CN1198565C - Volumizing hair care compositions containing siloxysilicates - Google Patents

Abstract

This invention relates to an improved formulation hair volumizers which comprise: (a) from 0.01-15 percent by weight (based on the total weight of the composition) of a selected liquid MQ resin having an M:Q ratio of 0.5-1.5 and a medium viscosity in the range of 1.0x103-1x106 centipoise; and (b) from 85-99.99 percent by weight (based on the total weight of the composition) of a hair care carrier (also called a vehicle). The compositions of this invention provide hair with increased volume without significant stiffness or stickiness and may be made in the form of a shampoo, conditioner, combination shampoo/conditioner, sprays, liquid rinses, gels or mousses.

Description

What contain siloxysilicates makes the fluffy Haircare composition of hair

Invention field

The present invention relates to a kind of hair conditioning preparation of improvement.Specifically, compositions of the present invention has been sneaked into a kind of siloxysilicates polymer that can be used as the selection type of hot oil (volumizers) in the hair care agent.This case is relevant with the still unratified application case of submitting on the same day (agent's number of putting on record IR 6232M), and both are had (Application No. of this case is not given so far) by same company.

Background of invention

People are in the research of constantly carrying out improveing hair products.Because the hair style difference, the product type that is used to handle dissimilar hairs is also different.This product of a class that people are used for making its hair produce fuller outward appearance is called hot oil.The previous method that increases hair volume relates to the spray, gel or the foam silk that use adhesive substrate and drenches and strengthen typing and generation volume.These products are by working the synthetic fixedly hair style that increases volume of hair gel.This product has usually makes hair stiff or excessively be clamminess and without eccysis with use the user shortcoming of shaping hair again usually again.The bond property of these setting agents has brought the difficulty of typing again.In addition, this fixative base product can produce fluffy effect at first, causes the decline of hair volume but long-term these products of use continuously may cause the accumulation on hair.This problem is more serious on the fine person, because this hair type is responsive especially to the weight of bringing owing to the treatment deposition.

The consumers need be not long-acting setting lotion or adhesive substrate hair spray or shaping glue make hair fluffy (volumizing) product.The consumers need be to increase the fluffy product that flat or sparse hair volume keeps some abilities of finalizing the design again simultaneously.Therefore, hot oil used herein does not produce long-acting hair style, but can allow hair finalize the design again with fluffy.

An example that is used for the retention agent of hair fixing is No. 95/06057, the open WO of people's such as Torgerson PCT patent application.The document has been described the thermoplastic elastomer copolymer of silicone graft and has been comprised the hair care and the skin care compositions of this material.These copolymers can be used for hair spray and the foam silk drenches compositions.Copolymer described in the document is water-soluble or pure molten or dispersible thermoplastic copolymer, and it has a skeleton and two or more hydrophilic polymeric side chain and one or more silicone side chain, and wherein said copolymer comprises:

(a) 20-89.9% can with (b) and (c) monomeric unit of copolymerization;

(b) the hydrophilic big monomeric unit of 10-60%, have a polymeric part and one can with (a) and (c) part of copolymerization;

(c) the big monomeric unit of 0.1-20% silicone, have a polymeric part and one can with (a) and (b) part of copolymerization.

People's such as Bolich United States Patent (USP) 4,902,499 discloses that the hair style that improvement can be provided keeps and the hair care agent of hair conditioning effect.Described Haircare composition comprises rigidity silicone polymer and the volatile vehicle of 0.01-10%.The polymer that is suitable for comprises the enhanced poly dimethyl silicone adhesive of filler, crosslinked silicone, the silicone adhesive of organic replacement, the enhanced silicone of resin and crosslinked silicone polymer.

United States Patent (USP) 5,817,302 have described low viscosity MQ silicone resin, and with the compositions of this MQ resins article and personal care articles.

WO 95/31173 has described the purposes of solid MQ resin (trimethylsiloxy esters of silicon acis) in shampoo of selecting.

WO 94/08557 has described the purposes of the solid MQ resin of selecting (poly-trimethylsiloxy esters of silicon acis) in shampoo.

People's such as Snyder European patent application EP 0 0,240 350 B1 have proposed to have the use patent of the compositions that keeps hair style and hair conditioning performance, and wherein said compositions comprises that (a) is a kind of and has at least 1 * 10 ⁶Pascal second (1 * 10 ⁷The rigidity silicone polymer of complex viscosity pool), it is selected from organic replacement silicone adhesive, silicone elastomer, the enhanced poly dimethyl silicone adhesive of filler, the enhanced silicone of resin and crosslink silicone polymers; (b) a kind of volatile vehicle, be selected from water, straight or branched C10-C16 volatile hydrocarbon and have the volatile silicone of 99-260 ℃ of boiling point, if wherein water is unique carrier, the surfactant that so also has 0.05-50% weight, and wherein do not use silicone polymer in the production of moisture aerosol hair dressing foam silk pouring compositions, the form of wherein said silicone polymer is the emulsion that contains the stable hydroxylated poly-organosilicon ketone of anion.

Other trial comprises formation hair thickening agent.The open WO of the PCT patent application of Grossman has described a kind of hair thickening agent and conditioning gelatin composition that is locally applied to hair for No. 96/38120.Disclosed preparation comprises aqueous gelatin solution, water-soluble, film-forming polymers and the maintenance compositions pH acid neutralizing agent in the 6.0-9.5 scope.The type of the water-soluble, film-forming polymers that said composition is suitable for concerning us comprises the copolymer, polyvinyl alcohol, acrylate-acrylamide copolymer, acrylate-PVP copolymer of polyvinyl acetate, pVP and the vinyl acetate of polyvinylpyrrolidone (PVP), polyvinyl acetate, partial hydrolysis etc., and wherein said polymer has the daltonian number-average molecular weight of 5000-10000.

Comprise that three organic silicone unit and the unitary silicone resin of silicon dioxide are the preparations that known commercialization material and being used for comprises the various products of binding agent, defoamer and personal care articles; But the author does not think that these chemical compounds are in the industrial hair products that are used for type described in this.This resin is called as " MQ resin " sometimes, because have monovalence (M) silicone unit and tetravalence (Q) silicon dioxide unit.

In view of the reactivity of silyl hydride groups, need in MQ type resin, comprise this group sometimes.Because wherein the high response of silyl hydride functional group often uses by silicon dioxide unit and general formula HR ¹R ²SiO _1/2The silicone resin formed of unit, each R wherein ¹And R ²Can identical or different and respectively be selected from hydrogen, monovalence hydrocarbon and monovalence halogenated hydrocarbons.This resin is used as organic silicone elastomer always.As the precursor of other synthetic silicone, need these resins to comprise the silicyl of limited quantity usually.United States Patent (USP) 3772247 discloses and has contained R ³R ⁴R ⁵SiO _1/2Unit, SiO ₂Unit and HR ³SiO and/or HSiO _3/2Unitary organic silicone resin of type, wherein R ³, R ⁴And R ⁵Respectively be independently selected from alkyl, aryl, alkaryl, alkenyl, cycloalkyl and cycloalkenyl group.Although this resin has silyl hydride groups, they also have obviously can the survey level bivalence and the organic siloxy of trivalent.

The United States Patent (USP) of Butler discloses by R for 4,774, No. 310 ³R ⁴R ⁵SiO _1/2Unit and SiO ₂The MQ resin that the unit is formed, wherein R ³, R ⁴And R ⁵Respectively be independently selected from alkyl, aryl, alkaryl, alkenyl, cycloalkyl and cycloalkenyl group.The MQ resin of the document uses acidic catalyst further to form MQ type silicone resin with the reaction of two silicone, and its M: the Q ratio is 0.4: 1 to 1: 1, and general formula H ^aR ⁿ _3-aSiO _1/2The cell mesh that interrupts of hydride be the 0.1-30% of the M unit sum that exists, wherein R ⁿBe selected from as R ³, R ⁴And R ⁵Defined group.

People's such as Berthiaume British patent 2,297,757 has been described " MQ " type and can be used as cosmetics or the low viscosity functional organic siloxysilicates of personal care articles use.These functionalized MQ silicone resins have following general formula:

R wherein ¹And R ²Be phenyl or C ₁-C ₁₂Alkyl, and M ¹And M ²All be independently selected from phenyl, phenethyl, polyethers, hydrogen and C ₁-C ₂₃Alkyl (it can comprise the alkyl that halogen replaces), and among relational expression: 0.5≤(x+y)/z≤4.0 and x and the y can be 0 below wherein x, y and z satisfied.

The United States Patent (USP) 5 of Villamarin, 585,094 discloses a kind of method of half long-acting conditioning hair, wherein the low viscosity O/w emulsion of two kinds of silicones (a kind of is hydroxy-end capped dimethyl silicone, and another kind is the methyl hydrogen silicone) mixture is used under acid pH and unreacted state.Preferably come crosslinked described polymer with heating.

People's such as Bolich United States Patent (USP) 4,963,348 has been described setting agent that comprises binder copolymer and volatile thinner and the compositions that is used to provide hair fixing and maintenance.

But, still exist not making the needs that are suitable for the compositions that is hot oil that hair is stiff or excessively be clamminess.

Therefore, a target of the present invention provides not rely on and comes together to obtain the fluffy compositions that volume increases with hair fiber is bonding.Specifically, a free-revving engine of the present invention provides a kind of hot oil that can give hair fluffy (volume) and can bonding hair fiber.Another object of the present invention provides a kind of leavening agent that can arrange hair and fluffy again (volumize) hair after hair washing again.Also purpose of the present invention provides and is applicable to the compositions as hot oil that increases a certain amount of hair volume.A further object of the present invention provides to be suitable for and is the compositions of hot oil, and it uses the MQ resin and makes the pressure of hair tolerance hairnet.Be appreciated that these and other purpose of the present invention by following explanation.

The present invention's summary

Compositions of the present invention is a hot oil, comprises

(a) the liquid MQ resin of the selection of 0.01-15% weight (based on the gross weight of compositions), described resin have the M of 0.5-1.5: Q ratio and 1.0 * 10 ³To 1 * 10 ⁶The medium-viscosity of centipoise (" cps " or " cP ") (for example 0.1-10% weight, more preferably 0.1-7.0%, most preferably 0.1-4%); With

(b) the hair care carrier (being also referred to as vehicle) of 85-99.99% weight (based on the gross weight of compositions).

Compositions of the present invention provides the volume that increases hair and has not had significantly not stiff or excessively be clamminess or product causes the minimizing of volume on hair.Compositions of the present invention can be prepared into the form that shampoo, conditioner, shampoo-conditioner complexing agent (so-called 2 close 1 product), spray, liquid detergent, gel or foam silk drench.

Detailed description of the present invention

Compositions of the present invention can be with the liquid MQ resins of one or more selections, and described MQ resin has the M of 0.5-1.5: Q than [be also referred to as x+y/z than (for formula 1A) or x '/z ' than (if the x part is identical with the y part, suc as formula 1B)] and 1.0 * 10 ³To 1 * 10 ⁶Centipoise (" cps " or " cP ") (or 1.0 to 1 * 10 ³Pa-sec) viscosity, preferred 1.5 * 10 ³To 1 * 10 ⁶Centipoise, more preferably 1000-100,000Cps even more preferably 1000-50,000cps, more preferably 1000-20 more also, 000cps be as 2,000-14, and the viscosity of 000cps, an object lesson is 3,000-12,000cps.Though can use and have viscosity higher (as 50,000-100, MQ resin 000cps) uses then more convenient than low viscosity.

Be applicable to that MQ resin of the present invention can be represented by formula IA:

Formula LA

R in the formula ⁴, R ⁵, R ⁶And R ⁷Respectively be independently selected from phenyl and C ₁-C ₁₂Branch or unbranched hydro carbons, preferably C ₁-C ₁₂Branch and unbranched alkyl, more preferably branch and unbranched C ₁-C ₅Alkyl, particularly methyl;

M ¹And M ²Respectively be independently selected from

(a) hydrogen,

(b) phenyl,

(c) phenethyl,

(d) polyethers of facial II under:

-H ₂C-(CH ₂) _n-(O-CH (R ¹⁰)-CH ₂) _u-(OCH ₂-CH ₂) _v-OR ¹¹N is the number of 1-20 in the formula ,-(CH ₂)-chain can be chosen wantonly and comprise 1 or 2 degree of unsaturation; Respectively for being independently selected from the integer of 0-20, condition is u+v 〉=1 for u and v; R ¹⁰Be selected from C ₁-C ₂₀Alkyl; R ¹¹Be selected from H ,-CH ₃With-C (O) CH ₃With

(e) C that is replaced by halogen ₁-C ₃The optional C that replaces of alkyl ₁-C ₂₄Branch or unbranched hydrocarbon, occurrence are C ₁-C ₂₄Alkyl, particularly methyl; With

(x+y)/z is the number in 0.5 to 1.5 scope and preferably equals 1 in the formula; With

Select R ⁴, R ⁵, R ⁶, R ⁷, x, y, z, M ¹And M ²Thereby value make described MQ resin for having 1.0 * 10 ³To 1 * 10 ⁶The viscosity of centipoise is as 1.5 * 10 ³To 1 * 10 ⁶The liquid of centipoise viscosity.

When x was identical with y, the MQ resin of the particular type of formula IA can be represented by formula IB:

Formula IB

R in the formula ¹And R ³Each is selected and the R of formula IA independently ⁴, R ⁵, R ⁶And R ⁷The identical group of definition; R ²Be selected from as M ¹And M ²Described identical group; Preferred R ¹, R ², R ³It respectively is methyl; X '/z ' is 0.5 to 1.5 a value, and preferred x '/z ' is 1.

It is a kind of that specifically to can be used for MQ resin of the present invention be liquid trimethylsiloxy esters of silicon acis polymer, be specially and have M: the ratio of Q is 1 (for example can be available from General ElectricCompany, Waterford, the resin of the commodity of New York " MQ-A " by name).

It is different with the MQ resin of other type that does not have all required character of the present invention to can be used for MQ resin of the present invention.Just as described in greater detail below, have been found that to have M: the Q ratio does not provide big volume for 2 low-viscosity (mobile) liquid MQ resin, and does not embody the significant bond properties to hair; Have M: the Q ratio does not provide big volume for 2 solid MQ resin, and does not embody the significant bond properties to hair yet; M with 0.7-1.0: the solid MQ resin of Q ratio provides volume (volume) but has not embodied significant bond properties to hair.

The vehicle at MQ resin place is selected from spray, hair dye (rinse), shampoo, conditioner and " 2 close 1 " conditioning shampoo.Particularly, these products can be with volatile vehicle (promptly having the carrier that can survey vapour pressure) as volatile silicone, C ₂-C ₃The mixture of alcohol, isopropyl myristate He Shui and aforementioned substances, condition is if water is unique carrier such as water base shampoo, water base conditioner etc., so also uses at least a surfactant.The preferred carrier of one class is that boiling point is 99-260 ℃ a volatile silicone.Described silicone can be linearity or ring-type poly dimethyl silicone, and wherein ring-type poly dimethyl silicone comprises 3 to about 7 silicon atoms, most preferably 5 silicon atoms.These volatile silicones can use separately or use in conjunction with other volatile vehicle.A kind of concrete volatile silicone is cyclomethicone (a particularly D5 cyclomethicone).

If water is unique carrier, then also there is the surfactant (being selected from one group of material described below) of 0.1-50% weight (in the gross weight of compositions).

Shampoo can be used as carrier, and selected MQ resin can add wherein.The shampoo that is suitable for comprises conventional shampoo and conditioning shampoo.Concrete shampoo comprises the shampoo with the liquid MQ resin preparation of surfactant, stabilizing agent and selection as mentioned above.As described below, other optional member such as thickening agent, antiseptic, spice, opacifiers, foam modifier etc. also can be included in this preparation.

The surfactant that is fit to comprises:

(a) as at the anion surfactant described in people's such as people's such as Bolich United States Patent (USP) 4,902,499 and Bolich the United States Patent (USP) 4,963,348 (both all incorporate this paper by reference into), such as:

(i) formula R ²⁰OSO ₃M and R ²⁰O (C ₂H ₄O) _wSO ₃The alkyl of M and alkyl ether sulfate, R in the formula ²⁰Be the alkyl or the alkenyl of 10-20 carbon atom, w is 1 to 10 number, and M is water-soluble cationic such as ammonium, sodium, potassium and triethanolamine;

(ii) fatty acid (as the fatty acid derived from cocos nucifera oil) is also used the neutral product of sodium hydroxide with isethionic acid (isethionic acid) esterification;

(iii) Succinamate (salt), for example N-octadecane sulfo-succinic acid disodium salt, N-(1,2-two carboxyethyls)-N-octadecane sulfosuccinamic acid tetrasodium salt, the diamyl ester of sodium sulfo-succinate, the dihexyl of sodium sulfo-succinate and the dioctyl ester of sodium sulfo-succinate; With

The alkene sulfonate that (iv) has 12 to 24 carbon atoms;

(b) amphoteric surfactant described in people's such as Bolich United States Patent (USP) 4,902,499 (incorporating this paper by reference into), such as

(i) derivant of aliphatic secondary amine and tertiary amine, wherein said aliphatic group can be that straight or branched and one of them aliphatic substituent group comprise 8 to 18 carbon atoms and one and comprise anion water solubilization group (for example carboxyl, sulfonate radical, sulfate radical, phosphate radical or phosphonate radical), the example of this chemical compound comprises that 3-dodecyl-alanine sodium, 3-dodecyl amino propane sulfonic acid sodium, N-alkyl taurine, N-senior alkyl aspartic acid are (for example as United States Patent (USP) 2, product described in 528, No. 378) with trade name " MIRANOL " sale;

(ii) zwitterionic surfactant, its example has the derivant of aliphatic quaternary ammonium, Phosphonium and sulfonium compound, wherein aliphatic group can be a straight or branched, and one of them aliphatic substituent group comprises 8 to 18 carbon atoms and one and comprises anion water solubilization group (for example, carboxyl, sulfonate radical, sulfate radical, phosphate radical or phosphonate radical);

(iii) betanin, for example senior alkyl betanin such as coco dimethyl carboxymethyl betaine, lauryl dimethyl carboxymethyl betaine, lauryl dimethyl α-carboxyethyl betanin, cetyl dimethyl carboxymethyl betaine, lauryl two-(2-ethoxy) carboxymethyl betaine, stearyl be two-(2-hydroxypropyl) carboxymethyl betaine, oil base dimethyl-γ-carboxylic CAB, lauryl be two-(2-hydroxypropyl) α-carboxyethyl betanin and cocamidopropyl betaine.

(c) non-ionic surface active agent comprises those non-ionic surface active agents described in the United States Patent (USP) 4,741, No. 855 (it incorporates this paper by reference into) that is selected from people such as Grote, and they are

(i) polyethylene oxide condensation compound of alkylphenol, the moieties of wherein said alkylphenol have 6-12 carbon atom and can be straight or branched, and ethylene oxide moiety exists with the amount of every mole of alkylphenol 10-60 moles of ethylene oxide;

(ii) oxirane with a kind of by expoxy propane and adopt according to required hydrophobic/hydrophilic balance different ethylenediamines product condensation product (for example, contain the polyoxyethylene of 40-80% weight and have 5,000-11, the chemical compound of 000 molecular weight, it comes from the reaction of ethylene oxide group and the hydrophobic alkali that is made of the product of ethylenediamine and excessive expoxy propane, wherein said alkali has 2,500-3,000 molecular weight);

(iii) C _8-18The condensation product of straight or branched aliphatic alcohol and oxirane (the cocoanut oil alcohol ethylene oxide condensate of for example every mole of coco alcohol 10-30 moles of ethylene oxide, wherein said cocos nucifera oil partly has 10-14 carbon atom);

(iv) formula (R ³⁰) (R ³¹) (R ³²The long chain tertiary amine oxide of)-N → O, wherein R ³⁰Be C _8-18Alkyl, alkenyl or monohydroxyalkyl group; It has 0-10 ethylene moiety and 0-1 glyceryl part; R ³¹And R ³²Can identical or different and respectively be independently selected from C _1-3An alkyl and 0-1 hydroxyl.Arrow in structure is that the routine of semi-polar bond is represented.The example of the long chain tertiary amine oxide that is fit to comprises cocamidopropyl propylamine oxide and lauryl amine oxide.

(v) formula R ²⁰R ²¹R ²²The long chain tertiary phosphine oxide of-P → O, wherein R ²⁰Be C _8-18Alkyl, alkenyl or monohydroxyalkyl group; It has 0-10 ethylene oxide moiety and 0-1 glyceryl part; R ²¹And R ²²Each is C independently _1-3Alkyl or monohydroxy alkyl.Arrow in formula is that the routine of semi-polar bond is represented.

(vi) long-chain dialkyl sulphoxide, it contains the short-chain alkyl of a 1-3 carbon atom or hydroxyalkyl (particularly methyl) and one and has C _8-20The long hydrophobic chain of alkyl, alkenyl, hydroxyalkyl or oxoalkyl group has 0-10 ethylene oxide moiety and 0-1 glyceryl part.

Stabilizing agent comprises one or more of following ingredients listed, and the amount of the final stabilizing agent that adds is 0.1-7.0%:

(a) have 14 above carbon atoms such as C _20-40The mixture (for example a kind of C＞14 are pure and mild available from Petrolite Corporation, St.Louis, the Alathon PETROLITE C-7138 of Missouri) of the pure and mild this long-chain fatty alcohol of long-chain fat.

(b) acrylate/steareth-20 methacrylate copolymer is (for example available from Rohm ﹠amp; Haas, Philadephia, the ACULYN of Pennsylvania ^22); And acrylate copolymer is (for example available from Rohm ﹠amp; The acrylate copolymer ACULYN of Haas ^33, ACUSOL ^-445 ,-810 and-830, ACRYSOL ^ASE 75); And acrylate/C _10-30Alkyl acrylate crosspolymer is (available from BF Goodrich Company, Brecksville, the PEMULEN of Ohio ^TMPolymeric emulsifiers, the product of TR-1 particularly by name and TR-2).For acrylate copolymer (ACUL YN  33) product (pH with 2.1-3.5 scope), acceptable organic amine carries out neutralization procedure and pH is brought up to about 6.5 on use sodium phosphate (such as disodium hydrogen phosphate), sodium hydroxide or the cosmetics.

(c) at United States Patent (USP) 5,015, the N of the reagent, particularly formula III described in No. 415 (incorporating this paper by reference into), the dibasic phthalamic acid of N-and its ammonium salt:

Formula III

R in the formula ²⁴And R ²⁵Can be identical or different, and respectively be selected from C ₁₀-C ₄₀Straight chain and branched alkyl and C ₁₀-C ₄₀Straight chain and side chain aryl alkyl (for example, R in the formula ²⁴And R ²⁵Identical and respectively be selected from stearyl and hydrogenated tallow such as available from Stepan Company, Northfield, the STEPAN SAB-2 of Illinois and STEPAN TAB ^-2).

Described stabilizing agent should be that cosmetics use to be gone up acceptable grade and purity or by acceptable essential purification on the cosmetics.The further discussion of these reagent can be referring to people's such as Goze United States Patent (USP) 5,015,415 and our still unratified patent application U. S. application number 08/933521.

The vectorial shampoo carrier that can be used as above-mentioned selected MQ resin can be prepared into solution, suspension or the emulsion of composition of detergent that contains gentleness, moisture, foaming and conditioning, and described compositions comprises (in composition total weight):

(a) detersive surfactant of 4.00-60.00%, it is selected from C ₈-C ₁₈Alkyl sulfate, in molecule, contain the C of 1-5 oxyethylene group ₈-C ₁₈Alkyl oxyethylene group ether sulfate, C ₁₀-C ₁₈Acyl isethinate, C ₁₀-C ₂₀Alkylsulfonate, C ₁₀-C ₂₀The anionic detergent of olefin sulfonate and its mixture; With choose any one kind of them:

(i) C of the water-soluble growth regulator of 0.10-5.00% anion ₁-C ₃Alkylbenzenesulfonate or C ₅-C ₆Alkyl sulfate;

(ii) the 0.10-15.00% amphoteric surfactant is selected from C ₈-C ₁₈Alkyl betaine, C ₈-C ₁₈Alkyl sulfobetaines, C ₈-C ₁₈Alkylamidoalkyl C ₂-C ₃Alkyl betaine, C ₈-C ₁₈Alkylamidoalkyl C ₂-C ₃Alkyl sulfobetaines, C ₈-C ₁₈Alkyl both sexes acetate, C ₈-C ₁₈Alkyl both sexes propionate, cocamidopropyl betaine and its mixture; With

(iii) the 0.1-4.0% nonionic surfactant particularly is selected from C ₈-C ₂₂Single ethanol amide and its mixture and C ₈-C ₂₂Diglycollic amide and its mixture, particularly coconut monoethanol amide and cocos nucifera oil diglycollic amide;

Condition is 60% weight that the total amount of detersive surfactant is no more than described composition total weight, and preferred scope at 6-30%;

(b) 0.10-7.0 (more preferably 0.10-5.00) %'s is selected from above-mentioned stabilizing agent, the derivant of polyacrylic acid, polyacrylic derivant, acrylate copolymer, acrylate copolymer and polymeric emulsifiers such as acrylate/C10-30 alkyl acrylate cross-linked copolymer particularly, specific product comprises that trade mark is called ACULYN  33, TAB -2, SAB-2 and PEMULEN ^TMProduct; Also can use the mixture of ACULYN  22 acrylate/steareth-20 methacrylate copolymer and ACULYN  33 products (all according to appointment 50 to 50);

(c) Ren Xuan quaternized cellulosic polymer (particularly at least a quaternized cellulosic polymer, for example Polyquaternium-10);

(d) all the other materials such as water or water-bearing media.

For conditioning shampoo, optional can add another kind of composition (e):

(e) the water-insoluble conditioner of 0.01-10.00%, it is selected from:

(i) the water-insoluble silicone of 0.10-6.00% is selected from the silicone described in No. 4,741,855, poly dimethyl silicone and silicone such as the United States Patent (USP) of incorporating this paper by reference into; They comprise the mixture of poly-alkyl silicone, poly-aryl silicone, polyoxyethylene alkyl aryl base silicone, polyester silicone copolymer and aforementioned substances, its amount is 0.1-10.00%, preferred about 0.5-5.0%, for example can Viscasil series available from General Electric Company and with Dow Corning 200 series available from Dow Corning, at 25 ℃ of following tool 5-600, the poly dimethyl silicone of 000 centistoke (as 60,000 centistokes) viscosity; Under 25 ℃, have 15-30, the polymethyl-benzene base silicone of 000 centistoke (for example can available from the SF 1075 aminomethyl phenyl fluids of General Electric Company and can be available from the Dow Corning 556 cosmetics-stage fluids of Dow Corning); With material with the mixture modification of the dimethyl silicone of poly(propylene oxide) modification and oxirane or EO and PO;

(ii) at least a (d) (i) with the mixture of 0.01-3.00% cationic polymer, described cationic polymer is as being selected from the poly quaternary ammonium compound of quaternized cellulosic polymer (particularly at least a quaternized cellulosic polymer such as Polyquaternium-10);

(iii) non-cellulose quaternary ammonium compound (for example Polyquaternium-7); With

(iv) at least a (d) (i) with the mixture of 0.01-3.00% cationic polymer, described cationic polymer is as being selected from the poly-quaternary compound of at least a quaternized cellulosic polymer and non-cellulose quaternary ammonium conditioning polymer.

Note as needing to use suspending agent or stabilizing agent with some silicone of use described in the patent documentation here.

The shampoo of another particular type can prepare by the MQ resin that mixes 0.1-15%, the surfactant (as synthetic surfactant) of 4-60%, the stabilizing agent (based on 100% activity) and the water of remainder of 0.5-7%.The example of the surfactant that is fit to comprises ammonium lauryl sulfate; Zetesol AP; the lauryl sulfate triethylamine; lauryl ether sulphuric acid triethylamine; triethanolamine lauryl sulfate; lauryl ether sulphuric acid triethanolamine; lauryl sulfate monoethanolamine; lauryl ether sulphuric acid monoethanolamine; lauryl sulfate diethanolamine; lauryl ether sulphuric acid diethanolamine; Laurel monoglyceride sodium sulfate; sodium lauryl sulfate; sodium laureth sulfate; lauryl potassium sulfate; the lauryl ether potassium sulfate; the sarcosine Lauryl Ester; sarcosine cocoyl ester; cocoyl ammonium sulfate; lauroyl ammonium sulfate; cocoyl sodium sulfate; lauroyl sodium sulfate; the cocoyl potassium sulfate; the lauroyl potassium sulfate; lauroyl sulphuric acid triethanolamine; lauroyl sulphuric acid triethanolamine; cocoyl sulphuric acid monoethanolamine; lauroyl sulphuric acid monoethanolamine; tridecyl benzene sulfonic acid sodium salt and dodecylbenzene sodium sulfonate and at the people's such as Bolich that incorporate this paper by reference into United States Patent (USP) 4; other material described in 902, No. 499 the 4-6 hurdle.

Be used to carry suitable vectorial another object lesson of preparation of the present invention to comprise conditioner.Concrete preparation is the preparation that adopts matrix material, cationic surfactant and water preparation.This preparation can be referring to No. 5,120,531, the United States Patent (USP) of incorporating this paper by reference into.

Being used for lipid vehicle material of the present invention is to have hydrophobic and water-insoluble compound hydrophilic segment.The example of the matrix material that is fit to is that it has 12-22 carbon from natural or the deutero-acid of synthetic method, acid derivative, alcohol, ester, ether, ketone, alcohol ethoxylates and amide, and the carbochain of preferred 12-18 and 16-18 carbon.Object lesson comprises ester such as cetyl palmitate and glyceryl monostearate; Alcohol is such as spermol and stearyl alcohol.Concrete matrix material has the octadecanol of (a) monoester material form and (b) mixture of the octadecanol of 55-65% spermol and remaining sum.These matrix materials comprise and derive from natural or the deutero-aliphatic alcohol of synthetic method, fat alcohol ethoxyl compound and fatty ester.

The cationic surfactant that can be used for forming this conditioner comprises cationic surfactant described in above mentioned United States Patent (USP) 5,120,531 other documents of neutralization.Object lesson comprises the cationic surfactant of the hydrophilic segment that contains amino or quaternary ammonium positively charged when being dissolved in Aquo-composition, such as general formula (R ¹⁰) (R ¹¹) (R ¹²) (R ¹³) N ^{+ 1}The cationic surfactant of-X, R in the formula ¹⁰For the aliphatic group of hydrogen, a 1-22 carbon atom or have the aromatics aryl or the alkylaryl of 12-22 carbon atom; R ¹¹For having the aliphatic group of 1-22 carbon atom; R ¹²And R ¹³Respectively be independently selected from alkyl with 1-3 carbon atom; X is the anion that is selected from halogen, acetate, phosphate radical, nitrate anion and alkyl sulfate group.Except carbon atom and hydrogen atom, described aliphatic group can comprise ehter bond and other group such as amide groups.The example of quaternary ammonium salt comprises hexadecyltrimethylammonium chloride (" cetrimonium chloride "), lauryl trimethyl ammonium chloride (" laurtrimonium chloride "), three (cetyl) ammonio methacrylate (" tricetylmonium chloride "), stearyl dimethyl benzyl ammonium chloride (" stearalkonium chloride ") and two (partial hydrogenation Adeps Bovis seu Bubali) alkyl dimethyl ammonium chloride, two (octadecyl) alkyl dimethyl ammonium chlorides etc.

A concrete class conditioner is selected from quaternary ammonium compound, particularly two (cetyl) alkyl dimethyl ammonium chloride, two (octadecyl) alkyl dimethyl ammonium chlorides and above-listed other cationic substance in cationic surfactant.

The example that selected MQ resin can add conditioner wherein is the conditioner with 0.1-10.0% lipid matter, 0.05-5.0% cationic surfactant and water preparation.

The agent of rinsing hair care can be by mixing aforesaid MQ resin (or its mixture) and preparing as the water (preferably distilled water or deionized water) or the water/alcohol mixture (as the ratio with 20: 1 to 1: 2) of carrier part.The surfactant that also comprises simultaneously 0.1-10%.Described carrier with account for total composition 75-99.5% weight, preferably about 85-99% and more preferably from about the amount of 90-99% exist.

Spray can prepare by MQ resin (or its mixture) and one or more volatile material such as above-mentioned water, ethanol, cyclomethicone (if comprise the water of significant quantity, then comprising at least a surfactant of 0.1-10% as mentioned above like that) and one or more the aforesaid optional members that mix 0.01-10%.

Other object lesson (it can be forms such as shampoo, conditioner, conditioning shampoo, spray) that is suitable as the carrier of leavening agent of the present invention is familiar with for those skilled in the art, for example be described in people's such as Kobot United States Patent (USP) 3,577,517, people's such as Calvert United States Patent (USP) 3,907,984, the United States Patent (USP) 4 of Farber, 012,501, people's such as Chakrabarti United States Patent (USP) 4,223,009 and people's such as Jacquet United States Patent (USP) 4,283, in 384, described patent is all incorporated this paper by reference into.

Except the above-mentioned basic recipe that is used for shampoo and conditioner, also may need to add one or more following ingredients and their mixture:

(a) be used for the viscosity modifier of shampoo-

The block polymer of the diglycollic amide of polyvinyl alcohol, ethanol, acrylate copolymer and copolymer, cellulose ether, long-chain fatty acid or single ethanol amide (as PEG 3 lauramides), oxirane and expoxy propane, sodium chloride, sodium sulfate, water-soluble polymer (such as guar gum) be thickening agent such as hydroxypropyl cellulose, Rhaball Gum CG-M 8M, PEG-120 methyl glucoside dioleate, pentaerythritol tetrastearate and Xanthan gum particularly.

(a1) be used for the viscosity modifier of conditioner-

Polyvinyl alcohol, ethanol, cellulose ether, polyacrylamide, particularly a kind of thickening agent of water-soluble polymer (such as hydroxyethyl-cellulose, guar gum and starch) are such as hydroxyethyl-cellulose and Rhaball Gum CG-M 8M.

(b) spice is such as acceptable spice on the cosmetics that are used for hair products;

(c) antiseptic, antibacterial for example, particularly the mixture of methyl chloride Methylisothiazolinone and Methylisothiazolinone is (by Rohm and Haas, Philadelphia, Pennsylvania sells with trade name KATHON  CG), also can comprise benzyl alcohol, ethylparaben, propyl p-hydroxybenzoate and imidazolidinyl urea, DMDM Hydantoin, formalin, 2-bromo-2-nitropropane-1, the mixture of 3-glycol (" Bronopol ") and aforementioned substances.Object lesson also can comprise synergist such as ethylenediaminetetraacetic acid (EDTA) or its sodium-salt form (for example Bronopol and EDTA (such as 0.04%Bronopol and 0.1%EDTA); Formalin, DMDM Hydantoin and EDTA (such as 0.1% formalin, 0.45%DMDM hydantoin and 0.2%EDTA));

(d) be applicable to dyestuff or coloring agent, pearling agent (such as glycol distearate, sodium octyl sulfate, titanium dioxide or Muscovitum) and the opacifiers (such as glycol distearate, fatty ethoxy compound, latex opacifiers, stearmide monoethanolamine (MEA) stearate, cetyl sodium stearate and lanolin derivative) of hair products;

(e) pH regulator agent such as citric acid, sodium carbonate etc.;

(f) chelating agen such as ethylenediaminetetraacetic acid and its sodium salt.

These additives can for example respectively account for the about 0.01-60% of described composition total weight in right amount, preferably the amount of about 0.5-40% weight comprises wherein.

Thereby but one skilled in the art will realize that according to the lasting fluffy effect on the composition prepared generation time of the present invention purposes according to the product of the present invention preparation can be changed by the commodity shampoo of other type to obtain and to keep required fluffy effect.Though the increase of hair volume is different with the people, increase by the cumulative volume of adhering to using compositions of the present invention can obtain the 10-40% that Mannequin volume test method as described below records.In general, will be more remarkable to sparse, fine influence than dense, long thick hair.

Should be noted that also compositions of the present invention provides the fluffy effect under the chemical adhesion that does not have between actual fixed performance (viscosity) and hair fiber.Therefore described hair can the typing again by combing or fluffy again processing again.The hair that this method is handled for fixative is invalid, thereby because it will cause the cracked of fixative bounding point between hair and lose fixative typing effect.The shortage situation of fixed performance can be estimated by the endurance life test of curling in compositions of the present invention, and one of them is described below.

Can comprise according to the example of the preparation of the present invention preparation:

Shampoo:

Prescription A-0.1-7.5%, preferred 0.1-5% or 0.1-3.0% and the more preferably selected liquid MQ resin of 0.25-2.5%, all the other are shampoo vehicle.For conditioning shampoo, also can comprise the conditioner of 0.1-3.0%, particularly 0.1-2.0%.

Prescription B-

The surfactant of 10-18% particularly is selected from the mixture of ammonium lauryl sulfate, Zetesol AP, sodium laureth sulfate, lauryl ether ether sodium sulfate, Zetesol AP, lauryl ether ether ammonium sulfate and aforementioned substances;

The selected MQ resin of 0.25-2.5%;

The stabilizing agent of 0.10-5.00%;

The spume composition (for example at least a cocamidopropyl diethanolamine, cocamidopropyl monoethanolamine and the cocamido propyl betaine of being selected from) of regulator and/or viscosity modifier effect of 1-3%; With

Remaining water or other water-bearing media can comprise antiseptic and the spice and the coloring agent of effective dose.

Prescription C-

The 10-20% mixed surfactant system, comprise that ratio is 60: 40-40: 60 at least a anion surfactant and at least a amphoteric surfactant (suitable examples of anionic surfactants identical with described in the prescription B, the example of the amphoteric surfactant that is suitable for is cocamido propyl betaine and cocamidopropyl propyl amide amine oxide); The MQ resin that 0.25-2.5% selects;

The stabilizing agent of 0.10-5.00%; With

Remaining water or other water-bearing media, described medium can comprise antiseptic and the spice and the coloring agent of effective dose.

Conditioner:

0.1-7.5%, preferred 0.1-5%, more preferably 0.2-2.5% selection liquid MQ resin and as all the other materials of the carrier of compositions.

Prescription D-

The matrix material of 1-4% (for example mixture of octadecanol and octadecanol and spermol);

The quaternized chemical compound of 1-3% (two (cetyl) alkyl dimethyl ammonium chloride for example; At least a in VARISOFT TA100 and the hexadecyltrimethylammonium chloride); With

Remaining water or other water-bearing media, described medium can comprise antiseptic and the spice and the coloring agent of effective dose.

Fluffy spray:

0.01-7.5%, preferred 0.03-5.0%, more preferably the selection MQ resin of 0.05-2.0% and volatile vehicle be such as ethanol.

Fluffy hair dye:

0.1-7.5%, preferred 0.1-5.0%, more preferably selection MQ resin and carrier such as the water of 0.2-2.5% and the proper amount of surfactant/stabilizing agent (for example Ceteth-20 and hexadecyltrimethylammonium chloride) (amount of stabilizing agent depends on the amount of used MQ resin) that is used to keep emulsion-stabilizing.

Tool is the hair spray of additive fixedly:

The selection liquid MQ resin of 0.01-7.5%, preferred 0.05-2.0%;

The volatile vehicle of 0.1-20%, preferred 0.5-1 5;

The fixative vehicle (itself can contain volatile vehicle) of 72.5-99.89%, preferred 83-99.45% such as ethanol;

Its various compositions can be that single composition also can be a mixture.

Compositions of the present invention usually can be by conventional interpolation and hybrid technology preparation.Described MQ resin can several modes add.Under the situation of shampoo preparation, the MQ resin can separate interpolation as following embodiment, mixes adding separately or with cyclomethicone or dimethyl silscone.Perhaps the MQ resin can join in the oil phase of heating before forming any emulsion.

Compositions of the present invention makes hair maintenance concrete hair style or structure more easy.Obviously, the use of this compositions does not hinder the influence of decorating and not opsonifying the agent existence.In addition, the increase of verified its volume of test does not reduce with repeated use, and this is the following situation that may occur of the fixative on being accumulated in hair not.

Another feature of the present invention is the compositions that can be mixed with the hair rinse.Therefore, though can be mixed with the product of persistencing (leave in produets) based on the leavening agent of adhesive substrate, situation of the present invention is different with it, and it can be mixed with persistence product or eluting product (rinse-offproducts).

Compositions of the present invention also can be used in combination with fixative and can not lose fluffy effect.Test has shown that the resin of MQ described in this does not demonstrate the effect of disturbing fixative.

Though compositions of the present invention is described by the term of " comprising (containing) ", described compositions also will comprise by term " by ... form " and the compositions of " basically by ... composition " narrower scope of illustrating.Equally, though compositions of the present invention was described with " comprising (containing) ", it should be understood that described compositions also comprises those compositionss of making by with the composition combination of listing in the described compositions.

Embodiment

Following embodiment is used to illustrate the present invention, but can not regard limitation of the invention as.Unless add explanation in addition, otherwise all percentage ratios all are based on the percentage by weight of 100% effect level of all the components, all chemistry and scientific terminology all have its meaning common and custom.All temperature be degree centigrade (℃).These agreements also are applicable to the remainder of present patent application.

Embodiment 1-4 conditioner

Use the material preparation conditioner of listed type of table 1 and amount.In a suitable container, at room temperature hydroxyethyl-cellulose is dispersed in the distilled water.Under agitation add C9-11 alcohol ethoxylates (EO6: 1) (" C9-11 Pareth-6 "), and the solution that obtains is heated to 75 ℃ then.In a container that is fit to, mix ceteth-20, steareth-20, octadecanol, iso stearyl amido propyl dimethyl amine and two (cetyl) alkyl dimethyl ammonium chloride and under agitation be heated to 75 ℃.When two kinds of solution are 75 ℃, under agitation water is joined in the oil phase.The emulsion that obtains was stirred 10 minutes down at 75 ℃, be cooled to 60 ℃ then.Liquid trimethylsiloxy silicate is dissolved in the cyclomethicone and under 62 ℃ joins in the emulsion.Then emulsion is cooled to 38 ℃ and under this temperature, add spice and antiseptic.At last with the preparation cool to room temperature.The MQ resin that uses is the trimethylsiloxy silicate (" MQ-A ") available from GE.

Table 1

Material	Embodiment 1 % weight	Embodiment 2 % weight	Embodiment 3 % weight	Embodiment 4 % weight
					Distilled water	93.85％	93.85％	?93.85％	?93.85％
Hydroxyethyl-cellulose	0.50	1.00	?1.0	?1.0
					C9-11?Pareth-6	0.20	0.20	?0.20	?0.20
Ceteth-20	0.50	0.50	?0.50	?0.50
					Steareth-20	0.50	0.50	?0.50	?0.50
Octadecanol	2.00	2.00	?2.00	?2.00
					Isostearoyl amine propyl group dimethylamine	0.80	0.80	?0.80	?0.80
Two (cetyl) alkyl dimethyl ammonium chloride	1.50	1.50	?1.50	?1.50
					Liquid trimethylsiloxy silicate	2.50	2.50	?0.75	?1.5
Cyclomethicone (D5)	2.50	2.50	?2.50	?2.50
					Spice	0.75	0.75	?0.75	?0.75
Methyl chloride Methylisothiazolinone and Methylisothiazolinone	0.07	0.07	?0.07	?0.07

Embodiment 5 conditioners

With following material preparation 300g conditioner sample: 0.50% hydroxyethyl-cellulose; 93.35% distilled water; 2.75%Cetearyl alcohol; 0.50% stearamide propyl dimethylamine; 0.15% polyglyceryl-3 diisopstearate; 0.25% citric acid; 0.20% methyl dibromo glutaronitrile and phenyl phenol (available from Calgon Corporation, Pittsburgh, the MERUARD  1200 of Pennsylvania); 0.15% glyceryl monostearate; 1.50% VARISOFT TA100; MQ resin described in the 0.25% embodiment 1-4; 0.40% spice.In a container that is fit to, mix described hydroxyethyl-cellulose and distilled water.Solution is heated to 80 ℃.In another container, mix cetearyl alcohol, VARISOFT TA100, stearamide propyl dimethyl amine, glyceryl monostearate and polyglyceryl-3 diisopstearate and under agitation be heated to 80 ℃.When two kinds of mixture are 80 ℃, water is under agitation joined in the oil phase.The emulsion that obtains is cooled to 60 ℃ also under agitation adds silicone MQ resin.When reaching 38 ℃, temperature adds spice and antiseptic.Then with last preparation cool to room temperature.

Embodiment 6-7 shampoo preparation

Use type of material described in the Table II and amount preparation shampoo preparation.In the container that is fit to, except that staying 10% distilled water, the water that other is all, EDTA four sodium, sodium hydrogen phosphate (disodium hydrogen phosphate), ammonium lauryl sulfate, deceth-3 sodium sulfate, cumenyl sodium sulfonate, cocamido propyl betaine mix.The solution that obtains under agitation is heated to 90 ℃.In a little container, mix the distilled water and the Polyquaternium-10 of remaining 10% weight.Adding the content of pining for small container joins above the solution that is just heating.In a suitable container, mix and fusion isosteareth-2, C _20-40Pure and mild VARISOFT TA100.In case fusion just under agitation joins this mixture in 90 ℃ the aqueous solution.Then the emulsion that obtains is cooled to 60 ℃.Liquid trimethylsiloxy silicate (with MQ resin identical described in the embodiment 1-4) is dissolved in the emulsion that also under agitation joins 60 ℃ in the cyclomethicone.Then the mixture that obtains is cooled to 38 ℃ and under this temperature, add spice and antiseptic.Then with final preparation cool to room temperature.Attention has been used this step for embodiment 7, but does not use deceth-3 sodium sulfate, isosteareth-2, VARISOFT TA100 or cyclomethicone.

Table II

Material	Embodiment 6% (weight)	Embodiment 7% (weight)
			Distilled water	In right amount	In right amount
EDTA four sodium	0.10	0.10
			Disodium hydrogen phosphate	0.20	0.20
Ammonium lauryl sulfate	3.36	8.26
			Deceth-3 sodium sulfate	4.50	0
Cumene sodium sulfonate	2.80	0.66
			Cocamido propyl betaine	9.00	9.00
Polyquaternium-10	0.90	0.55
			Isosteareth-2	0.80	0.00
C20-40 alcohol	4.00	2.00
			VARISOFT TA100	1.00	0.00
Liquid trimethylsiloxy silicate	2.50	1.00
			Cyclomethicone (D5)	2.50	0.00
Spice	1.20	0.75
			Methyl chloride Methylisothiazolinone and Methylisothiazolinone	0.07	0.07

Embodiment 8-9 shampoo preparation

Use the listed type of Table III and the material preparation shampoo preparation of amount.In the container that is fit to, except that staying 10% distilled water, remaining distilled water and sodium phosphate are mixed and mixed 10 minutes.The adding ammonium lauryl sulfate also mixed 5 minutes.The solution that obtains is heated to 50 ℃.With the water and Polyquaternium-10 premixing 1-2 minute of remainder and joined in the described container remix 15 minutes.In an independent container, under constantly stirring, cocos nucifera oil diglycollic amide (" coconut oleoyl amine DEA "), guar gum are mixed and be heated to 50 ℃.When two containers reach 50 ℃, under agitation merge.Silicone MQ resin (resin identical with embodiment 1-4) and dimethyl silscone (if being included in the preparation) separated join in the container and mixed 15 minutes.Allow container cool off then.Premixing acrylate copolymer (" ACULYN  33 ") and spice also join in the described emulsion.When the temperature of mixture reaches 38 ℃, add antiseptic.Then with final preparation cool to room temperature.

Table III

Material	Embodiment 8% (weight)	Embodiment 9% (weight)
			Distilled water	In right amount	In right amount
Ammonium lauryl sulfate	16.80	16.80
			Sodium dihydrogen phosphate	0.30	0.30
Polyquaternium-10	0.25	0.25
			The cocos nucifera oil diglycollic amide	2.00	2.00
Guar gum	0.22	0.22
			VARISOFT TA100	0.25	0.25
Dimethyl silscone	0.00	1.00
			The MQ resin	2.50	2.50
Acrylate copolymer	1.65	1.65
			Spice	0.75	0.75
Methyl chloride Methylisothiazolinone and Methylisothiazolinone	0.07	0.07

Embodiment 10-11 shampoo preparation

In a fitted vessel, except that staying 10% distilled water, distilled water that all the other are all and sodium phosphate mix.Under agitation add ammonium lauryl sulfate.The solution that obtains is heated to 90 ℃.In another container with remaining distilled water and Polyquaternium-10 premixing 1 to 2 minute and joined in the solution remix 15 minutes.In an independent container, cocos nucifera oil diglycollic amide, the pure and mild VARISOFT TA100 fusion of C20-40 are also under agitation joined in the solution.Allow the emulsion that obtains cool off then.Under agitation separately add silicone MQ resin (resin identical) and dimethyl silscone (if in preparation, using) in 60 ℃ of solution with embodiment 1-4.When the temperature of emulsion reaches 38 ℃, add spice and antiseptic.Allow final preparation cool to room temperature then.

Table IV

Material	Embodiment 10% (weight)	Embodiment 11% (weight)
			Distilled water	In right amount	In right amount
Ammonium lauryl sulfate	16.80	?16.80
			Sodium phosphate	0.30	?0.30
Polyquaternium-10	0.25	?0.25
			The cocos nucifera oil diglycollic amide	2.00	?2.00
C20-40 alcohol	2.00	?2.00
			VARISOFT TA100	0.25	?0.25
Dimethyl silscone	0.00	?1.00
			The MQ resin	2.50	?2.50
Spice	0.75	?0.75
			Methyl chloride Methylisothiazolinone and Methylisothiazolinone	0.07	?0.07

Embodiment 12-13 shampoo preparation

In a fitted vessel, except that the distilled water that stays 10% weight, distilled water and sodium dihydrogen phosphate that all the other are all under agitation mix.Stir and add ammonium lauryl sulfate down.The solution that obtains is heated to 60 ℃.In a small container, remaining 10% (weight) distilled water and Polyquaternium-10 are mixed.Joined on the described solution remix 15 minutes adding the content of pining for small container then.In an independent container, cocos nucifera oil diglycollic amide, guar gum and VARISOFT TA100 are mixed and fusion.In case fusion just under agitation joins this mixture in 60 ℃ of aqueous solutions.Separately silicone MQ resin (resin identical with embodiment 1-4) and dimethyl silscone (if being included in the preparation) are under agitation joined in the emulsion.In an independent container with (TAB-2) fusion of distearyl phthalic acid amide and join in the mixture that is cooled to 55 ℃.Then the mixture that obtains is cooled to 38 ℃ and under this temperature, add spice and antiseptic.With final preparation cool to room temperature.

Table V

Material	Embodiment 12% (weight)	Embodiment 13% (weight)
			Distilled water	In right amount	In right amount
Ammonium lauryl sulfate	16.80	16.80
			Sodium phosphate	0.30	0.30
Polyquaternium-10	0.25	0.25
			The cocos nucifera oil diglycollic amide	2.00	2.00
Guar gum	0.22	0.22
			VARISOFT TA100	0.25	0.25
Dimethyl silscone	0.00	1.00
			The MQ resin	1.00	1.00
Spice	0.75	0.75
			Methyl chloride Methylisothiazolinone and Methylisothiazolinone	0.07	0.07
Distearyl phthalic acid amide	2.00	2.00

Embodiment 14-15 shampoo preparation

In a fitted vessel, except that staying 10% (weight) distilled water, distilled water that all the other are all and acrylate acrylic acid C10-30 alkyl ester cross-linked polymer (PEMULEN ^TMTR-1) under agitation mix.Stir adding ammonium lauryl sulfate down, then add sodium phosphate.In a small container, remaining 10% (weight) distilled water and Polyquaternium-10 are mixed.Then the content of small container was joined in the described solution remix 15 minutes.In an independent container, also slowly join in the described solution cocos nucifera oil diglycollic amide, guar gum, spice and VARISOFT TA100 mixing and fully stirring.Separately silicone MQ resin (resin identical with embodiment 1-4) and dimethyl silscone (if being included in the preparation) are joined in the emulsion under continuous stirring.Add antiseptic then and obtain final preparation.(noticing that whole this embodiment uses basically and the same way as heating described in the embodiment 12-13).With final preparation cool to room temperature.

Table VI

Material	Embodiment 14% (weight)	Embodiment 15% (weight)
			Distilled water	In right amount	In right amount
Ammonium lauryl sulfate	55.00	55.00
			Sodium phosphate	0.30	0.30
Polyquaternium-10	0.20	0.20
			The cocos nucifera oil diglycollic amide	2.00	2.00
Guar gum	0.15	0.15
			VARISOFT TA100	0.25	0.25
Dimethyl silscone	0.00	0.75
			Silicone MQ resin	2.25	2.25
Spice	0.75	0.75
			Methyl chloride Methylisothiazolinone and Methylisothiazolinone	0.07	0.07
Acrylate acrylic acid C10-30 alkyl ester cross-linked polymer	0.30	0.30

Embodiment 16 sprays

Prepare spray with following ingredients: 0.17% dimethyl silscone polyol; 0.2% cyclomethicone (pentamer); 0.001% ethylhexyl salicylate; 0.001% benzophenone-3; 0.001% hydrolyzed animal keratin; 0.35% spice; 1.0%MQ resin (with the used resin same type of embodiment 1-4) and an amount of ethanol (for example 95%).The pure and mild trimethylsiloxy esters of silicon acis of SD is mixed in a fitted vessel.Dimethyl silscone polyol, cyclomethicone, ethylhexyl salicylate, benzophenone-3, hydrolyzed animal keratin and spice joined in the described solution and the mixture that obtains placed bottle with atomizing pump.

Performance evaluation

Volume increase and bond properties and aesthetic property are carried out performance evaluation.The following examples are described these evaluations.

The contrast conditioner that is used for the anthropometric dummy test: embodiment A

Use following ingredients to prepare control sample: first: 4.50% hexadecanol; 2.50% octadecanol; 2.40% glyceryl monostearate; 1.00% cyclomethicone; The mixture of 0.50% Polysorbate 80, acetic acid cetyl and Acetylated lanolin alcohols. (available from AmercholCorporation, Danbury, the SOLULAN 98 of CT); 1.50% mineral oil; 2.50% white vaseline; 0.50% propylene glycol; Second portion: appropriate amount of deionized water, 4.00% Dodecyl trimethyl ammonium chloride (available from Akzo, Chicago, the ARQUD  12-50 of IL) in aqueous isopropanol; Third part: 0.50% diazolidinylurea; 0.75% spice.Stir down and mix the material of all firsts and be heated to 80 ℃.In an independent container, under agitation mix the material of all second portions and be heated to 80 ℃.When two parts are 80 ℃, the mixture of first are under agitation joined in the second portion mixture and stirred 10 minutes down and be cooled to 40 ℃ then at 80 ℃.When the mixture that merges during at 40 ℃, the composition that adds third part also mixes whole mixture to evenly.With the mixture cool to room temperature that obtains.

The anthropometric dummy stereometry

It is sure needs that the more approaching reliable test of result in use and the actual life on the hair of user comes evaluation volume.The anthropometric dummy cubage measuring method has satisfied this needs.

The volume of hair goes up the volume of the total combination of hair fiber with head but not the volume of single fiber is relevant.According to the hair style and the length of hair, the contact of the single fiber of hair also helps to support other fiber, keeps the structure of hair as a whole therefrom.For example, the fine weight of itself or the weight of other hair of not supporting so.As a result, whole hair combination lies low on head and therefore occupies less volume.With regard to getting in touch of the structure of hair volume and as a whole hair, go up any hair volume test that the volume of hair carries out and must use its configuration and actual the last pattern of the combination of the similar hair fiber of configuration of hair in order to predict actual head.The existing method of great majority is not used this standard, because its many dependence ultimate fibres, the combination of revocable fiber or the cubing of pigtail.Because all fibres all at one end is fixed together rather than is fixed on thousands of the some place that spreads all on the hair separately in pigtail, hair fiber in pigtail can not regard as actual hair and be full of spatial structure, and each hair supports mutually and produces volume.Therefore can not expect to indicate truly the change in volume of actual hair to the cubing of pigtail.

British patent 2,297,757 have described a kind of Robbins and Crawford method of improvement, wherein provide data in order to analyze to the measurement of pigtail.Be not full of fiber combinations or hair style on the hair because the hair fiber in the pigtail has actual chance to form the space, can not look to this method acquisition result relevant to the situation of actual hair with consumer.

With regard to the work that laboratory is done compositions of the present invention, on the anthropometric dummy head, carried out cubing, spread all over point on the whole head of anthropometric dummy with many fixing actual hairs.Therefore can suppose this hair with on the number of people, form to be full of spatial structure type identical.Comprise in the test of the half a head (half-head) of beauty parlor and dependent field the women is tested, confirm that the test of anthropometric dummy volume can predict very well that the actual volume on consumer's head changes.

The variation that the test of anthropometric dummy volume utilizes traditional beauty parlor's half a head method of testing and image analysis technology to come quantitative volume.In this test, the hair portion of correct every side is carried out cubing to eliminate the deviation that may cause owing to the inequality that two hair division headers are sent out before processing.The enemy handles and is dry then.All preparations of the present invention serve as that contrast is tested with light conditioner all.The volume that the friction damage that needs use conditioner prescription to eliminate appearance in the time of may modifying in contrast on the anthropometric dummy head is brought increases.The entanglement of hair surface or roughening are the extensive acceptable methods that increases hair volume.The technology of combing hair has been used and has been made recent decades hair volume that big increase is arranged.Noted among the result below and contrasted the volume that conditioner does not influence hair negatively.All change in volume that record from control treatment all are positive, show that the volume after the processing will never be lower than the preceding volume of processing.(volume before noting handling is the volume of clean hair).

In order to prove that conditioner tester (embodiment A) does not reduce volume, carried out a series of experiments and proved conclusively light conditioner purposes in contrast.For described conditioner, tested do not have the MQ resin according to the compositions of embodiment 1 preparation situation with respect to the light conditioner for preparing in the embodiment A.Its result does not have significant difference (4.8% difference and 0.27 p value).For shampoo, used same logic; Will be according to the compositions of embodiment A preparation with respect to according to embodiment 8 preparations but there is not the preparation of MQ resin to test.The measurement volumes that two kinds of preparations provide does not have significant difference (3% difference, the p value equals 0.73), confirms the reduction of conditioner contrast not causing hair volume.

Used anthropometric dummy head is available from Pivot Point International in the volume experiment, Chicago, " Sarah " head of Illinois.Before experiment is handled, the anthropometric dummy head is cleaned with the detergent solution that contains 20%SLES 2EO, 5% cocamido propyl betaine and 0.8% cumene sodium sulfonate.Tangle for reducing, bring detergent into hair with ventilation brush (vent brush).With the circulating water rinsing head of 38 ℃ (100) up to the washings clean transparent.With an anthropometric dummy washed twice, use the 5ml detergent solution at every turn, then use 2.5ml solution.After the washing, anthropometric dummy hair comb is logical and comb is straight then with brush.Dry dry the spending the night of discount then.Thereby must combing getting to put down as far as possible through the hair of the anthropometric dummy of washing makes the intrinsic volume that at this moment records be subjected to the minimum that influences of hair style.In the volume experiment, the both sides of separate processes anthropometric dummy head.Every side at first uses the water of 38 ℃ (100) moistening, handles with 3ml control formulation or fluffy preparation then.Alternately use a side of fluffy preparation on each new measuring head.After the administered formulation, test formulation is rubbed into 30 seconds of hair, the water rinse of using 38 ℃ (100) then is up to the washings clean transparent and continued for 60 seconds at least.Surpass once experiment for the process of using fluffy preparation and rinsing, all apply process and all carry out rather than hocket in the both sides of head in a side continuously.For the conditioner that contains the MQ resin (embodiment 1-5), carry out cubing after using once.For the shampoo that contains the MQ resin (embodiment 7-15), shampoo is washed 3 times before carrying out cubing.For embodiment 6, only carry out once washing.Use is connected with the performance that the Zeiss Kontron image analyzer of Sony XC-77CE miniature camera (tool 60mm Nikon AFMicro-Nikkor camera lens) measures on the anthropometric dummy head and changes.The anthropometric dummy image by video camera take in, digitized and use for this reason and written program is measured the area of every side.By measuring anthropometric dummy head, the human body model head after the cleaning and remeasuring the apparent variation of evaluation volume.The stereomutation percentage ratio of every side uses following formula to calculate:

Change in volume (V _{One side})=100 * [V _{One side}(back)-V _{One side}(preceding)]/V _{One side}V in (preceding) formula _{One side}The apparent volume that records for the concrete side of head, and preceding and after be meant handle before and after the value that records.The change in volume of concrete single treatment is by formula Δ V=Δ V _Handle-Δ V _ContrastRepresent.In measuring once the concrete change in volume of handling, each experiment is measured on 5 statures at least.Use paired t-check (Paired t test) to estimate the data of contrast and processing side then.The result also can comprise acceptable " p " value in the statistics practice; P value greater than 0.05 shows that these data are not significant statistically on 95% confidence level.

Obtain volume data from the described preparation of embodiment 1-15.Described data are listed in Table VII.What note described data reflection is the meansigma methods of at least 5 evaluations.

Table VII

Embodiment	The % volume increases	The p-value
			1	?24.4	?0.039
2	?21.9	?0.032
			3	?-	?-
4	?20.7	?0.008
			5	?26.1	?0.014
6	?37.3	?0.058
			7	?21.8	?0.025
8	?20.0	?0.044
			9	?20.7	?0.003
10	?16.7	?0.045
			11	?-	?-
12	?20.1	?0.017
			13	?-	?-
14	?29.2	?0.007
			15	?21.1	?0.020

The volume increase of reporting in Table VII almost is significant (p＜0.05) on the statistics entirely.The amplitude 16.6%-37.3% that volume increases shows that compositions of the present invention is very effective aspect the increase significantly making hair volume.

Viewed from MQ resin, MQ-A with the conditioner that is not the evidence that increases from the volume of carrier by comparing embodiment 1 and do not have the experimental result of anthropometric dummy volume test of the same preparation of MQ resin to provide.Relatively conditioner deducts MQ and handles side, observes with containing a side that the MQ preparation handles to have 25% volume and increase, and confirms that volume is from resin but not carrier.

The human test

The further supporting evidence of the fluffy effectiveness of preparation of the present invention can provide by the human body experimenter.In independent test, provide the test specimen of the fluffy shampoo of the fluffy conditioner of embodiment 1 or embodiment 9 to female subjects.The indication experimenter used sample product 5 days under the situation of conditioner, used 10 days under the situation of shampoo.

The experimenter notes and the evaluation of the correlated test products of its normal hair volume to the hair volume effect.Estimate and use 1 to 5 classification, 1 expression is few volume significantly, the volume that 5 expressions are significantly many.Collect data and use then as at Practical Nonparametric Statistics, 2nded, W.J.Conover, John Wiley and Sons, the Wilcoxon SignedRank Test described in 1980 analyzes.The result shows that conditioner and shampoo test products all provide significantly the increasing of hair volume (95% confidence level).

Curling persistency

The European hair (every tuft 3.5g) of each experiment Processing of Preparation three tufts cleaning.Before processing, measure the length (L that do not curl of every tuft hair _u).Then that the hair water is moistening, the clear hair of combing is extruded excessive water with the thumb and the forefinger of glove hands then.Then, hair is hung up and fixed and allow its drying 16 hours at least with the plastic clip that standard 2.22cm (7/8 inch) plastics curler curls, provides with curler from the root of hair end.After the drying, the plastics curler is taken off from hair carefully, handle with the 2.5% test MQ resin solution that is dissolved in toluene then.Use this solvent to be because itself and the MQ resin formation solution of surveying.Use Seaquist P 22/290 pump of each about 0.25g of driving that test solution is sprayed on the hair.In order to ensure evenly applying, locating the hair of spraying from hair 15cm (6 inches).Every tuft hair is sprayed four times in front, sprays in the back four times, obtains the applied amount of 2 gram solution altogether.The hair of will newly spraying places on the coil holder and allows its dry 1 hour.Then, they are hung in the moist chamber of 21 ℃ and 80% relative humidity.In 0,0.25,0.5,1,2,3,4 and 24 hour record length measurment values.Use following formula to calculate the curling persistency of each reading:

Persistency (%)=[L curls _u-L (t)]/[L _u-L (0)]

L in the formula _uBe the length of hair crimping not, L (t) is in t hair lengths constantly, and L (0) is 0 length of hair constantly.Its data are listed in Table VIII.Tabular value is " percentage curl persistency ".All used MQ resins are available from General Electric Company.

Table VIII

The MQ resin	15 minutes	1 hour	4 hours	24 hours
					The cyclomethicone solution (MQ-B) of 50% solid trimethylsiloxy silicate a，d	43.3 *	39.8 *	35.0 *	?34.1 *
Trimethylsiloxy silicate (MQ-A) a	2.2	-6.1	-5.5	?-5.1
					Myristyl dimethyl silane oxygen base silicate (MQ-D) a，b	2.4	2.5	3.6	?4.1
Octadecyl dimethyl silane oxygen base silicate (MQ-E) a，b	24.3 *	3.0	3.4	?4.5
					(C16-18) alkyl dimethyl siloxysilicates (MQ-G) a, b, e	11.6	8.3	4.3	?4.2
C20-24 dimetylsilyl silicate (MQ-F) a，b	9.7	2.1	2.0	?3.1
					Poly-(oxygen ethylene) dimethyl silane oxygen base silicate (MQ-H) a，c，e	15.9 *	16.3 *	9.7	?7.8

A=is available from General Electric Company

Each M unit of b=polymer replaces with chain alkyl

Each M unit of c=polymer replaces with the polyoxyethylene group of each group 12-13 oxygen ethylene unit

D=is available from the commodity of General Electric

E=is described in United States Patent (USP) 5,684, in 112

All curling persistency values have deducted the toluene control value.Significant tabular value is all used the asterisk labelling on the statistics.

In the MQ resin of in Table VIII, listing, after reaching 24 hours fully, experiment have only " MQ-B " to show the significant persistency of curling.This shows that this resin has significant bond properties.Therefore, the increase of the volume of listed this resin can be worked among the mechanism of ammonium fixation his-and-hers watches IX.

On the other hand, liquid MQ " MQ-A " does not show the significant persistency of curling, and does not therefore have significant bond properties.Although the shortage cohesive still obviously provides big volume from the visible liquid MQ of the embodiment of Table VII.

Sum up embodiment

By summing up embodiment, Table I X has listed the cubing value that obtains on the resin of MQ described in the Table VIII, and wherein every kind of MQ resin is formulated in the conditioner preparation of the hair washing preparation of embodiment 8 and embodiment 1 or among both.The level of the MQ resin that adds in these preparations is 2.5% active substance.

In Table I X, be marked with data in " deposition " hurdle actual be relative deposition value and at the Pilus Caprae seu Ovis sample (7cm * 11cm) goes up and obtains, and described Pilus Caprae seu Ovis sample is moistening in 38 ℃ of mobile tap waters, with 1ml test products (contain the shampoo of test MQ resin or contain the conditioner of test MQ resin) processing and rinsing 1 minute under 38 ℃ of mobile tap waters.The ESCA (being used for chemico-analytic electronic spectrum) that uses those skilled in the art to be familiar with then measures the MQ pitch deposition.ESCA is used for quantitatively and the elemental constituent of the qualitative determination surface of solids.The surface of institute's test products is a Pilus Caprae seu Ovis.Pilus Caprae seu Ovis is through being commonly used for the substitute of Crinis Carbonisatus, because all be similar to Crinis Carbonisatus on its chemistry and the form, also because to compare woolen measurement much easier with Crinis Carbonisatus.Such just as those skilled in the familiar, ESCA uses photoelectric effect to obtain the data of relevant chemistry of solid surfaces component.Sample surfaces is by X-ray photons irradiation, the atomic interaction of described photon and material surface.If photon has enough energy, electronics is from the track emission of surface atom.The photoelectronic kinetic energy of these emissions is measured by electron spectrometer.The relational expression of describing this process is BE=X-ray energy-KE, and wherein KE and BE are respectively the binding energy of photoelectronic measurement kinetic energy of emission and calculating.Electron binding energy be element and emission electron the electronics subgrade feature and be used to identify the different elements of the surface of solids.The characteristic peak of MQ resin at first uses pure material to measure.The peak area that occurs on sample is used to measure the relative concentration of element at sample surfaces.For the MQ pitch deposition, the Si peak demonstrates unique shape, and it helps to distinguish MQ resin and other silicone such as the poly dimethyl silicone.Area under the silicon peak can calculate the silicon percent of existence.For each institute's test sample product, prepare 3 and repeat the Pilus Caprae seu Ovis sample.In three samples, 2 is initial the analysis.If in 2 times are measured, big difference is arranged, confirms with regard to the test of carrying out the 3rd sample.This method is carried out with embodiment listed among the Table I X.Value in the deposition hurdle is by calculating the deposition measured value of concrete MQ resin on the Pilus Caprae seu Ovis sample divided by the deposition of trimethylsiloxy silicate resin (MQ-A) on Pilus Caprae seu Ovis.Therefore these values are various resins relative depositions with respect to the MQ-A resin.

Table I X

Explanation	Form	M: Q ratio	Viscosity	Result's (change in volume)	P-value (change in volume)	Deposition
							Trimethylsiloxy silicate (MQ-A)	Liquid	1∶1	?4500-12000 ?cP	Shampoo+20% conditioner+24.4%	?0.044 ?0.039	?1 ?1
The cyclomethicone solution (MQ-B) of 50% solid trimethylsiloxy silicate	Be dissolved in the solid of cyclomethicone	0.7∶1	Solid	Shampoo+31.1% conditioner+21.4%	?0.002 ?0.066	?0.80 ?0.70
							Myristyl dimethyl silane oxygen base silicate (MQ-D)	Liquid	2∶1	?50cP	Shampoo-2.8%	?0.52	?1.57
Octadecyl dimethyl silane oxygen base silicate (MQ-E)	Solid (wax shape)	2∶1	Solid	Shampoo+2.1% conditioner+8%	?0.67 ?0.37	?1.71 ?0.68
							(C20-C24) alkyl dimethyl siloxysilicates (MQ-F)	Solid (wax shape)	2∶1	Solid	Shampoo+6.4% conditioner-8.9%	?0.30 ?0.57	?2.40 ?1.32
(C16-C18) alkyl dimethyl siloxysilicates (MQ-G)	Liquid	2∶1	?50cP	Shampoo+4.3%	?0.33	?2.15
							Poly-(oxygen ethylene) dimethyl silane oxygen base silicate (MQ-H)	Liquid	2∶1	?340cP	Conditioner-12.7%	?0.22	?0.50

Attention is called " MQ-A " in Table I X resin has not had to provide under the tangible bond property volume that increases.Compare with this performance, do not observe any M: the Q ratio provides big volume for 2 MQ resin; Although a great deal of (relative value) is arranged these resins or greater than the amount of the preferred trimethylsiloxy silicate (MQ-A) of not observing obvious bond properties deposition, they do not have or do not have fully bond properties (Table VIII) substantially and volume is not provided.The MQ-B resin provides tangible volume, but shows bond properties (not resembling the MQ-A resin).Because the MQ-B resin has bond properties, so prediction MQ-B resin will be subjected to and the conventional the same defect influence of fixed polymer.

Embodiment 16 and 17

Use following ingredients to prepare embodiment 16 and 17 samples: 16.80% ammonium lauryl sulfate; 0.30% sodium dihydrogen phosphate; 0.25%Polyquaternium-10; 2.00% cocos nucifera oil diglycollic amide; 0.22% guar gum; 0.25% VARISOFT TA100; 0.50% distearyl phthalic acid amide; 1.76% cumene sodium sulfonate; 0.75% spice; 0.07% antiseptic (KATHONCG), and the composition of the listed amount of Table X.Use an amount of distilled water to make total amount reach 100%.Notice that MQ-A is identical with the described MQ-A of front embodiment.

Table X

Composition	Embodiment 16	Embodiment 17
			MQ resin (MQ-A)	?0.75	?0.60
The poly dimethyl silicone	?1.00	?2.00
			ACULYN?22	?0.90	?0.90
ACULYN?33	?0.84	?0.84
			Distilled water	In right amount	In right amount

Except that staying 10% distilled water, will residue all water and sodium phosphate merge, mixed 10 minutes in a container that is fit to and be heated to 50 ℃.ACULYN  22 acrylate materials, ACULYN  33 acrylate copolymers and ammonium lauryl sulfate are joined in the container, use 50% sodium hydroxide that pH is brought up to 7.0 and composition mixed 10 minutes.Add cumene sodium sulfonate and be mixed into even.Use 50% citric acid that pH is reduced to 6.0-6.5 then.With remaining distilled water and Polyquaternium-10 premixing 1-2 minute and join in the container.In an independent container, cocos nucifera oil diglycollic amide, guar gum and VARISOFT TA100 are mixed and under agitation be heated to 50 ℃.Under agitation it is joined in the primary tank.In an independent container under 45-50 ℃ temperature fusion distearyl phthalic acid amide, under agitation join in the described container then.Join silicone MQ resin in the container and mixed 15 minutes.Join the poly dimethyl silicone in the container and mixed 15 minutes.Allow container begin to cool down then.When the temperature of mixture reaches 40 ℃, add spice.After continuing cooling, under the temperature below 38 ℃, add antiseptic.With final preparation cool to room temperature.

Claims (28)

1, a kind of fluffy Haircare composition of hair that makes comprises the MQ resin of the formula IA of effective dose:

Formula IA

In the formula:

M ¹And M ²Respectively be independently selected from

(a) hydrogen,

(b) phenyl,

(c) phenethyl,

(d) polyethers of Formula Il:

-H ₂C-(CH ₂) _n-(O-CH (R ¹⁰)-CH ₂) _u-(OCH ₂-CH ₂) _v-OR ¹¹N is the number of 1-20 in the formula II formula ,-(CH ₂)-chain can be chosen wantonly and comprise 1 or 2 degree of unsaturation; U and v respectively are independently selected from the integer of 0-20, and condition is u+v 〉=1; R ⁴, R ⁵, R ⁶And R ⁷Respectively be independently selected from phenyl and C _1-12Branch and unbranched hydrocarbon; R ¹⁰Be selected from C ₁-C ₂₀Alkyl; R ¹¹Be selected from H ,-CH ₃With-C (O) CH ₃With

(e) C that is replaced by halogen ₁-C ₃The optional C that replaces of alkyl ₁-C ₂₄Branch or unbranched hydrocarbon; With

(x+y)/z is the number of 0.5 to 1.5 scope in the formula; And R ⁴, R ⁵, R ⁶, R ⁷, x, y, z, M ¹And M ²Value be selected from and make described MQ resin for having 1.0 * 10 ³To 1 * 10 ⁶The value of the liquid of the viscosity of centipoise.

2, according to the compositions of claim 1, wherein said compositions is a kind of water base shampoo.

3, according to the compositions of claim 1, wherein said compositions is water base conditioner.

4, according to the compositions of claim 1, wherein said compositions is a kind of spray.

5, according to the compositions of claim 1, wherein said compositions is a kind of hair dye.

6, according to the compositions of claim 1, comprise

(a) based on the MQ resin of the formula IA of described composition total weight 0.01-15% weight; With

(b) based on the hair care carrier that is selected from shampoo, conditioner, spray and hair dye of described composition total weight 85-99.99% weight.

7, according to the compositions of claim 1, the viscosity of wherein said MQ resin is 1.5 * 10 ³To 1 * 10 ⁶The scope of centipoise.

8, according to the compositions of claim 1, the viscosity of wherein said MQ resin is at 1000-100, the scope of 000 centipoise.

9, according to the compositions of claim 1, the viscosity of wherein said MQ resin is 1,000-50, the scope of 000 centipoise.

10, according to the compositions of claim 1, wherein said MQ resin has formula IB:

Formula IB

R in the formula ²Be selected from and M ¹Identical group; R ¹And R ³Respectively be independently selected from and R ⁴Defined identical group; X '/z ' is 0.5 to 1.5 a number.

11, according to the compositions of claim 1, M wherein ¹And M ²Respectively be independently selected from C ₁-C ₂₄Branch and unbranched alkyl.

12, according to the compositions of claim 11, M wherein ¹, M ², R ⁴, R ⁵, R ⁶And R ⁷It respectively is methyl.

13, according to the compositions of claim 10, R wherein ²Be selected from C ₁-C ₂₄Branch and unbranched alkyl.

14, according to the compositions of claim 13, R wherein ¹, R ²And R ³It respectively is methyl.

15, according to the compositions of claim 1, (x+y)/z=1 wherein.

16, according to the compositions of claim 10, x '/z '=1 wherein.

17, according to the compositions of claim 14, x '/z '=1 wherein.

18, according to the compositions of claim 1, also comprise fixative.

19,, comprise the MQ resin of 0.1-7.5% according to the compositions of claim 2.

20,, comprise the MQ resin of 0.1-5.0% according to the compositions of claim 19.

21,, comprise the MQ resin of 0.1-3.0% according to the compositions of claim 19.

22,, comprise the MQ resin of 0.2-2.5% according to the compositions of claim 19.

23,, also comprise the conditioner of 0.1-2.0% according to the compositions of claim 18.

24, according to the compositions of claim 2, also comprise the detersive surfactant of 4.00-60.00%, be selected from C ₈-C ₁₈Alkyl sulfate, in molecule, contain the C of 1-5 oxyethylene group ₈-C ₁₈Alkyl oxyethylene group ether sulfate, C ₁₀-C ₁₈Acyl isethinate, C ₁₀-C ₂₀Alkylsulfonate, C ₁₀-C ₂₀At least a anionic detergent of olefin sulfonate or its mixture; Or at least a:

(i) C of the water-soluble growth regulator of 0.10-5.00% anion ₁-C ₃Alkylbenzenesulfonate or C ₅-C ₆Alkyl sulfate;

(ii) the 0.10-15.00% amphoteric surfactant is selected from C ₈-C ₁₈Alkyl betaine, C ₈-C ₁₈Alkyl sulfobetaines, C ₈-C ₁₈Alkylamidoalkyl C ₂-C ₃Alkyl betaine, C ₈-C ₁₈Alkylamidoalkyl C ₂-C ₃Alkyl sulfobetaines, C ₈-C ₁₈Alkyl both sexes acetate, C ₈-C ₁₈Alkyl both sexes propionate, cocamidopropyl betaine or its mixture; With

(iii) 0.1-4.0% non-ionic surface active agent,

Condition is 60% weight that the total amount of detersive surfactant is no more than described composition total weight.

25,, also comprise the stabilizing agent of 0.10-5.00% according to the compositions of claim 2.

26,, also comprise matrix material and at least a cationic surfactant according to the compositions of claim 3.

27, according to the compositions of claim 26, wherein said at least a cationic surfactant is selected from the cationic surfactant that contains amino or quaternary ammonium hydrophilic segment.

28, according to the compositions of claim 27, wherein said at least a cationic surfactant is selected from formula (R ¹⁰) (R ¹¹) (R ¹²) (R ¹³) N ^{+ 1}The component of-X, R in the formula ¹⁰For the aliphatic group of hydrogen, a 1-22 carbon atom or have the aromatics aryl or the alkylaryl of 12-22 carbon atom; R ¹¹For having the aliphatic group of 1-22 carbon atom; R ¹²And R ¹³Respectively be independently selected from alkyl with 1-3 carbon atom; X is the anion that is selected from halogen, acetate, phosphate radical, nitrate anion and alkyl sulfate group.