmitate, propanoic acid tetradecyl alchohol ester, glycol distearate, Palmic acid 2-Octyl Nitrite, Dermol 105, di-2-ethylhexyl maleate, cetin, myristic acid tetradecyl alchohol ester, geoceric acid stearyl alcohol ester, stearic acid spermaceti alcohol ester, behenic acid docosane alcohol ester, di-2-ethylhexyl maleate, di-n-octyl sebacate, diisopropyl adipate, sad spermaceti alcohol ester, the dilinoleic acid diisopropyl ester, the caprylic/capric triglyceride, PEG-6 caprylic/capric triglyceride, PEG-8 caprylic/capric triglyceride, the ricinoleic acid cetyl, the hydroxy stearic acid cholesterol ester, isostearic acid cholesterol ester, and their mixture.

Various C1-C30 monoglycerides, how sweet ester and relevant composition also are suitable for.This class ester can be derived from glycerol and one or more carboxylic moiety.According to the acid and the glycerol that constitute, this class ester at room temperature can be liquid or solid.The non-limiting example of solid esters comprises: three behenic acid glyceride, tristerin, tripalmitin, distearin, glycerol-1,3-dipalmitate.

Various C1-C30 sugar monoesters also use with sugared polyester and relevant composition.This class ester is derived from sugar or polyol moiety and one or more carboxylic moiety.According to the acid that constitutes and sugared, this class ester at room temperature can be liquid or solid.The example of liquid ester comprises: four oleic acid glucose esters, soya fatty acid glucose four esters (unsaturated), mixed soya fatty acid mannose four esters, oleic acid galactose four esters, linoleic acid arabinose four esters, four linoleic acid xylose esters, five oleic acid gala sugar esters, four oleic acid sorbitol esters, unsaturated soya fatty acid sorbitol six esters, the five oleic acid esters of xylitol, four oleic acid sucrose ester, five oleic acid sucrose ester, six oleic acid sucrose ester, seven oleic acid sucrose ester, eight oleic acid sucrose ester, and their mixture.The example of solid ester comprises: sorbitol six esters, and wherein carboxylate moiety is that mol ratio is 1: 2 palm acid ester and an Arachidate; The Raffinose octaester, wherein carboxylate moiety is that mol ratio is 1: 3 linoleic acid and a behenic acid; Maltose seven esters, wherein esterification carboxylic moiety are that mol ratio is 3: 4 Oleum Helianthi fatty acid and a haze tallow acid esters; Sucrose octaester, wherein esterification carboxylic moiety are that mol ratio is that 2: 6 oleate is with the behenic acid ester; Sucrose octaester, wherein esterification carboxylic moiety are that mol ratio is 1: 3: 4 laurate, linoleate He a behenic acid ester.Preferred solid material is a sucrose polyfatty acid esters, and wherein esterification degree is 7-8, that wherein fatty acid part is C18 is single-/or two-unsaturated fatty acid ester with behenic acid, wherein unsaturated fatty acid ester is Yu the mol ratio of behenic acid is 1: 7 to 3: 5.Particularly preferred sugar cube polyester is the sucrose octaester, contains 7 docosyl fatty acid parts and 1 oleic acid part in its molecule approximately.Other composition comprises Oleum Gossypii semen or soya fatty acid sucrose ester.This class esters composition also sees United States Patent (USP) 2831854, United States Patent (USP) 4005196 (Jandacek, on January 25th, 1977 authorized); United States Patent (USP) 4005195 (Jandacek, on January 25th, 1977 authorized), United States Patent (USP) 5306516 people such as (, on April 26th, 1994 authorized) Letton; United States Patent (USP) 5306515 (people such as Letton, on April 26th, 1994 authorized); United States Patent (USP) 5305514 (people such as Letton, on April 26th, 1994 authorized); United States Patent (USP) 4797300 (people such as Jandacek, on January 10th, 1989 authorized); United States Patent (USP) 3963699 (people such as Rizzi, on June 15th, 1976 authorized); United States Patent (USP) 4518772 (Volpenhein, on May 21st, 1985 authorized); United States Patent (USP) 4517360 (Volpenhein, on May 21st, 1985 authorized); All in conjunction with in the present invention as a reference.

Non-volatile polysiloxanes such as polydialkysiloxane, poly-diaromatic siloxane and poly-alkaryl siloxanes also are the oils compositions that is suitable for.These polysiloxanes see United States Patent (USP) 5069897 (Orr, on December 3rd, 1991), and combination in the present invention as a reference in full.The chemical general formula of poly-alkylsiloxane is R3SiO[R2SiO] xSiR3, wherein R is alkyl (preferred R is methyl or ethyl, is more preferably methyl), x is about 500 integer at the most, to reach required molecular weight.Commercially available poly-alkylsiloxane comprises polydimethylsiloxane, is also referred to as dimethicone, and its non-limiting example comprises the VICASIL  that General Electric Co. Limited sells, and DOW CORNING  200 series of products of being sold by Dow Corning Corporation.The instantiation that is applicable to this polydimethylsiloxane comprises that viscosity is that 10 centistokes, boiling point are higher than 200 ℃ DOWCORNING  225 fluids, and viscosity is respectively 50,350 and 12500 centistokes, boiling point is higher than 200 ℃ DOW CORNING  200 fluids.The composition that is suitable for also comprises the trimethylsiloxy esters of silicon acis, and wherein component of polymer is corresponding to chemical general formula [(CH2) 3SiO1/2] x[SiO2] y, wherein x is the integer that is about 1-500, y is the integer that is about 1-500.Commercially available trimethylsiloxy esters of silicon acis is to sell with DOW CORNING  593 fluids of the form of mixtures of polydimethylsiloxane.Be applicable to the dimethiconol that also comprises of the present invention, it is the polydimethylsiloxane of contain hydroxy end groups.The chemical general formula of this constituents is R3SiO[R2SiO] xSiR2OH and HOR2SiO[R2SiO] _xSiR2OH, wherein R be alkyl (preferred R be methyl or and, be more preferably methyl), x is about 500 integer at the most, and it is selected to reach required molecular weight.Commercially available dimethiconol is generally to sell (for example, DOW CORNING  1401,1402 and 1403 fluids) with the form of mixtures of polydimethylsiloxane or cyclohexyl methyl polysiloxanes.Be applicable to the poly-alkaryl siloxanes of also having of this, preferred 25 ℃ of following viscosity are about the PSI of 15-65 centistoke.This constituents is commercially available, as SF 1075 aminomethyl phenyl fluids (being sold by General Electric Co. Limited) and 556 cosmetics-stage phenyl trimethyl polysiloxane fluids (being sold by Dow Corning Corporation).

Vegetable oil and hydrogenated vegetable oil also are applicable to this.The example of vegetable oil and hydrogenated vegetable oil comprises safflower oil, Oleum Ricini, Oleum Cocois, Oleum Gossypii semen, pilchardine, palm-kernel oil, Petiolus Trachycarpi oil, Oleum Arachidis hypogaeae semen, soybean oil, Oleum Brassicae campestris, Semen Lini oil, Testa oryzae oil, Oleum Pini, Oleum sesami, Oleum Helianthi, hydrogenation safflower oil, castor oil hydrogenated, hydrogenated coconut oil, cotmar, hydrogenation pilchardine, hydrogenated palm kernel oil, hydrogenated palm oil, hydrogenated groundnut, oil with hydrogenated soybean, hydrogenated rapeseed oil, hydrogenation Semen Lini oil, hydrogenation Testa oryzae oil, hydrogenation Oleum sesami, hydrogenation Oleum Helianthi, and their mixture.

Polypropylene glycol C4-C20 alkyl ether, polypropylene glycol C1-C20 carboxylate, and two-C8-C30 alkyl ether also is suitable for.The non-limiting example of this constituents comprises the PPG-14 butyl ether, PPG-15 stearyl ether, dicaprylyl ether, dodecyl Octyl Ether, and their mixture.

Other oil-soluble conditioner that is suitable for comprises CREMEROL (available from Amerchol), ELDEWCL301 (available from Ajinomoto), MODULAN (available from the acetylated lanolin of Croda), OHLAN (available from the hydroxylated lanolin of Amerchol), phytantriol (phytantriol), suprasterol ester (super sterol ester) as C1-C30 cholesterol/lanosterol ester (available from Croda), and composition thereof.

The non-limiting example of the water solublity conditioner that is suitable for comprises polyhydroxy-alcohol, polypropylene glycol, Polyethylene Glycol, carbamide, 2-pyrrolidone-5-carboxylic acid, ethoxylation and/or propoxylation C3-C6 two pure and mild triols, Alpha-hydroxy C2-C6 carboxylic acid, ethoxylation and/or propoxylation sugar, acrylic copolymer, the highest sugar of 12 carbon atoms, the highest sugar alcohol that contains 12 carbon atoms approximately of containing approximately, and their mixture.The instantiation of the water solublity conditioner that is suitable for comprises following composition such as urea; Guanidine; Glycolic and glycollate (for example ammonium salt or quaternized alkylammonium salt); Lactic acid and lactate (for example ammonium salt or quaternized alkylammonium salt); Sucrose, fructose, glucose, eruthrose, erythritol, sorbitol, xylitol, glycerol, hexanetriol, propylene glycol, butanediol, hexanediol etc.Polyethylene Glycol such as PEG-2, PEG-3, PEG-4, PEG-5, PEG-6, PEG-8, PEG-9, PEG-10, PEG-15, PEG-30, PEG-50, polypropylene glycol such as PPG-9, PPG-12, PPG-15, PPG-17, PPG-20, PPG-26, PPG-30, PPG-34; The alkoxylate glucose; Hyaluronic acid; And their mixture.The composition that is suitable for also comprises the Lu Yun (for example Lu Yun gel), chitin of various dosage forms, starch-grafted sodium polyacrylate, as SANWET (RTM) IM-1000, IM-1500 and IM-2500 (available from Celanese Superabsorbent Materials, Portsmouth, VA); The lactamide monoethanolamine; The acetamide monoethanolamine; And their mixture.What be suitable for also has propoxylated glycerol, sees United States Patent (USP) 4976953 (people such as Orr, nineteen ninety December 11 days), in conjunction with in the present invention as a reference.Other water solublity conditioner that is suitable for comprises arginine; arginine aspartate (available from Ajinomoto); ARGININE PCA (available from Argidone-UCIB); 1; the 3-butanediol; CHITOLAM NB/101 (available from Lamberti); chitosan salts; collagen amino acid (available from Crotein CAA-Croda); creatine; glucosan; dextrin; two glycerol; dipropylene glycol; erithritol; FUCOGEL (available from Solabia); fructose; glucamine salt; glutamic acid glucose (available from the commodity WICKENOL 545 of Caschem); glucuronate; glutamate, Glu; glycereth 12; glycereth20; glycereth 7; glycerol; glyceryl PCA; glycogen; hexanediol; Mel; hydrogenated honey; hydrogenated starch hydrolysate; the hydrolysis mucopolysaccharide; hydroxyproline; inositol; keratin aminoacid (available from the commodity CROTEIN HKP of Croda); LYSINE PLA (available from the commodity LYSIDONE of UCIB); maltose alcohol; maltose; mannitol; mannose; methoxyl group; methyl gluceth 10 (available from the GLUCAM E10 of Amerchol); methyl gluceth 20 (available from the GLUCAM E20 of Amerchol); methyl glucoside; the 3-methyl isophthalic acid; the 3-butanediol; N-acetyl glucosamine salt; pantothenylol; butanediol; tetramethylolmethane; 1, the 2-pentanediol; the polyglycereol sorbitol; the PPG-1 glycerin ether; proline; propylene glycol; 2-Pyrrolidone-5-carboxylic acid and salt thereof; sugar isomeric compound (available from the PENTAVITIN of Pentapharm); serine; Silk Amino Acids (available from the CROSLIK LIQUID of Croda); the acetyl group hyaluronate sodium; hyaluronate sodium; poly (sodium aspartate) (available from the AQUADEW SPA-30 of Ajinomoto); polyglutamic acid sodium (available from the AJICOAT SPG of Ajinomoto); sorbeth 20; sorbeth 6; sorbitol; trehalose; triglycerin; trimethylolpropane; three (methylol) aminomethane salt; xylitol; xylose; and composition thereof.

Hardness number

Also contain in the conditioning component specific embodiments of (this conditioning component comprises oil-soluble conditioner, skin care activity component), preferably the lowest hardness value of these goods is about 0.02kg.Hardness number is the measured value to the bonded physical hardness of all the components in the skin care activity component (for example water solublity skin care activity thing, oil-soluble skin care active matter and conditioner).No matter how the user bubbles, and it is generally acknowledged that the increase of hardness can promote the deposition concordance of skin care activity thing and conditioner.Increase that it is generally acknowledged skin care activity component hardness can reduce its transmission in the substrate, also reduces in the foaming step surfactant to the emulsification of skin care activity component.Thereby can have the skin care activity components that retain more in contact mechanical transfer on skin or hair.

The hardness number of skin care activity component of the present invention is approximately greater than 0.02kg, more preferably greater than about 0.05kg, more preferably greater than 0.10kg.The hardness number of preferred skin care activity component should be not more than about 5.00kg, more preferably no more than about 4.00kg, hardness number most preferably is not more than 3.00kg, because can have a negative impact to the deposition of each component on skin or hair in the skin care activity component greater than this point.

Hardness test

Adopt the conventional method of measuring soap bar hardness to measure hardness number.Adopt the Chatillon ergometer to measure to 5-8 ounce skin care activity component sample.Carry out the several times reading to obtain meansigma methods for each new sample.DFIS 100 type Chatillon ergometers are by Chatillon company product (company is positioned at Greensboro, North Carolina).

Be used to increase the material of hardness number

Can contain hardening material in the cleaning article of the present invention, it can mix use with the skin care activity thing of forming above-mentioned skin care activity component.Many compositions both can be used as conditioner, can be used as the lipid hardening material again.In fact, any above-mentioned solid conditioner all can be used as hardening material.The consumption that can make the lowest hardness value reach the hardening material of 0.02kg will be decided on used concrete material, and those of ordinary skills are easy to determine this consumption.The hardening material form that hardening material can be independent or the form of hardening material mixture are used, its concentration accounts for the 0.1-99.9% (weight) of skin care activity component, preferably be about 0.5-75% (weight), be more preferably 1-50% (weight), be more preferably 2-25% (weight).

Here the term of Cai Yonging " hardening material " is meant that fusing point is approximately higher than 30 ℃, preferably about 30-250 ℃, more preferably from about 37-100 ℃, 37-80 ℃ composition more preferably from about.

Can adopt any material to be used to increase the hardness number of skin care activity component, as long as it can satisfy following standard: (i) this composition must dissolve in the skin care activity thing of skin care activity component, and (ii) the fusing point of this composition must be higher than 20 ℃ (for example at room temperature being solid).The example of the hardening material that is suitable for comprises vaseline, highly branched hydro carbons, aliphatic alcohol, fatty acid ester, vegetable oil, hydrogenated vegetable oil, polypropylene glycol, alpha-hydroxy fatty acid, contains the fatty acid, two of 10-40 carbon atom-and/or three-first alkyl-carboxylic acid amide, n-acyl amino acid derivative approximately; and their mixture, but be not limited only to this.Be applicable to that hardening material of the present invention also sees United States Patent (USP) 4919934 (people such as Deckner, authorize April 24 nineteen ninety), in full in conjunction with in the present invention as a reference.

The highly branched hydro carbons that is applicable to this comprises the hydrocarbon compound that contains 17-40 carbon atom approximately.The non-limiting example of this class hydrocarbon compound comprises squalane, cholesterol, lanoline, docosane (that is C22 hydrocarbon) and isoparaffin.

The aliphatic alcohol that is applicable to this comprises single hydroxyl alcohol, ethoxylized fatty alcohol and aliphatic alcohol ester, is used as except the ethoxylized fatty alcohol and ethoxylized fatty alcohol ester of emulsifying agent in the present invention.The instantiation of commercially available aliphatic alcohol comprises UNILIN 550, UNILIN 700, UNILIN 425, UNILIN 400, UNILIN 350 and the UNILIN 325 available from Petrolite, but is not limited only to this.The ethoxylized fatty alcohol that is suitable for comprises UNITHOX 325, UNITHOX 400 available from Petrolite and UNITHOX 450, UNITHOX 480, UNITHOX520, UNITHOX 550, UNITHOX 720, UNITHOX 750, but is not limited thereto.The non-limiting example of the aliphatic alcohol ester that is suitable for comprises citric acid three isostearates, ethylene glycol bisthioglycolate-12-hydroxy stearic acid ester, citric acid three stearic alcohol esters, sad stearic alcohol ester, enanthic acid stearate, citric acid three lauryl alcohol esters.

Be applicable to that fatty acid ester of the present invention comprises ester type waxes, monoglyceride, two sweet esters, triglyceride, and their mixture.The non-limiting example of the ester type waxes that is suitable for comprises geoceric acid stearyl alcohol ester, the stearic alcohol ester of behenic acid, stearic acid Petiolus Trachycarpi alcohol ester, stearyl octyldodecanol, cetyl, behenic acid spermaceti-stearic alcohol ester, behenic acid behenyl alcohol ester, diglycol stearate, two Palmic acid glycol esters, and Cera Flava.The example of commercially available ester type waxes comprises the KESTER wax available from Koster Keunen, available from the CRODAMOL SS of Croda with available from the DEMALCARE SPS of Rhone Poulenc.

At room temperature (about 20-25 ℃) is solid or semisolid vegetable oil and hydrogenated vegetable oil and also is applicable in the present invention as hardening material.The vegetable oil that is suitable for and the example of hydrogenated vegetable oil comprise butterfat, chicken fat, goose grease, horse fat, Adeps Sus domestica (fatty tissue), rabbit fat, pilchard oil, Adeps Bovis seu Bubali, Adeps caprae seu ovis, stillingia oil, babassu oil, cocoa butter, Oleum Cocois, Petiolus Trachycarpi oil, palm-kernel oil, the hydrogenation safflower oil, castor oil hydrogenated, hydrogenated coconut oil, cotmar, the hydrogenation pilchardine, hydrogenated palm kernel oil, hydrogenated palm oil, hydrogenated groundnut, oil with hydrogenated soybean, hydrogenated rapeseed oil, the hydrogenation Semen Lini oil, the hydrogenation Testa oryzae oil, the hydrogenation Oleum sesami, hydrogenation Oleum Helianthi, and their derivant and mixture.

The alpha-hydroxy fatty acid that contains the 10-40 carbon atom approximately that is suitable for and the example of fatty acid comprise 12-hydroxy stearic acid, 12-hydroxylauric acid, juniperic acid, behenic acid, erucic acid, stearic acid, sad, lauric acid, isostearic acid, and their mixture.The example of the fatty acid that some is suitable for also sees United States Patent (USP) 5429816 people such as (, authorize July 4 nineteen ninety-five) Hofrichter; And United States Patent (USP) 5552136 (Motley, on August 3rd, 1996 authorized), described content combination is in the present invention as a reference.

Be applicable to this two-and/or the alkylamide of three-first carboxylic acid comprise that two replace or the monoamides of side chain, the single replacement or diamides, the Disnalon (Ferrer). of side chain, and their mixture.Some two-and/or the instantiation of the alkylamide of three-first carboxylic acid comprise the alkylamide in citric acid, tricarballylic acid, aconitic acid, nitrilotriacetic acid(NTA) and itaconic acid, for example 1,2,3-propane tributyl amide, 2-hydroxyl-1,2,3-propane tributyl amide, 1-propylene-1,2,3-trioctylphosphine amide, N, N ', N " three (methyl decyl acylamino-) amine, 2-lauryl-N, N '-dibutyl succinamide, and their mixture.Other amide that is suitable for comprises the n-acyl amino acid derivative, sees United States Patent (USP) 5429816 people such as (, authorize July 4 nineteen ninety-five) Hofrichter.

Be applicable to that the HLB value that also comprises of the present invention is about the wax of 1-10, preferably be about 6, be more preferably 5.The abundant description of HLB (abbreviation of hydrophile-lipophile balance) value system and the HLB value of various materials see " guide that saves time that emulsifying agent is selected " (ICI AmericasInc., (Wilmington, Del; ) publish 1984).Described content combination in the present invention as a reference.

The ester type waxes that is suitable for comprises the C10-C40 fatty acid, C10-C40 fatty acid diester, alcohol wherein is propylene glycol, ethylene glycol, Polyethylene Glycol, polypropylene glycol, polyglycereol or glycerol, C10-C40 fatty acid triglyceride or two sweet esters, C10-C40 fatty acid tetramethylolmethane three esters or four esters, C10-C40 fatty acid anhydro sorbitol three esters, contain the substituent C10-C40 fatty acid of 3-8 mole sucrose polyfatty acid esters, myristic acid Semen Myristicae alcohol ester, paraffin, synthetic wax such as Fischer-Tropsch wax, microwax, castor wax, partially hydrogenated vegetable oil behenic acid behenyl alcohol ester, propanoic acid Semen Myristicae alcohol ester, and their mixture.

Two ester type waxes that are suitable for comprise SYNCHROWAX ERL-C (C18-36 acid diol ester) (available from Croda) and propylene glycol diesters wax, comprising glycol distearate and glycol distearate.The triglyceride wax that is suitable for comprises Adeps Bovis seu Bubali resin, cocoa butter, SYNCHROWAXHGL-C (C18-36 acid triglyceride), SYNCHROWAX HRC (behenic acid triglyceride), SYNCHROWAX HRS[behenic acid triglyceride (with) behenic acid calcium] (all available from Croda Inc.), stearic acid triglyceride, three myristinates and perhydrogenate vegetable oil, and their mixture.The preferable amount ratio is about 5: 1 to 1: 1 two ester type waxes and triglyceride wax mixture, is more preferably 4: 1 to 1: 1.

The wax that is applicable to the present composition sees following document, and their are in full in conjunction with in the present invention as a reference: United States Patent (USP) 5219558 (on June 15th, 1993 authorized for Woodin, people such as Jr.); United States Patent (USP) 4049792 (Elsnau, JIUYUE was authorized on the 20th in 1977); United States Patent (USP) 4151272 (people such as Geary, on April 24th, 1975 authorized); United States Patent (USP) 4229432 (Geria, on October 21st, 1980 authorized); United States Patent (USP) 4280994 (Turney, on July 28th, 1981 authorized); United States Patent (USP) 4126679 (people such as Davy, on November 21st, 1978 authorized); European patent application discloses 117070 (May, on August 29th, 1984 is open), " wax chemistry and technology " A.H.Warth, second edition (nineteen sixty reprints) 391-393,421 pages (Reinhold publishing company); " petrochemical industry " R.F.Goldstein and A.L.Waddeam, the 3rd edition (1967, E ﹠amp; The F.N.Span company limited) 33-40 page or leaf; " cosmetic chemistry and production " M.G.DeNavarre (second edition) (1970), Van Nostrand ﹠amp; Company (354-376 page or leaf); And " encyclopedia of chemical technology " (volume 24, Kirk-Othmer, the 3rd edition (1979), 466-481 page or leaf).

The non-limiting example of the hardening material that is suitable for is selected from Isosorbide Dinitrate, glyceride, polyglycerin ester, methyl glucose ester, sucrose ester, ethoxylized fatty alcohol, castor oil hydrogenated ethoxylate, Isosorbide Dinitrate ethoxylate, polymeric emulsifiers and silicone emulsifiers.

Other is applicable to that sclerosing agent of the present invention comprises monoglyceride, preferred C16-C22 is saturated, unsaturated and the monoglyceride of branched chain fatty acid, as olein, glyceryl monostearate, monopalmitin, Dan behenic acid glyceride and their mixture; C16-C22 is saturated, the polyglycerin ester of undersaturated branched chain fatty acid, as polyglycereol-4 isostearate, polyglycereol-3-oleate, single oleic acid two sweet esters, single oleic acid four sweet esters, and their mixture; Methyl glucose ester, preferred C16-C22 is saturated, the methyl glucose ester of undersaturated branched chain fatty acid, as two oleic acid methyl glucose esters, the different stearic methyl glucose ester of sesquialter, and their mixture; Sucrose fatty acid ester, preferred saturated, the undersaturated branched chain fatty acid sucrose ester of C12-C22, as stearic acid sucrose ester, three lauric acid sucrose ester, distearyl acid sucrose ester (for example CRODESTA  F10), and their mixture; The C12-C22 ethoxylized fatty alcohol, as oleyl ether-2, oleyl ether-3, stearyl ether-2, and their mixture; Castor oil hydrogenated ethoxylate such as PEG-7 castor oil hydrogenated; Isosorbide Dinitrate ethoxylate such as the full oleate of PEG-40 anhydro sorbitol, poly-Isosorbide Dinitrate-80, and their mixture; Polymer emulsifier such as ethoxylation dodecyl diol copolymer; And silicone emulsifiers, as lauryl methyl polysiloxanes polyol, cetyl dimethyl polysiloxane, dimethicone copolyol, and their mixture, but be not limited only to this.

Compositions such as lecithin that other sclerosing agent that is suitable for comprises phosphatidylcholine and contains the phosphatidyl choline; Long-chain C16-C22 soap such as sodium stearate; Long-chain C16-C22 two aliphatic series, short chain C1-C4 two aliphatic quaternary ammonium salts are as Varisoft DHT and two Adeps Bovis seu Bubali base dimethyl methyl ammonium sulfate; Long-chain C16-C22 two alkanoyls (enoyl-)-2-ethoxy, short chain C1-C4 two aliphatic quaternary ammonium salts are as two Adeps Bovis seu Bubalis acyl group-2-hydroxyethyl dimethyl ammonium chloride; Long-chain C16-C22 two aliphatic imidazoline quaternary ammonium salts are as methyl isophthalic acid-Adeps Bovis seu Bubali acylamino-ethyl-2-Adeps Bovis seu Bubali imidazoline Methylsulfate and methyl isophthalic acid-oil base acylamino-ethyl-2-oil-based imidazoline Methylsulfate; Short chain C1-C4 two aliphatic series, long-chain C16-C22 monoester family benzyl quaternary ammonium salt, as dimethyl stearyl benzyl ammonium chloride, and synthetic phospholipid, as the amino propyl group pg dimonium chloride (available from the phospholipid PTS of Mona Industries) of stearoyl.

Other non-essential composition

Can contain various other non-essential components in the present composition.These annexing ingredients should be pharmaceutically useful." CTFA cosmetic composition handbook second edition (1992) in conjunction with in the present invention as a reference, is wherein addressed various indefiniteness cosmetics and the medicinal ingredients that are usually used in the skin protection industry in full, all is applicable to compositions of the present invention.The non-limiting example of the functional classification of composition is seen 537 pages of this handbook.These or other functional classification composition example comprises: abrasive material, absorbent, anticaking agent, antioxidant, vitamin, binding agent, bio-additive, buffer agent, extender, chelating agen, chemical addition agent, coloring agent, beauty treatment astringent, denaturant, medicinal astringent, film former, perfume composition, opacifier, pH additive, antiseptic, propellant and Reducing agent.

Aesthetic components also is applicable to this, as spice, pigment, coloring agent, essential oil, dermal sensation agent and astringent.

Preparation method

But being prepared as follows of the disposable personal cleansing articles of disposal type of the present invention: go up adding or immerse lathering surfactant, skin care activity component and preferred deposition aid in water-insoluble substrate (for example with any arrangement) respectively or simultaneously.Non-essential conditioning component also can add respectively or simultaneously with other three kinds of components or immerse in the substrate." difference " is meant surfactant and skin care activity component added from random order, in advance without mixing." simultaneously " be meant and add surfactant and conditioner simultaneously, no matter whether mix in advance.

Preferred lathering surfactant and skin care activity component add respectively to prevent the emulsifying of skin care activity thing.This mode of handling substrate respectively also is applicable to nonessential conditioning component.In this preferred embodiment, nonessential deposition aid can (i) mix with foaming surface active agent, uses this mixture process substrate then, (ii) mixes with the skin care activity component, use this mixture process substrate then, or (iii) add respectively or immerse in the substrate.If but surfactant adds by immersion/rolling (dip/nip) mode, preferably after applying surfactant, add skin care activity component and any optional component to substrate.No matter what processing sequence, unnecessary surfactant, skin care activity component and/or deposition aid should be removed (as passing through rolling mode).Then, the substrate after the processing is by the usual manner drying.Surfactant, skin protection component, deposition aid and any optional component are added or immerse in the substrate by any way well known by persons skilled in the art: for example nebulization, laser imprinted method, sputtering method, dip coating, infusion method or cladding process (for example extrude and apply and the slotted eye coating).

Adopt in the preparation method or when having water or moisture, the processed substrate of gained is answered drying, makes it not moisture substantially.Can adopt various drying means well known by persons skilled in the art to handle substrate.The non-limiting example of known drying means comprises employing convective oven, radiant heat source, microwave oven, hot blast heater, hot cylinder or heating tank.Except also comprising, the air-dry drying of room temperature need not to add the air-dry of heat.Also various drying meanss can be used in combination.Keep the skin care activity component substantially in the method for stromal surface

Product of the present invention can be transported to the skin care activity thing on skin and the hair in stromal surface substantially effectively by keeping the skin care activity thing.Describe in further detail below and make top layer and the method and the composition that suck than more than or equal to about 1.25 improve.Following all methods and composition improve and can use separately or be used in combination to keep the skin care activity thing basically on the surface.Here term " chemical constituent " refers to the combination of skin care activity thing or conditioner and skin care activity thing.

The chemical treatment of substrate

Basically a method that chemical constituent is maintained stromal surface is with fiber hydrophobic or hydrophilic substance chemical treatment substrate or substrate.According to the characteristic for the treatment of sedimentary chemical constituent, select with suitable material (hydrophobic substance or hydrophilic substance).For example, if with the oil-soluble conditioning agent deposit on skin or hair, typically handle substrate or its fiber with hydrophilic substance, vice versa.Because most of substrate essence are hydrophobic, for example polyolefinic derivant, this chapter is mainly described the hydrophilic chemical treatment of substrate.

Any surfactant comprises ionic surface active agent and non-ionic surface active agent, all can be used for the hydrophilic modifying of substrate.The surfactant that is fit to can be the inter-modification agent, for example just modified compound is added in the polymer composition at spinning or before forming fiber, or the partial modification agent, for example in fiber or adhesive-bonded fabric forming process or afterwards, the local application modified compound.A kind of inter-modification method is disclosed in people's such as Sawyer USP4, and in 578,414, a kind of partial modification method is disclosed in people's such as Sayovitz USP5, and in 057,361, two pieces of documents all are incorporated herein by reference.

The limiting examples of the surfactant that is fit to comprises the surfactant based on polysiloxanes, for example polydimethylsiloxane of polyalkylene oxides modification; Fluoro aliphatic series surfactant, for example perfluoroalkyl polyalkylene oxides; With other surfactant, for example acryloyl group (actyl) phenoxy group polyethoxy ethanol non-ionic surface active agent, alkyl aryl polyether alcohol and poly(ethylene oxide).Be suitable for merchant of the present invention and sell the surfactant that surfactant comprises the poly(ethylene oxide) base of extensive stock Triton by name, for example the X-102 level of Rohm and Haas Corp. company; The surfactant of the polyethylene glycol groups of extensive stock EMEREST by name, for example 2620 and 2650 of Emery Indust. company grades; The surfactant of the polydimethylsiloxane base of the polyalkylene oxide modification of extensive stock SILWET by name, for example the Y12488 level of OSI SpecialtyChemicals company; With the alkenyl succinamide surfactant of commodity LUBRIZOL by name, as 85870 grades of aliphatic surfactants of the fluoro with the polyoxy alkylidene modification of Minnesota Mining and Manufacturing Co. of OS of Lubrizol Corp. company.The hydrophilic of the substrate of the amount of required surfactant and modification or matrix fiber changes according to the kind of the component polymer of the kind of selected table surface-active agent and use when using at every turn.Usually, local add or the amount of the inner surfactant that adds be substrate or matrix fiber weight about 0.1% to about 5%, be preferably about 0.3% to about 4%.

Increase viscosity

Another kind of keep substantially chemical constituent the method for stromal surface be administered on the substrate before the viscosity of increase chemical constituent.Will prevent that like this substrate is saturated by chemical constituent.Usually, the method for viscosity that increases chemical constituent has two kinds: (i) be administered on the substrate when chemical constituent is in phase transition temperature and (ii) before being administered on the substrate, add thickening agent in the mixture of chemical constituent.Preferably these two kinds of methods are used in combination.

When phase transition temperature, be administered on the substrate:

Keeping chemical constituent is when chemical constituent is in its phase transition temperature it to be administered on the substrate in a method of stromal surface.This method is higher than the chemical constituent of about 35 ℃ (for example at room temperature viscosity is very big) applicable to any its phase transition temperature." phase transition temperature " used herein is defined as that chemical constituent changes the viscous attitude into from mobile liquid state under this temperature.Importantly, in cooling procedure when chemical constituent when mobile liquid state changes the temperature of viscous attitude into, use this chemical constituent.

Typically, by fusing or heating this chemical constituent is administered on the substrate.In addition, be administered on the substrate again after also can and being dissolved in the solvent the chemical constituent heating.Can be administered on the substrate though also have enough flowabilities but some chemical constituents its viscosity when not heating is very big.If a kind of chemical constituent phase transition temperature be during about room temperature or a little more than room temperature, just must use other method of introducing in this section that chemical constituent is administered on the stromal surface.The phase transition temperature of most of chemical substances (fusing point) can be easily from Merck index, the 10th edition (1983) and CTFA cosmetic composition handbook, obtaining in the 2nd edition (1992), above document is incorporated herein by reference.

When phase transition temperature, being administered to a inference on the substrate and being on being administered to substrate that chemical constituent is supercool." supercool " refers to increases rate of cooling artificially above its rate of cooling when the normal room temperature.The double advantage of doing like this is that chemical constituent has enough flowabilities when handling, and chemical constituent has reached its phase transition temperature before substrate is saturated by chemical constituent.When at room temperature being viscous and plasticity, chemical constituent should adopt this method.

Thickening agent:

If chemical constituent at room temperature is liquid (for example not being the viscous attitude), chemical constituent can mainly not maintain stromal surface.On the contrary, chemical group branch is penetrated into or flows in the space of substrate and goes.Method of the present invention provides a kind of solution of adding thickening agent in chemical constituent.This method by increase chemical constituent the identical effect used when reaching of viscosity with phase transition temperature.Because the viscosity of chemical constituent is increased effectively, chemical constituent just can maintain stromal surface and can be unsaturated to substrate basically.Usually, thickening agent at room temperature must be heavy-gravity, and must with chemical group phase-splitting mixing.The suitable viscosity of phase transition temperature and thickening agent has very big variation with concrete thickening agent.But typically, the phase transition temperature of thickening agent must be preferably greater than about 40 ℃ greater than about 35 ℃.

Usually, any at room temperature is that heavy-gravity material can be as thickening agent. CTFA makes up Product composition handbook, the 2nd edition (1992) have introduced many suitable thickening, and the document is incorporated herein by reference in full.In fact, any foregoing description also can all can be used as suitable thickening for miscible conditioner in chemical constituent than chemical constituent thickness.

The limiting examples of the thickening agent of Shi Yonging is selected from polyacrylic resin, starch, glue, cellulose ether, polycationic polymer, non-ionic polymers, the Polyethylene Glycol (PEG) of aliphatic alcohol, fatty acid, ethoxylized fatty alcohol (average degree of ethoxylation is 2 to about 30), Isosorbide Dinitrate, glyceride, polyglycerin ester, methyl glucoside ester, sucrose ester, ethoxylation dehydrated sorbitol ester, natural or synthetic wax, polyacrylic and hydrophobically modified in the present invention, and composition thereof.

The limiting examples of the thickening agent of Shi Yonging comprises in the present invention: stearic acid behenic acid, stearyl alcohol, spermol, Arlacel-80, Arlacel-83, anhydro sorbitol list isostearate, sorbitan monostearate, sorbitan trioleate, Arlacel-65, the anhydro sorbitol dipalmitate, the anhydro sorbitol isostearate, glyceryl oleate, glyceryl monostearate, the glycerol monopalmitate, glycerol Dan behenic acid ester, polyglycereol-4 isostearate, polyglycereol-3 oleate, two glycerin mono-fatty acid esters, four glycerin mono-fatty acid esters, the methyl glucoside dioleate, methyl glucoside sesquialter isostearate, sucrose stearate, the sucrose trilaurin, sucrose distearate, oleth-2, oleth-3, steareth-2, the full oleate of PEG-40 anhydro sorbitol, Polysorbate-80, Cera Flava, Tissuemat E, CARBOPOL, PEMULEN, corn starch, potato starch, Maninot esculenta crantz., guar gum, arabic gum, hydroxypropyl cellulose, hydroxyethyl-cellulose, carboxymethyl cellulose, RETEN201, KYMENE 557H , ACCO 7112, CARBOWAX.

Use on the substrate unevenly

Basically the other method that chemical constituent is maintained on the stromal surface is that chemical constituent is administered to stromal surface unevenly." inhomogeneous " refers to the amount that chemical constituent distributes on stromal surface be different with pattern etc.For example, the amount of the chemical constituent that the some parts on stromal surface uses is greater than or less than the amount of another part, and certain part that is included in the surface is without any chemical constituent.

On substrate, use the order of composition

Basically the other method that chemical constituent is maintained on the stromal surface is to control the order of the composition of using.Usually, it is best chemical constituent being administered to the result who obtains on the exsiccant substrate.Therefore, use the expansion type surfactant earlier, the dry then substrate of handling with surfactant is then used chemical constituent again, can strengthen the conveying of chemical constituent so widely.

The cleaning of skin or hair and processing method

The invention still further relates to the method that adopts goods cleaning of the present invention and handle skin and hair.These methods may further comprise the steps: but will contain the disposable personal cleansing articles water-wet of disposal type of the substantially dry of water-insoluble substrate, lathering surfactant and skin care activity component, and the goods of moistening are contacted with hair with skin.In another embodiment, the present invention also is used to carry various skins or hair active component.

Goods substantially dry of the present invention, and should use water-wet before use.Available water is soaked this goods, or under current these goods of moistening.At goods with before skin or hair contact or during contact, through mechanical friction and/or goods deformation is bubbled.The gained foam is used for cleaning and handles skin or hair.Cleaning and subsequently in the water rinse cycle, skin care activity thing and non-essential composition can be deposited on skin or the hair.Substrate contacts the deposition that can promote skin care activity thing and conditioning ingredients with the physics of skin or hair.

Skin care activity thing and any conditioning ingredients consistent sedimentary method on skin or hair

Goods of the present invention can be used for making that skin care activity thing of the present invention is consistent is deposited on skin or the hair.In another embodiment, when conditioner existed, said composition can be used for also making that conditioner is consistent is deposited on skin or the hair.

The deposition unanimity degree of goods of the present invention is greater than about 60%, be preferably greater than about 65%, more preferably greater than about 70%, most preferably greater than about 75%.

The mensuration that deposits consistent degree is by the deposition of when using " foaming of imperfect mode and " the skin care activity thing quotient divided by the deposition of when using " foaming of ideal style and " skin care activity thing.Here the imperfect mode of saying is bubbled and is meant that friction goods contains the surface or rub relative with contact surface of skin care activity thing, will contact with skin and hair with one side then.This can cause the deposition deficiency of skin care activity thing, because some skin care activity thing can be by surfactant emulsifying.Here the ideal foaming of saying is meant that friction contains the one side of surfactant or with its rubs relative with contact surface, the one side that will contain the skin care activity thing then contacts with skin and hair.This viewpoint all also is suitable for (deposition after the blistered one side that for example contains emulsive skin care activity thing and the contact skin is with respect to the deposition after the non-blistered one side that contains not emulsive skin care activity thing and the contact skin) with the goods that the skin care activity thing is handled for the substrate two sides.The hardness of skin care activity thing can reach maximum deposition unanimity degree greater than about 0.02kg.

The deposition of various standard analytical techniques quantitative assay skin care activity components on skin or hair that can adopt those of ordinary skills to know.These methods for example comprise with suitable solvent to be extracted immediately to the skin care activity component at certain position on skin or the hair, analyze infrared spectrometry, ultraviolet spectrometry, mass spectrography etc. through chromatography (for example gas chromatography, liquid chromatography, supercritical fluid chromatography etc.) then.Can adopt technology such as infrared spectrometry, ultraviolet spectrometry, shading algoscopy, fluorescent spectrometry, electron spectroscopy for chemical analysis on skin or hair, directly to measure.

In the conventional method of measuring deposition, with water-wet goods of the present invention, extruding and friction are bubbled.Then with these goods at the about 25-30 square centimeter that marks with the labelling that is difficult for eccysis on skin or the head, preferably embrocate about 15 seconds on the position of about 50-100 square centimeter.This position of rinsing about 10 seconds then, air-dry about 10 minutes.After this test and extract analysis are extracted in this position, or the technology of enumerating more than directly adopting is analyzed directly.

Embodiment

Following examples are in order to further specify specific embodiments of the present invention.In following examples, listed all the components is all in active component.Embodiment only is used for explanation, and the present invention is not constituted any qualification, can carry out multiple variation under the condition that does not deviate from spirit and scope of the invention.

Each composition adopts chemical name or CTFA name, and all wt is active component percentage ratio.

Embodiment 1-5

I. surfactant phase

In appropriate vessel, add following composition under the room temperature.Can heat as needs and to make its thorough dispersion.

Composition	% (weight)
Composition	% (weight)						Embodiment 1	Embodiment 2	Embodiment 3	Embodiment 4	Embodiment 5
Water	Add to 100	Add to 100	Add to 100	Add to 100	Add to 100		Embodiment 1	Embodiment 2	Embodiment 3	Embodiment 4	Embodiment 5
Water	Add to 100	Add to 100	Add to 100	Add to 100	Add to 100	Polyquaternary ammonium salt 10	0.25	-	-	-	-
PEG 14M	0.5	-	-	0.5	-	Polyquaternary ammonium salt 10	0.25	-	-	-	-
PEG 14M	0.5	-	-	0.5	-	Hydroxypropyl-trimethyl ammonium chloride	-	-	-	-	0.5
Hydroxyethyl-cellulose	-	0.25	-	-	-	Hydroxypropyl-trimethyl ammonium chloride	-	-	-	-	0.5
Hydroxyethyl-cellulose	-	0.25	-	-	-	Guar gum	-	0.25	-	-	-

When said mixture mixes, in this mixture, add following component:

The EDTA disodium	0.10	0.10	0.10	0.10	0.10
The EDTA disodium	0.10	0.10	0.10	0.10	0.10	Sodium N-lauroyl sarcosinate	3.33	3.33	3.33	3.33	3.33
Lauroyl both sexes sodium acetate	-	-	-	-	3.33	Sodium N-lauroyl sarcosinate	3.33	3.33	3.33	3.33	3.33
Lauroyl both sexes sodium acetate	-	-	-	-	3.33	Cocoamidopropyl	3.33	3.33	3.33	3.33	-
Decyl polysaccharide glycosides	3.33	3.33	3.33	3.33	3.33	Cocoamidopropyl	3.33	3.33	3.33	3.33	-
Decyl polysaccharide glycosides	3.33	3.33	3.33	3.33	3.33	Methyl parahydroxybenzoate	0.25	0.25	0.25	0.25	0.25
Phenyl phenol	0.3	0.3	0.3	0.3	0.3	Methyl parahydroxybenzoate	0.25	0.25	0.25	0.25	0.25
Phenyl phenol	0.3	0.3	0.3	0.3	0.3	Benzylalcohol	0.3	0.3	0.3	0.3	0.3

In another mixer, add following component.Mixing (as needs, can be heated to 40 ℃) dissolves until propyl p-hydroxybenzoate.

Water	2.0	2.0	2.0	2.0	2.0
Water	2.0	2.0	2.0	2.0	2.0	Butanediol	2.0	2.0	2.0	2.0	2.0
Propyl p-hydroxybenzoate	0.15	0.15	0.15	0.15	0.15	Butanediol	2.0	2.0	2.0	2.0	2.0

This mixture is added in first mixer.1.5-2.5g gained mixture is added on the substrate described here, dry then.

II. skin care activity thing phase

In appropriate containers, at room temperature mix following composition.If desired, heat to disperse fully.

Water	Add to 100	Add to 100	Add to 100	Add to 100	Add to 100
Water	Add to 100	Add to 100	Add to 100	Add to 100	Add to 100	Glycerol	60.0	40.0	0.0	50.0	30.0
D-panthenol	1.0	4.0	2.0	4.0	4.0	Glycerol	60.0	40.0	0.0	50.0	30.0
D-panthenol	1.0	4.0	2.0	4.0	4.0	Urea	-	-	-	2.0	-
PEG-30	-	20.0	25.0	-	5.0	Urea	-	-	-	2.0	-
PEG-30	-	20.0	25.0	-	5.0	Lactic acid	-	-	4.0	-	-
Dihydroxy acetone	4.0	-	-	-	-	Lactic acid	-	-	4.0	-	-
Dihydroxy acetone	4.0	-	-	-	-	Nicotiamide	-	-	-	5.0	10.0
Arbutin	-	3.0	-	-	-	Nicotiamide	-	-	-	5.0	10.0
Arbutin	-	3.0	-	-	-	Kojic acid	-	-	3.0	-	-
Allantoin	-	-	-	2.0	2.0	Kojic acid	-	-	3.0	-	-
Allantoin	-	-	-	2.0	2.0	Propylene glycol	-	5.0	30.0	-	-
Polyquaternary ammonium salt-10	-	3.0	-	-	-	Propylene glycol	-	5.0	30.0	-	-
Polyquaternary ammonium salt-10	-	3.0	-	-	-	PEG 14M	5.0	3.0	3.0	3.0	5.0
Hydroxyethyl-cellulose	-	-	2.0	2.0	-	PEG 14M	5.0	3.0	3.0	3.0	5.0
Hydroxyethyl-cellulose	-	-	2.0	2.0	-	Guar gum	-	-	-	1.0	-

0.10 to 1.0 this phase material of gram is added on the butt matter that contains surfactant phase material.Drying is removed the moisture of any interpolation.By use the cleaning article of gained with water-wet, be used for cleaning skin or hair and deposit the skin care activity component to skin or hair.In addition, the skin care activity thing can add before the surfactant phase or immerse in the insoluble matrix mutually, as long as by immersion/rolling mode adding surfactant.Extrude or intaglio plate is stenciled when applying mode when use, a kind of mode in back is possible.

Embodiment 6-10

I. surfactant phase

Composition	% (weight)
Composition	% (weight)						Embodiment 6	Embodiment 7	Embodiment 8	Embodiment 9	Embodiment 10
Water	Add to 100	Add to 100	Add to 100	Add to 100	Add to 100		Embodiment 6	Embodiment 7	Embodiment 8	Embodiment 9	Embodiment 10
Water	Add to 100	Add to 100	Add to 100	Add to 100	Add to 100	Polyquaternary ammonium salt 10	-	-	-	0.25	-
PEG 14M	0.5	-	-	0.5	-	Polyquaternary ammonium salt 10	-	-	-	0.25	-
PEG 14M	0.5	-	-	0.5	-	Hydroxypropyl-trimethyl ammonium chloride	-	-	-	-	0.5
Hydroxyethyl-cellulose	-	0.25	-	-	-	Hydroxypropyl-trimethyl ammonium chloride	-	-	-	-	0.5
Hydroxyethyl-cellulose	-	0.25	-	-	-	Guar gum	-	0.25	-	-	-

When said mixture mixes, in this mixture, add following component:

II. skin care activity thing phase

In appropriate containers, under heating, mix following composition, until melting (between 75-115 ℃).

SEFA* cotton seed acid esters	48.00	43.00	46.00	48.00	48.00
SEFA* cotton seed acid esters	48.00	43.00	46.00	48.00	48.00	SEFA* behenic acid ester	12.00	-	-	-	-
Vaseline	10.00	10.00	10.00	10.00	10.00	SEFA* behenic acid ester	12.00	-	-	-	-
Vaseline	10.00	10.00	10.00	10.00	10.00	The behenic acid triglyceride	5.00	5.0	5.0	5.0	5.0
Tissuemat E	-	9.0	9.0	9.0	-	The behenic acid triglyceride	5.00	5.0	5.0	5.0	5.0
Tissuemat E	-	9.0	9.0	9.0	-	Paraffin	-	-	-	-	12.00
Synthetic bees wax	-	3.0	3.0	3.0	-	Paraffin	-	-	-	-	12.00
Synthetic bees wax	-	3.0	3.0	3.0	-	C10-30 cholesterol/lanosterol ester	18.00	23.00	23.00	23.00	20.00
Vitamin E acetate	-	2.0	2.0	2.0	2.0	C10-30 cholesterol/lanosterol ester	18.00	23.00	23.00	23.00	20.00

* SEFA is the acronym of fatty acid cane sugar ester.

When above-mentioned molten mixture reaches even, to wherein adding following composition.

Retinyl palmitate	-	-	2.0	-	1.0
Retinyl palmitate	-	-	2.0	-	1.0	The PPG-15 stearyl ether	5.0*	-	-	-	-
Salicylic acid	2.0*	-	-	-	-	The PPG-15 stearyl ether	5.0*	-	-	-	-
Salicylic acid	2.0*	-	-	-	-	Titanium dioxide	-	5.0	-	-	2.0

* mixing these compositions dissolves until salicylic acid.

0.05 to 0.75 this phase material of gram is added on the substrate that contains surfactant phase material.This skin care activity is corresponding to be applied with liquid state/molten state, then cooling.By use the cleaning article of gained with water-wet, be used for cleaning skin or hair and concordance ground to skin or hair deposition skin care activity component.In addition, skin care activity can add before the surfactant phase or immerse in the insoluble matrix mutually, as long as by immersion/rolling mode adding surfactant.Extrude or intaglio plate is stenciled when applying mode when use, a kind of mode in back is possible.

Embodiment 11-15

I. surfactant phase

Composition	% (weight)
Composition	% (weight)						Embodiment 11	Embodiment 12	Embodiment 13	Embodiment 14	Embodiment 15
Water	Add to 100	Add to 100	Add to 100	Add to 100	Add to 100		Embodiment 11	Embodiment 12	Embodiment 13	Embodiment 14	Embodiment 15
Water	Add to 100	Add to 100	Add to 100	Add to 100	Add to 100	Polyquaternary ammonium salt 10	0.25	-	-	-	-
PEG 14M	0.5	-	-	0.5	-	Polyquaternary ammonium salt 10	0.25	-	-	-	-
PEG 14M	0.5	-	-	0.5	-	Hydroxypropyl-trimethyl ammonium chloride	-	-	-	-	0.5
Hydroxyethyl-cellulose	-	0.25	-	-	-	Hydroxypropyl-trimethyl ammonium chloride	-	-	-	-	0.5
Hydroxyethyl-cellulose	-	0.25	-	-	-	Guar gum	-	0.25	-	-	-

When said mixture mixes, in this mixture, add following component:

II. facial treatment milk phase

In appropriate containers, under heating, mix following composition, until even (between 75-115 ℃).

SEFA* cotton seed acid esters	27.36	25.36	46.00	48.00	48.00
SEFA* cotton seed acid esters	27.36	25.36	46.00	48.00	48.00	SEFA* behenic acid ester	-	-	-	-	-
Vaseline	5.7	5.7	10.00	10.00	10.00	SEFA* behenic acid ester	-	-	-	-	-
Vaseline	5.7	5.7	10.00	10.00	10.00	The behenic acid triglyceride	2.85	2.85	5.0	5.0	5.0
Tissuemat E	5.13	5.13	9.0	9.0	-	The behenic acid triglyceride	2.85	2.85	5.0	5.0	5.0
Tissuemat E	5.13	5.13	9.0	9.0	-	Paraffin	-	-	-	-	12.00
Synthetic bees wax	1.71	1.71	3.0	3.0	-	Paraffin	-	-	-	-	12.00
Synthetic bees wax	1.71	1.71	3.0	3.0	-	C10-30 cholesterol/lanosterol ester	13.1	13.1	23.00	23.00	20.00
Vitamin E acetate	1.15	1.15	2.0	2.0	2.0	C10-30 cholesterol/lanosterol ester	13.1	13.1	23.00	23.00	20.00
Vitamin E acetate	1.15	1.15	2.0	2.0	2.0	Two Palmic acids, ten glyceride	0.3	-	0.3	0.3	-
Mono stearic acid triacyl glycerol	2.7	0.3	2.7	2.7	0.3	Two Palmic acids, ten glyceride	0.3	-	0.3	0.3	-
Mono stearic acid triacyl glycerol	2.7	0.3	2.7	2.7	0.3	Stearic acid ten glyceride	-	2.7	-	-	2.7
Three stearic acid polyglycerin ester	-	-	-	-	-	Stearic acid ten glyceride	-	2.7	-	-	2.7
Three stearic acid polyglycerin ester	-	-	-	-	-	Retinyl palmitate	-	2.0	2.0	-	1.0

At room temperature mix following composition.When it reaches even, under agitation slowly join in the said mixture.

Water	5.0	2.0	11.0	10.0	0.0
Water	5.0	2.0	11.0	10.0	0.0	Glycerol	30.0	9.0	5.0	5.0	10.0
D-panthenol	1.0	1.0	2.0	4.0	3.0	Glycerol	30.0	9.0	5.0	5.0	10.0
D-panthenol	1.0	1.0	2.0	4.0	3.0	Urea	-	-	-	2.0	-
PEG-30	-	20.0	15.0	12.0	10.0	Urea	-	-	-	2.0	-
PEG-30	-	20.0	15.0	12.0	10.0	Lactic acid	-	-	4.0	-	-
Dihydroxy acetone	4.0	-	-	-	-	Lactic acid	-	-	4.0	-	-
Dihydroxy acetone	4.0	-	-	-	-	Nicotiamide	-	-	-	5.0	10.0
Arbutin	-	3.0	-	-	-	Nicotiamide	-	-	-	5.0	10.0
Arbutin	-	3.0	-	-	-	Kojic acid	-	-	3.0	-	-
Allantoin	-	-	-	2.0	-	Kojic acid	-	-	3.0	-	-
Allantoin	-	-	-	2.0	-	Propylene glycol	-	5.0	-	-	7.0

0.05 to 1.5 this phase material of gram is added on the butt matter that contains surfactant phase material cooling then.By use the cleaning article of gained with water-wet, be used for cleaning skin or hair and deposit the skin care activity component to skin or hair.In addition, facial treatment milk can add before the surfactant phase or immerse in the insoluble matrix mutually, as long as by immersion/rolling mode adding surfactant.Extrude or intaglio plate is stenciled when applying mode when use, a kind of mode in back is possible.

Another following preparation method goes for foregoing arbitrary embodiment.Has two-layer substrate in order to handle, can distinguish or simultaneously (i) two-layer be bonded to layered article before or (ii) two-layer be bonded to layered article after, lathering surfactant, skin care activity component and non-essential composition be added in or immerse on one deck or two-layer arbitrary.Can be added in surfactant and/or conditioning component on the substrate or immerse wherein by nebulization, stamped method, sputtering method, dip coating or cladding process.

Equally, can random order lathering surfactant and skin care activity component be added substrate.The non-limiting example of this method program comprises: (i) earlier surfactant is used for the second layer, cohesive matrix is handled with the skin care activity component then; (ii) earlier surfactant is mixed with the skin care activity component, handle the second layer then, bond two; (iii) bond before two, handle the second layer with surfactant earlier, handle the second layer with the skin care activity component then, bond two.

In another embodiment, can adopt the substrate of the alternative present embodiment of other substrate, as textile substrates, hydro entanglement substrate, natural or synthetic sponge or polymer wire side.

Claims

1. the disposable personal care cleaning article of disposal type wherein comprises:

(A) water-insoluble substrate,

(B) be added on the described substrate or immerse substrate at least a lathering surfactant and

(C) skin protection component, this component comprises at least a skin care activity thing that is selected from water solublity skin care activity thing, oil-soluble skin care active matter and composition thereof, this skin care activity thing component also is added on the substrate or immerses in the substrate, wherein said goods comprise the water that is lower than 10% weight and wherein said goods can produce average foam volume more than or equal to 30ml.

2. the goods of claim 1, wherein said lathering surfactant accounts for the 0.5-40% weight of described water-insoluble substrate and the 0.001-50% weight of the described water-insoluble substrate of described skin care activity ingredients constitute.

3. claim 1 or 2 goods, wherein said cleaning article to skin or hair surface deposition greater than 0.001 μ g/cm ²Described skin care activity thing.

4. the goods of claim 1 also comprise at least a deposition aid that is added in or immerses described substrate.

5. the goods of claim 1, wherein said skin care activity thing is selected from: anti-acne active ingredient, crease-resistant and anti-atrophoderma active component, skin sealing coat repairing activity composition, non-sterols beauty treatment skin moistening active component, artificial suntan and promoter, brightening agent, antimicrobial and antifungal, sunscreen actives composition, sebum stimulant, sebum inhibitor, antioxidant and their mixture.

6. the goods of claim 4; wherein said skin care activity composition is selected from: salicylic acid; nicotiamide; nicotinic acid; benzoyl peroxide; cis-retinoic acid; trans retinoic acid; retinol; retinyl palmitate; phytic acid; N-acetyl group-L-cysteine; Azelaic Acid; thioctic acid; resorcinol; lactic acid; glycolic; ibuprofen; naproxen; hydrocortisone; phenyl phenol; phenoxypropanol; the phenoxy group isopropyl alcohol; 2; 4; 4 '-three chloro-2 '-hydroxy diphenyl ether; 3; 4; 4 '-trichloro-symmetrical diphenyl urea; p-methoxycinnamic acid 2-Octyl Nitrite; oxybenzone; 2-Phenylbenzimidazole-5-sulfonic acid; dihydroxy acetone; pantothenylol; arbutin; deoxyarbutin; kojic acid; allantoin; cholesterol; the ester of C10-C30 cholesterol/lanosterol; tocopherol; Tocopherol acetate ester, and their mixture.

7. the goods of claim 1, wherein said skin care activity thing is an emulsion form, it comprises:

(A) discontinuous phase, it comprises the water soluble compound that is selected from water, water solublity skin care activity thing and composition thereof; With

(B) continuous phase, it comprises the oil-soluble skin care active matter.

8. the goods of claim 7, the emulsifying agent that wherein also comprises the 0.01-20% that accounts for described skin care activity emulsion weight, this emulsifying agent can form the emulsion of described discontinuous phase and continuous phase, and it is one or more emulsifying agents of 1 to 7 that wherein said emulsifying agent is selected from weighted arithmetic mean HLB value.

9. the goods of claim 4, wherein said deposition aid is selected from non-ionic polymers, cationic polymer, non-polymeric type cationic surfactant and composition thereof.

10. the goods of claim 9, wherein said deposition aid is selected from: the polymer of natural gum, cellulose-derived, the polymer of protein derived, aggretion type ether, synthetic polymer and composition thereof.

11. comprising, the goods of claim 1, wherein said water-insoluble substrate are selected from one or more following materials: silk; Keratin; Cellulose, acetas, acrylic compounds, cellulose esters, improvement acrylic compounds, polyamide, polyolefin, polyvinyl alcohol, wood pulp, cotton, Fructus Cannabis, Corchorus olitorius L., Caulis et Folium Lini, acrylic compounds, nylon, polyester, polypropylene, polyethylene, polyvinyl acetate, polyurethane, artificial silk, and composition thereof.

12. the goods of claim 11, wherein said water-insoluble substrate is selected from nonwoven substrate, textile substrates, and water sprays the substrate of entwining, natural sponge, synthetic sponge, polymeric web, shaping membrane, and composition thereof.

13. the goods of claim 12 comprise the nonwoven layers that is selected from following fiber in the wherein said water-insoluble substrate: rayon fiber, cellulose fibre, polyester fiber, and composition thereof.

14. the goods of claim 11, wherein said water-insoluble substrate comprise every layer of two-layer or multi-layer fiber with differing texture.

15. the goods of claim 11, wherein said foaming surface active agent are selected from anion lathering surfactant, nonionic lathering surfactant, both sexes lathering surfactant and composition thereof.

16. the goods of claim 15, wherein said anion lathering surfactant is selected from: sarcosinate, sulfate, isethionate, phosphate, taurate, lactate, glutamate, Glu and their mixture; Wherein said nonionic lathering surfactant is selected from amine oxide, alkyl polyglucoside, alkyl poly glucoside, polyhydroxy fatty acid amide, alkoxy fatty acid ester, sucrose ester and their mixture; Wherein said both sexes lathering surfactant is selected from betanin, sulfobetaines, hydroxyl sulfo betaine, alkyl imino acetate, imino-diacetic alkyl salt, aminoalkyl salt and their mixture.

17. the goods of claim 1, wherein also comprise the conditioning component that is added in or immerses substrate with described foaming surface active agent respectively, this conditioning component comprises and is selected from following conditioner: oil-soluble conditioner, water solublity conditioner, lipid hardening material, and composition thereof.

18. the goods of claim 17, the hardness number of wherein said skin care activity component is greater than 0.02kg.

19. the goods of claim 17 or 18, wherein said oil-soluble conditioner and described lipid hardening material are selected from: fatty acid, fatty acid ester, aliphatic alcohol, ethoxylated alcohol, polyol polyester, monoglyceride, glycerol polyester, epidermis and sebum hydrocarbon, lanoline, mineral oil, silicone oil, silicone gums, vegetable oil, vegetable oil adduct, vaseline, non-ionic polymers, hydrogenated vegetable oil, non-ionic polymers, native paraffin, synthetic wax, polyolefin diols, polyolefin monoesters, polyolefin polyester, cholesterol, cholesterol ester, and their mixture; With wherein said water solublity conditioner be selected from glycerol, propylene glycol, polypropylene glycol, Polyethylene Glycol, ethohexadiol, hexanediol, other aliphatic alcohol, pantothenylol, urea, cationic polymer, polyhydric alcohol, glycolic, lactic acid, and composition thereof.

20. a method for preparing the disposable personal cleansing articles of disposal type may further comprise the steps:

(A) add or immersion to water-insoluble substrate respectively or simultaneously:

(i) at least a add to or immerse described substrate foaming surface active agent and

(ii) skin care activity component, it comprises and is selected from following at least a skin care activity thing: water solublity skin care activity thing, oil-soluble skin care active matter and composition thereof and

(B) with the product dried handled in the step (A) to comprising the water that is lower than 10% weight,

Wherein resulting product can produce the average foam volume more than or equal to 30ml.

21. the method for claim 20, foaming surface active agent described in wherein said skin care activity component and the step (A) adds to respectively or immerses in the described water-insoluble substrate.

22. the method for claim 20 or 21, wherein step (A) also comprises adding and is selected from following chemical compound: deposition aid, oil-soluble conditioner, water solublity conditioner, lipid hardening material, and composition thereof.

23. one kind is used personal cleansing articles cleaning skin or hair and the skin care activity thing is deposited to the method for skin or hair, may further comprise the steps:

(A) with water-wet and the disposable personal cleansing articles that stirs the disposal type comprise the water that is lower than 10% weight produce the foam of the average foam volume that is equal to or greater than 30ml, wherein goods comprise:

(i) water-insoluble substrate,

(ii) at least a lathering surfactant, and

(iii) skin care activity component, it comprises and is selected from following at least a skin care activity thing: water solublity skin care activity thing, oil-soluble skin care active matter and composition thereof and

(B) foam with described goods and generation thereof contacts with skin or hair.

24. the method for claim 23, wherein the described goods that use in the step (A) also comprise and are selected from following chemical compound: deposition aid, oil-soluble conditioner, water solublity conditioner, lipid hardening material, and composition thereof.

25. the method for claim 23 or 24, wherein said skin care activity thing is transported to skin or hair to deposit consistent degree 60% the degree of being at least.