CN1186694C - Printing printmaking method and printing plate thereof - Google Patents
Printing printmaking method and printing plate thereof Download PDFInfo
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- CN1186694C CN1186694C CNB021537003A CN02153700A CN1186694C CN 1186694 C CN1186694 C CN 1186694C CN B021537003 A CNB021537003 A CN B021537003A CN 02153700 A CN02153700 A CN 02153700A CN 1186694 C CN1186694 C CN 1186694C
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/30—Inkjet printing inks
- C09D11/36—Inkjet printing inks based on non-aqueous solvents
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41C—PROCESSES FOR THE MANUFACTURE OR REPRODUCTION OF PRINTING SURFACES
- B41C1/00—Forme preparation
- B41C1/10—Forme preparation for lithographic printing; Master sheets for transferring a lithographic image to the forme
- B41C1/1066—Forme preparation for lithographic printing; Master sheets for transferring a lithographic image to the forme by spraying with powders, by using a nozzle, e.g. an ink jet system, by fusing a previously coated powder, e.g. with a laser
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/101—Inks specially adapted for printing processes involving curing by wave energy or particle radiation, e.g. with UV-curing following the printing
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- Manufacturing & Machinery (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
- Ink Jet Recording Methods And Recording Media Thereof (AREA)
- Manufacture Or Reproduction Of Printing Formes (AREA)
Abstract
The present invention provides a printing plate preparation method and a printing plate obtained by adopting the method. The present invention has the printing plate preparation method that ink composition which carries out polymerization reaction under the illumination condition is adopted, and the ink composition comprises monomers for the polymerization reaction, optical polymerization initiator, coloring agent and organic solvent. Pictures and characters are directly printed on a printing plate material through an ink-jet printer with high precision. Since the light irradiation, ink is solidified quickly on the printing plate material, the ink does not overflow toward periphery, and an image is clear. The printing plate has no halftone dot loss and easy color correction, and the present invention can carry out multicolor overprint.
Description
Technical field
The present invention relates to a kind of method of plate making, particularly a kind of method that adopts inkjet printing to prepare galley, and the galley that adopts this method to obtain.
Technical background
Traditional colored printing method for platemaking mainly may further comprise the steps: (1) at first generates general printed text with printing figure message in computing machine, as PS file or pdf document etc., (2) this document is carried out color separation processing (RIP explanation), with laser photocomposing machine exposure phototypesetting film, make the film of printing usefulness then through development, photographic fixing and washing; (3) adopt manual imposition that this film is pressed on PS version or other photographic plate, use the ultraviolet photoetching printing down, after developing, make the polychrome forme, carrying out obtaining colored print sample after the chromatography of polychrome China ink on traditional proof press; (4) print sample is after client's approval, the printing that step (2) is obtained is taken the printing house with film and is combined into big version by bookbinding folding hand mode again, the version film is pressed on PS version or other photographic plate greatly again, use the ultraviolet photoetching printing down, after developing, make the polychrome printing version, use this polychrome printing version a large amount of printing finished products on printing machine then.From described printing plate-making method, we as can be seen, need through three exposures, develop for three times to making final galley with computer documents from taking printing, operate very complicated, consume great deal of raw materials, as laser photo-typesetting sheet, developer solution, PS version or other photographic plate and paper etc., and produce a large amount of waste water.Also need a large amount of equipment simultaneously, show photographic fixing machine, PS version printer and PS version developing machine etc. as laser photocomposing machine, film, therefore investment is big, cost is high.
Advantages such as in recent years, Computer To Plate (CTP) technology was owing to going out film, and was simple to operate, and speed is fast have obtained development rapidly.This method for platemaking mainly comprises: file or picture that (1) at first will need to print generate general printed text in computing machine, as PS file or pdf document etc.; (2) resulting printed text is carried out color separation processing and routinely printing bookbinding folding tablet held before the breast by officials formula and in computing machine, be combined into big version file; (3) the version file goes out specimen page by the high precision printing of inkjet printer greatly; (4), normally will print the file of specimen page and make the galley of the printing that is available on the machine, as aluminium base edition etc. by direct platemaking machine through after the client approval.But still there are following two big defectives at present: the one, because existing ink for ink-jet printer is water miscible basically, when print paper adopts art paper or other ganoid paper, printing is easy to generate spillover, print image is unintelligible, effect is bad, can only be printed on the special printer paper or imitation art paper, therefore produce printing specimen page paper and the inconsistent problem of printing sheets, cause printed sample and print product there are differences; The 2nd, owing to print specimen page by the high precision printing of inkjet printer, and the galley that is used to print is made by direct platemaking machine, the site of two kinds of machine generations is discrepant.Above-mentioned two defectives must be brought the difficulty of color correction, make to produce contradiction and dispute between printing enterprise and the client, bring unnecessary trouble and loss to enterprise.Simultaneously, when directly platemaking machine generates the galley of the printing that is available on the machine, need to develop, produce sewage.
Chinese patent CN1145152A discloses a kind of Computer To Plate method, it is to adopt to spray lipophilic resin on hydrophilic metal plate surface with ink-jetting style, the employed marking ink of this method is different with common ink, be that macromolecule resin is dissolved in the volatile organic solvent, print volatilization that the back relies on solvent with the macromolecule resin drying and forming-film on metallograph, but repetition test according to the inventor, serious ink latch up phenomenon appears in this method for platemaking on the high precision ink-jet printer, and it is when being printed on the smooth aluminium plate, not fogging clear.
Summary of the invention
The objective of the invention is in order to overcome the defective that above-mentioned prior art exists, a kind of preparation method of galley is provided, this method adopts the composition for ink that can carry out photopolymerization reaction under illumination, directly be printed on picture and text on the printing plate by the high precision ink-jet printer, because the irradiation of light, ink is solidificated on the printing plate fast, and ink does not overflow to periphery, clear picture.
The present invention also provides the galley that adopts above-mentioned method for platemaking to obtain.
Another object of the present invention provides a kind of composition for ink that is used for inkjet printing, and adopts this composition for ink to obtain print sample or photograph by the high precision ink-jet printer.
A kind of method for preparing galley, this method are that the printed text that computing machine generates is passed through ink-jet printer, directly are printed on the printing plate;
Wherein the ink of ink-jet printer use is for carrying out the composition of photopolymerization reaction under illumination, and it contains following component and parts by weight:
(1) be used for the monomer of photopolymerization reaction: 20-80 is preferably 50-70;
(2) Photoepolymerizationinitiater initiater: 2-20 is preferably 5-15;
(3) colorant: 2-10 is preferably 5-8;
(4) organic solvent: 10-70 is preferably 20-30;
Mostly existing ink commonly used is aqueous ink, and it mainly is fixed on by infiltration, absorption and volatile dry and prints substrate surface, because galley mostly is sheet metal, absorbability is relatively poor, is difficult to form distinct image on its surface.What existing water-insoluble ink (solvent-based inks) mainly used is organic solvent, quick volatilization by solvent is fixed on substrate surface, though this ink can be printed on not sorbent surface such as metal, glass or plastics, but owing to contain a certain amount of polymer (resin) in the ink, in the high precision ink-jet printer, be easy to stop up ink gun, and when printing on smooth metallograph, image is also unintelligible.
In method for platemaking of the present invention, since adopt ink-jet printer directly with image print on non-absorbent sheet metal, in order to obtain distinct image, the inventor has developed a kind of above-mentioned composition for ink, and it is a kind of at the light-initiated response type ink that can produce polyreaction down.But ink loses not polymerization of long preservation in the print cartridge of light in sealing, and when ink printed during on the stock surface, under the effect of illumination, the quick polymerization reaction take place of trigger monomer generates crosslinked high molecular polymer.Because crosslinked high molecular polymer has very strong adhesive, makes marking ink be solidificated in the stock surface fast, marking ink does not overflow to periphery, and print image is clear.
The monomeric compound that is used for photopolymerization reaction described in the composition for ink of the present invention, be typically chosen in infrared light, visible light and ultraviolet light can carry out the compound of light initiating polymerizing reaction down, wherein preferably can under ultraviolet light, carry out the compound of light initiating polymerizing reaction, acrylic ester compound for example, specifically can be selected from trimethylolpropane triacrylate, ethoxylated trimethylolpropane triacrylate, pentaerythritol triacrylate, the polyethers trimethylolpropane triacrylate, neopentylglycol diacrylate, ethoxylated neopentylglycol diacrylate, tripropylene glycol diacrylate, propylene glycol diacrylate, 1, the 4-butanediol diacrylate, polyglycol (200) diacrylate, polyglycol (400) diacrylate, diethylene glycol diacrylate, triethylene glycol diacrylate, PDDA, the EA epoxy acrylate, 1, the 6-hexanediyl ester, the propoxylated glycerol triacrylate, the phthalic acid tripropylene glycol diacrylate, in ethoxylated bisphenol a diacrylate and the glytidyl methacrylate one or more, wherein preferred trimethylolpropane triacrylate, ethoxylated trimethylolpropane triacrylate, pentaerythritol triacrylate, the polyethers trimethylolpropane triacrylate.
Photoepolymerizationinitiater initiater described in the composition for ink of the present invention can be selected styrax and alkyl ether thereof, the benzoate class, acetophenones, phenol, peroxide, the thioxanthones compounds, preferred styrax and alkyl ether thereof, acetophenones, concrete as: styrax, benzoin methyl ether, the Alpha-Methyl styrax, α-phenyl styrax, benzoin ethyl ether, benzoin isobutyl ether, benzoin isobutyl ether, benzophenone, dibenzoyl, Michler's keton, to the phenyl benzophenone, halo acetophenone, Alpha-hydroxy-Alpha-Methyl propiophenone, 2-hydroxyl-[4-(2-hydroxyl-oxethyl) phenyl]-2-methyl acetone, 2-methyl isophthalic acid-(4-methyl mercapto phenyl)-2-morpholine-1-acetone, 1-hydroxy-cyclohexyl phenyl ketone.
Colorant described in the composition for ink of the present invention can adopt solvent dye or oil-soluble dyes conventional in the prior art, because pigment generally is scattered in the solvent with particulate forms, dyestuff then is dissolved in the solvent with molecular forms, therefore dyestuff can molecular conformation form stable homogeneous phase with solvent, and image resolution ratio height, the sharpness of this ink formation are good.Therefore, colorant of the present invention preferably adopts solvent dye or oil-soluble dyes, comprising: oil-soluble Huang, pure molten everbright fast yellow CGG, pure molten everbright fast yellow CGR, Spirit Fast Yellow GR, sun-proof fluorescein D, oil red G, red, the pure molten everbright fast red CG of Oil Violet, alcohol molten scarlet LG, the red as fire B of pure molten sun-proof, pure molten sun-proof fluorescein GG, solvent blue B, oily molten ethereal blue, spirit blue, pure molten sun-proof blue HL, solvent blue RS, the green HL of pure molten sun-proof, nigrosine, nigrosine, solvent black 827 and solvent black 834 etc.
Solvent described in the composition for ink of the present invention generally select for use with composition for ink in other components ethers, alcohols, ketone, ester class or the amides compound that do not react, concrete as: ethanol, propyl alcohol, butanols, isopropyl alcohol, amylalcohol, hexanol, octanol, ethylene glycol monomethyl ether, ethylene glycol monobutyl ether, cyclohexanone, dimethyl formamide, diglycol butanone, MEK, butyrolactone, valerolactone etc.Wherein preferred boiling point is 75-200 ℃ a compound.If boiling point is too high, it is slower to volatilize, and influences print quality; If boiling point is low excessively, it is too fast to volatilize, and stops up print nozzles easily.
In method for platemaking of the present invention, the raw material of the described plate of undertaking the printing of can use metal, plastics, paper and their compound, preferred metal materials wherein, for example: aluminium, magnesium, iron, zinc, chromium, nickel or their alloy.Preferably especially adopt low-cost aluminium plate, normally will aluminium plate through form the alundum (Al film of the about 2-3 micron thickness of one deck after the anodic oxidation on its surface, this layer film has good hydrophilicity.
In order to prolong the holding time and to improve water wettability, also can carry a hydrophilic layer on the above-mentioned printed substrate, described hydrophilic layer comprises the potpourri of hydrophilic high molecular polymer and non-ionic surfactant, the weight ratio of described hydrophilic high molecular polymer and non-ionic surfactant is 1: 4-20, preferred 1: 8-10.Wherein hydrophilic high molecular polymer can synthesize, and also can be natural, is selected from polyvinyl alcohol (PVA) and derivant thereof, carboxymethyl cellulose, polyvinyl acetate emulsion, gum arabic or the gelatin one or more.Wherein non-ionic surfactant is selected from the potpourri (OP series) of polyoxy alkene fatty alcohol ether (peregal series), AEO and APES etc.
Preferably, method for platemaking of the present invention can may further comprise the steps:
(1) file or the picture that will need to print generates general printed text in computing machine, as PS file or pdf document etc.;
(2) resulting printed text is carried out color separation processing in computing machine, generally be divided into four looks, can be divided into polychrome, and printing bookbinding format is routinely pieced together the big version of system if any specific (special) requirements;
(3) adopt publication grade, as art paper, the version file goes out specimen page by the high precision printing of inkjet printer greatly;
(4) through after the client approval, by ink-jet printer, directly will big edition file printout on printing plate.
Adopt method for platemaking of the present invention, can be with ink printed on smooth stock surface, on art paper, the paper and the printing sheets that can guarantee to print specimen page like this are in full accord, color correction is easy, avoided the difference between specimen page and the final printed matter, reduced producing contradiction and dispute between printing enterprise and the client.In addition, in method for platemaking of the present invention, directly incite somebody to action the file printout of big version on printing plate by ink-jet printer, the site that is printed on like this on the galley (as aluminium plate) is in full accord with the site that is printed on the printing, also solved the ink-jet printer and direct platemaking machine or ink-jet printer and the laser photo-typesetting film-discharging machine that exist in the prior art, the problem of difference appears in the site of two kinds of machine generations.
Method for platemaking technology of the present invention is simple, easy to operate, and equipment investment simultaneously is few, only needs a high-precision printer, does not need to show the photographic fixing machine, does not have any sewage and produces, and is fit to very much suitability for industrialized production and popularization.
The present invention also provides the galley that adopts above-mentioned method for platemaking to obtain, this galley can be printed on multicolour press, because the high molecular polymer that light initiation polymerization produces has lipophilicity, so the picture and text of galley partly have the oleophylic China ink, and blank parts possess hydrophilic property or oleophobic property in advance, so press resistance rate height, can not have printing stock, can generate frequency modulation or amplitude modulation net-point printing, do not lose the site, color correction is simple and easy, can carry out multicolor overprint.
In addition, adopt the composition for ink described in the invention described above method for platemaking, figure message printing just can be generated print sample or black and white and photochrome at printing or on taking a picture with printing paper.Because the high molecular polymer that light initiation polymerization produces has stronger adhesive to paper, makes colorant and paper adhesion very solid, therefore resulting print sample or photo waterproof are sun-proof, but long preservation.
Embodiment
Embodiment given below is for the present invention is described, rather than limits the invention.
Example 1
(1) prescription of composition for ink: trimethylolpropane triacrylate 720g
Benzoin isobutyl ether 84g
Butanols 360g
Above-mentioned three kinds of compound are stirred, to be mixedly be divided into four parts after evenly, every part adds the following dyestuff of 9g, after stirring respectively, after filtering by film (aperture is 0.2um) filtrator, puts into respectively in yellow, red, blue, the tusche box again.Print cartridge is inserted in the respective ink tanks hole of Epson 9600 printers.
The molten everbright fast yellow CGG 9g yellow of alcohol
The molten everbright fast red CG of alcohol
4The 9g redness
The blue HL 9g of the molten sun-proof of alcohol blueness
Solvent black 827 9g black
(2) the galley base material utilizes the aluminium base version before the uncoated photoresists in the production of PS version, just through aluminium base edition behind the anodic oxidation generation water wettability aluminum oxide film.
(3) ultraviolet light generator is installed on Epson 9600 printers, is allowed ultraviolet light along with printer port of printer moves, when stamping ink one printed on the base material, ultraviolet light just can shine at once.The chromatography clothes-hook will be loaded onto on 9600 printers.
(4) Zhi Ban concrete steps: computer documents has been pieced together big version by printing bookbinding folding hand, version file printout is on coated paper for printing, though art paper is smooth, because ink of the present invention is under UV-irradiation greatly, just can solidify within less than 1 second, picture and text are clear not to be spent.After the client approves specimen page, a big version file is divided into four looks by Rip.The aluminium base version of above-mentioned water wettability is inserted in Epson printer, and printer is set as sheet-fed and prints, and printing precision is made as 2880 * 1440dpi, aluminium plate is punched and hangs over overlap on the printing device.The color separation file divided be printed on respectively for four times on four aluminium plates the printing that just is available on the machine of these four aluminium plates.Because the stamping ink quick solidifying, picture and text are clear not to be spent, and the picture and text that solidify have the oleophylic China ink, and blank parts is possess hydrophilic property in advance, therefore is fit to offset printing.
From whole plate-making process as can be seen, above-mentioned ink have quick solidifying, oleophylic China ink good, do not block printer ink head three big advantages.Simultaneously, because the paper of drawing a design is consistent with printing sheets, the site that is printed on the aluminium plate is consistent with the site of the specimen page of drawing a design, so utilizes computing machine color correction system to be easy to the draw a design color of specimen page and print sample of calibration in advance.
Embodiment 2:
Employing is with embodiment 1 identical marking ink and printer, and print substrate adopts smooth printing paper, and the electronic paper printer that digital camera is provided is on printing paper, and print quality can match in excellence or beauty fully with the photochrome that washes out.Because this ink cured speed is fast, and waterproof is sun-proof, but long preservation.
Claims (14)
1, a kind of preparation method of galley, this method pass through ink-jet printer with the printed text that computing machine generates, and directly are printed on the printing plate;
Wherein the ink of ink-jet printer use is for carrying out the composition of photopolymerization reaction under illumination, and said composition contains following component and parts by weight:
(1) is used for the monomer of photopolymerization reaction: 20-80
(2) Photoepolymerizationinitiater initiater: 2-20
(3) colorant: 2-10
(4) organic solvent: 10-70.
2, the preparation method of galley according to claim 1, it is characterized in that the monomer that is used for photopolymerization reaction in the described composition for ink is selected from trimethylolpropane triacrylate, ethoxylated trimethylolpropane triacrylate, pentaerythritol triacrylate, the polyethers trimethylolpropane triacrylate, neopentylglycol diacrylate, ethoxylated neopentylglycol diacrylate, tripropylene glycol diacrylate, propylene glycol diacrylate, 1, the 4-butanediol diacrylate, polyglycol (200) diacrylate, polyglycol (400) diacrylate, diethylene glycol diacrylate, triethylene glycol diacrylate, PDDA, the EA epoxy acrylate, 1,6 hexanediol diacrylate, the propoxylated glycerol triacrylate, the phthalic acid tripropylene glycol diacrylate, in ethoxylated bisphenol a diacrylate and the glytidyl methacrylate one or more.
3, the preparation method of galley according to claim 1 is characterized in that Photoepolymerizationinitiater initiater is selected from styrax in the described composition for ink, benzoin methyl ether, the Alpha-Methyl styrax, α-phenyl styrax, benzoin ethyl ether, benzoin isobutyl ether, benzoin isobutyl ether, benzophenone, dibenzoyl, Michler's keton, to the phenyl benzophenone, halo acetophenone, Alpha-hydroxy-Alpha-Methyl propiophenone, 2-hydroxyl-[4-(2-hydroxyl-oxethyl) phenyl]-2-methyl acetone, in 2-methyl isophthalic acid-(4-methyl mercapto phenyl)-2-morpholine-1-acetone and the 1-hydroxy-cyclohexyl phenyl ketone one or more.
4, the preparation method of galley according to claim 1 is characterized in that the colorant described in the described composition for ink is solvent dye or oil-soluble dyes.
5, the preparation method of galley according to claim 4 is characterized in that the colorant described in the described composition for ink is selected from one or more in oil-soluble Huang, pure molten everbright fast yellow CGG, pure molten everbright fast yellow CGR, Spirit Fast Yellow GR, sun-proof fluorescein D, oil red G, red, the pure molten everbright fast red CG of Oil Violet, alcohol molten scarlet LG, the red as fire B of pure molten sun-proof, pure molten sun-proof fluorescein GG, solvent blue B, oily molten ethereal blue, spirit blue, pure molten sun-proof blue HL, solvent blue RS, the green HL of pure molten sun-proof, nigrosine, nigrosine, solvent black 827 and the solvent black 834.
6, the preparation method of galley according to claim 1 is characterized in that the solvent described in the described composition for ink is selected from one or more in ethanol, propyl alcohol, butanols, isopropyl alcohol, amylalcohol, hexanol, octanol, ethylene glycol monomethyl ether, ethylene glycol monobutyl ether, cyclohexanone, dimethyl formamide, diglycol butanone, MEK, butyrolactone, the valerolactone etc.
7, the galley made of the described galley preparation method of one of claim 1-6.
8, a kind of composition for ink that is used for inkjet printing includes following component and parts by weight:
(1) is used for the monomer of photopolymerization reaction: 20-80
(2) Photoepolymerizationinitiater initiater: 2-20
(3) colorant: 2-10
(4) organic solvent: 10-70.
9, the composition for ink that is used for inkjet printing according to claim 8, it is characterized in that the monomer that is used for photopolymerization reaction in the described composition for ink is selected from trimethylolpropane triacrylate, ethoxylated trimethylolpropane triacrylate, pentaerythritol triacrylate, the polyethers trimethylolpropane triacrylate, neopentylglycol diacrylate, ethoxylated neopentylglycol diacrylate, tripropylene glycol diacrylate, propylene glycol diacrylate, 1, the 4-butanediol diacrylate, polyglycol (200) diacrylate, polyglycol (400) diacrylate, diethylene glycol diacrylate, triethylene glycol diacrylate, PDDA, the EA epoxy acrylate, 1,6 hexanediol diacrylate, the propoxylated glycerol triacrylate, the phthalic acid tripropylene glycol diacrylate, in ethoxylated bisphenol a diacrylate and the glytidyl methacrylate one or more.
10, the composition for ink that is used for inkjet printing according to claim 8 is characterized in that Photoepolymerizationinitiater initiater is selected from styrax in the described composition for ink, benzoin methyl ether, the Alpha-Methyl styrax, α-phenyl styrax, benzoin ethyl ether, benzoin isobutyl ether, benzoin isobutyl ether, benzophenone, dibenzoyl, Michler's keton, to the phenyl benzophenone, halo acetophenone, Alpha-hydroxy-Alpha-Methyl propiophenone, 2-footpath base-[4-(2-hydroxyl-oxethyl) phenyl]-2-methyl acetone, in 2-methyl isophthalic acid-(4-methyl mercapto phenyl)-2-morpholine-1-acetone and the 1-hydroxy-cyclohexyl phenyl ketone one or more.
11, the composition for ink that is used for inkjet printing according to claim 8 is characterized in that the colorant described in the described composition for ink is selected from the oil-soluble Huang, the molten everbright fast yellow CGG of alcohol, the molten everbright fast yellow CGR of alcohol, Spirit Fast Yellow GR, sun-proof fluorescein D, oil red G, Oil Violet is red, the molten everbright fast red CG of alcohol, the molten scarlet LG of alcohol, the red as fire B of the molten sun-proof of alcohol, the molten sun-proof fluorescein GG of alcohol, solvent blue B, the molten ethereal blue of oil, spirit blue, the blue HL of the molten sun-proof of alcohol, solvent blue RS, the green HL of the molten sun-proof of alcohol, nigrosine, nigrosine, in solvent black 827 and the solvent black 834 one or more.
12, the composition for ink that is used for inkjet printing according to claim 8,, it is characterized in that the solvent described in the described composition for ink is selected from one or more in ethanol, propyl alcohol, butanols, isopropyl alcohol, amylalcohol, hexanol, octanol, ethylene glycol monomethyl ether, ethylene glycol monobutyl ether, cyclohexanone, dimethyl formamide, diglycol butanone, MEK, butyrolactone, the valerolactone etc.
13, a kind of print sample, its adopt the high precision ink-jet printer with figure message printing on printing, wherein the ink that uses of ink-jet printer contains the described composition of one of claim 8-12.
14, a kind of black and white or photochrome, on taking a picture with printing paper, wherein the ink of ink-jet printer use contains the described composition of one of claim 8-12 to employing high precision ink-jet printer with figure message printing.
Priority Applications (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB021537003A CN1186694C (en) | 2002-12-05 | 2002-12-05 | Printing printmaking method and printing plate thereof |
| PCT/CN2003/001045 WO2004059385A1 (en) | 2002-12-05 | 2003-12-05 | Printing plate making method and the plate made by this method |
| CN 200380100187 CN1820227A (en) | 2002-12-05 | 2003-12-05 | Printing platemaking method and printing plate thereof |
| AU2003289608A AU2003289608A1 (en) | 2002-12-05 | 2003-12-05 | Printing plate making method and the plate made by this method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB021537003A CN1186694C (en) | 2002-12-05 | 2002-12-05 | Printing printmaking method and printing plate thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1504326A CN1504326A (en) | 2004-06-16 |
| CN1186694C true CN1186694C (en) | 2005-01-26 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB021537003A Expired - Fee Related CN1186694C (en) | 2002-12-05 | 2002-12-05 | Printing printmaking method and printing plate thereof |
| CN 200380100187 Pending CN1820227A (en) | 2002-12-05 | 2003-12-05 | Printing platemaking method and printing plate thereof |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 200380100187 Pending CN1820227A (en) | 2002-12-05 | 2003-12-05 | Printing platemaking method and printing plate thereof |
Country Status (3)
| Country | Link |
|---|---|
| CN (2) | CN1186694C (en) |
| AU (1) | AU2003289608A1 (en) |
| WO (1) | WO2004059385A1 (en) |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2006321868A (en) * | 2005-05-18 | 2006-11-30 | Fujifilm Holdings Corp | Ink composition, inkjet recording method, printed matter, manufacturing method of lithographic printing plate, and lithographic printing plate |
| CN100427556C (en) * | 2006-08-29 | 2008-10-22 | 林其武 | Printing ink for water-sticking |
| CN102395557A (en) * | 2008-12-09 | 2012-03-28 | 佛罗里达大学研究基金会公司 | Kinase inhibitor compounds |
| CN102176107B (en) * | 2011-01-06 | 2012-08-29 | 西安理工大学 | Offset print water-borne UV (ultraviolet) photo-sensitive resist jetting plate-making method |
| CN102993824A (en) * | 2011-09-14 | 2013-03-27 | 中国科学院化学研究所 | UV-curable ink used in inkjet printing direct-to-plate, and preparation method and application thereof |
| DE102013107996A1 (en) * | 2013-07-26 | 2015-02-19 | Manroland Web Systems Gmbh | Method and device for producing printing forms and printing method |
| EP3017945B1 (en) * | 2014-11-06 | 2017-10-25 | Agfa Graphics Nv | Inkjet CTP method for preparing a set of lithographic printing plates |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0844044A (en) * | 1994-03-24 | 1996-02-16 | Toray Ind Inc | Image forming method for printing plate |
| JP2001031875A (en) * | 1999-05-20 | 2001-02-06 | Mitsui Chemicals Inc | Photosensitive composition and printing plate using the same |
| CN1295307A (en) * | 1999-11-05 | 2001-05-16 | 张仲奎 | Manufacture and plate-making process of ink-jet computerized printing plate |
| US6555283B1 (en) * | 2000-06-07 | 2003-04-29 | Kodak Polychrome Graphics Llc | Imageable element and waterless printing plate |
-
2002
- 2002-12-05 CN CNB021537003A patent/CN1186694C/en not_active Expired - Fee Related
-
2003
- 2003-12-05 WO PCT/CN2003/001045 patent/WO2004059385A1/en not_active Application Discontinuation
- 2003-12-05 CN CN 200380100187 patent/CN1820227A/en active Pending
- 2003-12-05 AU AU2003289608A patent/AU2003289608A1/en not_active Abandoned
Also Published As
| Publication number | Publication date |
|---|---|
| WO2004059385A1 (en) | 2004-07-15 |
| CN1504326A (en) | 2004-06-16 |
| CN1820227A (en) | 2006-08-16 |
| AU2003289608A1 (en) | 2004-07-22 |
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