CN1185313A - Powdered cosmetic composition - Google Patents
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- CN1185313A CN1185313A CN 97125533 CN97125533A CN1185313A CN 1185313 A CN1185313 A CN 1185313A CN 97125533 CN97125533 CN 97125533 CN 97125533 A CN97125533 A CN 97125533A CN 1185313 A CN1185313 A CN 1185313A
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Abstract
This invention relates to a powdery cosmetics containing (A) 1-95 wt.% of fine powder having > 0.1 to 2 mu m volume average particle diameter and <=2 refractive index and (B) 1-95 wt.% of organic powder having short diameter which is 1/1 to 1/100 of long diameter and thickness which is below 1/2 of the long diameter, and the total amount of ingredients (A) and (B) is above 5 wt.% in the whole powdery cosmetics. This powdery cosmetics is good in touch such as slipperiness or adhesion on skin, wetness, and excellent in effects on making unevennesses such as skin pores or small wrinkles in conspicuous and capable of providing a natural finish without using ground make-up.
Description
The spreadability, the tack that the present invention relates on skin are good, have wetness sensation, and can make the unconspicuous powdered cosmetic compositions that become such as pore, rugula stricture of vagina.
The powdered cosmetic composition of cosmetic cosmetic composition etc. adopts cosmetic composition with powder body and oleaginous base and other components matching and make usually.To these cosmetics, usually require spreadability, tack on skin good, further also require to have defectives such as the senile plaque that hides skin, freckle, wrinkle, pore, adjust skin colour, functions such as protection dry skin.
For this reason, in the past, by in powdered cosmetic composition, allocating various spherical powder body into, thereby realize that smooth feeling is good, sprawl light good feel, at this used spherical powder body, though have good feel, but covering power is poor, can not make pore, rugula stricture of vagina etc. become not obvious.
On the other hand, in order to hide the defective of skin, the known cosmetic composition that the Chinese white that cooperates highs index of refraction such as more titanium oxide is also arranged, these cosmetic composition covering powers are good, though but can hide senile plaque, freckle etc., but its deficiency is sprawling heavily on skin, and makeup is thick, convex-concaves such as pore, rugula stricture of vagina are more obvious, can not obtain the makeup effect of nature.
For this reason, the applicant finds, by being used in combination micropowder and spherical powder body with specified particle diameter, thereby obtain sprawling good and can make skin defects such as pore, the rugula stricture of vagina unconspicuous powdered cosmetic composition that becomes on skin, and applied for patent (the flat 7-277925 of special Open number).
Yet though this powdered cosmetic composition has above-mentioned excellent results, tack is bad, and owing to have the distinctive dirt sense of micropartical, can not obtain the sensation of moistening, is anti-defective here, must and face powders such as emulsion, vanishing cream at the bottom of etc. shared.
Thus, expectation obtains can be without at the bottom of the face powder, and sprawling, adhering to and feel good on skin can obtain wetness sensation simultaneously, and can hide the convexo-concave powdered cosmetic compositions such as pore, rugula stricture of vagina of skin naturally.
The inventor etc., according to above-mentioned truth, through concentrating on studies discovery, by being used in combination micropowder with specified particle diameter and the organic powder with given shape, the powdered cosmetic composition of the gained not only spreadability on skin is good, and can make pore, rugula stricture of vagina etc. become not obvious, in addition can be without at the bottom of the face powder, good in adhering to of skin, can on skin, evenly be coated with and obtain wetness sensation, thereby finish the present invention.
Therefore, the invention provides and contain following compositions (A) and powdered cosmetic composition (B), wherein,
(A) be volume average particle size greater than 0.1 micron, less than 2 microns, refractive index is at the micropowder below 2, content is 1～95 weight %
(B) be minor axis be major diameter 1/1～1/100, thickness is the organic powder below 1/2 of major diameter, content is 1～95 weight %
(A) be more than the 5 weight % with (B) total proportional quantity.
In addition, in the present invention, if not special record, then volume average particle size is meant the meansigma methods of the sphere diameter suitable with the volume of the particle of measuring, what the value of gained was used for the powder body more than 1 micron is the laser refraction method, what use below 1 micron is laser scattering method, and dispersant is an ethanol, and refractive index adopts Larsen immersion method to try to achieve in the following manner.The powder body sample is added in the liquid, measure Becke line during illumination, when liquid was identical with the sample refractive index, Becke line disappeared, and becomes transparent.Thus, by changing the composition of mixed solution, change liquid refractive index, liquid refractive index is the refractive index of sample when measuring the Becke line disappearance with Abbe refractometer.In addition, the shape of powder body (minor axis, major diameter, thickness) adopts the meansigma methods after the transmission electron microscope photo is measured respectively the shape of 300 powder particles.
Micropowder as the used composition of the present invention (A), so long as volume average particle size is greater than 0.1 micron,, have no particular limits less than 2 microns, inorganic micro powder end, organic micropowder end all can, its shape can be spherical, tabular, granular, needle-like, arbitrary shape such as bar-shaped, unformed.Wherein spherical, shot-like particle, from aspects such as use feelings for preferably.As above-mentioned micropowder, can enumerate as inorganic micro powder ends such as silicon dioxide, aluminium oxide, barium sulfate, aluminium hydroxide, calcium carbonate, magnesium silicate, magnesium carbonate, aluminium silicate; Organic micropowder ends such as polyamide, polyvinyl resin, acrylic resin, polymethyl methacrylate resin, cellulosic resin, polystyrene resin, styrene and acrylic copolymer, silicone resin etc.Wherein, as low-refraction material such as the silicon dioxide at inorganic micro powder end, barium sulfate owing to can obtain the makeup effect of nature, for preferably.
In addition, these micropowders also can with usual method with coloring pigment, pigment, dyestuff, metal ion etc. be covered, interior bag is handled or painted after use.
The volume requirement mean diameter of these micropowders surpasses 0.1 micron, below 2 microns, and preferred 0.15～1.5 micron, special preferred 0.3～1.2 micron.0.1 when micron was following, use feeling was bad, and the convexo-concave not obvious effect that becomes such as pore, rugula stricture of vagina is reduced, and when surpassing 2 microns, the convexo-concave not obvious effects that become such as pore, rugula stricture of vagina also will be reduced, and is all not preferred.
In addition, special preferred volume mean diameter is 0.11～2 micron, and wherein particle diameter is the following person of 10 volume % less than the particle that 0.05 micron particle reaches greater than 5 microns.
In addition, composition (A) is coated after the skin, for obtaining special dizzy sense effect, obtained convex-concaves such as good pore, the rugula stricture of vagina unconspicuous effect that becomes thus, should make its refractive index is below 2.0, preferred 1.3～2.0, special preferred 1.4～1.8.Surpass 2.0 and can't obtain above result.
Organic powder as the used composition of the present invention (B), so long as minor axis is 1/1～1/100 of a major diameter, thick is non-composition (A) person below 1/2 of major diameter, have no particular limits, for example can adopt alkyl phosphoric acid multivalent metal salts such as cetyl zinc phosphate sodium, dodecylphosphoric acid zinc, dodecylphosphoric acid calcium (according to the method manufacturing of the clear 60-248605, of Te Open Te Open clear 61-229889 number and the flat 3-178987 of Te Open number each communique record); N-lauroyl-Beta-alanine calcium, N-lauroyl-Beta-alanine zinc, acylated amino multivalent metal salts (according to the method manufacturing of the flat 4-5216 communique record of special Open) such as the amino caproic acid calcium of N-lauroyl; N-lauroyl calcium taurinate, amidosulfonic acid multivalent metal salts such as N-palmityl calcium taurinate (according to the method manufacturing of the flat 3-294210 communique record of Te Open); N
1-lauroyl-L-lysine, N
1N-acyl-lysines such as-palmityl lysine (, the Amihope LL of aginomoto company product being arranged as commercially available product) according to the method manufacturing of the clear 60-67406 communique record of Te Open; Alpha-amido fatty acids such as alpha-amido capric acid, alpha-amido lauric acid (according to the method manufacturing of the clear 62-4211 communique record of Te Open); Flat or the tabular toner of polyethylene, polypropylene, nylon, polymethyl methacrylate, polystyrene, divinylbenzene styrol copolymer, tetrafluoroethene etc. (according to the method manufacturing of the clear 57-78466, of Te Open Te Open clear 62-190112 number and the clear 62-104706 communique record of Te Open) etc.
Above-mentioned organic powder, be necessary to make its minor axis be major diameter 1/1～1/100, preferred 1/1～1/50, special preferred 1/1～1/10, thickly be preferably 1/2～1/50 for below 1/2 of major diameter, preferred 1/2～1/100, spy.In the time of outside this scope, not preferred from the use feeling aspect.In addition, preferred powder body major diameter be 0.1～100 micron, special preferred 1～50 micron, 0.1～100 micron of minor axis, special preferred 1～50 micron, thick be 0.05～50 micron, special preferred 0.05～10 micron.
Above-mentioned organic powder, its volume average particle size are 0.1～100 micron, especially at 1～50 micron, further in the time of 1～20 micron, from sprawling on skin, adhere to, wetness sensation aspect for preferably.
In powdered cosmetic composition of the present invention, composition (A) and composition (B) can be used in combination the above-mentioned material more than a kind or 2 kinds respectively.Composition (A) accounts for 1～95 weight % (below be abbreviated as %), preferred 5～70%, special preferred 10～50% in total the composition.During less than 1%, not being preferred aspect makeup, surpassing at 95% o'clock, is not preferred aspect usability.In addition, composition (B) accounts for 1～95 weight % in total the composition, and preferred 5～70%, special preferred 10～50%.During less than 1%, not being preferred aspect usability, surpassing at 95% o'clock, is not preferred aspect makeup.In addition, when the total amount of the proportional quantity of composition (A) and composition (B) amounts to less than 5%, can not obtain to sprawl fully on skin and the unconspicuous effects that become such as pore or rugula stricture of vagina, be preferred.
In addition, in the scope of not damaging effect of the present invention, can be with the used inorganic agent of common used for cosmetic powder body, as, silicone, metallic soap, lecithin, aminoacid, collagen, fluoride etc. carry out composition (A) and composition (B) to use after the surface treatment.
In the powdered cosmetic composition of the present invention; adopt silicon dioxide, barium sulfate, polyamide, polymethyl methacrylate resin or silicone resin as composition (A); with alkyl phosphoric acid multivalent metal salt, acylated amino multivalent metal salt, N-acyl-lysine as composition (B) when being used in combination; can obtain the makeup effect of nature and good sense of touch, preferred especially.
In the cosmetic composition of the present invention, except that aforementioned necessary composition, in the scope of not damaging effect of the present invention, also can suitably add other powder body compositions.These powder body compositions can be to handle inorganic pigments such as Muscovitum such as Talcum, Muscovitum, sericite, Kaolin, bentonite, trematodiasis soil, Strese Hofmann's hectorite., zeolite, silicon dioxide, aluminium oxide, beidellite, aluminium silicate, magnesium silicate, calcium silicates, Magnesiumaluminumsilicate, magnesium carbonate, calcium carbonate, barium sulfate, hydroxyapatite, boron nitride, perfluorocarbon, barium sulfate; Polymer powders such as nylon powder, polymethyl methacrylate powder, polyethylene powders, polystyrene powder, benzoguanamine (benzoguanamine) powder, fluororesin powder, polymethylsilsesquioxane powder; Organic-inorganic composite powder such as zirconium oxide lining nylon powder, titanium oxide lining nylon powder; Spherical polymethyl methacrylate-Muscovitum composite granule, spherical polymethyl methacrylate-zeolite composite granule, spherical polymethyl methacrylate-Talcum composite granule, spherical silicon dioxide-spherical-tabular compoundization of composite granule pigment such as Muscovitum composite granule; Inorganic Chinese whites such as titanium dioxide, zinc oxide, zirconium oxide; Inorganic brown type pigment such as inorganic red type pigment such as ferrum oxide (red ferric oxide), iron titanate, smithsonite, gamma-iron oxide; Inorganic yellow such as yellow ferric oxide, loess type pigment; Inorganic black type pigment such as Black Rouge, carbon black, rudimentary titanium oxide; Inorganic purple type such as manganese violet, cobalt violet pigment; Inorganic green type pigment such as chromium oxide, chromic oxide gel, cobalt titanate; Ultramarine, dark blue or green inorganic cyan type pigment such as (dark purple); Gray paints such as titanium oxide lining Muscovitum, bismuth oxychloride, titanium oxide lining bismuth oxychloride, titanium oxide lining Talcum, painted titanium oxide lining Muscovitum, guanin; Organic pigments such as metallic powdery pigment such as aluminium powder, copper powder, cellulose, silk; Metallic soap classes such as zinc stearate; Red No. 201, red No. 202, red No. 203, red No. 203, red No. 205, red No. 213, red No. 219, red No. 220, red No. 226, red No. 228, red No. 405, orange No. 203, orange No. 204, yellow No. 205, yellow No. 401, No. 404, cyan, red No. 3, red No. 104, red No. 106, red No. 227, red No. 230, red No. 401, red No. 505, orange No. 205, yellow No. 4, yellow No. 5, yellow No. 202, yellow No. 203, green No. 3, and pigment and their zirconates such as No. 1, cyan, color lake pigment such as barium salt or aluminum salt; Anti-ultraviolet powder body such as natural pigment such as chlorophyll, beta-carotene, micropartical titanium oxide, micropartical zinc oxide, laminar zinc oxide, micropartical zirconium oxide, micropartical cerium oxide.
Above-mentioned powder body can directly use, and also can carry out surface treatment and/or carry out surface treatment use afterwards with organic type inorganic agents such as fluorine processing such as aminoacid processing, lecithin processing, collagen processing, polyethylene processing, polyacrylic acid processing, alkyl phosphate processing, the processing of alkyl phosphoric acid slaine, the processing of fluoro-alkyl phosphoric acid such as silicone-treated, metallic soap processing, acyl glutamic acid, the single long acyl basic amino acids of N-with inorganic type inorganic agents such as silica-treated, alumina treatment, silica alumina processing, titanium dioxide processing, barium sulfate processing.
In addition, in the cosmetic composition of the present invention, except that aforementioned composition, also can add composition used in the ordinary cosmetics compositions, shape oil, various surfactant, water soluble polymer, wetting agent, antiseptic, medicine, UV absorbent, oil-soluble macromolecule, polymer latex, spice, antioxidant, thickening agent, pH adjustment agent, water etc. suitably cooperate admittedly as liquid oil, solid shape fat (wax), half.
Specifically, as liquid oil, so long as the common used liquid oil of cosmetics has no particular limits, can enumerate as, American Avocado Tree oil, olive oil, simmondsia wet goods vegetable oil; Fatty acid such as oleic acid, isostearic acid; Aliphatic alcohols such as hexadecanol, oleyl alcohol; 2 ethyl hexanoic acid cetyl, Palmic acid-2-Octyl Nitrite, myristic acid-2-octyl group ten diester, two-2 ethyl hexanoic acid DOPCP, three-2 ethyl hexanoic acid glyceride, oleic acid-2-octyl dodecanol ester, isopropyl myristate, three glyceryl isostearates, 2 ethyl hexanoic acid diglyceride, two-p-methoxycinnamate-list-esters such as 2 ethyl hexanoic acid glyceride; Silicone oils such as dimethyl polysiloxane, hydrogenated methyl polysiloxanes, methyl phenyl silicone, prestox ring four oxosilanes; Fluorine type oil such as perfluoroalkyl ethers; Liquid hydrocarbon wet goods such as liquid paraffin, Squalene, three decanes will use after can or will mixing more than two kinds with wherein a kind of.
As above-mentioned solid shape fat or half shape fat admittedly, can enumerate as, vaseline, lanoline, ceresin(e), microwax, Brazil wax (Carnauba wax), candelilla wax etc.
As above-mentioned surfactant, can enumerate as nonionic surfactant such as, polyethylene oxide alkyl ethers, poly(ethylene oxide) fatty acid ester, poly(ethylene oxide) sorbitan fatty acid ester, fatty acid glyceride, polyglyceryl fatty acid ester, poly(ethylene oxide) fatty acid glyceride, poly(ethylene oxide) sclerosis Semen Ricini oil, poly(ethylene oxide) Spans; The anion surfactant of fatty acid soaps classes such as sodium stearate, Palmic acid triethanolamine salt representative; And cosmetics such as cationic surfactant, amphoteric surfactant surfactant commonly used.
As above-mentioned water soluble polymer, can enumerate as cosmetics water soluble polymers commonly used such as, carboxymethyl cellulose, methylcellulose, hydroxy methocel, polyvinyl alcohol, polyvinylpyrrolidone, yellow work glue, spiny dogfish dish glue (carrageenan), locust bean gum, dextrin, dextrin fatty acid ester, carboxyl ethylene polymer, xanthene glue, gelatin, sodium alginate, arabic gums.
As above-mentioned wetting agent, can enumerate as, sorbitol, xylitol, glycerol, maltitol, propylene glycol, 1,3 butylene glycol, 1, the wetting agent that cosmetics such as 4-butanediol, pyrrolidone sodium carboxylate, lactic acid, sodium lactate, polyvinyl alcohol are commonly used.
As above-mentioned antiseptic, can enumerate as, alkyl paraben, sodium benzoate, sodium sorbate, etc. cosmetics antiseptic commonly used.
As above-mentioned medicine, can enumerate as cosmetics such as, vitamins, crude drug, antiinflammatory, antibacterial medicine commonly used.
As above-mentioned UV absorbent, can enumerate as, cosmetics such as para-amino benzoic acid type UV absorbent, anthranilic acid type UV absorbent, salicylic acid type UV absorbent, Cortex cinnamomi japonici (Ramulus Cinnamomi) acid type UV absorbent, benzophenone UV absorbent commonly used,
Powdered cosmetic composition of the present invention can be according to the usual method manufacturing, can be made into as, foundation cream, face powder, rouge, eye shadow etc. are gone up cosmetics; Dosage forms such as body and function such as talcum powder, baby talcum powder cosmetics.
Powdered cosmetic composition of the present invention is by being used in combination micropowder with designated volume mean diameter and the organic powder with given shape, can obtain not only lubriciously on skin feeling good, can hide the convex-concave such as pore, rugula stricture of vagina of skin, and can be without at the bottom of the face powder, can on skin, have good sprawling, evenly coating on skin, and can obtain wetness sensation.
Below, the present invention is further described to enumerate embodiment, and the present invention is not subjected to the restriction of these embodiment.
Illustrate that volume average particle size shown in the embodiment all is dispersant with ethanol, the little measuring instrument of producing with SEISHIN enterprise of SK laser records, and powder body adopts the laser refraction method more than 1 micron, and powder body below 1 micron adopts the laser refraction method to measure.Embodiment 1
Make the powdery foundation cream of forming as shown in Table 1 and Table 2, makeup and use experience when estimating its use.The result as shown in Table 1 and Table 2.
(method for making)
The powder body composition is mixed with the HENSCHEL blender, further mixed to wherein adding oil content then.It is packed in the vessel, makes solid shape foundation cream.
(evaluation methodology)
Makeup:
With foundation cream coat makeup after the face by special syndic with visual by following standard evaluation.
Zero; Convex-concaves such as pore, rugula stricture of vagina almost be cannot see.
△; Convex-concaves such as pore, rugula stricture of vagina as seen.
*; Pore, rugula stricture of vagina etc. are very high-visible.
Use experience:
By special juror foundation cream is coated on the face with sponge, pressed following standard use experience dosage form evaluation this moment.
(sprawling)
Foundation cream is sprawled very good.
Zero; Foundation cream is sprawled.
△; Foundation cream is sprawled poorly.
*; Foundation cream is sprawled bad.
(adhering to)
Foundation cream adheres to very good.
Zero; The foundation cream good attachment.
△; Foundation cream adheres to poorly.
*; Foundation cream adheres to bad.
(wetness sensation)
Wetness sensation is very strong.
Zero; Wetness sensation is arranged.
△; Wetness sensation is not strong.
*; No wetness sensation.Embodiment 2
By making the powdery foundation cream of composition as shown in table 3 with embodiment 1 same procedure, makeup and use experience when estimating it and use with embodiment 1 same procedure.The result is as shown in table 3.In addition, be before coating powdery foundation cream, to be coated with at full face at the bottom of the face powder of product 8 of the present invention and contrast product 3 with emulsion (KAO. Corp. SA makes, Sofina Emolliel breast).Embodiment 3
By making the powdery foundation cream of composition as shown in table 4 with embodiment 1 same procedure, makeup and use experience when estimating it and use with embodiment 1 same procedure.The result is as shown in table 4.Embodiment 4
The loose type face powder that manufacturing is formed shown in table 5 and table 6, makeup and use experience when estimating it and use with embodiment 1 same procedure.The result is shown in table 5 and table 6.
(method for making)
The powder body composition is mixed with the HENSCHEL blender, then to wherein add oil content further mixed after, sieve and promptly make loose type face powder.
Table 1
* according to the BET specific surface area, the volume average particle size table of converting out by spheroid 2
* according to the BET specific surface area, the volume averaging material footpath table of converting out by spheroid 3
Table 4
Table 5
* according to the BET specific surface area, the volume average particle size table of converting out by spheroid 6
* according to the BET specific surface area, the volume average particle size embodiment 5 (powdery foundation cream) that converts out by spheroid
| Composition (%) | Product of the present invention | ||||
| 1 | 2 | 3 | 4 | ||
| (1) (2) (3) (4) (5) (6) (7) (8) (9) (10) | Sericite (8 microns of volume average particle size) Muscovitum (6 microns of volume average particle size) titanium oxide yellow ferric oxide red ferric oxide Black Rouge cetyl zinc phosphate sodium (powder body shape (on average): 18 microns of major diameters, 14 microns of minor axis, 1 micron of thickness) spherical plexiglass (0.4 micron of volume average particle size, refractive index 1.49) spherical plexiglass (0.8 micron of volume average particle size, refractive index 1.49) spherical silicone resin (0.5 micron of volume average particle size, refractive index 1.45) | 15 6.5 6 2.1 0.6 0.2 30 30 - - | 15 6.5 6 2.1 0.6 0.2 30 - 30 - | 15 6.5 6 2.1 0.6 0.2 30 - - 30 | 15 6.5 6 2.1 0.6 0.2 30 - - - |
| (11) (12) (13) (14) (15) (16) | Spherical silicon dioxide (0.5 micron of volume average particle size, refractive index 1.45) aluminium oxide (0.5 micron of volume average particle size, refractive index 1.74) barium sulfate (0.5 micron of volume average particle size, refractive index 1.63) fine-particle powder silicon dioxide (0.01 micron * of volume average particle size, refractive index 1.45) titanium oxide (0.3 micron of volume average particle size, refractive index 2.70) oil content (dimethyl polysiloxane) | ?- ?- ?- ?- ?- ?9.6 | ?- ?- ?- ?- ?- ?9.6 | - - - - - 9.6 | ?30 ?- ?- ?- ?- ?9.6 |
| Makeup is sprawled the adhesional wetting sense at the bottom of having or not face powder | No ◎ ◎ ◎ ◎ | No ◎ ◎ ◎ ◎ | No ◎ ◎ ◎ ◎ | No ◎ ◎ ◎ ◎ | |
| Composition (%) | Product of the present invention | Reference product | |||
| 5 | 6 | 1 | 2 | ||
| (1) (2) (3) (4) (5) (6) (7) (8) (9) (10) | Sericite (8 microns of volume average particle size) Muscovitum (6 microns of volume average particle size) titanium oxide yellow ferric oxide red ferric oxide Black Rouge cetyl zinc phosphate sodium (powder body shape (on average): 18 microns of major diameters, 14 microns of minor axis, 1 micron of thickness) spherical plexiglass (0.4 micron of volume average particle size, refractive index 1.49) spherical plexiglass (0.8 micron of volume average particle size, refractive index 1.49) spherical silicone resin (0.5 micron of volume average particle size, refractive index 1.45) | 15 6.5 6 2.1 0.6 0.2 30 - - - | 15 6.5 6 2.1 0.6 0.2 30 - - - | 15 6.5 6 2.1 0.6 0.2 30 - - - | 15 6.5 6 2.1 0.6 0.2 30 - - - |
| (11) (12) (13) (4) (15) (16) | Spherical silicon dioxide (0.5 micron of volume average particle size, refractive index 1.45) aluminium oxide (0.5 micron of volume average particle size, refractive index 1.74) barium sulfate (0.5 micron of volume average particle size, refractive index 1.63) fine-particle powder silicon dioxide (0.01 micron * of volume average particle size, refractive index 1.45) titanium oxide (0.3 micron of volume average particle size, refractive index 2.70) oil content (dimethyl polysiloxane) | ?- ?30 ?- ?- ?- ?9.6 | ?- ?- ?30 ?- ?- ?9.6 | - - - 30 - 9.6 | - - - - 30 9.6 |
| Makeup is sprawled the adhesional wetting sense at the bottom of having or not face powder | There are not 00 ◎ ◎ | There are not 00 ◎ ◎ | No △ * zero △ | There is not * zero ◎ ◎ | |
| Composition (%) | Product of the present invention | Reference product | |||||
| 7 | 8 | 9 | 10 | 3 | 4 | ||
| (1) (2) (3) (4) (5) (6) (7) (8) (9) (10) | The spherical plexiglass of sericite (8 microns of volume average particle size) Muscovitum (6 microns of volume average particle size) titanium oxide yellow ferric oxide red ferric oxide Black Rouge (0.4 micron of volume average particle size; refractive index 1.49) cetyl zinc phosphate sodium (powder body shape (on average): 18 microns of major diameters; 14 microns of minor axis; 1 micron of thickness) N-ε-lauroyl-L-lysine (powder body shape (on average): 9 microns of major diameters; 7 microns of minor axis; 0.3 micron of thickness) N-lauroyl calcium taurinate (powder body shape (on average): 9 microns of major diameters; 6 microns of minor axis; 0.5 micron of thickness) | 15 6.5 6 2.1 0.6 0.2 30 30 - - | 15 6.5 6 2.1 0.6 0.2 30 30 - - | 15 6.5 6 2.1 0.6 0.2 30 - 30 - | 15 6.5 6 2.1 0.6 0.2 30 - - 30 | 15 6.5 6 2.1 0.6 0.2 30 - - - | 15 6.5 6 2.1 0.6 0.2 30 - - - |
| (11) (12) | Spherical nylon (5 microns of volume average particle size) oil content (dimethyl polysiloxane) | ?- ?9.6 | - 9.6 | ?- ?9.6 | - 9.6 | 30 9.6 | 30 9.6 |
| Makeup is sprawled the adhesional wetting sense at the bottom of having or not face powder | No ◎ ◎ ◎ ◎ | ◎ ◎ ◎ ◎ is arranged | No ◎ ◎ ◎ ◎ | No ◎ ◎ ◎ ◎ | ◎ zero ◎ △ is arranged | No △ zero * * | |
| Composition (%) | Product of the present invention | Reference product | |||||
| 11 | 12 | 13 | 14 | 15 | 5 | ||
| (1) (2) (3) (4) (5) (6) (7) (8) (9) | Sericite (8 microns of volume average particle size) mica (6 microns of volume average particle size) titanium oxide yellow ferric oxide red ferric oxide Black Rouge cetyl sodium-zinc-phosphate (powder shape (on average): 18 microns of major diameters, 14 microns of minor axis, 1 micron of thickness) spherical plexiglass (0.4 micron of volume average particle size, refractive index 1.49) oil content (dimethyl polysiloxane) | 15 6.5 6 2.1 0.6 0.2 42 18 9.6 | 15 6.5 6 2.1 0.6 0.2 30 30 9.6 | 15 6.5 6 2.1 0.6 0.2 18 42 9.6 | 45 6.5 6 2.1 0.6 0.2 15 15 9.6 | 65 6.5 6 2.1 0.6 0.2 5 5 9.6 | 71 6.5 6 2.1 0.6 0.2 2 2 9.6 |
| Have or not at the bottom of the face powder | Do not have | Do not have | Do not have | Do not have | Do not have | Do not have | |
| Makeup is sprawled the adhesional wetting sense | ◎ ◎ ◎ ◎ | ◎ ◎ ◎ ◎ | ◎ ◎ ◎ ◎ | ◎ ◎ ◎ ◎ | ○ ○ ○ ○ | × × ○ △ |
| Composition (%) | Product of the present invention | ||||||
| 16 | 17 | 18 | 19 | 20 | 21 | ||
| (1) (2) (3) (4) (5) (6) (7) (8) (9) (10) | Talcum (10 microns of volume average particle size) titanium oxide red ferric oxide cetyl zinc phosphate sodium (powder body shape (on average): 18 microns of major diameters, 14 microns of minor axis, 1 micron of thickness) spherical plexiglass (0.4 micron of volume average particle size, refractive index 1.49) spherical plexiglass (0.8 micron of volume average particle size, refractive index 1.49) spherical silicone resin (0.5 micron of volume average particle size, refractive index 1.49) spherical silicon dioxide (0.5 micron of volume average particle size, refractive index 1.49) aluminium oxide (0.5 micron of volume average particle size, refractive index 1.74) barium sulfate (0.5 micron of volume average particle size, refractive index 1.63) | 18.4 0.5 0.1 40 40 - - - - - | 38.4 0.5 0.1 30 30 - - - - - | 58.4 0.5 0.1 20 20 - - - - - | 38.4 0.5 0.1 30 - 30 - - - - | 38.4 0.5 0.1 30 - 30 - - - | 38.4 0.5 0.1 30 - - - 30 - - |
| (11) (12) (13) | Fine-particle powder silicon dioxide (0.01 micron * of volume average particle size, refractive index 1.45) titanium oxide (0.3 micron of volume average particle size, refractive index 2.70) oil content (dimethyl polysiloxane) | ?- ?- ?1.0 | - - 1.0 | - - 1.0 | - - 1.0 | - - 1.0 | - - 1.0 |
| Makeup is sprawled the adhesional wetting sense at the bottom of having or not face powder | No ◎ ◎ ◎ ◎ | No ◎ ◎ ◎ ◎ | No ◎ ◎ ◎ ◎ | No ◎ ◎ ◎ ◎ | No ◎ ◎ ◎ ◎ | No ◎ ◎ ◎ ◎ | |
| Composition (%) | Product of the present invention | Reference product | ||||
| 22 | 23 | 6 | 7 | 8 | ||
| (1) (2) (3) (4) (5) (6) (7) (8) (9) (10) (11) | Talcum (10 microns of volume average particle size) titanium oxide red ferric oxide cetyl zinc phosphate sodium (powder body shape (on average): 18 microns of major diameters, 14 microns of minor axis, 1 micron of thickness) spherical plexiglass (0.4 micron of volume average particle size, refractive index 1.49) spherical plexiglass (0.8 micron of volume average particle size, refractive index 1.49) spherical silicone resin (0.5 micron of volume average particle size, refractive index 1.49) spherical silicon dioxide (0.5 micron of volume average particle size, refractive index 1.49) aluminium oxide (0.5 micron of volume average particle size, refractive index 1.74) barium sulfate (0.5 micron of volume average particle size, refractive index 1.63) fine-particle powder silicon dioxide (0.01 micron * of volume average particle size, refractive index 1.45) | 38.4 0.5 0.1 30 - - - - 30 - - | 38.4 0.5 0.1 30 - - - - - 30 - | 38.4 0.5 0.1 30 - - - - - - 30 | 38.4 0.5 0.1 30 - - - - - - - | 94.4 0.5 0.1 2 2 - - - - - - |
| (12) (13) | Titanium oxide (0.3 micron of volume average particle size, refractive index 2.70) oil content (dimethyl polysiloxane) | - 1.0 | - 1.0 | - 1.0 | 30 1.0 | - 1.0 |
| Makeup is sprawled the adhesional wetting sense at the bottom of having or not face powder | There are not 00 ◎ ◎ | There are not 00 ◎ ◎ | No △ * zero △ | There is not * zero ◎ ◎ | Nothing * △ zero △ | |
According to the method for No. 3632744 record of US Patent specification, the micropowder that (8) among the embodiment 1～(13) are used is scattered in perfluoralkyl phosphate dihydroxy ethyl amine salt [(C respectively
nF
2n+1C
2H
4O)
yP (=O) (ONH
2(CH
2CH
2OH)
2)
3-y] (n=6～18, n meansigma methods=9.2＞y＞1) in the aqueous solution, after the stirring at room, filter drying, handle the alternative above-mentioned micropowder of powder body with the fluorine that this method obtains, substitute the dimethyl polysiloxane of ultimate constituent (16) simultaneously with perfluoroalkyl ethers (FOMBLIN HC/04, Ausimont company produces), press embodiment 1 respectively and measure equally, press embodiment 1 same order and add, obtain the powdery foundation cream.In addition, composition (8)～(13) are as follows respectively through the particle diameter and the refractive index of the micropowder that fluorine is handled, fluorine is handled plexiglass (8) (0.4 micron of volume average particle size, refractive index 1.49), fluorine is handled plexiglass (9) (0.8 micron of volume average particle size, refractive index 1.49), fluorine is handled silicone resin (10) (0.5 micron of volume average particle size, refractive index 1.45), fluorine is handled spherical silicon dioxide (11) (0.5 micron of volume average particle size, refractive index 1.45), fluorine is handled spherical alumina (12) (0.5 micron of volume average particle size, refractive index 1.74), fluorine is handled barium sulfate (13) (0.5 micron of volume average particle size, refractive index 1.63).
The powdery foundation cream of gained, no matter the smooth feeling on skin, foundation cream adhere to all well, can obtain wetness sensation, and convexo-concave non-remarkableization effect such as pore, rugula stricture of vagina is also good.Embodiment 6 (powdery foundation cream)
Method according to No. 3632744 record of US Patent specification is scattered in two-17 fluoro decyl phosphoric acid [(C with (8) used micropowder among the embodiment 3
8F
17C
2H
4O)
2P (=O) (OH)] and 17 fluoro decyl phosphoric acid [(C
8F
17C
2H
4O) P (=O) (OH)
2] in about 1: the 1 mixture aqueous isopropanol, by the pressure reducing and steaming solvent, handle powder body (0.4 micron of volume average particle size with the fluorine that this method obtains, refractive index 1.49) substitutes above-mentioned micropowder, substitute the dimethyl polysiloxane of ultimate constituent (9) simultaneously with perfluoroalkyl ethers (FOMBLINHC/04, Ausimont company produces), press embodiment 2 respectively and measure equally, press embodiment 1 same order and add, obtain the powdery foundation cream.
The powdery foundation cream of gained, no matter the smooth feeling on skin, foundation cream adhere to all well, can obtain wetness sensation, and also good to convexo-concave non-remarkableization effects such as pore, rugula stricture of vaginas.Embodiment 7 (powdery foundation cream)
According to the method for No. 3632744 record of US Patent specification, with organic powder employing two-17 fluoro decyl the phosphoric acid [(C of (8) among the embodiment 3～(10)
8F
17C
2H
4O)
2P (=O) (OH)] press embodiment 6 and handle with method, handle the alternative above-mentioned micropowder of powder body with the fluorine that this method obtains, and with perfluoroalkyl ethers (FOMBLIN HC/04, the production of Ausimont company) dimethyl polysiloxane of alternative ultimate constituent (12), pressing embodiment 2 respectively measures equally, press embodiment 2 same orders and add, obtain the powdery foundation cream.In addition; powder body shape (on average) after composition (8)～(10) organic powder is handled with fluorine is as follows respectively; cetyl zinc phosphate sodium (8) (18 microns of major diameters, 14 microns of minor axis, 1 micron of thickness); N-ε-lauroyl-L-lysine (9) (9 microns of major diameters, 7 microns of minor axis, 0.3 micron of thickness), N-lauroyl calcium taurinate (10) (9 microns of major diameters, 6 microns of minor axis, 0.5 micron of thickness).Embodiment 8
Make rouge by the following method.
(composition) % mica (6 microns of volume average particle size) 12.9 talcums (10 microns of volume average particle size) 20.0 cetyl sodium-zinc-phosphates (18 microns of powder shape (on average) major diameters, 30.0 14 microns of minor axis, 1 micron of thickness) spherical polymethyl methacrylate resin (volume average particle size 30.00.4 micron, refractive index 1.49) red ferric oxide 0.1 yellow ferric oxide 0.1 Black Rouge 0.0 red No. 226 0.0 oil contents (dimethyl polysiloxane) 6.4
The powder body composition is mixed with the HENSCHEL blender, then to wherein add oil content further mixed after, promptly get rouge in the vessel of packing into.
The powdery rouge of gained, no matter the smooth feeling on skin, foundation cream adhere to all well, can obtain wetness sensation, and also good to convexo-concave non-remarkableization effects such as pore, rugula stricture of vaginas.Embodiment 9
Make the powdery eye shadow by following composition.
(composition) % mica (6 microns of volume average particle size) 13.8 sericites (8 microns of volume average particle size) 15.0N-lauroyl-calcium taurinate (powder shape (on average): 9 30.0 microns of major diameters; 6 microns of minor axis; 0.5 micron of thickness) spherical polymethyl methacrylate resin (volume average particle size 30.00.4 micron; refractive index 1.49) red ferric oxide 1.7 yellow ferric oxide 0.3 Black Rouge, 1.2 ultramarines, 2.0 oil contents (three decanes) 6.0
The powder body composition is mixed with the HENSCHEL blender, then to wherein add oil content further mixed after, promptly get the powdery eye shadow in the vessel of packing into.
The powdery eye shadow of gained, no matter the smooth feeling on skin, foundation cream adhere to all well, can obtain wetness sensation, and also good to convexo-concave non-remarkableization effects such as pore, rugula stricture of vaginas.Embodiment 10
Make talcum powder by following composition.
(composition) % Talcum (10 microns of volume average particle size) 13.8 cetyl zinc phosphate sodium (18 microns of powder body shape (on average) major diameters, 30.0 14 microns of minor axis, 1 micron of thickness) spherical polymethyl methacrylate resin (volume average particle size 30.00.4 micron, refractive index 1.49) oil content (dimethyl polysiloxane) 6.0 glycyl lysine dipotassiums 0.1 spice 0.1
(method for making)
The powder body composition is mixed with the HENSCHEL blender, then to wherein add oil content further mixed after, promptly get talcum powder in the vessel of packing into.
The talcum powder of gained, no matter the smooth feeling on skin, foundation cream adhere to all well, can obtain wetness sensation, and also good to convexo-concave non-remarkableization effects such as pore, rugula stricture of vaginas.
Claims (7)
1, a kind of powdered cosmetic composition contains following composition (A) and (B), and (A) composition and (B) use level of composition add up to more than the 5 weight %, wherein:
(A) volume average particle size is greater than 0.1 micron, and less than 2 microns, refractive index is at the micropowder below 2, and content is 1～95 weight %
(B) minor axis be major diameter 1/1～1/100, thickness is the organic powder of major diameter 1/2, content is 1～95 weight %
2, according to the powdered cosmetic composition of claim 1 record, wherein the volume average particle size of the organic powder of composition (B) is 0.1 micron～100 microns.
3, according to the powdered cosmetic composition of claim 1 record, wherein composition (A) be shaped as spherical or granular.
4, according to the powdered cosmetic composition of claim 1 record, wherein composition (A) is to be selected from selected inorganic micro powder end in silicon dioxide, aluminium oxide, barium sulfate, aluminium hydroxide, calcium carbonate, magnesium silicate, magnesium carbonate, the aluminium silicate; And/or be selected from the organic micropowder end of polyamide, polyvinyl resin, acrylic resin, polymethyl methacrylate resin, cellulosic resin, polystyrene resin, styrene and acrylic copolymer, silicone resin.
5, the powdered cosmetic composition of putting down in writing according to claim 1; wherein composition (B) is to be selected from the alkyl phosphoric acid multivalent metal salt; the acylated amino multivalent metal salt; the amidosulfonic acid multivalent metal salt; the N-acyl-lysine; alpha-amido fatty acid, and the mixture more than a kind or 2 kinds of flat or tabular toner.
6, according to the powdered cosmetic composition of claim 1 record, wherein composition (A) is the mixture more than a kind or 2 kinds that is selected from barium sulfate, polyamide, polymethyl methacrylate resin and silicone resin; (B) be to be selected from the alkyl phosphoric acid multivalent metal salt, N-acyl-lysine, acylated amino multivalent metal salt, the mixture more than a kind or 2 kinds of N-acyl-lysine.
7, the cosmetic cosmetic composition of making according to the powdered cosmetic composition of claim 1 record.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP33815596A JP3308177B2 (en) | 1996-12-18 | 1996-12-18 | Powder cosmetics |
| JP338155/96 | 1996-12-18 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1185313A true CN1185313A (en) | 1998-06-24 |
| CN1271985C CN1271985C (en) | 2006-08-30 |
Family
ID=18315439
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 97125533 Expired - Fee Related CN1271985C (en) | 1996-12-18 | 1997-12-17 | Powdered cosmetic composition |
Country Status (3)
| Country | Link |
|---|---|
| JP (1) | JP3308177B2 (en) |
| CN (1) | CN1271985C (en) |
| TW (1) | TW491705B (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105853251A (en) * | 2015-01-23 | 2016-08-17 | 于杰 | Functional whitening moisturizer |
| CN109906072A (en) * | 2016-08-31 | 2019-06-18 | 株式会社爱茉莉太平洋 | Eye cosmetic composition with high adhesion force |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP4931631B2 (en) * | 2007-02-20 | 2012-05-16 | 株式会社トキワ | Water-in-oil emulsified makeup cosmetic |
-
1996
- 1996-12-18 JP JP33815596A patent/JP3308177B2/en not_active Expired - Fee Related
-
1997
- 1997-11-10 TW TW86116760A patent/TW491705B/en not_active IP Right Cessation
- 1997-12-17 CN CN 97125533 patent/CN1271985C/en not_active Expired - Fee Related
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105853251A (en) * | 2015-01-23 | 2016-08-17 | 于杰 | Functional whitening moisturizer |
| CN109906072A (en) * | 2016-08-31 | 2019-06-18 | 株式会社爱茉莉太平洋 | Eye cosmetic composition with high adhesion force |
Also Published As
| Publication number | Publication date |
|---|---|
| JP3308177B2 (en) | 2002-07-29 |
| JPH10175822A (en) | 1998-06-30 |
| CN1271985C (en) | 2006-08-30 |
| TW491705B (en) | 2002-06-21 |
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